JPH01126310A - 改良された水吸収性樹脂の製造方法 - Google Patents

改良された水吸収性樹脂の製造方法

Info

Publication number: JPH01126310A
Authority: JP; Japan
Prior art keywords: monomer solution; initiator; monomer; polymerization; water
Prior art date: 1987-08-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP63203065A

Other languages

English (en)

Japanese (ja)

Inventor

William Alexander

ウィリアム　アレクサンダー

Mark Anderson

アンダーソンマーク

Barbara R Regan

バーバラ　アール　レーガン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Amcol International Corp

Original Assignee

Amcol International Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-08-14

Filing date

1988-08-15

Publication date

1989-05-18

1988-08-15 Application filed by Amcol International Corp filed Critical Amcol International Corp

1989-05-18 Publication of JPH01126310A publication Critical patent/JPH01126310A/ja

Status Pending legal-status Critical Current

Links

XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 47
239000011347 resin Substances 0.000 title claims abstract description 34
229920005989 resin Polymers 0.000 title claims abstract description 34
238000004519 manufacturing process Methods 0.000 title claims description 6
239000000178 monomer Substances 0.000 claims abstract description 284
239000003999 initiator Substances 0.000 claims abstract description 107
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 84
238000002156 mixing Methods 0.000 claims abstract description 80
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 78
239000012966 redox initiator Substances 0.000 claims abstract description 73
238000006116 polymerization reaction Methods 0.000 claims abstract description 50
238000000034 method Methods 0.000 claims abstract description 38
229920002554 vinyl polymer Polymers 0.000 claims abstract description 26
239000007787 solid Substances 0.000 claims abstract description 15
238000000354 decomposition reaction Methods 0.000 claims abstract description 4
239000003795 chemical substances by application Substances 0.000 claims description 30
239000000203 mixture Substances 0.000 claims description 23
230000003472 neutralizing effect Effects 0.000 claims description 21
238000006243 chemical reaction Methods 0.000 claims description 17
230000000977 initiatory effect Effects 0.000 claims description 11
ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 10
238000010521 absorption reaction Methods 0.000 claims description 9
238000001035 drying Methods 0.000 claims description 9
239000011837 N,N-methylenebisacrylamide Substances 0.000 claims description 8
239000003505 polymerization initiator Substances 0.000 claims description 8
238000004132 cross linking Methods 0.000 claims description 7
239000004925 Acrylic resin Substances 0.000 claims description 6
TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 claims description 4
239000000843 powder Substances 0.000 claims description 4
239000003960 organic solvent Substances 0.000 claims description 2
230000000694 effects Effects 0.000 claims 1
239000007788 liquid Substances 0.000 claims 1
238000010298 pulverizing process Methods 0.000 claims 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 170
239000000243 solution Substances 0.000 description 145
238000003860 storage Methods 0.000 description 93
239000007864 aqueous solution Substances 0.000 description 25
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 19
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 14
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
229920000642 polymer Polymers 0.000 description 12
239000004971 Cross linker Substances 0.000 description 11
229910021529 ammonia Inorganic materials 0.000 description 9
229910000027 potassium carbonate Inorganic materials 0.000 description 9
235000011181 potassium carbonates Nutrition 0.000 description 9
239000000047 product Substances 0.000 description 9
239000007921 spray Substances 0.000 description 9
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 8
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 8
239000000908 ammonium hydroxide Substances 0.000 description 8
-1 acryl Chemical group 0.000 description 7
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 7
229920000058 polyacrylate Polymers 0.000 description 7
229910000029 sodium carbonate Inorganic materials 0.000 description 7
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 7
235000019345 sodium thiosulphate Nutrition 0.000 description 7
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 6
239000001099 ammonium carbonate Substances 0.000 description 6
235000012501 ammonium carbonate Nutrition 0.000 description 6
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
238000005303 weighing Methods 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
238000010528 free radical solution polymerization reaction Methods 0.000 description 5
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
238000010924 continuous production Methods 0.000 description 4
239000003431 cross linking reagent Substances 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000000376 reactant Substances 0.000 description 4
AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 3
CCTFAOUOYLVUFG-UHFFFAOYSA-N 2-(1-amino-1-imino-2-methylpropan-2-yl)azo-2-methylpropanimidamide Chemical compound NC(=N)C(C)(C)N=NC(C)(C)C(N)=N CCTFAOUOYLVUFG-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
229910001870 ammonium persulfate Inorganic materials 0.000 description 3
238000010923 batch production Methods 0.000 description 3
239000003518 caustics Substances 0.000 description 3
238000011437 continuous method Methods 0.000 description 3
229920000609 methyl cellulose Polymers 0.000 description 3
239000001923 methylcellulose Substances 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
230000008569 process Effects 0.000 description 3
230000032258 transport Effects 0.000 description 3
WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 2
PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
150000001252 acrylic acid derivatives Chemical class 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
239000008394 flocculating agent Substances 0.000 description 2
229920000578 graft copolymer Polymers 0.000 description 2
239000011259 mixed solution Substances 0.000 description 2
238000013021 overheating Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
239000010802 sludge Substances 0.000 description 2
239000008107 starch Substances 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
239000002562 thickening agent Substances 0.000 description 2
238000011282 treatment Methods 0.000 description 2
KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
AKUNSTOMHUXJOZ-UHFFFAOYSA-N 1-hydroperoxybutane Chemical compound CCCCOO AKUNSTOMHUXJOZ-UHFFFAOYSA-N 0.000 description 1
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 1
LDQYWNUWKVADJV-UHFFFAOYSA-N 2-[(1-amino-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanamide;dihydrate Chemical compound O.O.NC(=O)C(C)(C)N=NC(C)(C)C(N)=O LDQYWNUWKVADJV-UHFFFAOYSA-N 0.000 description 1
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
LLDBOMNUMJVCBX-UHFFFAOYSA-N 2-butylperoxypropan-2-yl hydrogen carbonate Chemical compound CCCCOOC(C)(C)OC(O)=O LLDBOMNUMJVCBX-UHFFFAOYSA-N 0.000 description 1
CKSAKVMRQYOFBC-UHFFFAOYSA-N 2-cyanopropan-2-yliminourea Chemical compound N#CC(C)(C)N=NC(N)=O CKSAKVMRQYOFBC-UHFFFAOYSA-N 0.000 description 1
RCEJCSULJQNRQQ-UHFFFAOYSA-N 2-methylbutanenitrile Chemical compound CCC(C)C#N RCEJCSULJQNRQQ-UHFFFAOYSA-N 0.000 description 1
VXVUDUCBEZFQGY-UHFFFAOYSA-N 4,4-dimethylpentanenitrile Chemical compound CC(C)(C)CCC#N VXVUDUCBEZFQGY-UHFFFAOYSA-N 0.000 description 1
OPPHXULEHGYZRW-UHFFFAOYSA-N 4-methoxy-2,4-dimethyl-2-phenyldiazenylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC1=CC=CC=C1 OPPHXULEHGYZRW-UHFFFAOYSA-N 0.000 description 1
FKAJZOZTZXQGTJ-UHFFFAOYSA-N 5,5-dimethyl-1,3-diazabicyclo[2.2.0]hex-3-ene Chemical compound C1N2C(C1(C)C)=NC2 FKAJZOZTZXQGTJ-UHFFFAOYSA-N 0.000 description 1
PGFZYOCLSPEKSN-UHFFFAOYSA-N 5,5-dimethyl-1,3-diazabicyclo[2.2.0]hex-3-ene dihydrochloride Chemical compound Cl.Cl.CC1(C)CN2CN=C12 PGFZYOCLSPEKSN-UHFFFAOYSA-N 0.000 description 1
229920000178 Acrylic resin Polymers 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
235000002597 Solanum melongena Nutrition 0.000 description 1
244000061458 Solanum melongena Species 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
KYIKRXIYLAGAKQ-UHFFFAOYSA-N abcn Chemical compound C1CCCCC1(C#N)N=NC1(C#N)CCCCC1 KYIKRXIYLAGAKQ-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001339 alkali metal compounds Chemical class 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
RQQQALLRAMHWMY-UHFFFAOYSA-N benzhydryl(1-phenylethyl)diazene Chemical compound C=1C=CC=CC=1C(C)N=NC(C=1C=CC=CC=1)C1=CC=CC=C1 RQQQALLRAMHWMY-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000004566 building material Substances 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
VBWIZSYFQSOUFQ-UHFFFAOYSA-N cyclohexanecarbonitrile Chemical compound N#CC1CCCCC1 VBWIZSYFQSOUFQ-UHFFFAOYSA-N 0.000 description 1
125000004386 diacrylate group Chemical group 0.000 description 1
238000010586 diagram Methods 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000009826 distribution Methods 0.000 description 1
PCAXGMRPPOMODZ-UHFFFAOYSA-N disulfurous acid, diammonium salt Chemical compound [NH4+].[NH4+].[O-]S(=O)S([O-])(=O)=O PCAXGMRPPOMODZ-UHFFFAOYSA-N 0.000 description 1
GKCPCPKXFGQXGS-UHFFFAOYSA-N ditert-butyldiazene Chemical compound CC(C)(C)N=NC(C)(C)C GKCPCPKXFGQXGS-UHFFFAOYSA-N 0.000 description 1
239000003814 drug Substances 0.000 description 1
229940079593 drug Drugs 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
235000019256 formaldehyde Nutrition 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
230000036541 health Effects 0.000 description 1
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000003801 milling Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
TYUVZLLOYGAOPA-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;prop-2-enamide Chemical compound NC(=O)C=C.NC(=O)C=C.NCCNCCN TYUVZLLOYGAOPA-UHFFFAOYSA-N 0.000 description 1
VXRNYQMFDGOGSI-UHFFFAOYSA-N n-(1,3-dihydroxy-2-methylpropan-2-yl)-2-[[1-[(1,3-dihydroxy-2-methylpropan-2-yl)amino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCC(C)(CO)NC(=O)C(C)(C)N=NC(C)(C)C(=O)NC(C)(CO)CO VXRNYQMFDGOGSI-UHFFFAOYSA-N 0.000 description 1
WVFLGSMUPMVNTQ-UHFFFAOYSA-N n-(2-hydroxyethyl)-2-[[1-(2-hydroxyethylamino)-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCO WVFLGSMUPMVNTQ-UHFFFAOYSA-N 0.000 description 1
QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
CHDKQNHKDMEASZ-UHFFFAOYSA-N n-prop-2-enoylprop-2-enamide Chemical compound C=CC(=O)NC(=O)C=C CHDKQNHKDMEASZ-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920006350 polyacrylonitrile resin Polymers 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229940072033 potash Drugs 0.000 description 1
235000015320 potassium carbonate Nutrition 0.000 description 1
CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
229910001950 potassium oxide Inorganic materials 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
229940080818 propionamide Drugs 0.000 description 1
238000007717 redox polymerization reaction Methods 0.000 description 1
150000003839 salts Chemical group 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
238000012719 thermal polymerization Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Epidemiology (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Life Sciences & Earth Sciences (AREA)
Animal Behavior & Ethology (AREA)
General Health & Medical Sciences (AREA)
Public Health (AREA)
Veterinary Medicine (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

JP63203065A 1987-08-14 1988-08-15 改良された水吸収性樹脂の製造方法 Pending JPH01126310A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US8597487A	1987-08-14	1987-08-14
US085974		1987-08-14

Publications (1)

Publication Number	Publication Date
JPH01126310A true JPH01126310A (ja)	1989-05-18

Family

ID=22195168

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP63203065A Pending JPH01126310A (ja)	1987-08-14	1988-08-15	改良された水吸収性樹脂の製造方法

Country Status (7)

Country	Link
EP (1)	EP0303518B1 (de)
JP (1)	JPH01126310A (de)
KR (1)	KR0130652B1 (de)
AT (1)	ATE85801T1 (de)
AU (1)	AU615664B2 (de)
BR (1)	BR8804120A (de)
DE (1)	DE3878500T2 (de)

Cited By (11)

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US6174978B1 (en)	1997-12-10	2001-01-16	Nippon Shokubai Co., Ltd.	Production process of water-absorbent resin
EP0736060B2 (de) †	1993-12-23	2001-04-25	STOCKHAUSEN GmbH & CO. KG	Vernetzte synthetische polymerisate mit poröser struktur
US7265190B2 (en)	2002-11-07	2007-09-04	Nippon Shokubai Co., Ltd.	Process and apparatus for production of water-absorbent resin
JP2008531807A (ja) *	2005-03-03	2008-08-14	ビーエーエスエフソシエタス・ヨーロピア	水吸収性の架橋されたポリマー
US7473739B2 (en)	2004-02-05	2009-01-06	Nippon Shokubai Co., Ltd.	Particulate water absorbent agent and production method thereof, and water absorbent article
JP2010521580A (ja) *	2007-03-23	2010-06-24	ビーエーエスエフソシエタス・ヨーロピア	輸送手段または管路中へのモノマー組成物の輸送
WO2010095427A1 (ja)	2009-02-17	2010-08-26	株式会社日本触媒	ポリアクリル酸系吸水性樹脂粉末およびその製造方法
US8952116B2 (en)	2009-09-29	2015-02-10	Nippon Shokubai Co., Ltd.	Particulate water absorbent and process for production thereof
US9062140B2 (en)	2005-04-07	2015-06-23	Nippon Shokubai Co., Ltd.	Polyacrylic acid (salt) water-absorbent resin, production process thereof, and acrylic acid used in polymerization for production of water-absorbent resin
US9334376B2 (en)	2009-12-24	2016-05-10	Nippon Shokubai Co., Ltd	Water-absorbable polyacrylic acid resin powder, and process for production thereof
US9926449B2 (en)	2005-12-22	2018-03-27	Nippon Shokubai Co., Ltd.	Water-absorbent resin composition, method of manufacturing the same, and absorbent article

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US4861849A (en) *	1988-01-15	1989-08-29	The Dow Chemical Company	Sodium thiosulfate as part of a redox initiator system for the polymerization of water-swellable polymers
CA2003808C (en) *	1988-11-28	1999-11-09	Eugene Joseph Sehm	Crosslinked polyacrylic acid
DE4015085C2 (de) *	1990-05-11	1995-06-08	Stockhausen Chem Fab Gmbh	Vernetztes, wasserabsorbierendes Polymer und Verwendung zur Herstellung von Hygieneartikeln, zur Bodenverbesserung und in Kabelummantelungen
ES2070369T3 (es) *	1990-07-17	1995-06-01	Sanyo Chemical Ind Ltd	Procedimiento para la fabricacion de resinas absorbentes de agua.
JPH0768316B2 (ja) *	1990-09-07	1995-07-26	三洋化成工業株式会社	吸水性樹脂の製造法
DE69333752T3 (de)	1992-06-10	2011-03-03	Nippon Shokubai Co. Ltd.	Verfahren zur Herstellung eines hydrophilen Harzes
DE4420088C3 (de) *	1994-06-09	2001-02-15	Stockhausen Chem Fab Gmbh	Verfahren zur Herstellung eines wasserabsorbierenden Flächengebildes und dessen Verwendung
DE19752128A1 (de) *	1997-11-25	1999-07-29	Stockhausen Chem Fab Gmbh	Verfahren zur Herstellung von wasserlöslichen bzw. wasserquellbaren Polymerisaten mit sehr niedrigem Restmonomergehalt, danach hergestellte Produkte und deren Verwendung
DE19752127A1 (de) *	1997-11-25	1999-07-29	Stockhausen Chem Fab Gmbh	Verfahren zur Herstellung von synthetischen Polymerisaten mit sehr niedrigem Restmonomergehalt, danach hergestellte Produkte und deren Verwendung
KR100476170B1 (ko) *	1998-04-28	2005-03-10	니폰 쇼쿠바이 컴파니 리미티드	흡수성수지 함수겔상물의 제조방법
JP2006503123A (ja) *	2002-07-30	2006-01-26	ビーエーエスエフアクチェンゲゼルシャフト	ポリマーの製造法
KR101393681B1 (ko) *	2010-06-15	2014-05-13	주식회사 엘지화학	고흡수성 수지의 제조 방법
JP6157853B2 (ja)	2010-06-30	2017-07-05	株式会社日本触媒	ポリアクリル酸系吸水性樹脂及びその製造方法
EP2756018B1 (de) *	2011-09-15	2015-10-21	Bayer Intellectual Property GmbH	Verfahren zur durchgehenden herstellung einer wässrigen poly(meth)acrylatharzdispersion
CN115178703B (zh) *	2022-07-25	2025-03-04	共享新材料(山东)有限公司	一种热芯盒用呋喃树脂及其制备方法和使用方法

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EP0206808A3 (de) *	1985-06-24	1987-08-19	American Colloid Company	Kontinuverfahren zur Herstellung von Polyacrylat Harzen

1988
- 1988-08-13 KR KR1019880010392A patent/KR0130652B1/ko not_active Expired - Fee Related
- 1988-08-15 DE DE8888307546T patent/DE3878500T2/de not_active Expired - Fee Related
- 1988-08-15 AT AT88307546T patent/ATE85801T1/de not_active IP Right Cessation
- 1988-08-15 BR BR8804120A patent/BR8804120A/pt not_active IP Right Cessation
- 1988-08-15 AU AU21010/88A patent/AU615664B2/en not_active Expired - Fee Related
- 1988-08-15 EP EP88307546A patent/EP0303518B1/de not_active Expired - Lifetime
- 1988-08-15 JP JP63203065A patent/JPH01126310A/ja active Pending

Patent Citations (1)

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JPS5918712A (ja) *	1982-07-21	1984-01-31	Arakawa Chem Ind Co Ltd	乾燥した吸水性樹脂の製造方法

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0736060B2 (de) †	1993-12-23	2001-04-25	STOCKHAUSEN GmbH & CO. KG	Vernetzte synthetische polymerisate mit poröser struktur
US6174978B1 (en)	1997-12-10	2001-01-16	Nippon Shokubai Co., Ltd.	Production process of water-absorbent resin
US7265190B2 (en)	2002-11-07	2007-09-04	Nippon Shokubai Co., Ltd.	Process and apparatus for production of water-absorbent resin
US7473739B2 (en)	2004-02-05	2009-01-06	Nippon Shokubai Co., Ltd.	Particulate water absorbent agent and production method thereof, and water absorbent article
US7582705B2 (en)	2004-02-05	2009-09-01	Nippon Shokubai Co., Ltd.	Particulate water absorbent agent and production method thereof, and water absorbent article
JP2008531807A (ja) *	2005-03-03	2008-08-14	ビーエーエスエフソシエタス・ヨーロピア	水吸収性の架橋されたポリマー
US9062140B2 (en)	2005-04-07	2015-06-23	Nippon Shokubai Co., Ltd.	Polyacrylic acid (salt) water-absorbent resin, production process thereof, and acrylic acid used in polymerization for production of water-absorbent resin
US10358558B2 (en)	2005-12-22	2019-07-23	Nippon Shokubai Co., Ltd.	Water-absorbent resin composition, method of manufacturing the same, and absorbent article
US9926449B2 (en)	2005-12-22	2018-03-27	Nippon Shokubai Co., Ltd.	Water-absorbent resin composition, method of manufacturing the same, and absorbent article
JP2010521580A (ja) *	2007-03-23	2010-06-24	ビーエーエスエフソシエタス・ヨーロピア	輸送手段または管路中へのモノマー組成物の輸送
US8791210B2 (en)	2009-02-17	2014-07-29	Nippon Shokubai Co., Ltd.	Polyacrylic water-absorbent resin powder and method for producing the same
US9243079B2 (en)	2009-02-17	2016-01-26	Nippon Shokubai Co., Ltd.	Polyacrylic acid-based water-absorbing resin powder and method for producing the same
WO2010095427A1 (ja)	2009-02-17	2010-08-26	株式会社日本触媒	ポリアクリル酸系吸水性樹脂粉末およびその製造方法
US9775927B2 (en)	2009-09-29	2017-10-03	Nippon Shokubai Co., Ltd.	Particulate water absorbent and process for production thereof
US8952116B2 (en)	2009-09-29	2015-02-10	Nippon Shokubai Co., Ltd.	Particulate water absorbent and process for production thereof
US9334376B2 (en)	2009-12-24	2016-05-10	Nippon Shokubai Co., Ltd	Water-absorbable polyacrylic acid resin powder, and process for production thereof

Also Published As

Publication number	Publication date
BR8804120A (pt)	1989-03-07
AU2101088A (en)	1989-03-02
DE3878500T2 (de)	1993-06-03
KR0130652B1 (ko)	1998-04-07
EP0303518A2 (de)	1989-02-15
KR890003818A (ko)	1989-04-18
AU615664B2 (en)	1991-10-10
EP0303518A3 (en)	1989-10-18
EP0303518B1 (de)	1993-02-17
ATE85801T1 (de)	1993-03-15
DE3878500D1 (de)	1993-03-25

Publication	Publication Date	Title
JPH01126310A (ja)	1989-05-18	改良された水吸収性樹脂の製造方法
US4985518A (en)	1991-01-15	Process for preparing water-absorbing resins
US4525527A (en)	1985-06-25	Production process for highly water absorbable polymer
US4552938A (en)	1985-11-12	Process for preparing dry solid water absorbing polyacrylate resin
CN1136233C (zh)	2004-01-28	吸水剂树脂的生产方法
KR940006449B1 (ko)	1994-07-20	아크릴산염 및 아크릴산염-함유 중합체의 제조방법
EP0242478B1 (de)	1990-09-12	Wasserabsorbierende Acrylcopolymere
JP5376420B2 (ja)	2013-12-25	水溶性または水で膨潤可能なポリマー、特に低い残留モノマー含量を有する、アクリルアミドおよび少なくとも１種のイオン性コモノマーからなる水溶性または水で膨潤可能なコポリマーの製造方法
AU2010362811A1 (en)	2013-05-23	Method for producing water-absorbent resin particles and water-absorbent resin particles
CN101528789A (zh)	2009-09-09	生产超吸收剂的方法
EP0206808A2 (de)	1986-12-30	Kontinuverfahren zur Herstellung von Polyacrylat Harzen
WO2019074099A1 (ja)	2019-04-18	吸水性樹脂及び吸収性物品
JPH0214925B2 (de)	1990-04-10
US4820742A (en)	1989-04-11	Method for continuous manufacture of solid water absorbing resin
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CN1970595B (zh)	2010-05-05	高吸水性树脂的制造方法
JP2000128907A (ja)	2000-05-09	吸水性ポリマーの製造法
JP7793530B2 (ja)	2026-01-05	吸水性樹脂粒子の製造方法
JP2008095016A (ja)	2008-04-24	粉末状で水に不溶であり、水、し尿あるいは血液を吸収し、可溶物含有量の低い高吸水性樹脂の製造方法
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