JPH02259172A - Pigment printing paste composition - Google Patents
Pigment printing paste compositionInfo
- Publication number
- JPH02259172A JPH02259172A JP1080100A JP8010089A JPH02259172A JP H02259172 A JPH02259172 A JP H02259172A JP 1080100 A JP1080100 A JP 1080100A JP 8010089 A JP8010089 A JP 8010089A JP H02259172 A JPH02259172 A JP H02259172A
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- extender
- composition according
- printing paste
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Coloring (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、著しく濃度感が増し、かつ、色相が鮮明にな
る顔料捺染糊組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a pigment printing paste composition that has a significantly increased sense of density and a clear hue.
（従来の技術）
顔料捺染糊は、通常、顔料全水中に分散した水性加工顔
料と、顔料固着用樹脂エマルジ、ンとミネラルターペン
を界面活性剤で、水中に乳化した希釈糊とからなる。(Prior Art) Pigment printing paste usually consists of a water-based processed pigment dispersed in total pigment water, and a diluted paste made by emulsifying pigment fixing resin emulsion and mineral turpentine in water using a surfactant.
従来より、顔料捺染糊の中に、体質顔料を含有する物は
しばしば使用されてきている。しかしこれらの顔料捺染
糊はマットプリントとよばれる捺染に使用されてきた。Conventionally, pigment printing pastes containing extender pigments have often been used. However, these pigment printing pastes have been used for printing called matte printing.
マットプリントとは、既に染料または顔料で、均一な色
に着色された布（地染め布と呼ばれる）の上に別の絵柄
を捺染する時、従来の顔料捺染糊の中に、体質顔料を添
加して捺染する方法である。Matte printing is when a different pattern is printed onto a cloth that has already been uniformly colored with dyes or pigments (called ground-dyed cloth).Extender pigments are added to the conventional pigment printing paste. This is a method of printing.
（発明が解決しようとする課題）
ただし、これらの場合、体質顔料の添加量は、顔料捺染
糊中に１０重重量上り多く含有させる事が通常である。(Problems to be Solved by the Invention) However, in these cases, the amount of extender pigment added is usually 10 weight or more in the pigment printing paste.
体質顔料の持つ隠蔽外により、地染め布の色を消し、顔
料捺染糊の色をあらたに布上に表わすためである。もし
このとき体質顔料を全く含有していない場合には、捺染
された絵柄の色は、顔料捺染糊の色と地染め布の色の混
合した色となってしまう。This is to erase the color of the ground-dyed fabric through the concealment properties of the extender pigment, and to reveal the color of the pigment printing paste on the fabric. If no extender pigment is contained at this time, the color of the printed pattern will be a mixture of the color of the pigment printing paste and the color of the ground-dyed cloth.
（課題全解決するための手段）
本発明者等は、鋭意研究の結果、体質顔料全少量顔料捺
染糊に添加すると、得られた捺染布の濃度感と鮮明性が
著しく向上することを見い出し、本発明全完成するに至
った。(Means for Solving All the Problems) As a result of intensive research, the present inventors have discovered that when a small amount of extender pigment is added to a pigment printing paste, the density and sharpness of the resulting printed fabric are significantly improved. The present invention has now been fully completed.
すなわち、本発明は、体質顔料（ｒ ０．１〜１０重景
係含有することを特徴とする顔料捺染糊組成物を提供す
るものである。That is, the present invention provides a pigment printing paste composition characterized by containing an extender pigment (r 0.1 to 10).
本発明で用いる顔料捺染糊としては、例えば従来の顔料
？水中に分散した水性加工顔料と顔料固着用樹脂エマル
ジョン、増粘剤、疎水性有機溶剤及びその乳化剤から形
成される水中油滴型エマルジョンの捺染用糊剤より成る
通常の捺染糊でも、また特公昭５８−７７５５号公報等
に示されているようなソープフリー型捺染糊でもよく、
その形態は特に規定されない。ソープフリー型捺染剤は
捺染用糊剤と水性加工顔料とから成る顔料捺染糊であり
、例えば捺染用糊剤としては、特定のアルカリ増粘型水
性エマルジョン重合体全アルカリ性物質で中和し、ミネ
ラルターペンの如き疎水性有機溶剤を乳化させた水中油
滴型エマルジョン糊等が挙げられ、また水性加工顔料と
しては、アルカリ可溶性重合体及び顔料全混合した水性
加工顔料等が挙げられる。As the pigment printing paste used in the present invention, for example, conventional pigment printing paste may be used. Ordinary printing pastes consisting of printing pastes of oil-in-water emulsions formed from aqueous processing pigments dispersed in water, pigment-fixing resin emulsions, thickeners, hydrophobic organic solvents, and their emulsifiers; A soap-free printing paste as shown in Japanese Patent No. 58-7755 etc. may also be used.
Its form is not particularly defined. A soap-free printing agent is a pigment printing paste consisting of a printing sizing agent and a water-based processed pigment.For example, as a printing sizing agent, a specific alkali-thickened water-based emulsion polymer is neutralized with a total alkaline substance, and mineral Examples include oil-in-water emulsion pastes made by emulsifying a hydrophobic organic solvent such as turpentine, and examples of water-based processed pigments include water-based processed pigments that are a complete mixture of an alkali-soluble polymer and pigment.
本発明で用いる体質顔料とは、無彩色の無機顔料であり
、例えば酸化珪素、アルミナシリケート、沈降性炭酸カ
ルシウム、バライト、沈降性硫酸バリウム、炭酸マグネ
シウム、アルミナ、タレタルタ、硅藻土、石膏、白亜、
炭酸バリウム、クロスホワイト、サチン白などが挙げら
れる。The extender pigments used in the present invention are achromatic inorganic pigments, such as silicon oxide, alumina silicate, precipitated calcium carbonate, barite, precipitated barium sulfate, magnesium carbonate, alumina, taretarta, diatomaceous earth, gypsum, and chalk. ,
Examples include barium carbonate, cross white, and sachin white.
尚、亜鉛華、酸化チタン、鉛白、塩基性硫酸鉛、リトポ
ン、硫化亜鉛、チクン酸鉛、酸化ジルコニウム等の白色
顔料は少量の添加でもマット性がでるため、本発明の目
的には好ましくない。Note that white pigments such as zinc white, titanium oxide, lead white, basic lead sulfate, lithopone, zinc sulfide, lead ticunate, and zirconium oxide are not preferable for the purpose of the present invention because they cause matte properties even when added in small amounts. .
体質顔料の平均粒子径は、０６０１〜１０μｍのもの全
通常用いるが、なかでも０．０２〜６μｍのものが好寸
（−い。添加量は、顔料捺染糊と体質顔料とからなる顔
料捺染糊組成物中での含有率が通常０．１〜１０重量％
、好ましくは０．５〜６重量饅となる範囲である。Extender pigments with an average particle diameter of 0.601 to 10 μm are usually used, but those of 0.02 to 6 μm are particularly suitable. The content in the composition is usually 0.1 to 10% by weight.
, preferably within a range of 0.5 to 6 weight cakes.
体質顔料の添加は捺染糊中であっても、樹脂中であって
も、活性剤中であっても、あるいは、これらの混合物の
中であってもよく、特に規定するものでは無い。また、
体質顔料の形態は、粉末状であっても、コロイダルシリ
カのようにあらかじめ、水中に微分散されていても良い
。The extender pigment may be added in the printing paste, the resin, the activator, or a mixture thereof, and is not particularly limited. Also,
The extender pigment may be in the form of a powder or may be finely dispersed in water like colloidal silica.
（実施例）
以下に実施例および比較例金挙げて本発明を更に具体的
に説明する。尚、例中の部および％はすべで重量基準で
ある。(Examples) The present invention will be explained in more detail below by giving examples and comparative examples. In addition, all parts and percentages in the examples are based on weight.
実施例１〜５および比較例１〜５
増粘性乳化剤（ＲＹＵＤＹＥ −Ｗ ＲＥＤＵｃＥＲＣ
０ＮＣ５００大日本インキ化学工業株式会社裂）５部を
水３０部に溶解し、ホモミキサーで攪拌しながら、ミネ
ラルターペン６５部添加し、水中油滴型エマルジョン希
釈糊を得た。Examples 1 to 5 and Comparative Examples 1 to 5 Thickening emulsifier (RYUDYE-W REDUcERC
0NC500 Dainippon Ink & Chemicals Co., Ltd.) was dissolved in 30 parts of water, and while stirring with a homomixer, 65 parts of mineral turpentine was added to obtain an oil-in-water emulsion diluted paste.
次に、表−１に示す組成で希釈糊、顔料固着用アクリル
系樹脂エマルジョン（樹脂分４０％）水性加工顔料（銅
フタロシアニングルー２５％含有）および各体質顔料全
混合し、顔料捺染糊組成物中得た。Next, the diluted paste, acrylic resin emulsion for pigment fixation (resin content 40%), water-based processed pigment (containing 25% copper phthalocyanine blue), and each extender pigment were all mixed with the composition shown in Table 1 to form a pigment printing paste composition. Got it inside.
ついで、この顔料捺染糊組成物全使用し、下記条件で捺
染布を得た。Next, the entire pigment printing paste composition was used to obtain a printed fabric under the following conditions.
捺染方法＝フラットヌクリーン捺染（９０メツシユスク
リーン紗使用）
布地：綿６０番ブロード
工程：捺染−乾燥（１００ＣＸＩ分）−熱処理（１３０
ＣＸ２分）
この捺染布の濃度感および鮮明性について目視による評
価全実施した。結果を表−１に示す。Printing method = flat clean printing (using 90 mesh screen gauze) Fabric: No. 60 cotton broad Step: Printing - Drying (100 CXI minutes) - Heat treatment (130 CXI minutes)
CX 2 minutes) The density and sharpness of this printed fabric were visually evaluated. The results are shown in Table-1.
尚、濃度感鮮明性の評価は以下の基準で行った。Note that the evaluation of density sensitivity sharpness was performed based on the following criteria.
◎：最良
○：良
△：やや不良
×：％に不良
その結果、実施例１〜５ではいずれも濃度感および鮮明
性で比較例１および３より優れていた。◎: Best ○: Good △: Slightly poor ×: % poor As a result, Examples 1 to 5 were all superior to Comparative Examples 1 and 3 in terms of density and sharpness.
比較例２，４および５０色相はいずれもパステル調であ
り、実施例に見られるような濃度感および鮮明性は得ら
れなかった。The hues of Comparative Examples 2, 4, and 50 were all pastel, and the sense of density and sharpness as seen in the examples could not be obtained.
と ）
（発明の効果）
本発明の顔料捺染糊組成物を用いると濃度ｇおよび鮮明
性に優ね２る捺染布が得られる。(Effects of the Invention) When the pigment printing paste composition of the present invention is used, a printed fabric with excellent density g and sharpness can be obtained.
Claims (1)
とする顔料捺染糊組成物。 ２、体質顔料を０．５〜６重量％含有する請求項１記載
の組成物。 ３、体質顔料の平均粒子径が０．０１〜１０μｍである
請求項１記載の組成物。 ４、体質顔料の平均粒子径が０．０２〜６μｍである請
求項１記載の組成物。 ５、体質顔料が酸化珪素、アルミナシリケート、沈降性
炭酸カルシウム、バライト、沈降性硫酸バリウム、炭酸
マグネシウム、アルミナ、クレー、タルク、硅藻土、石
膏、白亜、炭酸バリウム、クロスホワイトおよびサチン
白から選ばれる一種以上の体質顔料である請求項１記載
の組成物。 ６、水性加工顔料と顔料固着用樹脂エマルジョンと増粘
剤と疎水性有機溶剤とその乳化剤を含有してなる水中油
滴型エマルジョンとを含む請求項１記載の組成物。 ７、水性加工顔料とアルカリ増粘型水性エマルジョン重
合体とアルカリ性物質と疎水性有機溶剤とを含有してな
る水中油滴型エマルジョンとを含む請求項１記載の組成
物。[Scope of Claims] 1. A pigment printing paste composition containing 0.1 to 10% by weight of an extender pigment. 2. The composition according to claim 1, which contains an extender pigment in an amount of 0.5 to 6% by weight. 3. The composition according to claim 1, wherein the extender pigment has an average particle diameter of 0.01 to 10 μm. 4. The composition according to claim 1, wherein the extender pigment has an average particle diameter of 0.02 to 6 μm. 5. Extender pigment selected from silicon oxide, alumina silicate, precipitated calcium carbonate, barite, precipitated barium sulfate, magnesium carbonate, alumina, clay, talc, diatomaceous earth, gypsum, chalk, barium carbonate, cross white and satin white The composition according to claim 1, which is one or more extender pigments. 6. The composition according to claim 1, comprising an oil-in-water emulsion containing a water-based processed pigment, a pigment fixing resin emulsion, a thickener, a hydrophobic organic solvent, and an emulsifier thereof. 7. The composition according to claim 1, comprising an aqueous processed pigment, an aqueous alkali-thickened emulsion polymer, an alkaline substance, and a hydrophobic organic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1080100A JPH02259172A (en) | 1989-03-30 | 1989-03-30 | Pigment printing paste composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1080100A JPH02259172A (en) | 1989-03-30 | 1989-03-30 | Pigment printing paste composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02259172A true JPH02259172A (en) | 1990-10-19 |
Family
ID=13708765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1080100A Pending JPH02259172A (en) | 1989-03-30 | 1989-03-30 | Pigment printing paste composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02259172A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103243577A (en) * | 2012-02-10 | 2013-08-14 | 山东欧化印染家纺有限公司 | High-mesh high-definition pattern printing technology |
-
1989
- 1989-03-30 JP JP1080100A patent/JPH02259172A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103243577A (en) * | 2012-02-10 | 2013-08-14 | 山东欧化印染家纺有限公司 | High-mesh high-definition pattern printing technology |
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