JP7486884B2 - 高吸水性樹脂の製造方法 - Google Patents

高吸水性樹脂の製造方法 Download PDF

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Publication number
JP7486884B2
JP7486884B2 JP2023504858A JP2023504858A JP7486884B2 JP 7486884 B2 JP7486884 B2 JP 7486884B2 JP 2023504858 A JP2023504858 A JP 2023504858A JP 2023504858 A JP2023504858 A JP 2023504858A JP 7486884 B2 JP7486884 B2 JP 7486884B2
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Prior art keywords
meth
acrylate
ppmw
superabsorbent resin
glycol
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JP2023504858A
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English (en)
Japanese (ja)
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JP2023535949A (ja
Inventor
セリン・イ
スン・フン・ヤン
ジュ・ウン・キム
ジュニル・チョ
ホヨン・イ
ジュンミン・イ
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LG Chem Ltd
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LG Chem Ltd
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Priority claimed from KR1020220012653A external-priority patent/KR102909962B1/ko
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04Acids, Metal salts or ammonium salts thereof
    • C08F20/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • C08L101/12Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
    • C08L101/14Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/24Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • A61L15/60Liquid-swellable gel-forming materials, e.g. super-absorbents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/10Aqueous solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/075Macromolecular gels
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/08Homopolymers or copolymers of acrylic acid esters

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Epidemiology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Hematology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Polymerization Catalysts (AREA)
JP2023504858A 2021-02-03 2022-01-28 高吸水性樹脂の製造方法 Active JP7486884B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR20210015453 2021-02-03
KR10-2021-0015453 2021-02-03
KR1020220012653A KR102909962B1 (ko) 2021-02-03 2022-01-27 고흡수성 수지의 제조 방법
KR10-2022-0012653 2022-01-27
PCT/KR2022/001592 WO2022169227A1 (fr) 2021-02-03 2022-01-28 Procédé de préparation d'un polymère superabsorbant

Publications (2)

Publication Number Publication Date
JP2023535949A JP2023535949A (ja) 2023-08-22
JP7486884B2 true JP7486884B2 (ja) 2024-05-20

Family

ID=82742293

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2023504858A Active JP7486884B2 (ja) 2021-02-03 2022-01-28 高吸水性樹脂の製造方法

Country Status (5)

Country Link
US (1) US20230287155A1 (fr)
EP (1) EP4166599A4 (fr)
JP (1) JP7486884B2 (fr)
CN (1) CN116249736B (fr)
WO (1) WO2022169227A1 (fr)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4861849A (en) * 1988-01-15 1989-08-29 The Dow Chemical Company Sodium thiosulfate as part of a redox initiator system for the polymerization of water-swellable polymers
EP0409136A3 (en) * 1989-07-18 1991-10-16 The Dow Chemical Company Erythorbate as part of a redox initiator system for the polymerization of water-swellable polymers
EP0603292A1 (fr) * 1991-09-09 1994-06-29 The Dow Chemical Company Polymeres superabsorbants et procede de production
JP2000038407A (ja) * 1998-07-24 2000-02-08 Nippon Shokubai Co Ltd 吸水性樹脂の製造方法
BRPI0509362A (pt) * 2004-03-31 2007-09-11 Nippon Catalytic Chem Ind agente absorvedor de lìquido aquoso e seu processo de produção
EP1900755B1 (fr) * 2005-07-04 2011-10-19 Sumitomo Seika Chemicals Co., Ltd. Procede de fabrication de resine absorbant l'eau
JP5718060B2 (ja) * 2009-02-06 2015-05-13 株式会社日本触媒 ポリアクリル酸(塩)系親水性樹脂およびその製造方法
JP6157853B2 (ja) * 2010-06-30 2017-07-05 株式会社日本触媒 ポリアクリル酸系吸水性樹脂及びその製造方法
CN105073792B (zh) * 2012-11-21 2017-08-11 巴斯夫欧洲公司 一种通过聚合单体溶液的液滴制备吸水性聚合物颗粒的方法
EP3000486B1 (fr) * 2014-09-23 2017-11-08 Evonik Degussa GmbH Production de super-absorbeur utilisant des machines d'extraction définies
US10537874B2 (en) * 2015-04-02 2020-01-21 Nippon Shokubai Co., Ltd. Method for producing particulate water-absorbing agent
WO2017170605A1 (fr) * 2016-03-28 2017-10-05 株式会社日本触媒 Agent d'absorption d'eau particulaire
US11602577B2 (en) * 2016-03-28 2023-03-14 Nippon Shokubai Co., Ltd. Water-absorbing agent and method for producing same, and absorbent article produced using water-absorbing agent
JP7064614B2 (ja) * 2018-09-21 2022-05-10 株式会社日本触媒 キレート剤を含む吸水性樹脂の製造方法

Also Published As

Publication number Publication date
CN116249736A (zh) 2023-06-09
JP2023535949A (ja) 2023-08-22
CN116249736B (zh) 2025-08-05
US20230287155A1 (en) 2023-09-14
EP4166599A1 (fr) 2023-04-19
WO2022169227A1 (fr) 2022-08-11
EP4166599A4 (fr) 2024-01-17

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