JPH02264100A - Production of matte coated paper - Google Patents
Production of matte coated paperInfo
- Publication number
- JPH02264100A JPH02264100A JP8551589A JP8551589A JPH02264100A JP H02264100 A JPH02264100 A JP H02264100A JP 8551589 A JP8551589 A JP 8551589A JP 8551589 A JP8551589 A JP 8551589A JP H02264100 A JPH02264100 A JP H02264100A
- Authority
- JP
- Japan
- Prior art keywords
- coated paper
- paper
- matte
- calcium carbonate
- average particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
「産業上の利用分野」
本発明は、艶消し塗被紙、特に低白紙光沢で低インキ光
沢を発現し、上品で印刷モトルが発生せず、且つ印刷適
性の優れた艶消し塗被紙を製造する方法に関する。Detailed Description of the Invention "Industrial Application Field" The present invention is a matte coated paper, especially one that exhibits low white paper gloss and low ink gloss, is elegant and does not generate printing mottle, and has excellent printability. The present invention relates to a method for producing matte coated paper.
「従来の技術」
艶消し塗被紙は高光沢を有する一般の印刷用塗被紙に比
較して上品で深みのあるトーンを醸し出すために高級イ
メージ惑が強(、例えば各種書籍や雑誌等の表紙、高級
ポスター、カタログ等から本文用紙に至るまで幅広く利
用され、汎用価値の高い塗被加工紙の一つである。``Prior art'' Matte coated paper has a more sophisticated and deep tone compared to high-gloss general coated paper for printing, so it has a strong image of being a high-class product (for example, it is used in various books, magazines, etc.) It is widely used for everything from covers, high-end posters, catalogs, etc. to body paper, and is one of the coated papers with high general-purpose value.
従来、艶消し塗被紙としては2種類が有り、その1つは
マント−グロス型と呼ばれ、白紙光沢は低いが高いイン
キ光沢を有する艶消し塗被紙であり、他の1つはマット
−マット型と呼ばれ、白紙光沢もインキ光沢も共に低い
艶消し塗被紙である。Conventionally, there are two types of matte coated paper: one is called a mantle-gloss type, which is a matte coated paper with low white paper gloss but high ink gloss, and the other is matte coated paper. - Called matte type, it is a matte coated paper with low white gloss and ink gloss.
即ち、前者のマント−グロス型塗被紙の製造方法は、印
刷インキの吸収を抑えて、インキ光沢を出す必要性から
、緻密な塗被層面を作る必要がありインキ光沢の出やす
い顔料、例えば平均粒子径が約0.5〜1.5μmの比
較的微粒子の顔料を使用した塗被組成物を塗被し、例え
ば特公昭59−53956号に記載されているように塗
被層表面を粗面化金属ロールを有するキャレンダーで艶
消し仕上げをする低白紙光沢−高インキ光沢の艶消し塗
被紙であり、白紙光沢(JIS P8142法)も25
〜40%と比較的高くなっている。又、後者のマット−
マット型塗被紙の製造方法は、通常の印刷塗被紙の製造
に用いられる塗被紙用顔料のうち、平均粒子径が1〜2
μm程度の比較的粗い顔料を主成分とする塗被液を原紙
に塗被乾燥後、キャレンダー等によって平滑化仕上げを
せずにそのまま仕上げるか、或いは非常に軽くキャレン
ダー処理をして仕上げられるもので、白紙光沢度も5〜
30%と低い低白紙光沢−低インキ光沢タイプの艶消し
塗被紙である。一般にこのような艶消し塗被紙は平滑度
が著しく劣り、且つ印刷適性も悪いものである。That is, in the former manufacturing method of cloak-gloss type coated paper, it is necessary to suppress the absorption of printing ink and produce ink gloss, so it is necessary to create a dense coating layer surface, and pigments that tend to produce ink gloss, such as pigments, are required to produce ink gloss. A coating composition using a relatively fine pigment having an average particle diameter of about 0.5 to 1.5 μm is applied, and the surface of the coating layer is roughened as described in Japanese Patent Publication No. 59-53956. It is a matte coated paper with low white gloss and high ink gloss that is finished with a matte finish using a calender with surfaced metal rolls, and the white paper gloss (JIS P8142 method) is also 25.
It is relatively high at ~40%. Also, the latter mat-
The method for producing matte coated paper uses pigments for coated paper used in the production of ordinary printing coated paper, which have an average particle size of 1 to 2.
A coating liquid whose main component is a relatively coarse pigment on the order of micrometers is coated on base paper, dried, and then finished as is without smoothing with a calender, etc., or it can be finished with a very light calender treatment. The white paper gloss level is 5~
It is a matte coated paper with a low white paper gloss of 30% - low ink gloss. Generally, such matte coated paper has extremely poor smoothness and printability.
従って、良好な平滑性を得る為にはやはり、キャレンダ
ー等による表面加圧処理が必要であるが、粒子径の細か
い、例えばカオリン等を高率配合したような塗被組成物
を用いると、容易に白紙光沢やインキ光沢が出やすくな
り、一方顔料に炭酸カルシウムのような粒子形状が不定
形の顔料を主顔料として使用すれば、白紙光沢はより低
く抑えることができるが、塗被層表面のミクロポーラス
性(微細孔)がキャレンダー処理により減少するために
インキ光沢がででしまい、結果としてマツドーグロス型
塗被紙になってしまう、特にオフセット印刷による多色
刷りのベタ部では、インキ光沢が斑になり非常に醜い印
刷仕上がりとなる。尚、塗被組成物を塗被後ブレードで
掻きおとして、計量と平滑化を行うような場合も塗被層
が緻密化されるために、結果としてインキ光沢が発現さ
れてしまう。上記の如き事情から、良好な平滑性を有す
るマット−マット型の艶消し塗被紙が得られていないの
が現状である。Therefore, in order to obtain good smoothness, surface pressure treatment with a calender or the like is still necessary, but if a coating composition containing a high proportion of fine particle size, such as kaolin, is used, On the other hand, if a pigment with irregular particle shape, such as calcium carbonate, is used as the main pigment, the white paper gloss can be suppressed to a lower level, but the surface of the coating layer Because the microporosity (micropores) of the paper is reduced by calendering, the ink becomes glossy, resulting in Mazdo gloss-type coated paper.Especially in the solid areas of multicolor printing by offset printing, the ink gloss becomes This results in mottling and a very ugly print finish. Incidentally, even when the coating composition is scraped off with a blade after coating to perform measurement and smoothing, the coating layer is densified, resulting in the development of ink gloss. Due to the above-mentioned circumstances, it is currently not possible to obtain a matte-matte type coated paper having good smoothness.
「発明が解決しようとする課題」
本発明の方法は、高い平滑性と印刷モトルのない優れた
印刷適性を有するマット−マット型の艶消し塗被紙を得
る方法を提供するものである。``Problem to be Solved by the Invention'' The method of the present invention provides a method for obtaining a matte-matte coated paper having high smoothness and excellent printability without printing mottle.
「課題を解決するための手段」
本発明は、原紙上に顔料と接着剤を主成分とする水性塗
被組成物を塗被乾燥後、キャレンダー仕上げする艶消し
塗被紙の製造方法において、原紙の動的濡れ値が−0,
32〜O,’20gであり、顔料として平均粒子径が2
〜15μmの炭酸カルシウムを50〜100重量部、サ
チンホワイトを0.1〜5.0重量部含有させたことを
特徴とする艶消し塗被紙の製造方法である。"Means for Solving the Problems" The present invention provides a method for producing matte coated paper in which a water-based coating composition containing pigments and adhesives as main components is coated on a base paper, dried, and then calendered. The dynamic wetting value of the base paper is -0,
32~O,'20g, and the average particle size is 2 as a pigment.
This is a method for producing a matte coated paper characterized by containing 50 to 100 parts by weight of calcium carbonate with a diameter of ~15 μm and 0.1 to 5.0 parts by weight of Sachin White.
「作用」
本発明者等は、前述の如くマット−マット型タイプの艶
消し塗被紙を得る方法において、塗被層を平滑化すると
インキ光沢が高くなり、その上に印刷インキモトルが発
現し、又インキ光沢を低くする対策を取ると逆に平滑度
を落とさなければならないという矛盾した問題について
鋭意検討、研究を重ねた結果、主顔料として平均粒子径
が2〜15μmである粗粒子炭酸カルシウム、補助顔料
として特定量のサチンホワイトを含有する水性塗被。"Function" The present inventors have discovered that in the method of obtaining a matte-matte type matte coated paper as described above, when the coating layer is smoothed, the ink gloss increases, and printing ink mottle develops thereon. In addition, as a result of intensive study and research into the contradictory problem that taking measures to lower the ink gloss would have to reduce the smoothness, we found that as the main pigment, coarse particle calcium carbonate with an average particle diameter of 2 to 15 μm, Water-based coating containing a specific amount of Sachin White as an auxiliary pigment.
組成物を、特定の動的濡れ値を有する原紙上に塗被する
ことによって、印刷インキモトルの発生がな(、しかも
印刷適性の極めて優れたマット−マット型タイプの艶消
し塗被紙が得られることを見出し、遂に本発明を完成す
るに至った。By coating the composition on a base paper having a specific dynamic wetting value, a matte-matte coated paper of the matte-mat type type, which does not generate printing ink mottle and has excellent printability, can be obtained. This discovery led to the completion of the present invention.
先ず、本発明の方法における原紙特性、即ち動的濡れ値
について述べる。First, the characteristics of the base paper in the method of the present invention, that is, the dynamic wetting value will be described.
原紙の動的濡れ値としては−0,32〜0.20gに特
定されるものであるが、該濡れ値が−0,32g未満の
場合は塗被液の原紙への浸透が非常に遅くなり、塗被液
の不動化時間が長くなり、バインダーのマイグレーシラ
ンが起こり易く、均一なバインダーの分布が損なわれる
ために、印刷後に印刷インキモトルが発生し易くなる。The dynamic wetting value of the base paper is specified as -0.32 to 0.20 g, but if the wetting value is less than -0.32 g, the penetration of the coating liquid into the base paper is extremely slow. , the immobilization time of the coating liquid becomes longer, migration of the binder is more likely to occur, and the uniform distribution of the binder is impaired, so that printing ink mottles are more likely to occur after printing.
一方0.20gを越えると原紙内への塗被液の浸透が速
く、本発明の塗被液を原紙上に塗被した場合、平均粒子
径が2〜15μmの重質炭酸カルシウムを主顔料とする
保水性の悪い塗被組成物は加速度的に原紙内への浸透が
促進され、結果として原紙面上に留まる塗被組成物が少
なくなり、原紙面の被覆が十分に行われないために、所
望とする面平滑を得ることができない。On the other hand, if it exceeds 0.20 g, the coating liquid penetrates into the base paper quickly, and when the coating liquid of the present invention is coated on the base paper, the main pigment is heavy calcium carbonate with an average particle size of 2 to 15 μm. Coating compositions with poor water retention properties are accelerated to penetrate into the base paper, and as a result, less of the coating composition remains on the base paper surface, and the base paper surface is not sufficiently covered. It is not possible to obtain the desired surface smoothness.
ここに、動的濡れ値とは動的濡れ性試験器(NET−3
000/IIレスカ製)を用いて、原紙の水に対する濡
れ易さ(付着力)を時間的に測定した値である。具体的
には上記試験器を用い、2X5cm+試験片を16禦■
/秒の速さで、水中12m−の深さに10秒間浸漬した
時の経時的濡れの大きさ(付着力)を測定するものであ
るが、本発明者等は濡れ値について、さらに検討を加え
た結果、試験スタートから2秒後の濡れ値がインキモト
ルと平滑性に極めて大きな相関関係を有することが判っ
た。よって、本発明ではこの2秒後の測定値を動的濡れ
値とするものである。そして、動的濡れ値は値が小さい
程、水濡れが悪く、値が大きくなる程水濡れがよくなる
ことを示すものである。Here, the dynamic wettability value is the dynamic wettability tester (NET-3
This is a value obtained by measuring the wettability (adhesive force) of the base paper with water over time using a 3D paper (manufactured by Resca 000/II). Specifically, using the above tester, test a 2 x 5 cm + test piece for 16 mm.
This method measures the degree of wetting over time (adhesion force) when immersed in water at a depth of 12 m for 10 seconds at a speed of 10 seconds. As a result, it was found that the wettability value 2 seconds after the start of the test had an extremely large correlation with the ink motility and smoothness. Therefore, in the present invention, the measured value after 2 seconds is defined as the dynamic wetting value. The smaller the dynamic wetting value, the worse the water wetting, and the larger the value, the better the water wetting.
なお、原紙の動的濡れ値の調整は、パルプ組成、叩解条
件、填料の種類と添加量、紙力剤、内添サイズ剤、pH
,表面サイズ剤、表面処理剤、乾燥条件等を個々の抄紙
機及び抄紙条件により適宜調整して決定されるものであ
り、−概に特定できるものではない。また、本発明の方
法で特定した原紙の動的濡れ値と印刷インキモトルとの
間に見られた明瞭な相関関係は、従来の吸水性適性とし
て祇試験等に適用されているコブ吸水度、ステキヒトサ
イズ度等の値との間には見出せ無かった。The dynamic wetting value of base paper can be adjusted by adjusting the pulp composition, beating conditions, type and amount of filler, paper strength agent, internal sizing agent, and pH.
, surface sizing agent, surface treatment agent, drying conditions, etc., are determined by appropriately adjusting them depending on the individual paper machine and paper making conditions, and cannot be generally specified. Furthermore, the clear correlation observed between the dynamic wetting value of the base paper and the printing ink mottle determined by the method of the present invention is similar to the Cobb water absorbency, which is applied in the Gio test, etc., as the conventional water absorbency aptitude. No correlation was found between the values of human size, etc.
因みに、原紙の動的濡れ値が0.20gを越えると(原
紙の濡れ値が大きいと)原紙内への水性系組成物の浸透
が速く、本発明の塗被液を原紙上に塗被した場合、平均
粒子径が2〜15μ霧の重質炭酸カルシウムを主顔料と
する保水性の悪い塗被組成の為、相乗効果的に水性系組
成物の原紙内への浸透が速くなり、原紙上に溜る水性系
塗被組成物の量が減少し、結果として原紙面の被覆が充
分行われず、所望とする面平滑を得ることが出来ない。Incidentally, when the dynamic wetting value of the base paper exceeds 0.20 g (when the wetting value of the base paper is large), the aqueous composition penetrates into the base paper quickly, and the coating liquid of the present invention was coated on the base paper. In this case, since the coating composition has poor water retention properties and contains heavy calcium carbonate as the main pigment with an average particle size of 2 to 15 μm, the aqueous composition synergistically penetrates into the base paper faster and The amount of aqueous coating composition that accumulates in the paper decreases, and as a result, the surface of the base paper is not sufficiently coated, making it impossible to obtain the desired surface smoothness.
一方、動的濡れ値が−0,32g未満(濡れ不足)にな
ると、原紙内への水性塗被組成物、の浸透が非常に遅く
なり、塗被液の不動化時間が長くなり、バインダーのマ
イグレーシランが起こり易くなり、均一なバインダーの
分布が損なわれ、結果として、印刷後、印刷インキモト
ルが発生する。On the other hand, when the dynamic wetting value is less than -0.32 g (insufficient wetting), the penetration of the aqueous coating composition into the base paper becomes very slow, the immobilization time of the coating liquid becomes long, and the binder Migration silane is more likely to occur, impairing the uniform binder distribution and resulting in printing ink mottles after printing.
次いで、塗被組成物の顔料特性について述べる。Next, the pigment characteristics of the coating composition will be described.
即ち、一般の印刷塗被紙用塗被組成物の主顔料として使
用される顔料としては、例えばカオリン、タルク、水酸
化アルミニウム等があるが、これら平板状の顔料を使用
すると、その平均粒子径が2〜15μ゛mを満たしてい
ても、これらの顔料は塗被層面に平行に配向し、塗被層
が緻密に仕上がり、インキ吸収性が遅くなるために、結
果としてインキ光沢が発現される。従って、本発明の方
法では、主顔料として粒子形状が不定形であり、且つ塗
被工程或いはカレンダー処理によっても原則的に並行に
配向化しない粗粒の重質炭酸カルシウムが特に好ましい
。また、二次凝集により粗粒子化した比表面積の大きい
軽質炭酸カルシウムを用いても、低いインキ光沢を維持
しながら面子滑性の良い艶消し塗被紙を得ることも可能
である。That is, pigments used as main pigments in coating compositions for general printing coated paper include, for example, kaolin, talc, aluminum hydroxide, etc., but when these tabular pigments are used, their average particle diameter Even if the thickness is 2 to 15 μm, these pigments are oriented parallel to the surface of the coated layer, resulting in a dense coated layer and slower ink absorption, resulting in ink gloss. . Therefore, in the method of the present invention, it is particularly preferable to use coarse-grained heavy calcium carbonate as the main pigment, which has an amorphous particle shape and which, in principle, does not become parallelly oriented during the coating process or calendering process. Further, even by using light calcium carbonate having a large specific surface area and made into coarse particles by secondary aggregation, it is possible to obtain matte coated paper with good surface smoothness while maintaining low ink gloss.
本発明における塗被組成物の主成分として使用される炭
酸カルシウムは比較的粗大粒子径のものを使用すること
を特徴とし、具体的にはその平均粒子径を2〜15μm
、より好ましくは3〜10μmに特定するものである。The calcium carbonate used as the main component of the coating composition in the present invention is characterized in that it has a relatively coarse particle size, and specifically, the average particle size is 2 to 15 μm.
, more preferably 3 to 10 μm.
因みに、2μm未満ではインキ光沢が高くなり過ぎ、1
5μmを越えると塗被層表面のミクロ平滑性が低下して
印刷適性が劣るようになり、いずれも不適当である。な
お、全顔料中に占める上記特定の炭酸カルシウムの量は
50〜100重量部が好ましく、50重量部未満の場合
は所望Φ効果を得ることが難しくなる。また、−方では
主顔料として粗大粒子径の炭酸カルシウムを用いるため
、塗被液の固状化点(紙パ技協誌39巻第7号621頁
参照)が高くなり、結果として乾燥工程において接着剤
のマイグレーシランが起こり印刷インキモトルを改良す
るには至らなかった。Incidentally, if the thickness is less than 2 μm, the ink gloss will become too high;
If it exceeds 5 μm, the micro-smoothness of the surface of the coating layer will decrease, resulting in poor printability, and both are unsuitable. Note that the amount of the above-mentioned specific calcium carbonate in the total pigment is preferably 50 to 100 parts by weight, and if it is less than 50 parts by weight, it becomes difficult to obtain the desired Φ effect. In addition, in the - method, since calcium carbonate with a coarse particle size is used as the main pigment, the solidification point of the coating liquid (see Paper and Paper Technical Association Vol. 39, No. 7, p. 621) becomes high, and as a result, in the drying process. Adhesive migration caused silane migration, and printing ink motility could not be improved.
従って、本発明者等は上記の如きインキモトルを改善す
る方法として、塗被組成物の固状化点を下げてやること
が極めて重要な要件であることを突き止め、種々検討、
研究を重ねた結果、塗被組成物中に補助顔料として、少
量のサチンホワイトを添加してやると、塗被組成物の固
状化点が極めて効果的に下がることを見出した。即ち、
サチンホワイトとして全顔料中に0.1〜5.0重量部
、より好ましくは0.5〜3.0重量部の範囲で適用す
ると好ましい結果を得ることができた。Therefore, the present inventors have found that lowering the solidification point of the coating composition is an extremely important requirement as a method for improving the above-mentioned ink motility, and have carried out various studies.
As a result of repeated research, it has been found that the solidification point of the coating composition can be extremely effectively lowered by adding a small amount of Sachin White as an auxiliary pigment to the coating composition. That is,
Favorable results were obtained when Sachin White was applied in an amount of 0.1 to 5.0 parts by weight, more preferably 0.5 to 3.0 parts by weight, to the total pigment.
理由については必ずしも明らかではないが、少量のサチ
ンホワイトを使用すると、本発明における粗大粒子径の
炭酸カルシウムを用いた場合に見られる、塗被液の固状
化点の上昇を顕著に低下させる作用効果を示すことであ
る。因みに、0.1重量部未満では固状化点の低下効果
が見られず、−方5.0重量部を越えると、塗被紙の白
紙光沢及びインキ光沢が高くなり所望のマット−マット
型の塗被紙を得ることができない、なお、本発明で使用
されるサチンホワイトの平均粒子径としては1゜2μm
以下のものが好ましい。1.2μmを越えると、塗被組
成物をブレード塗工する場合にストラクタイト、スクラ
ッチ及びストリーク等が発生し易くなるので望ましくな
い。Although the reason is not necessarily clear, the use of a small amount of Sachin White has the effect of significantly reducing the increase in the solidification point of the coating liquid, which is seen when calcium carbonate with a coarse particle size is used in the present invention. The goal is to demonstrate effectiveness. Incidentally, if it is less than 0.1 parts by weight, no effect of lowering the solidification point is observed, and if it exceeds 5.0 parts by weight, the white paper gloss and ink gloss of the coated paper will increase, resulting in the desired matte-matte type. However, the average particle diameter of Sachin White used in the present invention is 1°2 μm.
The following are preferred. If it exceeds 1.2 μm, it is undesirable because structite, scratches, streaks, etc. are likely to occur when the coating composition is applied with a blade.
また、サチンホワイトの平均粒子径は以下の如き測定方
法によって定めた値である。Moreover, the average particle diameter of Sachin White is a value determined by the following measurement method.
即ち、分散剤としてポリアクリル酸ナトリウムをサチン
ホワイト(固形分)に対し5重量%添加し、固形分濃度
2〜3重量%のサチンホワイトの分散液を調製し、30
〜35℃で超音波分散器により5分間分散させて、重力
沈降法(測定器/セデイグラフ5000−01 :島津
製作所製)により粒度重量分布を測定し、得られた粒度
重量分布で50%時の球相当直径をサチンホワイト(比
重;1.77とした)の平均粒子径とした。サチンホワ
イトの結晶形は針状或いは棒状であるが、本発明の所望
の効果を得るには、この平均粒子径測定法を用いて考察
するのが最も育効な方法であった。That is, 5% by weight of sodium polyacrylate was added to Sachin White (solid content) as a dispersant to prepare a dispersion of Sachin White with a solid content concentration of 2 to 3% by weight.
Dispersion was carried out at ~35°C for 5 minutes using an ultrasonic disperser, and the particle size and weight distribution was measured using the gravity sedimentation method (measuring device/Sedaygraph 5000-01: manufactured by Shimadzu Corporation). The equivalent sphere diameter was taken as the average particle diameter of Sachin White (specific gravity: 1.77). Although the crystal form of Sachin White is needle-like or rod-like, in order to obtain the desired effects of the present invention, the most effective method for growth was to use this average particle diameter measurement method.
なお、本発明の方法において調製される塗被組成物とし
ては、塗被層のミクロ平滑性を改良する為に、顔料とし
て炭酸カルシウム以外に塗被紙用顔料として汎用されて
いるカオリン、クレー、酸化チタン、タルク、焼成りレ
ー等の顔料が本発明の目的を損なわない範囲で適宜使用
される(全顔料に対し50重量%未満)、シかしながら
、これ等の顔料は通常平均粒子径が2μ以下のものが多
いから、本発明の効果が損なわれない程度に調節するこ
とが必要である。The coating composition prepared by the method of the present invention contains, in addition to calcium carbonate, kaolin, clay, which is commonly used as a pigment for coating paper, in order to improve the micro-smoothness of the coating layer. Pigments such as titanium oxide, talc, and calcined clay are used as appropriate within the range that does not impair the purpose of the present invention (less than 50% by weight based on the total pigment). However, these pigments usually have an average particle size of Since many of them have a diameter of 2μ or less, it is necessary to adjust the thickness to such an extent that the effects of the present invention are not impaired.
上記の如く、本発明で使用する顔料は各種のものが用い
られるが、顔料の種類によって比重が異なることもあっ
て、混合顔料の平均粒子径を直接測定することが難しく
、本発明では島津製作所■製の粒度分布測定器(SA
−CF2)により、予め用いる個々の顔料について単独
の平均粒子径を測定しておき、そのときの顔料配合に応
じて、計算により全顔料の平均粒子径を算出した。As mentioned above, various types of pigments are used in the present invention, but since the specific gravity differs depending on the type of pigment, it is difficult to directly measure the average particle diameter of the mixed pigment. ■Particle size distribution analyzer (SA
-CF2), the individual average particle size of each pigment used was measured in advance, and the average particle size of all pigments was calculated according to the pigment formulation at that time.
塗被組成物中に使用される接着剤としては、例えばカゼ
イン、大豆蛋白、合成蛋白等の蛋白質類とスチレン・ブ
タジェン共重合体、メチルメタクルレート・ブタジェン
共重合体等の共役ジエン系重合体ラテックス、アクリル
酸エステル及び/又はメタクリル酸エステルの重合体又
は共重合体等のアクリル系重合体ラテックス、エチレン
・酢酸ビニル共重合体等のビニル系重合体ラテックス、
或いはこれら各種重合体ラテックスをカルボキシル基等
の官能基含有単量体で変性したアルカリ溶解性或いはア
ルカリ非溶解性の重合体ラテックス;ポリビニルアルコ
ール、オレフィン・無水マレイン酸樹脂、メラミン樹脂
等の合成樹脂系接着剤陽性澱粉、酸化澱粉等の澱粉類;
カルボキシメチルセルロース、ヒドロキシエチルセルロ
ース等のセルロース誘導体の如き通常の塗被紙用接着剤
の1種又は2種以上が適宜選択して使用される。尚、一
般に接着剤は顔料100に対して5〜30重量%、より
好ましくは10〜20重量%程度の範囲で配合される。Examples of adhesives used in the coating composition include proteins such as casein, soybean protein, and synthetic proteins, and conjugated diene polymers such as styrene-butadiene copolymers and methyl methacrylate-butadiene copolymers. Acrylic polymer latex such as latex, polymer or copolymer of acrylic acid ester and/or methacrylic acid ester, vinyl polymer latex such as ethylene/vinyl acetate copolymer,
Or alkali-soluble or alkali-insoluble polymer latexes obtained by modifying these various polymer latexes with monomers containing functional groups such as carboxyl groups; synthetic resin systems such as polyvinyl alcohol, olefin/maleic anhydride resins, and melamine resins. Starches such as adhesive-positive starch and oxidized starch;
One or more types of common adhesives for coated paper such as cellulose derivatives such as carboxymethyl cellulose and hydroxyethyl cellulose are appropriately selected and used. The adhesive is generally blended in an amount of 5 to 30% by weight, more preferably 10 to 20% by weight, based on 100% of the pigment.
また、塗被組成物中には必要に応じて消泡剤、着色剤、
離型剤、流動変性剤等の各種助剤が適宜配合されるが、
塗被層の固化を促進する助剤として、例えばアミン、ア
ミド、ポリアクリルアミド等や亜鉛、アルミニウム、マ
グネシウム、カルシウム、バリウム等の多価金属塩を顔
料100に対して0.1〜10重量%程度添加すること
も可能である。In addition, antifoaming agents, coloring agents,
Various auxiliary agents such as mold release agents and flow modifiers are appropriately blended, but
As an auxiliary agent to promote solidification of the coating layer, for example, amine, amide, polyacrylamide, etc., or polyvalent metal salts such as zinc, aluminum, magnesium, calcium, barium, etc. are used in an amount of about 0.1 to 10% by weight based on 100 parts of the pigment. It is also possible to add.
かくして、得られた水性塗被組成物は一般公知の、例え
ばブレードコーター、エヤーナイフコーター、ロールコ
ータ−、リバースロールコターバーコーター、カーテン
コーター、ダイスロフトコーター、グラビヤコーター、
チャンブレックスコーター、サイズプレスコーター等の
塗被装置を設けたオンマシン或いはオフマシンコーター
によって原紙上に一層或いは多層に分けて塗被されるが
、特に、本発明の場合最上層の塗被層はブレードコータ
ーによって形成されることが重要である。The aqueous coating composition thus obtained can be coated using a generally known coating method such as a blade coater, air knife coater, roll coater, reverse roll coater, curtain coater, die loft coater, gravure coater, etc.
The base paper is coated in one layer or in multiple layers using an on-machine or off-machine coater equipped with a coating device such as a chambrax coater or a size press coater. In particular, in the case of the present invention, the uppermost coating layer is It is important that it is formed by a blade coater.
本発明における塗被組成液はベント型或いはベベル型の
ブレードコーターで塗被する場合には、エアーナイフコ
ーター、ロールコータ−、ロッドコーター等のコーター
で塗被した場合に比較して、より優れた平滑な塗被層面
が得られる。しかし、このようにブレード塗工を行う場
合は、前述した如く塗被液中に配合されるサチンホワイ
トの平均粒子径を1.2μm以下にしてお(ことが重要
である。When the coating composition of the present invention is coated with a vent type or bevel type blade coater, it has better properties than when coated with a coater such as an air knife coater, roll coater, or rod coater. A smooth coating layer surface can be obtained. However, when performing blade coating in this manner, it is important to keep the average particle size of Sachin White blended in the coating liquid to 1.2 μm or less, as described above.
さらに、本発明者等は塗被組成液を原紙に塗工した後の
乾燥についても検討を加えた結果、乾燥条件もバインダ
ーのマイグレーションの動向に大きく関与していること
が判った。特に、本発明の方法のように、粗粒子炭酸カ
ルシウムを主顔料に用いた場合には、原紙に塗被液を塗
被した後で従来の如き蒸気加熱、ガスヒーター加熱、熱
風加熱、ドラム加熱等によって乾燥すると、塗被層の表
面部分のみの乾燥が先行し、塗被層全体にわたる均一な
乾燥(特にZ軸方向の乾燥)が行われず、結果的に乾燥
ムラやバインダーのマイグレーションが起こり1、印刷
インキのモトル発生が助長される傾向のあることが判明
した。Furthermore, the present inventors also investigated the drying process after coating the base paper with the coating composition liquid, and as a result, it was found that the drying conditions are also greatly involved in the trend of binder migration. In particular, when coarse-particle calcium carbonate is used as the main pigment as in the method of the present invention, after coating the base paper with the coating liquid, conventional methods such as steam heating, gas heater heating, hot air heating, and drum heating are applied. When drying by such methods, only the surface portion of the coating layer dries first, and uniform drying over the entire coating layer (particularly drying in the Z-axis direction) is not achieved, resulting in uneven drying and binder migration. It was found that the occurrence of mottle in printing ink tends to be promoted.
かかる知見に基づき、さらに乾燥に関して鋭意研究を重
ねた結果、湿潤塗被層の乾燥手段として、近赤外線を使
用すると塗被層の乾燥が全体的(Z軸方向にわたり)に
均一となり、本発明の所望の効果を得るために、極めて
有効な手段であることが判った。Based on this knowledge, we conducted extensive research on drying, and found that using near-infrared rays as a means of drying a wet coating layer results in uniform drying of the coating layer as a whole (along the Z-axis direction). It has been found that this is an extremely effective means for obtaining the desired effect.
赤外線乾燥は従来からよ(知られている乾燥方式の1つ
であるが、赤外線は通常、その波長が0゜75〜2.5
μmの近赤外域、2.5〜25μmの中間赤外域、25
〜2000μmの遠赤外域の赤外線に大別されるもので
あり(機器分析のてびき一化学同人/1979年4月2
0日発行参照)、一般には波長が2.5μm以上の中間
赤外線や遠赤外線が専ら使用されているものであるが、
本発明の方法で使用する近赤外線による乾燥は比較的新
しい乾燥方式である。Infrared drying is one of the conventional (known drying methods), but the wavelength of infrared rays usually ranges from 0°75 to 2.5°.
Near-infrared region of μm, mid-infrared region of 2.5-25 μm, 25
It is broadly classified into infrared rays in the far infrared range of ~2000 μm (Instrumental Analysis Guide Ichi Kagaku Dojin/April 2, 1979)
(Refer to the issue published on 0th) Generally, mid-infrared rays and far infrared rays with a wavelength of 2.5 μm or more are exclusively used.
The near-infrared drying used in the method of the present invention is a relatively new drying method.
即ち、本発明の方法では、この近赤外域の赤外線を選択
的に利用するものであり、波長が0.75〜2.5μm
1より好ましくは1.0〜2.0μmの近赤外線を利用
するものである。因みに、波長が0.75μm未満であ
るとコート層の乾燥及び固化のための水分蒸発に対する
効果が極めて少なくなり、−方2.5μmを越えると、
通常の水分の蒸発、乾燥には有効であるが、本発明の所
望の効果を得ることができない。That is, in the method of the present invention, infrared rays in the near-infrared region are selectively used, and the wavelength is 0.75 to 2.5 μm.
More preferably, near-infrared rays of 1.0 to 2.0 μm are used. Incidentally, if the wavelength is less than 0.75 μm, the effect on water evaporation for drying and solidifying the coating layer will be extremely small, and if the wavelength exceeds 2.5 μm,
Although this method is effective for ordinary water evaporation and drying, the desired effect of the present invention cannot be obtained.
このように、近赤外線乾燥が印刷インキのモトル発生の
防止に効果があるのは、必ずしも明らかではないが、近
赤外線は塗被層に対する透過力が強く、且つエネルギー
密度も高いため、本発明で特定された原紙に特定のサチ
ンホワイトを含有した湿潤塗被組成物を乾燥する場合、
塗被層が瞬時に且つ均一に固化、乾燥が進行するために
バインダーのマイグレーションが効果的に抑制される結
果によるものとおもわれる。このために、塗被層中のバ
インダーの均一な分布が損なわれないので印刷インキモ
トルの発生しない、所望とする艶消し塗被紙が得られる
ものと推定される。As described above, it is not necessarily clear that near-infrared drying is effective in preventing the occurrence of mottle in printing ink, but near-infrared rays have a strong penetrating power through coating layers and a high energy density, so the present invention When drying a wet coating composition containing a specific satin white on a specified base paper,
This is thought to be due to the fact that the coating layer solidifies and dries instantly and uniformly, effectively suppressing migration of the binder. For this reason, it is presumed that the desired matte coated paper, which does not cause printing ink mottle, can be obtained because the uniform distribution of the binder in the coating layer is not impaired.
以上述べたように、特定の顔料配合から成る塗被組成物
を特定の動的濡れ値を有する原紙に塗被乾燥して仕上げ
ると両者の相乗効果によって、極めて効果的にインキモ
トルが解消され、然も優れた平滑性を有する艶消し塗被
紙を得ることができる。As mentioned above, when a coating composition consisting of a specific pigment formulation is coated and dried on a base paper having a specific dynamic wettability value, ink mottle can be eliminated extremely effectively due to the synergistic effect of the two. It is also possible to obtain matte coated paper with excellent smoothness.
なお、本発明において使用される原紙の米坪としては3
0〜400 g / rl程度のものが目的に応じて適
宜使用される。In addition, the base paper used in the present invention has a weight of 3.
A material having a weight of about 0 to 400 g/rl is used as appropriate depending on the purpose.
また、原紙への塗被量は、通常乾燥重量で片面当り3〜
50 g / rd程度であるが、得られる塗被紙の白
紙品質、印刷適性等を考慮すると8〜30g/−程度の
範囲で調節するのが望ましく、又、乾燥後の塗被紙の水
分は通常3〜10%の範囲に調節される。In addition, the amount of coating on the base paper is usually 3 to 3 per side on a dry weight basis.
It is about 50 g/rd, but considering the blank paper quality and printability of the coated paper obtained, it is desirable to adjust it within the range of about 8 to 30 g/rd, and the moisture content of the coated paper after drying is It is usually adjusted within the range of 3 to 10%.
かくして、得られた乾燥塗被紙はオン或いはオフのスー
パーキャレンダー、マントキャレンダー粗面化ロールキ
ャレンダーやソフトキャレンダー等で加圧仕上げされる
が、本発明の方法では白紙光沢(JIS P 8142
法に準じた測定に基づく)が25%以下、より好ましく
は20%以下となるように軽度の加圧仕上げが行われる
。この場合、本発明の所望とするバランスの取れた白紙
光沢と平滑性を得る為には、艶消し塗被紙の密度として
1.00〜1゜18g/m”程度の範囲になるように仕
上げるのが望ましい。The dried coated paper obtained in this way is pressure-finished using an on or off super calender, a cloak calender, a roughening roll calender, a soft calender, etc., but the method of the present invention provides a white paper gloss (JIS P) finish. 8142
Light pressure finishing is carried out so that the amount (based on measurements according to the law) is 25% or less, more preferably 20% or less. In this case, in order to obtain the balanced white paper gloss and smoothness desired by the present invention, the density of the matte coated paper should be in the range of about 1.00 to 1.18 g/m". is desirable.
上記の如き特定の原紙、塗料、塗工方法及び乾燥方法に
より得られる本発明の艶消し塗被紙は、白紙光沢及び印
刷インキ光沢が低く、且つ面平滑並びに印刷後の印刷モ
トルの改良されたマット−マット型の塗被紙を提供する
ものである。The matte coated paper of the present invention obtained using the above-mentioned specific base paper, paint, coating method and drying method has low white paper gloss and printing ink gloss, and has improved surface smoothness and printing mottle after printing. A matte-matte type coated paper is provided.
「実施例」
以下に実施例を挙げて本発明をより具体的に説明するが
、勿論これらに限定されるものではない。"Example" The present invention will be described in more detail with reference to Examples below, but it is of course not limited to these.
なお、特に断らない限り、例中の「部」及び「%」はそ
れぞれ「重量部」及び「重量%」を示す。Note that unless otherwise specified, "parts" and "%" in the examples indicate "parts by weight" and "% by weight," respectively.
実施例1
平均粒子径が8μ−の重質炭酸カルシウム99部、平均
粒子径が0.8μmのサチンホワイト1部、分散剤とし
てポリアクリル酸ソーダ0.2部をコーレス分散機を用
いて水中に分散し、固形分濃度70%の顔料スラリーを
調製した。この顔料スラリーに酸化澱粉7部(固形分)
を加え更に水を加えて固形分濃度60%の塗被液を調製
した。Example 1 99 parts of heavy calcium carbonate with an average particle size of 8 μm, 1 part of Sachin White with an average particle size of 0.8 μm, and 0.2 parts of sodium polyacrylate as a dispersant were added to water using a Coles disperser. A pigment slurry having a solid content concentration of 70% was prepared by dispersing the pigment. Add 7 parts of oxidized starch (solid content) to this pigment slurry.
was added, and water was further added to prepare a coating liquid with a solid content concentration of 60%.
この水性塗被液を動的濡れ値が−0,20gになるよう
に抄紙された米坪74 g / nrの原紙に乾燥重量
が片面当たり25 g / tdとなるようにブレード
コーターで両面を塗被し、熱風乾燥機で乾燥後、塗被紙
の密度が1.05g/cm3となるようにスーパーキャ
レンダー掛けを行って艶消し塗被紙を得た。得られた艶
消し塗被紙について下記に示す品質評価を行い、その結
果を表−1に示した。This aqueous coating liquid was coated on both sides with a blade coater so that the dry weight was 25 g/td per side on base paper of 74 g/nr, which was made to have a dynamic wetting value of -0.20 g. After coating and drying in a hot air dryer, super calendering was carried out so that the density of the coated paper was 1.05 g/cm 3 to obtain a matte coated paper. The quality evaluation shown below was performed on the obtained matte coated paper, and the results are shown in Table-1.
〔品質評価項目と評価方法コ
全顔料平均粒子径:粒度分布測定器5A−CF2 (島
津製作所製)を用いて各顔料の平均
粒子径(μ−)をそれぞれ測定し、計
算により求めた。[Quality evaluation items and evaluation methods] Average particle diameter of all pigments: The average particle diameter (μ-) of each pigment was measured using a particle size distribution analyzer 5A-CF2 (manufactured by Shimadzu Corporation) and determined by calculation.
白紙光沢i JIS P 8142に準じ角度75°で
測定した。White paper gloss i Measured at an angle of 75° according to JIS P 8142.
白紙平滑度;スムースター平滑度計(東英電子社製)を
用いて測定した。White paper smoothness: Measured using a Smoother smoothness meter (manufactured by Toei Denshi Co., Ltd.).
値が小さい程、平滑性が良い。The smaller the value, the better the smoothness.
印刷モトル;RI印刷機(明製作所製)を使用して印刷
を行い、藍インキの印刷ム
ラ状態を目視判定により評価した。Printing Mottle: Printing was performed using an RI printing machine (manufactured by Mei Seisakusho), and the state of printing unevenness of the indigo ink was evaluated by visual judgment.
極めて良好 良好 極めて劣る実施例2
実施例1において、重質炭酸カルシウム99部の代わり
に、平均粒子径が14μ−の重質炭酸カルシウム50部
、平均粒子径が4μ譜の軽質炭酸カルシウム49部を用
いた以外は、同様にして艶消し塗被紙を得た。得られた
艶消し塗被紙について実施例1と同様にして品質評価を
行い、その結果を表−1に示した。Very good Good Very poor Example 2 In Example 1, instead of 99 parts of heavy calcium carbonate, 50 parts of heavy calcium carbonate with an average particle size of 14μ and 49 parts of light calcium carbonate with an average particle size of 4μ were used. A matte coated paper was obtained in the same manner except that the following was used. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
実施例3
実施例1において、重質炭酸カルシウム99部の代わり
に、平均粒子径が3μ−の重質炭酸カルシウム99部を
用いた以外は、同様にして艶消し塗被紙を得た。得られ
た艶消し塗被紙について実施例1と同様にして品質評価
を行い、その結果を表−1に示した。Example 3 A matte coated paper was obtained in the same manner as in Example 1, except that 99 parts of heavy calcium carbonate having an average particle size of 3 μm was used instead of 99 parts of heavy calcium carbonate. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
実施例4
顔料として、平均粒子径が8μ■の重質炭酸カルシウム
96部、平均粒子径が0.8μ−のサチンホワイト4部
を用いた以外は実施例1と同様にして艶消し塗被紙を得
た。得られた艶消し塗被紙について実施例1と同様に品
質評価を行い、その結果を表−1に示した。Example 4 A matte coated paper was prepared in the same manner as in Example 1, except that 96 parts of heavy calcium carbonate with an average particle size of 8μ and 4 parts of Sachin White with an average particle size of 0.8μ were used as pigments. I got it. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
実施例5〜6
動的濡れ値がそれぞれ−0,25,0,15gである原
紙を用いた以外は、実施例1と同様にして艶消し塗被紙
を得た。得られた艶消し塗被紙について実施例1と同様
に品質評価を行い、その結果を表−1に示した。Examples 5 to 6 Matt coated papers were obtained in the same manner as in Example 1, except that base papers having dynamic wetting values of -0, 25, 0, and 15 g, respectively, were used. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
実施例7
顔料として平均粒子径が14μ−の重質炭酸カルシウム
89部、カオリン10部、平均粒子径が0.8μ醜のサ
チンホワイト1部を用い塗被液を調製し、この塗被液を
実施例1と同様の原紙に塗被した直後に1.2μm波長
の近赤外線を照射し、さらに熱風乾燥機で乾燥した以外
は、実施例1と同様にして艶消し塗被紙を得た。得られ
た艶消し塗被紙について実施例1と同様に品質評価を行
い、その結果を表−1に示した。Example 7 A coating liquid was prepared using 89 parts of heavy calcium carbonate with an average particle size of 14μ as pigments, 10 parts of kaolin, and 1 part of Sachin White with an average particle size of 0.8μ. A matte coated paper was obtained in the same manner as in Example 1, except that the same base paper as in Example 1 was coated with near-infrared rays at a wavelength of 1.2 μm and further dried in a hot air dryer. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
実施例8〜10
乾燥方法として、実施例7に準じた方法を用いたが、こ
の場合に赤外線照射における赤外線の波長をそれぞれ1
.2.1.7.0.7μlとした以外は、実施例1と同
様にして艶消し塗被紙を得た。得られた艶消し塗被紙に
ついて、実施例1と同様にして品質評価を行い、その結
果を表−1に示した。Examples 8 to 10 As a drying method, a method similar to Example 7 was used, but in this case, the wavelength of infrared rays in infrared irradiation was changed to 1
.. 2.1.7. A matte coated paper was obtained in the same manner as in Example 1, except that the volume was changed to 0.7 μl. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
比較例1〜2
実施例1において、顔料として平均粒子径が8μ−の重
質炭酸カルシウムの代わりに、平均粒子径がそれぞれ1
.0.17.0μ讃の重質炭酸カルシウムを用いた以外
は、実施例1と同様にして艶消し塗被紙を得た。得られ
た艶消し塗被紙について実施例1と同様に品質評価を行
い、その結果を表−1に示した。Comparative Examples 1 to 2 In Example 1, instead of heavy calcium carbonate having an average particle diameter of 8μ as a pigment, each pigment had an average particle diameter of 1μ.
.. A matte coated paper was obtained in the same manner as in Example 1, except that 0.17.0 μm of ground calcium carbonate was used. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
比較例3
実施例1において、塗被組成物用顔料である平均粒子径
が8μ−の重質炭酸カルシウム99部の代わりに、平均
粒子径が8μ−の重質炭酸カルシウム30部及びカオリ
ン69部を用いた以外は、実施例1と同様にして艶消し
塗被紙を得た。得られた艶消し塗被紙について実施例1
と同様に品質評価を行い、その結果を表−1に示した。Comparative Example 3 In Example 1, 30 parts of ground calcium carbonate with an average particle size of 8 μ- and 69 parts of kaolin were used instead of 99 parts of heavy calcium carbonate with an average particle size of 8 μ-, which is the pigment for coating composition. A matte coated paper was obtained in the same manner as in Example 1 except that . Example 1 for the obtained matte coated paper
Quality evaluation was conducted in the same manner as above, and the results are shown in Table 1.
比較例4
実施例1において、顔料として平均粒子径が8μ−の重
質炭酸カルシウム94部、平均粒子径が3μ−のサチン
ホワイト6部を用いた以外は、実施例1と同様にして艶
消し塗被紙を得た。得られた艶消し塗被紙について実施
例1と同様に品質評価を行い、その結果を表−1に示し
た。しかしながら、この場合はブレード塗工時にストラ
クタイト、スクラッチの発生がみられブレード塗工適性
が不適であった。Comparative Example 4 Matting was produced in the same manner as in Example 1, except that 94 parts of heavy calcium carbonate with an average particle diameter of 8 μ- and 6 parts of Sachin White with an average particle diameter of 3 μ- were used as pigments. A coated paper was obtained. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1. However, in this case, structite and scratches were observed during blade coating, making the blade coating unsuitable.
比較例5
顔料として平均粒子径が8μ−の重質炭酸カルシウム9
9.95部、平均粒子径が0.8μ閣のサチンホワイト
0.05部を用いた以外は、実施例1と同様にして艶消
し塗被紙を得た。得られた艶消し塗被紙について実施例
1と同様に品質評価を行い、その結果を表−1に示した
。Comparative Example 5 Heavy calcium carbonate 9 with an average particle diameter of 8μ as a pigment
A matte coated paper was obtained in the same manner as in Example 1, except that 9.95 parts and 0.05 parts of Sachin White having an average particle size of 0.8 μm were used. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
比較例6〜7
動的濡れ値がそれぞれ−0,34,0,22gである原
紙を用いた以外は、実施例1と同様にして艶消し塗被紙
を得た。得られた艶消し塗被紙について実施例1と同様
に品質評価を行いその結果を表−1に示した。Comparative Examples 6-7 Matte coated papers were obtained in the same manner as in Example 1, except that base papers having dynamic wetting values of -0, 34, 0, and 22 g were used, respectively. The quality of the obtained matte coated paper was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
尚、実施例7〜10で使用した赤外線照射装置の光源は
スイラメント、集光板、対向反射板より構成されており
、フィラメントにはタングステンを使用し、これを16
00〜3800−Kに電気加熱することにより近赤外線
を得た。そして得られた近赤外線を金コーティングした
集光板(フィラメント上部に配置)により集光し紙に放
射した。又、紙を通過した近赤外線は紙の裏側に配置さ
れたアルミニウム板で反射され、紙に再放射されるよう
に成っており塗被層がより一層均−に乾燥さるように工
夫されている。The light source of the infrared irradiation device used in Examples 7 to 10 is composed of a filament, a light condensing plate, and an opposing reflector, and the filament is made of tungsten.
Near-infrared radiation was obtained by electrical heating from 00 to 3800-K. The near-infrared rays thus obtained were collected by a gold-coated light collecting plate (placed above the filament) and radiated onto the paper. In addition, the near-infrared rays that have passed through the paper are reflected by an aluminum plate placed on the back side of the paper and re-radiated onto the paper, which is designed to dry the coated layer more evenly. .
「効果」
表−1の結果から明らかなように、本発明の実施例で得
られた塗被紙は、所望とする光沢及び平滑性を有し、且
つ印刷モトルの発生しない、優れたマット−マット型の
艶消し塗被紙であった。"Effects" As is clear from the results in Table 1, the coated paper obtained in the examples of the present invention has the desired gloss and smoothness, and has an excellent matte finish that does not cause printing mottle. It was a matte coated paper.
Claims (6)
成物を塗被乾燥後、キャレンダー仕上げする艶消し塗被
紙の製造方法において、原紙の動的濡れ値が−0.32
〜0.20gであり、顔料として平均粒子径が2〜15
μmの炭酸カルシウムを50〜100重量部、サチンホ
ワイトを0.1〜5.0重量部含有させたことを特徴と
する艶消し塗被紙の製造方法。(1) A method for producing matte coated paper in which an aqueous coating composition containing pigments and adhesives as main components is coated on a base paper, dried, and then calendered, in which the dynamic wetting value of the base paper is -0. 32
~0.20g, and the average particle size as a pigment is 2~15
A method for producing matte coated paper, characterized in that it contains 50 to 100 parts by weight of μm calcium carbonate and 0.1 to 5.0 parts by weight of Sachin White.
る請求項(1)記載の艶消し塗被紙の製造方法。(2) The method for producing a matte coated paper according to claim (1), wherein the base paper has a dynamic wettability value of -0.25 to 0.10 g.
項(1)記載の艶消し塗被紙の製造方法。(3) The method for producing matte coated paper according to claim (1), wherein the calcium carbonate is heavy calcium carbonate.
に準じた測定で25%以下である請求項(1)記載の艶
消し塗被紙の製造方法。(4) The method for producing matte coated paper according to claim 1, wherein the glossiness of the matte coated paper is 25% or less as measured in accordance with JISP8142 method.
含む水性塗被組成物をブレード塗工し、且つカレンダー
仕上げ後のスムースター平滑度が60cmHg以下であ
る請求項(1)記載の艶消し塗被紙の製造方法。(5) The matte according to claim (1), wherein the aqueous coating composition containing Sachin White having an average particle diameter of 1.2 μm or less is applied with a blade, and the smoothness after calendering is 60 cmHg or less. Method of manufacturing coated paper.
化又は乾燥手段として波長が0.75〜2.5μmであ
る近赤外線を使用する請求項(1)記載の艶消し塗被紙
の製造方法。(6) The matte matte according to claim (1), wherein after applying the aqueous coating composition, near infrared rays having a wavelength of 0.75 to 2.5 μm are used as means for solidifying or drying the wet coating liquid. Method of manufacturing coated paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8551589A JP2696795B2 (en) | 1989-04-03 | 1989-04-03 | Process for producing matte coated paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8551589A JP2696795B2 (en) | 1989-04-03 | 1989-04-03 | Process for producing matte coated paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02264100A true JPH02264100A (en) | 1990-10-26 |
| JP2696795B2 JP2696795B2 (en) | 1998-01-14 |
Family
ID=13861049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8551589A Expired - Fee Related JP2696795B2 (en) | 1989-04-03 | 1989-04-03 | Process for producing matte coated paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2696795B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0875792A3 (en) * | 1997-04-30 | 1999-01-13 | Xerox Corporation | Method of printing and printing medium |
| JP2014208933A (en) * | 2013-03-28 | 2014-11-06 | 日本製紙株式会社 | Coated white paperboard and production method thereof |
-
1989
- 1989-04-03 JP JP8551589A patent/JP2696795B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0875792A3 (en) * | 1997-04-30 | 1999-01-13 | Xerox Corporation | Method of printing and printing medium |
| US5935689A (en) * | 1997-04-30 | 1999-08-10 | Xerox Corporation | Method of printing and printing medium |
| JP2014208933A (en) * | 2013-03-28 | 2014-11-06 | 日本製紙株式会社 | Coated white paperboard and production method thereof |
| JP2019090159A (en) * | 2013-03-28 | 2019-06-13 | 日本製紙株式会社 | Coated white paperboard and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2696795B2 (en) | 1998-01-14 |
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