JPH02140254A - Vinyl chloride resin composition for agricultural use - Google Patents
Vinyl chloride resin composition for agricultural useInfo
- Publication number
- JPH02140254A JPH02140254A JP63292961A JP29296188A JPH02140254A JP H02140254 A JPH02140254 A JP H02140254A JP 63292961 A JP63292961 A JP 63292961A JP 29296188 A JP29296188 A JP 29296188A JP H02140254 A JPH02140254 A JP H02140254A
- Authority
- JP
- Japan
- Prior art keywords
- pts
- vinyl chloride
- chloride resin
- weight
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000011342 resin composition Substances 0.000 title claims abstract description 5
- -1 barium salt Chemical class 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 229910052788 barium Inorganic materials 0.000 claims abstract description 7
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000003014 phosphoric acid esters Chemical class 0.000 claims abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000002378 acidificating effect Effects 0.000 claims abstract description 5
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 5
- 239000011575 calcium Substances 0.000 claims abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 5
- 239000011777 magnesium Substances 0.000 claims abstract description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 4
- 239000000194 fatty acid Substances 0.000 claims abstract description 4
- 229930195729 fatty acid Natural products 0.000 claims abstract description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 229910052725 zinc Chemical class 0.000 claims description 6
- 239000011701 zinc Chemical class 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 abstract description 10
- 239000010452 phosphate Substances 0.000 abstract description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 9
- 150000001298 alcohols Chemical class 0.000 abstract description 2
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 abstract description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract description 2
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 abstract description 2
- 159000000009 barium salts Chemical class 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 13
- 230000006866 deterioration Effects 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- UZSAQAWEIQNGJT-UHFFFAOYSA-N tetracontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO UZSAQAWEIQNGJT-UHFFFAOYSA-N 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 2
- SVETUDAIEHYIKZ-IUPFWZBJSA-N tris[(z)-octadec-9-enyl] phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(=O)(OCCCCCCCC\C=C/CCCCCCCC)OCCCCCCCC\C=C/CCCCCCCC SVETUDAIEHYIKZ-IUPFWZBJSA-N 0.000 description 2
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- QHZLMUACJMDIAE-UHFFFAOYSA-N Palmitic acid monoglyceride Natural products CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- MJIAXOYYJWECDI-UHFFFAOYSA-L barium(2+);dibenzoate Chemical compound [Ba+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 MJIAXOYYJWECDI-UHFFFAOYSA-L 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- ZUUKAYQBTGMEPI-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite 2-[2-(2-hydroxyphenyl)propan-2-yl]phenol Chemical compound OP(O)OP(O)O.C(C)(C)(C1=C(C=CC=C1)O)C1=C(C=CC=C1)O ZUUKAYQBTGMEPI-UHFFFAOYSA-N 0.000 description 1
- OKXAFOJPRGDZPB-UHFFFAOYSA-N dioctadecoxy(oxo)phosphanium Chemical compound CCCCCCCCCCCCCCCCCCO[P+](=O)OCCCCCCCCCCCCCCCCCC OKXAFOJPRGDZPB-UHFFFAOYSA-N 0.000 description 1
- FRXGWNKDEMTFPL-UHFFFAOYSA-N dioctadecyl hydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCCCCCCCC FRXGWNKDEMTFPL-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- LDCJGXVGWOTHSW-UHFFFAOYSA-N pentacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO LDCJGXVGWOTHSW-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
- FRZSCIVUSFMNBX-UHFFFAOYSA-L zinc;12-hydroxyoctadecanoate Chemical compound [Zn+2].CCCCCCC(O)CCCCCCCCCCC([O-])=O.CCCCCCC(O)CCCCCCCCCCC([O-])=O FRZSCIVUSFMNBX-UHFFFAOYSA-L 0.000 description 1
- IJQXGKBNDNQWAT-UHFFFAOYSA-L zinc;docosanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O IJQXGKBNDNQWAT-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Landscapes
- Greenhouses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
一産】１上（７）ｌ」シＵＬ−
本発明はベタツキ、ブロッキング防止性、耐候性、はこ
りイ４着防止性、低温柔軟性および耐土中劣化性に優れ
た農業用塩化ビニル系樹脂組成物に関する。Detailed Description of the Invention [Product] 1 (7) UL The present invention relates to agricultural vinyl chloride resin compositions.
一従沫」ｌ支術−
近年、農作物の高１４加価値化・収量増加を目的として
、農業用塩化ビニル系樹脂フィルムを使用したハウス栽
培等の施設栽培が盛んに行なわれている。ところでこれ
らのハウス栽培においては、夏季あるいは昼間等の高温
時には、農作物の衰弱や焼けを防ぐため換気を必要とす
ることが多く、換気方法としてはハウスの側面のフィル
ムを巻き」−げ・巻さ戻しする方法が多く採用されてい
る。しかしながら、この巻き上げ・巻き戻しの作業にお
いて、これまでの農業用塩化ビニル系樹脂フィルムにお
いては、フィルムどうしのハクリ性が悪いという、いわ
ゆるブロッキング性が劣っており、作業がはかどらなか
ったり、フィルムが破損するという問題が存在していた
。BACKGROUND ART In recent years, with the aim of adding high value to agricultural products and increasing yields, greenhouse cultivation such as greenhouse cultivation using agricultural vinyl chloride resin films has been actively carried out. By the way, these greenhouse cultivation systems often require ventilation during high temperatures such as summer or daytime to prevent crops from weakening or burning. Many methods of reversal are used. However, in this winding and unwinding work, conventional agricultural vinyl chloride resin films have poor blocking properties, which means that the films do not peel off each other, so the work cannot be progressed or the film is damaged. There was a problem with doing so.
これまではこのブロッキング性の改良の為に、メチレン
ビススアアリルアマイドを塩化ビニル系樹脂１００重量
部に対し、０．１〜１．０重量部程度添加する場合がほ
とんどであったが、いまだに不十分てあり、更にベタツ
ギおよびブロッキング性の改良に効果のあるものが求め
られていた。Until now, in order to improve this blocking property, in most cases methylene bis-searlylamide was added in an amount of about 0.1 to 1.0 parts by weight per 100 parts by weight of vinyl chloride resin, but it still remains undesirable. There was a need for something that had sufficient properties and was also effective in improving stickiness and blocking properties.
また、耐候性については、単に光線による変色劣化の改
善ばかりではなく、はこり何着防止性の改善を望まれて
いた。すなわち、農家においては農業用ビニルフィル１
１を ・年目は天ノ１に使用し、二年目はサイド、二年
目はマルチと長期間使用する傾向があり、長期間の使用
に耐えることが必要であるとともに、二年日以降にフィ
ルムの柔軟性が負しくなる欠点があった。Regarding weather resistance, it was desired not only to improve the discoloration and deterioration caused by light rays, but also to improve the ability to prevent staining and wear. In other words, farmers use agricultural vinyl fill 1
・There is a tendency to use it for a long time as Amano 1 in the first year, side in the second year, and multi in the second year, so it is necessary to withstand long-term use, and However, there was a drawback that the flexibility of the film became negative.
また、寒冷期のフィルムの柔軟性の欠除はフィルムの破
れが発生し易く、大きな問題となっていた。フィルムが
土の中で埋もれる間に、柔軟性が喪失する。いわゆる土
中劣化も同様に使用サイクルが長くなる程問題となって
きていた。In addition, the lack of flexibility of the film during the cold season has caused the film to easily tear, which has been a major problem. While the film is buried in soil, it loses flexibility. Similarly, so-called deterioration in the soil became a problem as the usage cycle became longer.
＋ ／
本発明は」二記の問題を解決するためになされたもので
ある。+ / The present invention has been made in order to solve the problems mentioned in section 2.
７の
本発明は、塩化ビニル系樹脂１００重量部に（１）可塑
剤３０〜８０重量部
（２）バリウム、カルシウム、マグネシウム、亜鉛の少
なくとも・秤量−１−を０．１〜３．０重量部
（３）有機酸性リン酸エステル又はその金属塩の少なく
とも一秤量」−２を０．１〜５．０重量部
（４）炭素数１４以上の高級アルコール化合物又は脂肪
酸グリセリド化合物の少なくとも一種以上を０．Ｏ１〜
３．０重量部
（５）炭素数１４以りの脂肪族基を分子内に・つ以上含
有する有機リン酸ニス・アル又は有機リン酸ニスア・ル
の少なくとも・秤量」二を一ト
０．１〜１０重量部を含有させることを特徴とする農業
用塩化ビニル樹脂組成物を提供するものである。7 of the present invention, (1) 30 to 80 parts by weight of a plasticizer, and (2) 0.1 to 3.0 parts by weight of at least -1- of barium, calcium, magnesium, and zinc to 100 parts by weight of a vinyl chloride resin. Part (3) 0.1 to 5.0 parts by weight of at least one organic acidic phosphate ester or metal salt thereof (4) At least one type of higher alcohol compound having 14 or more carbon atoms or fatty acid glyceride compound 0. O1～
3.0 parts by weight (5) At least 1 to 0.0 parts by weight of organic varnish-alum or organic varnish-al phosphate containing 1 or more aliphatic groups having 14 or more carbon atoms in the molecule. The present invention provides an agricultural vinyl chloride resin composition characterized in that it contains 1 to 10 parts by weight.
本発明の塩化ビニル系樹脂とは、塩化ビニル単独重合体
又は塩化ビニルを主体とした樹脂等であって、例えば塩
化ビニルと、酢酸ビニル・塩化ビニリデン・エチレン・
プロピレン・メタアクリル酸エステル・ウレタン樹脂等
との共重合体やグラフ１４合体、あるいはこれらの樹脂
とのブレンド物等である。The vinyl chloride resin of the present invention is a vinyl chloride homopolymer or a resin mainly composed of vinyl chloride, such as vinyl chloride, vinyl acetate, vinylidene chloride, ethylene, etc.
These include copolymers with propylene, methacrylic acid esters, urethane resins, etc., graph 14 polymers, and blends with these resins.
（１）次に本発明で使用される可塑剤としては、フタル
酸エステル系、アジピン酸エステル系、ポリエステル系
、リン酸エステル系等があるが、例えば、ジオクチルフ
タレ−１・、ジヘ今シルフタレ−１・、ジイソデシルフ
タレ−ト、ジオクチルアジベ−・ト、トリクレジルボス
フェート、トリキシレニルボスフェート等が挙げられる
が、これらは単独あるいは２種以上ＤＩ用して用いられ
る。(1) Next, the plasticizers used in the present invention include phthalate esters, adipate esters, polyesters, phosphate esters, etc. For example, dioctyl phthalate-1, dihemosil phthalate, etc. -1., diisodecyl phthalate, dioctyl adibate, tricresyl bosphate, tricylenyl bosphate, etc., which may be used alone or in combination of two or more for DI.
（２）バリウム、カルシウム、マグネシウム、亜鉛の金
属塩としては、ステアリン酸バリウム、ステアリン酸カ
ルシウム、ステアリン酸マグネシウム、ステアリン酸亜
鉛、バルミチン酸亜鉛、ミリスチン酸亜鉛、ラウリン酸
亜鉛、ベヘニン酸亜鉛、オレイン酸亜鉛、１２−ヒドロ
キシステアリン酸亜鉛、オクチル酸亜鉛、安息香酸バリ
ウム、ｔ−ブチル安息香酸バリウム、石炭酸バリウム、
過塩基性石炭酸バリウム等が挙げられる。(2) Metal salts of barium, calcium, magnesium, and zinc include barium stearate, calcium stearate, magnesium stearate, zinc stearate, zinc valmitate, zinc myristate, zinc laurate, zinc behenate, and zinc oleate. , zinc 12-hydroxystearate, zinc octylate, barium benzoate, barium t-butylbenzoate, barium carbonate,
Examples include overbased barium carbonate.
（３）有機酸性リン酸エステル又はその金属塩としては
、モノスアアリルアシッドホスフエート、モノステアリ
ルアシッドホスフェート亜鉛、モノスアアリルアシッド
ホスフエ−トバリウム、モノスデアリルアシッドボスフ
エートカルシウム、モノスアアリルアシツドホスフエト
マグネシウム、モノステアリルアシッドホスフェートア
ルミニウム、ジスアアリルアシッドボスフエ ト、ジス
テアリルアシッドホスフェート亜鉛、ジスアアリルアシ
ツドホスフェートバリウム、モノラウリルアシツドボス
フェート、モノオクチルアシッドホスフェート、モノベ
ヘニルアシッドボスフェート、バルミチルアシッドボス
フエート、ジシクロへキシルアシントンＪクスフェート
、ジフェニルアシットボスフェ・ １・、ジオレイルア
シッドホスフェ−ト等が挙げられる。これらは通常モノ
体、ジ体の混合物として摺られることが多いが単独で使
用しても、モノ体、ジ体を併用してもさしつかえはない
。(3) Examples of organic acidic phosphoric acid esters or metal salts thereof include monosearlyl acid phosphate, zinc monosearyl acid phosphate, barium monosearyl acid phosphate, calcium monosearlyl acid bosphate, and monosearlyl acid phosphate. Magnesium dophosphate, aluminum monostearyl acid phosphate, disaaryl acid bosphate, zinc distearyl acid phosphate, barium disaaryl acid phosphate, monolauryl acid bosphate, monooctyl acid phosphate, monobehenyl acid bosphate , balmityl acid bosphate, dicyclohexyl athinthone J oxphate, diphenyl acid bosphate, dioleyl acid phosphate, and the like. These are usually printed as a mixture of mono- and di-forms, but there is no problem in using them alone or in combination with mono- and di-forms.
（４）炭素数１４以」二の高級アルコ・ル化合物として
は、ミリスチルアルコール、セチルアルコル、スデアリ
ルアルコール、ベヘニルアルコール、トリアコンタノー
ル、テトラコンタノール、ペンタコンタノ ル等が挙げ
られ、商品名としては花工ｆ１４１のカルコール６０（
Ｃ＝１６）・カルコール８６（Ｃ＝１１３）・カルコー
ル２２０−８０（Ｃ＝２２）、カルコ・−ル２００ＧＤ
（Ｃ＝２０） 、伊藤製油−のハイソコ−・ル＃ ２４
６（Ｃ＝２４〜２６）、東洋ペトロラ、イト■のユニリ
ン＃ ４２５（Ｃ＝３０）・ユニリン＃５５０（Ｃ＝４
０）・ユニリン＃ ７００（Ｃ＝５０）等が挙げられま
た、脂肪酸グリセライド化合物としては、ステアリン酸
ジグリセリド、ステアリン酸ジグリセリド、ステアリン
酸トリグリセリドパルミチン酸モノグリセリド、１２ヒ
ドロキシステアリン酸モノグリセリド、ベヘニン酸モノ
グリセリド、ミリスチン酸モノグリセリド等が挙げられ
る。(4) Higher alcohol compounds having 14 or more carbon atoms include myristyl alcohol, cetyl alcohol, sudearyl alcohol, behenyl alcohol, triacontanol, tetracontanol, pentacontanol, etc. is Karukor 60 (Flower Art F141)
C=16), Calcoal 86 (C=113), Calcoal 220-80 (C=22), Calcoal 200GD
(C=20), Ito Oil's Hysocol #24
6 (C = 24 ~ 26), Toyo Petrola, Ito ■ Unirin # 425 (C = 30) / Unirin # 550 (C = 4
0)・Unilin #700 (C=50), etc. Also, fatty acid glyceride compounds include stearic acid diglyceride, stearic acid diglyceride, stearic acid triglyceride, palmitic acid monoglyceride, 12-hydroxystearic acid monoglyceride, behenic acid monoglyceride, myristic acid Examples include monoglycerides.
（５）炭素数１４以上の脂肪族基を分子内に−・つ以上
含有する有機リン酸エステルとして、トリオレイルホス
フェ−・ト、モノスアアリルジフェニルホスフエート、
モノステアリルジクレジルボスフエ−ト、モノステアリ
ルジキシレニルボスフェート、ジステアリルモノベンジ
ルホスフェート、トリオレイルホスフェ・ト、等が挙げ
られる。(5) As organic phosphoric acid esters containing -. or more aliphatic groups having 14 or more carbon atoms in the molecule, trioleyl phosphate, monosaryl diphenyl phosphate,
Examples include monostearyl dicresyl bosphate, monostearyl dixylenyl bosphate, distearyl monobenzyl phosphate, trioleyl phosphate, and the like.
有機亜リン酸エステルとして、トリミリスチルボスファ
イト、トリバルミチルホスファイト、トリスアアリルボ
スファイト、ジステアリルホスファイト、モノステアリ
ルジフエニルボスファイト、ジステアリルモノフェニル
ホスファイト、アトラスアアリルー・４．／ｌ’イソプ
ロピリデンジフェノールジホスファイト、ジスアアリル
ペンタエリスエト −ルジボスファイト、ジステアリル
チオボスファイト、等が挙げられる。Examples of organic phosphites include trimyristylbosphite, tribalmitylphosphite, trisearylbosphite, distearylphosphite, monostearyldiphenylbosphite, distearylmonophenylphosphite, and atlasarylbosphite.4. /l' isopropylidene diphenol diphosphite, disaaryl pentaerythioethobosphite, distearyl thiobosphite, and the like.
実施例表１〜３の配合物を１８０℃のロールにて５分間
混練し、厚さ０．１ｍｍのフィルムとした。EXAMPLE The formulations shown in Tables 1 to 3 were kneaded for 5 minutes using a roll at 180°C to form a film with a thickness of 0.1 mm.
（ブ１コツキン性）
得られたフィルムを幅３ｃｍに切り取り、これを１０枚
瓜ね合わせて、温度５０℃、湿度９０％の条件下で２り
・月保存後、フィルムどうしを引き剥がずのに要する荷
重（ｇ＞を測定した。(Bulking property) The obtained film was cut into 3 cm wide pieces, 10 pieces were put together and stored for 2 months at a temperature of 50°C and a humidity of 90%. The load (g>) required for this was measured.
数字が小さい方がブロッキング性が良いことを示す。A smaller number indicates better blocking performance.
（耐候性）
得られたフィルムを２年問屋外暴露し、変色状態を目視
で判定した。(Weather resistance) The obtained film was exposed outdoors for two years, and the state of discoloration was visually determined.
判定 ◎ 変色なし
Ｏ僅か変色
△ 変色
× ひどく変色
（はこり１１着）
２年問屋外暴露したシートの未変色部分のほこりによっ
て黒ずんでいる状態を目視で判定した。Judgment: ◎ No discoloration O Slight discoloration △ Discoloration × Severe discoloration (11th grade) The state of darkening due to dust in the undiscolored part of the sheet exposed outdoors for 2 years was visually judged.
判定 ◎ はこり（１着が少ないＯはこりｉ４着
がある
△ はこり付着が多い
× はこり何着が非常に多い
（低温柔軟性）
６り・月間及び１２ケ月問屋外暴露したフィルムをそれ
ぞれ一５°Ｃの低温室に入れ触感にて柔軟性を総合判定
した。Judgment: ◎ There is a lot of flaking (there is a small number of flakes on one coat, there are four coats with flakes) △ There is a lot of flaking × There are very many flakes on the coat (low temperature flexibility) Films exposed outdoors for 6 months and 12 months, respectively. The pieces were placed in a cold room at -5°C and the overall flexibility was evaluated based on the feel.
判定 ○ 柔軟性が残る
△ 普通
× ごわごわする
（土中劣化）
得られたシートを湿潤土中に、６り・月間及び１２ケ月
間埋め、取り出した後触感にて総合判定した。Judgment: ○ Remains flexible △ Normal × Stiff (deterioration in soil) The obtained sheet was buried in moist soil for 6 months and 12 months, and after being taken out, an overall evaluation was made based on the feel.
判定 ◎ 劣化せず ０ （！Ｉｆかに劣化 △ 劣化 × かなり劣化Judgment ◎ No deterioration 0 (!If Crab Deterioration △ Deterioration × Considerably deteriorated
Claims (1)
属塩の少なくとも一種以上を０．１〜３．０重量部 （３）有機酸性リン酸エステル又はその金属塩の少なく
とも一種以上を０．１〜５．０重量部 （４）炭素数１４以上の高級アルコール化合物又は脂肪
酸グリセリド化合物の少なくとも一種以上を０．０１〜
３．０重量部 （５）炭素数１４以上の脂肪族基を分子内に一つ以上含
有する有機リン酸エステル又は有機亜リン酸エステルの
少なくとも一種以上を０．１〜１０重量部を含有させる
ことを特徴とする農業用塩化ビニル樹脂組成物。[Scope of Claims] 100 parts by weight of vinyl chloride resin, (1) 30 to 80 parts by weight of a plasticizer, and (2) 0.1 to 3.0 parts by weight of at least one of the metal salts of barium, calcium, magnesium, and zinc. Part (3) 0.1 to 5.0 parts by weight of at least one organic acidic phosphoric acid ester or metal salt thereof (4) 0.01 part of at least one higher alcohol compound having 14 or more carbon atoms or fatty acid glyceride compound ~
3.0 parts by weight (5) Contain 0.1 to 10 parts by weight of at least one type of organic phosphoric acid ester or organic phosphorous ester containing one or more aliphatic groups having 14 or more carbon atoms in the molecule. An agricultural vinyl chloride resin composition characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63292961A JPH02140254A (en) | 1988-11-18 | 1988-11-18 | Vinyl chloride resin composition for agricultural use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63292961A JPH02140254A (en) | 1988-11-18 | 1988-11-18 | Vinyl chloride resin composition for agricultural use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02140254A true JPH02140254A (en) | 1990-05-29 |
Family
ID=17788665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63292961A Pending JPH02140254A (en) | 1988-11-18 | 1988-11-18 | Vinyl chloride resin composition for agricultural use |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02140254A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014148678A (en) * | 2007-02-23 | 2014-08-21 | Basf Se | Mixtures of n-alkanols and their use |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5513762A (en) * | 1978-07-18 | 1980-01-30 | Adeka Argus Chem Co Ltd | Vinyl chloride resin composition for agricultural application |
| JPS5925827A (en) * | 1982-08-03 | 1984-02-09 | Mitsubishi Monsanto Chem Co | Synthetic resin agricultural covering materials and their usage |
| JPS62270644A (en) * | 1986-05-16 | 1987-11-25 | Sakai Chem Ind Co Ltd | Vinyl chloride resin composition for agricultural film |
-
1988
- 1988-11-18 JP JP63292961A patent/JPH02140254A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5513762A (en) * | 1978-07-18 | 1980-01-30 | Adeka Argus Chem Co Ltd | Vinyl chloride resin composition for agricultural application |
| JPS5925827A (en) * | 1982-08-03 | 1984-02-09 | Mitsubishi Monsanto Chem Co | Synthetic resin agricultural covering materials and their usage |
| JPS62270644A (en) * | 1986-05-16 | 1987-11-25 | Sakai Chem Ind Co Ltd | Vinyl chloride resin composition for agricultural film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014148678A (en) * | 2007-02-23 | 2014-08-21 | Basf Se | Mixtures of n-alkanols and their use |
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