JPH02220946A - Cover for containing air bag - Google Patents
Cover for containing air bagInfo
- Publication number
- JPH02220946A JPH02220946A JP1042733A JP4273389A JPH02220946A JP H02220946 A JPH02220946 A JP H02220946A JP 1042733 A JP1042733 A JP 1042733A JP 4273389 A JP4273389 A JP 4273389A JP H02220946 A JPH02220946 A JP H02220946A
- Authority
- JP
- Japan
- Prior art keywords
- core layer
- hardness
- jis
- cover
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 62
- 239000012792 core layer Substances 0.000 claims abstract description 51
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 13
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 12
- 238000005452 bending Methods 0.000 claims abstract description 7
- 238000003860 storage Methods 0.000 claims description 34
- 229920001971 elastomer Polymers 0.000 claims description 31
- 239000005060 rubber Substances 0.000 claims description 27
- 150000001336 alkenes Chemical class 0.000 claims description 16
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 239000012634 fragment Substances 0.000 abstract description 6
- 238000003776 cleavage reaction Methods 0.000 abstract description 4
- 230000007017 scission Effects 0.000 abstract description 4
- 210000003491 skin Anatomy 0.000 description 43
- 238000000034 method Methods 0.000 description 18
- 238000000465 moulding Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 16
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 11
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000011162 core material Substances 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 101710194092 Thiamine-phosphate synthase 1 Proteins 0.000 description 5
- 229920001400 block copolymer Polymers 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 229920005601 base polymer Polymers 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 229920005672 polyolefin resin Polymers 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 239000012779 reinforcing material Substances 0.000 description 4
- 229920003051 synthetic elastomer Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 210000002615 epidermis Anatomy 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920006465 Styrenic thermoplastic elastomer Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010097 foam moulding Methods 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 241000705989 Tetrax Species 0.000 description 1
- 101710194099 Thiamine-phosphate synthase 2 Proteins 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011981 development test Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000010550 living polymerization reaction Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
- B60R21/20—Arrangements for storing inflatable members in their non-use or deflated condition; Arrangement or mounting of air bag modules or components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Air Bags (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は車両衝突時にその衝撃、変形等を感知すること
により、動作膨張して展開するエアーバックを収納する
ためのカバーに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a cover for accommodating an air bag that is inflated and deployed by sensing the impact, deformation, etc. at the time of a vehicle collision.
[従来の技術]
この種のカバーとしては、エアーバック動作(膨張)時
に、それを収納しているカバーが破砕され、その破片が
飛散して乗員の顔又は目等に当って怪我をさせる危険が
あることから、従来のものは、破片飛散防止を目的とし
て補強材(ネット等)がインサートされているのが一般
的であった。(特開昭62−234764、特開昭5〇
−127336、実開昭52−80928、実開昭50
−43454、実開昭51−25342号公報等)。[Prior Art] This type of cover has the risk that when the airbag is activated (inflated), the cover containing the airbag will be crushed, and the fragments will fly off and hit the occupant's face or eyes, causing injury. Because of this, conventional products generally have a reinforcing material (such as a net) inserted in order to prevent fragments from scattering. (JP-A-62-234764, JP-A-50-127336, JP-A-52-80928, JP-A-Sho 50
-43454, Utility Model Application Publication No. 51-25342, etc.).
このようなネット状インサートを入れたカバーは、通常
、発泡ポリウレタン等の比較的低強度の材料でカバー全
体を作り、補強材ネットをこのカバー全体にインサート
して製造されるが、この際エアーバック膨張時にこれが
スムーズに展開してカバーが容易に破壊されるべく該補
強材ネットをインサートしないラインを設けるのが一般
的である。Covers with such net-like inserts are usually manufactured by making the entire cover out of a relatively low-strength material such as polyurethane foam, and inserting a reinforcing net into the entire cover. It is common to provide a line in which the reinforcing material net is not inserted so that the reinforcing material net can be easily expanded and the cover easily destroyed when inflated.
一方、実開昭52−76042号公報には、表面をきれ
いに仕上げるための硬質ウレタン発泡体からなる表皮層
と、カバー全体をやわらかくするため低密度(高倍率発
泡)ウレタン発泡体のコア層との2層からなり、該コア
層から表皮の一部に達するスリット(エアーバック膨張
時にスムーズに展開させるためのライン)を備えたエア
ーバック収納用カバーが提案されている。On the other hand, Japanese Utility Model Application Publication No. 52-76042 discloses that a skin layer made of hard urethane foam is used to finish the surface neatly, and a core layer is made of low-density (high-magnification foamed) urethane foam to make the entire cover soft. An airbag storage cover has been proposed that is composed of two layers and includes a slit (a line for smoothly deploying the airbag when the airbag is inflated) that extends from the core layer to a part of the skin.
[発明が解決しようとする課題]
上記従来のエアーバック収納用カバーのうち、ネット状
インサートを入れたエアーバック収納用カバーは、ネッ
ト状の補強材をインサートするため、製作工数が多く煩
雑であり、また、たとえウレタン発泡成形(RI M)
を用いても高い精度で製造するのが困難であり、歩留ま
りが低く、かつコスト高であるという問題があった。[Problems to be Solved by the Invention] Among the above-mentioned conventional air bag storage covers, the air bag storage cover with a net-like insert inserts a net-like reinforcing material, which requires a large number of manufacturing steps and is complicated. , Also, even if urethane foam molding (RIM)
Even with the use of the same method, it is difficult to manufacture with high precision, and there are problems in that the yield is low and the cost is high.
また実開昭52−76042号公報に開示されるカバー
は、表皮が硬質ウレタン発泡体(ASTM−D2240
、ショア硬度が30〜40)であるため、車両運転中な
どに身体の一部が当たると柔らかみが感じられずに不快
感が催される。更に、ウレタン系材料は衝撃強度が低く
、補強材インサートがないため、エアーバック膨張時に
破片が飛散することがあるという欠点もあった。Furthermore, the cover disclosed in Japanese Utility Model Application Publication No. 52-76042 has a surface made of hard urethane foam (ASTM-D2240
, Shore hardness is 30 to 40), so if a part of your body hits it while driving a vehicle, you will not feel the softness and will feel uncomfortable. Additionally, urethane-based materials have low impact strength and lack of reinforcing inserts, which can cause debris to fly when the airbag is inflated.
本発明は、上記従来のエアーバック収納用カバーの問題
点を解決し、表皮層は柔らかくソフト感を与え、コア層
は外圧に耐え得る形状を保持し、かつ、−40℃かう+
80℃の温度範囲において、エアーバック動作膨張時に
は容易に破壊されるが破片飛散することがないだけでな
く、実車装着を考慮し、110℃、500時間という長
時間高温下においた後においても上記温度範囲で同様の
良好な破壊性能を示し、外観変化も殆どないような品質
を有するエアーバック収納用カバーであって、射出成形
のような簡易な成形法により、不良品の出ない方法で高
い歩留りにて、高精度に、かつ、高い生産性、良好な経
済性をもって供給することができるエアーバック収納用
カバーを提供することを目的とする。The present invention solves the above-mentioned problems of conventional air bag storage covers, the skin layer gives a soft feel, the core layer maintains a shape that can withstand external pressure, and has a temperature range of -40°C.
In a temperature range of 80 degrees Celsius, the airbag is easily destroyed when inflated, but not only does it not scatter fragments, but it also remains the same even after being exposed to high temperatures of 110 degrees Celsius for 500 hours in consideration of actual vehicle installation. This is a cover for airbag storage that has the same good breaking performance in the temperature range and has almost no change in appearance, and is manufactured using a simple molding method such as injection molding that does not produce defective products. It is an object of the present invention to provide an air bag storage cover that can be supplied with high yield, high precision, high productivity, and good economic efficiency.
[課題を解決するための手段]
請求項(1)のエアーバック収納用カバーは、炭化水素
系ゴム用軟化剤を含有し、かつ、JIS−に6301の
JIS−A硬度が20〜90の熱可塑性ポリマーからな
る表皮層と、J I S−に7203の曲げ弾性率が1
000kg/cm2以上の熱可塑性樹脂からなるコア層
とを有し、該コア層は前記表皮層より硬度が高く、かつ
、該コア層には、エアーバック動作開始のとき容易に開
裂するための部分が付されていることを特徴とする
請求項(2)のエアーバック収納用カバーは、JIS−
に6301のJ I S−A硬度が20〜90の熱可塑
性ポリマーからなる表皮層と、オレフィン系ゴムを含有
し、かつ、J I S−に7203の曲げ弾性率が10
00 k g / c rn”以上の熱可塑性樹脂から
なるコア層とを有し、該コア層は前記表皮層より硬度が
高く、かつ、該コア層には、エアーバック動作開始のと
き容易に開裂するための部分が付されていることを特徴
とする特
請求項(3)のエアーバック収納用カバーは、炭化水素
系ゴム用軟化剤を含有し、かつ、JIS−に6301の
JIS−A硬度が20〜90の熱可塑性ポリマーからな
る表皮層と、オレフィン系ゴムを含有し、かつ、JIS
−に7203の曲げ弾性率が1000kg/cm”以上
の熱可塑性樹脂からなるコア層とを有し、該コア層は前
記表皮層より硬度が高く、かつ、該コア層には、エアー
バック動作開始のとき容易に開裂するための部分が付さ
れていることを特徴とする。[Means for Solving the Problem] The air bag storage cover of claim (1) contains a hydrocarbon rubber softener and has a JIS-A hardness of 20 to 90 according to JIS-6301. The skin layer is made of a plastic polymer and the flexural modulus of JIS-7203 is 1.
000 kg/cm2 or more, the core layer has a harder hardness than the skin layer, and the core layer has a portion that easily ruptures when the airbag starts operating. The air bag storage cover according to claim (2) is characterized in that it is affixed with JIS-
It contains a skin layer made of a thermoplastic polymer with a JIS-A hardness of 20 to 90 according to JIS-6301, and an olefin rubber, and has a flexural modulus of JIS-7203 of 10.
00 kg/c rn" or more, the core layer has higher hardness than the skin layer, and the core layer has a layer that is easily ruptured when the airbag starts operating. The air bag storage cover according to claim 3, characterized in that it has a part for hardening, contains a softening agent for hydrocarbon rubber, and has a JIS-A hardness of 6301 in accordance with JIS-6301. contains a skin layer made of a thermoplastic polymer with a diameter of 20 to 90, an olefin rubber, and a JIS
- a core layer made of a thermoplastic resin having a flexural modulus of 7203 of 1000 kg/cm or more, the core layer having a higher hardness than the skin layer; It is characterized by having a part attached to it for easy cleavage.
即ち、本発明者らは、前記目的を達成すべく、鋭意検討
を重ねた結果、特定の表皮層と特定のコア層とを採用し
、かつ、コア層に開裂容易な部分、例えば脆弱形状を施
すことによって上記目的が達成されることを見出し、本
発明を完成させた。That is, in order to achieve the above object, the inventors of the present invention have made extensive studies, and have adopted a specific skin layer and a specific core layer, and provided the core layer with an easily cleavable portion, for example, a brittle shape. The inventors have discovered that the above object can be achieved by applying the above-mentioned methods, and have completed the present invention.
以下に本発明を図面を参照して詳細に説明する。The present invention will be explained in detail below with reference to the drawings.
第1図は本発明の実施例に係るエアーバック収納用カバ
ーがエアーバックに装着された状態を示す概略的な部分
断面正面図であり、第2図はエアーバック収納用カバー
の背面図である。FIG. 1 is a schematic partial sectional front view showing a state in which an air bag storage cover according to an embodiment of the present invention is attached to an air bag, and FIG. 2 is a rear view of the air bag storage cover. .
図中、1はエアーバック収納用カバー 2はエアーバッ
ク、3はインフレータ−4はリングリテーナ、5はペー
スリテーナ、6はプレート、7はリベット、IAは表皮
層、IBはコア層、ICはミシン目状スリットである。In the figure, 1 is an air bag storage cover, 2 is an air bag, 3 is an inflator, 4 is a ring retainer, 5 is a pace retainer, 6 is a plate, 7 is a rivet, IA is a skin layer, IB is a core layer, and IC is a sewing machine. It is an eye-shaped slit.
図示の如く、本発明のエアーバック収納用カバー1は、
表皮層IAとして、炭化水素系ゴム用軟化剤を含有し、
或いは含有せず、かつ、JIS−に6301のJIS−
A硬度が20〜90の熱可塑性ポリマーからなる表皮層
を用いている。表皮層IAの炭化水素系ゴム用軟化剤の
含有量は30重量%以下が適当であり、熱可塑性ポリマ
ーとしてはオレフィン系熱可塑性エラストマー及び/又
はスチレン系熱可塑性エラストマーが好適である。As shown in the figure, the air bag storage cover 1 of the present invention includes:
The skin layer IA contains a softener for hydrocarbon rubber,
Or it does not contain and JIS-6301 JIS-
A skin layer made of a thermoplastic polymer having an A hardness of 20 to 90 is used. The content of the hydrocarbon rubber softener in the skin layer IA is suitably 30% by weight or less, and the thermoplastic polymer is suitably an olefin thermoplastic elastomer and/or a styrene thermoplastic elastomer.
一方、コア層IBとしては、オレフィン系ゴムを含有し
、或いは含有せず、かつ、J I S−に7203の曲
げ弾性率が110001c/crn”以上の熱可塑性樹
脂からなるコア層を用いている。コア層IBのオレフィ
ン系ゴムの含有量は60重量%以下が適当であり、熱可
塑性樹脂としてはオレフィン系樹脂が好適である。On the other hand, as the core layer IB, a core layer made of a thermoplastic resin containing or not containing olefin rubber and having a flexural modulus of JIS-7203 of 110001c/crn" or more is used. The content of the olefin rubber in the core layer IB is suitably 60% by weight or less, and the thermoplastic resin is preferably an olefin resin.
このコア層IBは表皮層IAより硬度が高く、かつ該コ
ア層IBには、エアーバック動作開始のとき容易に開裂
するための部分として、脆弱形状IC1例えばノツチ状
肉薄形状、ミシン目状のスリット形状等が施されている
ものである。This core layer IB has a higher hardness than the skin layer IA, and the core layer IB has a fragile shape IC1, such as a thin notch shape or a perforated slit, as a part to easily rupture when the airbag operation starts. It has a certain shape, etc.
本発明において、表皮層IAの構成材料とする炭化水素
系ゴム用軟化剤を含有し、或いは含有せず、かつ、JI
S−に6301のJIS−A硬度が20〜90のオレフ
ィン系熱可塑性エラストマーとしては、オレフィン系ゴ
ム、例えば、EPM%EPDM、エチレン−ブテン−1
共重合体ゴム等とオレフィン系樹脂、例えばポリプロピ
レン、ポリエチレン等を必要に応じて所定量の炭化水素
系ゴム用軟化剤、例えばパラフィン系オイル、ナフテン
系オイル等と、更に、場合により無機フィラー、例えば
炭酸カルシウム、シリカ、タルク等の各種充填剤、着色
剤、安定剤等を充填した複合物、又は、特開昭46−2
683+3、特開昭52−13541.特開昭52−3
7953、特開昭56−98248等に示された製法に
より製造される、部分的に架橋構造を有するものが好適
である。In the present invention, the surface layer IA contains or does not contain a softener for hydrocarbon rubber as a constituent material, and is compliant with JI
As the olefin thermoplastic elastomer having a JIS-A hardness of 20 to 90 in S-6301, olefin rubber such as EPM%EPDM, ethylene-butene-1
A copolymer rubber or the like and an olefin resin such as polypropylene or polyethylene, if necessary, a predetermined amount of a softener for hydrocarbon rubber such as paraffin oil or naphthenic oil, and optionally an inorganic filler such as Compounds filled with various fillers such as calcium carbonate, silica, talc, colorants, stabilizers, etc., or JP-A-46-2
683+3, JP-A-52-13541. JP-A-52-3
7953, JP-A No. 56-98248, etc., and which have a partially crosslinked structure are suitable.
また、表皮層IAに用いることができる上記性能を有す
るスチレン系エラストマーとしては、モノビニル芳香族
炭化水素の重合体ブロックと共役ジエンのエラストマー
性重合体ブロックからなるブロック共重合体又はその水
素添加誘導体をベースポリマーとした熱可塑性エラスト
マーが挙げられる。これらのベースポリマーは、リチウ
ム系触媒を用いたリビング重合等の常法にて得ることが
できる。なかでもスチレン重合体ブロックとブタジェン
及び/又はイソプレンの重合体ブロックからなるものの
水素添加誘導体をベースポリマーとしたものが、耐候性
、耐熱老化性、柔軟調節性等の点で好ましい。In addition, as a styrenic elastomer having the above-mentioned properties that can be used for the skin layer IA, a block copolymer consisting of a monovinyl aromatic hydrocarbon polymer block and a conjugated diene elastomeric polymer block or a hydrogenated derivative thereof is used. Examples include thermoplastic elastomers as base polymers. These base polymers can be obtained by conventional methods such as living polymerization using a lithium catalyst. Among these, those in which the base polymer is a hydrogenated derivative of a styrene polymer block and a butadiene and/or isoprene polymer block are preferred in terms of weather resistance, heat aging resistance, flexibility controllability, and the like.
より具体的には、表皮層IAを構成するスチレン系熱可
塑性エラストマーとしては、上記のベースポリマーに各
種熱可塑性樹脂、例えばオレフィン系樹脂、スチレン系
樹脂等と、場合により、前記のオレフィン系エラストマ
ーと同様の所定量の炭化水素系ゴム用軟化剤、無機フィ
ラー等を必要に応じて複合して硬度等の品質をコントロ
ールしたものが好適である。More specifically, the styrenic thermoplastic elastomer constituting the skin layer IA includes the above base polymer, various thermoplastic resins such as olefin resins, styrene resins, etc., and optionally the above olefin elastomer. Preferably, a similar predetermined amount of a softener for hydrocarbon rubber, an inorganic filler, etc. is combined as necessary to control quality such as hardness.
表皮層IAの構成材料としては、前記のオレフィン系、
スチレン系熱可塑性エラストマーをそれぞれ単独で用い
る場合に限らず、これらを適当な比率で混合して用いる
こともできる。The constituent materials of the epidermal layer IA include the above-mentioned olefins,
The styrenic thermoplastic elastomers are not limited to being used alone, but may also be used as a mixture in an appropriate ratio.
表皮層IAの炭化水素系ゴム用軟化剤の含有量は、前述
の如く、30重量%以下が望ましいが、炭化水素系ゴム
用軟化剤が30重量%を超えるものは、110℃、50
0時間時間後、外観不良(変形等)を起こし、また、−
40℃でのエアーバック膨張時に破壊不良、即ち、所定
の脆弱部以外の箇所での破壊や破片の飛散等が発生する
という問題がある。As mentioned above, the content of the hydrocarbon rubber softener in the skin layer IA is preferably 30% by weight or less, but if the content of the hydrocarbon rubber softener exceeds 30% by weight,
After 0 hours, appearance defects (deformation, etc.) occur, and -
There is a problem in that when the air bag is inflated at 40° C., fracture failure occurs, that is, fracture occurs at locations other than the predetermined fragile portions, and fragments are scattered.
炭化水素系ゴム用軟化剤の量としては、上述の問題点の
他、硬度(ソフト感)、成形加工性を考慮する必要があ
るが、これらを勘案した場合、好ましくは20重量%以
下、更に好ましくは10重量%以下の範囲であり、これ
を添加する場合の下限値は、最終品質の点からみて、好
ましくは1重量%、より好ましくは3重量%である。As for the amount of softener for hydrocarbon rubber, in addition to the above-mentioned problems, it is necessary to consider hardness (soft feel) and moldability, but when these are taken into consideration, it is preferably 20% by weight or less, and The range is preferably 10% by weight or less, and the lower limit when adding this is preferably 1% by weight, more preferably 3% by weight from the viewpoint of final quality.
本発明において、表皮層IAを構成する熱可塑性ポリマ
ーとしては、JIS−A硬度で20〜90のものが選定
されるが、硬度が上記範囲未満のものは、柔軟性に富む
が、成形加工性(例えば、射出成形性)、機械的強度に
劣り破損し易いという欠点がある。また、硬度が上記範
囲を超えるものは、成形加工性は問題ないが、ソフト感
に劣り実用的ではないという欠点を有する。硬度20〜
90の範囲内での硬度選択は、表皮層の肉厚によっても
変化するが、好ましくは硬度30〜70の範囲、より好
ましくは硬度40〜65の範囲とするのが望ましい。In the present invention, the thermoplastic polymer constituting the skin layer IA is selected from those with a JIS-A hardness of 20 to 90, but those with hardness below the above range are highly flexible but have poor moldability. (For example, injection moldability), mechanical strength is poor and easy to break. Further, those having a hardness exceeding the above range have no problem in molding processability, but have the disadvantage that they have a poor soft feel and are not practical. Hardness 20~
The selection of hardness within the range of 90 varies depending on the thickness of the skin layer, but it is preferably in the range of 30 to 70, more preferably in the range of 40 to 65.
表皮層IAの肉厚は、通常カバー1の部位により異なり
、全体にわたって全く均一であることばないが、本発明
においては、表皮層IAの表面積の70%以上の部分、
好ましくは80%以上の部分が厚さ0.5mm以上であ
ることが好適である。肉厚の上限は特にないが、デザイ
ン、経済面、ソフト感、エアーバックの動作性能、成形
加工面等から10mm程度以下とするのが適当である。The thickness of the epidermis layer IA usually varies depending on the part of the cover 1 and is not completely uniform over the entire cover, but in the present invention, the thickness of the epidermis layer IA is 70% or more of the surface area,
Preferably, 80% or more of the portion has a thickness of 0.5 mm or more. Although there is no particular upper limit to the wall thickness, it is appropriate to set it to about 10 mm or less in consideration of design, economy, soft feel, airbag operating performance, molding process, etc.
また、表皮層IAはソフト感、軽量化を改善する目的で
、3.0倍径度以下の発泡を施してあっても良い。Further, the skin layer IA may be foamed to a diameter of 3.0 times or less for the purpose of improving the soft feel and weight reduction.
本発明において、コア層IBの構成材料として用いる、
オレフィン系ゴムを含有し、或いは含有せず、JIS−
に7203の曲げ弾性率が1000kg/cm’以上で
、かつ前記表皮層IAの熱可塑性ポリマーより高い硬度
を有する熱可塑性樹脂としては、エチレン、プロピレン
等のα−オレフィンの単独重合体又は共重合体等が好適
である。また、オレフィン系ゴムとしてはEPM。In the present invention, used as a constituent material of the core layer IB,
Contains or does not contain olefin rubber, JIS-
Examples of the thermoplastic resin having a flexural modulus of 7203 of 1000 kg/cm' or more and a higher hardness than the thermoplastic polymer of the skin layer IA include homopolymers or copolymers of α-olefins such as ethylene and propylene. etc. are suitable. Also, EPM is an olefin rubber.
EPDM、エチレン、ブテン−1共重合体ゴム等を挙げ
ることができる。こららはそれぞれ単独で用いても良く
、また2種以上をブレンドして用いても良い。更に、上
記弾性率及び硬度の範囲内である限り、一般に広く行わ
れている手法により、他の各種樹脂、エラストマーやガ
ラスファイバー タルク、炭酸カルシウム、シリカ、マ
イカ等の各種充填剤、着色剤、安定剤等を充填したもの
であっても良い。EPDM, ethylene, butene-1 copolymer rubber, etc. can be mentioned. These may be used alone or in a blend of two or more. Furthermore, as long as the elastic modulus and hardness are within the above ranges, other various resins, elastomers, glass fibers, various fillers such as talc, calcium carbonate, silica, mica, colorants, stabilizers, etc. It may be filled with an agent or the like.
コア層IBのオレフィン系ゴムの含有量は、前述の如く
、60重量%以下が適当であるが、オレフィン系樹脂と
オレフィン系ゴムの配合組成において、オレフィン系ゴ
ムが60重量%を超える場合には、成形加工性、成形保
持性に問題が生じる。As mentioned above, the content of the olefin rubber in the core layer IB is suitably 60% by weight or less, but if the olefin rubber exceeds 60% by weight in the composition of the olefin resin and olefin rubber , problems arise in moldability and mold retention.
本発明において、コア層IBを構成する熱可塑性樹脂の
曲げ弾性率が1000kg/am”未満のもの或は硬度
が表皮層IAの熱可塑性エラストマーより低いものでは
、十分な形状保持が達成されず、外圧により変形しやす
く、エアーバック収納用カバーとして不適である。一方
、曲げ弾性率が10000 k g / cゴを超える
ものは、2層工アーバッグカバーとしての全体の柔かさ
及び−40℃におけるエアーバック動作時の破壊不良が
起こり易い。よって、曲げ弾性率は、カバー全体のソフ
ト感、動作特性及び形状保持の点から1000kg/c
m2以上であって、t ooo。In the present invention, if the thermoplastic resin constituting the core layer IB has a flexural modulus of less than 1000 kg/am" or has a hardness lower than the thermoplastic elastomer of the skin layer IA, sufficient shape retention will not be achieved. It easily deforms due to external pressure, making it unsuitable as an airbag storage cover.On the other hand, those with a bending modulus of elasticity exceeding 10,000 kg/c have poor overall softness as a two-layered airbag cover and are unsuitable for use as an airbag storage cover. Breakage failure is likely to occur during airbag operation.Therefore, the bending elastic modulus is set at 1000 kg/c from the viewpoint of softness, operating characteristics, and shape retention of the entire cover.
m2 or more, toooo.
k g / c rd以下、特に1500kg/crr
?〜7000 k g / c rn’であることが好
ましい。kg/crr or less, especially 1500kg/crr
? ~7000 kg/crn' is preferred.
とりわけ好ましい範囲は2000 k g/cd〜50
00 k g / c m’である。A particularly preferable range is 2000 kg/cd to 50
00 kg/cm'.
コア層IBの肉圧は特に制限はないが、一般には、0.
5〜5mm程度、好ましくは1〜3mm程度の厚さとさ
れる。There is no particular limit to the wall thickness of the core layer IB, but it is generally 0.
The thickness is about 5 to 5 mm, preferably about 1 to 3 mm.
本発明においては、このような熱可塑性樹脂で構成され
るコア層IBには、エアーバック動作開始の際に容易に
コア層IBが開裂するための脆弱形状が施されている。In the present invention, the core layer IB made of such a thermoplastic resin is given a brittle shape so that the core layer IB easily ruptures when the airbag operation starts.
この脆弱形状は、ミシン目状のスリット形状ICの他、
ノツチ状肉薄形状、その他各種のものを採用することが
できる。また、その形成箇所、形成範囲等には特に制限
はなく、コア層IBの形状、強度、エアバッグ動作時の
応力等に応じて適宜決定される。In addition to the perforated slit-shaped IC, this fragile shape
Notch-like thin-walled shapes and various other shapes can be adopted. Further, there are no particular restrictions on the formation location, formation range, etc., and are appropriately determined depending on the shape, strength, stress during airbag operation, etc. of the core layer IB.
次に、このような本発明のエアーバック収納用カバーの
製造方法について説明する。Next, a method of manufacturing the air bag storage cover of the present invention will be described.
本発明のエアーバック収納用カバーを製造するための成
形加工法としては、熱可塑性樹脂に用いる一般的成形加
工法が挙げられるが、デザイン等の点から射出成形法が
特に良い方法として挙げることができる。Examples of molding methods for manufacturing the airbag storage cover of the present invention include general molding methods used for thermoplastic resins, but injection molding is particularly preferred from the point of view of design, etc. can.
射出成形法としては、予めコア層を成形し、該成形品を
表皮層の空間を残した金型に装着し、その表皮層部に熱
可塑性ポリマーからなる表皮材料を射出成形するいわゆ
るインサートインジェクション法、又は、コア層を成形
し、次いでキャビティ型を引離し、コア成形品を金型か
ら取り出すことなく連続して表皮層空間を有する新たな
キャビティ型を被装して表皮材料を射出成形するいわゆ
る二色成形(ダブルインジェクション)法などが有効な
成形法として挙げることができる。The injection molding method is the so-called insert injection method in which a core layer is molded in advance, the molded product is mounted in a mold leaving a space for the skin layer, and a skin material made of thermoplastic polymer is injection molded into the skin layer. Alternatively, the core layer is molded, then the cavity mold is separated, and without taking out the core molded product from the mold, a new cavity mold having a skin layer space is continuously covered and the skin material is injection molded. A two-color molding (double injection) method can be cited as an effective molding method.
この際、コア層IBにはエアーバックが動作開始のとき
容易に開裂するための前述の脆弱形状を施しておく必要
がある。脆弱形状としては、前述の如く、ノツチ状肉薄
形状やミシン目状のスリット形状等があるが、この形状
はコア成形品を成形するに際し、その形状を有する金型
で成形して施してもよく、また、コア成形品を成形した
後、このような形状を付与する加工を施してから表皮層
を積層するようにしても良い。At this time, it is necessary to give the core layer IB the aforementioned brittle shape so that the airbag can easily rupture when the airbag starts operating. As mentioned above, the fragile shape includes a notch-like thin shape, a perforation-like slit shape, etc., but this shape may be formed by molding with a mold having the shape when molding the core molded product. Alternatively, after the core molded product is molded, it may be processed to give such a shape, and then the skin layer may be laminated.
なお、本発明のエアーバック用カバーは、車両室内の豪
華さ、他の内装部品との色合せ、フィーリング等を向上
させるために、必要に応じて表皮層IAを塗装すること
もできる。表皮層IAの塗装は耐湯付性の点からも好ま
しいものである。The airbag cover of the present invention may have the skin layer IA coated if necessary in order to improve the luxury of the vehicle interior, color matching with other interior parts, feel, etc. Coating the skin layer IA is also preferable from the viewpoint of hot water resistance.
[作用]
本発明のエアーバック収納用カバーにおいては、比較的
硬質なコア層が軟質な表皮層で被われていることから、
該カバーに身体が当たっても柔らかみがあり、不快に感
することがない。また、コア層が硬質であるため多少の
外力が作用してもカバーが変形したり、損壊したりする
ことがない。[Function] In the air bag storage cover of the present invention, since the relatively hard core layer is covered with the soft skin layer,
Even when the body touches the cover, it is soft and does not make the user feel uncomfortable. Further, since the core layer is hard, the cover will not be deformed or damaged even if some external force is applied.
また、本発明のカバーは、−40℃から+80℃の範囲
にて、車両衝突時等にカバー内のエアーバックが膨張し
た際に、予めコア層にもうけられたカバー開裂用の脆弱
形状に沿ってカバーが開裂するのであるが、このカバー
開裂時において、硬質なコア層が軟質な表皮層で密着し
て覆われていることから、カバー開裂破片が飛散するこ
とがない。In addition, the cover of the present invention can be used in a temperature range of -40°C to +80°C, so that when the airbag inside the cover expands during a vehicle collision, etc., the cover conforms to the fragile shape formed in the core layer in advance for cover rupture. However, when the cover is torn, the hard core layer is tightly covered with the soft skin layer, so the cover torn pieces will not be scattered.
更に本発明のカバーは、実車装着を考慮した110℃、
500時間時間後においても、上記温度範囲(−40℃
〜+80℃)で良好な破壊性能を示し、外観変化は殆ど
認められない良好なものである。Furthermore, the cover of the present invention can be heated to 110 degrees Celsius in consideration of mounting on an actual vehicle.
Even after 500 hours, the above temperature range (-40℃
It shows good fracture performance at temperatures up to +80°C, with almost no change in appearance observed.
[実施例]
次に、実施例及び比較例を挙げて本発明をより具体的に
説明するが、本発明はその要旨を超えない限り、以下の
実施例に限定されるものではない。[Examples] Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples unless it exceeds the gist thereof.
実施例1〜7、比較例1〜6
型締圧350トンのインラインスクリュー二色射出成形
機を用い、第1表に示すコア材料にて開裂用のミシン目
状スリット(約0.7cmの長さのものが29本)が入
ったコア層(厚さ1.0〜3.0mm)を成形し、次い
でその上に第1表に示す表皮材料にて表皮層を所定の肉
厚になるように射出成形し、第1図に示すエアーバック
用モジュールカバー1を得た。Examples 1 to 7, Comparative Examples 1 to 6 Using an in-line screw two-color injection molding machine with a mold clamping pressure of 350 tons, a perforated slit (about 0.7 cm long) for cleavage was formed using the core material shown in Table 1. A core layer (thickness: 1.0 to 3.0 mm) containing 29 fibers (29 pieces) is molded, and then a skin layer is formed with the skin material shown in Table 1 on top of it to a predetermined thickness. The air bag module cover 1 shown in FIG. 1 was obtained by injection molding.
なお、実施例6においては、発泡表皮層を成形した0発
泡成形においては二色成形における表皮材料に炭酸ガス
系発泡剤マスターバッチ(三菱油化社製ファインブロー
32ON)を5部トライブレンドして成形した。In addition, in Example 6, in zero-foam molding in which a foamed skin layer was molded, 5 parts of a carbon dioxide blowing agent masterbatch (Fine Blow 32ON manufactured by Mitsubishi Yuka Co., Ltd.) was triblended with the skin material in two-color molding. Molded.
また、実施例7においては、表皮層の塗装を行なった。Furthermore, in Example 7, the skin layer was painted.
塗装は、カバーの射出成形後に表皮層をイソプロピルア
ルコールで拭き、次に板弁化学社製ブライマー(MEX
5440とメチルエチルケトン1対1)を7〜10μm
スプレー塗布、室温にて10分間乾燥の後、板弁化学社
製ウレタントップコート(MEX−8047:硬化剤F
−3:シンナー58u=100 : 10 : 50)
を20〜25μmスプレー塗布、室温にて10分乾燥後
、80℃で30〜45分焼き付けることにより行なった
。For painting, after injection molding the cover, wipe the skin layer with isopropyl alcohol, then apply Brimer (MEX) manufactured by Itaben Kagaku Co., Ltd.
5440 and methyl ethyl ketone (1:1) to 7-10 μm
After spraying and drying at room temperature for 10 minutes, apply urethane top coat (MEX-8047: Curing agent F) manufactured by Itaben Kagaku Co., Ltd.
-3: Thinner 58u = 100: 10: 50)
This was carried out by spray coating 20 to 25 μm, drying at room temperature for 10 minutes, and baking at 80° C. for 30 to 45 minutes.
得られた製品は、後述の方法により評価し、結果を第1
表に示した。The obtained product was evaluated by the method described below, and the results were evaluated in the first
Shown in the table.
なお、第1表に示す使用材料は、下記の通りである。The materials used in Table 1 are as follows.
〔コア材料]
PP−1:プロピレンーエチレンブロックコボリマー樹
脂とエチレン−プロピレンゴムとのブレンド物(三菱油
化製BC4/日本合成ゴム製EPO7p=50150
(重量%))BO2:MFR(230℃、2.16kg
)6.5g/10分
曲げ弾性率11600kg/cゴ
EPO7p:ML (100℃)70プロピレン含
量27%
ブレンド物:曲げ弾性率2000 k g / c r
n’JIS−A硬度97
PP−2:プロピレン−エチレンブロックコポリマー樹
脂とエチレン−プロピレンゴムとのブレンド物(三菱油
化製BC4/日本合成ゴム製EPO7p−60/40
(重量%))ブレンド物;曲げ弾性率4000 k g
/ c m’JIS−A硬度99
PP−3:プロピレンホモポリマー樹脂(三菱油化類M
A−4)
MFR5g/10分
曲げ弾性率12000 k g / cゴJ I S−
A硬度100
PP−4:ブロビレンーエチレンブロックコボリマー樹
脂とエチレン−プロピレンゴムとのブレンド物(三菱油
化銀MA−47日本合成ゴム製EPO7P=30/70
(重量%))ブレンド物:曲げ弾性率500 k g
/ c m”JIS−A硬度86
PE−1:低圧法ポリエチレン樹脂(三菱油化類JX−
10)
MFR(190℃、2.16kg)
20g/lo分
曲げ弾性率9000 k g / c m’JIS−A
硬度100
PE−2:線状低密度ポリエチレン樹脂とエチレン−プ
ロピレンゴムとのブレンド物(三菱油化製UJZ807
日本合成ゴム製EPO7p=40/60 (重量%))
UJ280:MFR(190℃、2.16kg)30g
/10分
曲げ弾性率2600kg/crn’
ブレンド物:曲げ弾性率400 k g / c rn
”JIS−A硬度82
[表皮材料]
TPS−1:下記■〜■の4成分からなり、■5EBS
−1/■5PX9400/■PIB−1/■OIL冨3
5/15/40/10 (重量%)の配合組成のもの1
00重量部に、安定剤としてチパガイギー製イルガノッ
クス1010を0.2重量部及びカーボンブラック0.
5重量部を加えて二軸押出機にて200℃で混練したも
の。[Core material] PP-1: Blend of propylene-ethylene block copolymer resin and ethylene-propylene rubber (BC4 manufactured by Mitsubishi Yuka/EPO7p manufactured by Japan Synthetic Rubber Co., Ltd. = 50150
(wt%)) BO2: MFR (230℃, 2.16kg
) 6.5 g/10 minutes Flexural modulus 11600 kg/c GoEPO7p: ML (100°C) 70 Propylene content 27% Blend: Flexural modulus 2000 kg/cr
n'JIS-A hardness 97 PP-2: Blend of propylene-ethylene block copolymer resin and ethylene-propylene rubber (BC4 manufactured by Mitsubishi Yuka/EPO7p-60/40 manufactured by Nippon Synthetic Rubber)
(% by weight)) Blend; Flexural modulus 4000 kg
/cm' JIS-A hardness 99 PP-3: Propylene homopolymer resin (Mitsubishi Yuka M
A-4) MFR5g/10 minutes flexural modulus 12000kg/c
A hardness: 100 PP-4: Blend of brobylene-ethylene block copolymer resin and ethylene-propylene rubber (Mitsubishi Silver Oil MA-47 Nippon Synthetic Rubber EPO7P = 30/70
(% by weight)) Blend: Flexural modulus 500 kg
/ cm” JIS-A hardness 86 PE-1: Low pressure polyethylene resin (Mitsubishi Yuka JX-
10) MFR (190℃, 2.16kg) 20g/lo bending modulus 9000 kg/cm JIS-A
Hardness: 100 PE-2: Blend of linear low-density polyethylene resin and ethylene-propylene rubber (Mitsubishi Yuka UJZ807
Japan Synthetic Rubber EPO7p=40/60 (weight%) UJ280: MFR (190°C, 2.16kg) 30g
/10 minutes Flexural modulus 2600 kg/crn' Blend: Flexural modulus 400 kg/crn'
"JIS-A hardness 82 [Skin material] TPS-1: Consists of the following four components, ■5EBS
-1/■5PX9400/■PIB-1/■OIL Fuji 3
1 with a blending composition of 5/15/40/10 (wt%)
00 parts by weight, 0.2 parts by weight of Irganox 1010 manufactured by Chipa Geigy as a stabilizer, and 0.0 parts by weight of carbon black.
5 parts by weight was added and kneaded at 200°C in a twin-screw extruder.
JIS−A硬度;55
■スチレンーブタジェンブロック共重合体の水素添加誘
導体(SEBS−1);ブルックフィールド粘度20重
量%(トルエン溶液2000cps、25℃)
■ブロビレンーエチレンブロックコボリマー(樹脂三菱
油化製5PX9400)。JIS-A hardness; 55 ■ Hydrogenated derivative of styrene-butadiene block copolymer (SEBS-1); Brookfield viscosity 20% by weight (toluene solution 2000 cps, 25°C) ■ Brobylene-ethylene block copolymer (resin Mitsubishi Yuka 5PX9400).
MFR(230℃、2.16kg)6g/10分、曲げ
弾性率4500kg/crr?■ポリイソブチレン(P
IB−1)(日本石油化学製テトラックス3T);粘度
平均分子量30000
■パラフィン系ゴム用軟化剤(OI L)(出光興産製
pw380);40℃動粘度80cSt
TPS−2:TPS−1と同様の方法で下記組成にて調
製したもの。MFR (230℃, 2.16kg) 6g/10min, flexural modulus 4500kg/crr? ■Polyisobutylene (P
IB-1) (Tetrax 3T manufactured by Nippon Petrochemicals); Viscosity average molecular weight 30000 ■ Softener for paraffin rubber (OI L) (PW380 manufactured by Idemitsu Kosan); Kinematic viscosity at 40°C 80 cSt TPS-2: Same as TPS-1 Prepared using the following method using the following composition.
■5EBS−1/■5PX9400/■PIB−1/■
OI L= 35/15/30/20(重量%)
J I S−A硬度=45
TPS−3:スチレンーブタジエンブロック共重合体の
水素添加誘導体(SEBS−2)を用い、TPS−1と
同様の方法で下記組成にて調製したもの。■5EBS-1/■5PX9400/■PIB-1/■
OI L = 35/15/30/20 (wt%) JIS A hardness = 45 TPS-3: Same as TPS-1 using hydrogenated derivative of styrene-butadiene block copolymer (SEBS-2) Prepared using the following method using the following composition.
■5EBS−2/■5PX9400/■PIB−1/■
OI L= 45/15/30/10(重量%)
J I S−A硬度=68
ただし、■5EBS−2は、ブルック
フィールド粘度20重量%(トルエン溶液1500cp
s、25℃)である。■5EBS-2/■5PX9400/■PIB-1/■
OI L = 45/15/30/10 (wt%) JI S-A hardness = 68 However, ■5EBS-2 has a Brookfield viscosity of 20 wt% (toluene solution 1500 cp
s, 25°C).
TPS−4:TPS−1と同様の方法で下記組成にて調
製したもの。TPS-4: Prepared with the following composition in the same manner as TPS-1.
5EBS−1/5PX940010IL=3515/6
0 (重量%)
JIS−A硬度=15
TPS−5:TPS−1と同様の方法で下記組成にて調
製したもの。5EBS-1/5PX940010IL=3515/6
0 (wt%) JIS-A hardness = 15 TPS-5: Prepared with the following composition in the same manner as TPS-1.
5EBS−1/BC−410I L/炭酸カルシウム=
24/9/37/30 (重量%)J I S−A硬度
≠55
TPO−1ニオレフイン系熱可塑性エラストマー(三菱
油化製サーモラン3600B)
J I S−A硬度=70
TPO−2ニオレフイン系熱可塑性エラストマー(三菱
油化製サーモラン3920B)
J I S−A硬度=93
比較例7
比較例のため、高密度ウレタン発泡体の表皮層と低密度
ウレタンコア層の2層からなるエアーバック収納用カバ
・−を製造し、その評価を行なった。5EBS-1/BC-410I L/calcium carbonate=
24/9/37/30 (wt%) J I S-A hardness ≠ 55 TPO-1 Niolefin thermoplastic elastomer (Thermolan 3600B manufactured by Mitsubishi Yuka) J I S-A hardness = 70 TPO-2 Niolefin thermoplastic elastomer Elastomer (Thermolan 3920B manufactured by Mitsubishi Yuka) JI S-A hardness = 93 Comparative example 7 For the purpose of comparison, an airbag storage cover consisting of two layers: a skin layer of high-density urethane foam and a low-density urethane core layer. - was manufactured and evaluated.
成形は、リムウレタン成形法によって予めコア層を低発
泡密度で成形してキュア(硬化)させた後、表皮層を形
成すべく金型に装着させ、更に同方法で表皮層を成形す
るインサート成形法で行なフた。表皮層成形のための発
泡材はフロンガスを使用した。この方法は、キュア工程
を2回必要とし、生産性が悪かった。Molding is performed by insert molding, in which the core layer is molded in advance at a low foaming density using the rim urethane molding method and cured (hardened), then attached to a mold to form the skin layer, and then the skin layer is molded using the same method. It was done by law. Freon gas was used as the foaming material for forming the skin layer. This method required two curing steps and had poor productivity.
得られたエアーバック収納用カバーについて、実施例!
と同様な方法で評価を行ない、結果を第1表に示した。An example of the obtained air bag storage cover!
The evaluation was carried out in the same manner as above, and the results are shown in Table 1.
比較例8
更に比較のため、補強用ネットを設けたエアーバック収
納用カバーを製造し、その評価を行なった。Comparative Example 8 For further comparison, an air bag storage cover provided with a reinforcing net was manufactured and evaluated.
このネット入りリムウレタン成形では、比較例7と同様
にして2層成形するにあたり、ポリエステル繊維をネッ
ト状に編み、それをカバーの開裂に沿った形状に溶断し
、金具(フック)をつけた。これをリム金型に装着し、
ウレタンでリム成形した。この時、発泡材としてフロン
ガスを使用し、脱型した後、100℃、30分でキュア
させた。この方法では、ネットをインサートすることに
よって、安全なスキン層を作ることが難しく、成形サイ
クルがあがらないなどの欠点があった。In this net-containing rim urethane molding, two-layer molding was carried out in the same manner as in Comparative Example 7. Polyester fibers were woven into a net shape, which was melt-cut in a shape along the cleavage of the cover, and metal fittings (hooks) were attached. Attach this to the rim mold,
The rim was molded with urethane. At this time, chlorofluorocarbon gas was used as a foaming material, and after demolding, it was cured at 100° C. for 30 minutes. This method had drawbacks such as the difficulty of creating a safe skin layer by inserting the net, and the slow molding cycle.
得られたエアーバック収納用カバーについて、実施例1
と同様な方法で評価を行ない、結果を第1表に示した。Regarding the obtained air bag storage cover, Example 1
The evaluation was carried out in the same manner as above, and the results are shown in Table 1.
第1表より明らかなように、実施例1〜7に示された本
発明のエアーバック収納用カバーは、ソフト感、形状保
持性、−40℃の展開テスト、110℃、500時間の
耐久性テスト、生産性ともに非常に良好なものであった
。As is clear from Table 1, the airbag storage covers of the present invention shown in Examples 1 to 7 have a soft feel, shape retention, -40°C deployment test, 110°C, 500 hour durability. Both testing and productivity were very good.
[評価方法]
■ ソフト感
第1図の如く、エアーバック2とエアーバック収納用カ
バー1及びリテーナ−(取付金具)4.5とインフレー
タ−3を組み付けたモジュールカバー又は、カバ−11
L品を一20℃〜80℃中にサンプルが雰囲気温度に達
するまで放置し、その時のカバーを10人の人間による
手の感触で評価。ソフト感を感じたものが10人中10
人であれば○、10人中8人であれば△、それ以下はX
とした。[Evaluation method] ■ Soft feeling As shown in Figure 1, the module cover or cover 11 is assembled with the airbag 2, airbag storage cover 1, retainer (mounting hardware) 4.5, and inflator 3.
The L product was left at -20°C to 80°C until the sample reached the ambient temperature, and the cover was then evaluated by touch with the hands of 10 people. 10 out of 10 people felt it felt soft.
○ if it is 8 out of 10 people, △ if it is 8 out of 10 people, X if it is less than that
And so.
■ 形状保持性
第1図の如く、エアーバック2とエアーバック収納用カ
バー1及びリテーナ−(取付金具)4.5とインフレー
タ−3を組み付けたモジュールカバー又は、カバ−1単
品を80℃〜110℃の高温状態で長時間(<too。■ Shape retention As shown in Figure 1, the module cover assembled with the airbag 2, airbag storage cover 1, retainer (mounting hardware) 4.5, and inflator 3, or the cover 1 alone, is heated to 80℃ to 110℃. ℃ for a long time (<too.
hr)放置又は、−40℃〜100℃の熱サイクルで1
0サイクル放置し、テスト中又はテスト後に変形の状態
を観察し、変形の殆どないものはエアーバック収納用カ
バーとして好適(0)とし、著しい変形のあるものはエ
アーバック収納用カバーとして不適(×)とした。hr) Leave it alone or heat cycle from -40℃ to 100℃ for 1
Leave it for 0 cycles, observe the state of deformation during or after the test, and if there is almost no deformation, it is considered suitable as an air bag storage cover (0), and if there is significant deformation, it is not suitable as an air bag storage cover (× ).
■ −40℃展開テスト
■、■で組み付けたモジュールをステアリングに取付け
一40℃に雰囲気温度に達する程度の時間放置し、1分
以内に展開テストを実施し、その時にモジュールカバー
が割れて飛散したり、又は、カバーが鋭利な形状に割れ
て)<ラグを引き裂くなどのエアバッグとして正常な動
作がなかった場合を不適(×)とし、正常な動作がなさ
れた場合を好適(0)とした。■ -40℃ Deployment Test Attach the module assembled in ■ and ■ to the steering wheel and leave it for a period of time to reach the ambient temperature of 40℃, and conduct the deployment test within 1 minute. At that time, the module cover cracks and scatters. Cases in which the airbag did not function normally (such as the cover cracking into sharp shapes) or tearing the lugs were marked as unsuitable (×), and cases in which the cover operated normally were marked as suitable (0). .
■ 110℃、500時間の耐久性テストギヤ式熱老化
試験機にてモジュールカバーを上記条件でエージングし
た後、■のテスト方法に従い一40℃展開テストを実施
、更にエージング前後のモジュールカバー外観を比較し
、ソリ、変形、コア材への軟化剤のブリード等著しい変
化があるものは×、ないものはOとした。■ Durability test at 110℃ for 500 hours After aging the module cover under the above conditions using a gear-type heat aging tester, we conducted a development test at -40℃ according to the test method in ■, and further compared the appearance of the module cover before and after aging. , those with significant changes such as warpage, deformation, and bleeding of the softener into the core material were rated ×, and those without were rated O.
■ 生産性
連続して20個の製品を製造し、成形品の外観寸法、重
量をチエツクし、全数合格レベルならOとし、90%以
上なら△、それ以下は×と[発明の効果コ
以上詳述した通り、本発明のエアーバック収納用カバー
は、表皮層が軟質であるので身体の一部が当っても柔ら
かみがあるため快適感が高い。また、コア層が比較的硬
質であるため、形状保持性に優れ耐久性が高い。そして
、エアーバックの動作時には、カバー開裂用の脆弱形状
により、カバーは速やかに開裂する。しかも、軟質な表
皮層によりカバーの開裂時のコア層の飛散が確実に防止
される上に、良好な破壊性能を示し、耐久性に著しく(
量れる。■ Productivity Manufacture 20 products in a row and check the external dimensions and weight of the molded products. If all of them pass the level, mark O, if 90% or more, mark △, and below that mark × [Details of the effects of the invention] As described above, the air bag storage cover of the present invention has a soft skin layer, so even if a part of the body hits it, it remains soft, providing a high sense of comfort. Furthermore, since the core layer is relatively hard, it has excellent shape retention and high durability. Then, when the airbag is activated, the cover quickly ruptures due to the fragile shape for rupturing the cover. Moreover, the soft skin layer reliably prevents the core layer from scattering when the cover is torn, and also exhibits good breaking performance, significantly improving durability (
Can be measured.
しかして、本発明のエアーバック収納用カバーは、二色
成形法等の合理化された成形法により、簡便かつ高精度
に、不良品の発生も殆どなく、高い歩留りにて確実かつ
効率的に製造することが可能であり、製品の大幅なコス
トダウンを図ることが可能である。Therefore, the air bag storage cover of the present invention can be easily and precisely manufactured using a streamlined molding method such as the two-color molding method, with almost no defective products, and with a high yield and reliably and efficiently. It is possible to significantly reduce the cost of the product.
第1図は本発明の一実施例に係るエアーバック収納用カ
バーがエアーバックに装着された状態を示す概略的な部
分断面正面図であり、第2図はエアーバック収納用カバ
ーの背面図である。
1・・・エアーバック収納用カバー
IA・・・表皮層、 IB・・・コア層、2・・
・エアーバック、 3・・・インフレータ−4,5・
・・リテーナ。
代理人 弁理士 重 野 剛FIG. 1 is a schematic partial sectional front view showing a state in which an air bag storage cover according to an embodiment of the present invention is attached to an air bag, and FIG. 2 is a rear view of the air bag storage cover according to an embodiment of the present invention. be. 1...Airbag storage cover IA...Skin layer, IB...Core layer, 2...
・Air bag, 3...Inflator-4, 5・
・Retainer. Agent Patent Attorney Tsuyoshi Shigeno
Claims (3)
−K6301のJIS−A硬度が20〜90の熱可塑性
ポリマーからなる表皮層と、JIS−K7203の曲げ
弾性率が1000kg/cm^2以上の熱可塑性樹脂か
らなるコア層とを有し、 該コア層は前記表皮層より硬度が高く、かつ、該コア層
には、エアーバック動作開始のとき容易に開裂するため
の部分が付されていることを特徴とするエアーバック収
納用カバー。(1) Contains a softener for hydrocarbon rubber, and conforms to JIS
- having a skin layer made of a thermoplastic polymer with a JIS-A hardness of 20 to 90 according to K6301, and a core layer made of a thermoplastic resin with a flexural modulus of JIS-K7203 of 1000 kg/cm^2 or more, the core 1. A cover for storing an air bag, wherein the layer has a harder hardness than the skin layer, and the core layer has a portion for easily tearing when the air bag starts operating.
0の熱可塑性ポリマーからなる表皮層と、 オレフィン系ゴムを含有し、かつ、JIS−K7203
の曲げ弾性率が1000kg/cm^2以上の熱可塑性
樹脂からなるコア層とを有し、 該コア層は前記表皮層より硬度が高く、かつ、該コア層
には、エアーバック動作開始のとき容易に開裂するため
の部分が付されていることを特徴とするエアーバック収
納用カバー。(2) JIS-A hardness of JIS-K6301 is 20 to 9
0 thermoplastic polymer, contains olefin rubber, and conforms to JIS-K7203.
and a core layer made of a thermoplastic resin with a bending modulus of 1000 kg/cm^2 or more, the core layer has a higher hardness than the skin layer, and the core layer has a core layer made of a thermoplastic resin having a bending elastic modulus of 1000 kg/cm^2 or more, and the core layer has a hardness higher than that of the skin layer. An air bag storage cover characterized by having a part for easy tearing.
−K6301のJIS−A硬度が20〜90の熱可塑性
ポリマーからなる表皮層と、オレフィン系ゴムを含有し
、かつ、JIS−K7203の曲げ弾性率が1000k
g/cm^2以上の熱可塑性樹脂からなるコア層とを有
し、 該コア層は前記表皮層より硬度が高く、かつ、該コア層
には、エアーバック動作開始のとき容易に開裂するため
の部分が付されていることを特徴とするエアーバック収
納用カバー。(3) Contains a softener for hydrocarbon rubber, and conforms to JIS
- Contains a skin layer made of a thermoplastic polymer with a JIS-A hardness of 20 to 90 in K6301, and an olefin rubber, and has a flexural modulus of 1000k in JIS-K7203.
g/cm^2 or more, the core layer has a higher hardness than the skin layer, and the core layer contains a material that easily ruptures when the airbag starts operating. An air bag storage cover characterized by having a part attached thereto.
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1042733A JP2720500B2 (en) | 1989-02-22 | 1989-02-22 | Airbag storage cover |
| US07/453,685 US5110647A (en) | 1988-12-26 | 1989-12-20 | Cover for a vehicle air bag |
| CA002006284A CA2006284C (en) | 1988-12-26 | 1989-12-21 | Cover for a vehicle air bag |
| FR8917125A FR2640922B1 (en) | 1988-12-26 | 1989-12-22 | |
| DE3943757A DE3943757C2 (en) | 1988-12-26 | 1989-12-22 | Device for connecting an airbag cover to a base |
| DE3942694A DE3942694C3 (en) | 1988-12-26 | 1989-12-22 | Cover for a folded gas bag of an impact protection device in motor vehicles |
| GB8929115A GB2228235B (en) | 1988-12-26 | 1989-12-22 | Cover for a vehicle air bag |
| DE8915085U DE8915085U1 (en) | 1988-12-26 | 1989-12-22 | Cover for a safety airbag in motor vehicles |
| KR1019900000515A KR970008430B1 (en) | 1989-02-22 | 1990-01-17 | Cover for a vehicle air bag |
| US08/896,989 USRE36898E (en) | 1988-12-26 | 1997-07-18 | Cover for a vehicle air bag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1042733A JP2720500B2 (en) | 1989-02-22 | 1989-02-22 | Airbag storage cover |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02220946A true JPH02220946A (en) | 1990-09-04 |
| JP2720500B2 JP2720500B2 (en) | 1998-03-04 |
Family
ID=12644241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1042733A Expired - Lifetime JP2720500B2 (en) | 1988-12-26 | 1989-02-22 | Airbag storage cover |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2720500B2 (en) |
| KR (1) | KR970008430B1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0538996A (en) * | 1990-11-29 | 1993-02-19 | Asahi Chem Ind Co Ltd | Storage cover for air bag device |
| JPH0585294A (en) * | 1991-09-30 | 1993-04-06 | Nippon Plast Co Ltd | Cover for housing air bag |
| JPH0834304A (en) * | 1994-07-22 | 1996-02-06 | Mitsubishi Chem Corp | Air bag storage cover |
| EP1101795A1 (en) | 1999-11-18 | 2001-05-23 | Mitsubishi Chemical Corporation | Air bag cover for vehicles |
| JP2007243279A (en) * | 2006-03-06 | 2007-09-20 | Matsushita Electric Ind Co Ltd | Speaker diaphragm, speaker and electronic device using the diaphragm |
| JP2008030748A (en) * | 1998-06-25 | 2008-02-14 | Tip Engineering Group Inc | Process for manufacturing automotive trim piece pre-weakened to form airbag deployment opening |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52116537A (en) * | 1976-03-26 | 1977-09-30 | Toyota Motor Corp | Expansion type passenger restricting device for automobile or the like |
| JPS6322262U (en) * | 1986-07-28 | 1988-02-13 | ||
| JPH02171364A (en) * | 1988-11-01 | 1990-07-03 | Kolbenschmidt Ag | Gas bag type impact preventer |
-
1989
- 1989-02-22 JP JP1042733A patent/JP2720500B2/en not_active Expired - Lifetime
-
1990
- 1990-01-17 KR KR1019900000515A patent/KR970008430B1/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52116537A (en) * | 1976-03-26 | 1977-09-30 | Toyota Motor Corp | Expansion type passenger restricting device for automobile or the like |
| JPS6322262U (en) * | 1986-07-28 | 1988-02-13 | ||
| JPH02171364A (en) * | 1988-11-01 | 1990-07-03 | Kolbenschmidt Ag | Gas bag type impact preventer |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0538996A (en) * | 1990-11-29 | 1993-02-19 | Asahi Chem Ind Co Ltd | Storage cover for air bag device |
| JPH0585294A (en) * | 1991-09-30 | 1993-04-06 | Nippon Plast Co Ltd | Cover for housing air bag |
| JPH0834304A (en) * | 1994-07-22 | 1996-02-06 | Mitsubishi Chem Corp | Air bag storage cover |
| JP2008030748A (en) * | 1998-06-25 | 2008-02-14 | Tip Engineering Group Inc | Process for manufacturing automotive trim piece pre-weakened to form airbag deployment opening |
| JP2009255914A (en) * | 1998-06-25 | 2009-11-05 | Tip Engineering Group Inc | Method for manufacturing automotive trim piece pre-weakened to form airbag deployment opening |
| EP1101795A1 (en) | 1999-11-18 | 2001-05-23 | Mitsubishi Chemical Corporation | Air bag cover for vehicles |
| JP2007243279A (en) * | 2006-03-06 | 2007-09-20 | Matsushita Electric Ind Co Ltd | Speaker diaphragm, speaker and electronic device using the diaphragm |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2720500B2 (en) | 1998-03-04 |
| KR900012798A (en) | 1990-09-01 |
| KR970008430B1 (en) | 1997-05-24 |
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