JPH0146485B2 - - Google Patents

Info

Publication number
JPH0146485B2
JPH0146485B2 JP58225217A JP22521783A JPH0146485B2 JP H0146485 B2 JPH0146485 B2 JP H0146485B2 JP 58225217 A JP58225217 A JP 58225217A JP 22521783 A JP22521783 A JP 22521783A JP H0146485 B2 JPH0146485 B2 JP H0146485B2
Authority
JP
Japan
Prior art keywords
bentonite
cmc
pack
cosmetic
etherification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP58225217A
Other languages
Japanese (ja)
Other versions
JPS60115507A (en
Inventor
Takashi Umeno
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunstar Inc
Original Assignee
Sunstar Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunstar Inc filed Critical Sunstar Inc
Priority to JP22521783A priority Critical patent/JPS60115507A/en
Publication of JPS60115507A publication Critical patent/JPS60115507A/en
Publication of JPH0146485B2 publication Critical patent/JPH0146485B2/ja
Granted legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212Face masks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/965Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5424Polymers characterized by specific structures/properties characterized by the charge anionic

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は、皮膚の手入れに用いる化粧用パツク
剤に関し、さらに詳しくは、いわゆる泥状の化粧
用パツク剤に関する。 従来より、皮膚中の角質に水分を与え、また皮
表の汚れを取除く化粧料として、パツク剤が使用
されており、これらは、形状面から、泥状パツ
ク、クリーム状パツク、およびピールオフタイプ
パツクに大別されている。 このうち、泥状パツクに要求される特性として
は、安全性の高いこと、使用時適度な粘度であつ
て塗布しやすいこと、皮膚に適度な緊張感を与え
ること、適度に短時間で乾燥すること、洗い流し
が容易なこと、使用後しつとりとした快い感触が
持続することなど、が挙げられる。これらの特性
を達成するため、ベントナイトを主成分とし、乾
燥速度を速くするためにエチルアルコールを配合
し、ベントナイトによる独特の色の悪さをカバー
するために酸化チタン等を配合した泥状パツクが
提案されている。 しかしながら、これら従来の泥状パツクタイプ
の化粧用パツク剤は、保存期間中に粘度の上昇、
離水等を生じ、商品価値が著しく損なわれること
がしばしばであつた。 本発明者は、前記欠点のない、泥状タイプの化
粧用パツク剤を得るべく鋭意研究を行なつた結
果、特定エーテル化度のカルボキシメチルセルロ
ースナトリウム(以下、Na―CMCという)を配
合することにより良好な化粧用パツク剤が得られ
ることを見出し本発明を完成するに至つた。 すなわち、本発明は、ベントナイト、酸化チタ
ン、エチルアルコールおよびエーテル化度0.55〜
0.75以下のNa―CMCを配合したことを特徴とす
る化粧用パツク剤を提供するものである。 本発明によれば、ベントナイト、酸化チタン、
エチルアルコールを主成分とする泥状パツクに安
定化剤として該特定エーテル化度のNa―CMCを
配合したことにより、保存期間中における粘度の
上昇、離水等の欠点のない優れた化粧用パツク剤
を得ることができる。 本発明の化粧用パツクに配合されるNa―CMC
のエーテル化度は0.75以下、好ましくは0.55〜
0.75である。Na―CMCのエーテル化度が化粧用
パツク剤の性状に与える影響は、無機粉体を分散
させた歯磨等の他の組成物の場合とは、明らかに
異なつており、エーテル化度が0.75を超えると、
放置によりゲル化を生じ、ペーストの外観が悪化
する。つぎに、Na―CMCのエーテル化度が、泥
状パツクの性状に与える影響を第表に示す。こ
こで、泥状パツクの処方は、下記に従がい、常法
にて製造した。 成 分 配合量(重量%) ベントナイト 10.0 酸化チタン 3.5 精製水 67.5 D―パンテノール 0.1 クエン酸 0.15 ピロリドンカルボン酸ナトリウム
0.50 エチルアルコール 10.0 プロピレングリコール 8.0 メチルパラベン 0.05 Na―CMC 0.2 また、評価の基準は、つぎのとおりである。 〇:均一で滑らかな表面。 △:部分的に表面が滑らかでない。 ×:表面が凹凸になつて商品価値がない。 稠度:レオメーターNRM―20002J(フード工
業(株)製)、エレベーター上昇速度2cm/
min、アダプター直径10mm円盤
The present invention relates to a cosmetic pack for use in skin care, and more particularly to a so-called mud-like cosmetic pack. Traditionally, face packs have been used as cosmetics to moisturize the dead skin cells in the skin and remove dirt from the skin's surface.These have been divided into mud packs, cream packs, and peel-off types in terms of shape. It is broadly divided into patsuku. Among these, the characteristics required for a muddy pack are: high safety, appropriate viscosity during use and ease of application, giving an appropriate feeling of tension to the skin, and drying in an appropriate amount of time. These include being easy to wash off, and having a moist and pleasant feel that lasts after use. In order to achieve these properties, we proposed a muddy pack containing bentonite as the main ingredient, ethyl alcohol added to speed up the drying speed, and titanium oxide added to cover up the unique bad color caused by bentonite. has been done. However, these conventional mud-type cosmetic packs tend to increase in viscosity during storage.
Frequently, syneresis occurred, resulting in a significant loss of commercial value. The present inventor conducted extensive research to obtain a mud-type cosmetic pack that does not have the above-mentioned drawbacks, and found that by incorporating sodium carboxymethylcellulose (hereinafter referred to as Na-CMC) with a specific degree of etherification, The inventors discovered that a good cosmetic pack could be obtained and completed the present invention. That is, the present invention uses bentonite, titanium oxide, ethyl alcohol, and a degree of etherification of 0.55 to 0.55.
The present invention provides a cosmetic pack agent characterized by containing Na-CMC of 0.75 or less. According to the present invention, bentonite, titanium oxide,
By blending Na-CMC with the specified degree of etherification as a stabilizer into a muddy pack whose main component is ethyl alcohol, it is an excellent cosmetic pack that does not have drawbacks such as increased viscosity or syneresis during storage. can be obtained. Na-CMC blended into the cosmetic pack of the present invention
The degree of etherification is 0.75 or less, preferably 0.55~
It is 0.75. The influence of the degree of etherification of Na-CMC on the properties of cosmetic packs is clearly different from that of other compositions such as toothpaste in which inorganic powders are dispersed. If you exceed
If left as it is, gelation will occur and the appearance of the paste will deteriorate. Next, Table 1 shows the influence of the degree of etherification of Na-CMC on the properties of the mud pack. Here, the formulation of the slurry pack was as follows, and it was manufactured by a conventional method. Ingredients Amount (wt%) Bentonite 10.0 Titanium oxide 3.5 Purified water 67.5 D-Panthenol 0.1 Citric acid 0.15 Sodium pyrrolidone carboxylate
0.50 Ethyl alcohol 10.0 Propylene glycol 8.0 Methylparaben 0.05 Na-CMC 0.2 The evaluation criteria are as follows. ○: Uniform and smooth surface. △: The surface is partially not smooth. ×: The surface is uneven and has no commercial value. Consistency: Rheometer NRM-20002J (manufactured by Food Kogyo Co., Ltd.), elevator rising speed 2cm/
min, adapter diameter 10mm disk

【表】 第1表より明らかなごとく、エーテル化度の高
いNa―CMCを用いた場合ほど、放置下で、ゲル
化を生じ、ペーストの外観も極めて悪くなる。 また、化粧用パツク剤全重量に対するベントナ
イトの配合量は、8〜10%、好ましくは、9〜10
%であり、Na―CMCの配合量は、0.05〜0.3%、
好ましくは0.1〜0.2%である。つぎに、ベントナ
イトおよびNa―CMCの配合量と、化粧用パツク
剤の性能、安全性、安定性との関係を第2表に示
す。ここで、泥状パツクの処方は、下記に従が
い、常法にて製造した。 成 分 配合量(重量%) ベントナイト 5 〜15 Na―CMC 0.1〜0.3 酸化チタン 3.5 D―パンテノール 0.1 クエン酸 0.15 ピロリドンカルボン酸ナトリウム
0.50 エチルアルコール 10.0 プロピレングリコール 8.0 メチルパラベン 0.05精製水 残量 合 計 100.0 また、性状についての評価の基準〇,△,×は
前記と同様であり、使用感については、10人中標
記の結果を表明した人の割合で示した。使用時に
痛みを訴えた人に関しては、使用を中止したの
で、ベントナイトを12%および15%配合した場合
は、使用後の肌の感触についてのデータは得られ
なかつた。
[Table] As is clear from Table 1, when Na-CMC with a higher degree of etherification is used, gelation occurs when left to stand, and the appearance of the paste becomes extremely poor. In addition, the amount of bentonite blended in the total weight of the cosmetic pack is 8 to 10%, preferably 9 to 10%.
%, and the content of Na-CMC is 0.05-0.3%,
Preferably it is 0.1-0.2%. Next, Table 2 shows the relationship between the blending amounts of bentonite and Na-CMC and the performance, safety, and stability of cosmetic packs. Here, the formulation of the slurry pack was as follows, and it was manufactured by a conventional method. Component Amount (wt%) Bentonite 5 ~ 15 Na-CMC 0.1 ~ 0.3 Titanium oxide 3.5 D-Panthenol 0.1 Citric acid 0.15 Sodium pyrrolidone carboxylate
0.50 Ethyl alcohol 10.0 Propylene glycol 8.0 Methyl paraben 0.05 Total remaining amount of purified water 100.0 In addition, the criteria for evaluating properties 〇, △, × are the same as above, and for the feeling of use, the results listed below out of 10 were expressed. Expressed as a percentage of people. For those who complained of pain during use, use was discontinued, so we were unable to obtain data on how the skin felt after use for the 12% and 15% bentonite formulations.

【表】 第2表より、ベントナイト、Na―CMCの配合
量は、前記の範囲が好ましいことがわかる。 本発明の化粧用パツク剤は、常法により製造す
ることができる。製造にあたつては、ピロリドン
カルボン酸ナトリウム、プロピレングリコール、
グリセリン等の保湿剤、その他皮膚に有効なパン
テノール等の薬効剤を配合してもよい。 つぎに、本発明を実施例にもとづき、さらに詳
しく説明する。なお、実施例中、%は全て重量%
である。 実施例 1〜3 つぎの第2表に示す処方により、常法にて泥状
パツク化粧料を製造した。
[Table] From Table 2, it can be seen that the blending amounts of bentonite and Na-CMC are preferably within the above range. The cosmetic pack of the present invention can be manufactured by conventional methods. During manufacturing, sodium pyrrolidone carboxylate, propylene glycol,
Moisturizing agents such as glycerin and other medicinal agents effective for the skin such as panthenol may also be blended. Next, the present invention will be explained in more detail based on examples. In addition, in the examples, all percentages are by weight.
It is. Examples 1 to 3 Cosmetic mud packs were produced in a conventional manner according to the formulations shown in Table 2 below.

【表】【table】

【表】 得られた泥状の化粧料パツク剤は、いずれも製
造直後、および40℃1ケ月後においてゲル化を生
じることなく好ましい性状を保持し、使用感覚お
よび使用後の肌の感触も良くなつた。
[Table] All of the obtained mud-like cosmetic packs maintained favorable properties without gelation immediately after production and after one month at 40°C, and had a good feeling in use and on the skin after use. Summer.

Claims (1)

【特許請求の範囲】 1 ベントナイト、酸化チタン、エチルアルコー
ルおよびエーテル化度0.55〜0.75のカルボキシメ
チルセルロースナトリウムを配合したことを特徴
とする化粧用パツク剤。 2 ベントナイトの配合量が、組成物全体に対し
て8〜10重量%である前記第1項の化粧用パツク
剤。 3 カルボキシメチルセルロースナトリウムの配
合量が、組成物全体に対して0.05〜0.3重量%で
ある前記第1項または第2項の化粧用パツク剤。
[Scope of Claims] 1. A cosmetic pack comprising bentonite, titanium oxide, ethyl alcohol, and sodium carboxymethylcellulose with a degree of etherification of 0.55 to 0.75. 2. The cosmetic pack according to item 1 above, wherein the amount of bentonite is 8 to 10% by weight based on the total composition. 3. The cosmetic pack according to item 1 or 2 above, wherein the amount of sodium carboxymethylcellulose is 0.05 to 0.3% by weight based on the entire composition.
JP22521783A 1983-11-28 1983-11-28 Cosmetic pack Granted JPS60115507A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22521783A JPS60115507A (en) 1983-11-28 1983-11-28 Cosmetic pack

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22521783A JPS60115507A (en) 1983-11-28 1983-11-28 Cosmetic pack

Publications (2)

Publication Number Publication Date
JPS60115507A JPS60115507A (en) 1985-06-22
JPH0146485B2 true JPH0146485B2 (en) 1989-10-09

Family

ID=16825818

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22521783A Granted JPS60115507A (en) 1983-11-28 1983-11-28 Cosmetic pack

Country Status (1)

Country Link
JP (1) JPS60115507A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000048580A1 (en) 1999-02-19 2000-08-24 Hisamitsu Pharmaceutical Co., Inc. Sheet-form adhesive preparation
US7169402B2 (en) 2000-04-05 2007-01-30 The Cupron Corporation Antimicrobial and antiviral polymeric materials

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY128817A (en) 1999-01-28 2007-02-28 Hisamitsu Pharmaceutical Co Sheet-shaped pack agent
KR20010089937A (en) * 2000-03-14 2001-10-17 최용실 Mineral mud
WO2016101253A1 (en) * 2014-12-26 2016-06-30 L'oreal Aqueous composition for exfoliating the skin

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS609691B2 (en) * 1976-09-07 1985-03-12 サンスタ−株式会社 Pack composition with striped tubes
JPS57112314A (en) * 1980-12-29 1982-07-13 Nonogawa Shoji:Kk Pack

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000048580A1 (en) 1999-02-19 2000-08-24 Hisamitsu Pharmaceutical Co., Inc. Sheet-form adhesive preparation
US6936268B1 (en) 1999-02-19 2005-08-30 Hisamitsu Pharmaceutical Co., Inc. Sheet-form adhesive preparation
US7169402B2 (en) 2000-04-05 2007-01-30 The Cupron Corporation Antimicrobial and antiviral polymeric materials

Also Published As

Publication number Publication date
JPS60115507A (en) 1985-06-22

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