JPH01122919A - ゼオライトの二段合成方法 - Google Patents

ゼオライトの二段合成方法

Info

Publication number: JPH01122919A
Authority: JP; Japan
Prior art keywords: sio; zeolite; mixture; reaction mixture; silica
Prior art date: 1987-08-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP63215322A

Other languages

English (en)

Japanese (ja)

Inventor

Pochen Chu

ポーチエン　チユウ

Wayne Kirker Garry

ゲリー　ウエイン　キルカー

Donald J Klocke

ドナルド　ジヨセフ　クロツク

Pooru Makuuiriamuzu Jiyon

ジヨン　ポール　マクウイリアムズ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-08-31

Filing date

1988-08-31

Publication date

1989-05-16

1987-08-31 Priority claimed from US07/091,612 external-priority patent/US5063038A/en

1988-08-31 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1989-05-16 Publication of JPH01122919A publication Critical patent/JPH01122919A/ja

Status Pending legal-status Critical Current

Links

239000010457 zeolite Substances 0.000 title claims description 71
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 55
229910021536 Zeolite Inorganic materials 0.000 title claims description 52
230000015572 biosynthetic process Effects 0.000 title claims description 18
238000003786 synthesis reaction Methods 0.000 title claims description 17
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 111
238000000034 method Methods 0.000 claims description 54
239000000377 silicon dioxide Substances 0.000 claims description 51
239000000203 mixture Substances 0.000 claims description 45
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 42
239000011541 reaction mixture Substances 0.000 claims description 40
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 32
239000003054 catalyst Substances 0.000 claims description 32
238000006243 chemical reaction Methods 0.000 claims description 29
239000013078 crystal Substances 0.000 claims description 29
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
239000003795 chemical substances by application Substances 0.000 claims description 23
RWRDLPDLKQPQOW-UHFFFAOYSA-N tetrahydropyrrole Natural products C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 22
-1 alkali metal cations Chemical class 0.000 claims description 21
230000008569 process Effects 0.000 claims description 19
230000006911 nucleation Effects 0.000 claims description 16
238000010899 nucleation Methods 0.000 claims description 16
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 12
239000005977 Ethylene Substances 0.000 claims description 12
238000005804 alkylation reaction Methods 0.000 claims description 12
238000002425 crystallisation Methods 0.000 claims description 12
230000008025 crystallization Effects 0.000 claims description 12
150000002009 diols Chemical class 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 10
230000029936 alkylation Effects 0.000 claims description 10
238000006900 dealkylation reaction Methods 0.000 claims description 9
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 9
239000002131 composite material Substances 0.000 claims description 8
229910052708 sodium Inorganic materials 0.000 claims description 8
239000011734 sodium Substances 0.000 claims description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
239000004115 Sodium Silicate Substances 0.000 claims description 7
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
229910052911 sodium silicate Inorganic materials 0.000 claims description 7
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
150000001340 alkali metals Chemical class 0.000 claims description 6
230000020335 dealkylation Effects 0.000 claims description 6
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
230000001376 precipitating effect Effects 0.000 claims description 5
239000011230 binding agent Substances 0.000 claims description 4
238000001354 calcination Methods 0.000 claims description 4
150000002894 organic compounds Chemical class 0.000 claims description 4
230000002194 synthesizing effect Effects 0.000 claims description 4
239000003513 alkali Substances 0.000 claims description 3
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
238000005406 washing Methods 0.000 claims description 3
239000011363 dried mixture Substances 0.000 claims description 2
125000003916 ethylene diamine group Chemical group 0.000 claims description 2
125000000719 pyrrolidinyl group Chemical group 0.000 claims description 2
239000005416 organic matter Substances 0.000 claims 1
238000001694 spray drying Methods 0.000 claims 1
239000000243 solution Substances 0.000 description 16
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
239000002243 precursor Substances 0.000 description 15
150000001768 cations Chemical class 0.000 description 14
229910052739 hydrogen Inorganic materials 0.000 description 14
230000000694 effects Effects 0.000 description 13
239000001257 hydrogen Substances 0.000 description 13
239000000463 material Substances 0.000 description 12
229910052782 aluminium Inorganic materials 0.000 description 11
150000002430 hydrocarbons Chemical class 0.000 description 11
239000000047 product Substances 0.000 description 11
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
239000007787 solid Substances 0.000 description 10
229930195733 hydrocarbon Natural products 0.000 description 9
239000008096 xylene Substances 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
230000003197 catalytic effect Effects 0.000 description 8
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
229910000323 aluminium silicate Inorganic materials 0.000 description 7
239000002245 particle Substances 0.000 description 7
238000001556 precipitation Methods 0.000 description 7
238000006317 isomerization reaction Methods 0.000 description 6
239000011148 porous material Substances 0.000 description 6
239000002244 precipitate Substances 0.000 description 6
LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 6
239000001993 wax Substances 0.000 description 6
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
238000002441 X-ray diffraction Methods 0.000 description 5
239000002253 acid Substances 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
239000002168 alkylating agent Substances 0.000 description 5
229940100198 alkylating agent Drugs 0.000 description 5
150000001491 aromatic compounds Chemical class 0.000 description 5
150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
239000002199 base oil Substances 0.000 description 5
229910052681 coesite Inorganic materials 0.000 description 5
229910052906 cristobalite Inorganic materials 0.000 description 5
239000007788 liquid Substances 0.000 description 5
229910052710 silicon Inorganic materials 0.000 description 5
239000010703 silicon Substances 0.000 description 5
235000012239 silicon dioxide Nutrition 0.000 description 5
229910052682 stishovite Inorganic materials 0.000 description 5
239000000126 substance Substances 0.000 description 5
229910052905 tridymite Inorganic materials 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
150000002431 hydrogen Chemical class 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
229910052697 platinum Inorganic materials 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
230000008859 change Effects 0.000 description 3
238000007796 conventional method Methods 0.000 description 3
238000005336 cracking Methods 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
238000007323 disproportionation reaction Methods 0.000 description 3
238000001035 drying Methods 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000000499 gel Substances 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
239000000314 lubricant Substances 0.000 description 3
238000004062 sedimentation Methods 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
238000006467 substitution reaction Methods 0.000 description 3
238000010555 transalkylation reaction Methods 0.000 description 3
GWHJZXXIDMPWGX-UHFFFAOYSA-N 1,2,4-trimethylbenzene Chemical compound CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
241000272814 Anser sp. Species 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
241000255925 Diptera Species 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
239000000908 ammonium hydroxide Substances 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
229910052796 boron Inorganic materials 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000002178 crystalline material Substances 0.000 description 2
238000002447 crystallographic data Methods 0.000 description 2
238000006356 dehydrogenation reaction Methods 0.000 description 2
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000000295 fuel oil Substances 0.000 description 2
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
239000012535 impurity Substances 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000003921 oil Substances 0.000 description 2
125000001477 organic nitrogen group Chemical group 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
229910002027 silica gel Inorganic materials 0.000 description 2
239000000741 silica gel Substances 0.000 description 2
229910052814 silicon oxide Inorganic materials 0.000 description 2
241000894007 species Species 0.000 description 2
238000010025 steaming Methods 0.000 description 2
150000003738 xylenes Chemical class 0.000 description 2
VIDOPANCAUPXNH-UHFFFAOYSA-N 1,2,3-triethylbenzene Chemical compound CCC1=CC=CC(CC)=C1CC VIDOPANCAUPXNH-UHFFFAOYSA-N 0.000 description 1
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical group CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
241001580017 Jana Species 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
241001494479 Pecora Species 0.000 description 1
239000011149 active material Substances 0.000 description 1
150000001260 acyclic compounds Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
150000004645 aluminates Chemical class 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
229940045985 antineoplastic platinum compound Drugs 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
239000003637 basic solution Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
239000000571 coke Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
125000002592 cumenyl group Chemical class C1(=C(C=CC=C1)*)C(C)C 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
238000001514 detection method Methods 0.000 description 1
230000004069 differentiation Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
229910001387 inorganic aluminate Inorganic materials 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052909 inorganic silicate Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
238000011068 loading method Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
150000002892 organic cations Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
WHOPEPSOPUIRQQ-UHFFFAOYSA-N oxoaluminum Chemical compound O1[Al]O[Al]1 WHOPEPSOPUIRQQ-UHFFFAOYSA-N 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
150000003058 platinum compounds Chemical class 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
230000010287 polarization Effects 0.000 description 1
230000036619 pore blockages Effects 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
239000012254 powdered material Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000006257 total synthesis reaction Methods 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
- C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
- C07C4/18—Catalytic processes
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
- C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Geology (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Inorganic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP63215322A 1987-08-31 1988-08-31 ゼオライトの二段合成方法 Pending JPH01122919A (ja)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US9161387A	1987-08-31	1987-08-31
US07/091,612 US5063038A (en)	1985-10-21	1987-08-31	Zeolite synthesis using an alcohol or like molecule
US91613		1987-08-31
US91612		1987-08-31

Publications (1)

Publication Number	Publication Date
JPH01122919A true JPH01122919A (ja)	1989-05-16

Family

ID=26784141

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP63215322A Pending JPH01122919A (ja)	1987-08-31	1988-08-31	ゼオライトの二段合成方法

Country Status (9)

Country	Link
EP (1)	EP0306181B1 (2)
JP (1)	JPH01122919A (2)
KR (1)	KR970000302B1 (2)
AU (1)	AU610924B2 (2)
CA (1)	CA1321385C (2)
DE (1)	DE3874658T2 (2)
DK (1)	DK169252B1 (2)
IN (1)	IN171677B (2)
NZ (1)	NZ225852A (2)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0362484U (2) *	1989-10-20	1991-06-19
JP2001525781A (ja) *	1996-07-31	2001-12-11	シェブロンユー．エス．エー．インコーポレイテッド	有機テンプレートを用いたｙ型ホージャサイトの製造
JP2004535479A (ja) *	2001-04-26	2004-11-25	エクソンモービルリサーチアンドエンジニアリングカンパニー	炭化水素ストリームの異性化脱ロウ方法
JP2006512268A (ja) *	2002-12-30	2006-04-13	エスケーコーポレイション	有機テンプレートなしで可変温度を用いてｚｓｍ−５を製造する方法
JP2007050403A (ja) *	2005-08-15	2007-03-01	China Petrochemical Corp	トルエン形状選択的アルキル化によるパラキシレン製造に使用される触媒の製造法
JP2008184381A (ja) *	2007-01-30	2008-08-14	Ifp	Ｉｚｍ−１結晶固体およびその調製方法
WO2010018711A1 (ja) *	2008-08-12	2010-02-18	株式会社明電舎	低級炭化水素芳香族化触媒及び芳香族化合物の製造方法
JP2011246339A (ja) *	2010-04-28	2011-12-08	Jgc Catalysts & Chemicals Ltd	新規ペンタシル型ゼオライトおよびその合成方法
JP2024503644A (ja) *	2021-01-07	2024-01-26	中国石油化工股▲ふん▼有限公司	Ｚｓｍ－２３分子篩およびその調製方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5073530A (en) *	1989-05-10	1991-12-17	Chevron Research And Technology Company	Hydrocracking catalyst and process
EP0614853B1 (en) *	1993-02-02	1999-04-21	Tosoh Corporation	Method of producing zeolite beta
FR2805255B1 (fr)	2000-02-21	2002-04-12	Inst Francais Du Petrole	Zeolithe mtt comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des paraffines lineaires
EP2046703A1 (en) *	2006-07-27	2009-04-15	Total Petrochemicals Research Feluy	Catalytic conversion of alkylaromatic compounds
US8518847B2 (en)	2009-09-30	2013-08-27	Uop Llc	Aromatic alkylation catalyst
TWI411578B (zh) *	2010-02-06	2013-10-11	Dalian Chemical Physics Inst	Synthesis of a Small Grain Rare Earth - ZSM5 / ZSM11 Co - Crystallized Zeolite
CN111054426A (zh) *	2018-10-16	2020-04-24	中国石油化工股份有限公司	用于甲苯甲醇侧链烷基化制乙苯和苯乙烯的催化剂及其应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4016245A (en) *	1973-09-04	1977-04-05	Mobil Oil Corporation	Crystalline zeolite and method of preparing same
CA1064890A (en) *	1975-06-10	1979-10-23	Mae K. Rubin	Crystalline zeolite, synthesis and use thereof
DK155176C (da) *	1978-06-22	1989-07-17	Snam Progetti	Fremgangsmaade til fremstilling af aluminiumoxidmodificeret siliciumdioxid
CA1282398C (en) *	1985-10-21	1991-04-02	Donald J. Klocke	Synthesis of zeolites zsm-22 and zsm-23

1988
- 1988-08-11 IN IN577/MAS/88A patent/IN171677B/en unknown
- 1988-08-17 KR KR1019880010458A patent/KR970000302B1/ko not_active Expired - Fee Related
- 1988-08-17 DK DK460088A patent/DK169252B1/da not_active IP Right Cessation
- 1988-08-17 NZ NZ225852A patent/NZ225852A/xx unknown
- 1988-08-18 CA CA000575098A patent/CA1321385C/en not_active Expired - Fee Related
- 1988-08-18 EP EP88307651A patent/EP0306181B1/en not_active Expired - Lifetime
- 1988-08-18 DE DE8888307651T patent/DE3874658T2/de not_active Expired - Fee Related
- 1988-08-19 AU AU21136/88A patent/AU610924B2/en not_active Ceased
- 1988-08-31 JP JP63215322A patent/JPH01122919A/ja active Pending

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0362484U (2) *	1989-10-20	1991-06-19
JP2001525781A (ja) *	1996-07-31	2001-12-11	シェブロンユー．エス．エー．インコーポレイテッド	有機テンプレートを用いたｙ型ホージャサイトの製造
JP2004535479A (ja) *	2001-04-26	2004-11-25	エクソンモービルリサーチアンドエンジニアリングカンパニー	炭化水素ストリームの異性化脱ロウ方法
JP2006512268A (ja) *	2002-12-30	2006-04-13	エスケーコーポレイション	有機テンプレートなしで可変温度を用いてｚｓｍ−５を製造する方法
JP2007050403A (ja) *	2005-08-15	2007-03-01	China Petrochemical Corp	トルエン形状選択的アルキル化によるパラキシレン製造に使用される触媒の製造法
JP2008184381A (ja) *	2007-01-30	2008-08-14	Ifp	Ｉｚｍ−１結晶固体およびその調製方法
WO2010018711A1 (ja) *	2008-08-12	2010-02-18	株式会社明電舎	低級炭化水素芳香族化触媒及び芳香族化合物の製造方法
JP2010042348A (ja) *	2008-08-12	2010-02-25	Meidensha Corp	低級炭化水素芳香族化触媒及び芳香族化合物の製造方法
JP2011246339A (ja) *	2010-04-28	2011-12-08	Jgc Catalysts & Chemicals Ltd	新規ペンタシル型ゼオライトおよびその合成方法
JP2024503644A (ja) *	2021-01-07	2024-01-26	中国石油化工股▲ふん▼有限公司	Ｚｓｍ－２３分子篩およびその調製方法

Also Published As

Publication number	Publication date
DK169252B1 (da)	1994-09-26
DK460088D0 (da)	1988-08-17
EP0306181A3 (en)	1989-06-07
EP0306181A2 (en)	1989-03-08
DK460088A (da)	1989-04-12
IN171677B (2)	1992-12-05
AU610924B2 (en)	1991-05-30
EP0306181B1 (en)	1992-09-16
KR970000302B1 (ko)	1997-01-08
CA1321385C (en)	1993-08-17
NZ225852A (en)	1991-02-26
AU2113688A (en)	1989-03-02
DE3874658D1 (de)	1992-10-22
DE3874658T2 (de)	1993-04-22
KR890003622A (ko)	1989-04-15

Publication	Publication Date	Title
US5160500A (en)	1992-11-03	Zeolite synthesis using an alcohol or like molecules
US5063038A (en)	1991-11-05	Zeolite synthesis using an alcohol or like molecule
US4100262A (en)	1978-07-11	Synthesis of zeolite ZSM-5
US5397454A (en)	1995-03-14	Hydrocarbon conversion process using zeolite SSZ-32 having constraint index of 13 or greater
CA1231980A (en)	1988-01-26	Alkylation of aromatic hydrocarbons
US5342596A (en)	1994-08-30	Process for making theta-1 zeolite
US5053373A (en)	1991-10-01	Zeolite SSZ-32
JP3499870B2 (ja)	2004-02-23	ゼオライトｓｓｚ−３５
US3972983A (en)	1976-08-03	Crystalline zeolite ZSM-20 and method of preparing same
US4108881A (en)	1978-08-22	Synthesis of zeolite ZSM-11
US5236575A (en)	1993-08-17	Synthetic porous crystalline mcm-49, its synthesis and use
US4956514A (en)	1990-09-11	Process for converting olefins to higher hydrocarbons
US4021331A (en)	1977-05-03	Organic compound conversion by zeolite ZSM-20 catalysts
US6150293A (en)	2000-11-21	Preparation of zeolite bound by MFI structure type zeolite and use thereof
US5534656A (en)	1996-07-09	Organic compound conversion with MCM-58
US5116794A (en)	1992-05-26	Method for enhancing the activity of zeolite beta
CA1324615C (en)	1993-11-23	Zeolite ssz-26
US4112056A (en)	1978-09-05	Preparation of zeolites
KR100978979B1 (ko)	2010-08-30	분자체의 고 처리량 제조 방법
US4968402A (en)	1990-11-06	Process for upgrading hydrocarbons
JPH11501286A (ja)	1999-02-02	ゼオライト結合ゼオライト触媒を用いる炭化水素転化プロセス
US5200377A (en)	1993-04-06	Zeolite SSZ-28
CA2049035A1 (en)	1991-07-27	Zeolite ssz-31
EP0306181B1 (en)	1992-09-16	Two stage synthesis of zeolite
US4390457A (en)	1983-06-28	Synthesis of molecular sieves using 2-aminopyridine as a template