JPH02199806A - Superconducting coil and prepreg semicured tape - Google Patents

Superconducting coil and prepreg semicured tape

Info

Publication number
JPH02199806A
JPH02199806A JP1017637A JP1763789A JPH02199806A JP H02199806 A JPH02199806 A JP H02199806A JP 1017637 A JP1017637 A JP 1017637A JP 1763789 A JP1763789 A JP 1763789A JP H02199806 A JPH02199806 A JP H02199806A
Authority
JP
Japan
Prior art keywords
coil
superconducting
tape
resin
prepreg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1017637A
Other languages
Japanese (ja)
Inventor
Seiji Numata
沼田 征司
Naofumi Tada
直文 多田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP1017637A priority Critical patent/JPH02199806A/en
Publication of JPH02199806A publication Critical patent/JPH02199806A/en
Pending legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E40/00Technologies for an efficient electrical power generation, transmission or distribution
    • Y02E40/60Superconducting electric elements or equipment; Power systems integrating superconducting elements or equipment

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  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PURPOSE:To prevent a cracking of an impregnated resin from being produced by a method wherein a fiberlike filler is mixed with a resin layer between coil conductors. CONSTITUTION:In a superconducting coil 1, a superconducting wire 2 constituted of an NbTi superconducting filament and of stabilized copper is wound in a racetrack shape, and a prepreg semicured tape 5 is wound in one turn at a half-hooked manner between individual layers and on the surface of the coil. This superconducting coil 1 is put in a molding metal mold; while it is being heated, it is molded by executing a three-dimensional pressurization operation. By this pressurization molding operation, a fiberlike filler 6 is extruded, from the prepreg semicured tape 5 wound between coil conductors and on the surface of the coil, between the coil conductors and on the surface of the coil in a state that it is mixed with an epoxy resin 7, and through thermosetting a resin layer 8 is formed. The prepreg semicured tape 5 uses a polyimide film 9 as a base material; both faces are coated with the glass-fiberlike filler 6 to which the epoxy resin 7 mixed with a hardening agent and a solvent has been added; this assembly is heated; the epoxy resin is matured; a resin layer 10 is formed. Thereby, it is possible to prevent a crack of the impregnated resin layer from being produced and to obtain the superconducting coil whose reliability is high and whose current density is high.

Description

【発明の詳細な説明】 (産業上の利用分野〕 本発明は合成樹脂を含浸した超電導コイルに係り、特に
、含浸樹脂のクラックの発生を防止する超電導コイルに
関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a superconducting coil impregnated with a synthetic resin, and particularly to a superconducting coil that prevents cracks from forming in the impregnated resin.

〔従来の技術〕[Conventional technology]

第21iiiに磁気浮上車用超電導コイルの斜視図、第
3図に第2図の■−■矢視断面図を示す。
Fig. 21iii is a perspective view of a superconducting coil for a magnetically levitated vehicle, and Fig. 3 is a sectional view taken along the line ■-■ in Fig. 2.

第2図の従来の樹脂含浸超電導コイル1は、特公昭53
−3904号公報に示されているように、コイル層間、
及び、コイル表面にガラステープを巻き、コイルの外部
から合成樹脂を真空注入し、加圧状態で加熱硬化を行っ
てコイルを成形していた。このようにして製作したコイ
ルは、第3図のように、コイル導体2間に合成樹脂のみ
の厚い層ができ。
The conventional resin-impregnated superconducting coil 1 shown in FIG.
As shown in Publication No. 3904, between the coil layers,
Then, a glass tape was wrapped around the coil surface, a synthetic resin was vacuum injected from the outside of the coil, and the resin was heated and cured under pressure to form the coil. The coil manufactured in this way has a thick layer of only synthetic resin between the coil conductors 2, as shown in Figure 3.

極低温に冷却する時の熱収縮力及び超電導コイルの励磁
による電磁力で樹脂層3にクラック4が発生し、超電導
コイルはクエンチを起こす欠点があった。
Cracks 4 occur in the resin layer 3 due to thermal contraction force when cooling to an extremely low temperature and electromagnetic force due to excitation of the superconducting coil, and the superconducting coil has the drawback of causing quenching.

このようなりラック発生の防止には、含浸樹脂にコイル
を混入すると有効であることが知られているが、超電導
コイルのように、導体を密巻きにするコイルでは、フィ
ラーはコイル表面に溜り導体間までは侵入しない。この
ため、コイル導体間の樹脂層にもクラックが発生し易か
った。
It is known that it is effective to mix the coil into the impregnated resin to prevent the occurrence of racking, but in coils where the conductor is tightly wound, such as superconducting coils, the filler accumulates on the surface of the coil and the conductor Do not intrude into the space. Therefore, cracks were likely to occur in the resin layer between the coil conductors.

以上は真空含浸により樹脂をコイル表面からコイル内部
へ含浸する場合であるが、超電導線の表面に樹脂含浸の
プリプレグセミキュアテープを巻いて用い、これを多数
回巻回してコイルを形成し。
The above is a case where resin is impregnated from the coil surface to the inside of the coil by vacuum impregnation, and a resin-impregnated prepreg semicure tape is wound around the surface of the superconducting wire, and this is wound many times to form a coil.

加熱と加圧を行ってプリプレグセミキュアテープから押
し出される樹脂をコイル内部に含浸する方法がある。こ
の方法で製作したコイルも真空含浸の場合と同様にコイ
ル導体間の樹脂層が厚く、前述と同様に含浸樹脂にクラ
ックが発生し易い欠点がある。
There is a method of impregnating the inside of the coil with resin extruded from prepreg semi-cured tape by applying heat and pressure. The coil manufactured by this method also has the disadvantage that the resin layer between the coil conductors is thick, as in the case of vacuum impregnation, and cracks are likely to occur in the impregnated resin as described above.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

上記従来技術は超電導コイルの導体間樹脂層のクラック
発生の点について十分な考慮がされておらず、超電導コ
イルに加わる電磁応力、及び、熱収縮応力で含浸樹脂層
にクラックが入り、超電導コイルはクエンチを起こす問
題があった。
The above conventional technology does not give sufficient consideration to the occurrence of cracks in the interconductor resin layer of the superconducting coil, and cracks occur in the impregnated resin layer due to electromagnetic stress and thermal shrinkage stress applied to the superconducting coil. There was a problem that caused quenching.

本発明の目的は超電導コイルの含浸樹脂層のクラック発
生を防止し、クエンチを起こさない信頼性の高い高電流
密度の超電導コイルを提供することにある。
An object of the present invention is to provide a highly reliable superconducting coil with high current density that prevents cracks in the impregnated resin layer of a superconducting coil and does not cause quenching.

〔課題を解決するための手段〕[Means to solve the problem]

上記目的を達成するために、本発明では繊維状フィラー
を樹脂に混入したプリプレグセミキュアテープを製造し
、このテープを超電導コイルの層間、表面、あるいは、
導体に巻回し、加熱、及び、加圧を行ってプリプレグセ
ミキュアテープがら押し出される繊維状フィラーの混入
の樹脂をコイル導体間、及び、コイル表面に含浸する。
In order to achieve the above object, the present invention manufactures a prepreg semi-cured tape in which a fibrous filler is mixed into a resin, and uses this tape between the layers of a superconducting coil, on the surface, or on the surface of a superconducting coil.
The conductor is wound, heated, and pressurized to impregnate the space between the coil conductors and the coil surface with a resin mixed with a fibrous filler that is extruded from the prepreg semi-cured tape.

〔作用〕[Effect]

本発明のプリプレグセミキュアチーブはコイル導体間へ
の繊維状フィラーの含浸を可能とする。
The prepreg semi-cured cheese of the present invention allows fibrous filler to be impregnated between coil conductors.

本発明のテープを用いた超電導コイルは、導体間の樹脂
層に繊維状フィラーが絡み合って分散するので、樹脂層
の機械的強度は強化される。それによって、超電導コイ
ルの導体間樹脂層は、超電導コイルを冷却し1通電した
時に発生する熱収縮応力、及び、電磁応力に耐えること
ができ、クラックの発生を防ぐことができる。
In the superconducting coil using the tape of the present invention, the fibrous filler is entangled and dispersed in the resin layer between the conductors, so the mechanical strength of the resin layer is enhanced. Thereby, the interconductor resin layer of the superconducting coil can withstand thermal shrinkage stress and electromagnetic stress that occur when the superconducting coil is cooled and energized once, and can prevent cracks from occurring.

〔実施例〕〔Example〕

以下、本発明の実施例を第1図及び第4図ないし第6図
により説明する。
Embodiments of the present invention will be described below with reference to FIG. 1 and FIGS. 4 to 6.

第1図において、超電導コイル1はNbTiの超電導フ
ィラメントと安定化鋼で構成された直径1.5 mの超
電導線2をレーストラック形状に一千ターン以上巻回し
、コイルの各層間、及び、表面には本発明のプリプレグ
セミキュアテープ5が半掛けで一回巻かれている。この
超電導コイル1は成形型に入れ、加熱しながらプレスに
より三方向からの三次元加圧を行って成形する。この加
圧成形によって、コイル導体間、及び、コイル表面に巻
かれたプリプレグセミキュアテープ5から繊維状フィラ
ー6がエポキシ樹脂7に混入された状態でコイル導体°
間、及び、コイル表面に押し出され、加熱硬化によって
樹脂層8が形成される。この樹脂層の機械的強度は、繊
維状フィラーと樹脂とがからみ合うので、従来に比べて
約二倍に強化される。
In Fig. 1, a superconducting coil 1 consists of a superconducting wire 2 with a diameter of 1.5 m made of NbTi superconducting filament and stabilizing steel, which is wound in a racetrack shape with more than 1,000 turns. The prepreg semi-cured tape 5 of the present invention is wrapped once in half. This superconducting coil 1 is placed in a mold, and is molded by applying three-dimensional pressure from three directions using a press while heating. By this pressure forming, the coil conductor is formed with the fibrous filler 6 mixed into the epoxy resin 7 from the prepreg semi-cured tape 5 wound between the coil conductors and on the coil surface.
A resin layer 8 is formed by extruding the resin layer 8 between the layers and onto the surface of the coil and heating and curing the resin layer 8 . Since the fibrous filler and resin are intertwined, the mechanical strength of this resin layer is approximately doubled compared to the conventional method.

第4図は本発明のプリプレグセミキュアチーブの断面を
示す、プリプレグセミキュアテープ5の基材には50μ
m厚さのポリイミドフィルム9を用い、両面に10μm
径のガラス繊維を約1mの長さに切断した繊維状フィラ
ー6を、硬化剤、及び、溶剤の混入したエポキシ樹脂7
に20%(重量%)混入して塗布し、90〜100℃で
約−時間加熱してエポキシ樹脂を熟成させ、50μm厚
さの繊維状フィラー6の混入した樹脂層10を設ける。
FIG. 4 shows a cross section of the prepreg semi-cure tape 5 of the present invention.
m-thick polyimide film 9, with 10 μm on both sides.
A fibrous filler 6 obtained by cutting a glass fiber with a diameter of about 1 m into a length of about 1 m is mixed with an epoxy resin 7 mixed with a hardening agent and a solvent.
The epoxy resin is coated with 20% (wt%) mixed therein and heated at 90 to 100° C. for about an hour to age the epoxy resin, thereby providing a resin layer 10 having a thickness of 50 μm and containing the fibrous filler 6.

本実施例では基材に極低温下で電気絶縁性が良く機械的
強度の大きいポリイミドフィルムを用いたが、この他に
ポリビニルホルマール、ポリエステル、ポリアミド及び
アラミドの各合成フィルムもポリイミドフィルムと同様
の特性であるので、同様の効果が得られる。含浸樹脂の
クラック発生の防止に重点をおくならば、ガラスクロス
等の繊維布も基材として好適である。この他に極低温下
で機械的強度の大きいポリイミド、ポリビニルホルマー
ル、ポリエステル、ポリアミド、及び、アラミドの各合
成繊維布も好適である9コイル導体間の樹脂層の機械的
強度向上には、一般に用いられている粉末状フィラーは
効果がなく、繊維状フィラーは効果が大きい。合成樹脂
に含浸する繊維状フィラーとしては、エポキシ樹脂等の
合成樹脂との接着性が良く、極低温下での機械的強度の
大きい材料が好適である6ガラス繊維フイラーは合成樹
脂との接着性が良く、これを混入した樹脂層の機械的強
度は向上することから好適である。この他に前述の合成
繊維は合成樹脂との接着性が良く、極低温下での機械的
強度が大きいことから好適である。
In this example, polyimide film, which has good electrical insulation and high mechanical strength at extremely low temperatures, was used as the base material, but other synthetic films such as polyvinyl formal, polyester, polyamide, and aramid also have the same properties as polyimide film. Therefore, similar effects can be obtained. If emphasis is placed on preventing the occurrence of cracks in the impregnated resin, fiber cloth such as glass cloth is also suitable as the base material. In addition, synthetic fiber cloths such as polyimide, polyvinyl formal, polyester, polyamide, and aramid, which have high mechanical strength at extremely low temperatures, are also suitable.9 They are generally used to improve the mechanical strength of the resin layer between the coil conductors. Powder fillers are ineffective, while fibrous fillers are highly effective. As a fibrous filler to be impregnated into a synthetic resin, a material that has good adhesion with synthetic resins such as epoxy resin and has high mechanical strength at extremely low temperatures is suitable.6 Glass fiber fillers have good adhesion with synthetic resins. This is preferable because it improves the mechanical strength of the resin layer containing it. In addition, the aforementioned synthetic fibers are suitable because they have good adhesion to synthetic resins and have high mechanical strength at extremely low temperatures.

含浸樹脂は機械的強度、電気特性が良好で、接着力が大
きく5熱収縮率が他の樹脂に比べて小さいエポキシ樹脂
、及び、ポリエステル樹脂が好適である。
The impregnating resin is preferably an epoxy resin or a polyester resin, which has good mechanical strength and electrical properties, has a large adhesive force, and has a low heat shrinkage rate compared to other resins.

第5図は本発明の変形例で、超電導線の表面に第4図に
示した繊維状フィラー混入のプリプレグセミキュアチー
ブ5を半掛けで一回巻き、この超電導線を多数回巻回し
て超電導コイルを形成し、加熱及び三次元加圧を行って
コイル導体間、及び、コイル表面に繊維状フィラー混入
樹脂を押し出して含浸する。これによって含使樹脂層8
の機械的強度は従来の約二倍に強化され、コイル導体間
の絶縁性を改善することができる。
FIG. 5 shows a modification of the present invention, in which prepreg semi-cured chives 5 containing fibrous filler shown in FIG. A coil is formed, and heated and three-dimensionally pressurized to extrude and impregnate the fibrous filler-containing resin between the coil conductors and onto the coil surface. As a result, the resin layer 8
The mechanical strength of the coil is approximately twice that of the conventional one, and the insulation between the coil conductors can be improved.

第6図は本発明の効果を従来例と比較したもので、縦軸
に従来例を1.0 とした場合のコイル電流密度をとり
、横軸に従来例を1.0  とした場合の磁界をとって
、コイル電流密度と磁界との関係を示した。
Figure 6 compares the effects of the present invention with the conventional example. The vertical axis shows the coil current density when the conventional example is set to 1.0, and the horizontal axis shows the magnetic field when the conventional example is set to 1.0. The relationship between the coil current density and the magnetic field was shown.

すなわち、本実施例の超電導コ・イルの特性Pは。That is, the characteristic P of the superconducting coil of this example is as follows.

従来例の特性Qに比べてコイル電流密度が大きく優れて
おり、短尺線材の特性Rに近い特性になっている。すな
わち、従来の超電導コイルはコイル電流密度が1バーユ
ニツト(P、U)でクエンチを起こすのに対し、本実施
例の超電導コイルではコイル電流密度が1.2バーユニ
ツトでクエンチを起こすようになる。
The coil current density is greatly superior to the characteristic Q of the conventional example, and the characteristic is close to the characteristic R of a short wire. That is, while the conventional superconducting coil quenches when the coil current density is 1 bar unit (P, U), the superconducting coil of this embodiment causes quenching when the coil current density reaches 1.2 bar units.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、磁気浮上車に搭載する超電導コイルの
内部、及び、表面の樹脂層に繊維状のフィラーを混入し
てクラックの発生を起こり難くシたので、極低温下での
熱収縮力、及び、電磁力にも耐えることができ、高電流
密度で信頼性の高い磁気浮上車用超電導コイルを提供す
ることができる。
According to the present invention, fibrous filler is mixed into the inside of the superconducting coil mounted on the magnetically levitated vehicle and into the resin layer on the surface to make it difficult for cracks to occur. Furthermore, it is possible to provide a superconducting coil for a magnetically levitated vehicle that can withstand electromagnetic force, has a high current density, and is highly reliable.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例の超電導コイル断面図、第2
図は従来の磁気浮上車用超電導コイルの斜視図、第3図
は従来の磁気浮上車用超電導コイルの断面図、第4図は
本発明の超電導コイルに使用したプリプレグセミキュア
テープの断面図、第5図は本発明の他の実施例の超電導
コイルの断面図、第6図は本発明の超電導コイルの一実
施例と従来例のコイル電流密度と磁界との関係を示す特
性図である。 1・・・超電導コイル、2・・・超電導線、5・・・プ
リプレグセミキュアテープ、6・・・繊維状フィラー、
1゜第 ! 口 茶 第3 囚 第41iJ 茶5
Fig. 1 is a sectional view of a superconducting coil according to an embodiment of the present invention;
The figure is a perspective view of a conventional superconducting coil for a magnetic levitation vehicle, FIG. 3 is a sectional view of a conventional superconducting coil for a magnetic levitation vehicle, and FIG. 4 is a sectional view of a prepreg semicured tape used in the superconducting coil of the present invention. FIG. 5 is a sectional view of a superconducting coil according to another embodiment of the present invention, and FIG. 6 is a characteristic diagram showing the relationship between coil current density and magnetic field of one embodiment of the superconducting coil of the present invention and a conventional example. DESCRIPTION OF SYMBOLS 1... Superconducting coil, 2... Superconducting wire, 5... Prepreg semi-cured tape, 6... Fibrous filler,
1st degree! Kuchicha No. 3 Prisoner No. 41iJ Cha 5

Claims (5)

【特許請求の範囲】[Claims] 1.超電導線を多数回巻回し、合成樹脂を含浸した密巻
きの超電導コイルにおいて、 コイル導体間の樹脂層に繊維状のフィラーを混入したこ
とを特徴とする超電導コイル。
1. A tightly wound superconducting coil made by winding a superconducting wire many times and impregnating it with synthetic resin, which is characterized by having a fibrous filler mixed into the resin layer between the coil conductors.
2.前記超電導コイルの層間に、前記繊維状フィラー混
入のプリプレグセミキユアテープを巻き、加熱及び加圧
を行つてコイルを成形することを特徴とする特許請求項
第1項記載の超電導コイル。
2. The superconducting coil according to claim 1, wherein the prepreg semi-cure tape containing the fibrous filler is wound between the layers of the superconducting coil, and the coil is formed by heating and pressurizing.
3.超電導線の表面に繊維状フィラー混入のプリプレグ
セミキユアテープを巻き、前記超電導線を多数回巻回し
て前記電導コイルを形成し、加熱及び加圧を行つてコイ
ルを成形することを特徴とする特許請求項第1項記載の
超電導コイル。
3. A prepreg semi-cure tape containing a fibrous filler is wound on the surface of the superconducting wire, the superconducting wire is wound many times to form the conductive coil, and the coil is formed by heating and pressurizing. A superconducting coil according to claim 1.
4.特許請求項第2項または第3項において、合成フィ
ルム又は繊維布を基材として、これに繊維状フィラーを
混入した合成樹脂を塗布、又は、含浸したことを特徴と
するプリプレグセミキユアテープ。
4. A prepreg semi-cure tape according to claim 2 or 3, characterized in that a synthetic film or fiber cloth is used as a base material and is coated or impregnated with a synthetic resin mixed with a fibrous filler.
5.特許請求項第4項において、 テープ基材はポリイミド、ポリビニルホルマール、ポリ
エステル、ポリアミド及びアラミドの合成フィルム、又
は、合成繊維布、あるいは、ガラス繊維布を用い、繊維
状フィラーは前記テープ基材の材質であるフィラーを用
い、合成樹脂にはエポキシ樹脂、あるいは、ポリエステ
ル樹脂を用いることを特徴とするプリプレグセミキユア
テープ。
5. In claim 4, the tape base material is a synthetic film of polyimide, polyvinyl formal, polyester, polyamide, or aramid, or synthetic fiber cloth, or glass fiber cloth, and the fibrous filler is made of a material of the tape base material. A prepreg semi-cure tape characterized in that it uses a filler that is , and an epoxy resin or a polyester resin is used as the synthetic resin.
JP1017637A 1989-01-30 1989-01-30 Superconducting coil and prepreg semicured tape Pending JPH02199806A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1017637A JPH02199806A (en) 1989-01-30 1989-01-30 Superconducting coil and prepreg semicured tape

Applications Claiming Priority (1)

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JP1017637A JPH02199806A (en) 1989-01-30 1989-01-30 Superconducting coil and prepreg semicured tape

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JPH02199806A true JPH02199806A (en) 1990-08-08

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005340637A (en) * 2004-05-28 2005-12-08 Toshiba Corp Superconducting coil
JP2020031128A (en) * 2018-08-22 2020-02-27 株式会社東芝 Superconducting coil and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005340637A (en) * 2004-05-28 2005-12-08 Toshiba Corp Superconducting coil
JP2020031128A (en) * 2018-08-22 2020-02-27 株式会社東芝 Superconducting coil and manufacturing method thereof

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