JPH0159120B2 - - Google Patents

Description

[Detailed description of the invention]

The present invention relates to an improvement in heat-sensitive recording paper whose main components are a colorless or light-colored organic dye generally called a leuco compound and an organic acid such as a phenol compound that develops a color by reacting with the leuco compound. More specifically, in the heat-sensitive recording paper containing the above-mentioned two-component color-forming reactive substance, tribenzylamine (existing chemical substance name number 3-353) is used as a color-forming accelerator.
The present invention relates to a novel heat-sensitive recording paper characterized in that the color development characteristics and storage stability of the heat-sensitive recording paper are improved by incorporating the present invention into the recording layer. A thermosensitive recording paper containing a leuco compound and an organic acid is already known, for example, from Japanese Patent Publication No. 14039/1983. This recording paper is based on the principle that thermal energy is applied to the recording layer to soften or melt the leuco compound, organic acid, and binder, and the two coloring components are brought into contact to cause a coloring reaction. It is used in fields such as Although the recording characteristics of the recording paper differ depending on the use, for example, in order to increase the recording speed, it is necessary to improve the recording apparatus and to promote the color development of the recording paper itself. A commonly used method for promoting color development is to include a low melting point substance in the recording layer. As low melting point substances, i.e. color accelerators or sensitizers, urea, phthalic anhydride,
Acetonitride, paraffin wax, carnauba wax, beeswax, wood wax, higher fatty acids, and higher fatty acid esters are used in JP-A-48-19231, and salicylic acid, anisic acid, and
Phthalic acid monophenyl ester, phthalic acid monobenzyl ester, and fatty acid amide have recently been widely used as color accelerators. Specifically, Japanese Patent Publication No. 51-27599 describes the sensitizing effect of fatty acid amide by combining paraffin or microwax with fatty acid amide.
No. 139740 also describes the sensitizing effect of fatty acid amides such as stearamide and oleic acid amide, and is well known. The present inventors confirmed the effects of these known color accelerators, and investigated at least 180 types of substances in order to find substances with even better properties.
After extensive and deep research, we succeeded in discovering tribenzylamine as a new color accelerator. This substance is excellent in the effect of promoting oscillation, and also has other properties as a thermal recording paper, such as background density, background fogging after storage, and discoloration, which do not pose any practical problems. I was able to confirm that there was. The content of tribenzylamine is 1 to 30% by weight of the total solid content of the heat-sensitive recording layer.
The purpose of the present invention can be achieved with this method. Next, the substances used in the present invention will be described. (1) Leuco compounds Colorless or light-colored substances that develop color by reacting with organic acids, such as triphenylmethane, triphenylmethanephthalide, fluoran, leucoolamine, diphenylmethane, phenothiazine, phenoxazine, Examples include various derivatives such as spiropyran, indoline, and indigo derivatives. (2) Organic acid A substance that is solid at room temperature, melts when heated, and becomes a color developer when it comes into contact with a leuco compound.
Examples include various phenolic substances, fatty acids, aromatic carboxylic acids, and the like. (3) Binder A water-soluble binder is mainly used to isolate and fix the coloring agent dispersed in fine particles from each other, such as polyvinyl alcohol, methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, polyacrylic acid, and casein. , gelatin, starch and their derivatives. (4) Other additives In addition to the components (1) to (3) above, the whiteness of the recording layer,
Calcium carbonate, kaolin,
White pigments such as clay, talc, and titanium oxide may be added, and fatty acid metal salts may also be added for the purpose of preventing head wear and staking. Further, in combination with the color development accelerator according to the present invention, a known color development accelerator can be added and contained in the recording layer. Next, examples of the present invention will be shown. Example Liquids A and B having the following compositions were separately dispersed for 5 hours using a Bainto sheaker (manufactured by Toyo Seiki). Solution A: Leuco dye PSD-150 (Nippon Sokako) 5g Tribenzylamine 8g Aluminum hydroxide 20g Zinc stearate 5g Polyvinyl alcohol 12% solution 35g Water 52g Solution B: Bisphenol A 15g Kaolin 20g Zinc stearate 3g Polyvinyl alcohol 12% liquid 35g Water 52g Next, add 125g of liquid A, 125g of liquid B, 50g of polyvinyl alcohol 12% liquid, and 40g of water, mix, stir, and adjust to make a coating liquid. Next, add this coating liquid to 50g/ ^m2 . The coating was coated on the surface of high-quality paper using a Meyer bar so that the coated amount after drying was 8 g/m ² and dried to obtain heat-sensitive recording paper. Comparative Example Among the formulations of liquid A used in the examples, in the present invention,
A thermosensitive recording paper was obtained in the same manner as in Example except for the color development accelerator tribenzylamine. Reference Example Among the formulations of liquid A used in Examples, 8 g of tribenzylamine was mixed with 4 g of Amide AP-1 (Nippon Kasei Co., Ltd. stearamide/palmitic acid amide = 7/3) and methylolamide (Nippon Kasei Co., Ltd.). ) A thermosensitive recording paper was obtained in the same manner as in Example except that 4 g of methylolated stearamide was used. The heat-sensitive recording papers obtained in the above Examples, Comparative Examples, and Reference Examples were surface-treated with a test supercalender so that the recording surface had a Bekk smoothness of 500 seconds. Next, we measured the background density and the density of the colored part of the thermal recording paper obtained by surface treatment, as well as the background density (background fog) and the density of the colored part after storage, and investigated the storage stability such as background fogging and discoloration. Ta. The results are shown in Table 1.

【table】

[Table] In addition, solid recording was performed on the surface-treated heat-sensitive recording paper by varying the applied voltage using a commercially available facsimile machine, and the recording density was measured to examine color development. The results are shown in Table 2.

[Table] From the results in Table 2, it is clear from comparison with Examples and Comparative Examples that the color development promoting effect of the color development accelerator according to the present invention is significantly increased. Furthermore, the excellent effect of the color development accelerator tribenzylamine according to the present invention can be seen in a comparison with a fatty acid amide type as a reference example. Furthermore, from the results in Table 1, it is clear that the background density and storage stability are equal to or higher than those of fatty acid amide-based products commonly used in the past. It was demonstrated that there were no problems and that it was a superior color development accelerator.

Claims (1)

[Claims] 1. A thermal recording paper whose main components are a leuco compound and an organic acid that develops a color by reacting with the leuco compound, which is characterized in that the recording layer contains tribenzylamine as a color development accelerator.