JPH02265150A - Sheet plasma ion and electron source by uramoto method - Google Patents

Sheet plasma ion and electron source by uramoto method

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Publication number
JPH02265150A
JPH02265150A JP1085579A JP8557989A JPH02265150A JP H02265150 A JPH02265150 A JP H02265150A JP 1085579 A JP1085579 A JP 1085579A JP 8557989 A JP8557989 A JP 8557989A JP H02265150 A JPH02265150 A JP H02265150A
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Japan
Prior art keywords
gas
source
plasma
anode
discharge
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JP1085579A
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Japanese (ja)
Inventor
Joshin Uramoto
上進 浦本
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Individual
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  • Electron Sources, Ion Sources (AREA)

Abstract

PURPOSE:To generate an ion beam with high electric current density by supplying He gas from an ion source, an electron source, and a discharging cathode side and O2 gas from an anode side. CONSTITUTION:A porous first drawing out electrode 24 which has a large surface area and is to be mounted on a sheet plasma side plane and a first electrode 27 which is for drawing out an ion beam from a linear plasma source are kept positive voltage against an anode 13 and when high positive voltage is applied to a second drawing out electrode 25 with a large surface area and a second drawing out electrode 28, electrons are accelerated. In this case, the anode side becomes a linear electron source and generates plane-like electron beam. Meanwhile, the side plane of a sheet plasma becomes a plane-like electron source and the accelerated electrons are curved by a magnetic field and form an electron flow focusing in vertical direction to a horizontal plane. To generate ion source of O2 which is especially important and chemically active gas, O2 gas is supplied from the anode side 20 and basic electric discharge is maintained by supplying He gas from the cathode side. By this method, aimed oxygen ion source with large current and high electric current density is achieved.

Description

【発明の詳細な説明】 材料表面の改質をイオンビーム照射によって行う方法は
最近重要性を増している。しかしながら、大面積材料の
表面を高速で一様に改質するためには点状のイオン源か
ら加速されるイオンビーム(線形)では不可能に近い。
DETAILED DESCRIPTION OF THE INVENTION A method of modifying the surface of a material by ion beam irradiation has recently become increasingly important. However, it is nearly impossible to uniformly modify the surface of a large-area material at high speed with an ion beam (linear) accelerated from a point-like ion source.

新しい試みとして、長い線状のイオン源から加速された
イオンビーム(面積形)を用いて材料に照射し、材料を
一定速度で移動する方法、更に発展して大面積状のイオ
ン源から加速されたイオンビーム(体積形)を材料表面
に照射する方法が考えられる。この観点から、−様で高
密度の長い線状または大面積状イオン源の開発が先づ要
求される。この要求を簡単に充すのがシートプラズマで
ある。即ち、巾が広く、厚みが薄い紙状のプラズマであ
る。紙状の面を利用すれば面状のイオン源(電子源)と
なり、紙状の先端を利用すれば長い線状のイオン源(電
子源)となる。このシートプラズマを直流放電で生成す
るとすれば、留意すべき重要な問題として、放電の熱陰
極が物理的損傷(イオン逆流衝突と陰極材料の熱的寿命
)から保護されること、また化学的損傷(化学的活性気
体、例えば酸素のイオン源とするとき)からも保護され
ねばならないことである。かくて、陽極と細長い熱陰極
の間の直接放電によるシートプラズマの生成法は陰極が
物理的にも、化学的にも保護されないので工業化には適
しない。代って、陽極と陰極の間に中間電極を入れて、
陰極領域をI Torr前後、陽極領域を1O−3To
rr前後に保つ圧力勾配型放電が考えられる。この圧力
勾配型放電では、陽極領域からのイオン逆流衝突による
陰極の損傷は、陰極領域でのイオンの平均自由行程が極
めて短かいので避けることができる。この原理はまた、
陰極側から不活性気体(Ar、 He等)を流して基本
放電を維持し、陽極側に化学的活性気体(02、N2等
)を導入してそのイオン源をつくる場合にも適用される
。即ち、陰極領域の不活性気体の圧力が陽極領域より1
03倍程度高いので、陽極側の化学的活性気体による陰
極の化学的損傷が避けられる。
As a new attempt, we have developed a method in which an ion beam (area type) accelerated from a long linear ion source is used to irradiate the material and move the material at a constant speed. One possible method is to irradiate the material surface with an ion beam (volume type). From this point of view, the development of long linear or large area ion sources with -like high density is required first. Sheet plasma easily meets this requirement. That is, it is paper-like plasma that is wide and thin. If the paper-like surface is used, it becomes a planar ion source (electron source), and if the paper-like tip is used, it becomes a long linear ion source (electron source). If this sheet plasma is to be generated by a DC discharge, an important issue to keep in mind is that the hot cathode of the discharge is protected from physical damage (ion backflow collisions and thermal lifetime of the cathode material), and that it is protected from chemical damage. It must also be protected from chemically active gases (when used as an ion source of oxygen, for example). Thus, the method of generating sheet plasma by direct discharge between an anode and an elongated hot cathode is not suitable for industrialization because the cathode is neither physically nor chemically protected. Instead, insert an intermediate electrode between the anode and cathode,
The cathode area is around I Torr, and the anode area is 1O-3Torr.
A pressure gradient type discharge that maintains the temperature around rr is considered. In this pressure gradient type discharge, damage to the cathode due to ion backflow collisions from the anode region can be avoided because the mean free path of ions in the cathode region is extremely short. This principle also
It is also applied when an inert gas (Ar, He, etc.) is flowed from the cathode side to maintain a basic discharge, and a chemically active gas (02, N2, etc.) is introduced to the anode side to create an ion source. That is, the pressure of the inert gas in the cathode region is 1 lower than that in the anode region.
Since it is about 0.03 times higher, chemical damage to the cathode due to chemically active gas on the anode side can be avoided.

さてここで問題となるのはその圧力勾配型放電を構成す
る中間電極である。シートプラズマを放電によって生成
することを考えると、常識的には第1図と第2図に示し
たようなスリット形の窓を持った中間電極になり、陰極
も細長い形状になる。このとき中間電極の排気コンダク
タンスに注意しなければならない。例えば20cm巾の
シートプラズマを生成するとて、経験上20cm X 
0 、5cmのスリット窓で3 cm長さ程度の中間電
極が必要になる。そのスリット窓の排気のコンダクタン
スは約200 l /sec (Arに対して)になり
、陰極側をI Torr、陽極側を10’ Torrに
保つとすれば、200Torr4 /seeの気体流量
が陰極側から必要になり、陽極側で2 X 105/!
 /secの排気速度のポンプが要求される。この速度
は極めて大きなものであり、般の真空設備での実現は不
可能である。結局、このスリット形式の中間電極を有す
る圧力勾配型放電は以下の重大な欠点を生ずる。■ガス
効率が極めて悪い。■放電々力効率が悪い(放電々流が
中間電極を通過し難い)。■シートプラズマの中白のプ
ラズマ密度が一様になり難い。■簡単で長寿命の放電陰
極(特許出願54−057395 )を使用できない。
Now, the problem here is the intermediate electrode that constitutes the pressure gradient type discharge. Considering that sheet plasma is generated by electric discharge, common sense would require an intermediate electrode with a slit-shaped window as shown in Figures 1 and 2, and the cathode would also have an elongated shape. At this time, attention must be paid to the exhaust conductance of the intermediate electrode. For example, if you want to generate a sheet plasma with a width of 20 cm, experience shows that 20 cm
A slit window of 0.5 cm requires an intermediate electrode about 3 cm long. The exhaust conductance of the slit window is about 200 l/sec (relative to Ar), and if the cathode side is kept at I Torr and the anode side is kept at 10' Torr, a gas flow rate of 200 Torr4/see will be from the cathode side. 2 x 105/! on the anode side!
A pump with a pumping speed of /sec is required. This speed is extremely high and cannot be realized with general vacuum equipment. As a result, the pressure gradient type discharge having this slit-type intermediate electrode has the following serious drawbacks. ■Gas efficiency is extremely poor. ■Poor discharge efficiency (discharge current is difficult to pass through the intermediate electrode). ■It is difficult for the plasma density in the middle of the sheet plasma to be uniform. ■A simple and long-life discharge cathode (Patent Application No. 54-057395) cannot be used.

■外部的にシートプラズマの巾を調節できない。0弱磁
場で放電しない。従ってこのスリット形式の中間電極を
有するシートプラズマは一般の工業化のための線状、面
状のイオン源(電子源)に適しない。
■The width of the sheet plasma cannot be adjusted externally. No discharge in 0 weak magnetic field. Therefore, a sheet plasma having this slit-type intermediate electrode is not suitable for a linear or planar ion source (electron source) for general industrial use.

そこでこの発明では、圧力勾配型放電と流木式と呼ぶ簡
単で高能率なシートプラズマの生成法(特許出願57−
060634)を組合せて以上のスリット型の欠点を解
決した。先づ、陰極と中間電極は円柱プラズマ(0,7
cmφ前後)用のものをそのまま使用する。かくて、中
間電極は中心孔0 、7 cmφ、長さ3 cm程度の
簡単なものとなり、その排気のコンダクタンスは1.5
1!。
Therefore, in this invention, we developed a simple and highly efficient sheet plasma generation method called pressure gradient discharge and driftwood method (patent application 57-
060634) was combined to solve the above drawbacks of the slit type. First, the cathode and the intermediate electrode are cylindrical plasma (0,7
(around cmφ) can be used as is. In this way, the intermediate electrode is a simple one with a center hole of 0.7 cmφ and a length of about 3 cm, and its exhaust conductance is 1.5.
1! .

/5ec(Arに対して)程度に激減する。この中間電
極を通過した円柱の放電プラズマ流はその両側に配置さ
れた2枚の永久磁石によって簡単にシートプラズマに変
形される(特許出願の生成法)。この状態の真空度につ
いて考察すると、陰極側をI Torrに保つとしても
、陽極側(10−3Torr )に1 、5 X 10
37secの一般的な排気ポンプを配置すればよい(流
量1.5Torrl/5ec)。
/5ec (relative to Ar). The cylindrical discharge plasma flow that has passed through this intermediate electrode is easily transformed into sheet plasma by two permanent magnets placed on both sides (the generation method of the patent application). Considering the degree of vacuum in this state, even if the cathode side is kept at I Torr, the anode side (10-3 Torr) is 1.5 x 10
A general exhaust pump of 37 sec may be installed (flow rate: 1.5 Torrl/5 ec).

即ち、ガス効率とポンプの問題は簡単に解決する、次に
円柱プラズマは磁場に対して軸対称なので、中間電極を
放電プラズマ流が効率よく通過し、放電々力効率を悪化
させない。また、陰極として簡単で長寿命のものが使用
できることは極めて有利である。
That is, the problems of gas efficiency and pumping are easily solved.Secondly, since the cylindrical plasma is axially symmetrical with respect to the magnetic field, the discharge plasma flow passes through the intermediate electrode efficiently and does not deteriorate the discharge force efficiency. It is also very advantageous to be able to use a simple and long-life cathode.

他に、シート巾内でプラズマ密度が一様になる自動補正
機能もあり、弱磁場で使用(25ガウス以上)すること
もできるので、線状、面状のイオン源(電子源)の生成
が簡単で効率的になる。陰極が物理的(特許出願54−
057395の陰極を使用すれば熱的にも長寿命となる
ので更に完全な保護となる)、化学的損傷から保護され
ることは前述の通りである。
In addition, there is an automatic correction function that makes the plasma density uniform within the sheet width, and it can also be used in a weak magnetic field (25 Gauss or more), so it is possible to generate linear or planar ion sources (electron sources). Become easy and efficient. The cathode is physical (patent application 54-
As mentioned above, the use of a cathode made of 057395 provides even more complete protection due to its longer thermal life and protection from chemical damage.

この発明のイオン源は線状、面状のどちらでも選択でき
る。線状のイオン源は第3図のスリット陽極(13)近
辺で形成されるので高密度のプラズマが利用できる。従
って、高電流密度イオンビームを生成できる。なおこの
イオンビームの巾はシー)・プラズマの巾ではマ決定さ
れる(実施例としては現在40cm巾が簡単に実現され
ている)。一方、面状のイオン源はシートプラズマの側
面、第3図で24.25を利用するのでシート巾×シー
トの長さで最大面積が決定される(40cm X 50
cmが簡単に実現されている)。この面状の場合、線状
より可成り(数分の1)プラズマ密度が低下するが、低
電子温度プラズマになっているので(シートの中心から
小さな距離で急激に低電子温度になる)安定に利用でき
る。側面を線状に利用できることは当然である。
The ion source of this invention can be either linear or planar. Since the linear ion source is formed near the slit anode (13) in FIG. 3, high-density plasma can be used. Therefore, a high current density ion beam can be generated. The width of this ion beam is determined by the width of the plasma (currently, a width of 40 cm is easily achieved as an example). On the other hand, a planar ion source uses the side surface of the sheet plasma, 24.25 in Figure 3, so the maximum area is determined by sheet width x sheet length (40 cm x 50 cm).
cm is easily realized). In the case of this sheet shape, the plasma density is considerably lower (by a fraction) than in the linear shape, but it is stable because it is a low electron temperature plasma (the electron temperature suddenly becomes low at a small distance from the center of the sheet). Available for It is natural that the sides can be used linearly.

以上は主として流木式シートプラズマのイオン源への適
用を想定したが、第3図で24.27を陽極(13)に
対して正電位に保ち、25.28に更に高い正電位を与
えれば電子を加速することができる。この場合、陽極側
は線状電子源となり面状の電子ビームを形成する。一方
シートプラズマの側面は面状電子源となり、加速された
電子は磁場によって曲げられ、第3図で、紙面に垂直方
向に集束する形の電子流を形成する。従って、低エネル
ギー(1〜2 KeV)でも大電流の電子流(数A以上
)として利用できる。かくて、従来の電子ビームにない
新しい応用の道が開ける。
The above description mainly assumes application to a driftwood sheet plasma ion source, but in Figure 3, if 24.27 is kept at a positive potential with respect to the anode (13) and 25.28 is given a higher positive potential, electrons will be generated. can be accelerated. In this case, the anode side becomes a linear electron source and forms a planar electron beam. On the other hand, the side surface of the sheet plasma becomes a planar electron source, and the accelerated electrons are bent by the magnetic field, forming an electron stream that is focused in the direction perpendicular to the plane of the paper as shown in FIG. Therefore, even low energy (1 to 2 KeV) can be used as a large current of electrons (several amperes or more). This opens the door to new applications not available with conventional electron beams.

最近、酸素イオン源が超伝導の研究等に関連して重要性
を増している。しかしながら安定で大電流、大電流密度
の酸素イオン源はまだ実現していないのが現状である。
Recently, oxygen ion sources have become increasingly important in connection with research on superconductivity. However, at present, a stable oxygen ion source with high current and high current density has not yet been realized.

この発明を利用して、その特に重要な化学的活性気体で
ある酸素(0゜)のイオン源をつくるには、第3図で陽
極側20から02ガスを流し、基本的放電は陰極側から
流すHeガスによって維持すればよい。Heガスの電離
電圧は24 、5Vであり、0゜ガスの12.2Vより
2倍も高く、またHeガスの電離能率は最大1イオン対
/cm前後であり、02ガスの最大10イオン対/cm
に比較して1/10である。即ち、Heガスは同程度の
ガス圧力なら0゜ガスより10〜20倍電離作用が小さ
い。かくして、02ガスの陽極側でのプラズマ密度を、
Heガス(キャリアガスで不活性気体)のプラズマ密度
より著しく高くすることは容易になる。またHeガスの
He+イオンは質量は小さいので02ガスのイオン(O
云O+)と分離することも容易になる。この原理によっ
て、陰極を保護しながら大電流放電を行えば、目的の大
電流、大電流密度酸素イオン源が可能となる。
In order to create an ion source of oxygen (0°), which is a particularly important chemically active gas, by using this invention, as shown in Figure 3, 02 gas is flowed from the anode side 20, and the basic discharge is from the cathode side. It may be maintained by flowing He gas. The ionization voltage of He gas is 24.5V, which is twice as high as the 12.2V of 0° gas, and the ionization efficiency of He gas is around 1 ion pair/cm at maximum, which is about 10 ion pairs/cm at maximum for 02 gas. cm
It is 1/10 compared to . That is, He gas has a 10 to 20 times smaller ionizing effect than 0° gas at the same gas pressure. Thus, the plasma density on the anode side of the 02 gas is
It is easy to make the plasma density significantly higher than that of He gas (carrier gas and inert gas). Also, since He+ ions in He gas have a small mass, ions in 02 gas (O
It also becomes easier to separate it from the yen O+). Based on this principle, if large current discharge is performed while protecting the cathode, the desired large current and large current density oxygen ion source can be achieved.

【図面の簡単な説明】[Brief explanation of drawings]

図面の第1図はスリット形式の中間電極による圧力勾配
型放電シートプラズマ生成装置の構成図であり、第2図
はそのスリット形式中間電極の断面とシートプラズマの
断面の概念図である。また図面の第3図は流木式圧力勾
配型放電シートプラズマ生成装置の構成図であり、第4
図はその放電陽極の断面とシートプラズマの断面の概念
図である。図面において、1は細長い放電陰極、2はス
リット形式中間電極、3は放電陽極、4は基本放電用気
体(陰極側から流す)、5はシートプラズマ(巾方向を
示す)、6は放電電源、7は放電に沿った一様磁場を示
し、8は排気ポンプを示し、9はスリット形式中間電極
(2)の断面を示し、10はスリット形の窓を示し、1
1はシートプラズマ(5)の断面を示す。また、12は
簡単で長寿命の放電陰極(特許出願54−057395
 )、13はスリットを持った放電陽極、14は圧力勾
配型放電の第1中間電極で、円柱プラズマ用のものを転
用しており(中心に0.7cmφで3cm長さ程度の孔
を開けである)、15は圧力勾配型放電の第2中間電極
で、やはり円柱プラズマ用のものを転用しており(中心
に1.5cmφで4 cm長さ程度の孔を開けである)
、16は陰極側から導入する基本放電気体、17は放電
プラズマに沿って一様磁場を発生させるための空芯コイ
ル、18は円柱プラズマをシートプラズマに変形するた
めの一対の永久磁石(簡単で高能率なシートプラズマの
生成性特許出願57−060634)、19は流木式シ
ートプラズマ(紙面に垂直に大きな巾を持つ)、20は
陽極側から導入される付加気体、21は放電電源、22
はシートプラズマの側面の排気ポンプを示し、23はシ
ートプラズマの陽極から流出する気体の排気ポンプを示
し、24はシートプラズマ側面に配置される多孔型で大
面積の引き出し第1電極でイオンビームのときは陽極(
13)に対して負電位にバイアスされ、電子ビームのと
きは正電位にバイアスされる電極、25は大面積の引き
出し第2電極で、イオンビームのときは負、電子ビーム
のときは正の加速電圧が与えられる電極、26は加速さ
れて体積状になるイオンビームまたは電子ビーム(磁場
のため紙面に垂直方向に曲げられる)、27は第4図に
示したような線状のプラズマ源からイオンビームを引き
出すための第1電極で、イオンビームのときは陽極(1
3)に対して負電位、電子ビームのときは正電位にバイ
アスされる電極、28は引き出し第2電極、イオンビー
ムのときは負、電子ビームのときは正の加速電圧が与え
られる電極、29は加速されて面状になるイオンビーム
、30は陽極(13)の断面を示し、31は陽極のスリ
ット、32はシートプラズマの線状の断面を示す。
FIG. 1 of the drawings is a configuration diagram of a pressure gradient type discharge sheet plasma generation device using a slit type intermediate electrode, and FIG. 2 is a conceptual diagram of a cross section of the slit type intermediate electrode and a cross section of the sheet plasma. In addition, Figure 3 of the drawings is a configuration diagram of the driftwood type pressure gradient type discharge sheet plasma generation device, and Figure 4
The figure is a conceptual diagram of the cross section of the discharge anode and the sheet plasma. In the drawing, 1 is an elongated discharge cathode, 2 is a slit-type intermediate electrode, 3 is a discharge anode, 4 is a basic discharge gas (flowing from the cathode side), 5 is a sheet plasma (indicates the width direction), 6 is a discharge power source, 7 indicates the uniform magnetic field along the discharge, 8 indicates the exhaust pump, 9 indicates the cross section of the slit-type intermediate electrode (2), 10 indicates the slit-shaped window, 1
1 shows a cross section of the sheet plasma (5). In addition, 12 is a simple and long-life discharge cathode (patent application 54-057395).
), 13 is a discharge anode with a slit, and 14 is the first intermediate electrode for pressure gradient discharge, which is repurposed from one for cylindrical plasma (a hole with a diameter of 0.7 cm and a length of about 3 cm is drilled in the center). 15 is the second intermediate electrode for pressure gradient discharge, which is also a repurposed one for cylindrical plasma (a hole of 1.5 cm diameter and about 4 cm length is drilled in the center).
, 16 is a basic discharge body introduced from the cathode side, 17 is an air-core coil for generating a uniform magnetic field along the discharge plasma, and 18 is a pair of permanent magnets (simple) for transforming the cylindrical plasma into sheet plasma. Highly efficient sheet plasma generation (patent application 57-060634), 19 is a driftwood type sheet plasma (having a large width perpendicular to the plane of the paper), 20 is an additional gas introduced from the anode side, 21 is a discharge power source, 22
23 indicates an exhaust pump on the side of the sheet plasma, 23 indicates an exhaust pump for gas flowing out from the anode of the sheet plasma, and 24 indicates a porous, large-area extraction first electrode placed on the side of the sheet plasma, which pumps the ion beam. When the anode (
13) is biased to a negative potential when using an electron beam, and biased to a positive potential when using an electron beam; 25 is a large-area extraction second electrode; negative when using an ion beam and positive when using an electron beam; An electrode to which a voltage is applied, 26 an ion beam or an electron beam that is accelerated into a volume (bending perpendicular to the plane of the paper due to the magnetic field), and 27 an ion beam from a linear plasma source as shown in FIG. The first electrode for extracting the beam, and the anode (1) for ion beams.
3), an electrode that is biased to a negative potential and a positive potential when an electron beam is used; 28 is a second extraction electrode; an electrode to which a negative accelerating voltage is applied when an ion beam is used and a positive accelerating voltage is applied when an electron beam is used; 29; 30 shows the cross section of the anode (13), 31 shows the slit of the anode, and 32 shows the linear cross section of the sheet plasma.

Claims (1)

【特許請求の範囲】 圧力勾配型気体放電と簡単で高能率なシートプラズマの
生成法(特許出願57−060634)を利用した線状
または面状の (1)イオン源、(2)電子源、(3)放電の陰極側か
らHeガスを流し、陽極側からO_2ガスを流す酸素イ
オン源。
[Claims] Linear or planar (1) ion source, (2) electron source, using pressure gradient gas discharge and a simple and highly efficient sheet plasma generation method (Patent Application No. 57-060634). (3) An oxygen ion source that flows He gas from the cathode side of the discharge and O_2 gas from the anode side.
JP1085579A 1989-04-04 1989-04-04 Sheet plasma ion and electron source by uramoto method Pending JPH02265150A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1085579A JPH02265150A (en) 1989-04-04 1989-04-04 Sheet plasma ion and electron source by uramoto method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1085579A JPH02265150A (en) 1989-04-04 1989-04-04 Sheet plasma ion and electron source by uramoto method

Publications (1)

Publication Number Publication Date
JPH02265150A true JPH02265150A (en) 1990-10-29

Family

ID=13862724

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1085579A Pending JPH02265150A (en) 1989-04-04 1989-04-04 Sheet plasma ion and electron source by uramoto method

Country Status (1)

Country Link
JP (1) JPH02265150A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021513004A (en) * 2018-02-07 2021-05-20 アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated Deposition device, method of coating flexible substrate, and flexible substrate with coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021513004A (en) * 2018-02-07 2021-05-20 アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated Deposition device, method of coating flexible substrate, and flexible substrate with coating

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