JPH02101002A - Vermin-repelling sheet - Google Patents
Vermin-repelling sheetInfo
- Publication number
- JPH02101002A JPH02101002A JP63254296A JP25429688A JPH02101002A JP H02101002 A JPH02101002 A JP H02101002A JP 63254296 A JP63254296 A JP 63254296A JP 25429688 A JP25429688 A JP 25429688A JP H02101002 A JPH02101002 A JP H02101002A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- vermin
- polyurethane resin
- repelling
- pest control
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 241000607479 Yersinia pestis Species 0.000 claims description 19
- 229920005862 polyol Polymers 0.000 abstract description 14
- 150000003077 polyols Chemical class 0.000 abstract description 14
- 239000005056 polyisocyanate Substances 0.000 abstract description 9
- 229920001228 polyisocyanate Polymers 0.000 abstract description 9
- -1 polyethylene Polymers 0.000 abstract description 8
- 239000002655 kraft paper Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 229920003002 synthetic resin Polymers 0.000 abstract description 6
- 239000000057 synthetic resin Substances 0.000 abstract description 6
- 239000004698 Polyethylene Substances 0.000 abstract description 5
- 229920000573 polyethylene Polymers 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000035755 proliferation Effects 0.000 abstract description 3
- 238000010030 laminating Methods 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 3
- 230000001846 repelling effect Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 13
- 229940079593 drug Drugs 0.000 description 13
- 241000238876 Acari Species 0.000 description 9
- 239000002917 insecticide Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は害虫駆除シートに関するものであり、特に家屋
内の床部等に敷いて、ダニ等の害虫を駆除するためのシ
ートに関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a pest control sheet, and particularly to a sheet that is spread on the floor of a house to exterminate pests such as mites.
従来、家屋内の線種や畳の下などの床部に棲息するダニ
等を駆除する場合は、薬剤を混入した液化ガスが注入さ
れたスプレー式の殺虫剤を散布したり、殺虫剤を薄めた
溶液を畳等に注入したり、又は有機リン系殺虫剤を含浸
させたペーパーを線種や畳の下に敷く等の手段がとられ
ていた。Traditionally, when exterminating ticks that live inside a house or on floors such as under tatami mats, spray insecticides injected with liquefied gas mixed with chemicals or diluted insecticides were used. Measures were taken such as injecting a liquid solution into tatami mats, etc., or placing paper impregnated with organic phosphorus insecticides under the wires and tatami mats.
しかしながら、上記手段、すなわち、スプレー式殺虫剤
の散布の場合は、畳の下や絨種の下などに万遍なく散布
したつもりでも、ダニのいる場所に散布液が届かなかっ
たり、あるいは届いているのか届いていないのかわから
ないという問題があり、しかも不要な所まで散布液が飛
散するという問題があった。又、殺虫剤入りの液体を畳
や床に注入する場合は、部分的に注入液が滲み込むだけ
で、広い面積の駆除には不向きであり、しかも広い面積
に注入するときは注入液が多量に必要となり、しかもそ
の作業は大変煩わしいものであった。However, in the case of the above method, that is, spraying insecticides, even if you intend to spray evenly under the tatami mats or carpet seeds, the spray solution may not reach the areas where the mites are present, or may not reach the areas where the mites are present. There was a problem in that it was not clear whether the spray was being delivered or not, and there was also the problem that the spray liquid would scatter to unnecessary areas. Also, when injecting a liquid containing insecticide onto tatami mats or floors, the injected liquid only partially seeps into the floor, making it unsuitable for exterminating large areas; , and the work was extremely troublesome.
また、クラフト紙や不織布等のシート類に殺虫剤を含浸
させたものは、それらの繊維の隙間に殺虫剤を含ませて
いるだけで、殺虫剤の放出がコントロールされていない
ため、効果の持続性が期待できないという問題があった
。又、直接薬剤が露出しやすいため、手で触れる機会が
多く、居住環境が薬剤に汚染されるという問題があった
。In addition, sheets such as kraft paper and non-woven fabric impregnated with insecticides are only impregnated with the insecticide in the gaps between their fibers, and the release of the insecticide is not controlled, so the effect does not last long. There was a problem that sex was not expected. In addition, since the drugs are easily exposed directly, there are many opportunities to touch them with hands, resulting in the problem of contamination of the living environment with the drugs.
上記問題を解決するため、本発明の害虫駆除シートはシ
ート状支持体の片面に、害虫駆除薬剤を含むポリウレタ
ン樹脂を塗着し、その上に通気性を有する被覆シートを
積層したものである。In order to solve the above problem, the pest control sheet of the present invention is obtained by coating a polyurethane resin containing a pest control agent on one side of a sheet-like support, and laminating a breathable covering sheet thereon.
本発明の害虫駆除シートはポリウレタン樹脂皮膜中に害
虫駆除薬剤が封入された状態であるため、ポリウレタン
樹脂マトリックス中を薬剤が拡散することにより、皮膜
表面から徐々に少量の薬剤が放出される。そのため害虫
駆除効果が長期間持続すると同時に多量の薬剤が一度に
放出されることが無い。更に、薬剤を徐放するポリウレ
タン樹脂層の両面はシート状支持体及び通気性を有する
被覆シートがあるため、直接居住環境と薬剤が接触する
ことが無く、安全性の高いものである。しかも本発明の
構成によると、ポリウレタン樹脂がシート状支持体と被
覆シートとの中間にあって、両者を接合するための接着
剤としての役目もするものである。Since the pest control sheet of the present invention has a pest control drug encapsulated in a polyurethane resin film, a small amount of the drug is gradually released from the surface of the film as the drug diffuses through the polyurethane resin matrix. Therefore, the insect extermination effect lasts for a long time, and at the same time, a large amount of the chemical is not released at once. Furthermore, since there is a sheet-like support and a breathable covering sheet on both sides of the polyurethane resin layer for sustained release of the drug, the drug does not come into direct contact with the living environment, making it highly safe. Furthermore, according to the configuration of the present invention, the polyurethane resin is located between the sheet-like support and the covering sheet, and also serves as an adhesive for bonding them together.
以下に本発明の実施例について詳述する。 Examples of the present invention will be described in detail below.
図面は本発明の一実施例を示す断面図であって、１はシ
ート状支持体であり、片面にポリエチレン等のフィルム
をラミネートしたクラフト紙である。The drawing is a sectional view showing one embodiment of the present invention, and 1 is a sheet-like support, which is kraft paper laminated with a film such as polyethylene on one side.
厚みはクラフト紙が８０μｍ、ポリエチレンフィルムが
２０μｍである。該支持体１はポリエチレンフィルムが
ラミネートしであるため、液状のポリウレタン樹脂の滲
み出しがなく、薬剤が簡単に洩れ出したりすることがな
い。シート状支持体１としては、他にポリ塩化ビニルや
ポリエチレンテレフタレートフィルムや合成樹脂発泡シ
ート等種々のシートが使用できる。しかし、ポリウレタ
ン中に含まれる害虫駆除薬剤によって腐蝕されるものは
使用できないので、耐薬品性の良い合成樹脂フィルムや
発泡シート等を選択する必要がある。The thickness of the kraft paper is 80 μm, and the thickness of the polyethylene film is 20 μm. Since the support 1 is made of a laminated polyethylene film, the liquid polyurethane resin does not ooze out, and the drug does not easily leak out. As the sheet-like support 1, various other sheets such as polyvinyl chloride, polyethylene terephthalate film, synthetic resin foam sheet, etc. can be used. However, since polyurethane cannot be used if it is corroded by the pest control chemicals contained in it, it is necessary to select a synthetic resin film or foam sheet with good chemical resistance.
又、シート状支持体は必ずしも上記フィルム状のものや
発泡シートに限定されるものではなく、厚みのある硬質
の合成樹脂板やその他金属箔等でも良い。Further, the sheet-like support is not necessarily limited to the above-mentioned film-like or foamed sheet, but may also be a thick hard synthetic resin plate or other metal foil.
図中２はポリウレタン樹脂層であって、該樹脂層の中に
は害虫駆除薬剤が含まれている。ポリウレタン樹脂はポ
リオールとポリイソシアネートとの２液型の反応生成物
であって、ポリオールとしてはポリエチレングリコール
、ポリプロピレングリコール、ポリテトラメチレングリ
コール、及びそれらのブロック共重合体、ランダム共重
合体等のポリエーテルポリオールが用いられる。更に、
グリセリンやトリメチロールプロパンに上記ポリエーテ
ルポリオールをグラフトして多官能としたポリマーも好
適に使用できる。又、これらのポリオールは必ずしも液
状である必要はないが、加工の容易さを考慮すれば液状
であることが望ましい。2 in the figure is a polyurethane resin layer, and the resin layer contains a pest control agent. Polyurethane resin is a two-component reaction product of polyol and polyisocyanate, and polyols include polyethers such as polyethylene glycol, polypropylene glycol, polytetramethylene glycol, and block copolymers and random copolymers thereof. Polyols are used. Furthermore,
A polyfunctional polymer obtained by grafting the polyether polyol onto glycerin or trimethylolpropane can also be suitably used. Further, these polyols do not necessarily have to be in liquid form, but in consideration of ease of processing, it is desirable that they be in liquid form.
ポリイソシアネートとしては、ポリエチレングリコール
、ポリプロピレングリコール、ポリテトラメチレングリ
コール、及びそれらのブロック共重合体、ランダム共重
合体等のポリエーテルポリオール、更にグリセリンやト
リメチロールプロパンに１記ポリエーテルポリオールを
グラフトして多官能としたポリオールに通常のウレタン
反応により末端をイソシアネート基としたものが用いら
れる。イソシアネートとしては、４．４′−ジフェニル
メタンジイソシアネート（ＭＤＩ）、２．４トリレンジ
イソシアネート（ＴＤＩ） 、キシリレンジイソシアネ
ー）（ＸＤｒ）、ヘキサメチレンジイソシアネート（Ｈ
ＭＤ ｒ） 、イソホロンジイソシアネート（ＩＰＤＩ
）、水添化ＭＤＩ、Ｈ６ＸＤＩ等汎用のイソシアネート
が使用できる。これらのポリイソシアネートについても
ポリオールと同様に加工の容易さから、液状であること
が望ましい。Examples of polyisocyanates include polyether polyols such as polyethylene glycol, polypropylene glycol, polytetramethylene glycol, block copolymers and random copolymers thereof, and also glycerin and trimethylolpropane grafted with the polyether polyol described in 1 above. A polyfunctional polyol with isocyanate groups at its terminals by a normal urethane reaction is used. Isocyanates include 4,4'-diphenylmethane diisocyanate (MDI), 2,4-tolylene diisocyanate (TDI), xylylene diisocyanate (XDr), and hexamethylene diisocyanate (H
MD r), isophorone diisocyanate (IPDI
), hydrogenated MDI, H6XDI, and other general-purpose isocyanates can be used. These polyisocyanates are also preferably in liquid form for ease of processing, similar to polyols.
上記のポリオールとポリイソシアネートは自由に組み合
わせて使用することができるが、反応後の皮膜の粘着性
が適度に必要であり、又、保型性も必要であることを考
慮に入れれば、ポリオールとポリイソシアネートの少な
くともどちらか一方は３官能以上のものを用いることが
望ましく、しかも、ポリオールとポリイソシアネートの
少なくともどちらか一方のセグメントの分子量は２００
０以下とすることが望ましい。両方のセグメ、ントが２
０００以上の場合は、粘着性がなくなり、害虫駆除シー
トとして形成させることが困難となる。The above polyols and polyisocyanates can be used in any combination, but if you take into account that the film needs to have a certain level of tackiness after the reaction and also needs to have shape retention, it is best to use polyols and polyisocyanates. It is desirable that at least one of the polyisocyanates is trifunctional or higher, and the molecular weight of the segment of at least one of the polyol and the polyisocyanate is 200.
It is desirable to set it to 0 or less. Both segments are 2
000 or more, the adhesiveness is lost and it becomes difficult to form a pest control sheet.
又、ポリウレタン樹脂に混入する害虫駆除薬剤としては
ピレスロイド系のアレスリン、フタルスリン、レスメト
リン、エトフエンプロソクス、有機リン系のフェニトロ
チオン、トリクロルフオン等を用いることができる。Further, as pest control agents mixed into the polyurethane resin, pyrethroid allethrin, phthalthrin, resmethrin, etofenprosox, organophosphorus fenitrothion, trichlorfon, etc. can be used.
そして、ポリウレタン樹脂層２に覆せる被覆シート３は
、紙、微細な孔を穿設した合成樹脂フィルム、又通気性
のある合成樹脂発泡シート、不織布、布等であって、い
ずれも薬剤が通過する通気性を有する材料を用いること
ができる。The covering sheet 3 that can be covered with the polyurethane resin layer 2 is made of paper, a synthetic resin film with minute holes, a breathable synthetic resin foam sheet, non-woven fabric, cloth, etc., all of which allow the drug to pass through. A material with breathability that allows for
又、被覆シート３も耐薬品性の良い材料を選択する必要
があることは当然である。It goes without saying that it is also necessary to select a material with good chemical resistance for the covering sheet 3.
片面にポリエチレンをコーティングしたクラフト紙（坪
量５０ ｇ／ｍ、厚さ１００μｍ）をシト状支持体とし
て用いた。又、ポリウレタン樹脂層として、ピレスロイ
ド系殺虫剤（商品名：エトフェンプロソクス（三井東圧
化学株式会社製））を２部配合したポリオール（ポリプ
ロピレングリコール；サンニソクスＧＰ１００Ｏ（三洋
化成株式会社製）分子量１０００、官能基数３）を１０
０部とポリイソシアネート（サンブレンＰ−４１５３（
三洋化成株式会社製）分子量１７１４、官能基数２）を
１９７部、それに触媒としてジブチル錫ジラウレート０
．１部を均一に混合した。そしてその混合物を上記支持
体の樹脂コーティングした面に約５０μｍの厚みに塗布
し、皮膜を形成させた後、クラフト紙（坪量５０ ｇ／
ｎ（、厚さ８０μｍ）を被覆シートとして皮膜面上に積
層し、害虫駆除シートを得た。この害虫駆除シートを用
い、ケナガコナダニの増殖抑制効果を調べた。Kraft paper (basis weight 50 g/m, thickness 100 μm) coated with polyethylene on one side was used as a sheet-like support. In addition, as a polyurethane resin layer, a polyol (polypropylene glycol; Sannisox GP100O (manufactured by Sanyo Kasei Co., Ltd.), molecular weight 1000, containing two parts of a pyrethroid insecticide (trade name: etofenprosox (manufactured by Mitsui Toatsu Chemical Co., Ltd.)) was used. , the number of functional groups 3) is 10
0 parts and polyisocyanate (Sunbren P-4153 (
(manufactured by Sanyo Kasei Co., Ltd.) molecular weight 1714, number of functional groups 2) 197 parts, and 0 dibutyltin dilaurate as a catalyst.
．． 1 part was mixed uniformly. Then, the mixture was applied to the resin-coated surface of the support to a thickness of about 50 μm to form a film, and then kraft paper (basis weight 50 g/
n (thickness: 80 μm) was laminated on the film surface as a covering sheet to obtain a pest control sheet. Using this pest control sheet, the effect of suppressing the growth of the mites was investigated.
（以下余白）
（生ダニ数は３連×２回観察の平均値で１ｇ当りに換算
した値）
尚、表中の増殖抑制率は次の試験法で得たものである。(Margins below) (The number of live mites is the average value of 3 consecutive x 2 observations, converted to per 1 g) The growth inhibition rate in the table was obtained by the following test method.
直径１０ｃｍのシャーレ中に飽和培地を５０ｇ入れ、ケ
ナガコナダニを約７０００匹投入した。この中に１ｃｍ
角に切った本発明の害虫駆除シートを所定枚数加え、よ
く攪拌した後、湿度８０％、温度２５℃の環境下に保存
した。一定期間経過後、培地０．１ｇをとり、生ダニ数
を調べ、次式より増殖率を算出した。50 g of a saturated medium was placed in a Petri dish with a diameter of 10 cm, and approximately 7,000 mites were placed therein. 1cm inside this
A predetermined number of pest control sheets of the present invention cut into squares were added, stirred thoroughly, and then stored in an environment with a humidity of 80% and a temperature of 25°C. After a certain period of time had elapsed, 0.1 g of the medium was taken, the number of live mites was examined, and the proliferation rate was calculated from the following formula.
本発明の害虫駆除シートはポリウレタン樹脂皮膜中に害
虫駆除薬剤が封入された状態であるため薬剤が樹脂マト
リックス中を拡散することによって、徐々に樹脂皮膜表
面から薬剤が放出されるので、上記実験例の結果からも
明らかなように、長期間に亘って薬剤効力が持続し、ダ
ニ等の増殖を抑制し、害虫駆除シートとして顕著な効果
を有するものである。又、本発明シートは畳の下や線種
等の下に幅広く敷きつめることができ、その作業も簡単
で、しかも薬剤層であるポリウレタン樹脂の接着剤的役
割により、片面にシート状支持体、もう一方の面に被覆
シートが貼着しているので、薬剤が手に触れることがな
く、生活環境を汚すおそれもほとんどないと言える安全
性の高さでも優れたものである。Since the pest control sheet of the present invention has a pest control agent encapsulated in a polyurethane resin film, the drug diffuses through the resin matrix and is gradually released from the surface of the resin film. As is clear from the results, the drug maintains its efficacy over a long period of time, suppresses the proliferation of mites, etc., and has a remarkable effect as a pest control sheet. In addition, the sheet of the present invention can be widely spread under tatami mats, line types, etc., and is easy to work with.Moreover, due to the adhesive role of the polyurethane resin, which is the drug layer, the sheet-like support, Since a covering sheet is attached to the other side, the drug does not come into contact with hands, and there is almost no risk of contaminating the living environment, making it an excellent product with a high level of safety.
図面は本発明の害虫駆除シートの拡大積層断面図である
。
ｌ・・・シート状支持体、２・・・ポリウレタン樹脂層
、３・・・被覆シート。The drawing is an enlarged laminated cross-sectional view of the pest control sheet of the present invention. 1...Sheet-like support, 2...Polyurethane resin layer, 3...Coating sheet.
Claims (1)
ウレタン樹脂が塗着され、その上に通気性を有する被覆
シートが積層されていることを特徴とする害虫駆除シー
ト。(1) A pest control sheet, characterized in that a polyurethane resin containing a pest control agent is coated on one side of a sheet-like support, and a breathable covering sheet is laminated thereon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63254296A JPH02101002A (en) | 1988-10-07 | 1988-10-07 | Vermin-repelling sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63254296A JPH02101002A (en) | 1988-10-07 | 1988-10-07 | Vermin-repelling sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02101002A true JPH02101002A (en) | 1990-04-12 |
Family
ID=17263005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63254296A Pending JPH02101002A (en) | 1988-10-07 | 1988-10-07 | Vermin-repelling sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02101002A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0435778U (en) * | 1990-07-20 | 1992-03-25 | ||
| JPH0940508A (en) * | 1995-07-26 | 1997-02-10 | Fumitomo Takamura | Insect-proofing seal |
| WO2003055307A1 (en) * | 2001-12-22 | 2003-07-10 | Dct Aps | Pesticidal blanket |
| JP2018068248A (en) * | 2016-11-02 | 2018-05-10 | 株式会社大阪製薬 | Pest control sheet |
| JP2018104831A (en) * | 2016-12-22 | 2018-07-05 | アース製薬株式会社 | Insect proof fabric product |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5796041A (en) * | 1980-10-22 | 1982-06-15 | Bayer Ag | Polyurethane containing epizoon killing agent |
| JPS61267A (en) * | 1984-06-12 | 1986-01-06 | Shinku Seraa:Kk | Antproofing coating solution |
| JPS6155001U (en) * | 1984-09-12 | 1986-04-14 | ||
| JPS62502693A (en) * | 1985-05-01 | 1987-10-15 | アメリカン テレフオン アンド テレグラフ カムパニ− | Elastomeric controlled release formulations and articles containing the same |
-
1988
- 1988-10-07 JP JP63254296A patent/JPH02101002A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5796041A (en) * | 1980-10-22 | 1982-06-15 | Bayer Ag | Polyurethane containing epizoon killing agent |
| JPS61267A (en) * | 1984-06-12 | 1986-01-06 | Shinku Seraa:Kk | Antproofing coating solution |
| JPS6155001U (en) * | 1984-09-12 | 1986-04-14 | ||
| JPS62502693A (en) * | 1985-05-01 | 1987-10-15 | アメリカン テレフオン アンド テレグラフ カムパニ− | Elastomeric controlled release formulations and articles containing the same |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0435778U (en) * | 1990-07-20 | 1992-03-25 | ||
| JPH0940508A (en) * | 1995-07-26 | 1997-02-10 | Fumitomo Takamura | Insect-proofing seal |
| WO2003055307A1 (en) * | 2001-12-22 | 2003-07-10 | Dct Aps | Pesticidal blanket |
| JP2018068248A (en) * | 2016-11-02 | 2018-05-10 | 株式会社大阪製薬 | Pest control sheet |
| JP2018104831A (en) * | 2016-12-22 | 2018-07-05 | アース製薬株式会社 | Insect proof fabric product |
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