JPH0142241B2 - - Google Patents

Info

Publication number
JPH0142241B2
JPH0142241B2 JP56184809A JP18480981A JPH0142241B2 JP H0142241 B2 JPH0142241 B2 JP H0142241B2 JP 56184809 A JP56184809 A JP 56184809A JP 18480981 A JP18480981 A JP 18480981A JP H0142241 B2 JPH0142241 B2 JP H0142241B2
Authority
JP
Japan
Prior art keywords
rice
salt
weight
acid
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP56184809A
Other languages
Japanese (ja)
Other versions
JPS5885805A (en
Inventor
Masami Ogawa
Masahiro Kitaoka
Kanji Kobayashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sankyo Co Ltd
Original Assignee
Sankyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sankyo Co Ltd filed Critical Sankyo Co Ltd
Priority to JP56184809A priority Critical patent/JPS5885805A/en
Priority to KR8205190A priority patent/KR880001580B1/en
Publication of JPS5885805A publication Critical patent/JPS5885805A/en
Publication of JPH0142241B2 publication Critical patent/JPH0142241B2/ja
Granted legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は、3−ヒドロキシ−5メチルイソキサ
ゾールまたはその塩と、メチオニンおよび/また
はアブシジン酸と、2,4−ジクロロフエノキシ
酢酸またはその塩、エステルもしくは酸アミドと
を有効成分とするイネの登熟促進剤に関する。 異常気象によつて、わが国の稲作は北海道及び
東北地方を中心に冷害に見舞われることがしばし
ばあり、その様相は穂孕期の低温によるいわゆる
障害型不稔のみならず、開花期の障害不稔、さら
に登熟期の低温による登熟不良によつて一層深刻
なものとなるのが常であつて、その解決策が切に
望まれている。 最近、化学物質による冷害防止効果が検討され
はじめ、3−ヒドロキシ−5−メチルイソキサゾ
ールが低温下で水稲の登熟向上作用を示すこと
(濃業および園芸、56、657−660、1981)、および
3−ヒドロキシ−5−メチルイソキサゾールにβ
−インドール−3−ブチル酸(IBA)およびメチ
オニンを併用することにより、低温下における水
稲の登熟向上効果を高められること(日本作物学
会第169回講演会要旨集、161−162、1980)がす
でに知られている。 本発明者等は、3−ヒドロキシ−5−メチルイ
ソキサゾールまたはその塩(A)およびメチオニン(B)
または/およびアブシジン酸(C)に、2,4−ジク
ロロフエノキシ酢酸またはその塩、エステルもし
くは酸アミド(D)を配合したところ、意外にも上記
3種または4種の化合物の配合剤が低温下におけ
るイネに対して穂への炭化水素の転流を促進して
きわめて顕著な登熟促進作用を示すことを見出し
た。すなわち、本配合剤をイネの出穂開花期に施
用することにより、特に低温の影響を受けやすい
弱勢頴花の登熟を促進し、発育停止米(クズ米)
を健全米に変えることを見い出し、本発明を完成
した。 特に本配合剤の処理により、遅延型冷害による
被害を軽減し、増収をもたらすことは、イネ作の
減反が進みつつある日本農度において、きわめて
有意義なことである。 3−ヒドロキシ−5−メチルイソキサゾールの
塩としてはナトリウム、カリウム、カルシウム、
マグネシウム、アンモニウムのような塩があげら
れ、特にカリウム塩が好適に使用される。これら
の塩における金属原子等は3−位置のヒドロキシ
ル基の水素原子と置換している。 2,4−ジクロロフエノキシ酢酸の塩、エステ
ルもしくは酸アミドとしては、たとえばナトリウ
ム塩、カリウム塩、アミン塩、アンモニウム塩:
メチルエステル、エチルエステル、ブチルエステ
ルまたはイソブチルエステルのようなアルキルエ
ステル、アリルエステル、酸アミド等があげられ
るが、必ずしもこれらに限定されるものではな
い。 本発明のイネの登熟促進剤中の有効成分の配合
割合は、2,4−ジクロロフエノキシ酢酸の塩、
エステルもしくは酸アミド(D)1重量部に対して、
3−ヒドロキシ−5−メチルイソキサゾールもし
くはその塩(A)2.000ないし200重量部およびメチオ
ニン(B)3000ないし100重量部またはアブシジン酸
(C)10ないし0.1重量部が適当である。 本発明のイネの登熟促進剤は、(A)、(B)または/
および(C)並びに(D)を上記の割合で坦体と混合して
通常の農薬の製剤形態である粉剤、水和剤、乳剤
等に製剤される。 製剤の性状を改善し、あるいは生物効果を高め
る目的で、種々の界面活性剤、高分子化合物等が
適宜使用される。もちろん他の値物生長調節剤、
除草剤、殺菌剤、殺虫剤、肥料等を併用すること
もできる。 薬剤の処理方法としては、対象とする植物に茎
葉散布するか、または土壤潅注により使用される
が、前者がより好ましい。 次に本発明のイネの登熟促進剤の効果を試験例
をあげて説明する。 試験例 1 1/5000アールワグネルポツトによく砕土した
砂壤土をつめ、催芽した稲の種子(品種:日本
晴)を6月10日にポツト当り20粒づつ播種した。
分けつは適宜切除し、主桿のみとして戸外で生育
させ、9月5日当日に出穂開花した個体を選び、
後記製剤例1に準じて調製した所定濃度の混合液
に稲の穂を浸漬処理した。翌日、ポツトを昼20
℃、夜13℃の人工気象箱に移し、育成した。 9月22日に穂をサンプリングし、30℃で48時間
通風乾燥後、上位より5番目の一次枝梗について
解体し、先端部より2番目、弱勢頴花に由来する
籾の乾燥重を測定した。 データは各区14穂について示した。
The present invention provides a rice product containing 3-hydroxy-5methylisoxazole or its salt, methionine and/or abscisic acid, and 2,4-dichlorophenoxyacetic acid or its salt, ester, or acid amide as active ingredients. Concerning a ripening accelerator. Due to abnormal weather, rice crops in Japan are often affected by cold damage, mainly in Hokkaido and the Tohoku region, and this is not only caused by so-called impaired sterility due to low temperatures during the heading stage, but also impaired sterility during the flowering stage. Furthermore, poor ripening caused by low temperatures during the ripening stage is always made more serious, and a solution to this problem is desperately needed. Recently, studies have begun to examine the effects of chemical substances on preventing cold damage, and it has been found that 3-hydroxy-5-methylisoxazole improves ripening of paddy rice at low temperatures (Kokuyo and Horiku, 56, 657-660, 1981). , and β to 3-hydroxy-5-methylisoxazole
- The combined use of indole-3-butyric acid (IBA) and methionine has been shown to enhance the effect of improving ripening in paddy rice at low temperatures (Collection of Abstracts of the 169th Conference of the Crop Science Society of Japan, 161-162, 1980). Already known. The present inventors have discovered that 3-hydroxy-5-methylisoxazole or its salt (A) and methionine (B)
When 2,4-dichlorophenoxyacetic acid or its salt, ester or acid amide (D) was blended with or/and abscisic acid (C), unexpectedly, the combination of the above three or four compounds was We have found that this method has a very significant effect on rice grain filling at low temperatures by promoting the translocation of hydrocarbons to the panicle. In other words, by applying this combination agent during the earing and flowering stage of rice, it promotes the ripening of weak rice plants that are particularly susceptible to low temperatures, and improves the growth of stunted rice (kudzu rice).
They discovered that rice can be transformed into healthy rice, and completed the present invention. In particular, the reduction of damage caused by delayed cold damage and increased yield through treatment with this combination agent is extremely significant for Japan's agricultural industry, where the reduction of rice acreage is progressing. Salts of 3-hydroxy-5-methylisoxazole include sodium, potassium, calcium,
Examples include salts such as magnesium and ammonium, and potassium salts are particularly preferred. The metal atom etc. in these salts is substituted with the hydrogen atom of the hydroxyl group at the 3-position. Examples of the salt, ester or acid amide of 2,4-dichlorophenoxyacetic acid include sodium salt, potassium salt, amine salt, ammonium salt:
Examples include, but are not limited to, alkyl esters such as methyl ester, ethyl ester, butyl ester, or isobutyl ester, allyl esters, acid amides, and the like. The blending ratio of the active ingredients in the rice ripening accelerator of the present invention is 2,4-dichlorophenoxyacetic acid salt,
For 1 part by weight of ester or acid amide (D),
2.000 to 200 parts by weight of 3-hydroxy-5-methylisoxazole or its salt (A) and 3000 to 100 parts by weight of methionine (B) or abscisic acid
(C) 10 to 0.1 parts by weight is suitable. The rice ripening accelerator of the present invention comprises (A), (B) or/
(C) and (D) are mixed with a carrier in the above proportions to formulate powders, wettable powders, emulsions, etc., which are the usual formulation forms of agricultural chemicals. Various surfactants, polymer compounds, etc. are used as appropriate for the purpose of improving the properties of the preparation or increasing its biological effects. Of course other valuable growth regulators,
Herbicides, fungicides, insecticides, fertilizers, etc. can also be used in combination. As a treatment method for the chemical, it is used by spraying the target plants on the foliage or by irrigating the target plants, with the former being more preferred. Next, the effect of the rice ripening accelerator of the present invention will be explained with reference to test examples. Test Example 1 A 1/5000 Ahl Wagner pot was filled with well-crushed sandy soil, and germinated rice seeds (variety: Nipponbare) were sown on June 10th at 20 grains per pot.
Cut off the divisions as appropriate, grow them outdoors with only the main stem, and select the individuals that started heading and bloomed on September 5th.
Rice ears were immersed in a mixed solution of a predetermined concentration prepared according to Formulation Example 1 described later. The next day, I had pottu at 20pm.
They were transferred to an artificial climate box at 13°C at night and grown. The ears were sampled on September 22nd, and after drying with ventilation at 30°C for 48 hours, the fifth primary branch stem from the top was dissected, and the dry weight of the paddy derived from the second weakest branch stem from the tip was measured. . Data are shown for 14 panicles in each plot.

【表】 製剤例 1 水和剤 3−ヒドロキシ−5−メチルイソキサゾールカル
シウム塩 ……10重量部 メチオニン ……20重量部 2,4−ジクロロフエノキシ酢酸ナトリウム塩
……0.02重量部 ポリビニルアルコール ……1重量部 ドデシルベンゼンスルホン酸ナトリウム
……3重量部 クレー ……残部 を混合粉砕して水和剤を得る。 製剤例 2 液剤 3−ヒドロキシ−5−メチルイソキサゾールカリ
ウム塩 ……3重量部 メチオニン ……3重量部 2,4−ジクロロフエノキシ酢酸ナトリウム塩
……0.005重量部 水 ……残部 を混合して液剤を得る。
[Table] Formulation example 1 Wettable powder 3-hydroxy-5-methylisoxazole calcium salt ...10 parts by weight Methionine ...20 parts by weight 2,4-dichlorophenoxyacetic acid sodium salt
...0.02 parts by weight polyvinyl alcohol ...1 parts by weight Sodium dodecylbenzenesulfonate
...3 parts by weight of clay ...The remainder is mixed and ground to obtain a wettable powder. Formulation Example 2 Liquid 3-hydroxy-5-methylisoxazole potassium salt...3 parts by weight Methionine...3 parts by weight 2,4-dichlorophenoxyacetic acid sodium salt
...0.005 parts by weight of water ...Mix the remainder to obtain a liquid agent.

Claims (1)

【特許請求の範囲】[Claims] 1 3−ヒドロキシ−5メチルイソキサゾールま
たはその塩と、メチオニンおよび/またはアブシ
ジン酸と、2,4−ジクロロフエノキシ酢酸また
はその塩、エステルもしくは酸アミドとを有効成
分とするイネの登熟促進剤。
1 Ripening of rice containing 3-hydroxy-5methylisoxazole or its salt, methionine and/or abscisic acid, and 2,4-dichlorophenoxyacetic acid or its salt, ester or acid amide as active ingredients Accelerator.
JP56184809A 1981-11-18 1981-11-18 Rice grain filling promotor Granted JPS5885805A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP56184809A JPS5885805A (en) 1981-11-18 1981-11-18 Rice grain filling promotor
KR8205190A KR880001580B1 (en) 1981-11-18 1982-11-17 Promoting composition for filling of rice grain

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56184809A JPS5885805A (en) 1981-11-18 1981-11-18 Rice grain filling promotor

Publications (2)

Publication Number Publication Date
JPS5885805A JPS5885805A (en) 1983-05-23
JPH0142241B2 true JPH0142241B2 (en) 1989-09-11

Family

ID=16159664

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56184809A Granted JPS5885805A (en) 1981-11-18 1981-11-18 Rice grain filling promotor

Country Status (2)

Country Link
JP (1) JPS5885805A (en)
KR (1) KR880001580B1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1101132C (en) * 1999-09-14 2003-02-12 贵州大学 Production method of hymexazol powder
US8232230B2 (en) 2000-12-01 2012-07-31 Helena Holding Company Manufacture and use of a herbicide formulation
WO2003103396A1 (en) * 2002-06-11 2003-12-18 Helena Chemical Company Research Extension And Service Center Manufacture and use of a herbicide formulation
US8426341B2 (en) 2005-05-27 2013-04-23 Helena Holding Company Herbicide formulation

Also Published As

Publication number Publication date
KR840002203A (en) 1984-06-25
JPS5885805A (en) 1983-05-23
KR880001580B1 (en) 1988-08-24

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