JPH0222862B2 - - Google Patents
Info
- Publication number
- JPH0222862B2 JPH0222862B2 JP59148054A JP14805484A JPH0222862B2 JP H0222862 B2 JPH0222862 B2 JP H0222862B2 JP 59148054 A JP59148054 A JP 59148054A JP 14805484 A JP14805484 A JP 14805484A JP H0222862 B2 JPH0222862 B2 JP H0222862B2
- Authority
- JP
- Japan
- Prior art keywords
- heat exchange
- copper
- heat
- corrosion
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 150000002739 metals Chemical class 0.000 claims description 3
- 229910000881 Cu alloy Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 238000005260 corrosion Methods 0.000 description 15
- 230000007797 corrosion Effects 0.000 description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 4
- 229910001431 copper ion Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- -1 chlorine ions Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S40/00—Safety or protection arrangements of solar heat collectors; Preventing malfunction of solar heat collectors
- F24S40/40—Preventing corrosion; Protecting against dirt or contamination
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は太陽熱温水器に関するものである。[Detailed description of the invention] Industrial applications The present invention relates to a solar water heater.
従来例の構成とその問題点
銅パイプを素材としたヒートパイプ式の熱交換
部を太陽熱温水器に採用する際、通常、貯湯タン
クの水中に銅の裸管状態で、ヒートパイプの熱交
換部が複数本挿入される。この種の方式で、昇温
貯湯された水には、熱交換部素成の材質である銅
が溶出して銅イオン濃度が高くなつている。いわ
ゆる銅パイプ表面全体に亘り腐食を起すのが通例
である。Conventional structure and its problems When a heat pipe heat exchange section made of copper pipes is used in a solar water heater, the heat exchange section of the heat pipe is usually placed in a bare copper tube under water in a hot water tank. Multiple lines are inserted. In this type of system, the water stored at an elevated temperature has a high copper ion concentration due to the elution of copper, which is the material of the heat exchanger. Corrosion typically occurs over the entire surface of so-called copper pipes.
この銅イオン濃度は、水道水基準である1ppm
を越えることも多い。この銅イオンの溶出は、使
用水に含まれる塩素イオン、硫酸イオン、硝酸イ
オン、残留塩素などの増加及び水素イオン濃度
(PH)の低下による影響が大きい為である。 This copper ion concentration is 1ppm, which is the tap water standard.
It often exceeds. This elution of copper ions is largely influenced by an increase in chlorine ions, sulfate ions, nitrate ions, residual chlorine, etc. contained in the water used and a decrease in hydrogen ion concentration (PH).
この銅イオンを含む水を浴槽、洗面器、タオル
に繰り返し接触させていると、不溶性の青色物質
が付着する場合がある。これは石けんや汗などに
含まれている脂肪酸、アンモニウムと反応して脂
肪酸銅又は、銅のアンモニウム塩が生成して、青
色の物質となるためである。一般に云われている
「青い水」問題である。 If water containing copper ions is repeatedly brought into contact with bathtubs, washbasins, and towels, insoluble blue substances may adhere to them. This is because copper reacts with fatty acids and ammonium contained in soap and sweat, producing fatty acid copper or ammonium salts of copper, resulting in a blue substance. This is what is commonly referred to as the "blue water" problem.
発明の目的
本発明は、上記の不溶性の青色物質が付着す
る、いわゆる「青い水」問題を無くすことを目的
とする。OBJECT OF THE INVENTION The purpose of the present invention is to eliminate the so-called "blue water" problem in which the above-mentioned insoluble blue substances adhere.
発明の構成
上記目的を達成するため本発明は、熱交換部
に、それよりもイオン化傾向の大なる金属を当接
し、バネ作用をもつ固定線にて取付け、固定線は
金属の消耗時には熱交換部から離脱させるもので
ある。Structure of the Invention In order to achieve the above object, the present invention brings a metal with a higher ionization tendency into contact with the heat exchange part and attaches it with a fixed wire having a spring action, and the fixed wire is used for heat exchange when the metal is consumed. This is to make them leave the department.
実施例の説明
第1図に於て、1が太陽熱温水器の本体であ
り、その内側に銅パイプ内にフロンガス等を封入
したヒートパイプ2が装着される。ヒートパイプ
2の上方部には熱交換部4があり、太陽熱を集熱
した熱量を、貯湯タンク3の水3bに移す働きを
する。この熱交換部4の上面に防食ユニツト5を
取りつける。この防食ユニツト5は、第2図に於
て、貯湯タンク上面開口部3a、即ち給水用ボー
ルタツプ6を装着する部分から任意に取りつけ取
り外しが出来る形態寸法に加工される。DESCRIPTION OF THE EMBODIMENTS In FIG. 1, reference numeral 1 denotes the main body of a solar water heater, and a heat pipe 2 in which fluorocarbon gas or the like is sealed in a copper pipe is installed inside the main body. There is a heat exchange section 4 above the heat pipe 2, which functions to transfer the amount of heat collected from the sun to the water 3b of the hot water storage tank 3. A corrosion protection unit 5 is attached to the upper surface of this heat exchange section 4. This anti-corrosion unit 5 is machined to have such a size that it can be attached and removed at will from the upper opening 3a of the hot water storage tank, ie, from the portion where the water supply ball tap 6 is attached, as shown in FIG.
第3図に於て、この防食ユニツト5の構造を説
明する。 Referring to FIG. 3, the structure of this corrosion protection unit 5 will be explained.
5aがマグネシユームの棒で、これが熱交換部
4よりもイオン化傾向の大なる金属として用いた
ものである。この棒5aは図示の如く2本でもよ
いが、一本丈、もしくは複数本であつてもよい。 5a is a rod of magnesium, which is used as a metal having a greater tendency to ionize than the heat exchanger 4. The length of this rod 5a may be two as shown in the figure, but it may also be one length or a plurality of rods.
マグネシユームの棒5aには内部に芯線材が同
時加工されていないもの、即ち丸棒全部がマグネ
シウム素材のものを使用する。固定線5lはステ
ンレス線等によりV字状に加工し、バネ弾性を持
たせたものとする。V字状の両切断、先端部はL
字状に曲げておく(第6図)。 The magnesium rod 5a used is one in which the core wire is not simultaneously processed, that is, the entire round rod is made of magnesium material. The fixed wire 5l is made of stainless steel wire or the like and processed into a V-shape to have spring elasticity. V-shaped double cut, tip is L
Bend it into a letter shape (Figure 6).
構造的にはこれ丈のものであるが、装着の際は
この固定線5lを3本の熱交換部4のうち中央の
パイプに引掛けて後、マグネシユームの棒5a2
本を図示の如く十字状に交差させて置き、固定線
の5lの両先端を、両側の熱交換部4に引掛け、
止めているのである。この状態で固定線5lは熱
交換部4に交差したものとなる。このヒートパイ
プ2は、通常複数本で形成するが、本防食ユニツ
ト5の装着の為に用いるのは3本丈である。又、
複数本のヒートパイプ2は、集熱部のフイン2a
により電気的に一体のものとなつている。本防食
ユニツト5が長時間使用後、マグネシユームの棒
5aが損耗すると、第5図の如く切断状態とな
り、固定線5lは下方へ落下し、熱交換部4から
離脱する。万一、離脱不完全であつても、熱交換
部4に対する固定線5lは、L字曲げ部ロの部分
の空間があり、隙間腐食を起す様な条件を作らな
い。 Structurally, it is this length, but when installing it, hook this fixed wire 5l to the central pipe of the three heat exchange parts 4, and then attach it to the magnesium rod 5a2.
Place the books in a cross shape as shown in the figure, hook both ends of the 5L fixed wire to the heat exchange parts 4 on both sides,
It is stopping it. In this state, the fixed line 5l intersects the heat exchange section 4. This heat pipe 2 is usually formed of a plurality of pieces, but the length of three pieces is used for mounting the corrosion protection unit 5. or,
The plurality of heat pipes 2 have fins 2a of a heat collecting part.
This makes them electrically integrated. When the corrosion protection unit 5 is used for a long period of time and the magnesium rod 5a is worn out, it becomes disconnected as shown in FIG. Even if detachment is incomplete, the fixing wire 5l to the heat exchange part 4 has a space at the L-shaped bent part B, and does not create conditions that would cause crevice corrosion.
一方、構造的特長として、固定線5l、マグネ
シユームの棒5a、熱交換部4、各々の相互接触
状態は、第4図のイの如く、丸線対丸棒の直交状
態であり、全て点接触状態が基本となつており、
通常の隙間腐食要因部が極めて少ない。 On the other hand, as a structural feature, the fixed wire 5l, the magnesium rod 5a, and the heat exchanger 4 are in mutual contact with each other, as shown in FIG. The condition is the basis,
There are very few areas that cause normal crevice corrosion.
発明の効果
本発明では銅よりイオン化傾向の大なる金属が
積極的に溶出し、銅の溶出が抑制されるので、
「青い水」問題は起らなくなる。またバネ弾性を
利用しているので、熱交換部との長期、水中での
電気的接続が良好に保たれるので防食機能が安定
する。Effects of the Invention In the present invention, metals with a higher ionization tendency than copper are actively eluted, and the leaching of copper is suppressed.
The "blue water" problem will no longer arise. In addition, since spring elasticity is used, electrical connection with the heat exchange part is maintained well over a long period of time underwater, resulting in stable corrosion protection.
即ち、犠牲陽極棒としての効果を発揮するわけ
であるが、この犠牲陽極棒の消耗時には、再度付
加する必要が生ずる。これを付加せず放置される
と通常、固定線と熱交換部の間係は、異極金属接
触による電食や、隙間腐食の機会を作ることにな
る。本構成によれば、犠牲陽極棒の消耗が即ち、
固定線の離脱を実現することになるので、上記の
如き心配が全くない。仮りに何らかの理由で、離
脱不十分の現象を生じた場合であつても、構造接
触部が全て点である為、隙間腐食の恐れは皆無に
近い。一方、固定線の構造が上記の目的でL字曲
げのみ加工方法をとることになり、工作的にも容
易で、安価に提供でき、信頼性も高いものとな
る。 In other words, although it is effective as a sacrificial anode rod, when the sacrificial anode rod wears out, it becomes necessary to add it again. If left without this addition, the connection between the fixed wire and the heat exchanger will usually create an opportunity for electrolytic corrosion or crevice corrosion due to contact between different metals. According to this configuration, the consumption of the sacrificial anode rod is reduced to
Since the fixed line can be removed, there is no need to worry about the above. Even if insufficient detachment occurs for some reason, there is almost no risk of crevice corrosion since all structural contact parts are points. On the other hand, for the above-mentioned purpose, the structure of the fixed wire requires only L-shaped bending, which is easy to work with, can be provided at low cost, and has high reliability.
第1図は本発明の一実施例の太陽熱温水器の断
面図、第2図は同要部の一部切欠斜視図、第3図
は同防食ユニツト部の斜視図、第4図は同防食ユ
ニツトの正面図、第5図は同作動後の正面図、第
6図は同固定線の斜視図である。
1……太陽熱温水器の本体、2……ヒートパイ
プ、2a……集熱フイン、3……貯湯タンク、3
a……上面開孔部、3b……水、4……熱交換
部、5……防食ユニツト、5a……マグネシユー
ムの棒(金属)、5l……固定線、6……ボール
タツプ、イ……点接触部、ロ……L字曲げ部。
Fig. 1 is a sectional view of a solar water heater according to an embodiment of the present invention, Fig. 2 is a partially cutaway perspective view of the main parts, Fig. 3 is a perspective view of the anti-corrosion unit, and Fig. 4 is a perspective view of the anti-corrosion unit. FIG. 5 is a front view of the unit, FIG. 5 is a front view after the same operation, and FIG. 6 is a perspective view of the fixing line. 1... Main body of solar water heater, 2... Heat pipe, 2a... Heat collection fin, 3... Hot water storage tank, 3
a...Top opening, 3b...Water, 4...Heat exchange section, 5...Corrosion protection unit, 5a...Magnesium rod (metal), 5l...Fixed wire, 6...Ball tap, I... Point contact part, B...L-shaped bent part.
Claims (1)
側に、この熱交換部構成金属よりイオン化傾向の
大なる金属棒を十字状に交差当接させると共に、
バネ作用を持つW型固定線により、前記金属棒が
カンヌキ状に係止固定され、当金属棒の消耗又は
折損時にカンヌキ解除となり、W型固定線が熱交
換部から離脱できる構成とした太陽熱温水器。1. On one side of a plurality of heat exchange parts made of copper or copper alloy, metal rods having a higher ionization tendency than the metals constituting the heat exchange parts are brought into cross-abutment in a cross shape,
The metal rod is locked and fixed in a canopy shape by a W-shaped fixing wire with a spring action, and when the metal rod wears out or breaks, the locking is released and the W-shaped fixing wire can be detached from the heat exchange section. vessel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14805484A JPS6127450A (en) | 1984-07-16 | 1984-07-16 | solar water heater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14805484A JPS6127450A (en) | 1984-07-16 | 1984-07-16 | solar water heater |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6127450A JPS6127450A (en) | 1986-02-06 |
| JPH0222862B2 true JPH0222862B2 (en) | 1990-05-22 |
Family
ID=15444126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14805484A Granted JPS6127450A (en) | 1984-07-16 | 1984-07-16 | solar water heater |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6127450A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0413379U (en) * | 1990-05-26 | 1992-02-03 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2199985B (en) * | 1986-12-22 | 1991-09-11 | Raytheon Co | Surface acoustic wave device |
-
1984
- 1984-07-16 JP JP14805484A patent/JPS6127450A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0413379U (en) * | 1990-05-26 | 1992-02-03 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6127450A (en) | 1986-02-06 |
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