JPH02111820A - 遷移元素の非金属的単原子形態 - Google Patents

遷移元素の非金属的単原子形態

Info

Publication number: JPH02111820A
Authority: JP; Japan
Prior art keywords: monatomic; rearranged; orbitally; metal; gold
Prior art date: 1988-06-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP1159395A

Other languages

English (en)

Japanese (ja)

Inventor

David Radius Hudson

デビッド．ラディウス．ハドソン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

CONCORD RES CORP

Original Assignee

CONCORD RES CORP

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-06-21

Filing date

1989-06-21

Publication date

1990-04-24

1989-06-21 Application filed by CONCORD RES CORP filed Critical CONCORD RES CORP

1990-04-24 Publication of JPH02111820A publication Critical patent/JPH02111820A/ja

Status Pending legal-status Critical Current

Links

230000007704 transition Effects 0.000 title claims description 23
229910052751 metal Inorganic materials 0.000 claims abstract description 97
239000002184 metal Substances 0.000 claims abstract description 96
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 72
229910052737 gold Inorganic materials 0.000 claims abstract description 65
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 46
150000003839 salts Chemical class 0.000 claims abstract description 45
229910052741 iridium Inorganic materials 0.000 claims abstract description 40
229910052703 rhodium Inorganic materials 0.000 claims abstract description 36
150000002739 metals Chemical class 0.000 claims abstract description 24
229910052707 ruthenium Inorganic materials 0.000 claims abstract description 22
229910052762 osmium Inorganic materials 0.000 claims abstract description 21
229910052763 palladium Inorganic materials 0.000 claims abstract description 21
229910052697 platinum Inorganic materials 0.000 claims abstract description 21
229910052723 transition metal Inorganic materials 0.000 claims abstract description 15
229910052802 copper Inorganic materials 0.000 claims abstract description 11
229910000510 noble metal Inorganic materials 0.000 claims abstract description 11
150000003624 transition metals Chemical class 0.000 claims abstract description 11
229910052759 nickel Inorganic materials 0.000 claims abstract description 10
229910052709 silver Inorganic materials 0.000 claims abstract description 10
239000010931 gold Substances 0.000 claims description 65
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 63
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 41
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 39
239000010948 rhodium Substances 0.000 claims description 35
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 35
230000005291 magnetic effect Effects 0.000 claims description 27
238000000034 method Methods 0.000 claims description 26
239000000126 substance Substances 0.000 claims description 23
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 21
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 21
229910017604 nitric acid Inorganic materials 0.000 claims description 21
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 20
238000010438 heat treatment Methods 0.000 claims description 19
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
239000000463 material Substances 0.000 claims description 18
238000001816 cooling Methods 0.000 claims description 16
238000000926 separation method Methods 0.000 claims description 14
238000011282 treatment Methods 0.000 claims description 13
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
239000010949 copper Substances 0.000 claims description 10
229910017052 cobalt Inorganic materials 0.000 claims description 9
239000010941 cobalt Substances 0.000 claims description 9
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
239000004332 silver Substances 0.000 claims description 9
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
230000015572 biosynthetic process Effects 0.000 claims description 6
238000002329 infrared spectrum Methods 0.000 claims description 6
238000001704 evaporation Methods 0.000 claims description 5
230000004907 flux Effects 0.000 claims description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 4
238000009713 electroplating Methods 0.000 claims 1
229910052756 noble gas Inorganic materials 0.000 claims 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 11
239000000155 melt Substances 0.000 abstract description 8
239000011780 sodium chloride Substances 0.000 abstract description 6
239000002253 acid Substances 0.000 abstract description 5
229910044991 metal oxide Inorganic materials 0.000 abstract description 2
150000004706 metal oxides Chemical class 0.000 abstract description 2
239000002994 raw material Substances 0.000 abstract 2
230000002378 acidificating effect Effects 0.000 abstract 1
239000000243 solution Substances 0.000 description 95
239000000523 sample Substances 0.000 description 67
235000002639 sodium chloride Nutrition 0.000 description 44
125000004429 atom Chemical group 0.000 description 42
239000002244 precipitate Substances 0.000 description 41
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 33
239000001257 hydrogen Substances 0.000 description 32
229910052739 hydrogen Inorganic materials 0.000 description 32
238000009835 boiling Methods 0.000 description 15
238000006722 reduction reaction Methods 0.000 description 15
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
230000009467 reduction Effects 0.000 description 14
230000002829 reductive effect Effects 0.000 description 14
239000011734 sodium Substances 0.000 description 14
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
229910052500 inorganic mineral Inorganic materials 0.000 description 13
235000010755 mineral Nutrition 0.000 description 13
239000011707 mineral Substances 0.000 description 13
229910052799 carbon Inorganic materials 0.000 description 12
238000004821 distillation Methods 0.000 description 12
239000000843 powder Substances 0.000 description 12
239000013078 crystal Substances 0.000 description 11
239000012153 distilled water Substances 0.000 description 11
229910052708 sodium Inorganic materials 0.000 description 11
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 10
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 10
230000008707 rearrangement Effects 0.000 description 10
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
238000004458 analytical method Methods 0.000 description 9
-1 cobal l- Chemical compound 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 9
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
239000007864 aqueous solution Substances 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
238000002485 combustion reaction Methods 0.000 description 8
239000000706 filtrate Substances 0.000 description 8
239000007789 gas Substances 0.000 description 8
239000007788 liquid Substances 0.000 description 8
238000001556 precipitation Methods 0.000 description 8
238000003756 stirring Methods 0.000 description 8
239000011521 glass Substances 0.000 description 7
230000008569 process Effects 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
230000000694 effects Effects 0.000 description 6
239000000284 extract Substances 0.000 description 6
239000010453 quartz Substances 0.000 description 6
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 6
239000007787 solid Substances 0.000 description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
229910052786 argon Inorganic materials 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
238000002425 crystallisation Methods 0.000 description 5
230000008025 crystallization Effects 0.000 description 5
239000005416 organic matter Substances 0.000 description 5
230000003647 oxidation Effects 0.000 description 5
238000007254 oxidation reaction Methods 0.000 description 5
229910052573 porcelain Inorganic materials 0.000 description 5
230000004044 response Effects 0.000 description 5
238000012546 transfer Methods 0.000 description 5
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
239000001569 carbon dioxide Substances 0.000 description 4
229910002092 carbon dioxide Inorganic materials 0.000 description 4
238000010586 diagram Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
238000005194 fractionation Methods 0.000 description 4
229910021505 gold(III) hydroxide Inorganic materials 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
239000000203 mixture Substances 0.000 description 4
229920006395 saturated elastomer Polymers 0.000 description 4
229910052721 tungsten Inorganic materials 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
229910001873 dinitrogen Inorganic materials 0.000 description 3
235000019441 ethanol Nutrition 0.000 description 3
238000000605 extraction Methods 0.000 description 3
150000002343 gold Chemical class 0.000 description 3
RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical class Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 description 3
230000036571 hydration Effects 0.000 description 3
238000006703 hydration reaction Methods 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
230000005389 magnetism Effects 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000010970 precious metal Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
238000004445 quantitative analysis Methods 0.000 description 3
230000005855 radiation Effects 0.000 description 3
238000011084 recovery Methods 0.000 description 3
239000013049 sediment Substances 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
235000017557 sodium bicarbonate Nutrition 0.000 description 3
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 3
235000011149 sulphuric acid Nutrition 0.000 description 3
239000002887 superconductor Substances 0.000 description 3
238000002411 thermogravimetry Methods 0.000 description 3
239000010936 titanium Substances 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
239000010938 white gold Substances 0.000 description 3
229910000832 white gold Inorganic materials 0.000 description 3
229910052726 zirconium Inorganic materials 0.000 description 3
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
239000004809 Teflon Substances 0.000 description 2
229920006362 Teflon® Polymers 0.000 description 2
229910052776 Thorium Inorganic materials 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
238000000137 annealing Methods 0.000 description 2
238000013459 approach Methods 0.000 description 2
239000011013 aquamarine Substances 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
239000000470 constituent Substances 0.000 description 2
238000010908 decantation Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000001514 detection method Methods 0.000 description 2
238000004455 differential thermal analysis Methods 0.000 description 2
JGUQDUKBUKFFRO-CIIODKQPSA-N dimethylglyoxime Chemical compound O/N=C(/C)\C(\C)=N\O JGUQDUKBUKFFRO-CIIODKQPSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
229920001971 elastomer Polymers 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000003292 glue Substances 0.000 description 2
FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
AZMMUMQYPBKXHS-UHFFFAOYSA-N gold sodium Chemical compound [Na].[Au] AZMMUMQYPBKXHS-UHFFFAOYSA-N 0.000 description 2
230000005283 ground state Effects 0.000 description 2
239000001307 helium Substances 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
239000012728 immediate-release (IR) tablet Substances 0.000 description 2
238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
230000009191 jumping Effects 0.000 description 2
239000012528 membrane Substances 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
229910052655 plagioclase feldspar Inorganic materials 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
238000006479 redox reaction Methods 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
230000027756 respiratory electron transport chain Effects 0.000 description 2
WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
239000012488 sample solution Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
238000000859 sublimation Methods 0.000 description 2
230000008022 sublimation Effects 0.000 description 2
238000012360 testing method Methods 0.000 description 2
238000007704 wet chemistry method Methods 0.000 description 2
GMVPRGQOIOIIMI-UHFFFAOYSA-N (8R,11R,12R,13E,15S)-11,15-Dihydroxy-9-oxo-13-prostenoic acid Natural products CCCCCC(O)C=CC1C(O)CC(=O)C1CCCCCCC(O)=O GMVPRGQOIOIIMI-UHFFFAOYSA-N 0.000 description 1
MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 description 1
229910000497 Amalgam Inorganic materials 0.000 description 1
241000206761 Bacillariophyta Species 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
241000931705 Cicada Species 0.000 description 1
235000015210 Fockea angustifolia Nutrition 0.000 description 1
244000186654 Fockea angustifolia Species 0.000 description 1
244000182067 Fraxinus ornus Species 0.000 description 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
229920000557 Nafion® Polymers 0.000 description 1
239000000020 Nitrocellulose Substances 0.000 description 1
229910021130 PdO2 Inorganic materials 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
235000014676 Phragmites communis Nutrition 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229910019834 RhO2 Inorganic materials 0.000 description 1
108091006629 SLC13A2 Proteins 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
239000003929 acidic solution Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000005273 aeration Methods 0.000 description 1
229960000711 alprostadil Drugs 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
AXQKUBACYUKQDI-UHFFFAOYSA-N aniline argon Chemical compound [Ar].NC1=CC=CC=C1 AXQKUBACYUKQDI-UHFFFAOYSA-N 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical class [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
238000007664 blowing Methods 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
235000009508 confectionery Nutrition 0.000 description 1
238000012790 confirmation Methods 0.000 description 1
230000008094 contradictory effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
230000005292 diamagnetic effect Effects 0.000 description 1
RBNPZEHAODHBPZ-UHFFFAOYSA-M dihydroxyaluminium Chemical compound O.O.NCC(=O)O[Al] RBNPZEHAODHBPZ-UHFFFAOYSA-M 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
125000002084 dioxo-lambda(5)-bromanyloxy group Chemical group *OBr(=O)=O 0.000 description 1
KZYDBKYFEURFNC-UHFFFAOYSA-N dioxorhodium Chemical compound O=[Rh]=O KZYDBKYFEURFNC-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
230000005670 electromagnetic radiation Effects 0.000 description 1
230000005274 electronic transitions Effects 0.000 description 1
238000000295 emission spectrum Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
239000003574 free electron Substances 0.000 description 1
238000007429 general method Methods 0.000 description 1
230000005358 geomagnetic field Effects 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
QUCZBHXJAUTYHE-UHFFFAOYSA-N gold Chemical compound [Au].[Au] QUCZBHXJAUTYHE-UHFFFAOYSA-N 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
230000003100 immobilizing effect Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
230000007774 longterm Effects 0.000 description 1
238000000504 luminescence detection Methods 0.000 description 1
238000004020 luminiscence type Methods 0.000 description 1
230000005415 magnetization Effects 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
239000002366 mineral element Substances 0.000 description 1
239000000178 monomer Substances 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical class ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
ITVGXXMINPYUHD-CUVHLRMHSA-N neohesperidin dihydrochalcone Chemical compound C1=C(O)C(OC)=CC=C1CCC(=O)C(C(=C1)O)=C(O)C=C1O[C@H]1[C@H](O[C@H]2[C@@H]([C@H](O)[C@@H](O)[C@H](C)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 ITVGXXMINPYUHD-CUVHLRMHSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
229920001220 nitrocellulos Polymers 0.000 description 1
229910052755 nonmetal Inorganic materials 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
238000013021 overheating Methods 0.000 description 1
230000002572 peristaltic effect Effects 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000007747 plating Methods 0.000 description 1
239000005373 porous glass Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000005381 potential energy Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
GMVPRGQOIOIIMI-DWKJAMRDSA-N prostaglandin E1 Chemical compound CCCCC[C@H](O)\C=C\[C@H]1[C@H](O)CC(=O)[C@@H]1CCCCCCC(O)=O GMVPRGQOIOIIMI-DWKJAMRDSA-N 0.000 description 1
238000010298 pulverizing process Methods 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000008213 purified water Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000001226 reprecipitation Methods 0.000 description 1
238000005070 sampling Methods 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
238000005245 sintering Methods 0.000 description 1
230000035943 smell Effects 0.000 description 1
125000004436 sodium atom Chemical group 0.000 description 1
XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
239000004317 sodium nitrate Substances 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
238000010183 spectrum analysis Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000004575 stone Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
BVJAAVMKGRODCT-UHFFFAOYSA-N sulfanylidenerhodium Chemical compound [Rh]=S BVJAAVMKGRODCT-UHFFFAOYSA-N 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
238000006557 surface reaction Methods 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
238000002076 thermal analysis method Methods 0.000 description 1
WEQHQGJDZLDFID-UHFFFAOYSA-J thorium(iv) chloride Chemical compound Cl[Th](Cl)(Cl)Cl WEQHQGJDZLDFID-UHFFFAOYSA-J 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
230000009466 transformation Effects 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/04—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering with simultaneous application of supersonic waves, magnetic or electric fields
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G5/00—Compounds of silver
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G7/00—Compounds of gold
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Crystallography & Structural Chemistry (AREA)
Mechanical Engineering (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Manufacture And Refinement Of Metals (AREA)
Catalysts (AREA)
Analysing Materials By The Use Of Radiation (AREA)

JP1159395A 1988-06-21 1989-06-21 遷移元素の非金属的単原子形態 Pending JPH02111820A (ja)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US20929788A	1988-06-21	1988-06-21
US209.297		1988-06-21
US36317389A	1989-06-07	1989-06-07
US363.173		1989-06-07

Publications (1)

Publication Number	Publication Date
JPH02111820A true JPH02111820A (ja)	1990-04-24

Family

ID=26904024

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP1159395A Pending JPH02111820A (ja)	1988-06-21	1989-06-21	遷移元素の非金属的単原子形態

Country Status (11)

Country	Link
JP (1)	JPH02111820A (it)
AT (1)	AT395313B (it)
BE (1)	BE1003134A4 (it)
CH (1)	CH680136A5 (it)
DE (1)	DE3920144A1 (it)
ES (1)	ES2016468A6 (it)
FR (1)	FR2632974B1 (it)
GB (1)	GB2219995B (it)
IT (1)	IT1237457B (it)
NL (1)	NL8901538A (it)
SE (1)	SE8902258L (it)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
PL236093B1 (pl)	2017-07-04	2020-11-30	Dominika Szczepaniak	Rozpuszczalne w wodzie kompleksy złota (III), sposób wytwarzania rozpuszczalnych w wodzie kompleksów złota (III) i ich zastosowanie
PL244960B1 (pl)	2021-02-15	2024-04-08	Dominika Szczepaniak	Zastosowanie rozpuszczalnych w wodzie kompleksów złota (III)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3511017A1 (de) *	1985-03-27	1986-10-02	Udo Dipl.-Chem. 2000 Hamburg Ohlerich	Verfahren und vorrichtung zur gewinnung ueberwiegend monoatomar disperser metalle bei niedrigen temperaturen

1989
- 1989-06-19 NL NL8901538A patent/NL8901538A/nl not_active Application Discontinuation
- 1989-06-20 IT IT8983430A patent/IT1237457B/it active
- 1989-06-20 ES ES8902149A patent/ES2016468A6/es not_active Expired - Fee Related
- 1989-06-20 DE DE3920144A patent/DE3920144A1/de not_active Withdrawn
- 1989-06-20 CH CH2296/89A patent/CH680136A5/de not_active IP Right Cessation
- 1989-06-20 FR FR898908170A patent/FR2632974B1/fr not_active Expired - Fee Related
- 1989-06-21 BE BE8900671A patent/BE1003134A4/nl not_active IP Right Cessation
- 1989-06-21 AT AT0152489A patent/AT395313B/de not_active IP Right Cessation
- 1989-06-21 GB GB8914216A patent/GB2219995B/en not_active Expired - Fee Related
- 1989-06-21 JP JP1159395A patent/JPH02111820A/ja active Pending
- 1989-06-21 SE SE8902258A patent/SE8902258L/ not_active Application Discontinuation

Also Published As

Publication number	Publication date
CH680136A5 (it)	1992-06-30
BE1003134A4 (nl)	1991-12-03
SE8902258D0 (sv)	1989-06-21
GB2219995B (en)	1992-03-11
SE8902258L (sv)	1989-12-22
AT395313B (de)	1992-11-25
GB8914216D0 (en)	1989-08-09
IT1237457B (it)	1993-06-05
GB2219995A (en)	1989-12-28
FR2632974B1 (fr)	1992-07-03
FR2632974A1 (fr)	1989-12-22
ES2016468A6 (es)	1990-11-01
DE3920144A1 (de)	1989-12-28
ATA152489A (de)	1992-04-15
IT8983430A0 (it)	1989-06-20
NL8901538A (nl)	1990-01-16

Publication	Publication Date	Title
Gao et al.	2019	Enhanced photocatalytic N2 fixation by promoting N2 adsorption with a co-catalyst
Liu et al.	2021	Synthesis of NiFeAl LDHs from electroplating sludge and Their excellent supercapacitor performance
Pinkard et al.	2018	Molecular clusters: nanoscale building blocks for solid-state materials
Zhang et al.	2015	Scale‐up synthesis of fragrant nitrogen‐doped carbon dots from bee pollens for bioimaging and catalysis
Lan et al.	2022	Controllable fabrication of sulfur-vacancy-rich Bi2S3 nanorods with efficient near-infrared light photocatalytic for nitrogen fixation
Wang et al.	2017	Two-dimensional metal phosphorus trisulfide nanosheet with solar hydrogen-evolving activity
Reber et al.	2017	Superatoms: electronic and geometric effects on reactivity
Jørgensen	1959	Electron transfer spectra of hexahalide complexes
AbdulHalim et al.	2015	Ag29 (BDT) 12 (TPP) 4: a tetravalent nanocluster
Wang et al.	2015	Ultrathin black phosphorus nanosheets for efficient singlet oxygen generation
Selinger et al.	1991	Evidence for the encagement of alkali metal ions through the formation of gas-phase clathrates: cesium (1+) in water clusters
Mishra et al.	2021	Studying the effects of Cu doping on structure and photoluminescence properties of SnO2 nanoparticle with its effectiveness towards the mineralization of toxic industrial dye
Rajbhar et al.	2020	Broad beam-induced fragmentation and joining of tungsten oxide nanorods: implications for nanodevice fabrication and the development of fusion reactors
Liu et al.	2023	Rapid photocatalytic degradation of tetrabromobisphenol A using synergistic pn/Z-scheme dual heterojunction of black phosphorus nanosheets/FeSe2/g-C3N4
Nastapova et al.	2020	Two-step mediated electrosynthesis and catalytic activity of Au/Cu2O@ poly (N-vinylpyrrolidone) nanocomposite
Chu et al.	2025	Ru-doped Bi2O3 with rich oxygen vacancy for enhanced photocatalytic nitrogen reduction
Gupta et al.	1989	Determination of Ruthenium, Palladium and Iridium in 27 In ternational Reference Silicate and I Ron‐Formation Rocks, Ores and Related Materials By Isotope Dilution Inductively‐Coupled Plasma Mass Spectrometry
Svedberg	1921	The formation of colloids
Lashgari et al.	2014	Efficient mesoporous/nanostructured Ag-doped alloy semiconductor for solar hydrogen generation
JPH02111820A (ja)	1990-04-24	遷移元素の非金属的単原子形態
Lanje et al.	2010	Luminescence properties of Sn1− xFexO2 nanoparticles
Holleman	1902	A text-book of inorganic chemistry
Sicius	2024	Nickel Group: Elements of the Tenth Subgroup
McGarvey	1962	ESR and optical spectrum of potassium perchromate
Achar et al.	1999	Novelsynthetic metals' based on symmetrically tetrasubstituted nickel phthalocyanines