JPH0157685B2 - - Google Patents
Info
- Publication number
- JPH0157685B2 JPH0157685B2 JP56077880A JP7788081A JPH0157685B2 JP H0157685 B2 JPH0157685 B2 JP H0157685B2 JP 56077880 A JP56077880 A JP 56077880A JP 7788081 A JP7788081 A JP 7788081A JP H0157685 B2 JPH0157685 B2 JP H0157685B2
- Authority
- JP
- Japan
- Prior art keywords
- vanadium
- bis
- chlorinated
- alkyl
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 49
- -1 ethanediyl Chemical group 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 32
- 239000012190 activator Substances 0.000 claims description 25
- 125000004432 carbon atom Chemical group C* 0.000 claims description 23
- 238000006116 polymerization reaction Methods 0.000 claims description 23
- 125000002947 alkylene group Chemical group 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 21
- 229910052720 vanadium Inorganic materials 0.000 claims description 15
- 150000003682 vanadium compounds Chemical class 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- CUJPFPXNDSIBPG-UHFFFAOYSA-N 1,3-propanediyl Chemical group [CH2]C[CH2] CUJPFPXNDSIBPG-UHFFFAOYSA-N 0.000 claims description 11
- YBNLWIZAWPBUKQ-UHFFFAOYSA-N trichloro(trichloromethylsulfonyl)methane Chemical compound ClC(Cl)(Cl)S(=O)(=O)C(Cl)(Cl)Cl YBNLWIZAWPBUKQ-UHFFFAOYSA-N 0.000 claims description 9
- SMNDYUVBFMFKNZ-UHFFFAOYSA-M 2-furoate Chemical compound [O-]C(=O)C1=CC=CO1 SMNDYUVBFMFKNZ-UHFFFAOYSA-M 0.000 claims description 8
- 150000004645 aluminates Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 125000005907 alkyl ester group Chemical group 0.000 claims description 7
- 150000002902 organometallic compounds Chemical class 0.000 claims description 7
- 239000004711 α-olefin Substances 0.000 claims description 7
- SPFDFLODYWCNLS-UHFFFAOYSA-N 2,3,3,4-tetrachlorooxolane-2-carboxylic acid Chemical compound OC(=O)C1(Cl)OCC(Cl)C1(Cl)Cl SPFDFLODYWCNLS-UHFFFAOYSA-N 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- LGWFUHPGJWCWHX-UHFFFAOYSA-N oxolan-2-ylmethyl oxolane-2-carboxylate Chemical group C1CCOC1C(=O)OCC1CCCO1 LGWFUHPGJWCWHX-UHFFFAOYSA-N 0.000 claims description 5
- ZIFOIIHJRNANEP-UHFFFAOYSA-N ClC1(Cl)C(C(=O)O)(Cl)OCC1(Cl)C(Cl)(Cl)C1(Cl)C(Cl)CCO1 Chemical group ClC1(Cl)C(C(=O)O)(Cl)OCC1(Cl)C(Cl)(Cl)C1(Cl)C(Cl)CCO1 ZIFOIIHJRNANEP-UHFFFAOYSA-N 0.000 claims description 4
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- UJJLJRQIPMGXEZ-UHFFFAOYSA-N tetrahydro-2-furoic acid Chemical class OC(=O)C1CCCO1 UJJLJRQIPMGXEZ-UHFFFAOYSA-N 0.000 claims description 4
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 230000003993 interaction Effects 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- FSJSYDFBTIVUFD-SUKNRPLKSA-N (z)-4-hydroxypent-3-en-2-one;oxovanadium Chemical compound [V]=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FSJSYDFBTIVUFD-SUKNRPLKSA-N 0.000 claims description 2
- MFWFDRBPQDXFRC-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;vanadium Chemical compound [V].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MFWFDRBPQDXFRC-LNTINUHCSA-N 0.000 claims description 2
- UBGJVKACXRMKQX-UHFFFAOYSA-N 3-[1-[2-(2-carboxyfuran-3-yl)propoxy]propan-2-yl]furan-2-carboxylic acid Chemical class C1=COC(C(O)=O)=C1C(C)COCC(C)C=1C=COC=1C(O)=O UBGJVKACXRMKQX-UHFFFAOYSA-N 0.000 claims description 2
- FBPTUMLMBBIEQD-UHFFFAOYSA-N 3-[2-(2-carboxyfuran-3-yl)ethyl]furan-2-carboxylic acid Chemical group O1C=CC(CCC2=C(OC=C2)C(O)=O)=C1C(=O)O FBPTUMLMBBIEQD-UHFFFAOYSA-N 0.000 claims description 2
- SPJKMWWLCMXROL-UHFFFAOYSA-N 3-[2-(2-carboxyfuran-3-yl)propyl]furan-2-carboxylic acid Chemical class C1=COC(C(O)=O)=C1C(C)CC=1C=COC=1C(O)=O SPJKMWWLCMXROL-UHFFFAOYSA-N 0.000 claims description 2
- HJQITCCAVHKRKU-UHFFFAOYSA-N 3-[2-[2-(2-carboxyfuran-3-yl)ethoxy]ethyl]furan-2-carboxylic acid Chemical class O1C=CC(CCOCCC2=C(OC=C2)C(O)=O)=C1C(=O)O HJQITCCAVHKRKU-UHFFFAOYSA-N 0.000 claims description 2
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 claims description 2
- CKCYDFVZAPRMBQ-UHFFFAOYSA-M [Cl-].CCCCCCCCCC[Mg+] Chemical compound [Cl-].CCCCCCCCCC[Mg+] CKCYDFVZAPRMBQ-UHFFFAOYSA-M 0.000 claims description 2
- CLGLRNZWNSOYFG-UHFFFAOYSA-M [I-].C(CCCCCCCCC)[Mg+] Chemical group [I-].C(CCCCCCCCC)[Mg+] CLGLRNZWNSOYFG-UHFFFAOYSA-M 0.000 claims description 2
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- ZHXZNKNQUHUIGN-UHFFFAOYSA-N chloro hypochlorite;vanadium Chemical compound [V].ClOCl ZHXZNKNQUHUIGN-UHFFFAOYSA-N 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- LZFCBBSYZJPPIV-UHFFFAOYSA-M magnesium;hexane;bromide Chemical compound [Mg+2].[Br-].CCCCC[CH2-] LZFCBBSYZJPPIV-UHFFFAOYSA-M 0.000 claims description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- BIEFSHWAGDHEIT-UHFFFAOYSA-J tetrabromovanadium Chemical compound [V+4].[Br-].[Br-].[Br-].[Br-] BIEFSHWAGDHEIT-UHFFFAOYSA-J 0.000 claims description 2
- JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 claims description 2
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 5
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000000460 chlorine Substances 0.000 description 33
- 238000000034 method Methods 0.000 description 17
- 230000004913 activation Effects 0.000 description 15
- 238000000921 elemental analysis Methods 0.000 description 11
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 10
- 229910052801 chlorine Inorganic materials 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000005660 chlorination reaction Methods 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 239000012299 nitrogen atmosphere Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- SMNDYUVBFMFKNZ-UHFFFAOYSA-N 2-furoic acid Chemical compound OC(=O)C1=CC=CO1 SMNDYUVBFMFKNZ-UHFFFAOYSA-N 0.000 description 4
- 125000001309 chloro group Chemical group Cl* 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 3
- PAMQYEWNNPDBLM-UHFFFAOYSA-N butyl furan-2-carboxylate Chemical compound CCCCOC(=O)C1=CC=CO1 PAMQYEWNNPDBLM-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 3
- 150000004291 polyenes Chemical class 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 2
- JAZVLZAPAXXFSI-UHFFFAOYSA-N 2-(furan-2-carbonyloxy)ethyl furan-2-carboxylate Chemical compound C=1C=COC=1C(=O)OCCOC(=O)C1=CC=CO1 JAZVLZAPAXXFSI-UHFFFAOYSA-N 0.000 description 2
- PNVQFOXOMZGQGX-UHFFFAOYSA-N 2-(furan-2-carbonyloxy)propyl furan-2-carboxylate Chemical compound C=1C=COC=1C(=O)OC(C)COC(=O)C1=CC=CO1 PNVQFOXOMZGQGX-UHFFFAOYSA-N 0.000 description 2
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 description 2
- 238000010953 Ames test Methods 0.000 description 2
- 231100000039 Ames test Toxicity 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- KMLFVAGUWNPADU-UHFFFAOYSA-N Hexyl 2-furoate Chemical compound CCCCCCOC(=O)C1=CC=CO1 KMLFVAGUWNPADU-UHFFFAOYSA-N 0.000 description 2
- BZSWRPWKYCIVFA-UHFFFAOYSA-N [dichloro-(2,3-dichlorooxolan-2-yl)methyl] 2,3,3,4-tetrachlorooxolane-2-carboxylate Chemical compound ClC1CCOC1(Cl)C(Cl)(Cl)OC(=O)C1(Cl)C(Cl)(Cl)C(Cl)CO1 BZSWRPWKYCIVFA-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical class CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- KMDZFXFLPOTNHQ-UHFFFAOYSA-N 11-ethyltrideca-1,11-diene Chemical compound CCC(=CC)CCCCCCCCC=C KMDZFXFLPOTNHQ-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- NHXSTXWKZVAVOQ-UHFFFAOYSA-N Ethyl furoate Chemical compound CCOC(=O)C1=CC=CO1 NHXSTXWKZVAVOQ-UHFFFAOYSA-N 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- HDJLSECJEQSPKW-UHFFFAOYSA-N Methyl 2-Furancarboxylate Chemical compound COC(=O)C1=CC=CO1 HDJLSECJEQSPKW-UHFFFAOYSA-N 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 241000364021 Tulsa Species 0.000 description 1
- CRVDCQGYSPZSJG-UHFFFAOYSA-M [Cl-].CCCCCCCCCCCC[Mg+] Chemical compound [Cl-].CCCCCCCCCCCC[Mg+] CRVDCQGYSPZSJG-UHFFFAOYSA-M 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- AGKHJVLQDSGARV-UHFFFAOYSA-N butan-2-yl furan-2-carboxylate Chemical compound CCC(C)OC(=O)C1=CC=CO1 AGKHJVLQDSGARV-UHFFFAOYSA-N 0.000 description 1
- PSNVMRJKNZNDGZ-UHFFFAOYSA-N butyl 2,3,3,4-tetrachlorooxolane-2-carboxylate Chemical compound CCCCOC(=O)C1(Cl)OCC(Cl)C1(Cl)Cl PSNVMRJKNZNDGZ-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012718 coordination polymerization Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- JFICPAADTOQAMU-UHFFFAOYSA-L ethylaluminum(2+);dibromide Chemical compound CC[Al](Br)Br JFICPAADTOQAMU-UHFFFAOYSA-L 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- IWCVDCOJSPWGRW-UHFFFAOYSA-M magnesium;benzene;chloride Chemical compound [Mg+2].[Cl-].C1=CC=[C-]C=C1 IWCVDCOJSPWGRW-UHFFFAOYSA-M 0.000 description 1
- MBHQEXPGNCWWBP-UHFFFAOYSA-M magnesium;dodecane;bromide Chemical compound [Mg+2].[Br-].CCCCCCCCCCC[CH2-] MBHQEXPGNCWWBP-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 229940082615 organic nitrates used in cardiac disease Drugs 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- YGRHYJIWZFEDBT-UHFFFAOYSA-N tridecylaluminum Chemical compound CCCCCCCCCCCCC[Al] YGRHYJIWZFEDBT-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯æ°èŠãªè§Šåªçµæç©åã³ãããã®æ¹è¯ã
ãã觊åªã䜿çšããαâãªã¬ãã€ã³ã®éåæ¹æ³ã«
é¢ããã (1)å çŽ ã®åšæåŸè¡šç¬¬âæåã¯ç¬¬âæé
å±ã®ååç©ãš(2)ååšæåŸè¡šç¬¬âæéå±ã®ææ©
éå±ååç©ãšã®çžäºäœçšçæç©ã§ããã€ãªã³é äœ
éå觊åªã¯åšç¥ã§ããããã®ãããªè§Šåªã«ã¯å€ã
ã®å Žå觊åªæŽ»æ§ïŒåäœæéåœãã®ãé·ç§»éå±åå
ç©ã®ééã«å¯Ÿããéåäœã®ééïŒãäœããéåé
床ã觊åªãæ¯èŒçé«æ¿åºŠã§äœ¿çšããªããšæãŸãã
ãªãã»ã©é ããªãããããŠå¯æº¶æ§è§Šåªã䜿çšãã
ãšããã®æŽ»æ§ããã°ãã°éåäžã«æ¥éã«äœäžãã
ãšããæ¬ ç¹ãããã æ¬çºæã¯ãããžãŠã ååç©ãšææ©éå±ååç©ãš
ã«åºã¥ã觊åªïŒä»¥äžã«ãããŠã¯äžæ¬¡è§Šåªç³»ãšã称
ããïŒã¯ãã®æŽ»æ§ãäžå±€å¹æçã«ããåã³ïŒåã¯
ãã®æŽ»æ§ãé·æéã«ããã€ãŠç¶æããåã³ïŒåã¯
ãã®è§Šåªã«æŽ»æ§å€ãæ·»å ãããŠãããšãããã®è§Š
åªãæ²»æ§ã倱ãªãå§ããŠããåæ²»æ§åããããšã
ã§ãããšããé©ãã¹ãçºèŠã«åºã¥ããããå Žå
ã¯ã掻æ§å€ã®æ·»å ã¯ååéã調ç¯ããäœçšãå¥ã
ãã觊åªæŽ»æ§å€ã¯æ¶èãã觊åªãšåå¿ããç©è³ªå
ã¯ååç©ã®ããšã§ããã®ãããªæ¶è觊åªãæå³ã
ãååŠåå¿ãä¿é²ãç¶ããããšãã§ããç¶æ ã«ã
ã©ããåæ§ã®è§Šåªãšãããã®æŽ»æ§å€ãšã®åŸæ¥ã®çµ
ã¿åããã¯æ¬¡ã®ç¹èš±æ现æžã«èšèŒãããŠãããã
ãªãã¡ãã¢ã¡ãªã«åœç¹èš±ç¬¬3377325å·æ现æžã¯ç¡«
é»ã«ãã掻æ§åãçšããã«ããåœç¹èš±ç¬¬833651å·
æ现æžã¯äžå¡©åãªã³ãšïŒâããããããã³ã«ãã
掻æ§åãçšããã¢ã«ã«ãªåœç¹èš±ç¬¬3441546å·æ现
æžã¯ææ©ãããååç©ã«ãã掻æ§åãçšããã¢ã¡
ãªã«åœç¹èš±ç¬¬3444149å·æ现æžã¯ããããœååç©
åã¯ããã³ã«ãã掻æ§åãçšããã¢ã¡ãªã«åœç¹èš±
第3462399å·æ现æžã¯ææ©ãã€ãã¬ãŒããææ©ã
ã€ãã©ã€ããã¢ãŸãã·ååç©ãç¹æ®ãªææ©éå±å
åç©åã¯ã¢ã«ãã«ãžã¹ã«ããã«ãã掻æ§åã«é¢
ãããããŠã¢ã¡ãªã«åœç¹èš±ç¬¬3507843å·æ现æžã¯
äžå¡©åãªã³ã«ãã掻æ§åãçšããŠããã æ¬çºæã®è§Šåªçµæç©ã¯ãäžæ¬¡è§Šåªç³»ããããžãŠ
ã ååç©åã³åŒRMgXãLiAlR4åã¯RAAl2XBïŒåŒ
äžãã¯ïŒã12åã®ççŽ ååãæããçåæ°ŽçŽ
åºã奜ãŸããã¯ïŒã12åã®ççŽ ååãæããã¢ã«
ãã«åºã§ãããã¯ããã²ã³ååã§ãããã¯ïŒ
ãïŒã®æ°ã§ããããããŠïŒ¢ã¯ïŒãïŒã®æ°ã§ããã
ãã ãããšïŒ¢ã®åã¯ïŒã§ããïŒã®ææ©éå±åå
ç©ïŒãã ãããããžãŠã ååç©ããåã¯ææ©éå±
ååç©ã®ããããã«çµåããŠããåºã®å°ãªããšã
ïŒåã¯ããã²ã³ååïŒäŸãã°ãããçŽ ãå¡©çŽ ãè
çŽ åã³ãšãŠçŽ ïŒã§ããïŒããæãããããŠæŽ»æ§å€
ãå¡©çŽ åããã©ããããã«ããªã«ããã©ãããã
ããšãŒãã奜ãŸããã¯ããã©ã¯ããããã©ããã
ãã«ããªã«ããã©ã¯ããããã©ããããããšãŒ
ããå¡©çŽ åããã©ãããããé žã奜ãŸããã¯ãã
ã©ã¯ããããã©ãããããé žã®ã¢ã«ãã«ãšã¹ãã«
ïŒãã ããã¢ã«ãã«åºã¯ïŒãïŒåã奜ãŸããã¯ïŒ
ãïŒåã®ççŽ ååãæããïŒãå¡©çŽ åã¢ã«ãã¬ã³
ãã¹âããã©ããããããšãŒãïŒãã ããã¢ã«ã
ã¬ã³åºã¯ïŒååã¯ïŒåã®ççŽ ååãæããïŒãå¡©
çŽ åãªãã·âãã¹ãã¢ã«ãã¬ã³ïŒïŒâãããšãŒ
ãïŒãïŒãã ããã¢ã«ãã¬ã³åºã¯ãšã¿ã³ãžã€ã«ã
ïŒïŒïŒâãããã³ãžã€ã«ãã¢ã«ãã«çœ®æãšã¿ã³ãž
ã€ã«ãã¢ã«ãã«çœ®æïŒïŒïŒâãããã³ãžã€ã«âã
ã ãããšã¿ã³ãžã€ã«åã¯ïŒïŒïŒâãããã³ãžã€ã«
äžã®ã¢ã«ãã«åºã¯ïŒãïŒåã奜ãŸããã¯ïŒãïŒå
ã®ççŽ ååãæããâã§ããïŒãåã¯ãã¹ïŒããª
ã¯ããã¡ãã«ïŒã¹ã«ãã³ã§ãããäžæ¬¡è§Šåªç³»ãšæŽ»
æ§å€ãšã®çµã¿åãããæãã æ¬çºæã¯ãŸããå¡©çŽ åããã©ããããã«ããªã«
ããã©ããããããšãŒãã奜ãŸããã¯ããã©ã¯ã
ãããã©ããããã«ããªã«ããã©ã¯ããããã©ã
ãããããšãŒããå¡©çŽ åããã©ãããããé žã奜
ãŸããã¯ããã©ã¯ããããã©ãããããé žã®ã¢ã«
ãã«ãšã¹ãã«ïŒãã ããã¢ã«ãã«åºã¯ïŒãïŒåã
奜ãŸããã¯ïŒãïŒåã®ççŽ ååãæããïŒãå¡©çŽ
åã¢ã«ãã¬ã³ãã¹âããã©ããããããšãŒãïŒã
ã ããã¢ã«ãã¬ã³åºã¯ïŒååã¯ïŒåã®ççŽ ååã
æããïŒãå¡©çŽ åãªãã·âãã¹ãã¢ã«ãã¬ã³ïŒïŒ
âãããšãŒãïŒãïŒãã ããã¢ã«ãã¬ã³åºã¯ãšã¿ã³
ãžã€ã«ãïŒïŒïŒâãããã³ãžã€ã«ãã¢ã«ãã«çœ®æ
ãšã¿ã³ãžã€ã«ãã¢ã«ãã«çœ®æïŒïŒïŒâãããã³ãž
ã€ã«âãã ãããšã¿ã³ãžã€ã«åã¯ïŒïŒïŒâããã
ã³ãžã€ã«äžã®ã¢ã«ãã«åºã¯ïŒãïŒåã奜ãŸããã¯
ïŒãïŒåã®ççŽ ååãæããâã§ããïŒãåã¯ã
ã¹ïŒããªã¯ããã¡ãã«ïŒã¹ã«ãã³ããããžãŠã å
åç©ãšåŒRMgXãLiAlR4åã¯RAAl2XBïŒåŒäžã
ããåã³ïŒ¢ã¯åèšå®çŸ©ã®éãã§ããïŒãšã®
åå¿çæç©ãšåéäœåã¯åéäœé¡ã®ååšäžã§åå¿
ãããããšããæã觊åªã®è£œé æ¹æ³ãå å«ããã æ¬çºæã¯ãŸãæ¬çºæã®è§Šåªã䜿çšããαâãªã¬
ãã€ã³ã®éåæ¹æ³åã³ãã®éåæ¹æ³ã«ãã€ãŠè£œé
ãããéåäœã«é¢ãããéåãããαâãªã¬ãã€
ã³ååã¯å šãŠåãã§ãã€ãŠããããããããã¯ç°
ãªã€ãŠããŠããããäŸãã°ããšãã¬ã³ã®éåã¯ã
ãªãšãã¬ã³ãäžãããŸããšãã¬ã³ãšãããã¬ã³ãš
ã®æ··åç©ã®éåã¯å ±éåäœãçæãããã奜ãŸã
ãéåæ¹æ³ã¯ãšãã¬ã³ããããã¬ã³åã³ããªãšã³
ã䜿çšããŠç¡«é»å ç¡«äœã®äžå å ±éåäœã補é ãã
å Žåã§ããã åèšäžæ¬¡è§Šåªç³»ã¯å¥åã«èª¿è£œãã次ãã§éåç³»
ã«å ããããšãã§ãããããããã¯éåã®å Žã§èª¿
補ããããšãã§ãããæ¬çºæã®æŽ»æ§å€ã¯äžæ¬¡è§Šåª
ç³»ã®å°å ¥åãå°å ¥äžãããã¯å°å ¥åŸã«éåç³»ã«å
ããããšãã§ããã掻æ§å€ã¯ãŸãäžæ¬¡è§Šåªç³»ã®ïŒ
æåã«ããã®ç¬¬äºæåã®æ·»å åã«å ããŠãããã
äžæ¬¡è§Šåªç³»ã®èª¿æŽå·¥çšã瀺ããããŒãã€ãŒãã®äž
äŸã第ïŒå³ã«ç€ºãã第ïŒå³ã¯äžæ æ§ã§ãã€ãŠæ¬çº
æã®äžæ¬¡è§Šåªç³»ã®èª¿æŽå·¥çšã¯ããã«éå®ãããã
ã®ã§ã¯ãªãã æ¬çºæã®è§Šåªçµæç©ã«çšããããšãã§ãããã
ãžãŠã ååç©ã®ééå®äŸã¯ãããžãŠã ãã©ã€ãã
ãªãã·ãã©ã€ããã¢ã«ã³ãã·ãã奜ãŸããã¯ïŒå
åã¯ïŒåã®ççŽ ååãæããã¢ã«ã³ãã·ããåã³
ã¢ã»ãã«ã¢ã»ãããŒãã§ããããã©ã€ãã®äŸã¯ã
ãåç©ãå¡©åç©ãèåç©åã³ãšãŠåç©ã§ãããã
ããžãŠã ååç©ã®ç¹å®ã®äŸã¯äžå¡©åãããžãŠã ã
åå¡©åãããžãŠã ãåèåãããžãŠã ããªãã·äž
å¡©åãããžãŠã ããããžã³é žã¢ã«ãã«ã奜ãŸãã
ã¯ïŒã12åã®ççŽ ååãæãããããžã³é žã¢ã«ã
ã«ããããžã«ã¢ã»ãã«ã¢ã»ãããŒãããããžãŠã
ã¢ã»ãã«ã¢ã»ãããŒãåã³ããããããŒãã§ã
ãã äžæ¬¡è§Šåªç³»ã®ããææ©ã¢ã«ãããŠã ååç©ã説
æããã®ã«çšããçµéšåŒRAAl2XBã¯ããªã¢ã«ãã«
ã¢ã«ãããŠã ãšã¢ã«ãããŠã ããªãã©ã€ãããã
ããã®å²åã§äžç·ã«æ··åããããšã«ãã€ãŠåŸãã
ããšæãããåºç¯å²ã®ååç©åã¯ååç©ã®æ··åç©
ãå å«ãããã®ãšããããã®ãããªææ©ã¢ã«ãã
ãŠã ååç©ã®ç¹å®ã®äŸã¯ãšãã«ã¢ã«ãããŠã ã»ã¹
ãã¯ãã©ã€ãããžã€ãœããã«ã¢ã«ãããŠã ã¯ãã©
ã€ãããšãã«ã¢ã«ãããŠã ãžãããã€ããããªâ
ïœâããã·ã«ã¢ã«ãããŠã ããžãšãã«ã¢ã«ãããŠ
ã ã¢ã€ãªãã€ããããªãã·ã«ã¢ã«ãããŠã åã¯ã¡
ãã«ã¢ã«ãããŠã ã»ã¹ãã¯ãã©ã€ãã§ããã äžæ¬¡è§Šåªç³»ã§çšããããåŒLiAlR4ãæããå
åç©ã®ééå®äŸã¯ãªããŠã ããã©ã¢ã«ãã«ã¢ã«ã
ããŒãïŒïŒâïŒãäŸãã°ããã©ãšãã«ã¢ã«ãããŒ
ãïŒïŒâïŒãããã©ããã«ã¢ã«ãããŒãïŒïŒâïŒ
åã³ããã©ããã·ã«ã¢ã«ãããŒãïŒïŒâïŒã§ã
ãã åèšã®ããã©ããããã«ããªã«ããã©ãããã
ããšãŒããããã©ãããããé žã®ã¢ã«ãã«ãšã¹ã
ã«ãã¢ã«ãã¬ã³ãã¹âããã©ããããããšãŒãå
ã³ãªãã·âãã¹ãã¢ã«ãã¬ã³ïŒïŒâãããšãŒãïŒã
ã®åååç©ã®å¡©çŽ åã§åããã©ãããããªã«åºå
ã¯åçµåéã«ã€ããŠããããããã®æ°ŽçŽ ååã
ïŒãïŒãïŒååã¯ïŒåã®å¡©çŽ ååã§çœ®æããããš
ãã§ããããã®ãããªåååç©ã¯ããçšåºŠã®è§Šåª
ã瀺ãã奜ãŸããååç©ã¯ãããšãŒãåã³ïŒåã¯
ãã«ããªã«ãšã¹ãã«ã®ãã©ã³ç°ãããã©å¡©çŽ åã
ããŠããå Žåã®ååç©ã§ãããαâãªã¬ãã€ã³å ±
éåäœåã³äžå å ±éåäœã®éåå·¥çšã§ã¯åå¿å®¹åš
ã«é žã®å ç©ãäœåºŠãè¡ãããããã¯æ¬¡ç¬¬ã«ïŒã€ã®
åéäœã®ä»ã®åéäœã«å¯Ÿããå¶åŸ¡äžèœã®åªå éå
ãããããããã®åå¿ã¯é©åœãªé žæå»å€ãå°å ¥ã
ãããšã«ãã€ãŠå®å®åããããšãã§ããããªãã·
âãã¹ããã¬ãŒãã®ãšãŒãã«é žçŽ çµåã¯ãã®ç®ç
ã«å¯ŸããŠè¯å¥œãªé žå容æ§ãæã€ãŠããã äžæ¬¡è§Šåªç³»ã§çšããããRMgXã®ééå®äŸã¯
ãã·ã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãããã·ã«ãã°ã
ã·ãŠã ã¯ãã©ã€ããããã·ã«ãã°ãã·ãŠã ããã
ã€ããããã·ã«ãã°ãã·ãŠã ã¯ãã©ã€ããããšã
ã«ãã°ãã·ãŠã ã¯ãã©ã€ãåã³ããã·ã«ãã°ãã·
ãŠã ãããã€ãã§ããã ããã©ã¯ããããã©ãããããé žã®ã¢ã«ãã«ãš
ã¹ãã«ã®ééå®äŸã¯ã¡ãã«ããšãã«ãããã«ãã
ãã·ã«ããªã¯ãã«ãã€ãœãããã«ãsecâããã«
åã³tertâããã«ãšã¹ãã«ã§ãããå¡©çŽ åã¢ã«ã
ã¬ã³âãã¹âïŒâãããšãŒãã®ééå®äŸã¯ãšãã¬
ã³âãã¹âïŒïŒâãããšãŒãïŒåã³ãããã¬ã³â
ãã¹âïŒïŒâãããšãŒãïŒã§ããããªãã·âãã¹
ãã¢ã«ãã¬ã³ïŒïŒâãããšãŒãïŒãã®ééå®äŸã¯ãª
ãã·âãã¹ããšãã¬ã³ïŒïŒâãããšãŒãïŒãåã³
ãªãã·âãã¹ããããã¬ã³ïŒïŒâãããšãŒãïŒã
ã§ããã奜ãŸãããšã¹ãã«ã¯æº¶åªã®çåæ°ŽçŽ ã«æ
ã容æã«æº¶è§£ãããã®ãæ倧ãããšãŒãå«æéã
æãããã®ãåã³åŸãããéåäœã«å ãçãæ®çº
æ§æçãäžããªããã®ã§ããã奜ãŸãããããšãŒ
ãã¯ããã«ããã©ã¯ããããã©ããããããšãŒ
ããããã©ã¯ããããã©ããããã«ããªã«ããã©
ã¯ããããã©ããããããšãŒãåã³å¡©çŽ åãªãã·
âãã¹âã¢ã«ãã¬ã³ãããšãŒãã§ããã æ¬çºæã®è§Šåªã§éåããããšãã§ããαâãªã¬
ãã€ã³ã®ééå®äŸã¯ãšãã¬ã³ããããã¬ã³ããã
ã³ãªã©ãåã³ãããã®æ··åç©ã§ãããéåäœã®å
ç¡«ã®ããã®äžé£œåãå°å ¥ããããã«ãããªãšã³ã
å°éã§çšããããšãã§ãããããªãšã³åã¯è€æ°ã®
ççŽ âççŽ äºéçµåãå«æããä»ã®ãšãã¬ã³æ§äž
飜åååç©ã¯ãšãã¬ã³âãããã¬ã³âããªãšã³äž
å å ±éåäœã®åæã«ãããŠç¬¬äžã®åéäœãšããŠã®
䜿çšã®ããã«åŸæ¥æ³ã®åç®ã«é瀺ããããã®ãã
éžã¶ããšãã§ããããã«ã¯ïŒïŒïŒâãããµãžãš
ã³ã11âãšãã«âïŒã11âããªãã«ãžãšã³ãïŒïŒ
ïŒâãªã¯ã¿ãžãšã³ã®ãããªïŒã20åã®ççŽ ååã
æããééããªäžé£œåçåæ°ŽçŽ ãäžç°ããªãšã³å
ã³å€ç°ããªãšã³ãããããžã·ã¯ããã³ã¿ãžãšã³ã
ãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒããã¿âïŒïŒïŒâãžãšã³
ã®ãããªãæ©ããç°ã®ïŒã€ã®äžã«å°ãªããšãïŒå
ã®äºéçµåãååšããŠãããã·ã¯ãïŒïŒïŒïŒïŒ
ïŒïŒããã¿ã³ã®ããªäžé£œåèªå°äœãã¢ã«ããªãã³
ãã«ããŒãã³ãç¹ã«ã¢ã«ããªãã³åºãïŒã20åã
奜ãŸããã¯ïŒãïŒåã®ççŽ ååãå«æããŠããïŒ
âã¢ã«ããªãã³âïŒâãã«ããŒãã³ãã¢ã«ã±ãã«
ãã«ããŒãã³ãç¹ã«ã¢ã«ã±ãã«åºãçŽïŒã20åã
奜ãŸããã¯ïŒã10åã®ççŽ ååãå«æããŠããïŒ
âã¢ã«ã±ãã«âïŒâãã«ããŒãã³ã®ãããªããªäž
飜åæ©ããç°çåæ°ŽçŽ ã䜿çšããããšãã§ããã
ä»ã®æ©ããç°çåæ°ŽçŽ ã«ãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒ
ãªã¯ã¿âïŒïŒïŒâãžãšã³ã®ãããªãã·ã¯ãïŒïŒïŒ
ïŒïŒïŒïŒãªã¯ã¿ã³ã®ããªäžé£œåèªå°äœããã·ã¯ã
ïŒïŒïŒïŒïŒïŒïŒãªã¯ã¿ã³ã®ããªäžé£œåèªå°äœãã
ã·ã¯ãïŒïŒïŒïŒïŒïŒïŒããã³ã®ããªäžé£œåèªå°äœ
åã³ãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒããã³ã®ããªäžé£œå
èªé£œäœããããäžèšååç©ã®æ©ããç°ã«ã¯å°ãªã
ãšãïŒåã®äºéçµåãååšãããŸãæ©ããç°åã¯
åŽéäžã«å°ãªããšãïŒåã®ä»ã®äºéçµåãååšã
ãã ãšãã¬ã³åã³ãããã¬ã³ã®äžå å ±éååã¯å ±é
åã®ããã®å¥œãŸããäžæ¬¡è§Šåªç³»ã¯ãããžãŠã ãªã
ã·ã¯ãã©ã€ããåå¡©åãããžãŠã ããããžã³é žã¢
ã«ãã«ãããã«å¥œãŸããã¯ã¢ã«ãã«åºãïŒã12å
ã®ççŽ ååãæãããããžã³é žã¢ã«ãã«ãåã¯ã¢
ã«ãã«ã¯ããããããŒããããã«å¥œãŸããã¯ã¢ã«
ãã«åºãïŒã12åã®ççŽ ååãæããã¢ã«ãã«ã¯
ããããããŒããšã¢ã«ãã«ã¢ã«ãããŠã ãã©ã€
ããããã«å¥œãŸããã¯ïŒã12åã®ççŽ ååãæã
ãã¢ã«ãã«ã¢ã«ãããŠã ãã©ã€ããšã®çžäºäœçšã«
ãã€ãŠåœ¢æãããçåæ°ŽçŽ ã«å¯æº¶æ§ã®è§Šåªã§ã
ãããããã®å¥œãŸããå¯æº¶æ§è§Šåªç³»ã«ãããŠãã¢
ã«ãããŠã 察ãããžãŠã ã®ã°ã©ã ååæ¯ã¯å°ãªã
ãšãïŒïŒïŒã奜ãŸããã¯10ïŒïŒã§ããã20ïŒïŒã
35ïŒïŒåã³50ïŒïŒåã¯ãã以äžã®ãããªé«ãã°ã©
ã ååæ¯ãããç¹ã«ãããžãŠã ã®äœ¿çšéãå°ãªã
ãšãã«çšããããšãã§ãããæåŸã®ã±ãŒã¹ã«ãã
ãŠã200ïŒïŒã®æ¯ãäŒå³ããããšãã§ããããã
ãã®å¥œãŸããå¯æº¶æ§è§Šåªç³»ã¯éæ¶è³ªã®ããŽã ç¶
ã®ãç¡«é»å ç¡«æ§ã®é«çŽãŽã åæã圢æãããèœå
ãæã€ãŠããããã®å¯æº¶æ§è§Šåªçµæç©ã¯ãšãã¬ã³
âãããã¬ã³å ±éåäœã®ãããªãŽã çµæç©ã«å¯Ÿã
ãŠå¥œãŸããããã©ããä»ã®å Žåããšãããããã
ã¬ã³ã®åç¬éåã«ãããŠã¯ãäžæº¶æ§ã®ãåã¯äžå
質ã¿ã€ãã®è§Šåªã奜ãŸããã æ¬çºæã§çšãããã掻æ§å€ã®éã¯ç¹ã«èšççã§
ã¯ãªãããããžãŠã ã®ã¢ã«åœã0.01ã¢ã«ã®æŽ»æ§å€
ã®ãªãŒããŒã®å°éãããå Žåã«é¡èãªæŽ»æ§ãçã
ã®ã«ååã§ãããéåžžãè¥å¹²å€§éã®ãå žåœ¢çã«ã¯
ãããžãŠã ã®ã¢ã«åœãçŽïŒã¢ã«ãçŽ10ã¢ã«ã®æŽ»æ§
å€ãçšããã®ã奜ãŸãããææã«ãã€ãŠã¯ããã
ã«å€§éã®æŽ»æ§å€ãçšããããšãã§ãããç¹ã«ãã¢
ã«ãããŠã ååç©å¯ŸãããžãŠã ã®ã°ã©ã ååæ¯ã
50åã¯ãã以äžã®ãšãã¯ã50ã¢ã«åã¯ãã以äžã®
掻æ§å€ãçšããããšãã§ããããããã«ããŠãã
ææ©ã¢ã«ãããŠã ååç©ã®éãããå€ã掻æ§å€ã
å ããã®ã¯æ害ã§ãããã æ¬çºæã®éåæ¹æ³ã¯äžæŽ»æ§æº¶å€äžã§è¡ãããšã
ã§ãããããããªãããéåãããŠããéå°ã®å
éäœåã¯åéäœé¡ã¯æº¶å€ãšããŠäœçšããããšãã§
ããã®ã§ãæ·»å 溶å€ã¯äžè¬ã«æ¬è³ªçã§ãªããäžè¬
çã«ãã€ãŠãã€ãªã³é äœã¿ã€ãã®éåã«ãããŠçš
ããããéåžžã®æº¶å€ã䜿çšããããšãã§ãããã
ããã®æº¶å€ã«è³éŠæçåæ°ŽçŽ ãèèªæçåæ°ŽçŽ ã
ã¯ãããã³ãŒã³ãããã©ã¯ãããšãã¬ã³åã³è§Šåª
ãç Žå£ããªãä»ã®æº¶å€ããããéåã¯åžžæ³ã«ãã
ãããã«å®æœããããšãã§ãããäŸãã°ãâ20ã
200âã®éå枩床ãïŒã50æ°å§åã¯ãã以äžã®å§
åã0.001ãïŒã®ãããžãŠã å¯Ÿå ±è§Šåªã®ã¢ã«æ¯ã
溶液äžã§ïŒïŒïŒãïŒïŒ200ã®ãšãã¬ã³å¯Ÿãããã¬
ã³ã®åéäœã®ã¢ã«æ¯ãå žåœ¢çã§ããããããã¯é
å®æ¡ä»¶ã§ã¯ãªãã 次ã®å®æœäŸã¯æ¬çºæã®å®æœãããã«è©³çŽ°ã«èª¬æ
ããããã®ãã®ã§ããã觊åªã®å¹çã¯å šãŠã®å®æœ
äŸã§ãããžãŠã ååç©ã®ã°ã©ã åœãã®éåäœã®ã°
ã©ã ãšããŠèšç®ãããã å®æœäŸ ïŒ ãã«ããªã«ãããšãŒãã®åæ ãã®ãšã¹ãã«ã¯ãžã€ãŒãã« ãªã ã¢ã¡ãªã«ã³
ã±ãã«ã« ãœãµã€ãã€ãŒïŒJ.Am.Chem.Soc.ïŒ
66ã1230ïŒ1944ïŒã«é瀺ãããã€ãŒã»ã¢ãŒã«ã»ã
ãŒã«ã»ã³ïŒE.R.NielsenïŒã®æ¹æ³ã«åŸã€ãŠåæã
ãã ãšã¹ãã«ã¯ãšã¹ãã«ã®å10ïœã«å¯ŸããŠ20mlã®ãš
ãŒãã«ãš10mlã®ç³æ²¹ãšãŒãã«ããæãæ··å溶å€ã
ãã®äœæž©åçµæ¶ã«ãã€ãŠç²Ÿè£œãããåŸãããèç¹
29ã31.5âã®åºäœã¯90ïŒ ã®ååçã§åŸãããã å®æœäŸ ïŒ ããã©ã¯ããããã©ããããã«ããªã«ããã©ã¯
ããããã©ããããããšãŒãïŒZXUïŒã®åæ 0.25ã¢ã«ïŒ48ïœïŒã®ãã«ããªã«ãããšãŒãã®
750mlã®CCl4äžæº¶æ¶²ãçªçŽ ãµãå²æ°äžã§â15âã«
å·åŽããããã®æº¶æ¶²ã«â10âã«å·åŽãã500mlã®ã
å¡©çŽ 2Mã®CCl4溶液ãå ããããã®æ·»å ã¯æ¥éæ¹
æäžåã³çªçŽ ãµãå²æ°äžã§ã枩床ãïŒâ以äžã«ã¯
ãªããªãããã«ããé床ã§è¡ã€ããå¡©çŽ æº¶æ¶²ã®æ·»
å åŸããã®åå¿æ··åç©ãçªçŽ äžãâ10âã«ãããŠ
ïŒãïŒæéæ¹æãããæªåå¿ã®å¡©çŽ ã¯ãã®æº¶æ¶²ã«
çªçŽ ã®ãã€ããããæµããéãããããŠãã®æº¶æ¶²
ã宀枩ãŸã§ãã€ããå æž©ããããšã«ãã€ãŠé€å»ã
ããCCl4ã次ã«å転èžçºåšäžã§é§åºãããããŠ
æåŸã®çè·¡ã®CCl4ã¯ãã®åå¿æ··åç©ãé«ç空ã«
äžå€æé²ããããšã«ãã€ãŠé€å»ããããã®æç¹ã§
åŸãããç²çš ãªã·ãããã¯å®å šã«ç¡è²ã§ãå åã³
湿åããä¿è·ãããšãã¯é·æéã«ããã€ãŠç¡è²ã®
ãŸãã§ãã€ãã N.M.R.ã¯æ¬¡ã®æ§é ãšäžèŽãããN.M.R.ã¹ãã¯ãã«ã¯äºæãããã
ã«ïŒïŒïŒã®ããŠã³ãã€ãŒã«ã匷床æ¯ãæããŠã
ããå¯èœãªåçš®ç°æ§äœã¯è€éãªã¹ãã¯ãã«ãäžã
ããšäºæ³ãããããå®éã«ãã®ãããªã¹ãã¯ãã«
ãåŸããããå çŽ åæãææ¡ãããæ§é ãšäžèŽã
ãã20âã«ãããå±æçã¯ïŒã5334ã§ãã€ãã å çŽ åæïŒC10H8Cl8O4 èšç®å€ 枬å®å€ ïŒ£ïŒ 25.24 23.82 ïŒšïŒ 1.69 1.70 ClïŒ 59.61 59.72 ZXUã®æ¯æ§è©Šéšã¯æ¬¡ã®éãã§ãã€ãã æ¥æ§çµå£âLD50ïŒ1.1±0.15ïœïŒKgâäœéïŒã©ã
ãïŒ äžæ¬¡ç®èåºæ¿ïŒå®¶ãããã®ç®èã«å¯ŸããŠäžçšåºŠã®
åºæ¿ ç®ã«å¯Ÿããåºæ¿ïŒå°å ¥ïŒç§åŸã«ãã®ç©è³ªãæŽå»ã
ããšã軜ãåºæ¿ãæŽå»ãªãã§ãã®ãŸãæ®ã€ãŠã
ãå Žåã¯æ¿ããåºæ¿ ãšãŒã ãºè©ŠéšïŒAmes TestïŒã¯çªç¶å€ç°ã«å¯Ÿ
ããŠè² ã§ãã€ãã åœãåŸã泚æãåãã°ããã®ç©è³ªã¯çç£å·¥çšã§
䜿çšããããšãã§ããã å®æœäŸ ïŒ ããã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ããâïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããâïŒâãããšãŒã
ïŒUKUïŒã®åæ 500mlã®äžãå£äžžåºãã©ã¹ã³äžã§33.6ïœïŒ0.2ã¢
ã«ïŒã®èžçããã°ããã®æ°ããïŒâããã«ãããš
ãŒãã200mlã®ä¹Ÿç¥CCl4ã«æº¶è§£ããå€åŽã®æ°·âå¡©
济ã§ïŒâãŸã§å·åŽããã次ã«ããã®æº¶æ¶²ã«ïŒæé
ã«ããã€ãŠ0.4ã¢ã«ã®Cl2ã¬ã¹ããã€ããå°å ¥ãã
泡ç«ãŠããåå¿æ··åç©ããæªåå¿ã¬ã¹ãé€å»ãã
ããã«ããã®æ··åç©ã«ã宀枩ãŸã§å æž©ããªããã
ãã®æº¶æ¶²ãç¡è²ã«ãªããŸã§ä¹Ÿç¥çªçŽ ãéããã溶
å€ã®CCl4ãå転èžçºåšã§ããŠã¹ãããŠãŒã
ïŒhouse vaccumïŒäžãçŽ40âã«ãããŠé€å»ããã
åŸãããç²çš ãªæ¶²äœããã以äžç²Ÿè£œããããšãªã
ã«è§Šåªå掻æ§åå€ãšããŠäœ¿çšãããåçã¯ã»ãšã
ã©å®éçã§ãã€ãã å çŽ åæïŒC9H12Cl4O3 èšç®å€ 枬å®å€ïŒïŒåè¡ã€ãïŒ ïŒ£ïŒ 34.86 34.82 34.79 ïŒšïŒ 3.90 3.69 3.37 ClïŒ 45.75 43.68 43.57 N.M.RïŒååŠã·ãããšã¹ããªããã€ã³ã°ãã¿ãŒ
ã³ã¯æ¬¡ã®ææ¡ãããæ§é ã«äžèŽããã 97Hzã«ãããŠã¡ãã«åºïŒããã«åºããïŒïŒã
ãªãã¬ãããšããŠïŒ160Hzã«ãããŠäžå€®ã®âïŒâ
CH2ïŒ2âïŒãã«ããã¬ãããšããŠïŒïŒ427Hzã«ã
ããŠââCH2âïŒããªãã¬ãããšããŠïŒã487
Hzã«ãããŠïŒåã®ç°ã®ãå¡©çŽ ã«å¯ŸããŠÎ±âäœã®
æ°ŽçŽ ïŒãã«ããã¬ãããšããŠïŒïŒåã³630Hzã«ã
ããŠé žçŽ ã«å¯ŸããŠæ¬¡ã®éæ°ŽçŽ ã ãšãŒã ãºè©Šéšã¯çªç¶å€äœã«å¯ŸããŠè² ã§ãã€ãã å®æœäŸ ïŒ ã¡ãã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ããâïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããâïŒâãããšãŒãã®
åæ ãã®ååç©ã¯ãããã«ãããšãŒãã®ä»£ãã«ã¡ã
ã«ãããšãŒãã䜿çšããç¹ãé€ããŠå®æœäŸïŒã®æ¹
æ³ã«ãã€ãŠåæããã å çŽ åæïŒC6H6Cl4O3 èšç®å€ 枬å®å€ ïŒ£ïŒ 26.90 26.72 26.22 ïŒšïŒ 2.26 1.93 1.91 ClïŒ 52.93 57.89 57.90 å®æœäŸ ïŒ ãšãã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ããâïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããâïŒâãããšãŒã
ïŒTOUïŒã®åæ ãã®ååç©ã¯ããã«ãããšãŒãã®ä»£ãã«ãšãã«
ãããšãŒããçšããŠå®æœäŸïŒã®æ¹æ³ã«ãã€ãŠåæ
ããã å çŽ åæïŒC7H8Cl4O3 èšç®å€ 枬å®å€ ïŒ£ïŒ 29.82 29.43 29.23 ïŒšïŒ 2.84 2.35 2.27 ClïŒ 50.31 49.78 49.78 å®æœäŸ ïŒ ããã·ã«ïŒâãããšãŒãã®å¡©çŽ å ãã®ååç©ã¯å®æœäŸïŒã®æ¹æ³ã«ãã€ãŠãããã«
ãããšãŒãã®ä»£ãã«ããã·ã«ãããšãŒããçšããŠ
åæããã å çŽ åæïŒC11H15Cl5O3 èšç®å€ 枬å®å€ ïŒ£ïŒ 35.47 33.67 33.52 ïŒšïŒ 4.06 3.47 3.55 ClïŒ 47.59 45.81 45.80 å®æœäŸ ïŒ UKUãçšããŠã®ã±ã ã³ ãªã¢ã¯ã¿ãŒ
ïŒChemco ReactorïŒã«ããã掻æ§åå®éšïŒå®
æœäŸïŒãåç §ïŒ ïŒã®ãã¯ãããã°ã©ãã€ãŒïŒã¢ã«ããïŒã§ç²Ÿ
補ãã也ç¥ãããµã³ãïŒã¬ãã³ã®æŸæãªä¹Ÿç¥ã±ã
ã³ ãªã¢ã¯ã¿ãŒïŒãã«ãµãTulsaããOKã74135
ã®ã±ãã«ã« ã€ã¯ã€ããã¡ã³ã瀟ãChemical
Equipment Corporationãã®åæšïŒã«å ããã
ããã«å¿ èŠéã®25ïŒ ïŒ0.740MïŒãšãã«ã¢ã«ãã
ãŠã ã»ã¹ãã¯ãã©ã€ãïŒEASCïŒæº¶æ¶²ãå ããã
ãããã¬ã³ã0.2345MPaã®å¹³è¡¡å§ãŸã§ãæ°ŽçŽ ã
0.2483MPaãŸã§ããããŠãšãã¬ã³ã0.3448MPaã®
å šå§ãŸã§å ããããšããªãã³ãã«ããŒãã³
ïŒENBïŒã®è©ŠæïŒmlãå ãããããŠVOCl3溶液ã®
æ·»å ã«ãã€ãŠéåãéå§ãããã ïŒååŸã«ãå¿ èŠéã®1M UKU溶液ã«å ãã掻
æ§åãè¡ã€ããïŒæéã«ãããªãããã¬ã³ã°ãªã³
ãŒã«ã«ããéåãè¿ éåæ¢ããããããŠéåäœã
é žåé²æ¢å€ãå«æããã€ãœãããããŒã«ã«ããå
éã«ãã€ãŠååãããéåäœã次ã«æ°ããã€ãœã
ããããŒã«ïŒé žåé²æ¢å€ãå«ãïŒãå ¥ã€ãŠããã¯
ãŒã€ã³ã° ãã¬ã³ããŒïŒWaring blenderïŒïŒã€ãŒ
ã¹ã ããŒãããªãŒããEast HartfordããCt.ã®
ã¯ãŒã€ã³ã° ãããã¯ã瀟ãWaring Productsã
ã®åæšïŒäžã§åæãã次ãã§ä¹Ÿç¥ããã 第ïŒè¡šã«ç€ºãããçµæã¯ãè¯å¥œãªæŽ»æ§åãéæ
ãããå¹çã¯æãäœãå Žåã§635ãã1177ãŸã§å¢
å ãããŸãæãé«ãå Žåã§2331ãŸã§å¢å ããããš
ã瀺ããŠããããã®éåã§ã¯ãUKUã®æ¿åºŠãå¢
å ãããšãšãã«ååéãäžããéåžžã«é¡èãªåŸå
ããã€ããäŸãã°ãå®éšçªå·ïŒ¡ïŒãã©ã³ã¯ïŒã®ç
æç©ã®ç²åºŠãå®éšçªå·ïŒ¢åã³ïŒ£ã®çæç©ã®ç²åºŠãš
æ¯èŒããããã ãè¡šã (a) ãšãã«ã¢ã«ãããŠã ã»ã¹ãã¯ãã©ã€ã
(b) ã€ãœãããããŒã«
(c) ããã©ãªã³äžã135âã«ããã極éç²åºŠ
(d) 100âã§4ååŸã®ã ãŒããŒç²åºŠ
(e) ã°ã©ã ååâã¢ã«ãããŠã ïŒã°ã©ã ååâã
ããžãŠã
å®æœäŸ ïŒ ZXUã掻æ§å€ãšããŠäœ¿çšãã掻æ§åã®ç 究 UKUã®ç 究ã§äœ¿çšããæ¡ä»¶ãçšããŠå®éšãè¡
ã€ãããã ãã掻æ§å€ã¯Et3Al2Cl3ã®æ·»å åŸåã³
éåãéå§ããåã«å ããã第衚ã«ç€ºãããçµ
æããã掻æ§åã¯èŠ³å¯ãããããååé調æŽã¯å š
ã芳å¯ãããªãããã®ãããé«ååéãæãã
ãããããè¯å¥œãªæŽ»æ§åãéæããããšãæããš
ãã¯ãZYUãUKU以äžã«å¥œãŸããã ãè¡šã å®æœäŸ ïŒ ZXUã«ããEPMã®éåã«ããããããžã³é žã
ãã«ãšEt3Al2Cl3ããã®äºåæ··å觊åªïŒäžæŽ»æ§ïŒ
ã®æŽ»æ§å å°ããç·è²ã®ãœãŒãã³ãïŒæž æµã«ãã110âã®
çäžã§ä¹Ÿç¥ãããããŠçªçŽ ãµãå²æ°äžã§å·åŽã
ãïŒã«93.5mlã®ä¹Ÿç¥ãããµã³ãš1.1mlã®0.353Mã
ããžã³é žããã«æº¶æ¶²ãå ããããã®ã³ãã«ãŽã ã®
éèãå«ãïŒãç©Žã®ãã€ããã§ãµããããã5.4
mlã®25ïŒ EASCïŒ0.740MïŒã®æ·»å ã¯ãããžãŠã
0.004Måã³EASC0.04MïŒAlïŒïŒ¶ïŒ20ïŒïŒïŒã®äº
åæ··å觊åªæº¶æ¶²ãäžããã 也ç¥ããïŒã®äžãå£ãã©ã¹ã³ã«ããã®ãã©ã¹
ã³ã«å ããããã¹ã液äœã®ã¬ãã«ããäžã«å»¶åšã
äœçœ®ãããã¬ã¹å°å ¥ç®¡ã枩床èšãæ¹æèšãåã³å°
éã®é±æ²¹ãå ¥ã€ãŠããã¬ã¹æŽæµã³ãã«æ¥ç¶ããã
éæµå·åŽåšãåãä»ããããã®ãã©ã¹ã³ã«400ml
ã®ä¹Ÿç¥ãããµã³ãçªçŽ ãµãå²æ°äžã«ãããŠæºã
ãããã®æº¶æ¶²ã«æ¬¡ã«ãšãã¬ã³ãšãããã¬ã³ã®ïŒïŒ
ïŒäŸçµŠåæã15åé飜åããããïŒååŸã«ïŒmlã®
25ïŒ EASCãå ãã也ç¥ç³»ãä¿èšŒããã10ååŸã«
ïŒmlã®åèšäºåæ··å觊åªïŒ0.02ããªã¢ã«ã®ïŒ¶ãš
0.4ããªã¢ã«ã®AlãæããïŒãå ãããçºç±ã¯èŠ³
å¯ããããéåã¯èµ·ããªãã€ãã15ååŸã«ïŒmlã®
0.05ã¢ã«UKUãå ããããã®æº¶æ¶²ã¯çŽã¡ã«ææž©
ãå§ãïŒæŽ»æ§ãªéå觊åªã§ããããšã瀺ãïŒãã
ããŠïŒååŸã«ãã®æž©åºŠã¯19âãã28âã«è³ã€ãã äžèšã®æäœãè¡ã€ãŠå¥ã®äºåæ··å觊åªã調補
ãããããŠåéäœã®ååšäžã§ZXUåã¯UKUã®ã
ãããã§åŠçãããçµæã第衚ã«ç€ºããããã
ããé©ãã¹ãããšã«ããžã€ãœããã«ã¢ã«ãããŠã
ã¯ãã©ã€ãïŒDIBACïŒâVOCl3ã¯å掻æ§åããã
ãšãã§ããããåã«æããã«ããããã«ãä»ã®é ž
åå€ã¯çŽãžãã©ã€ãåã¯çŽãããã©ã€ãïŒã¢ã«ã
ã«ã¢ã«ãããŠã æåïŒã®ãããããã調補ããäº
åæ··å觊åªã掻æ§åããªãã€ãã ãè¡šã (b) ã°ã©ã ååâã¢ã«ãããŠã ïŒã°ã©ã ååâãã
ãžãŠã
å®æœäŸ 10 ããã©ã¯ããããã©ãããããé žã®ãšã¹ãã«ã
䜿çšããã±ã ã³ ãªã¢ã¯ã¿ãŒã®å®éšã®ä»ã®äŸã以
äžã®ç¬¬è¡šã«ç€ºããå®æœäŸïŒã§çšããã®ãšåãå
å¿æ¡ä»¶ãçšããããã ããEASCåã³VOCl3ã®ã¢
ã«éã䞊ã³ã«æŽ»æ§å€ã®ã¿ã€ãåã³éã¯å€ããã ãè¡šã ãè¡šã å®æœäŸ 11 ïŒïŒ2â²âãªãã·âãã¹ããšãã¬ã³ïŒïŒâãããš
ãŒãïŒãïŒJMUïŒã®å¡©çŽ å é žçŽ åã¯æ¹¿åã®å°å ¥ãé²ãããããã®å šæäœã¯
çªçŽ ãµãå²æ°äžã§è¡ã€ããæ©æ¢°çæ¹ææ©ã枩床
èšã滎äžæŒæåã³ç°æµå·åŽåšãåããïŒã®äžã
å£ãã©ã¹ã³ãå§å解æŸæ段ãæã€ïŒå§åãã»ã倧
æ°å§ã«ä¿ã€ããïŒçªçŽ ç³»ã«æ¥ç¶ããããã«750.0
mlã®ç²Ÿè£œã也ç¥ããåå¡©åççŽ ãš42.2ïœã®JMU
ïŒ0.143ã¢ã«ïŒãå ããããã®æº¶æ¶²ãâ10âã«å·åŽ
ãããJMUã¯çŽ°ããæ²æ®¿ãšããŠæº¶æ¶²ããæåºã
ãããã®æ··åç©ã«500mlã®å¡©çŽ 1.5Mã®CCl4溶液ã
å ãããã枩床äžæã¯èªããããªãã€ãããã®æ··
åç©ãïŒæéã«ããã€ãŠ20âãŸã§å æž©ããããã®
æ··åç©ã次ã«â15âã«åå·åŽãããæ²æ®¿ã®åœ¢æã¯
ãªããåå¿ã¯æããã«èµ·ããããã®åå¿æ··åç©ã
次ã«16æéæ¹æãã次ãã§å®€æž©ãŸã§ãã€ãå æž©ã
ïŒN2ãµãå²æ°äžïŒãåå¿ãå®çµãããã16æéåŸã
ãã®è²ã¯ã»ãšãã©æ¶ãããããã¯æ¯èŒçå°éã®å¡©
çŽ ããæ®çããŠããªãããšã瀺ããŠããããã®æº¶
液ã«N2ãéããŠæ³¡ç«ãŠãæ®çCl2ãæé€ããã
CCl4ã¯å転èžçºåšã®äœ¿çšã«ãã€ãŠé€å»ãããåŸ
ãããç©è³ªãCCl4ã®æåŸã®çè·¡ããé«ç空ã«æŽ
è·¯ããããšã«ãã€ãŠåé¢ããã10åã®å¡©çŽ ååã
çµåããŠæããååç©ã®åéã¯94ïœïŒåç100ïŒ ïŒ
ã§ãã€ãã å çŽ åæïŒC14H12Cl10O7ïŒMQWïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 26.00 26.54 26.68 ïŒšïŒ 1.87 2.05 2.05 ClïŒ 54.81 50.77 51.01 TLCã¯ïŒã€ã®ãã³ãã瀺ããããã¯ïŒçš®ã®å¥
åã®ç°æ§äœã瀺ããŠããã å®æœäŸ 12 ãããã¬ã³ ãã¹ïŒïŒâãããšãŒãïŒã®å¡©çŽ å 0.117ã¢ã«ã®ãããã¬ã³ãã¹ïŒïŒâãããšãŒãïŒ
ãš0.68ã¢ã«ã®å¡©çŽ ãçšããŠå®æœäŸ11ã®æ¹æ³ãè¡ã€
ããåéã¯ããžãããšãŒãã®ã¢ã«åœã4.5ã¢ã«ã®
Clã®ä»å ã«åºã¥ããŠã65.5ïœïŒåçïŒ96.1ïŒ ïŒã§
ãã€ãã å çŽ åæïŒC13H11Cl9O6ïŒïŒ¡âïŒïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 26.81 26.54 26.68 ïŒšïŒ 1.90 2.05 2.05 ClïŒ 54.80 53.76 53.80 20âã«ãããå±æçã¯1.5208ã§ãã€ãã å®æœäŸ 13 ïŒïŒ2â²âãªãã·âãã¹ïŒãããã¬ã³âïŒâãã
ãšãŒãïŒã®å¡©çŽ å 32ïœïŒ0.1ã¢ã«ïŒã®ïŒïŒ2â²âãªãã·âãã¹ãã
ããã¬ã³ïŒïŒâãããšãŒãïŒããš0.69ã¢ã«ã®å¡©çŽ
ãçšããŠå®æœäŸ11ã®æ¹æ³ãè¡ã€ããåéã¯76.5ïœ
ã§ãã€ããC16H15Cl11O7ã«åºã¥ããŠããã®åçã¯
100ïŒ ïŒåºçºç©è³ªã®ééã«åºã¥ããŠïŒã§ãã€ãã å çŽ åæïŒC16H15Cl11O7ïŒïŒ¡âïŒïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 27.09 25.94 26.12 ïŒšïŒ 2.13 2.25 2.21 ClïŒ 54.98 53.73 53.60 å®æœäŸ 14 ãšãã¬ã³ãã¹ïŒïŒâãããšãŒãïŒã®å¡©çŽ å 0.15ã¢ã«ã®ãšãã¬ã³ãã¹ïŒïŒâãããšãŒãïŒãš
0.640ã¢ã«ã®Cl2ãçšããŠå®æœäŸ11ã®æ¹æ³ãè¡ã€
ããããããªããããã®ãžãããšãŒãã¯CCl4ã«
ã¯äžæº¶ã§ãããããCCl4ã®ä»£ãã«750mlã®å¡©åã¡
ãã¬ã³ãçšãããå·åŽãããšããžãããšãŒãã现
ããç²æ«ãšããŠæ²æŸ±ãããããã¯å¡©çŽ åãããã
ã®ã§ãã€ããå çŽ åæã¯ããã®ãžãããšãŒãã¯æ
äœãšããŠæåŸ ãããïŒåã®å¡©çŽ ååãä»å ãããª
ãã€ãããšã瀺ããŠããã å çŽ åæïŒC12H10Cl8O6ïŒïŒ¡âïŒïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 27.00 30.30 30.19 ïŒšïŒ 1.89 1.92 2.04 ClïŒ 53.13 44.35 44.50 å®æœäŸ 15 觊åªæ··åç©ãåå¿ã®å Žã§èª¿è£œããç¹ãé€ããŠã
第衚ã«èšèŒã®æŽ»æ§å€ãå®æœäŸïŒã®æ¡ä»¶ãçšããŠ
è©Šéšããããã©ã³ã¯ïŒå®éšïŒ§ïŒãšã®æ¯èŒã¯ããã
ãååç©ã¯å šãŠæŽ»æ§å€ãšããŠäœçšããããè¥å¹²ã®
ååç©ã¯çæéåäœã®ååé調æŽå€ãšããŠè¯å¥œã§
ã¯ãªãããšã瀺ããŠããã ãè¡šã å®æœäŸ 16 ãã¹ïŒããªã¯ããã¡ãã«ïŒã¹ã«ãã³ãã¢ã¡ãªã«
åœç¹èš±ç¬¬3304331å·æ现æžïŒC.A.66 104691eïŒ
ã«é瀺ããããã€ãŒã«ãº ãž ãµã³ãïŒCharles
Di SontoïŒã®æ¹æ³ã«ãããžã¡ãã«ã¹ã«ããã·ã
ã®å¡©çŽ åã«ãã€ãŠåæããã 掻æ§åã®å®éšã¯ãã¹ïŒããªã¯ããã¡ãã«ïŒã¹ã«
ãã³ïŒCYUïŒãUKUã®ä»£ããã«çšããç¹ãé€ã
ãŠå®æœäŸïŒã®æ¹æ³ã«ãã€ãŠè¡ã€ãã ãè¡šã ãè¡šã ãè¡šã ãè¡šã ãè¡šã ãè¡šã ãè¡šã
ãã觊åªã䜿çšããαâãªã¬ãã€ã³ã®éåæ¹æ³ã«
é¢ããã (1)å çŽ ã®åšæåŸè¡šç¬¬âæåã¯ç¬¬âæé
å±ã®ååç©ãš(2)ååšæåŸè¡šç¬¬âæéå±ã®ææ©
éå±ååç©ãšã®çžäºäœçšçæç©ã§ããã€ãªã³é äœ
éå觊åªã¯åšç¥ã§ããããã®ãããªè§Šåªã«ã¯å€ã
ã®å Žå觊åªæŽ»æ§ïŒåäœæéåœãã®ãé·ç§»éå±åå
ç©ã®ééã«å¯Ÿããéåäœã®ééïŒãäœããéåé
床ã觊åªãæ¯èŒçé«æ¿åºŠã§äœ¿çšããªããšæãŸãã
ãªãã»ã©é ããªãããããŠå¯æº¶æ§è§Šåªã䜿çšãã
ãšããã®æŽ»æ§ããã°ãã°éåäžã«æ¥éã«äœäžãã
ãšããæ¬ ç¹ãããã æ¬çºæã¯ãããžãŠã ååç©ãšææ©éå±ååç©ãš
ã«åºã¥ã觊åªïŒä»¥äžã«ãããŠã¯äžæ¬¡è§Šåªç³»ãšã称
ããïŒã¯ãã®æŽ»æ§ãäžå±€å¹æçã«ããåã³ïŒåã¯
ãã®æŽ»æ§ãé·æéã«ããã€ãŠç¶æããåã³ïŒåã¯
ãã®è§Šåªã«æŽ»æ§å€ãæ·»å ãããŠãããšãããã®è§Š
åªãæ²»æ§ã倱ãªãå§ããŠããåæ²»æ§åããããšã
ã§ãããšããé©ãã¹ãçºèŠã«åºã¥ããããå Žå
ã¯ã掻æ§å€ã®æ·»å ã¯ååéã調ç¯ããäœçšãå¥ã
ãã觊åªæŽ»æ§å€ã¯æ¶èãã觊åªãšåå¿ããç©è³ªå
ã¯ååç©ã®ããšã§ããã®ãããªæ¶è觊åªãæå³ã
ãååŠåå¿ãä¿é²ãç¶ããããšãã§ããç¶æ ã«ã
ã©ããåæ§ã®è§Šåªãšãããã®æŽ»æ§å€ãšã®åŸæ¥ã®çµ
ã¿åããã¯æ¬¡ã®ç¹èš±æ现æžã«èšèŒãããŠãããã
ãªãã¡ãã¢ã¡ãªã«åœç¹èš±ç¬¬3377325å·æ现æžã¯ç¡«
é»ã«ãã掻æ§åãçšããã«ããåœç¹èš±ç¬¬833651å·
æ现æžã¯äžå¡©åãªã³ãšïŒâããããããã³ã«ãã
掻æ§åãçšããã¢ã«ã«ãªåœç¹èš±ç¬¬3441546å·æ现
æžã¯ææ©ãããååç©ã«ãã掻æ§åãçšããã¢ã¡
ãªã«åœç¹èš±ç¬¬3444149å·æ现æžã¯ããããœååç©
åã¯ããã³ã«ãã掻æ§åãçšããã¢ã¡ãªã«åœç¹èš±
第3462399å·æ现æžã¯ææ©ãã€ãã¬ãŒããææ©ã
ã€ãã©ã€ããã¢ãŸãã·ååç©ãç¹æ®ãªææ©éå±å
åç©åã¯ã¢ã«ãã«ãžã¹ã«ããã«ãã掻æ§åã«é¢
ãããããŠã¢ã¡ãªã«åœç¹èš±ç¬¬3507843å·æ现æžã¯
äžå¡©åãªã³ã«ãã掻æ§åãçšããŠããã æ¬çºæã®è§Šåªçµæç©ã¯ãäžæ¬¡è§Šåªç³»ããããžãŠ
ã ååç©åã³åŒRMgXãLiAlR4åã¯RAAl2XBïŒåŒ
äžãã¯ïŒã12åã®ççŽ ååãæããçåæ°ŽçŽ
åºã奜ãŸããã¯ïŒã12åã®ççŽ ååãæããã¢ã«
ãã«åºã§ãããã¯ããã²ã³ååã§ãããã¯ïŒ
ãïŒã®æ°ã§ããããããŠïŒ¢ã¯ïŒãïŒã®æ°ã§ããã
ãã ãããšïŒ¢ã®åã¯ïŒã§ããïŒã®ææ©éå±åå
ç©ïŒãã ãããããžãŠã ååç©ããåã¯ææ©éå±
ååç©ã®ããããã«çµåããŠããåºã®å°ãªããšã
ïŒåã¯ããã²ã³ååïŒäŸãã°ãããçŽ ãå¡©çŽ ãè
çŽ åã³ãšãŠçŽ ïŒã§ããïŒããæãããããŠæŽ»æ§å€
ãå¡©çŽ åããã©ããããã«ããªã«ããã©ãããã
ããšãŒãã奜ãŸããã¯ããã©ã¯ããããã©ããã
ãã«ããªã«ããã©ã¯ããããã©ããããããšãŒ
ããå¡©çŽ åããã©ãããããé žã奜ãŸããã¯ãã
ã©ã¯ããããã©ãããããé žã®ã¢ã«ãã«ãšã¹ãã«
ïŒãã ããã¢ã«ãã«åºã¯ïŒãïŒåã奜ãŸããã¯ïŒ
ãïŒåã®ççŽ ååãæããïŒãå¡©çŽ åã¢ã«ãã¬ã³
ãã¹âããã©ããããããšãŒãïŒãã ããã¢ã«ã
ã¬ã³åºã¯ïŒååã¯ïŒåã®ççŽ ååãæããïŒãå¡©
çŽ åãªãã·âãã¹ãã¢ã«ãã¬ã³ïŒïŒâãããšãŒ
ãïŒãïŒãã ããã¢ã«ãã¬ã³åºã¯ãšã¿ã³ãžã€ã«ã
ïŒïŒïŒâãããã³ãžã€ã«ãã¢ã«ãã«çœ®æãšã¿ã³ãž
ã€ã«ãã¢ã«ãã«çœ®æïŒïŒïŒâãããã³ãžã€ã«âã
ã ãããšã¿ã³ãžã€ã«åã¯ïŒïŒïŒâãããã³ãžã€ã«
äžã®ã¢ã«ãã«åºã¯ïŒãïŒåã奜ãŸããã¯ïŒãïŒå
ã®ççŽ ååãæããâã§ããïŒãåã¯ãã¹ïŒããª
ã¯ããã¡ãã«ïŒã¹ã«ãã³ã§ãããäžæ¬¡è§Šåªç³»ãšæŽ»
æ§å€ãšã®çµã¿åãããæãã æ¬çºæã¯ãŸããå¡©çŽ åããã©ããããã«ããªã«
ããã©ããããããšãŒãã奜ãŸããã¯ããã©ã¯ã
ãããã©ããããã«ããªã«ããã©ã¯ããããã©ã
ãããããšãŒããå¡©çŽ åããã©ãããããé žã奜
ãŸããã¯ããã©ã¯ããããã©ãããããé žã®ã¢ã«
ãã«ãšã¹ãã«ïŒãã ããã¢ã«ãã«åºã¯ïŒãïŒåã
奜ãŸããã¯ïŒãïŒåã®ççŽ ååãæããïŒãå¡©çŽ
åã¢ã«ãã¬ã³ãã¹âããã©ããããããšãŒãïŒã
ã ããã¢ã«ãã¬ã³åºã¯ïŒååã¯ïŒåã®ççŽ ååã
æããïŒãå¡©çŽ åãªãã·âãã¹ãã¢ã«ãã¬ã³ïŒïŒ
âãããšãŒãïŒãïŒãã ããã¢ã«ãã¬ã³åºã¯ãšã¿ã³
ãžã€ã«ãïŒïŒïŒâãããã³ãžã€ã«ãã¢ã«ãã«çœ®æ
ãšã¿ã³ãžã€ã«ãã¢ã«ãã«çœ®æïŒïŒïŒâãããã³ãž
ã€ã«âãã ãããšã¿ã³ãžã€ã«åã¯ïŒïŒïŒâããã
ã³ãžã€ã«äžã®ã¢ã«ãã«åºã¯ïŒãïŒåã奜ãŸããã¯
ïŒãïŒåã®ççŽ ååãæããâã§ããïŒãåã¯ã
ã¹ïŒããªã¯ããã¡ãã«ïŒã¹ã«ãã³ããããžãŠã å
åç©ãšåŒRMgXãLiAlR4åã¯RAAl2XBïŒåŒäžã
ããåã³ïŒ¢ã¯åèšå®çŸ©ã®éãã§ããïŒãšã®
åå¿çæç©ãšåéäœåã¯åéäœé¡ã®ååšäžã§åå¿
ãããããšããæã觊åªã®è£œé æ¹æ³ãå å«ããã æ¬çºæã¯ãŸãæ¬çºæã®è§Šåªã䜿çšããαâãªã¬
ãã€ã³ã®éåæ¹æ³åã³ãã®éåæ¹æ³ã«ãã€ãŠè£œé
ãããéåäœã«é¢ãããéåãããαâãªã¬ãã€
ã³ååã¯å šãŠåãã§ãã€ãŠããããããããã¯ç°
ãªã€ãŠããŠããããäŸãã°ããšãã¬ã³ã®éåã¯ã
ãªãšãã¬ã³ãäžãããŸããšãã¬ã³ãšãããã¬ã³ãš
ã®æ··åç©ã®éåã¯å ±éåäœãçæãããã奜ãŸã
ãéåæ¹æ³ã¯ãšãã¬ã³ããããã¬ã³åã³ããªãšã³
ã䜿çšããŠç¡«é»å ç¡«äœã®äžå å ±éåäœã補é ãã
å Žåã§ããã åèšäžæ¬¡è§Šåªç³»ã¯å¥åã«èª¿è£œãã次ãã§éåç³»
ã«å ããããšãã§ãããããããã¯éåã®å Žã§èª¿
補ããããšãã§ãããæ¬çºæã®æŽ»æ§å€ã¯äžæ¬¡è§Šåª
ç³»ã®å°å ¥åãå°å ¥äžãããã¯å°å ¥åŸã«éåç³»ã«å
ããããšãã§ããã掻æ§å€ã¯ãŸãäžæ¬¡è§Šåªç³»ã®ïŒ
æåã«ããã®ç¬¬äºæåã®æ·»å åã«å ããŠãããã
äžæ¬¡è§Šåªç³»ã®èª¿æŽå·¥çšã瀺ããããŒãã€ãŒãã®äž
äŸã第ïŒå³ã«ç€ºãã第ïŒå³ã¯äžæ æ§ã§ãã€ãŠæ¬çº
æã®äžæ¬¡è§Šåªç³»ã®èª¿æŽå·¥çšã¯ããã«éå®ãããã
ã®ã§ã¯ãªãã æ¬çºæã®è§Šåªçµæç©ã«çšããããšãã§ãããã
ãžãŠã ååç©ã®ééå®äŸã¯ãããžãŠã ãã©ã€ãã
ãªãã·ãã©ã€ããã¢ã«ã³ãã·ãã奜ãŸããã¯ïŒå
åã¯ïŒåã®ççŽ ååãæããã¢ã«ã³ãã·ããåã³
ã¢ã»ãã«ã¢ã»ãããŒãã§ããããã©ã€ãã®äŸã¯ã
ãåç©ãå¡©åç©ãèåç©åã³ãšãŠåç©ã§ãããã
ããžãŠã ååç©ã®ç¹å®ã®äŸã¯äžå¡©åãããžãŠã ã
åå¡©åãããžãŠã ãåèåãããžãŠã ããªãã·äž
å¡©åãããžãŠã ããããžã³é žã¢ã«ãã«ã奜ãŸãã
ã¯ïŒã12åã®ççŽ ååãæãããããžã³é žã¢ã«ã
ã«ããããžã«ã¢ã»ãã«ã¢ã»ãããŒãããããžãŠã
ã¢ã»ãã«ã¢ã»ãããŒãåã³ããããããŒãã§ã
ãã äžæ¬¡è§Šåªç³»ã®ããææ©ã¢ã«ãããŠã ååç©ã説
æããã®ã«çšããçµéšåŒRAAl2XBã¯ããªã¢ã«ãã«
ã¢ã«ãããŠã ãšã¢ã«ãããŠã ããªãã©ã€ãããã
ããã®å²åã§äžç·ã«æ··åããããšã«ãã€ãŠåŸãã
ããšæãããåºç¯å²ã®ååç©åã¯ååç©ã®æ··åç©
ãå å«ãããã®ãšããããã®ãããªææ©ã¢ã«ãã
ãŠã ååç©ã®ç¹å®ã®äŸã¯ãšãã«ã¢ã«ãããŠã ã»ã¹
ãã¯ãã©ã€ãããžã€ãœããã«ã¢ã«ãããŠã ã¯ãã©
ã€ãããšãã«ã¢ã«ãããŠã ãžãããã€ããããªâ
ïœâããã·ã«ã¢ã«ãããŠã ããžãšãã«ã¢ã«ãããŠ
ã ã¢ã€ãªãã€ããããªãã·ã«ã¢ã«ãããŠã åã¯ã¡
ãã«ã¢ã«ãããŠã ã»ã¹ãã¯ãã©ã€ãã§ããã äžæ¬¡è§Šåªç³»ã§çšããããåŒLiAlR4ãæããå
åç©ã®ééå®äŸã¯ãªããŠã ããã©ã¢ã«ãã«ã¢ã«ã
ããŒãïŒïŒâïŒãäŸãã°ããã©ãšãã«ã¢ã«ãããŒ
ãïŒïŒâïŒãããã©ããã«ã¢ã«ãããŒãïŒïŒâïŒ
åã³ããã©ããã·ã«ã¢ã«ãããŒãïŒïŒâïŒã§ã
ãã åèšã®ããã©ããããã«ããªã«ããã©ãããã
ããšãŒããããã©ãããããé žã®ã¢ã«ãã«ãšã¹ã
ã«ãã¢ã«ãã¬ã³ãã¹âããã©ããããããšãŒãå
ã³ãªãã·âãã¹ãã¢ã«ãã¬ã³ïŒïŒâãããšãŒãïŒã
ã®åååç©ã®å¡©çŽ åã§åããã©ãããããªã«åºå
ã¯åçµåéã«ã€ããŠããããããã®æ°ŽçŽ ååã
ïŒãïŒãïŒååã¯ïŒåã®å¡©çŽ ååã§çœ®æããããš
ãã§ããããã®ãããªåååç©ã¯ããçšåºŠã®è§Šåª
ã瀺ãã奜ãŸããååç©ã¯ãããšãŒãåã³ïŒåã¯
ãã«ããªã«ãšã¹ãã«ã®ãã©ã³ç°ãããã©å¡©çŽ åã
ããŠããå Žåã®ååç©ã§ãããαâãªã¬ãã€ã³å ±
éåäœåã³äžå å ±éåäœã®éåå·¥çšã§ã¯åå¿å®¹åš
ã«é žã®å ç©ãäœåºŠãè¡ãããããã¯æ¬¡ç¬¬ã«ïŒã€ã®
åéäœã®ä»ã®åéäœã«å¯Ÿããå¶åŸ¡äžèœã®åªå éå
ãããããããã®åå¿ã¯é©åœãªé žæå»å€ãå°å ¥ã
ãããšã«ãã€ãŠå®å®åããããšãã§ããããªãã·
âãã¹ããã¬ãŒãã®ãšãŒãã«é žçŽ çµåã¯ãã®ç®ç
ã«å¯ŸããŠè¯å¥œãªé žå容æ§ãæã€ãŠããã äžæ¬¡è§Šåªç³»ã§çšããããRMgXã®ééå®äŸã¯
ãã·ã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãããã·ã«ãã°ã
ã·ãŠã ã¯ãã©ã€ããããã·ã«ãã°ãã·ãŠã ããã
ã€ããããã·ã«ãã°ãã·ãŠã ã¯ãã©ã€ããããšã
ã«ãã°ãã·ãŠã ã¯ãã©ã€ãåã³ããã·ã«ãã°ãã·
ãŠã ãããã€ãã§ããã ããã©ã¯ããããã©ãããããé žã®ã¢ã«ãã«ãš
ã¹ãã«ã®ééå®äŸã¯ã¡ãã«ããšãã«ãããã«ãã
ãã·ã«ããªã¯ãã«ãã€ãœãããã«ãsecâããã«
åã³tertâããã«ãšã¹ãã«ã§ãããå¡©çŽ åã¢ã«ã
ã¬ã³âãã¹âïŒâãããšãŒãã®ééå®äŸã¯ãšãã¬
ã³âãã¹âïŒïŒâãããšãŒãïŒåã³ãããã¬ã³â
ãã¹âïŒïŒâãããšãŒãïŒã§ããããªãã·âãã¹
ãã¢ã«ãã¬ã³ïŒïŒâãããšãŒãïŒãã®ééå®äŸã¯ãª
ãã·âãã¹ããšãã¬ã³ïŒïŒâãããšãŒãïŒãåã³
ãªãã·âãã¹ããããã¬ã³ïŒïŒâãããšãŒãïŒã
ã§ããã奜ãŸãããšã¹ãã«ã¯æº¶åªã®çåæ°ŽçŽ ã«æ
ã容æã«æº¶è§£ãããã®ãæ倧ãããšãŒãå«æéã
æãããã®ãåã³åŸãããéåäœã«å ãçãæ®çº
æ§æçãäžããªããã®ã§ããã奜ãŸãããããšãŒ
ãã¯ããã«ããã©ã¯ããããã©ããããããšãŒ
ããããã©ã¯ããããã©ããããã«ããªã«ããã©
ã¯ããããã©ããããããšãŒãåã³å¡©çŽ åãªãã·
âãã¹âã¢ã«ãã¬ã³ãããšãŒãã§ããã æ¬çºæã®è§Šåªã§éåããããšãã§ããαâãªã¬
ãã€ã³ã®ééå®äŸã¯ãšãã¬ã³ããããã¬ã³ããã
ã³ãªã©ãåã³ãããã®æ··åç©ã§ãããéåäœã®å
ç¡«ã®ããã®äžé£œåãå°å ¥ããããã«ãããªãšã³ã
å°éã§çšããããšãã§ãããããªãšã³åã¯è€æ°ã®
ççŽ âççŽ äºéçµåãå«æããä»ã®ãšãã¬ã³æ§äž
飜åååç©ã¯ãšãã¬ã³âãããã¬ã³âããªãšã³äž
å å ±éåäœã®åæã«ãããŠç¬¬äžã®åéäœãšããŠã®
䜿çšã®ããã«åŸæ¥æ³ã®åç®ã«é瀺ããããã®ãã
éžã¶ããšãã§ããããã«ã¯ïŒïŒïŒâãããµãžãš
ã³ã11âãšãã«âïŒã11âããªãã«ãžãšã³ãïŒïŒ
ïŒâãªã¯ã¿ãžãšã³ã®ãããªïŒã20åã®ççŽ ååã
æããééããªäžé£œåçåæ°ŽçŽ ãäžç°ããªãšã³å
ã³å€ç°ããªãšã³ãããããžã·ã¯ããã³ã¿ãžãšã³ã
ãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒããã¿âïŒïŒïŒâãžãšã³
ã®ãããªãæ©ããç°ã®ïŒã€ã®äžã«å°ãªããšãïŒå
ã®äºéçµåãååšããŠãããã·ã¯ãïŒïŒïŒïŒïŒ
ïŒïŒããã¿ã³ã®ããªäžé£œåèªå°äœãã¢ã«ããªãã³
ãã«ããŒãã³ãç¹ã«ã¢ã«ããªãã³åºãïŒã20åã
奜ãŸããã¯ïŒãïŒåã®ççŽ ååãå«æããŠããïŒ
âã¢ã«ããªãã³âïŒâãã«ããŒãã³ãã¢ã«ã±ãã«
ãã«ããŒãã³ãç¹ã«ã¢ã«ã±ãã«åºãçŽïŒã20åã
奜ãŸããã¯ïŒã10åã®ççŽ ååãå«æããŠããïŒ
âã¢ã«ã±ãã«âïŒâãã«ããŒãã³ã®ãããªããªäž
飜åæ©ããç°çåæ°ŽçŽ ã䜿çšããããšãã§ããã
ä»ã®æ©ããç°çåæ°ŽçŽ ã«ãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒ
ãªã¯ã¿âïŒïŒïŒâãžãšã³ã®ãããªãã·ã¯ãïŒïŒïŒ
ïŒïŒïŒïŒãªã¯ã¿ã³ã®ããªäžé£œåèªå°äœããã·ã¯ã
ïŒïŒïŒïŒïŒïŒïŒãªã¯ã¿ã³ã®ããªäžé£œåèªå°äœãã
ã·ã¯ãïŒïŒïŒïŒïŒïŒïŒããã³ã®ããªäžé£œåèªå°äœ
åã³ãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒããã³ã®ããªäžé£œå
èªé£œäœããããäžèšååç©ã®æ©ããç°ã«ã¯å°ãªã
ãšãïŒåã®äºéçµåãååšãããŸãæ©ããç°åã¯
åŽéäžã«å°ãªããšãïŒåã®ä»ã®äºéçµåãååšã
ãã ãšãã¬ã³åã³ãããã¬ã³ã®äžå å ±éååã¯å ±é
åã®ããã®å¥œãŸããäžæ¬¡è§Šåªç³»ã¯ãããžãŠã ãªã
ã·ã¯ãã©ã€ããåå¡©åãããžãŠã ããããžã³é žã¢
ã«ãã«ãããã«å¥œãŸããã¯ã¢ã«ãã«åºãïŒã12å
ã®ççŽ ååãæãããããžã³é žã¢ã«ãã«ãåã¯ã¢
ã«ãã«ã¯ããããããŒããããã«å¥œãŸããã¯ã¢ã«
ãã«åºãïŒã12åã®ççŽ ååãæããã¢ã«ãã«ã¯
ããããããŒããšã¢ã«ãã«ã¢ã«ãããŠã ãã©ã€
ããããã«å¥œãŸããã¯ïŒã12åã®ççŽ ååãæã
ãã¢ã«ãã«ã¢ã«ãããŠã ãã©ã€ããšã®çžäºäœçšã«
ãã€ãŠåœ¢æãããçåæ°ŽçŽ ã«å¯æº¶æ§ã®è§Šåªã§ã
ãããããã®å¥œãŸããå¯æº¶æ§è§Šåªç³»ã«ãããŠãã¢
ã«ãããŠã 察ãããžãŠã ã®ã°ã©ã ååæ¯ã¯å°ãªã
ãšãïŒïŒïŒã奜ãŸããã¯10ïŒïŒã§ããã20ïŒïŒã
35ïŒïŒåã³50ïŒïŒåã¯ãã以äžã®ãããªé«ãã°ã©
ã ååæ¯ãããç¹ã«ãããžãŠã ã®äœ¿çšéãå°ãªã
ãšãã«çšããããšãã§ãããæåŸã®ã±ãŒã¹ã«ãã
ãŠã200ïŒïŒã®æ¯ãäŒå³ããããšãã§ããããã
ãã®å¥œãŸããå¯æº¶æ§è§Šåªç³»ã¯éæ¶è³ªã®ããŽã ç¶
ã®ãç¡«é»å ç¡«æ§ã®é«çŽãŽã åæã圢æãããèœå
ãæã€ãŠããããã®å¯æº¶æ§è§Šåªçµæç©ã¯ãšãã¬ã³
âãããã¬ã³å ±éåäœã®ãããªãŽã çµæç©ã«å¯Ÿã
ãŠå¥œãŸããããã©ããä»ã®å Žåããšãããããã
ã¬ã³ã®åç¬éåã«ãããŠã¯ãäžæº¶æ§ã®ãåã¯äžå
質ã¿ã€ãã®è§Šåªã奜ãŸããã æ¬çºæã§çšãããã掻æ§å€ã®éã¯ç¹ã«èšççã§
ã¯ãªãããããžãŠã ã®ã¢ã«åœã0.01ã¢ã«ã®æŽ»æ§å€
ã®ãªãŒããŒã®å°éãããå Žåã«é¡èãªæŽ»æ§ãçã
ã®ã«ååã§ãããéåžžãè¥å¹²å€§éã®ãå žåœ¢çã«ã¯
ãããžãŠã ã®ã¢ã«åœãçŽïŒã¢ã«ãçŽ10ã¢ã«ã®æŽ»æ§
å€ãçšããã®ã奜ãŸãããææã«ãã€ãŠã¯ããã
ã«å€§éã®æŽ»æ§å€ãçšããããšãã§ãããç¹ã«ãã¢
ã«ãããŠã ååç©å¯ŸãããžãŠã ã®ã°ã©ã ååæ¯ã
50åã¯ãã以äžã®ãšãã¯ã50ã¢ã«åã¯ãã以äžã®
掻æ§å€ãçšããããšãã§ããããããã«ããŠãã
ææ©ã¢ã«ãããŠã ååç©ã®éãããå€ã掻æ§å€ã
å ããã®ã¯æ害ã§ãããã æ¬çºæã®éåæ¹æ³ã¯äžæŽ»æ§æº¶å€äžã§è¡ãããšã
ã§ãããããããªãããéåãããŠããéå°ã®å
éäœåã¯åéäœé¡ã¯æº¶å€ãšããŠäœçšããããšãã§
ããã®ã§ãæ·»å 溶å€ã¯äžè¬ã«æ¬è³ªçã§ãªããäžè¬
çã«ãã€ãŠãã€ãªã³é äœã¿ã€ãã®éåã«ãããŠçš
ããããéåžžã®æº¶å€ã䜿çšããããšãã§ãããã
ããã®æº¶å€ã«è³éŠæçåæ°ŽçŽ ãèèªæçåæ°ŽçŽ ã
ã¯ãããã³ãŒã³ãããã©ã¯ãããšãã¬ã³åã³è§Šåª
ãç Žå£ããªãä»ã®æº¶å€ããããéåã¯åžžæ³ã«ãã
ãããã«å®æœããããšãã§ãããäŸãã°ãâ20ã
200âã®éå枩床ãïŒã50æ°å§åã¯ãã以äžã®å§
åã0.001ãïŒã®ãããžãŠã å¯Ÿå ±è§Šåªã®ã¢ã«æ¯ã
溶液äžã§ïŒïŒïŒãïŒïŒ200ã®ãšãã¬ã³å¯Ÿãããã¬
ã³ã®åéäœã®ã¢ã«æ¯ãå žåœ¢çã§ããããããã¯é
å®æ¡ä»¶ã§ã¯ãªãã 次ã®å®æœäŸã¯æ¬çºæã®å®æœãããã«è©³çŽ°ã«èª¬æ
ããããã®ãã®ã§ããã觊åªã®å¹çã¯å šãŠã®å®æœ
äŸã§ãããžãŠã ååç©ã®ã°ã©ã åœãã®éåäœã®ã°
ã©ã ãšããŠèšç®ãããã å®æœäŸ ïŒ ãã«ããªã«ãããšãŒãã®åæ ãã®ãšã¹ãã«ã¯ãžã€ãŒãã« ãªã ã¢ã¡ãªã«ã³
ã±ãã«ã« ãœãµã€ãã€ãŒïŒJ.Am.Chem.Soc.ïŒ
66ã1230ïŒ1944ïŒã«é瀺ãããã€ãŒã»ã¢ãŒã«ã»ã
ãŒã«ã»ã³ïŒE.R.NielsenïŒã®æ¹æ³ã«åŸã€ãŠåæã
ãã ãšã¹ãã«ã¯ãšã¹ãã«ã®å10ïœã«å¯ŸããŠ20mlã®ãš
ãŒãã«ãš10mlã®ç³æ²¹ãšãŒãã«ããæãæ··å溶å€ã
ãã®äœæž©åçµæ¶ã«ãã€ãŠç²Ÿè£œãããåŸãããèç¹
29ã31.5âã®åºäœã¯90ïŒ ã®ååçã§åŸãããã å®æœäŸ ïŒ ããã©ã¯ããããã©ããããã«ããªã«ããã©ã¯
ããããã©ããããããšãŒãïŒZXUïŒã®åæ 0.25ã¢ã«ïŒ48ïœïŒã®ãã«ããªã«ãããšãŒãã®
750mlã®CCl4äžæº¶æ¶²ãçªçŽ ãµãå²æ°äžã§â15âã«
å·åŽããããã®æº¶æ¶²ã«â10âã«å·åŽãã500mlã®ã
å¡©çŽ 2Mã®CCl4溶液ãå ããããã®æ·»å ã¯æ¥éæ¹
æäžåã³çªçŽ ãµãå²æ°äžã§ã枩床ãïŒâ以äžã«ã¯
ãªããªãããã«ããé床ã§è¡ã€ããå¡©çŽ æº¶æ¶²ã®æ·»
å åŸããã®åå¿æ··åç©ãçªçŽ äžãâ10âã«ãããŠ
ïŒãïŒæéæ¹æãããæªåå¿ã®å¡©çŽ ã¯ãã®æº¶æ¶²ã«
çªçŽ ã®ãã€ããããæµããéãããããŠãã®æº¶æ¶²
ã宀枩ãŸã§ãã€ããå æž©ããããšã«ãã€ãŠé€å»ã
ããCCl4ã次ã«å転èžçºåšäžã§é§åºãããããŠ
æåŸã®çè·¡ã®CCl4ã¯ãã®åå¿æ··åç©ãé«ç空ã«
äžå€æé²ããããšã«ãã€ãŠé€å»ããããã®æç¹ã§
åŸãããç²çš ãªã·ãããã¯å®å šã«ç¡è²ã§ãå åã³
湿åããä¿è·ãããšãã¯é·æéã«ããã€ãŠç¡è²ã®
ãŸãã§ãã€ãã N.M.R.ã¯æ¬¡ã®æ§é ãšäžèŽãããN.M.R.ã¹ãã¯ãã«ã¯äºæãããã
ã«ïŒïŒïŒã®ããŠã³ãã€ãŒã«ã匷床æ¯ãæããŠã
ããå¯èœãªåçš®ç°æ§äœã¯è€éãªã¹ãã¯ãã«ãäžã
ããšäºæ³ãããããå®éã«ãã®ãããªã¹ãã¯ãã«
ãåŸããããå çŽ åæãææ¡ãããæ§é ãšäžèŽã
ãã20âã«ãããå±æçã¯ïŒã5334ã§ãã€ãã å çŽ åæïŒC10H8Cl8O4 èšç®å€ 枬å®å€ ïŒ£ïŒ 25.24 23.82 ïŒšïŒ 1.69 1.70 ClïŒ 59.61 59.72 ZXUã®æ¯æ§è©Šéšã¯æ¬¡ã®éãã§ãã€ãã æ¥æ§çµå£âLD50ïŒ1.1±0.15ïœïŒKgâäœéïŒã©ã
ãïŒ äžæ¬¡ç®èåºæ¿ïŒå®¶ãããã®ç®èã«å¯ŸããŠäžçšåºŠã®
åºæ¿ ç®ã«å¯Ÿããåºæ¿ïŒå°å ¥ïŒç§åŸã«ãã®ç©è³ªãæŽå»ã
ããšã軜ãåºæ¿ãæŽå»ãªãã§ãã®ãŸãæ®ã€ãŠã
ãå Žåã¯æ¿ããåºæ¿ ãšãŒã ãºè©ŠéšïŒAmes TestïŒã¯çªç¶å€ç°ã«å¯Ÿ
ããŠè² ã§ãã€ãã åœãåŸã泚æãåãã°ããã®ç©è³ªã¯çç£å·¥çšã§
䜿çšããããšãã§ããã å®æœäŸ ïŒ ããã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ããâïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããâïŒâãããšãŒã
ïŒUKUïŒã®åæ 500mlã®äžãå£äžžåºãã©ã¹ã³äžã§33.6ïœïŒ0.2ã¢
ã«ïŒã®èžçããã°ããã®æ°ããïŒâããã«ãããš
ãŒãã200mlã®ä¹Ÿç¥CCl4ã«æº¶è§£ããå€åŽã®æ°·âå¡©
济ã§ïŒâãŸã§å·åŽããã次ã«ããã®æº¶æ¶²ã«ïŒæé
ã«ããã€ãŠ0.4ã¢ã«ã®Cl2ã¬ã¹ããã€ããå°å ¥ãã
泡ç«ãŠããåå¿æ··åç©ããæªåå¿ã¬ã¹ãé€å»ãã
ããã«ããã®æ··åç©ã«ã宀枩ãŸã§å æž©ããªããã
ãã®æº¶æ¶²ãç¡è²ã«ãªããŸã§ä¹Ÿç¥çªçŽ ãéããã溶
å€ã®CCl4ãå転èžçºåšã§ããŠã¹ãããŠãŒã
ïŒhouse vaccumïŒäžãçŽ40âã«ãããŠé€å»ããã
åŸãããç²çš ãªæ¶²äœããã以äžç²Ÿè£œããããšãªã
ã«è§Šåªå掻æ§åå€ãšããŠäœ¿çšãããåçã¯ã»ãšã
ã©å®éçã§ãã€ãã å çŽ åæïŒC9H12Cl4O3 èšç®å€ 枬å®å€ïŒïŒåè¡ã€ãïŒ ïŒ£ïŒ 34.86 34.82 34.79 ïŒšïŒ 3.90 3.69 3.37 ClïŒ 45.75 43.68 43.57 N.M.RïŒååŠã·ãããšã¹ããªããã€ã³ã°ãã¿ãŒ
ã³ã¯æ¬¡ã®ææ¡ãããæ§é ã«äžèŽããã 97Hzã«ãããŠã¡ãã«åºïŒããã«åºããïŒïŒã
ãªãã¬ãããšããŠïŒ160Hzã«ãããŠäžå€®ã®âïŒâ
CH2ïŒ2âïŒãã«ããã¬ãããšããŠïŒïŒ427Hzã«ã
ããŠââCH2âïŒããªãã¬ãããšããŠïŒã487
Hzã«ãããŠïŒåã®ç°ã®ãå¡©çŽ ã«å¯ŸããŠÎ±âäœã®
æ°ŽçŽ ïŒãã«ããã¬ãããšããŠïŒïŒåã³630Hzã«ã
ããŠé žçŽ ã«å¯ŸããŠæ¬¡ã®éæ°ŽçŽ ã ãšãŒã ãºè©Šéšã¯çªç¶å€äœã«å¯ŸããŠè² ã§ãã€ãã å®æœäŸ ïŒ ã¡ãã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ããâïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããâïŒâãããšãŒãã®
åæ ãã®ååç©ã¯ãããã«ãããšãŒãã®ä»£ãã«ã¡ã
ã«ãããšãŒãã䜿çšããç¹ãé€ããŠå®æœäŸïŒã®æ¹
æ³ã«ãã€ãŠåæããã å çŽ åæïŒC6H6Cl4O3 èšç®å€ 枬å®å€ ïŒ£ïŒ 26.90 26.72 26.22 ïŒšïŒ 2.26 1.93 1.91 ClïŒ 52.93 57.89 57.90 å®æœäŸ ïŒ ãšãã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¯ããâïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããâïŒâãããšãŒã
ïŒTOUïŒã®åæ ãã®ååç©ã¯ããã«ãããšãŒãã®ä»£ãã«ãšãã«
ãããšãŒããçšããŠå®æœäŸïŒã®æ¹æ³ã«ãã€ãŠåæ
ããã å çŽ åæïŒC7H8Cl4O3 èšç®å€ 枬å®å€ ïŒ£ïŒ 29.82 29.43 29.23 ïŒšïŒ 2.84 2.35 2.27 ClïŒ 50.31 49.78 49.78 å®æœäŸ ïŒ ããã·ã«ïŒâãããšãŒãã®å¡©çŽ å ãã®ååç©ã¯å®æœäŸïŒã®æ¹æ³ã«ãã€ãŠãããã«
ãããšãŒãã®ä»£ãã«ããã·ã«ãããšãŒããçšããŠ
åæããã å çŽ åæïŒC11H15Cl5O3 èšç®å€ 枬å®å€ ïŒ£ïŒ 35.47 33.67 33.52 ïŒšïŒ 4.06 3.47 3.55 ClïŒ 47.59 45.81 45.80 å®æœäŸ ïŒ UKUãçšããŠã®ã±ã ã³ ãªã¢ã¯ã¿ãŒ
ïŒChemco ReactorïŒã«ããã掻æ§åå®éšïŒå®
æœäŸïŒãåç §ïŒ ïŒã®ãã¯ãããã°ã©ãã€ãŒïŒã¢ã«ããïŒã§ç²Ÿ
補ãã也ç¥ãããµã³ãïŒã¬ãã³ã®æŸæãªä¹Ÿç¥ã±ã
ã³ ãªã¢ã¯ã¿ãŒïŒãã«ãµãTulsaããOKã74135
ã®ã±ãã«ã« ã€ã¯ã€ããã¡ã³ã瀟ãChemical
Equipment Corporationãã®åæšïŒã«å ããã
ããã«å¿ èŠéã®25ïŒ ïŒ0.740MïŒãšãã«ã¢ã«ãã
ãŠã ã»ã¹ãã¯ãã©ã€ãïŒEASCïŒæº¶æ¶²ãå ããã
ãããã¬ã³ã0.2345MPaã®å¹³è¡¡å§ãŸã§ãæ°ŽçŽ ã
0.2483MPaãŸã§ããããŠãšãã¬ã³ã0.3448MPaã®
å šå§ãŸã§å ããããšããªãã³ãã«ããŒãã³
ïŒENBïŒã®è©ŠæïŒmlãå ãããããŠVOCl3溶液ã®
æ·»å ã«ãã€ãŠéåãéå§ãããã ïŒååŸã«ãå¿ èŠéã®1M UKU溶液ã«å ãã掻
æ§åãè¡ã€ããïŒæéã«ãããªãããã¬ã³ã°ãªã³
ãŒã«ã«ããéåãè¿ éåæ¢ããããããŠéåäœã
é žåé²æ¢å€ãå«æããã€ãœãããããŒã«ã«ããå
éã«ãã€ãŠååãããéåäœã次ã«æ°ããã€ãœã
ããããŒã«ïŒé žåé²æ¢å€ãå«ãïŒãå ¥ã€ãŠããã¯
ãŒã€ã³ã° ãã¬ã³ããŒïŒWaring blenderïŒïŒã€ãŒ
ã¹ã ããŒãããªãŒããEast HartfordããCt.ã®
ã¯ãŒã€ã³ã° ãããã¯ã瀟ãWaring Productsã
ã®åæšïŒäžã§åæãã次ãã§ä¹Ÿç¥ããã 第ïŒè¡šã«ç€ºãããçµæã¯ãè¯å¥œãªæŽ»æ§åãéæ
ãããå¹çã¯æãäœãå Žåã§635ãã1177ãŸã§å¢
å ãããŸãæãé«ãå Žåã§2331ãŸã§å¢å ããããš
ã瀺ããŠããããã®éåã§ã¯ãUKUã®æ¿åºŠãå¢
å ãããšãšãã«ååéãäžããéåžžã«é¡èãªåŸå
ããã€ããäŸãã°ãå®éšçªå·ïŒ¡ïŒãã©ã³ã¯ïŒã®ç
æç©ã®ç²åºŠãå®éšçªå·ïŒ¢åã³ïŒ£ã®çæç©ã®ç²åºŠãš
æ¯èŒããããã ãè¡šã (a) ãšãã«ã¢ã«ãããŠã ã»ã¹ãã¯ãã©ã€ã
(b) ã€ãœãããããŒã«
(c) ããã©ãªã³äžã135âã«ããã極éç²åºŠ
(d) 100âã§4ååŸã®ã ãŒããŒç²åºŠ
(e) ã°ã©ã ååâã¢ã«ãããŠã ïŒã°ã©ã ååâã
ããžãŠã
å®æœäŸ ïŒ ZXUã掻æ§å€ãšããŠäœ¿çšãã掻æ§åã®ç 究 UKUã®ç 究ã§äœ¿çšããæ¡ä»¶ãçšããŠå®éšãè¡
ã€ãããã ãã掻æ§å€ã¯Et3Al2Cl3ã®æ·»å åŸåã³
éåãéå§ããåã«å ããã第衚ã«ç€ºãããçµ
æããã掻æ§åã¯èŠ³å¯ãããããååé調æŽã¯å š
ã芳å¯ãããªãããã®ãããé«ååéãæãã
ãããããè¯å¥œãªæŽ»æ§åãéæããããšãæããš
ãã¯ãZYUãUKU以äžã«å¥œãŸããã ãè¡šã å®æœäŸ ïŒ ZXUã«ããEPMã®éåã«ããããããžã³é žã
ãã«ãšEt3Al2Cl3ããã®äºåæ··å觊åªïŒäžæŽ»æ§ïŒ
ã®æŽ»æ§å å°ããç·è²ã®ãœãŒãã³ãïŒæž æµã«ãã110âã®
çäžã§ä¹Ÿç¥ãããããŠçªçŽ ãµãå²æ°äžã§å·åŽã
ãïŒã«93.5mlã®ä¹Ÿç¥ãããµã³ãš1.1mlã®0.353Mã
ããžã³é žããã«æº¶æ¶²ãå ããããã®ã³ãã«ãŽã ã®
éèãå«ãïŒãç©Žã®ãã€ããã§ãµããããã5.4
mlã®25ïŒ EASCïŒ0.740MïŒã®æ·»å ã¯ãããžãŠã
0.004Måã³EASC0.04MïŒAlïŒïŒ¶ïŒ20ïŒïŒïŒã®äº
åæ··å觊åªæº¶æ¶²ãäžããã 也ç¥ããïŒã®äžãå£ãã©ã¹ã³ã«ããã®ãã©ã¹
ã³ã«å ããããã¹ã液äœã®ã¬ãã«ããäžã«å»¶åšã
äœçœ®ãããã¬ã¹å°å ¥ç®¡ã枩床èšãæ¹æèšãåã³å°
éã®é±æ²¹ãå ¥ã€ãŠããã¬ã¹æŽæµã³ãã«æ¥ç¶ããã
éæµå·åŽåšãåãä»ããããã®ãã©ã¹ã³ã«400ml
ã®ä¹Ÿç¥ãããµã³ãçªçŽ ãµãå²æ°äžã«ãããŠæºã
ãããã®æº¶æ¶²ã«æ¬¡ã«ãšãã¬ã³ãšãããã¬ã³ã®ïŒïŒ
ïŒäŸçµŠåæã15åé飜åããããïŒååŸã«ïŒmlã®
25ïŒ EASCãå ãã也ç¥ç³»ãä¿èšŒããã10ååŸã«
ïŒmlã®åèšäºåæ··å觊åªïŒ0.02ããªã¢ã«ã®ïŒ¶ãš
0.4ããªã¢ã«ã®AlãæããïŒãå ãããçºç±ã¯èŠ³
å¯ããããéåã¯èµ·ããªãã€ãã15ååŸã«ïŒmlã®
0.05ã¢ã«UKUãå ããããã®æº¶æ¶²ã¯çŽã¡ã«ææž©
ãå§ãïŒæŽ»æ§ãªéå觊åªã§ããããšã瀺ãïŒãã
ããŠïŒååŸã«ãã®æž©åºŠã¯19âãã28âã«è³ã€ãã äžèšã®æäœãè¡ã€ãŠå¥ã®äºåæ··å觊åªã調補
ãããããŠåéäœã®ååšäžã§ZXUåã¯UKUã®ã
ãããã§åŠçãããçµæã第衚ã«ç€ºããããã
ããé©ãã¹ãããšã«ããžã€ãœããã«ã¢ã«ãããŠã
ã¯ãã©ã€ãïŒDIBACïŒâVOCl3ã¯å掻æ§åããã
ãšãã§ããããåã«æããã«ããããã«ãä»ã®é ž
åå€ã¯çŽãžãã©ã€ãåã¯çŽãããã©ã€ãïŒã¢ã«ã
ã«ã¢ã«ãããŠã æåïŒã®ãããããã調補ããäº
åæ··å觊åªã掻æ§åããªãã€ãã ãè¡šã (b) ã°ã©ã ååâã¢ã«ãããŠã ïŒã°ã©ã ååâãã
ãžãŠã
å®æœäŸ 10 ããã©ã¯ããããã©ãããããé žã®ãšã¹ãã«ã
䜿çšããã±ã ã³ ãªã¢ã¯ã¿ãŒã®å®éšã®ä»ã®äŸã以
äžã®ç¬¬è¡šã«ç€ºããå®æœäŸïŒã§çšããã®ãšåãå
å¿æ¡ä»¶ãçšããããã ããEASCåã³VOCl3ã®ã¢
ã«éã䞊ã³ã«æŽ»æ§å€ã®ã¿ã€ãåã³éã¯å€ããã ãè¡šã ãè¡šã å®æœäŸ 11 ïŒïŒ2â²âãªãã·âãã¹ããšãã¬ã³ïŒïŒâãããš
ãŒãïŒãïŒJMUïŒã®å¡©çŽ å é žçŽ åã¯æ¹¿åã®å°å ¥ãé²ãããããã®å šæäœã¯
çªçŽ ãµãå²æ°äžã§è¡ã€ããæ©æ¢°çæ¹ææ©ã枩床
èšã滎äžæŒæåã³ç°æµå·åŽåšãåããïŒã®äžã
å£ãã©ã¹ã³ãå§å解æŸæ段ãæã€ïŒå§åãã»ã倧
æ°å§ã«ä¿ã€ããïŒçªçŽ ç³»ã«æ¥ç¶ããããã«750.0
mlã®ç²Ÿè£œã也ç¥ããåå¡©åççŽ ãš42.2ïœã®JMU
ïŒ0.143ã¢ã«ïŒãå ããããã®æº¶æ¶²ãâ10âã«å·åŽ
ãããJMUã¯çŽ°ããæ²æ®¿ãšããŠæº¶æ¶²ããæåºã
ãããã®æ··åç©ã«500mlã®å¡©çŽ 1.5Mã®CCl4溶液ã
å ãããã枩床äžæã¯èªããããªãã€ãããã®æ··
åç©ãïŒæéã«ããã€ãŠ20âãŸã§å æž©ããããã®
æ··åç©ã次ã«â15âã«åå·åŽãããæ²æ®¿ã®åœ¢æã¯
ãªããåå¿ã¯æããã«èµ·ããããã®åå¿æ··åç©ã
次ã«16æéæ¹æãã次ãã§å®€æž©ãŸã§ãã€ãå æž©ã
ïŒN2ãµãå²æ°äžïŒãåå¿ãå®çµãããã16æéåŸã
ãã®è²ã¯ã»ãšãã©æ¶ãããããã¯æ¯èŒçå°éã®å¡©
çŽ ããæ®çããŠããªãããšã瀺ããŠããããã®æº¶
液ã«N2ãéããŠæ³¡ç«ãŠãæ®çCl2ãæé€ããã
CCl4ã¯å転èžçºåšã®äœ¿çšã«ãã€ãŠé€å»ãããåŸ
ãããç©è³ªãCCl4ã®æåŸã®çè·¡ããé«ç空ã«æŽ
è·¯ããããšã«ãã€ãŠåé¢ããã10åã®å¡©çŽ ååã
çµåããŠæããååç©ã®åéã¯94ïœïŒåç100ïŒ ïŒ
ã§ãã€ãã å çŽ åæïŒC14H12Cl10O7ïŒMQWïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 26.00 26.54 26.68 ïŒšïŒ 1.87 2.05 2.05 ClïŒ 54.81 50.77 51.01 TLCã¯ïŒã€ã®ãã³ãã瀺ããããã¯ïŒçš®ã®å¥
åã®ç°æ§äœã瀺ããŠããã å®æœäŸ 12 ãããã¬ã³ ãã¹ïŒïŒâãããšãŒãïŒã®å¡©çŽ å 0.117ã¢ã«ã®ãããã¬ã³ãã¹ïŒïŒâãããšãŒãïŒ
ãš0.68ã¢ã«ã®å¡©çŽ ãçšããŠå®æœäŸ11ã®æ¹æ³ãè¡ã€
ããåéã¯ããžãããšãŒãã®ã¢ã«åœã4.5ã¢ã«ã®
Clã®ä»å ã«åºã¥ããŠã65.5ïœïŒåçïŒ96.1ïŒ ïŒã§
ãã€ãã å çŽ åæïŒC13H11Cl9O6ïŒïŒ¡âïŒïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 26.81 26.54 26.68 ïŒšïŒ 1.90 2.05 2.05 ClïŒ 54.80 53.76 53.80 20âã«ãããå±æçã¯1.5208ã§ãã€ãã å®æœäŸ 13 ïŒïŒ2â²âãªãã·âãã¹ïŒãããã¬ã³âïŒâãã
ãšãŒãïŒã®å¡©çŽ å 32ïœïŒ0.1ã¢ã«ïŒã®ïŒïŒ2â²âãªãã·âãã¹ãã
ããã¬ã³ïŒïŒâãããšãŒãïŒããš0.69ã¢ã«ã®å¡©çŽ
ãçšããŠå®æœäŸ11ã®æ¹æ³ãè¡ã€ããåéã¯76.5ïœ
ã§ãã€ããC16H15Cl11O7ã«åºã¥ããŠããã®åçã¯
100ïŒ ïŒåºçºç©è³ªã®ééã«åºã¥ããŠïŒã§ãã€ãã å çŽ åæïŒC16H15Cl11O7ïŒïŒ¡âïŒïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 27.09 25.94 26.12 ïŒšïŒ 2.13 2.25 2.21 ClïŒ 54.98 53.73 53.60 å®æœäŸ 14 ãšãã¬ã³ãã¹ïŒïŒâãããšãŒãïŒã®å¡©çŽ å 0.15ã¢ã«ã®ãšãã¬ã³ãã¹ïŒïŒâãããšãŒãïŒãš
0.640ã¢ã«ã®Cl2ãçšããŠå®æœäŸ11ã®æ¹æ³ãè¡ã€
ããããããªããããã®ãžãããšãŒãã¯CCl4ã«
ã¯äžæº¶ã§ãããããCCl4ã®ä»£ãã«750mlã®å¡©åã¡
ãã¬ã³ãçšãããå·åŽãããšããžãããšãŒãã现
ããç²æ«ãšããŠæ²æŸ±ãããããã¯å¡©çŽ åãããã
ã®ã§ãã€ããå çŽ åæã¯ããã®ãžãããšãŒãã¯æ
äœãšããŠæåŸ ãããïŒåã®å¡©çŽ ååãä»å ãããª
ãã€ãããšã瀺ããŠããã å çŽ åæïŒC12H10Cl8O6ïŒïŒ¡âïŒïŒ èšç®å€ 枬å®å€ ïŒ£ïŒ 27.00 30.30 30.19 ïŒšïŒ 1.89 1.92 2.04 ClïŒ 53.13 44.35 44.50 å®æœäŸ 15 觊åªæ··åç©ãåå¿ã®å Žã§èª¿è£œããç¹ãé€ããŠã
第衚ã«èšèŒã®æŽ»æ§å€ãå®æœäŸïŒã®æ¡ä»¶ãçšããŠ
è©Šéšããããã©ã³ã¯ïŒå®éšïŒ§ïŒãšã®æ¯èŒã¯ããã
ãååç©ã¯å šãŠæŽ»æ§å€ãšããŠäœçšããããè¥å¹²ã®
ååç©ã¯çæéåäœã®ååé調æŽå€ãšããŠè¯å¥œã§
ã¯ãªãããšã瀺ããŠããã ãè¡šã å®æœäŸ 16 ãã¹ïŒããªã¯ããã¡ãã«ïŒã¹ã«ãã³ãã¢ã¡ãªã«
åœç¹èš±ç¬¬3304331å·æ现æžïŒC.A.66 104691eïŒ
ã«é瀺ããããã€ãŒã«ãº ãž ãµã³ãïŒCharles
Di SontoïŒã®æ¹æ³ã«ãããžã¡ãã«ã¹ã«ããã·ã
ã®å¡©çŽ åã«ãã€ãŠåæããã 掻æ§åã®å®éšã¯ãã¹ïŒããªã¯ããã¡ãã«ïŒã¹ã«
ãã³ïŒCYUïŒãUKUã®ä»£ããã«çšããç¹ãé€ã
ãŠå®æœäŸïŒã®æ¹æ³ã«ãã€ãŠè¡ã€ãã ãè¡šã ãè¡šã ãè¡šã ãè¡šã ãè¡šã ãè¡šã ãè¡šã
第ïŒå³ã¯äžæ¬¡è§Šåªç³»ã®èª¿æŽå·¥çšã瀺ããããŒã
ã€ãŒãã®äžäŸã§ããã
ã€ãŒãã®äžäŸã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžæ¬¡è§Šåªç³»ããããžãŠã ååç©åã³åŒ
RMgXãLiAlR4åã¯RAAl2XBïŒåŒäžãã¯ïŒã12
åã®ççŽ ååãæããçåæ°ŽçŽ åºã§ãããã¯ã
ãã²ã³ååã§ãããã¯ïŒãïŒã®æ°ã§ããããã
ãŠïŒ¢ã¯ïŒãïŒã®æ°ã§ããããã ãããšïŒ¢ã®åã¯
ïŒã§ãããïŒã®ææ©éå±ååç©ïŒãã ãããããž
ãŠã ååç©ããåã¯ææ©éå±ååç©ã®ããããã«
çµåããŠããåºã®å°ãªããšãïŒåã¯ããã²ã³åå
ã§ããïŒããæãããããŠæŽ»æ§å€ãå¡©çŽ åããã©
ããããã«ããªã«ããã©ããããããšãŒããå¡©çŽ
åããã©ãããããé žã®ã¢ã«ãã«ãšã¹ãã«ïŒãã
ããã¢ã«ãã«åºã¯ïŒãïŒåã®ççŽ ååãæããïŒã
å¡©çŽ åã¢ã«ãã¬ã³ãã¹âããã©ããããããšãŒã
ïŒãã ããã¢ã«ãã¬ã³åºã¯ïŒååã¯ïŒåã®ççŽ å
åãæããïŒãå¡©çŽ åãªãã·âãã¹ãã¢ã«ãã¬ã³
ïŒïŒâãããšãŒãïŒãïŒãã ããã¢ã«ãã¬ã³åºã¯ãš
ã¿ã³ãžã€ã«ãïŒïŒïŒâãããã³ãžã€ã«ãã¢ã«ãã«
眮æãšã¿ã³ãžã€ã«åã¯ã¢ã«ãã«çœ®æïŒïŒïŒâãã
ãã³ãžã€ã«âãã ãããšã¿ã³ãžã€ã«åã¯ïŒïŒïŒâ
ãããã³ãžã€ã«äžã®ã¢ã«ãã«åºã¯ïŒãïŒåã®ççŽ
ååãæããâã§ããïŒåã¯ãã¹ïŒããªã¯ããã¡
ãã«ïŒã¹ã«ãã³ã§ãããäžæ¬¡è§Šåªç³»ãšæŽ»æ§å€ãšã®
çµã¿åãããæãããšãç¹åŸŽãšãããαâãªã¬ã
ã€ã³éåçšè§Šåªçµæç©ã ïŒ äžæ¬¡è§Šåªç³»ããããžãŠã ååç©åã³RAAl2XB
ïŒåŒäžãã¯ïŒã12åã®ççŽ ååãæããçåæ°Ž
çŽ åºã§ãããã¯ããã²ã³ååã§ãããã¯ïŒã
ïŒã®æ°ã§ããããããŠïŒ¢ã¯ïŒãïŒã®æ°ã§ãããã
ã ãããšïŒ¢ã®åã¯ïŒã§ãããïŒã®ææ©éå±åå
ç©ïŒãã ãããããžãŠã ååç©ããåã¯ææ©éå±
ååç©ã®ããããã«çµåããŠããåºã®å°ãªããšã
ïŒåã¯ããã²ã³ååã§ããïŒããæãããããŠæŽ»
æ§å€ãå¡©çŽ åããã©ããããã«ããªã«ããã©ãã
ããããšãŒããå¡©çŽ åããã©ãããããé žã®ã¢ã«
ãã«ãšã¹ãã«ïŒãã ããã¢ã«ãã«åºã¯ïŒãïŒåã®
ççŽ ååãæããïŒãå¡©çŽ åã¢ã«ãã¬ã³ãã¹âã
ãã©ããããããšãŒãïŒãã ããã¢ã«ãã¬ã³åºã¯
ïŒãïŒåã®ççŽ ååãæããïŒãå¡©çŽ åãªãã·â
ãã¹ãã¢ã«ãã¬ã³ïŒïŒâãããšãŒãïŒãïŒãã ãã
ã¢ã«ãã¬ã³åºã¯ãšã¿ã³ãžã€ã«ãïŒïŒïŒâãããã³
ãžã€ã«ãã¢ã«ãã«çœ®æãšã¿ã³ãžã€ã«åã¯ã¢ã«ãã«
眮æïŒïŒïŒâãããã³ãžã€ã«âãã ãããšã¿ã³ãž
ã€ã«åã¯ïŒïŒïŒâãããã³ãžã€ã«äžã®ã¢ã«ãã«åº
ã¯ïŒãïŒåã®ççŽ ååãæããâã§ããïŒåã¯ã
ã¹ïŒããªã¯ããã¡ãã«ïŒã¹ã«ãã³ã§ãããäžæ¬¡è§Š
åªç³»ãšæŽ»æ§å€ã®çµã¿åãããæãããšãç¹åŸŽãšã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®Î±âãªã¬ãã€ã³é
åçšè§Šåªçµæç©ã ïŒ æŽ»æ§å€ãããã©ã¯ããããã©ããããã«ããª
ã«ããã©ã¯ããããã©ããããããšãŒããããã©
ã¯ããããã©ãããããé žã®ã¢ã«ãã«ãšã¹ãã«ã
ã¢ã«ãã¬ã³ãã¹âããã©ã¯ããããã©ããããã
ãšãŒãããªãã·âãã¹ãã¢ã«ãã¬ã³ïŒããã©ã¯ã
ãããã©ãããïŒâãããšãŒãïŒãåã¯ãã¹ïŒã
ãªã¯ããã¡ãã«ïŒã¹ã«ãã³ã§ããåèšç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒ ãããžãŠã ååç©ããã©ã€ãããªãã·ãã©ã€
ããã¢ã«ã³ãã·ãåã¯ã¢ã»ãã«ã¢ã»ãããŒãã§ã
ãåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®
çµæç©ã ïŒ ãããžãŠã ååç©ãäžå¡©åãããžãŠã ãåå¡©
åãããžãŠã ãåèåãããžãŠã ããªãã·äžå¡©å
ãããžãŠã ããããžã³é žã¢ã«ãã«ããããžã«ã¢ã»
ãã«ã¢ã»ãããŒãããããžãŠã ã¢ã»ãã«ã¢ã»ãã
ãŒãåã¯ããããããŒãã§ããåèšç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒ ææ©ã¢ã«ãããŠã ååç©ãåŒRAAl2XBãæã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®çµæ
ç©ã ïŒ RAAl2XBããšãã«ã¢ã«ãããŠã ã»ã¹ãã¯ãã©
ã€ãããžã€ãœããã«ã¢ã«ãããŠã ã¯ãã©ã€ãããš
ãã«ã¢ã«ãããŠã ãžãããã€ããããªâïœâãã
ã·ã«âã¢ã«ãããŠã ããžãšãã«ã¢ã«ãããŠã ã¢ã€
ãªãã€ããããªãã·ã«ã¢ã«ãããŠã åã¯ã¡ãã«ã¢
ã«ãããŠã ã»ã¹ãã¯ãã©ã€ãã§ããåèšç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒ åŒLiAlR4ãæããååç©ããªããŠã ããã©
ã¢ã«ãã«ã¢ã«ãããŒãïŒïŒâïŒã§ããåèšç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒ ãªããŠã ããã©ã¢ã«ãã«ã¢ã«ãããŒãããã
ã©ãšãã«ã¢ã«ãããŒããããã©ããã«ã¢ã«ãããŒ
ãåã¯ããã©ããã·ã«ã¢ã«ãããŒãã§ããåèšç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒïŒ åŒRMgXã®ååç©ããã·ã«ãã°ãã·ãŠã
ã¢ã€ãªãã€ãããã·ã«ãã°ãã·ãŠã ã¯ãã©ã€ãå
ã¯ããã·ã«ãã°ãã·ãŠã ãããã€ãã§ããåèšç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒïŒ 掻æ§å€ãå¡©çŽ åãšãã¬ã³âãã¹âïŒïŒâã
ããšãŒãïŒãå¡©çŽ åãããã¬ã³âãã¹âïŒïŒâãã
ãšãŒãïŒãå¡©çŽ åãªãã·âãã¹ããšãã¬ã³ïŒïŒâ
ãããšãŒãïŒããå¡©çŽ åãªãã·âãã¹ããããã¬ã³
ïŒïŒâãããšãŒãïŒããè¥ããã¯ããã©ã¯ãããã
ã©ãããããé žã®ã¡ãã«ããšãã«ãããã«ããã
ã·ã«ããªã¯ãã«ãã€ãœãããã«ãsecâããã«å
ã¯tertâããã«ãšã¹ãã«ãåã¯ããã©ã¯ãããã
ã©ããããã«ããªã«ããã©ã¯ããããã©ãããã
ããšãŒãã§ããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬
ïŒé ã«èšèŒã®çµæç©ã ïŒïŒ 掻æ§å€ãããã«ããã©ã¯ããããã©ããã
ããããŒãåã¯ããã©ã¯ããããã©ããããã«ã
ãªã«ããã©ã¯ããããã©ããããããšãŒãã§ãã
åèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé ã«èšèŒã®çµæç©ã ïŒïŒ äžæ¬¡è§Šåªç³»ãã¢ã«ãã«ã¢ã«ãããŠã ãã©ã€
ããšãããžãŠã ãªãã·ã¯ãã©ã€ãããããžãŠã ã
ãã©ã¯ãã©ã€ããã¢ã«ãã«ããããŒãåã¯ã¢ã«ã
ã«âã¯ããããããŒããšã®çžäºäœçšã«ãã€ãŠåœ¢æ
ãããçåæ°ŽçŽ å¯æº¶æ§è§Šåªã§ããåèšç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒïŒ ã¢ã«ãããŠã 察ãããžãŠã ã®ã°ã©ã ååæ¯
ãå°ãªããšãïŒïŒïŒã§ããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé ã«èšèŒã®çµæç©ã ïŒïŒ ã¢ã«ãããŠã 察ãããžãŠã ã®ã°ã©ã ååæ¯
ãå°ãªããšã10ïŒïŒã§ããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé ã«èšèŒã®çµæç©ã ïŒïŒ ãããžãŠã ã®ã¢ã«åœããå°ãªããšã0.01ã¢
ã«ã®æŽ»æ§å€ãååšããŠããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒïŒ ãããžãŠã ã®ã¢ã«åœããå°ãªããšãïŒã¢ã«
ã®æŽ»æ§å€ãååšããŠããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é åã¯ç¬¬ïŒé ã«èšèŒã®çµæç©ã ïŒïŒ ãããžãŠã ã®ã¢ã«åœããïŒã10ã¢ã«ã®æŽ»æ§
å€ãååšããŠããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé ã«
èšèŒã®çµæç©ã ïŒïŒ ãšã¿ã³ãžã€ã«äžã«ããã¢ã«ãã«åºãïŒãïŒ
åã®ççŽ ååãæããŠããåèšç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé åã¯ç¬¬ïŒé ã«èšèŒã®çµæç©ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/152,900 US4347159A (en) | 1980-05-23 | 1980-05-23 | Activators for Ziegler type polymerization catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5712004A JPS5712004A (en) | 1982-01-21 |
| JPH0157685B2 true JPH0157685B2 (ja) | 1989-12-07 |
Family
ID=22544932
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7788081A Granted JPS5712004A (en) | 1980-05-23 | 1981-05-22 | Catalyst composition and alpha-olefin polymerization |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4347159A (ja) |
| EP (1) | EP0040889B1 (ja) |
| JP (1) | JPS5712004A (ja) |
| BR (1) | BR8103025A (ja) |
| CA (1) | CA1147717A (ja) |
| DE (1) | DE3163847D1 (ja) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5527951A (en) * | 1982-12-14 | 1996-06-18 | Uniroyal Chemical Company, Inc. | Polymerization catalyst and process |
| EP0134079B1 (en) * | 1983-08-31 | 1990-08-29 | UNIROYAL CHEMICAL COMPANY, Inc. | Process for preparing poly alpha olefins |
| NL9101536A (nl) * | 1991-09-11 | 1993-04-01 | Dsm Nv | Katalysator en werkwijze voor de bereiding van een amorf copolymeer van etheen. |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3026311A (en) * | 1959-08-14 | 1962-03-20 | Eastman Kodak Co | Olefin polymerization using catalysts containing organic sulfur compounds |
| US3203940A (en) * | 1962-10-04 | 1965-08-31 | Hercules Powder Co Ltd | Olefin copolymerization process |
| US3337518A (en) * | 1964-01-24 | 1967-08-22 | Exxon Research Engineering Co | Polymerization initiators consisting of halogenated sulfur containing organic compounds having at least one s(o)n functional group |
| DE1299874B (de) * | 1964-02-21 | 1969-07-24 | Huels Chemische Werke Ag | Verfahren zur Herstellung von mit Schwefel vulkanisierbaren, elastomeren Copolymerisaten aus AEthylen, Propylen und Trienen |
| US3629212A (en) * | 1965-05-08 | 1971-12-21 | Huels Chemische Werke Ag | Reactivation of ziegler-type catalysts |
| US3845159A (en) * | 1971-04-15 | 1974-10-29 | Du Pont | Tetrapolymer of ethylene/c3-c12 alpha-monoolefin/maleic anhydride/c6-c22 nonconjugated diene |
| NL7606508A (nl) * | 1975-06-16 | 1976-12-20 | Ici Ltd | Katalysatoren voor de polymerisatie van olefinen en werkwijze voor de bereiding daarvan. |
| US4168358A (en) * | 1976-07-05 | 1979-09-18 | Sumitomo Chemical Company Limited | Method for producing olefin polymers |
-
1980
- 1980-05-23 US US06/152,900 patent/US4347159A/en not_active Expired - Lifetime
- 1980-08-20 CA CA000358680A patent/CA1147717A/en not_active Expired
-
1981
- 1981-05-15 BR BR8103025A patent/BR8103025A/pt unknown
- 1981-05-22 DE DE8181200559T patent/DE3163847D1/de not_active Expired
- 1981-05-22 EP EP81200559A patent/EP0040889B1/en not_active Expired
- 1981-05-22 JP JP7788081A patent/JPS5712004A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0040889B1 (en) | 1984-05-30 |
| US4347159A (en) | 1982-08-31 |
| EP0040889A1 (en) | 1981-12-02 |
| JPS5712004A (en) | 1982-01-21 |
| DE3163847D1 (en) | 1984-07-05 |
| BR8103025A (pt) | 1982-02-09 |
| CA1147717A (en) | 1983-06-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4871523A (en) | Vanadium tetrachloride stabilization | |
| JP5490760B2 (ja) | 賊掻ããããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã ã䜿çšããããã«ãŽã ã®æ¹è¯ããã補é æ³ | |
| US3629212A (en) | Reactivation of ziegler-type catalysts | |
| EP0516743B1 (en) | Transition metal catalyst composition for olefin polymerization | |
| KR101942989B1 (ko) | ìížë ê³µì€í©ì²Žì ì ì¡° ë°©ë² | |
| WO2006009942A1 (en) | Polymerization process | |
| WO2006083303A1 (en) | Polymerization process | |
| JP2018510244A (ja) | äœã¬ãã«ã®é·éåå²ãæããé«ååéãšãã¬ã³ïŒÎ±âãªã¬ãã£ã³ïŒéå ±åœ¹ã€ã³ã¿ãŒããªããŒã®çææ¹æ³ | |
| WO2006002132A2 (en) | Olefin polymerization process | |
| EP0901457B1 (en) | Polymerization catalyst promoter | |
| US3674755A (en) | Process for copolymerizing alpha-monoolefins with or without a polyene,using catalyst comprising organoaluminum compound and vanadyl compound containing cyclic hydrocarbon group | |
| EP0040889B1 (en) | Activators for ziegler type polymerization catalysts | |
| US3655583A (en) | Vanadye compound having cyclic hydrocarbon substituent and polymerization catalyst containing said compound | |
| US5527951A (en) | Polymerization catalyst and process | |
| US4451575A (en) | Activators for Ziegler type polymerization catalysts using bis(trichloromethyl) sulfone | |
| JPS5946525B2 (ja) | å ±éåäœããã³ãã®è£œé æ¹æ³ | |
| US3595843A (en) | Vanadium coordination catalysts | |
| JPS6037124B2 (ja) | ãªã¬ãã€ã³é¡ã®éåæ¹æ³ | |
| EP0134080B2 (en) | Catalyst for alpha-olefin polymerization | |
| US3725444A (en) | Vanadium organometallic compounds and polymerization catalysts thereof | |
| US3849517A (en) | Tetrapolymer-terpolymer blends | |
| US3562228A (en) | Copolymerization of olefins | |
| JPH11322834A (ja) | ãªã¬ãã£ã³éåæ¹æ³ããã³ããçšã®è§Šåªç³» | |
| KR100463644B1 (ko) | ì€í©ë°ììŽë§€ìŽì§ì | |
| KR20260015988A (ko) | ì©ì¡ ìŽë§€ê³ ë° ìŽì ì©ë |