JPH0119691B2 - - Google Patents
Info
- Publication number
- JPH0119691B2 JPH0119691B2 JP58052821A JP5282183A JPH0119691B2 JP H0119691 B2 JPH0119691 B2 JP H0119691B2 JP 58052821 A JP58052821 A JP 58052821A JP 5282183 A JP5282183 A JP 5282183A JP H0119691 B2 JPH0119691 B2 JP H0119691B2
- Authority
- JP
- Japan
- Prior art keywords
- composition according
- composition
- water
- ethylene
- diphenylamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 59
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 46
- 229920001223 polyethylene glycol Polymers 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 17
- 229910000077 silane Inorganic materials 0.000 claims description 17
- -1 polyethylene Polymers 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 150000001451 organic peroxides Chemical class 0.000 claims description 7
- 238000004132 cross linking Methods 0.000 claims description 6
- 239000003623 enhancer Substances 0.000 claims description 6
- 150000002430 hydrocarbons Chemical group 0.000 claims description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 2
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 240000005572 Syzygium cordatum Species 0.000 description 32
- 235000006650 Syzygium cordatum Nutrition 0.000 description 32
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 16
- 238000012360 testing method Methods 0.000 description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- 239000004705 High-molecular-weight polyethylene Chemical class 0.000 description 9
- YLJJAVFOBDSYAN-UHFFFAOYSA-N dichloro-ethenyl-methylsilane Chemical compound C[Si](Cl)(Cl)C=C YLJJAVFOBDSYAN-UHFFFAOYSA-N 0.000 description 9
- 239000012212 insulator Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 2
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000011067 equilibration Methods 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 150000002978 peroxides Chemical group 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 1
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- NGSWKAQJJWESNS-ZZXKWVIFSA-N trans-4-coumaric acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C=C1 NGSWKAQJJWESNS-ZZXKWVIFSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Description
çºæã®æè¡åé
æ¬çºã¯ãçåæ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ãšé«å
åéããªãšãã¬ã³ã°ãªã³ãŒã«ãããªããŠãªãŒã¿ãŒ
ããªâæå¶å€ãå«ãéåäœçµæç©ãäŸãã°ãšãã¬
ã³éåäœãåºæãšããçµæç©ã«é¢ãããåŸããã
çµæç©ã¯ããŠãªãŒã¿ãŒããªãŒã€ã³ã°æµææ§ã§ãã
絶çžäœãè¡šé¢ã«åããé»æ°å°äœã®æŒåºç©ãšããŠæ
çšã§ããã çºæã®èæ¯ çµ¶çžé»åã±ãŒãã«ã®æå¹å¯¿åœã¯ããŠãªãŒã¿ãŒã
ãªãŒã€ã³ã°ãšç§°ããç Žå£çŸè±¡ã«ãã€ãŠççž®ããã
ããšãç¥ãããŠããã ãã®çµæãéåäœçµæç©ãäŸãã°ãšãã¬ã³éå
äœçµæç©ãåºæãšãã絶çžäœã¯ããŠãªãŒã¿ãŒããª
ãŒã€ã³ã°æµææ§ãç¹åŸŽãšãã絶çžäœãæäŸããç®
çã§åçš®ã®æ·»å å€ãæ·»å ããããšã«ãã€ãŠå€æ§ã
ããããŠãªãŒã¿ãŒããªãŒã¯ã絶çžäœãæ°Žãååšã
ãç°å¢ã«ããäžæ¹ã§é·æéã«ããã€ãŠé»çã«çœ®ã
ãããšãã«èµ·ãããŠãªãŒã¿ãŒããªãŒã¯ãæã®ãã
æšã«äŒŒãŠããããã«ãã®ããã«åŒã°ãããå®éã«
ã¯ããŠãªãŒã¿ãŒããªãŒã¯ãæ°Žã§æºããããšãã«æ
ããã«çœè²ã§ããã也ç¥ãããšãã«èŠããªããªã
埮å°ãªéè·¯åã¯ç©ºéã§ããã芳å¯ããããã«ã¯ã
ãŠãªãŒã¿ãŒããªãŒãæããè©Šéšçã¯æ°Žäžã§ç ®æ²žã
åã¯ä¹Ÿç¥ãããã°ãªããªãã ãŠãªãŒã¿ãŒããªãŒã¯çµ¶çžäœäžã§é»å§å¿åã®ç¹ã§
æé·ãå§ãããå¿åã®ç¹ã¯ã空éãæ±æç©åã¯äž
èŠåéšãäŸãã°çµ¶çžäœãšåå°é»æ§å±€ãšã®éã®çé¢
ã«ãããäžèŠåéšãååšãã絶çžäœäžã®å Žæã§ã
ãåŸãã空éåã¯æ±æç©ã®å Žåã«ã¯ããŠãªãŒã¿ãŒ
ããªãŒã¯ãããªâã®ç¹ïŒæ žïŒã®å¯ŸåããåŽã«æé·
ããåŸåãããããããŠãããŠã¯ã¡ãããã¯ã¿ã€
ã«é¡ãããã«æé·ãããçé¢ã§éå§ããããªãŒã¯
ããã·ãŠã®åœ¢ã§äžæ¹åã«æé·ãããããŠããã¯é
æ°åœ¢ããªãŒãšç§°ãããããããïŒçš®ã®ãŠãªãŒã¿ãŒ
ããªãŒãå³ã¡ã¡ãããã¯ã¿ã€åã³éæ°åœ¢ããªãŒ
ã¯ãè©ŠéšããããŠãªãŒã¿ãŒããªæå¶å€ã®å€ãã«å¯Ÿ
ããç°ãªã€ãå¿çã«ãã瀺ãããããã«ãç°ãªã€
ãæ©æ§ã«ããéå§ãæé·ãããã®ãšæãããã çŸå°ç¹ãŸã§ã®ãšããã§ã¯ãéåäœçµæç©ã«æ·»å
ãããšãã«ãé·æéã«ãããã¡ãããã¯ã¿ã€åœ¢ã
ãªãŒåã³éæ°åœ¢ãŠãªãŒã¿ãŒããªãŒåœ¢ææµææ§ãå«
ããŠåæ¥çã«æºè¶³ã§ãã調åããæ§è³ªãæããçµ
æç©ãçããåäžãŠãªãŒã¿ãŒããªãŒæå¶å€ç³»ã¯é
çºãããªãã€ãã çºæã®èª¬æ æ¬çºæã¯ããšãã¬ã³éåäœã®ãããªéåäœææ
ã«æ·»å ãããšãã«ãã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒ
ããªãŒåã³éæ°åœ¢ãŠãªãŒã¿ãŒããªãŒåœ¢ææµææ§ã
å«ããŠåæ¥çã«æºè¶³ã§ãã調åããæ§è³ªãæãã
çµæç©ãæäŸãããšããã®çåæ°ŽçŽ çœ®æãžããšã
ã«ã¢ãã³ãšé«ååéããªãšãã¬ã³ã°ãªã³ãŒã«ãã
ãªããŠãªãŒã¿ãŒããªãŒæå¶çµæç©ãæäŸãããæ¬
çºæã®çµæç©ã¯ãããããåšå²ã«æŒåºæ圢ãã絶
çžé»æ°å°äœã®éåžžã®äœååã¯äœ¿çšæž©åºŠã«ãããŠã
ç©ççåã¯é»æ°çæ§è³ªã®æãŸãããªãäœäžãåã
ãããšãªããé·æéã«ããã€ãŠãŠãªãŒã¿ãŒããªãŒ
ã€ã³ã°æµææ§ãä¿æãããããã«ãæ¬çºæã®çµæ
ç©ã¯ãé©åœãªæ¶æ©å¢é²å€ã®æ·»å ã«ãã€ãŠãæ¶æ©
å€ãå³ã¡ææ©éé žåç©ã®éåžžæ¿åºŠãããã»ã©å¢å€§
ãããããšãªãããŠãªãŒã¿ãŒããªãŒæµææ§ã®æ¶æ©
çæç©ã«ç¡¬åãããããšãã§ããã äžè¿°ããããã«ãæ¬çºæã®ãŠãªãŒã¿ãŒããªãŒæ
å¶å€ã¯ãçåæ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ãšé«åå
éããªãšãã¬ã³ã°ãªã³ãŒã«ãšã®çµåããããªãã æ¬çºæã®ç®çã«å¯ŸããŠå¥œé©ã§ãããè³éŠæç°äž
ã«ïŒå以äžã®çåæ°ŽçŽ åºã眮æããŠãããžããšã
ã«ã¢ãã³ãšããŠã¯ãæ¬¡åŒ ïŒããã§ãåã¯ãåäžåã¯ç°ãªã€ãŠããŠã
ããæ°ŽçŽ åã¯ã¢ããåºã«å¯ŸããŠãã©åã³ïŒåã¯ïŒ
ãªã«ãäœçœ®ã«çœ®æããŠããã¢ã«ãã«åã¯ã¢ã©ãŒã«
ãã«åºã®ãããªçåæ°ŽçŽ åºã§ããããã ããã¯
å°ãªããšãïŒåã¯çåæ°ŽçŽ åºã§ããïŒ ãæãããã®ããããããã ååãšããŠãåã¯ïŒã18åã®ççŽ ååã奜ãŸ
ããã¯ïŒãïŒåã®ççŽ ååãæããããã®ãããª
åºã®äŸã¯ãïœâããã»ã³ãïœâãããã³ãïœâãª
ã¯ãã³ãïœâããã³ãªã©ã®ãããªÎ±âãªã¬ãã€ã³
ããå°ããããã®äžŠã³ã«ã¹ãã¬ã³ãαâã¡ãã«ã¹
ãã¬ã³ãªã©ããå°ãããåºã§ããã æ¬çºæã®ç®çã«å¯ŸããŠç¹ã«æãŸãããã®ã¯ãã¹
ãã¬ã³åã¯ãªã¯ãã¬ã³ã§ã¢ã«ãã«åãããžããšã
ã«ã¢ãã³ã®ãããªæ¶²ç¶ãžããšãã«ã¢ãã³ã§ããã
ã¹ãã¬ã³ã§ã¢ã«ãã«åããã液ç¶ãžããšãã«ã¢ã
ã³ã§ãã€ãŠãã°ããã€ã€ãŒã»ã¿ã€ã€ïŒã©ããŒç€Ÿã
ãWingstay29ã®åååã§åžè²©ãããŠãããã®ãã
ãã®ãããªååç©ã®äžäŸã§ããããã®ååç©ã¯ã
äžèšã®çæ³åŒã«åŸããããªãŒãã«ã»ã¯ã©ãã觊åª
ã䜿çšããã¢ã«ãã«åæ¡ä»¶äžã§ãžããšãã«ã¢ãã³
ãšã¹ãã¬ã³ãåå¿ãããããšã«ãã€ãŠåŸãããã å®éã«ã¯ããã®ååç©ã¯ã¢ã眮æäœãšãžçœ®æäœ
ãšã®æ··åç©ã§ãããã®ãšæãããã 液ç¶çåæ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ãé«ååé
ããªãšãã¬ã³ã°ãªã³ãŒã«ãšçµåããŠå«æããçµæ
ç©ã¯ãåèšããæ§è³ªãç¹åŸŽãšããããšä»¥å€ã«ã
ããã«ãŒãã³ã°ãïŒè¡šé¢æ»²åºã説æããã®ã«çšãã
ããçšèªïŒãæ¯èŒç瀺ããªãã ãã®ä»ã®å¥œé©ãªãžããšãã«ã¢ãã³ã¯ä»¥äžã«èšèŒ
ããã æ¬çºæã®ç®çã«å¯ŸããŠå¥œé©ãªããªãšãã¬ã³ã°ãª
ã³ãŒã«ã¯ãçŽ1000ãçŽ20000ã®ååéãæããã
ã®ã§ãããç¹ã«æãŸããããªãšãã¬ã³ã°ãªã³ãŒã«
ã¯ãå°ãªããšã30ã奜ãŸããã¯å°ãªããšã80ã®ç
çŽ æ°ãå³ã¡ççŽ ååæ°ãæãããæ¬çºæã«å¯ŸããŠ
奜é©ãªåžå Žã§å ¥æã§ããããªãšãã¬ã³ã°ãªã³ãŒã«
ã¯ãåååãCarbowaxããåŒç§°20MãšããŠãŠã
ãªã³ã»ã«ãŒãã€ã瀟ããåžè²©ãããŠãããããã
ã®ææã¯ããŠããªã³ã»ã«ãŒãã€ã瀟ã®ãã³ãã¬ã
ãNo.â4772Iã1/78ããå称ïŒã«ãŒãã¯ãã¯ã¹ã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãã«èšèŒãããŠããã ãžããšãã«ã¢ãã³ã«å¯Ÿããããªãšãã¬ã³ã°ãªã³
ãŒã«ã®éã¯ãéåäœã«æ·»å ãããšãã«ãåäžãã
ãŠãªãŒã¿ãŒããªãŒã€ã³ã°æµææ§ãæããéåäœçµ
æç©ãçããçµæç©ãæäŸããã®ã«ååãªãã®ã§
ããã 奜ãŸããã¯ãçåæ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ã«
察ããããªãšãã¬ã³ã°ãªã³ãŒã«ã®éã¯ããžããšã
ã«ã¢ãã³ïŒéééšã«ã€ãçŽ0.2ãçŽïŒéééšã§ã
ãã ãŠãªãŒã¿ãŒããªãŒæµææ§ã®çµæç©ãæäŸããã
ãã«åèšã®ãŠãªãŒã¿ãŒããªãŒæå¶å€çµæç©ãæ·»å
ã§ãã奜é©ãªéåäœææã«ã¯ãéåžžåºäœã®ãšãã¬
ã³ãã¢éåäœããšãã¬ã³âαâãªã¬ãã€ã³å ±éå
äœããšãã¬ã³âαâãªã¬ãã€ã³âãžãšã³åéäœã®
å ±éåäœã®ãããªãšãã¬ã³éåäœãããã奜é©ãª
å ±éåæ§ã®åéäœã¯ããããã¬ã³ãããã³âïŒã
ããã»ã³âïŒãªã©ã®ãããªÎ±âãªã¬ãã€ã³ïŒãã¿
ãžãšã³ãã€ãœãã¬ã³ãªã©ã®ãããªãžãšã³åéäœã§
ããããããŠãã®å Žåã«éåäœã¯å°ãªããšãçŽ70
ééïŒ ã®ãšãã¬ã³ãå«æããã 奜ãŸããå ±éåäœã¯ããšãã¬ã³âãããã¬ã³å ±
éåäœããšãã¬ã³âããã³å ±éåäœãªã©ã§ããã
ãããã®å ±éåäœã¯ã1977幎ïŒæïŒæ¥ã«çºè¡ãã
ãç±³åœç¹èš±ç¬¬4011382å·ã«é瀺ãããŠããããã«ã
ãã¿ã³å€æ§é žåã¯ãã 觊åªãçšããŠçŽ150ãçŽ
300psiã®äœå§äžã§è£œé ããããšãã§ããã ææãªãã°ãããªãããã¬ã³ããšãã¬ã³âãã
ãã¬ã³ãŽã ããšãã¬ã³âãããã¬ã³âãžãšã³ãŽã
ãªã©ã®ãããªä»ã®éåäœãæ¬çºæã®ãšãã¬ã³éå
äœçµæç©ã«æ·»å ããããšãã§ããã æ¬çºæã®çµæç©ã¯ãç«äœé害ããšããŒã«åã³ã¢
ãã³ãéåããïŒïŒïŒïŒïŒâããã©ã¡ãã«ããã
ããã³ãïŒïŒ4â²âããªãã¹ïŒïŒâïœâããã«âïŒ
âã¡ãã«ããšããŒã«ïŒãããªãžãšãã¬ã³ãã¹ïŒïŒïŒ
ïŒâïœâããã«âïŒâããããã·ïŒããããã·ã·
ã³ãã¡ãŒãããžã¹ãã¢ãªã«ããªãžããããªããŒã
ãªã©ã®ãããªé žåé²æ¢å€ãå«æããããšãã§ã
ãã ãŸããæ¬çºæã®çµæç©ã¯ããããç±å¯å¡æ§çµæ
ç©ãšããŠããããããå ç¡«åã¯æ¶æ©çæç©ãšããŠ
çšããããšãããšãã«ã¯ãæ¶æ©å€ãå«æããããš
ãã§ãããå ç¡«åã¯æ¶æ©å€ã¯åœæ¥çã§åšç¥ã§ã
ãã1967幎ïŒæïŒæ¥ã«çºè¡ãããç±³åœç¹èš±ç¬¬
3296189å·ã«èšèŒã®ãããªææ©éé žåç©ãå«ãŸã
ãããããã®ååç©ã¯ãåç¬ã§ãäºã®æ··åç©ãšã
ãŠãåã¯æ¶æ©å¢é²å€ãšå ±ã«çšããããšãã§ããã æ¬çºæã®ç®çã«å¯ŸããŠç¹ã«æãŸãã硬åæ§çµæ
ç©ã¯ããšãã¬ã³éåäœã液ç¶ã®çåæ°ŽçŽ çœ®æãžã
ãšãã«ã¢ãã³ãé«ååéããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãææ©éé žåç©åã³æ¬¡ã®å¹³ååŒ ïŒããã§R1åã³R2ã¯ãåäžåã¯ç°ãªã€ãŠããŠ
ãããäžè¬ã«ïŒã18åã®ççŽ ååã奜ãŸããã¯12
ã14åã®ççŽ ååãæããçåæ°ŽçŽ åºã§ãããïœ
ã¯ïŒã20ã奜ãŸããã¯ïŒã16ã®å€ãæããæŽæ°ã§
ããïŒ ãæããã·ã©ã³æ¶æ©å¢é²å€åã¯æ¬¡ã®å¹³ååŒ ïŒããã§R1åã³R2ã¯åèšãããã®ãšåãã§ã
ããïœåã³ïœã¯åäžåã¯ç°ãªã€ãŠããŠãããïŒã
ïŒã®å€ãæããæŽæ°ã§ããïŒ ãæããã·ã©ã³æ¶æ©å¢é²å€ãå«ãã R1åã³R2ã®å¥œé©ãªåºã®äŸã¯ããªã¯ãã«ããã
ã«ããã·ã«ããŠã³ãã·ã«ãããã·ã«ãã¹ãã¢ãªã«
ãªã©ã®ãããªã¢ã«ãã«åºã§ããã åŒåã³ã®ç¯å²å ã«å ¥ãã·ã©ã³ã®è£œé ã¯ãã¡
ãã«ããã«ãžã¯ãã«ã·ã©ã³åã¯ã¡ãã«ããã«ãžã¯
ãã«ã·ã©ã³ãšãžã¡ãã«ãžã¯ãã«ã·ã©ã³ãšã®æ··åç©
ãæ°Žåã³èèªæã¢ã«ã³ãŒã«åã¯èèªæã¢ã«ã³ãŒã«
æ··åç©ãšåå¿ããã次ãã§é žæ§æ®çç©ã平衡åã
ããäžåãããããšã«ãã€ãŠå ·åãã補é ããã
ãšãã§ãããæ°Žãšã¢ã«ã³ãŒã«ã®ã¢ã«æ¯ã¯ãäžèšã®
ååŠéè«çæ¹çšåŒïŒç°¡åã«ããããã«åå¿äœã¯ã¡
ãã«ããã«ãžã¯ãã«ã·ã©ã³ãæ°Žåã³ããã·ã«ã¢ã«
ã³ãŒã«ã§ãããã®ãšããŠç€ºãïŒãããŠã¯ãŸããã
ã«äºå®èœæ§ã¯ãã«ã·ã©ã³ã®ïŒã¢ã«ããšã«ã€ããŠå€
ããããšãã§ããã åŒã®ç¯å²å ã«å ¥ãã·ã©ã³ã補é ããã«ããã€
ãŠã¯ãã¡ãã«ããã«ãžã¯ãã«ã·ã©ã³ã®éïŒïœïŒãš
ãžã¡ãã«ã¯ãã«ã·ã©ã³ã®éïŒïœïŒã®åèšã¯ã次ã®
ååŠéè«çåå¿åŒã«åŸã€ãŠãïœã«çããã åå¿ã®è©³çŽ°ãäžèšã®æäœã§ç€ºãã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æµžéã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ããããã ã·ã©ã³ïŒã¯äžèšã®ããã«è£œé ãããã 滎äžããŒããæ©æ¢°çæ¹ææ©ã枩床èšåã³çªçŽ ã
ã€ãã¹ã§ä¿è·ããååšä»èžçããããåãã2lã®
äžå£ã®ãã©ã¹ã³ã«846.0ïœïŒ6.0ã¢ã«ïŒã®ã¡ãã«ã
ãã«ãžã¯ãã«ã·ã©ã³ãå ããã滎äžããŒãããã
ã©ã¹ã³ã«294.7ïœïŒ1.5ã¢ã«ïŒã®ããã«ããŒã«ãç·©
ããªé床ã§ããããŸããªããå ããããã©ã¹ã³ã®
枩床ã¯HCã®çºçã®ããã«ïŒ10âã«äœäžããã
ãã«ããŒã«ãæ·»å ããåŸããã©ã¹ã³ã®æž©åºŠãå€éš
氷济ã«ãã10±ïŒâã«ä¿æããªãã89.7ïœïŒ5.0
ã¢ã«ãå³ã¡ååŠéè«çéã®95ïŒ ïŒã®æ°Žã滎äžããŒ
ããããã€ãããšè£ å ¥ãããæ°Žãæ·»å ããåŸãã
ã©ã¹ã³ããããŸããªãã15±ïŒâã§ïŒæéä¿æã
ãïŒHCl平衡åå·¥çšïŒã滎äžããŒããN2âã¹ããŒ
ãžç®¡ã§ä»£ãããã©ã¹ã³ã®å 容ç©ã90âã«ãã€ãã
ãšå ç±ãããã©ã¹ã³ããHClãé£ç¶çã«é€å»ã
ãã30ååŸã«ãã©ã¹ã³ãããšã€ãè©Šæãåæãã
ããè©ŠæïŒïœã«ã€ã0.11meq Cl-ãå«æããããš
ãããã€ããæ°Žã®æ®éïŒ4.5ïœã0.25ã¢ã«ïŒã飜
åNa2CO3溶液ãšããŠæ·»å ãããå ç±ã80âã§ã
ãã«30åéåéãããããŠN2ã¹ããŒãžãç¶ããã
æ®çé žå¡©åç©ã湿ã€ãNaHCO3ã§äžåãããç
æç©ãéããŠã0.01meqïŒïœïŒ0.04ïŒ ïŒã®å¡©çŽ
å«æéãæããç²åºŠ16.5cstkã®éæç¡è²æµåäœ
759.0ïœïŒçè«é792.5ïœãå³ã¡çè«éã®96ïŒ ïŒã
åŸãã ããã«èšèŒã®ã·ã©ã³ã®è£œé ã«çšããããã«ããŒ
ã«ã¯ãããã¯ã¿ãŒïŒã®ã€ã³ãã«ç€Ÿè£œã®Coâ
1214Fatty AlcoholïŒããã«ããŒã«ãšå°éã®C14ã¢
ã«ã³ãŒã«ãå«æããæ··åç©ã®åååïŒã§ãã€ãã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æ»²éã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ãããããããã¯æ¬¡
ã®ããã«è£œé ããã 滎äžããŒããåçž®åšãæ©æ¢°çæ¹ææ©ã枩床èšã
åãããããŠçªçŽ ãã€ãã¹ç®¡ã§ä¿è·ãã1lã®äžå£
ã®ãã©ã¹ã³ã«282.0ïœïŒ2.0ã¢ã«ïŒã®ã¡ãã«ããã«
ãžã¯ãã«ã·ã©ã³ãå ããã枩床ã10ã15âã«ä¿ã¡
ãªãããã€ãããšãããŸããŠã滎äžããŒããã
98.25ïœïŒ0.5ã¢ã«ïŒã®ããã«ããŒã«ãæ·»å ããã
ããã«ããŒã«ãæ·»å ããåŸãåå¿å®¹åšã®æž©åºŠãæ°·
济ã«ãã10ã15âã«ãããŸããªããä¿æããŠ
28.44ïœïŒ1.58ã¢ã«ã1.75ã¢ã«ã®ååŠéè«çéã«å¿
èŠãª90ïŒ ïŒã®æ°Žãæ·»å ããããã©ã¹ã³ã®å 容ç©ã
10ã15âã®æž©åºŠã§ïŒæéãããŸããã滎äžããŒã
ã液äœåå¿æ··åç©äžã«æ¿å ¥ãã管ã§çœ®ãæããçª
çŽ ãæ··åç©äžã«éããäžæ¹ã§ããããŸããªãã90
âã®æž©åºŠã«å ç±ããŠãã©ã¹ã³ããå¡©åæ°ŽçŽ ãé€å»
ããã90âã®æž©åºŠã§0.5æéåŸã«ãæ°Žã®æ®éïŒ3.1
ïœïŒã飜åNa2CO3溶液ãšããŠæ·»å ããã次ãã§
å šãŠã®æ®çå¡©åæ°ŽçŽ ãã·ã©ã³ïŒã®è£œé ã«ãããèš
èŒããããã«ããŠäžåãããéããåŸãç²åºŠã
18.4cstkïŒ25âïŒã§ãã250ïœã®éæç¡è²æµåäœã
åŸãããã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æ»²éã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ããããã ã·ã©ã³ïŒã¯ãã·ã©ã³ïŒã«ã€ããŠèšèŒããæ¹æ³ã«
åŸã€ãŠã282.0ïœïŒïŒã¢ã«ïŒã®ã¡ãã«ããã«ãžã¯
ãã«ã·ã©ã³ã46.6ïœïŒ0.25ã¢ã«ïŒã®ããã«ããŒã«
åã³33.75ïœïŒïŒã»875ã¢ã«ïŒã®H2Oãåå¿ãããŠ
178.5ïœã®éæç¡è²æµåäœãçããããããšã«ã
ã補é ããã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æ»²éã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ããããã ã·ã©ã³ïŒã¯ãã·ã©ã³ïŒã«ã€ããŠèšèŒããæ¹æ³ã«
åŸã€ãŠã141.0ïœïŒ1.0ã¢ã«ïŒã®ã¡ãã«ããã«ãžã¯
ãã«ã·ã©ã³ã129.1ïœïŒ1.0ã¢ã«ïŒã®ãžã¡ãã«ãžã¯
ãã«ã·ã©ã³ã93.2ïœïŒ0.5ã¢ã«ïŒã®ããã«ããŒã«
åã³31.5ïœïŒ1.75ã¢ã«ïŒã®æ°Žãåå¿ãããŠ193.5ïœ
ã®éæç¡è²æµåäœãçããããããšã«ãã補é ã
ãã æ¬çºæã®çµæç©ãåŠæ¹ããã«ããã€ãŠã¯ãçå
æ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ãé«ååéããªãšãã¬
ã³ã°ãªã³ãŒã«ãææ©éé žåç©åã³ã·ã©ã³æ¶æ©å¢é²
å€ã®éïŒçµæç©ã®å šééãåºã«ããŠïŒã¯æ¬¡ã®éã
ã§ããã ãžããšãã«ã¢ãã³ã¯ãé«ååéããªãšãã¬ã³ã°
ãªã³ãŒã«ãšå ±ã«ãçµæç©ã®ãŠãªãŒã¿ãŒããªãŒæµæ
æ§ãåäžãããã®ã«ååãªéã§ãäžè¬ã«çŽ0.2ã
çŽïŒééïŒ ã奜ãŸããã¯çŽ0.5ãçŽïŒééïŒ ã®é
ã§ååšããã é«ååéããªãšãã¬ã³ã°ãªã³ãŒã«ã¯ããžããšã
ã«ã¢ãã³ãšå ±ã«ãçµæç©ã®ãŠãªãŒã¿ãŒããªãŒæµæ
æ§ãåäžãããã®ã«ååãªéã§ãäžè¬ã«çŽ0.2ã
çŽïŒééïŒ ã奜ãŸããã¯çŽ0.2ãçŽ0.5ééïŒ ã®é
ã§ååšããã ææ©éé žåç©ã¯ãçµæç©ãæ¶æ©çæç©ã«ç¡¬åã
ããã®ã«ååãªéã§ãäžè¬ã«çŽïŒãçŽïŒééïŒ ã
奜ãŸããã¯çŽ1.5ãçŽïŒééïŒ ã®éã§ååšããã æ¶æ©å¢é²å€ã¯ãçŽ0.5ãçŽïŒééïŒ ã奜ãŸãã
ã¯çŽ0.5ãçŽ1.5ééïŒ ã®éã§ååšããã æ¬æ现æžã«èšèŒã®æåã®æ··åç©ãæããªãã°ã
ãã䜿çšã§ãããã®ã§ããã 以äžã«è¡šåã³è¡šã«èšèŒã®å®æœäŸåã³å¯Ÿç §äŸ
ãå®æœããã®ã«çšããææã説æããã éåäœ éåäœïŒ¡ïŒ0.7ã®ã¡ã«ãã€ã³ããã¯ã¹åã³0.92
ã®å¯åºŠãæãããšãã¬ã³ãšïœâããã³ãšã®å ±
éåäœ éåäœïŒ¢ïŒïŒã®ã¡ã«ãã€ã³ããã¯ã¹åã³0.92ã®
å¯åºŠãæããããªãšãã¬ã³ éåäœïŒ£ïŒ0.2ã®ã¡ã«ãã€ã³ããã¯ã¹åã³0.92
ã®å¯åºŠãæããããªãšãã¬ã³ ãžããšãã«ã¢ãã³ ïŒã¹ãã¬ã³ã§ã¢ã«ãã«åãããžããšãã«ã¢ã
ã³ïŒWingstay29ãã°ããã€ã€ãŒç€ŸïŒâæ¶²ç¶ ïŒãžã€ãœããã¬ã³ã§ã¢ã«ãã«åãããžããšã
ã«ã¢ãã³ïŒNavgalube438LããŠããã€ã€ã«
瀟ïŒâæ¶²ç¶ ïŒãªã¯ãã¬ã³ã§ã¢ã«ãã«åãããžããšãã«ã¢
ãã³ïŒStaliteâR.V.ããã³ãã«ãã«ã瀟ïŒ
âæ¶²ç¶ ïŒÎ±âã¡ãã«ã¹ãã¬ã³ã§ã¢ã«ãã«åãããžã
ãšãã«ã¢ãã³ïŒNaugard445ããŠããã€ã€ã«
瀟ïŒâåºäœ ïŒãªã¯ãã¬ã³ã§ã¢ã«ãã«åãããžããšãã«ã¢
ãã³ïŒStaliteââR.V.ããã³ãã«ãã«ã
瀟ïŒâåºäœ é žåé²æ¢å€ïŒAQïŒ AQâïŒïŒïŒïŒ4â²âããªãã¹ïŒïŒâïœâããã«
âïŒâã¡ãã«ããšããŒã«ïŒ AQâïŒïŒãžã¹ãã¢ãªã«ããªãžããããªããŒã AQâïŒïŒããªãžãšãã¬ã³ãã¹ïŒïŒïŒïŒâãžâ
ïœâããã«âïŒâããããã·ïŒãããã·ã³ã
ã¡ãŒã ããªãšãã¬ã³ã°ãªã³ãŒã« ããªãšãã¬ã³ã°ãªã³ãŒã« ååéçŽ4000â ãŠããªã³ã«ãŒãã€ã瀟ããååå
ãCarbowaxããšããŠåžè²© ããªãšãã¬ã³ã°ãªã³ãŒã« ååéçŽ20000â ãŠããªã³ã«ãŒãã€ã瀟ããååå20Mãšã
ãŠåžè²© è¡šã«èšèŒã®çµæç©ãåŠæ¹ãè©Šéšããã®ã«çšã
ãæ¹æ³ã次ã«èª¬æããã ãšãã¬ã³éåäœãã¢ã«ãã«ãžããšãã«ã¢ãã³å
ã³é«ååéããªãšãã¬ã³ã°ãªã³ãŒã«ããã©ãã³ã
ãŒãããµãŒã«è£ å ¥ããçŽ150âã®æº¶è枩床ãŸã§é
åãããçããçµæç©ãç²ç¶åãã160âã®æž©åºŠ
ã§è©Šéšçã«å§çž®æ圢ããã éæ°åœ¢ãŠãªãŒã¿ãŒããªãŒïŒãŠãªãŒã¿ãŒããªãŒæ
é·é床ïŒWTGRïŒãšããŠæž¬å®ã1981幎ïŒæ21æ¥
ã«çºè¡ãããç±³åœç¹èš±ç¬¬4263158å·ã«è©³è¿°ãããŠ
ããããã«ããŠæ±ºå®ãWTGRã¯ã次ã®æ¡ä»¶ïŒ1K
Hzã5KVã72æéã§æ±ºå®ããã å®çŸ©ã«ãã€ãŠããŠãªãŒã¿ãŒããªãŒæµææ§æ·»å å€
ãæ·»å ããªãã€ãŠçµæç©ã®WTGRã¯1.0ã§ãã
ïŒè¡šã®å¯Ÿç §äŸïŒãè¡šã®å¯Ÿç §äŸïŒ¡ïŒã ã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒïŒWTGR
è©Šéšã«ã€ããŠèšèŒããããã«è£œé ããè©Šéšçãé¡
埮é¡ïŒåç40ÃïŒã§èŠ³å¯ããã¡ãããã¯ã¿ã€åœ¢ã
ãªãŒã®æ°åã³å€§ãããèšé²ããããšã«ãã€ãŠæ±º
å®ãåè©Šéšçã¯ãïŒïŒã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿
ãŒããªãŒãååšããªãïŒããïŒïŒå€ãã®ã¡ããã
ã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒãååšïŒãŸã§ã®å°ºåºŠã§
å®æ§çã«è©äŸ¡ããã ãã«ãŒãã³ã°ïŒ1inåã®1/100è©Šéšçãæ圢ãã
è©Šéšçã宀枩ã§ïŒã±ææŸçœ®ãããè©Šéšçè¡šé¢ã滲
åºã«ã€ããŠæ€æ»ããå®æ§çè©äŸ¡ãè¡ãããšã«ãã€
ãŠæ±ºå®ã åæ¥ç芳ç¹ããã¯ãæ°Žäžã§é²åãããã¹ãé»æ°
å°äœãåãå·»ã絶çžäœãšããŠäœ¿çšãã¹ãçµæç©ã«
ã€ããŠã®äž»ãªç®çã¯ã WIGRã0.2ã«çãããåã¯0.2ããå°ãããã¡
ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒè©ç¹ãïŒããå°
ããã ãã«ãŒãã³ã°ãè¡šé¢æ»²åºã®ã¬ãã«ãäœãããšã§
ããã è¡šåã³è¡šã®äŸã¯ãæ¬çºæãäŸç€ºãããã®
ã§ããã®ç¯å²ãäœãå¶éããªãã è¡šã«èšèŒã®è¡šã¯éééšã§ããã
åéããªãšãã¬ã³ã°ãªã³ãŒã«ãããªããŠãªãŒã¿ãŒ
ããªâæå¶å€ãå«ãéåäœçµæç©ãäŸãã°ãšãã¬
ã³éåäœãåºæãšããçµæç©ã«é¢ãããåŸããã
çµæç©ã¯ããŠãªãŒã¿ãŒããªãŒã€ã³ã°æµææ§ã§ãã
絶çžäœãè¡šé¢ã«åããé»æ°å°äœã®æŒåºç©ãšããŠæ
çšã§ããã çºæã®èæ¯ çµ¶çžé»åã±ãŒãã«ã®æå¹å¯¿åœã¯ããŠãªãŒã¿ãŒã
ãªãŒã€ã³ã°ãšç§°ããç Žå£çŸè±¡ã«ãã€ãŠççž®ããã
ããšãç¥ãããŠããã ãã®çµæãéåäœçµæç©ãäŸãã°ãšãã¬ã³éå
äœçµæç©ãåºæãšãã絶çžäœã¯ããŠãªãŒã¿ãŒããª
ãŒã€ã³ã°æµææ§ãç¹åŸŽãšãã絶çžäœãæäŸããç®
çã§åçš®ã®æ·»å å€ãæ·»å ããããšã«ãã€ãŠå€æ§ã
ããããŠãªãŒã¿ãŒããªãŒã¯ã絶çžäœãæ°Žãååšã
ãç°å¢ã«ããäžæ¹ã§é·æéã«ããã€ãŠé»çã«çœ®ã
ãããšãã«èµ·ãããŠãªãŒã¿ãŒããªãŒã¯ãæã®ãã
æšã«äŒŒãŠããããã«ãã®ããã«åŒã°ãããå®éã«
ã¯ããŠãªãŒã¿ãŒããªãŒã¯ãæ°Žã§æºããããšãã«æ
ããã«çœè²ã§ããã也ç¥ãããšãã«èŠããªããªã
埮å°ãªéè·¯åã¯ç©ºéã§ããã芳å¯ããããã«ã¯ã
ãŠãªãŒã¿ãŒããªãŒãæããè©Šéšçã¯æ°Žäžã§ç ®æ²žã
åã¯ä¹Ÿç¥ãããã°ãªããªãã ãŠãªãŒã¿ãŒããªãŒã¯çµ¶çžäœäžã§é»å§å¿åã®ç¹ã§
æé·ãå§ãããå¿åã®ç¹ã¯ã空éãæ±æç©åã¯äž
èŠåéšãäŸãã°çµ¶çžäœãšåå°é»æ§å±€ãšã®éã®çé¢
ã«ãããäžèŠåéšãååšãã絶çžäœäžã®å Žæã§ã
ãåŸãã空éåã¯æ±æç©ã®å Žåã«ã¯ããŠãªãŒã¿ãŒ
ããªãŒã¯ãããªâã®ç¹ïŒæ žïŒã®å¯ŸåããåŽã«æé·
ããåŸåãããããããŠãããŠã¯ã¡ãããã¯ã¿ã€
ã«é¡ãããã«æé·ãããçé¢ã§éå§ããããªãŒã¯
ããã·ãŠã®åœ¢ã§äžæ¹åã«æé·ãããããŠããã¯é
æ°åœ¢ããªãŒãšç§°ãããããããïŒçš®ã®ãŠãªãŒã¿ãŒ
ããªãŒãå³ã¡ã¡ãããã¯ã¿ã€åã³éæ°åœ¢ããªãŒ
ã¯ãè©ŠéšããããŠãªãŒã¿ãŒããªæå¶å€ã®å€ãã«å¯Ÿ
ããç°ãªã€ãå¿çã«ãã瀺ãããããã«ãç°ãªã€
ãæ©æ§ã«ããéå§ãæé·ãããã®ãšæãããã çŸå°ç¹ãŸã§ã®ãšããã§ã¯ãéåäœçµæç©ã«æ·»å
ãããšãã«ãé·æéã«ãããã¡ãããã¯ã¿ã€åœ¢ã
ãªãŒåã³éæ°åœ¢ãŠãªãŒã¿ãŒããªãŒåœ¢ææµææ§ãå«
ããŠåæ¥çã«æºè¶³ã§ãã調åããæ§è³ªãæããçµ
æç©ãçããåäžãŠãªãŒã¿ãŒããªãŒæå¶å€ç³»ã¯é
çºãããªãã€ãã çºæã®èª¬æ æ¬çºæã¯ããšãã¬ã³éåäœã®ãããªéåäœææ
ã«æ·»å ãããšãã«ãã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒ
ããªãŒåã³éæ°åœ¢ãŠãªãŒã¿ãŒããªãŒåœ¢ææµææ§ã
å«ããŠåæ¥çã«æºè¶³ã§ãã調åããæ§è³ªãæãã
çµæç©ãæäŸãããšããã®çåæ°ŽçŽ çœ®æãžããšã
ã«ã¢ãã³ãšé«ååéããªãšãã¬ã³ã°ãªã³ãŒã«ãã
ãªããŠãªãŒã¿ãŒããªãŒæå¶çµæç©ãæäŸãããæ¬
çºæã®çµæç©ã¯ãããããåšå²ã«æŒåºæ圢ãã絶
çžé»æ°å°äœã®éåžžã®äœååã¯äœ¿çšæž©åºŠã«ãããŠã
ç©ççåã¯é»æ°çæ§è³ªã®æãŸãããªãäœäžãåã
ãããšãªããé·æéã«ããã€ãŠãŠãªãŒã¿ãŒããªãŒ
ã€ã³ã°æµææ§ãä¿æãããããã«ãæ¬çºæã®çµæ
ç©ã¯ãé©åœãªæ¶æ©å¢é²å€ã®æ·»å ã«ãã€ãŠãæ¶æ©
å€ãå³ã¡ææ©éé žåç©ã®éåžžæ¿åºŠãããã»ã©å¢å€§
ãããããšãªãããŠãªãŒã¿ãŒããªãŒæµææ§ã®æ¶æ©
çæç©ã«ç¡¬åãããããšãã§ããã äžè¿°ããããã«ãæ¬çºæã®ãŠãªãŒã¿ãŒããªãŒæ
å¶å€ã¯ãçåæ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ãšé«åå
éããªãšãã¬ã³ã°ãªã³ãŒã«ãšã®çµåããããªãã æ¬çºæã®ç®çã«å¯ŸããŠå¥œé©ã§ãããè³éŠæç°äž
ã«ïŒå以äžã®çåæ°ŽçŽ åºã眮æããŠãããžããšã
ã«ã¢ãã³ãšããŠã¯ãæ¬¡åŒ ïŒããã§ãåã¯ãåäžåã¯ç°ãªã€ãŠããŠã
ããæ°ŽçŽ åã¯ã¢ããåºã«å¯ŸããŠãã©åã³ïŒåã¯ïŒ
ãªã«ãäœçœ®ã«çœ®æããŠããã¢ã«ãã«åã¯ã¢ã©ãŒã«
ãã«åºã®ãããªçåæ°ŽçŽ åºã§ããããã ããã¯
å°ãªããšãïŒåã¯çåæ°ŽçŽ åºã§ããïŒ ãæãããã®ããããããã ååãšããŠãåã¯ïŒã18åã®ççŽ ååã奜ãŸ
ããã¯ïŒãïŒåã®ççŽ ååãæããããã®ãããª
åºã®äŸã¯ãïœâããã»ã³ãïœâãããã³ãïœâãª
ã¯ãã³ãïœâããã³ãªã©ã®ãããªÎ±âãªã¬ãã€ã³
ããå°ããããã®äžŠã³ã«ã¹ãã¬ã³ãαâã¡ãã«ã¹
ãã¬ã³ãªã©ããå°ãããåºã§ããã æ¬çºæã®ç®çã«å¯ŸããŠç¹ã«æãŸãããã®ã¯ãã¹
ãã¬ã³åã¯ãªã¯ãã¬ã³ã§ã¢ã«ãã«åãããžããšã
ã«ã¢ãã³ã®ãããªæ¶²ç¶ãžããšãã«ã¢ãã³ã§ããã
ã¹ãã¬ã³ã§ã¢ã«ãã«åããã液ç¶ãžããšãã«ã¢ã
ã³ã§ãã€ãŠãã°ããã€ã€ãŒã»ã¿ã€ã€ïŒã©ããŒç€Ÿã
ãWingstay29ã®åååã§åžè²©ãããŠãããã®ãã
ãã®ãããªååç©ã®äžäŸã§ããããã®ååç©ã¯ã
äžèšã®çæ³åŒã«åŸããããªãŒãã«ã»ã¯ã©ãã觊åª
ã䜿çšããã¢ã«ãã«åæ¡ä»¶äžã§ãžããšãã«ã¢ãã³
ãšã¹ãã¬ã³ãåå¿ãããããšã«ãã€ãŠåŸãããã å®éã«ã¯ããã®ååç©ã¯ã¢ã眮æäœãšãžçœ®æäœ
ãšã®æ··åç©ã§ãããã®ãšæãããã 液ç¶çåæ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ãé«ååé
ããªãšãã¬ã³ã°ãªã³ãŒã«ãšçµåããŠå«æããçµæ
ç©ã¯ãåèšããæ§è³ªãç¹åŸŽãšããããšä»¥å€ã«ã
ããã«ãŒãã³ã°ãïŒè¡šé¢æ»²åºã説æããã®ã«çšãã
ããçšèªïŒãæ¯èŒç瀺ããªãã ãã®ä»ã®å¥œé©ãªãžããšãã«ã¢ãã³ã¯ä»¥äžã«èšèŒ
ããã æ¬çºæã®ç®çã«å¯ŸããŠå¥œé©ãªããªãšãã¬ã³ã°ãª
ã³ãŒã«ã¯ãçŽ1000ãçŽ20000ã®ååéãæããã
ã®ã§ãããç¹ã«æãŸããããªãšãã¬ã³ã°ãªã³ãŒã«
ã¯ãå°ãªããšã30ã奜ãŸããã¯å°ãªããšã80ã®ç
çŽ æ°ãå³ã¡ççŽ ååæ°ãæãããæ¬çºæã«å¯ŸããŠ
奜é©ãªåžå Žã§å ¥æã§ããããªãšãã¬ã³ã°ãªã³ãŒã«
ã¯ãåååãCarbowaxããåŒç§°20MãšããŠãŠã
ãªã³ã»ã«ãŒãã€ã瀟ããåžè²©ãããŠãããããã
ã®ææã¯ããŠããªã³ã»ã«ãŒãã€ã瀟ã®ãã³ãã¬ã
ãNo.â4772Iã1/78ããå称ïŒã«ãŒãã¯ãã¯ã¹ã
ããªãšãã¬ã³ã°ãªã³ãŒã«ãã«èšèŒãããŠããã ãžããšãã«ã¢ãã³ã«å¯Ÿããããªãšãã¬ã³ã°ãªã³
ãŒã«ã®éã¯ãéåäœã«æ·»å ãããšãã«ãåäžãã
ãŠãªãŒã¿ãŒããªãŒã€ã³ã°æµææ§ãæããéåäœçµ
æç©ãçããçµæç©ãæäŸããã®ã«ååãªãã®ã§
ããã 奜ãŸããã¯ãçåæ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ã«
察ããããªãšãã¬ã³ã°ãªã³ãŒã«ã®éã¯ããžããšã
ã«ã¢ãã³ïŒéééšã«ã€ãçŽ0.2ãçŽïŒéééšã§ã
ãã ãŠãªãŒã¿ãŒããªãŒæµææ§ã®çµæç©ãæäŸããã
ãã«åèšã®ãŠãªãŒã¿ãŒããªãŒæå¶å€çµæç©ãæ·»å
ã§ãã奜é©ãªéåäœææã«ã¯ãéåžžåºäœã®ãšãã¬
ã³ãã¢éåäœããšãã¬ã³âαâãªã¬ãã€ã³å ±éå
äœããšãã¬ã³âαâãªã¬ãã€ã³âãžãšã³åéäœã®
å ±éåäœã®ãããªãšãã¬ã³éåäœãããã奜é©ãª
å ±éåæ§ã®åéäœã¯ããããã¬ã³ãããã³âïŒã
ããã»ã³âïŒãªã©ã®ãããªÎ±âãªã¬ãã€ã³ïŒãã¿
ãžãšã³ãã€ãœãã¬ã³ãªã©ã®ãããªãžãšã³åéäœã§
ããããããŠãã®å Žåã«éåäœã¯å°ãªããšãçŽ70
ééïŒ ã®ãšãã¬ã³ãå«æããã 奜ãŸããå ±éåäœã¯ããšãã¬ã³âãããã¬ã³å ±
éåäœããšãã¬ã³âããã³å ±éåäœãªã©ã§ããã
ãããã®å ±éåäœã¯ã1977幎ïŒæïŒæ¥ã«çºè¡ãã
ãç±³åœç¹èš±ç¬¬4011382å·ã«é瀺ãããŠããããã«ã
ãã¿ã³å€æ§é žåã¯ãã 觊åªãçšããŠçŽ150ãçŽ
300psiã®äœå§äžã§è£œé ããããšãã§ããã ææãªãã°ãããªãããã¬ã³ããšãã¬ã³âãã
ãã¬ã³ãŽã ããšãã¬ã³âãããã¬ã³âãžãšã³ãŽã
ãªã©ã®ãããªä»ã®éåäœãæ¬çºæã®ãšãã¬ã³éå
äœçµæç©ã«æ·»å ããããšãã§ããã æ¬çºæã®çµæç©ã¯ãç«äœé害ããšããŒã«åã³ã¢
ãã³ãéåããïŒïŒïŒïŒïŒâããã©ã¡ãã«ããã
ããã³ãïŒïŒ4â²âããªãã¹ïŒïŒâïœâããã«âïŒ
âã¡ãã«ããšããŒã«ïŒãããªãžãšãã¬ã³ãã¹ïŒïŒïŒ
ïŒâïœâããã«âïŒâããããã·ïŒããããã·ã·
ã³ãã¡ãŒãããžã¹ãã¢ãªã«ããªãžããããªããŒã
ãªã©ã®ãããªé žåé²æ¢å€ãå«æããããšãã§ã
ãã ãŸããæ¬çºæã®çµæç©ã¯ããããç±å¯å¡æ§çµæ
ç©ãšããŠããããããå ç¡«åã¯æ¶æ©çæç©ãšããŠ
çšããããšãããšãã«ã¯ãæ¶æ©å€ãå«æããããš
ãã§ãããå ç¡«åã¯æ¶æ©å€ã¯åœæ¥çã§åšç¥ã§ã
ãã1967幎ïŒæïŒæ¥ã«çºè¡ãããç±³åœç¹èš±ç¬¬
3296189å·ã«èšèŒã®ãããªææ©éé žåç©ãå«ãŸã
ãããããã®ååç©ã¯ãåç¬ã§ãäºã®æ··åç©ãšã
ãŠãåã¯æ¶æ©å¢é²å€ãšå ±ã«çšããããšãã§ããã æ¬çºæã®ç®çã«å¯ŸããŠç¹ã«æãŸãã硬åæ§çµæ
ç©ã¯ããšãã¬ã³éåäœã液ç¶ã®çåæ°ŽçŽ çœ®æãžã
ãšãã«ã¢ãã³ãé«ååéããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãææ©éé žåç©åã³æ¬¡ã®å¹³ååŒ ïŒããã§R1åã³R2ã¯ãåäžåã¯ç°ãªã€ãŠããŠ
ãããäžè¬ã«ïŒã18åã®ççŽ ååã奜ãŸããã¯12
ã14åã®ççŽ ååãæããçåæ°ŽçŽ åºã§ãããïœ
ã¯ïŒã20ã奜ãŸããã¯ïŒã16ã®å€ãæããæŽæ°ã§
ããïŒ ãæããã·ã©ã³æ¶æ©å¢é²å€åã¯æ¬¡ã®å¹³ååŒ ïŒããã§R1åã³R2ã¯åèšãããã®ãšåãã§ã
ããïœåã³ïœã¯åäžåã¯ç°ãªã€ãŠããŠãããïŒã
ïŒã®å€ãæããæŽæ°ã§ããïŒ ãæããã·ã©ã³æ¶æ©å¢é²å€ãå«ãã R1åã³R2ã®å¥œé©ãªåºã®äŸã¯ããªã¯ãã«ããã
ã«ããã·ã«ããŠã³ãã·ã«ãããã·ã«ãã¹ãã¢ãªã«
ãªã©ã®ãããªã¢ã«ãã«åºã§ããã åŒåã³ã®ç¯å²å ã«å ¥ãã·ã©ã³ã®è£œé ã¯ãã¡
ãã«ããã«ãžã¯ãã«ã·ã©ã³åã¯ã¡ãã«ããã«ãžã¯
ãã«ã·ã©ã³ãšãžã¡ãã«ãžã¯ãã«ã·ã©ã³ãšã®æ··åç©
ãæ°Žåã³èèªæã¢ã«ã³ãŒã«åã¯èèªæã¢ã«ã³ãŒã«
æ··åç©ãšåå¿ããã次ãã§é žæ§æ®çç©ã平衡åã
ããäžåãããããšã«ãã€ãŠå ·åãã補é ããã
ãšãã§ãããæ°Žãšã¢ã«ã³ãŒã«ã®ã¢ã«æ¯ã¯ãäžèšã®
ååŠéè«çæ¹çšåŒïŒç°¡åã«ããããã«åå¿äœã¯ã¡
ãã«ããã«ãžã¯ãã«ã·ã©ã³ãæ°Žåã³ããã·ã«ã¢ã«
ã³ãŒã«ã§ãããã®ãšããŠç€ºãïŒãããŠã¯ãŸããã
ã«äºå®èœæ§ã¯ãã«ã·ã©ã³ã®ïŒã¢ã«ããšã«ã€ããŠå€
ããããšãã§ããã åŒã®ç¯å²å ã«å ¥ãã·ã©ã³ã補é ããã«ããã€
ãŠã¯ãã¡ãã«ããã«ãžã¯ãã«ã·ã©ã³ã®éïŒïœïŒãš
ãžã¡ãã«ã¯ãã«ã·ã©ã³ã®éïŒïœïŒã®åèšã¯ã次ã®
ååŠéè«çåå¿åŒã«åŸã€ãŠãïœã«çããã åå¿ã®è©³çŽ°ãäžèšã®æäœã§ç€ºãã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æµžéã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ããããã ã·ã©ã³ïŒã¯äžèšã®ããã«è£œé ãããã 滎äžããŒããæ©æ¢°çæ¹ææ©ã枩床èšåã³çªçŽ ã
ã€ãã¹ã§ä¿è·ããååšä»èžçããããåãã2lã®
äžå£ã®ãã©ã¹ã³ã«846.0ïœïŒ6.0ã¢ã«ïŒã®ã¡ãã«ã
ãã«ãžã¯ãã«ã·ã©ã³ãå ããã滎äžããŒãããã
ã©ã¹ã³ã«294.7ïœïŒ1.5ã¢ã«ïŒã®ããã«ããŒã«ãç·©
ããªé床ã§ããããŸããªããå ããããã©ã¹ã³ã®
枩床ã¯HCã®çºçã®ããã«ïŒ10âã«äœäžããã
ãã«ããŒã«ãæ·»å ããåŸããã©ã¹ã³ã®æž©åºŠãå€éš
氷济ã«ãã10±ïŒâã«ä¿æããªãã89.7ïœïŒ5.0
ã¢ã«ãå³ã¡ååŠéè«çéã®95ïŒ ïŒã®æ°Žã滎äžããŒ
ããããã€ãããšè£ å ¥ãããæ°Žãæ·»å ããåŸãã
ã©ã¹ã³ããããŸããªãã15±ïŒâã§ïŒæéä¿æã
ãïŒHCl平衡åå·¥çšïŒã滎äžããŒããN2âã¹ããŒ
ãžç®¡ã§ä»£ãããã©ã¹ã³ã®å 容ç©ã90âã«ãã€ãã
ãšå ç±ãããã©ã¹ã³ããHClãé£ç¶çã«é€å»ã
ãã30ååŸã«ãã©ã¹ã³ãããšã€ãè©Šæãåæãã
ããè©ŠæïŒïœã«ã€ã0.11meq Cl-ãå«æããããš
ãããã€ããæ°Žã®æ®éïŒ4.5ïœã0.25ã¢ã«ïŒã飜
åNa2CO3溶液ãšããŠæ·»å ãããå ç±ã80âã§ã
ãã«30åéåéãããããŠN2ã¹ããŒãžãç¶ããã
æ®çé žå¡©åç©ã湿ã€ãNaHCO3ã§äžåãããç
æç©ãéããŠã0.01meqïŒïœïŒ0.04ïŒ ïŒã®å¡©çŽ
å«æéãæããç²åºŠ16.5cstkã®éæç¡è²æµåäœ
759.0ïœïŒçè«é792.5ïœãå³ã¡çè«éã®96ïŒ ïŒã
åŸãã ããã«èšèŒã®ã·ã©ã³ã®è£œé ã«çšããããã«ããŒ
ã«ã¯ãããã¯ã¿ãŒïŒã®ã€ã³ãã«ç€Ÿè£œã®Coâ
1214Fatty AlcoholïŒããã«ããŒã«ãšå°éã®C14ã¢
ã«ã³ãŒã«ãå«æããæ··åç©ã®åååïŒã§ãã€ãã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æ»²éã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ãããããããã¯æ¬¡
ã®ããã«è£œé ããã 滎äžããŒããåçž®åšãæ©æ¢°çæ¹ææ©ã枩床èšã
åãããããŠçªçŽ ãã€ãã¹ç®¡ã§ä¿è·ãã1lã®äžå£
ã®ãã©ã¹ã³ã«282.0ïœïŒ2.0ã¢ã«ïŒã®ã¡ãã«ããã«
ãžã¯ãã«ã·ã©ã³ãå ããã枩床ã10ã15âã«ä¿ã¡
ãªãããã€ãããšãããŸããŠã滎äžããŒããã
98.25ïœïŒ0.5ã¢ã«ïŒã®ããã«ããŒã«ãæ·»å ããã
ããã«ããŒã«ãæ·»å ããåŸãåå¿å®¹åšã®æž©åºŠãæ°·
济ã«ãã10ã15âã«ãããŸããªããä¿æããŠ
28.44ïœïŒ1.58ã¢ã«ã1.75ã¢ã«ã®ååŠéè«çéã«å¿
èŠãª90ïŒ ïŒã®æ°Žãæ·»å ããããã©ã¹ã³ã®å 容ç©ã
10ã15âã®æž©åºŠã§ïŒæéãããŸããã滎äžããŒã
ã液äœåå¿æ··åç©äžã«æ¿å ¥ãã管ã§çœ®ãæããçª
çŽ ãæ··åç©äžã«éããäžæ¹ã§ããããŸããªãã90
âã®æž©åºŠã«å ç±ããŠãã©ã¹ã³ããå¡©åæ°ŽçŽ ãé€å»
ããã90âã®æž©åºŠã§0.5æéåŸã«ãæ°Žã®æ®éïŒ3.1
ïœïŒã飜åNa2CO3溶液ãšããŠæ·»å ããã次ãã§
å šãŠã®æ®çå¡©åæ°ŽçŽ ãã·ã©ã³ïŒã®è£œé ã«ãããèš
èŒããããã«ããŠäžåãããéããåŸãç²åºŠã
18.4cstkïŒ25âïŒã§ãã250ïœã®éæç¡è²æµåäœã
åŸãããã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æ»²éã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ããããã ã·ã©ã³ïŒã¯ãã·ã©ã³ïŒã«ã€ããŠèšèŒããæ¹æ³ã«
åŸã€ãŠã282.0ïœïŒïŒã¢ã«ïŒã®ã¡ãã«ããã«ãžã¯
ãã«ã·ã©ã³ã46.6ïœïŒ0.25ã¢ã«ïŒã®ããã«ããŒã«
åã³33.75ïœïŒïŒã»875ã¢ã«ïŒã®H2Oãåå¿ãããŠ
178.5ïœã®éæç¡è²æµåäœãçããããããšã«ã
ã補é ããã ã·ã©ã³ ïŒ æ¬¡ã®å¹³ååŒ ãæãããã®ãšããŠã²ã«æ»²éã¯ãããã°ã©ãã€ãŒ
åã³æ žç£æ°å ±é³Žã«ããç¹åŸŽã¥ããããã ã·ã©ã³ïŒã¯ãã·ã©ã³ïŒã«ã€ããŠèšèŒããæ¹æ³ã«
åŸã€ãŠã141.0ïœïŒ1.0ã¢ã«ïŒã®ã¡ãã«ããã«ãžã¯
ãã«ã·ã©ã³ã129.1ïœïŒ1.0ã¢ã«ïŒã®ãžã¡ãã«ãžã¯
ãã«ã·ã©ã³ã93.2ïœïŒ0.5ã¢ã«ïŒã®ããã«ããŒã«
åã³31.5ïœïŒ1.75ã¢ã«ïŒã®æ°Žãåå¿ãããŠ193.5ïœ
ã®éæç¡è²æµåäœãçããããããšã«ãã補é ã
ãã æ¬çºæã®çµæç©ãåŠæ¹ããã«ããã€ãŠã¯ãçå
æ°ŽçŽ çœ®æãžããšãã«ã¢ãã³ãé«ååéããªãšãã¬
ã³ã°ãªã³ãŒã«ãææ©éé žåç©åã³ã·ã©ã³æ¶æ©å¢é²
å€ã®éïŒçµæç©ã®å šééãåºã«ããŠïŒã¯æ¬¡ã®éã
ã§ããã ãžããšãã«ã¢ãã³ã¯ãé«ååéããªãšãã¬ã³ã°
ãªã³ãŒã«ãšå ±ã«ãçµæç©ã®ãŠãªãŒã¿ãŒããªãŒæµæ
æ§ãåäžãããã®ã«ååãªéã§ãäžè¬ã«çŽ0.2ã
çŽïŒééïŒ ã奜ãŸããã¯çŽ0.5ãçŽïŒééïŒ ã®é
ã§ååšããã é«ååéããªãšãã¬ã³ã°ãªã³ãŒã«ã¯ããžããšã
ã«ã¢ãã³ãšå ±ã«ãçµæç©ã®ãŠãªãŒã¿ãŒããªãŒæµæ
æ§ãåäžãããã®ã«ååãªéã§ãäžè¬ã«çŽ0.2ã
çŽïŒééïŒ ã奜ãŸããã¯çŽ0.2ãçŽ0.5ééïŒ ã®é
ã§ååšããã ææ©éé žåç©ã¯ãçµæç©ãæ¶æ©çæç©ã«ç¡¬åã
ããã®ã«ååãªéã§ãäžè¬ã«çŽïŒãçŽïŒééïŒ ã
奜ãŸããã¯çŽ1.5ãçŽïŒééïŒ ã®éã§ååšããã æ¶æ©å¢é²å€ã¯ãçŽ0.5ãçŽïŒééïŒ ã奜ãŸãã
ã¯çŽ0.5ãçŽ1.5ééïŒ ã®éã§ååšããã æ¬æ现æžã«èšèŒã®æåã®æ··åç©ãæããªãã°ã
ãã䜿çšã§ãããã®ã§ããã 以äžã«è¡šåã³è¡šã«èšèŒã®å®æœäŸåã³å¯Ÿç §äŸ
ãå®æœããã®ã«çšããææã説æããã éåäœ éåäœïŒ¡ïŒ0.7ã®ã¡ã«ãã€ã³ããã¯ã¹åã³0.92
ã®å¯åºŠãæãããšãã¬ã³ãšïœâããã³ãšã®å ±
éåäœ éåäœïŒ¢ïŒïŒã®ã¡ã«ãã€ã³ããã¯ã¹åã³0.92ã®
å¯åºŠãæããããªãšãã¬ã³ éåäœïŒ£ïŒ0.2ã®ã¡ã«ãã€ã³ããã¯ã¹åã³0.92
ã®å¯åºŠãæããããªãšãã¬ã³ ãžããšãã«ã¢ãã³ ïŒã¹ãã¬ã³ã§ã¢ã«ãã«åãããžããšãã«ã¢ã
ã³ïŒWingstay29ãã°ããã€ã€ãŒç€ŸïŒâæ¶²ç¶ ïŒãžã€ãœããã¬ã³ã§ã¢ã«ãã«åãããžããšã
ã«ã¢ãã³ïŒNavgalube438LããŠããã€ã€ã«
瀟ïŒâæ¶²ç¶ ïŒãªã¯ãã¬ã³ã§ã¢ã«ãã«åãããžããšãã«ã¢
ãã³ïŒStaliteâR.V.ããã³ãã«ãã«ã瀟ïŒ
âæ¶²ç¶ ïŒÎ±âã¡ãã«ã¹ãã¬ã³ã§ã¢ã«ãã«åãããžã
ãšãã«ã¢ãã³ïŒNaugard445ããŠããã€ã€ã«
瀟ïŒâåºäœ ïŒãªã¯ãã¬ã³ã§ã¢ã«ãã«åãããžããšãã«ã¢
ãã³ïŒStaliteââR.V.ããã³ãã«ãã«ã
瀟ïŒâåºäœ é žåé²æ¢å€ïŒAQïŒ AQâïŒïŒïŒïŒ4â²âããªãã¹ïŒïŒâïœâããã«
âïŒâã¡ãã«ããšããŒã«ïŒ AQâïŒïŒãžã¹ãã¢ãªã«ããªãžããããªããŒã AQâïŒïŒããªãžãšãã¬ã³ãã¹ïŒïŒïŒïŒâãžâ
ïœâããã«âïŒâããããã·ïŒãããã·ã³ã
ã¡ãŒã ããªãšãã¬ã³ã°ãªã³ãŒã« ããªãšãã¬ã³ã°ãªã³ãŒã« ååéçŽ4000â ãŠããªã³ã«ãŒãã€ã瀟ããååå
ãCarbowaxããšããŠåžè²© ããªãšãã¬ã³ã°ãªã³ãŒã« ååéçŽ20000â ãŠããªã³ã«ãŒãã€ã瀟ããååå20Mãšã
ãŠåžè²© è¡šã«èšèŒã®çµæç©ãåŠæ¹ãè©Šéšããã®ã«çšã
ãæ¹æ³ã次ã«èª¬æããã ãšãã¬ã³éåäœãã¢ã«ãã«ãžããšãã«ã¢ãã³å
ã³é«ååéããªãšãã¬ã³ã°ãªã³ãŒã«ããã©ãã³ã
ãŒãããµãŒã«è£ å ¥ããçŽ150âã®æº¶è枩床ãŸã§é
åãããçããçµæç©ãç²ç¶åãã160âã®æž©åºŠ
ã§è©Šéšçã«å§çž®æ圢ããã éæ°åœ¢ãŠãªãŒã¿ãŒããªãŒïŒãŠãªãŒã¿ãŒããªãŒæ
é·é床ïŒWTGRïŒãšããŠæž¬å®ã1981幎ïŒæ21æ¥
ã«çºè¡ãããç±³åœç¹èš±ç¬¬4263158å·ã«è©³è¿°ãããŠ
ããããã«ããŠæ±ºå®ãWTGRã¯ã次ã®æ¡ä»¶ïŒ1K
Hzã5KVã72æéã§æ±ºå®ããã å®çŸ©ã«ãã€ãŠããŠãªãŒã¿ãŒããªãŒæµææ§æ·»å å€
ãæ·»å ããªãã€ãŠçµæç©ã®WTGRã¯1.0ã§ãã
ïŒè¡šã®å¯Ÿç §äŸïŒãè¡šã®å¯Ÿç §äŸïŒ¡ïŒã ã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒïŒWTGR
è©Šéšã«ã€ããŠèšèŒããããã«è£œé ããè©Šéšçãé¡
埮é¡ïŒåç40ÃïŒã§èŠ³å¯ããã¡ãããã¯ã¿ã€åœ¢ã
ãªãŒã®æ°åã³å€§ãããèšé²ããããšã«ãã€ãŠæ±º
å®ãåè©Šéšçã¯ãïŒïŒã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿
ãŒããªãŒãååšããªãïŒããïŒïŒå€ãã®ã¡ããã
ã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒãååšïŒãŸã§ã®å°ºåºŠã§
å®æ§çã«è©äŸ¡ããã ãã«ãŒãã³ã°ïŒ1inåã®1/100è©Šéšçãæ圢ãã
è©Šéšçã宀枩ã§ïŒã±ææŸçœ®ãããè©Šéšçè¡šé¢ã滲
åºã«ã€ããŠæ€æ»ããå®æ§çè©äŸ¡ãè¡ãããšã«ãã€
ãŠæ±ºå®ã åæ¥ç芳ç¹ããã¯ãæ°Žäžã§é²åãããã¹ãé»æ°
å°äœãåãå·»ã絶çžäœãšããŠäœ¿çšãã¹ãçµæç©ã«
ã€ããŠã®äž»ãªç®çã¯ã WIGRã0.2ã«çãããåã¯0.2ããå°ãããã¡
ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒè©ç¹ãïŒããå°
ããã ãã«ãŒãã³ã°ãè¡šé¢æ»²åºã®ã¬ãã«ãäœãããšã§
ããã è¡šåã³è¡šã®äŸã¯ãæ¬çºæãäŸç€ºãããã®
ã§ããã®ç¯å²ãäœãå¶éããªãã è¡šã«èšèŒã®è¡šã¯éééšã§ããã
ãè¡šã
ãŒããªãŒã®è©
ç¹
è¡šã®æ¶æ©çµæç©ã¯ãåæåããã©ãã³ããŒã
ããµãŒã«è£ å ¥ããçããæ··åç©ãçŽ120âã®æº¶è
枩床ãŸã§é åããããšã«ãã€ãŠè£œé ãããåçµæ
ç©ãç²ç¶åãã125âã®æž©åºŠã§è©Šéšçã«å§çž®æ圢
ãããè©Šéšçã180âã®æž©åºŠã§åå ã§ç¡¬åãããã
WIGRã«ã€ããŠè©Šéšããåã«ãå硬åè©Šéšçã
115âã®æž©åºŠã«ãããªãŒãã³ã§15åéã¢ããŒãªã³
ã°ãããã®åŸè©Šéšçã85âã®æž©åºŠã®ç空ãªãŒãã³
ã§ïŒæ¥éå ç±ããããšã«ãã€ãŠéé žåç©æ®çç©ã
é€å»ããã è¡šã«èšèŒã®è©Šéšã¯ã次ã®ããã«å®æœããã WTGRïŒ5KVã1KHzã72æéã§æ±ºå®ã åçµæç©ã®ç¡¬å床ã¯ã1977幎ïŒæ19æ¥ã«çºè¡ã
ããç±³åœç¹èš±ç¬¬4018852å·ã«è©³è¿°ãããã¢ã³ãµã³
ãã»ã¬ãªã¡ãŒã¿è©Šéšã«ãã決å®ãããããŠ1bâin
ã§èšé²ããã ç©ççå£åã«å¯Ÿããæµææ§ïŒåèšã®ããã«è£œé
ãã硬åè©ŠéšçãçšããASTM â638ã«èšèŒ
ã®æ¹æ³ã«åŸã䌞ã³ã®æ®çãè©Šéšããããšã«ãã決
å®ã ãã«ãŒãã³ã°ïŒæªç¡¬åè©ŠéšçãïŒâã60âã®æž©
床ã§ïŒã±ææŸçœ®ããè©Šéšçã®è¡šé¢ã滲åºã«ã€ããŠ
ç®èŠæ€æ»ããå®æ§è©äŸ¡ãè¡ãªãããšã«ãã決å®ã ã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒïŒåçµæç©
ã«ã€ããŠããããã0.02inåã®ïŒæã®ã·ãŒããæ
圢ããïŒæã®ã·ãŒãã®çé¢ã«å°éã®ç²æ«ç¶NaCl
ã眮ããïŒæã®ã·ãŒããäžç·ã«ããŠ125âã®æž©åºŠ
ã§æ圢ããŠè©Šéšçãäœæããããšã«ãã決å®ãè©Š
éšçã¯ã180âã®æž©åºŠã§åå ã§ç¡¬åããããéé ž
åç©æ®çç©ã¯ãè©Šéšçã85âã®æž©åºŠãšããç空ãª
ãŒãã³å ã§ïŒæ¥éå ç±ããããšã«ããé€å»ããã æ·»éã®å³é¢ãåç §ããã«ãè©ŠéšçïŒãã¬ã©ã¹å®¹
åšïŒã®äžå€®éå£éšã«å ¥ããŠä¿æããã¬ã©ã¹å®¹åšïŒ
ãäºã€ã®åºç»ã«åãããè©ŠéšçïŒãã¬ã©ã¹å®¹åšïŒ
ã«å ¥ãã0.1Nå¡©åãããªãŠã 氎溶液ïŒãšæ¥è§Šã
ããã氎溶液ïŒãé«é»å§ãªãŒãç·ïŒãä»ããŠé»æº
ïŒå³ç€ºããŠãªãïŒãšæ¥ç¶ãããããŠæ¥å°ç·ïŒïŒã
ä»ããŠæ¥å°ããããACé»å§ã5KVã1KHzããªãŒ
ãç·ãä»ããŠæ¥éå°å ãããïŒæ¥éåŸã«ãè©Šéšç
ãã¡ãã¬ã³ãã«ãŒæ°Žæº¶æ¶²ã§æè²ããããŠãªãŒã¿ãŒ
ããªãŒãç®èŠã§ããããã«ããããåè©Šéšçãé¡
埮é¡ïŒåç40ÃïŒã§ç®èŠæ€æ»ããïŒïŒã¡ãããã¯
ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒãååšããªãïŒããïŒ
ïŒå€ãã®ã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒãå
åšïŒãŸã§ã®å°ºåºŠã§å®æ§çã«è©äŸ¡ããã WTGRãã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒ
ã«ã€ããŠã®äž»ãªåæ¥çç®çã¯ãå ã«èšèŒããã 硬å床ã«ã€ããŠã®äž»ãªåæ¥çç®çã¯ã48±41b
âinã§ããã150âã§ïŒæ¥éã®äŒžã³ã®æ®çïŒ ã¯75
ïŒ ä»¥äžã§ããã
ç¹
è¡šã®æ¶æ©çµæç©ã¯ãåæåããã©ãã³ããŒã
ããµãŒã«è£ å ¥ããçããæ··åç©ãçŽ120âã®æº¶è
枩床ãŸã§é åããããšã«ãã€ãŠè£œé ãããåçµæ
ç©ãç²ç¶åãã125âã®æž©åºŠã§è©Šéšçã«å§çž®æ圢
ãããè©Šéšçã180âã®æž©åºŠã§åå ã§ç¡¬åãããã
WIGRã«ã€ããŠè©Šéšããåã«ãå硬åè©Šéšçã
115âã®æž©åºŠã«ãããªãŒãã³ã§15åéã¢ããŒãªã³
ã°ãããã®åŸè©Šéšçã85âã®æž©åºŠã®ç空ãªãŒãã³
ã§ïŒæ¥éå ç±ããããšã«ãã€ãŠéé žåç©æ®çç©ã
é€å»ããã è¡šã«èšèŒã®è©Šéšã¯ã次ã®ããã«å®æœããã WTGRïŒ5KVã1KHzã72æéã§æ±ºå®ã åçµæç©ã®ç¡¬å床ã¯ã1977幎ïŒæ19æ¥ã«çºè¡ã
ããç±³åœç¹èš±ç¬¬4018852å·ã«è©³è¿°ãããã¢ã³ãµã³
ãã»ã¬ãªã¡ãŒã¿è©Šéšã«ãã決å®ãããããŠ1bâin
ã§èšé²ããã ç©ççå£åã«å¯Ÿããæµææ§ïŒåèšã®ããã«è£œé
ãã硬åè©ŠéšçãçšããASTM â638ã«èšèŒ
ã®æ¹æ³ã«åŸã䌞ã³ã®æ®çãè©Šéšããããšã«ãã決
å®ã ãã«ãŒãã³ã°ïŒæªç¡¬åè©ŠéšçãïŒâã60âã®æž©
床ã§ïŒã±ææŸçœ®ããè©Šéšçã®è¡šé¢ã滲åºã«ã€ããŠ
ç®èŠæ€æ»ããå®æ§è©äŸ¡ãè¡ãªãããšã«ãã決å®ã ã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒïŒåçµæç©
ã«ã€ããŠããããã0.02inåã®ïŒæã®ã·ãŒããæ
圢ããïŒæã®ã·ãŒãã®çé¢ã«å°éã®ç²æ«ç¶NaCl
ã眮ããïŒæã®ã·ãŒããäžç·ã«ããŠ125âã®æž©åºŠ
ã§æ圢ããŠè©Šéšçãäœæããããšã«ãã決å®ãè©Š
éšçã¯ã180âã®æž©åºŠã§åå ã§ç¡¬åããããéé ž
åç©æ®çç©ã¯ãè©Šéšçã85âã®æž©åºŠãšããç空ãª
ãŒãã³å ã§ïŒæ¥éå ç±ããããšã«ããé€å»ããã æ·»éã®å³é¢ãåç §ããã«ãè©ŠéšçïŒãã¬ã©ã¹å®¹
åšïŒã®äžå€®éå£éšã«å ¥ããŠä¿æããã¬ã©ã¹å®¹åšïŒ
ãäºã€ã®åºç»ã«åãããè©ŠéšçïŒãã¬ã©ã¹å®¹åšïŒ
ã«å ¥ãã0.1Nå¡©åãããªãŠã 氎溶液ïŒãšæ¥è§Šã
ããã氎溶液ïŒãé«é»å§ãªãŒãç·ïŒãä»ããŠé»æº
ïŒå³ç€ºããŠãªãïŒãšæ¥ç¶ãããããŠæ¥å°ç·ïŒïŒã
ä»ããŠæ¥å°ããããACé»å§ã5KVã1KHzããªãŒ
ãç·ãä»ããŠæ¥éå°å ãããïŒæ¥éåŸã«ãè©Šéšç
ãã¡ãã¬ã³ãã«ãŒæ°Žæº¶æ¶²ã§æè²ããããŠãªãŒã¿ãŒ
ããªãŒãç®èŠã§ããããã«ããããåè©Šéšçãé¡
埮é¡ïŒåç40ÃïŒã§ç®èŠæ€æ»ããïŒïŒã¡ãããã¯
ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒãååšããªãïŒããïŒ
ïŒå€ãã®ã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒãå
åšïŒãŸã§ã®å°ºåºŠã§å®æ§çã«è©äŸ¡ããã WTGRãã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒããªãŒ
ã«ã€ããŠã®äž»ãªåæ¥çç®çã¯ãå ã«èšèŒããã 硬å床ã«ã€ããŠã®äž»ãªåæ¥çç®çã¯ã48±41b
âinã§ããã150âã§ïŒæ¥éã®äŒžã³ã®æ®çïŒ ã¯75
ïŒ ä»¥äžã§ããã
ãè¡šã
æ¬çºæã§çšããã·ã©ã³å¢é²å€ã¯ãHerbert B.
Pettyã®ç±³åœç¹èš±åºé¡ã«èšèŒãããŠããã æ¬æ现æžã§èšèŒã®ã¡ã«ãã€ã³ããã¯ã¹ã¯ã
ASTMè©ŠéšïŒ€â1238ã§æ±ºå®ãããïœïœïŒminã§
è¡šããããã ãŸããå¯åºŠã¯ãASTMè©ŠéšïŒ€â1505ã§æ±ºå®ã
ããïœïŒcm3ã§è¡šããããã
Pettyã®ç±³åœç¹èš±åºé¡ã«èšèŒãããŠããã æ¬æ现æžã§èšèŒã®ã¡ã«ãã€ã³ããã¯ã¹ã¯ã
ASTMè©ŠéšïŒ€â1238ã§æ±ºå®ãããïœïœïŒminã§
è¡šããããã ãŸããå¯åºŠã¯ãASTMè©ŠéšïŒ€â1505ã§æ±ºå®ã
ããïœïŒcm3ã§è¡šããããã
æ·»éã®å³é¢ã¯ãã¡ãããã¯ã¿ã€åœ¢ãŠãªãŒã¿ãŒã
ãªãŒãè©Šéšçã«æé·ãããã®ã«çšããè£ çœ®ã®æšªæ
é¢å³ã§ããã ïŒã¯è©ŠéšçãïŒã¯ã¬ã©ã¹å®¹åšãïŒã¯å¡©åãããª
ãŠã 氎溶液ãïŒã¯é«å§ãªãŒãç·ã
ãªãŒãè©Šéšçã«æé·ãããã®ã«çšããè£ çœ®ã®æšªæ
é¢å³ã§ããã ïŒã¯è©ŠéšçãïŒã¯ã¬ã©ã¹å®¹åšãïŒã¯å¡©åãããª
ãŠã 氎溶液ãïŒã¯é«å§ãªãŒãç·ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãšãã¬ã³éåäœãšãçµæç©ã®å šééãåºã«ã
ãŠ0.2ãïŒééïŒ ã®éã®çåæ°ŽçŽ çœ®æãžããšãã«
ã¢ãã³ãšã0.2ãïŒééïŒ ã®éã®1000ã20000ã®å
åéãæããããªãšãã¬ã³ã°ãªã³ãŒã«ãšãå«ãã
åäžãããŠãªãŒã¿ãŒããªãŒã€ã³ã°æµææ§ãæãã
ãšãã¬ã³ç³»éåäœçµæç©ã ïŒ ãšãã¬ã³éåäœãããªãšãã¬ã³ã§ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ ãšãã¬ã³éåäœããšãã¬ã³å ±éåäœã§ããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ å ±éåäœããšãã¬ã³âããã³å ±éåäœã§ãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ ã¢ãã³ããªã¯ãã¬ã³ã§ã¢ã«ãã«åããããžã
ãšãã«ã¢ãã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
çµæç©ã ïŒ ã¢ãã³ãã¹ãã¬ã³ã§ã¢ã«ãã«åããããžããš
ãã«ã¢ãã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµ
æç©ã ïŒ ã¢ãã³ãαâã¡ãã«ã¹ãã¬ã³ã§ã¢ã«ãã«åã
ãããžããšãã«ã¢ãã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®çµæç©ã ïŒ ã°ãªã³ãŒã«ã4000ã®ååéãæããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ ã°ãªã³ãŒã«ã20000ã®ååéãæããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒïŒ ææ©éé žåç©ãå«æããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®çµæç©ã ïŒïŒ ææ©éé žåç©åã³æ¶æ©å¢é²å€ãå«æããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒïŒ å¢é²å€ãæ¬¡åŒ ïŒããã§ãR1åã³R2ã¯çåæ°ŽçŽ åºã§ãããïœ
ã¯ïŒã16ã®å€ãæããæŽæ°ã§ããïŒ ãæããã·ã©ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èš
èŒã®çµæç©ã ïŒïŒ å¢é²å€ãæ¬¡åŒ ïŒããã§ãR1åã³R2ã¯çåæ°ŽçŽ åºã§ãããïœ
åã³ïœã¯ããããïŒãïŒã®å€ãæããæŽæ°ã§ã
ãïŒ ãæããã·ã©ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èš
èŒã®çµæç©ã ïŒïŒ ã·ã©ã³ãC12çåæ°ŽçŽ ã§æ«ç«¯ãããã¯ãã
ãã¡ãã«ããã«ã·ãããµã³ã§ããããããŠïœãïŒ
ã®å€ãæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®çµæ
ç©ã ïŒïŒ ã·ã©ã³ãC12çåæ°ŽçŽ ã§æ«ç«¯ãããã¯ãã
ãã¡ãã«ããã«ã·ãããµã³ã§ããããããŠïœã16
ã®å€ãæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®çµæ
ç©ã ïŒïŒ ã·ã©ã³ãC12çåæ°ŽçŽ ã§æ«ç«¯ãããã¯ãã
ãŠããããããŠïœåã³ïœãããããïŒã®å€ãæã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®çµæç©ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36295982A | 1982-03-31 | 1982-03-31 | |
| US362959 | 1982-03-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58201843A JPS58201843A (ja) | 1983-11-24 |
| JPH0119691B2 true JPH0119691B2 (ja) | 1989-04-12 |
Family
ID=23428218
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58052821A Granted JPS58201843A (ja) | 1982-03-31 | 1983-03-30 | ãŠã©ãŒã¿ãŒããªãŒã€ã³ã°æµææ§ãæãããšãã¬ã³ç³»éåäœçµæç© |
| JP62316388A Pending JPS63178151A (ja) | 1982-03-31 | 1987-12-16 | ãšãã¬ã³ç³»éåäœçµæç©çšãŠãªãŒã¿ãŒããªãŒæå¶æ·»å å€çµæç© |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62316388A Pending JPS63178151A (ja) | 1982-03-31 | 1987-12-16 | ãšãã¬ã³ç³»éåäœçµæç©çšãŠãªãŒã¿ãŒããªãŒæå¶æ·»å å€çµæç© |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0090427B1 (ja) |
| JP (2) | JPS58201843A (ja) |
| AU (1) | AU550853B2 (ja) |
| BR (1) | BR8301639A (ja) |
| CA (1) | CA1181940A (ja) |
| DE (1) | DE3365239D1 (ja) |
| ES (1) | ES521159A0 (ja) |
| GR (1) | GR77987B (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994030031A1 (en) * | 1993-06-16 | 1994-12-22 | Nippon Yakin Kogyo Co., Ltd. | Container for electromagnetic cooking and production thereof |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1181940A (en) * | 1982-03-31 | 1985-02-05 | Robert J. Turbett | Compositions of hydrocarbon-substituted diphenyl amines and high molecular weight polyethylene glycols; and the use thereof as water-tree retardants for polymers |
| EP0217585A3 (en) * | 1985-09-24 | 1989-08-30 | Du Pont Canada Inc. | Manufacture of film from linear low density polyethylene |
| US4812505A (en) * | 1987-05-18 | 1989-03-14 | Union Carbide Corporation | Tree resistant compositions |
| US4797511A (en) * | 1987-09-25 | 1989-01-10 | Uniroyal Chemical Company, Inc. | Polyethylene stabilized by mixture of hindered phenol and amine antioxidants |
| JPH0794582B2 (ja) * | 1990-08-24 | 1995-10-11 | ãã€ãã³å·¥æ¥æ ªåŒäŒç€Ÿ | åºçæ§ã®æ¹è¯ããããã«ãªããšã©ã¹ãããŒçµæç© |
| TW403916B (en) * | 1995-03-30 | 2000-09-01 | Union Carbide Chem Plastic | Tree resistant cable |
| GB0022687D0 (en) * | 2000-09-15 | 2000-11-01 | Biccgeneral Uk Cables Ltd | Polymer composition and a method and apparatus for testing the resistance of the of the polymer composition to electrical stress induced degradation |
| CN1965377B (zh) | 2004-06-09 | 2010-12-22 | é¶æ°åº·å®å ¬åž | çšäºçµçŒä¿®å€æµäœçæè èæ·»å å |
| KR102210037B1 (ko) | 2012-12-21 | 2021-02-01 | ë€ì° êžë¡ë² í í¬ëë¡ì§ì€ ìììš | ê°ì ë ë°í¬ì± ë° í¥ìë ê°ê³µì±ì ìí íŽëŠ¬ì¬ë í-êž°ì¬ ìŒìŽëž íí©ë¬Œ ì ì |
| CN109593265B (zh) * | 2018-12-14 | 2021-07-27 | æéœé«æé¹é«ååç§æè¡ä»œæéå ¬åž | äžç§äœæ¶çŒ©ç¡ ç·äº€èçµçŒæåå ¶å¶å€æ¹æ³ |
| WO2022040763A1 (pt) | 2020-08-24 | 2022-03-03 | Tiecher Mauro | Sistema de ajuste de mancais para máquinas de processamento de miúdos de aves de abate |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5628231A (en) * | 1979-08-16 | 1981-03-19 | Nippon Yunikaa Kk | Polyolefin composition for electrical insulation |
| CA1181940A (en) * | 1982-03-31 | 1985-02-05 | Robert J. Turbett | Compositions of hydrocarbon-substituted diphenyl amines and high molecular weight polyethylene glycols; and the use thereof as water-tree retardants for polymers |
-
1983
- 1983-03-25 CA CA000424555A patent/CA1181940A/en not_active Expired
- 1983-03-30 EP EP83103194A patent/EP0090427B1/en not_active Expired
- 1983-03-30 ES ES521159A patent/ES521159A0/es active Granted
- 1983-03-30 GR GR70943A patent/GR77987B/el unknown
- 1983-03-30 BR BR8301639A patent/BR8301639A/pt unknown
- 1983-03-30 AU AU13030/83A patent/AU550853B2/en not_active Expired
- 1983-03-30 DE DE8383103194T patent/DE3365239D1/de not_active Expired
- 1983-03-30 JP JP58052821A patent/JPS58201843A/ja active Granted
-
1987
- 1987-12-16 JP JP62316388A patent/JPS63178151A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994030031A1 (en) * | 1993-06-16 | 1994-12-22 | Nippon Yakin Kogyo Co., Ltd. | Container for electromagnetic cooking and production thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1303083A (en) | 1983-10-06 |
| JPS58201843A (ja) | 1983-11-24 |
| ES8405828A1 (es) | 1984-06-16 |
| CA1181940A (en) | 1985-02-05 |
| EP0090427B1 (en) | 1986-08-13 |
| DE3365239D1 (en) | 1986-09-18 |
| GR77987B (ja) | 1984-09-25 |
| EP0090427A1 (en) | 1983-10-05 |
| JPS63178151A (ja) | 1988-07-22 |
| BR8301639A (pt) | 1983-12-13 |
| AU550853B2 (en) | 1986-04-10 |
| ES521159A0 (es) | 1984-06-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4440671A (en) | Compositions of hydrocarbon-substituted diphenyl amines and high molecular weight polyethylene glycols; and the use thereof as water-tree retardants for polymers | |
| JP5680107B2 (ja) | äžé»å§ã±ãŒãã«çšçµ¶çžæ | |
| JPH0119691B2 (ja) | ||
| JPH086023B2 (ja) | æããªãŒæ§çµæç© | |
| EP0252878A1 (en) | Voltage stabilized polyolefin compositions and silicone-glycol derivatives suitable therefor | |
| JP2002514262A (ja) | ãšãã¬ã³âé ¢é žããã«ã³ããªããŒãšãšãã¬ã³âé ¢é žããã«âäžé žåççŽ ã¿ãŒããªããŒãšã®é åç© | |
| JPS6323944A (ja) | é»æ°çµ¶çžçµæç©åã³ããã§çµ¶çžãããé»ç·åã¯ã±âãã« | |
| KR0122076B1 (ko) | íë íë ë° ì믌 ì°íë°©ì§ì íŒí©ë¬Œì í¬íšíë íŽëŠ¬ìížë ì ìì í ì¡°ì±ë¬Œ | |
| JPS5869236A (ja) | ãŠãªâã¿âããªâã€ã³ã°ãïœâããšãã«çœ®æã¢ããã·ã©ã³ã«ããå®å®åããããšãã¬ã³éåäœåã³é»æ°å°äœã®çµ¶çžäœãšããŠã®ãããçµæç©ã®äœ¿çš | |
| JP7181869B2 (ja) | 硬åæ§åå°äœçµæç© | |
| JPS62283984A (ja) | ããªâã€ã³ã°é²æ¢çšæ·»å å€ | |
| EP0090382B1 (en) | Organo siloxanes, method for the preparation thereof and polymeric compositions containing same | |
| JP2020513422A (ja) | åçµæ¶æ§ããªãªã¬ãã£ã³ç³»æ·»å å€ãã¹ã¿ãŒãããçµæç© | |
| US4426480A (en) | Organo siloxanes, method for the preparation thereof and polymeric compositions containing same | |
| US4492647A (en) | Organopolysiloxanes useful as dielectric fluids and anti-treeing additives | |
| SU973567A1 (ru) | СÑОваÑÑа Ñ ÐºÐŸÐŒÐ¿ÐŸÐ·ÐžÑО Ма ПÑМПве пПлОÑÑОлеМа | |
| TWI805586B (zh) | å¯äº€è¯çµåç©ã補å以åå°é»æ¹æ³ | |
| JPH0668043B2 (ja) | å®å®åãããããªãªã¬ãã£ã³çµæç© | |
| EP0829090A1 (en) | Polymer compositions and electric cables | |
| EP0109797A2 (en) | Polymeric compositions resistant to electrical and water treeing | |
| JPH03166246A (ja) | éåäœãã¬ã³ãçµæç© |