JPH0225373B2 - - Google Patents

Info

Publication number: JPH0225373B2
Authority: JP; Japan
Prior art keywords: acetylene; benzene; polymerization; xylene; highly oriented
Prior art date: 1983-06-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP10496083A

Other languages

English (en)

Japanese (ja)

Other versions

JPS59230009A (ja

Inventor

Masaru Ozaki

Yukihiro Ikeda

Tatsumi Arakawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-06-14

Filing date

1983-06-14

Publication date

1990-06-01

1983-06-14 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1983-06-14 Priority to JP10496083A priority Critical patent/JPS59230009A/ja

1984-12-24 Publication of JPS59230009A publication Critical patent/JPS59230009A/ja

1990-06-01 Publication of JPH0225373B2 publication Critical patent/JPH0225373B2/ja

Status Granted legal-status Critical Current

Links

UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 75
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 55
125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 55
229920000642 polymer Polymers 0.000 claims description 26
239000013078 crystal Substances 0.000 claims description 22
238000006116 polymerization reaction Methods 0.000 claims description 20
239000002685 polymerization catalyst Substances 0.000 claims description 14
239000007787 solid Substances 0.000 claims description 14
238000004519 manufacturing process Methods 0.000 claims description 13
239000000178 monomer Substances 0.000 claims description 6
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
239000008096 xylene Substances 0.000 claims description 4
URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 32
238000000034 method Methods 0.000 description 28
239000010409 thin film Substances 0.000 description 17
239000007789 gas Substances 0.000 description 11
239000003054 catalyst Substances 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
239000002904 solvent Substances 0.000 description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
238000007710 freezing Methods 0.000 description 5
230000008014 freezing Effects 0.000 description 5
239000011521 glass Substances 0.000 description 5
239000000758 substrate Substances 0.000 description 5
230000003287 optical effect Effects 0.000 description 4
230000010287 polarization Effects 0.000 description 4
238000004627 transmission electron microscopy Methods 0.000 description 4
239000002019 doping agent Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
238000001291 vacuum drying Methods 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
239000002841 Lewis acid Substances 0.000 description 2
-1 Lewis acids Chemical class 0.000 description 2
ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 description 2
CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
238000001816 cooling Methods 0.000 description 2
150000007517 lewis acids Chemical class 0.000 description 2
238000005259 measurement Methods 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
229910021630 Antimony pentafluoride Inorganic materials 0.000 description 1
229910017049 AsF5 Inorganic materials 0.000 description 1
229910015900 BF3 Inorganic materials 0.000 description 1
229910052688 Gadolinium Inorganic materials 0.000 description 1
229910013063 LiBF 4 Inorganic materials 0.000 description 1
229910013684 LiClO 4 Inorganic materials 0.000 description 1
PHXQIAWFIIMOKG-UHFFFAOYSA-N NClO Chemical compound NClO PHXQIAWFIIMOKG-UHFFFAOYSA-N 0.000 description 1
229910052779 Neodymium Inorganic materials 0.000 description 1
229910021174 PF5 Inorganic materials 0.000 description 1
229910052777 Praseodymium Inorganic materials 0.000 description 1
229910018286 SbF 6 Inorganic materials 0.000 description 1
125000005595 acetylacetonate group Chemical group 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
VBVBHWZYQGJZLR-UHFFFAOYSA-I antimony pentafluoride Chemical compound F[Sb](F)(F)(F)F VBVBHWZYQGJZLR-UHFFFAOYSA-I 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
239000012300 argon atmosphere Substances 0.000 description 1
YBGKQGSCGDNZIB-UHFFFAOYSA-N arsenic pentafluoride Chemical compound F[As](F)(F)(F)F YBGKQGSCGDNZIB-UHFFFAOYSA-N 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
238000002524 electron diffraction data Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
239000004973 liquid crystal related substance Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
239000000523 sample Substances 0.000 description 1
238000004626 scanning electron microscopy Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000012279 sodium borohydride Substances 0.000 description 1
229910000033 sodium borohydride Inorganic materials 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
229910021381 transition metal chloride Inorganic materials 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
238000007740 vapor deposition Methods 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymerization Catalysts (AREA)

JP10496083A 1983-06-14 1983-06-14 高配向アセチレン重合体の製造方法 Granted JPS59230009A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP10496083A JPS59230009A (ja)	1983-06-14	1983-06-14	高配向アセチレン重合体の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP10496083A JPS59230009A (ja)	1983-06-14	1983-06-14	高配向アセチレン重合体の製造方法

Publications (2)

Publication Number	Publication Date
JPS59230009A JPS59230009A (ja)	1984-12-24
JPH0225373B2 true JPH0225373B2 (de)	1990-06-01

Family

ID=14394662

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP10496083A Granted JPS59230009A (ja)	1983-06-14	1983-06-14	高配向アセチレン重合体の製造方法

Country Status (1)

Country	Link
JP (1)	JPS59230009A (de)

1983
- 1983-06-14 JP JP10496083A patent/JPS59230009A/ja active Granted

Also Published As

Publication number	Publication date
JPS59230009A (ja)	1984-12-24

Publication	Publication Date	Title
Lee et al.	1997	Effect of process parameters on the characteristics of indium tin oxide thin film for flat panel display application
US4880508A (en)	1989-11-14	Water-soluble conductive polymers
US4394304A (en)	1983-07-19	Electrically conducting polymer blends
EP0026234B1 (de)	1984-07-11	Verfahren zur herstellung eines hoch-leitfähigen acetylen-hochpolymers
Passerini et al.	1995	Spin-coated V2O5 xerogel thin films. 1. Microstructure and morphology
US4362680A (en)	1982-12-07	Process for production of molded articles of acetylene polymer
Möller et al.	1989	Poly (2‐vinylpyridine) block copolymers. Phase separation and electric conductivity of iodine complexes
US4596852A (en)	1986-06-24	Process for producing a gel-like composition of a high polymer of acetylene, and process for molding said composition
US4228060A (en)	1980-10-14	Polymerization of acetylene
JPH0225373B2 (de)	1990-06-01
US4600756A (en)	1986-07-15	High-orientability polyacetylene films and process for their production
US4579921A (en)	1986-04-01	Process for the manufacture of polyacetylene
EP0332704A1 (de)	1989-09-20	Verfahren zur herstellung leitfähiger polymerfilme
EP0124979B1 (de)	1989-04-26	Polyacethylenherstellung
Grayer et al.	1995	Perfectly alternating ethylene—carbon monoxide copolymers: structure and morphology of epitaxially grown crystals
JPS647445B2 (de)	1989-02-08
US4870147A (en)	1989-09-26	Process for producing highly conductive polyacetylene film
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JPH03109430A (ja)	1991-05-09	一軸配向ポリアセチレン膜の製造方法
JPH02119008A (ja)	1990-05-07	導電性ポリアセチレン膜の製造方法
JPS6342565B2 (de)	1988-08-24
JPS60124609A (ja)	1985-07-03	単結晶ポリアセチレンの製造方法
Piao et al.	2000	Advanced conjugated polymer—helical polyacetylene
JPS62139266A (ja)	1987-06-22	高分子固体電解質
US4927578A (en)	1990-05-22	Method for producing uncrosslinked polyacetylene film