JPH01111180A - Throwaway cold accumulator and usage thereof - Google Patents

Throwaway cold accumulator and usage thereof

Info

Publication number
JPH01111180A
JPH01111180A JP62270968A JP27096887A JPH01111180A JP H01111180 A JPH01111180 A JP H01111180A JP 62270968 A JP62270968 A JP 62270968A JP 27096887 A JP27096887 A JP 27096887A JP H01111180 A JPH01111180 A JP H01111180A
Authority
JP
Japan
Prior art keywords
water
storage body
cold storage
permeable material
bag
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62270968A
Other languages
Japanese (ja)
Inventor
Isamu Tsuda
勇 津田
Satoshi Hosokawa
細川 敏
Itaru Yoshida
至 吉田
Michiyo Tsuda
津田 倫代
Keiichi Hayashi
敬一 林
Shigemi Yasuda
安田 成美
Yoko Noborihama
上り浜 洋子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OZEKI KAGAKU KOGYO KK
Original Assignee
OZEKI KAGAKU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OZEKI KAGAKU KOGYO KK filed Critical OZEKI KAGAKU KOGYO KK
Priority to JP62270968A priority Critical patent/JPH01111180A/en
Publication of JPH01111180A publication Critical patent/JPH01111180A/en
Pending legal-status Critical Current

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  • Freezing, Cooling And Drying Of Foods (AREA)
  • Laminated Bodies (AREA)

Abstract

PURPOSE: To obtain a disposable cold storage body by a method wherein at least two kinds of water absorbing high polymer agents different in water absorbing rate are wrapped and held in a bag formed into a sheet-shaped body and at least a part of the bag is made of a water permeable material. CONSTITUTION: In this disposable cold storage body, at least for two kinds of water absorbing high polymer agents different in water absorbing rate are wrapped and held in a bag formed into a sheet-shaped body, and at least a part of the bag is made of a water permeable material. The disposable cold storage body is immersed and held in normal temperature water or a normal temperature saline solution for several minutes and the water absorbing high polymer agents contact the water or the saline solution to be swelled absorbing water. Then, the cold storage body is frozen for several ten hours at about -20 deg.C in a refrigerator to be used for an object to be desired to reserve cold. This prevents water from flowing outside the cold storage body during the thawing period in the application process, hence causing no damage fouling it. The water permeable material herein used is nonwoven fiber, an open cell resin sheet, an adhesive sheet impregnated with activated charcoal, fibrous activated charcoal or the like. The non-water permeable material herein used is preferably a nylon/polyester laminated film viewed from strength and economic aspects.

Description

【発明の詳細な説明】 (イ)産業上の利用分野 本発明は生鮮食品、切り花などの低温少量輸送および貯
蔵、または病院および一般家庭の発熱患者などに使用す
る蓄冷体に関するもので、特に吸水速度の異なる少なく
とも2種の吸水性高分子剤による使い捨て蓄冷体および
その使用方法に関するものである。
Detailed Description of the Invention (a) Industrial Application Field The present invention relates to a cold storage body used for the low-temperature small volume transportation and storage of fresh foods, cut flowers, etc., or for fever patients in hospitals and general households. The present invention relates to a disposable cold storage body made of at least two kinds of water-absorbing polymer agents having different speeds, and a method for using the same.

(ロ)従来の技術 従来、吸水性高分子剤が被包されたシート状体の少なく
とも一部分が透水性の不織布などによって形成された蓄
冷体で、前記蓄冷体に注水することなく、蓄冷体を水と
接触させることにより、透水性素材表面から水が透水さ
れ、さらに吸水性高分子剤が吸水した後に凍結し、被保
冷体の使用に供する使い捨て蓄冷体がある。
(B) Conventional technology Conventionally, a cold storage body is formed of a sheet-like body in which a water-absorbing polymer agent is encapsulated, at least a portion of which is made of a water-permeable nonwoven fabric, etc., and the cold storage body is heated without pouring water into the cold storage body. When brought into contact with water, water permeates through the surface of a water-permeable material, and after the water-absorbing polymer agent absorbs water, it freezes, and is used as a cold storage object.

(ハ)発明が解決しようとする問題点 しかしながら、上記蓄冷体は使用時間の経過に従って、
吸水凍結された吸水性高分子剤の解氷とともに水和水以
外の毛細管現象、浸透圧現象によって吸水された自由水
の一部の水が加圧などにより放出される。その結果、蓄
冷体の表面不織布などに水滴が付着し、被保冷体を汚水
させる結果となる。
(c) Problems to be solved by the invention However, the above-mentioned cold storage body deteriorates over time as it is used.
When the frozen water-absorbing polymer agent is thawed, part of the free water other than hydration water absorbed by capillary action and osmotic pressure phenomenon is released by pressurization or the like. As a result, water droplets adhere to the surface nonwoven fabric of the cold storage body, resulting in the cold storage body being contaminated with water.

本発明はこの欠点を無くし、がっ、透水性不織布などに
よる透水利点を活用した使い捨て蓄冷体を提供すること
にある。
The object of the present invention is to eliminate this drawback and provide a disposable cold storage body that utilizes the water permeability advantages of a water permeable nonwoven fabric.

(ニ)問題点を解決するための手段 本発明は、シート状体に構成されたバッグ内に吸水速度
の異なる少なくとも2種の吸水性高分子剤が被包され、
該バッグの少なくとも一部分が透水性素材からなる使い
捨て蓄冷体である。
(D) Means for Solving the Problems The present invention provides at least two types of water-absorbing polymeric agents having different water-absorbing speeds encapsulated in a bag configured as a sheet-like body,
At least a portion of the bag is a disposable cold storage body made of a water-permeable material.

また、前記使い捨て蓄冷体を常温水中または常温食塩水
中に約数分間浸漬保持し、吸水性高分子剤を水または食
塩水と接触、吸水膨潤化後、同蓄冷体を冷凍庫で約−2
0°b 保冷体に使用する使い捨て蓄冷体の使用方法を含む。
Further, the disposable cold storage body is immersed in room temperature water or room temperature saline solution for about several minutes, and the water-absorbing polymer agent is brought into contact with water or saline solution to absorb water and swell, and then the same cold storage body is placed in a freezer for about -2 minutes.
0°b Includes how to use disposable cold storage bodies used as cold storage bodies.

吸水速度の異なる吸水性高分子剤として、まず吸水速度
の速いものとしては、アクリル酸ソーダ重合体(例えば
、住友化学工業株式会社製、商品名スミカゲルN−10
0)、アクリル酸・ビニルアルコール共重合体(例えば
、住友化学工業株式会社製、商品名スミカゲルS−50
)、澱粉・アクリル酸グラフト共重合体(例えば、三洋
化成工業株式会社製、商品名サンウェッ) T Mlo
oO)などであり、吸水速度の遅いものとしてはポリエ
チレンオキサイド変成物(例えば、住友化学工業株式会
社製、商品名スミカゲルR30F) 、EVA樹脂コン
パウンド(例えば、住友化学工業株式会社製、商品名ス
ミカゲルGRC−EVH−100)などがある吸水速度
の速い高分子剤と吸水速度の遅い高分子剤の配合割合は
前者が後者に対して50〜90重景%、好ましくは60
〜80重量%である。
Among water-absorbing polymer agents with different water-absorbing speeds, one that has a fast water-absorbing speed is sodium acrylate polymer (for example, manufactured by Sumitomo Chemical Co., Ltd., product name Sumikagel N-10).
0), acrylic acid/vinyl alcohol copolymer (for example, Sumikagel S-50, manufactured by Sumitomo Chemical Co., Ltd.
), starch/acrylic acid graft copolymer (for example, manufactured by Sanyo Chemical Industries, Ltd., trade name Sanwet) T Mlo
oO), and those with slow water absorption rates include polyethylene oxide modified products (for example, Sumikagel R30F, manufactured by Sumitomo Chemical Co., Ltd.), and EVA resin compounds (for example, Sumikagel GRC, manufactured by Sumitomo Chemical Co., Ltd., product name). -EVH-100) etc. The blending ratio of a polymeric agent with a high water absorption rate and a polymeric agent with a slow water absorption rate is 50 to 90%, preferably 60% to the latter.
~80% by weight.

本バッグの透水性素材としては不織布、連続多孔樹脂シ
ート、活性炭含浸接着シート、繊維状活性炭などが挙げ
られる。非透水性の素材としては強度や経済面からナイ
ロン・ポリエステル積層フィルムなどが望ましい。
Examples of water permeable materials for this bag include nonwoven fabric, continuous porous resin sheet, activated carbon impregnated adhesive sheet, and fibrous activated carbon. As the non-water permeable material, nylon/polyester laminated film is desirable from the viewpoint of strength and economy.

また、透水性素材の部分がシート状体に構成された両面
、片面、または片面の一部などいづれでもよい。
Further, the water-permeable material portion may be formed into a sheet-like body on both sides, one side, or a part of one side.

浸漬液は水または約3%濃度の食塩水であってもよい。The immersion liquid may be water or about 3% saline.

約3%濃度の食塩水を使用した場合には約2°Cの凝固
点降下がある。
When a saline solution with a concentration of about 3% is used, there is a freezing point depression of about 2°C.

(ホ)作用 吸水速度の異なる少なくとも2種の吸水性高分子剤を不
織布などで被包したバッグにその表面から短時間に透水
させ、凍結使用する場合に、蓄冷体の解氷時に吸水速度
の速い吸水性高分子剤の自由水の一部が同高分子剤から
放出されるが、未だ完全に吸水されていない吸水速度の
遅い吸水性高分子剤に補足されることにより不織布など
からの逆送水による蓄冷体外部への流水を防止する。
(E) Action: When a bag is made of at least two types of water-absorbing polymer agents with different water-absorbing speeds and is covered with non-woven fabric, water permeates through the surface of the bag in a short period of time, and the water-absorbing polymer agent with different water-absorbing speeds is used when the cold storage body is thawed. A part of the free water of the fast water-absorbing polymer is released from the same polymer, but it is captured by the water-absorbing polymer with a slow water absorption rate that has not yet completely absorbed the water, resulting in reverse water absorption from nonwoven fabrics, etc. Prevents water from flowing outside the cold storage body due to water supply.

(へ)実施例 吸水速度の速い吸水性高分子剤のアクリル酸ソーダ重合
体2.0gと吸水速度の遅い吸水性高分子剤のEVA樹
脂コンパウンド0.5 gの配合剤を、片面シートを透
水性素材のポリプロピレン不織布、他面シートを非透水
性素材のポリエチレンフィルムに被包させ、その周縁部
を熱接着法により接着して、第1図に示す使い捨て蓄冷
体を作成した上記蓄冷体を常温(25°C)水中に5分
間浸漬保持した後に、−20°Cの冷凍庫で24時間凍
結させた蓄冷体内の吸水速度の異なる2種の吸水性高分
子剤1.0g当たりの25°C水道水における吸水量と
吸水時間との関係を第2図に示した。なお、吸水能の測
定法はティーバッグ法によった。
(F) Example A mixture of 2.0 g of sodium acrylate polymer, a water-absorbing polymer agent with a fast water absorption rate, and 0.5 g of an EVA resin compound, a water-absorbing polymer agent with a slow water absorption rate, was permeable through a single-sided sheet. The disposable cold storage body shown in Fig. 1 was created by wrapping a polypropylene nonwoven fabric made of a transparent material and a sheet on the other side in a polyethylene film made of a non-water permeable material, and bonding the periphery using a thermal bonding method. (25°C) After being immersed in water for 5 minutes, it was frozen in a -20°C freezer for 24 hours. Two kinds of water-absorbing polymers with different water absorption rates in the cold storage body per 1.0 g of 25°C tap water. The relationship between the amount of water absorbed and the water absorption time is shown in Figure 2. The water absorption capacity was measured by the tea bag method.

第2図から明らかなように、吸水速度の速い吸水性高分
子剤は5分間で水道水を400倍まで吸水し平衡に達す
るが、吸水速度の遅い吸水性高分子剤は5分間で水道水
を50倍、60分間で200倍まで吸水し、その後は平
衡状態となった。即ち、蓄冷体の浸漬5分間後における
吸水性高分子剤の吸水量は一方の吸水速度の速い吸水性
高分子剤がその吸水能の100%まで達するのに対して
、この時点で他方の吸水速度の遅い吸水性高分子剤の吸
水量は未だその吸水能の25%であった。
As is clear from Figure 2, a water-absorbing polymer agent with a fast water absorption rate absorbs 400 times as much tap water in 5 minutes and reaches equilibrium, but a water-absorbing polymer agent with a slow water absorption rate absorbs tap water in 5 minutes. It absorbed 50 times more water, up to 200 times more water in 60 minutes, and then reached an equilibrium state. In other words, the amount of water absorbed by the water-absorbing polymer agents after 5 minutes of immersion in the cold storage body is that one of the water-absorbing polymer agents, which has a faster water absorption rate, reaches 100% of its water absorption capacity, while the other water-absorbing agent reaches 100% of its water absorption capacity at this point. The amount of water absorbed by the slow water absorbing polymer agent was still 25% of its water absorption capacity.

本蓄冷体の吸水後の内容重量は825gであった凍結し
た蓄冷体を、品温2°Cまで予冷した被保冷体5.0 
kgを含む発泡容器(厚さ25m、内径300mm X
200 mm x200 [11m H)に入れ密封し
、30°Cの恒温槽内で保存した。保存10時間後の同
容器内温度は第3図かられかるように5°Cであった。
The content weight of this cold storage body after water absorption was 825g.The frozen cold storage body was pre-cooled to a product temperature of 2°C.
Foam container containing kg (thickness 25m, inner diameter 300mm
It was placed in a 200 mm x 200 [11 m H], sealed, and stored in a constant temperature bath at 30°C. The temperature inside the same container after 10 hours of storage was 5°C as seen in Figure 3.

この時点で同様に作成した別の容器を開封したが蓄冷体
は解氷されていなかった。同容器から取り出した前記蓄
冷体を室温で解氷させ、透水性素材の不織布表面の濡れ
程度を検討したが、不織布表面からの逆透水による濡れ
が認められなかった。
At this point, another similarly prepared container was opened, but the ice had not thawed. The cold storage body taken out from the same container was thawed at room temperature and the degree of wetting of the surface of the nonwoven fabric of the water permeable material was examined, but no wetting due to reverse water permeation from the surface of the nonwoven fabric was observed.

一方、吸水速度の速い吸水性高分子剤のアクリル酸ソー
ダ重合体2.0gのみによる前記同様の方法で使い捨て
蓄冷体を作成し、前記同法により、凍結したものを解氷
した結果、透水性素材の不織布表面に逆透水による水滴
が認められた。
On the other hand, a disposable cold storage body was prepared using only 2.0 g of sodium acrylate polymer, which is a water-absorbing polymer agent with a high water absorption rate, in the same manner as above, and as a result of thawing the frozen object using the same method, water permeability Water droplets due to reverse water permeation were observed on the nonwoven surface of the material.

(ト)発明の効果 本発明はドライタイプの蓄冷体に手作業で水を注入する
ことなく、効率的に水槽などに蓄冷体を短時間浸漬して
凍結することにより被保冷体の使用に供することができ
る。さらに、その使用過程での解氷時における蓄冷体外
への流水が防止され、被保冷体に対する汚水被害がない
(G) Effects of the Invention The present invention efficiently immerses the cold storage body in a water tank or the like for a short time and freezes it, without manually injecting water into the dry type cold storage body, thereby making it usable as a cold storage body. be able to. Furthermore, water is prevented from flowing out of the cold storage body when the ice is thawed during its use, and there is no sewage damage to the cold storage body.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明に係る使い捨て蓄冷体の一実施例の断
面図、第2図は、実施例について、吸水速度の異なる吸
水性高分子剤の吸水量と吸水時間との関係を示すグラフ
、第3図は、同実施例の発泡容器内温度の時間経過を示
すグラフである。 1−−−−−・−−−−−一・透水性素材、2−−−−
−−−−−−一非透水性素材、3−−−−−−−−−−
−−一吸水速度の速い吸水性高分子剤、4−−−−−−
−−−−−−一吸水速度の遅い吸水性高分子剤び く 
筆 ; 手続補正書(自発) 昭和62年11月 270 j 事件の表示    昭和62年特許願第27096
8号2 発明の名称     使い捨て蓄冷体およびそ
の使用方法3 補正をする者 事件との関係 幌午出願人 4 補正命令の日限 ■、明細書、第4頁第16〜17行のr−−−−−一な
どがある。」の次に「さらには同−剤であっても吸水性
高分子の表面と内部において架橋度の勾配をつけた場合
、または同−剤の粒径の大小による場合などのいづれで
もよい。吸水性高分子剤は粒状、シート状、吸水性高分
子剤含浸または付着不織布などのいづれでもよい。」を
挿入する。 ■、明細書、第5頁第8行と第9行の間に「バッグ両面
の接着はバッグ自身が小さい場合にはハングの周縁部分
のみでもよい。バッグが大きい場合にはその周縁部分お
よびバッグ内に設けた複数の区画の区画部分を接着する
。」を挿入する。 昭和62年12月11日 特許庁長官            殿11 事件。表
示    昭和6油晰許願第270968号2 発明の
名称     使い捨て蓄冷体およびその使用方法3 
補正をする者 事件との関係 特許出願人 住所(居所)兵庫県神戸市東灘区木山中町1丁目11番
6号4 補正命令の日限 5 補正の対象   明細書の発明の詳細な説明の欄1
、明細書、第4頁第19行目、「後者」とあるを、「両
者」と補正する。 昭和62年12月 25日 特許庁長官            殿3 補正をする
者 事件との関係 特許出願人 (MPiA(MM)  兵庫県神戸市東灘区本山中町1
丁目11番6号4 補正命令の日限 ■、明細書、第4頁第19行から第20行まで、「に対
して50〜90重量%、好ましくは60〜80重量%で
ある。」とあるを、「に対して20〜95重景%、好ま
しくは50〜90重量%、さらに好ましくは60〜80
重量%である。jと補正する。
FIG. 1 is a cross-sectional view of an embodiment of the disposable cool storage body according to the present invention, and FIG. 2 is a graph showing the relationship between water absorption amount and water absorption time of water-absorbing polymer agents with different water absorption rates for the embodiment. , FIG. 3 is a graph showing the temperature within the foaming container over time in the same example. 1-------・-----1. Water-permeable material, 2-------
--------- 1. Non-water permeable material, 3.
---Water-absorbing polymer agent with high water absorption rate, 4-------
−−−−−−Water-absorbing polymer agent with slow water absorption rate
Written by: Procedural amendment (spontaneous) November 1988 270 j Indication of case Patent application No. 27096 of 1988
No. 8 No. 2 Title of the invention Disposable cold storage body and its method of use 3 Relationship with the case of the person making the amendment Horogo applicant 4 Date of amendment order■, Specification, page 4, lines 16-17 r--- --There are one and so on. '' followed by ``Furthermore, even if the same agent is used, the degree of crosslinking may be gradient between the surface and inside of the water-absorbing polymer, or the particle size of the same agent may be large or small. The absorbent polymer agent may be in the form of particles, sheets, nonwoven fabrics impregnated with or adhered to the water absorbing polymer agent.'' ■, Specification, page 5, lines 8 and 9: ``If the bag itself is small, it is sufficient to glue only the periphery of the hang.If the bag is large, the periphery and the bag may be glued together.'' Insert "Glue the compartment parts of the multiple compartments provided inside." December 11, 1988, Commissioner of the Patent Office 11 Case. Indication: Showa 6 Yusei Patent Application No. 270968 2 Title of Invention: Disposable cold storage body and method of using the same 3
Relationship with the case of the person making the amendment Patent applicant address (residence) 1-11-6-4 Kiyamanaka-cho, Higashinada-ku, Kobe-shi, Hyogo Prefecture Date of amendment order 5 Subject of amendment Detailed explanation of the invention in the specification 1
, Specification, page 4, line 19, "the latter" is amended to read "both." December 25, 1988 Commissioner of the Japan Patent Office 3 Relationship with the case of the person making the amendment Patent applicant (MPiA (MM) 1 Motoyama Nakacho, Higashinada Ward, Kobe City, Hyogo Prefecture
Chome 11-6 4 Date of amendment order ■, Specification, page 4, lines 19 to 20, it says "50 to 90% by weight, preferably 60 to 80% by weight." 20 to 95% by weight, preferably 50 to 90% by weight, more preferably 60 to 80% by weight
Weight%. Correct it as j.

Claims (1)

【特許請求の範囲】 1 シート状体に構成されたバッグ内に吸水速度の異な
る少なくとも2種の吸水性高分子剤が被包され、該バッ
グの少なくとも一部分が透水性素材であることを特徴と
する使い捨て蓄冷体。 2 透水性素材が不織布、連続多孔樹脂シート、活性炭
含浸接着シート、繊維状活性炭からなる群より選ばれた
1種類である特許請求の範囲第1項記載の使い捨て蓄冷
体。 3 シート状体に構成されたバッグ内に吸水速度の異な
る少なくとも2種の吸水性高分子剤が被包され、該バッ
グの少なくとも一部分が透水性素材である使い捨て蓄冷
体を常温水中または常温食塩水中に約数分間浸漬保持し
、吸水性高分子剤を水または食塩水と接触、吸水膨潤処
理し、該蓄冷体を冷凍庫で約−20℃、数十時間凍結し
てなる被保冷体への使い捨て蓄冷体の使用方法。 4 透水性素材が不織布、連続多孔樹脂シート、活性炭
含浸接着シート、繊維状活性炭からなる群より選ばれた
1種類である特許請求の範囲第3項記載の使い捨て蓄冷
体。
[Scope of Claims] 1. At least two types of water-absorbing polymeric agents having different water absorption speeds are encapsulated in a bag configured as a sheet-like body, and at least a portion of the bag is made of a water-permeable material. A disposable cold storage body. 2. The disposable cool storage body according to claim 1, wherein the water-permeable material is one type selected from the group consisting of a nonwoven fabric, a continuous porous resin sheet, an activated carbon-impregnated adhesive sheet, and a fibrous activated carbon. 3. A disposable cold storage body in which at least two types of water-absorbing polymeric agents having different water absorption rates are encapsulated in a sheet-shaped bag, and at least a portion of the bag is made of a water-permeable material is placed in room temperature water or room temperature saline water. The water-absorbing polymer agent is immersed in water for about several minutes, brought into contact with water or saline, treated to absorb and swell, and then frozen in a freezer at about -20°C for several tens of hours. How to use a cold storage body. 4. The disposable cool storage body according to claim 3, wherein the water-permeable material is one type selected from the group consisting of a nonwoven fabric, a continuous porous resin sheet, an activated carbon-impregnated adhesive sheet, and a fibrous activated carbon.
JP62270968A 1987-10-26 1987-10-26 Throwaway cold accumulator and usage thereof Pending JPH01111180A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62270968A JPH01111180A (en) 1987-10-26 1987-10-26 Throwaway cold accumulator and usage thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62270968A JPH01111180A (en) 1987-10-26 1987-10-26 Throwaway cold accumulator and usage thereof

Publications (1)

Publication Number Publication Date
JPH01111180A true JPH01111180A (en) 1989-04-27

Family

ID=17493536

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62270968A Pending JPH01111180A (en) 1987-10-26 1987-10-26 Throwaway cold accumulator and usage thereof

Country Status (1)

Country Link
JP (1) JPH01111180A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04363137A (en) * 1991-06-06 1992-12-16 Koreatsu Ito Salt water ice pack and salt water absorbing pack
FR2719599A1 (en) * 1994-05-06 1995-11-10 Zincone Anne Granular refrigerant compsn.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04363137A (en) * 1991-06-06 1992-12-16 Koreatsu Ito Salt water ice pack and salt water absorbing pack
FR2719599A1 (en) * 1994-05-06 1995-11-10 Zincone Anne Granular refrigerant compsn.

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