JPH02275256A - Air blower control device of freezer - Google Patents
Air blower control device of freezerInfo
- Publication number
- JPH02275256A JPH02275256A JP9317189A JP9317189A JPH02275256A JP H02275256 A JPH02275256 A JP H02275256A JP 9317189 A JP9317189 A JP 9317189A JP 9317189 A JP9317189 A JP 9317189A JP H02275256 A JPH02275256 A JP H02275256A
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- refrigerator
- blower
- refrigerant
- thermostat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Devices That Are Associated With Refrigeration Equipment (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔発明の目的〕
(産業上の利用分野)
この発明は冷凍ショーケースや冷蔵庫等に用いられる冷
凍機に係り、特に、コンデンサの凝縮圧力制御を行なう
冷凍機の送J!I機制御装置に関す〈従来の技術)
この種の冷凍機は大型冷蔵庫や冷凍ショーケース、冷凍
設備等の主に業務用冷凍機械に用いられ、−船釣には別
置きタイプの室外側ユニットを備えている。[Detailed Description of the Invention] [Object of the Invention] (Industrial Application Field) This invention relates to a refrigerator used in a refrigerator showcase, a refrigerator, etc. ! <Conventional technology regarding I machine control device> This type of refrigerator is mainly used in commercial refrigeration machines such as large refrigerators, refrigerator showcases, and refrigeration equipment. It is equipped with
このスプリット型冷凍磯は、第5図に示すように、室外
側ユニツ1−1内にコンプレッサ2、コンデンナ3およ
び送J!1機4等を収容しており、上記コンデンサ3の
中間部以降の伝熱バイブ5にファンコントローラ用サー
モスタット6が取り付けられる。このサーモスタツ]・
6は冷媒の温度を検出して送風機4の作動を制御し、外
気温に見合った冷媒の凝縮圧力を確保するようになって
いる。As shown in FIG. 5, this split-type refrigerating vessel has a compressor 2, a condenser 3, and a feeder J! in an outdoor unit 1-1. A thermostat 6 for a fan controller is attached to a heat transfer vibrator 5 located after the middle part of the capacitor 3. This thermostat]・
6 detects the temperature of the refrigerant and controls the operation of the blower 4 to ensure the condensation pressure of the refrigerant commensurate with the outside temperature.
(発明が解決しようとする課題)
従来の冷凍機は、コンデンサ3の中間部以降に1つのサ
ーモスタット6を温度センサとして取り付けるだけであ
るから、低外気温時の立ち上がりのように、送J!14
のファンモータ7が停止状態から駆動されると、実際の
冷媒の凝縮温度とす−モスタット6の感熱管で検出され
る温度との間に、熱伝達遅れによる温度差が生じ、この
熱伝達遅れに起因して送風機4の動作時間が遅延する。(Problem to be Solved by the Invention) In the conventional refrigerator, only one thermostat 6 is attached as a temperature sensor after the middle part of the condenser 3, so the transmission J! 14
When the fan motor 7 is driven from a stopped state, a temperature difference occurs between the actual condensation temperature of the refrigerant and the temperature detected by the heat-sensitive tube of the mostat 6 due to a heat transfer delay. Due to this, the operation time of the blower 4 is delayed.
このために、冷媒の凝縮圧力が高圧になり、許容量を上
廻って高圧スイッチが誤動作してしまうおそれがあった
(第6図参照)。For this reason, the condensation pressure of the refrigerant becomes high and exceeds the allowable amount, which may cause the high pressure switch to malfunction (see FIG. 6).
高圧スイッチが誤動作すると、コンプレッサ2の駆動が
停止されるため、冷凍機の機能が損われたり、また、コ
ンプレッサ2が一旦停止すると所定時間の間再起動がで
きなかったり、再起動を手動にてその都度行なわなけれ
ばならず、面倒で冷凍機の信頼性を低下さばる原因とな
っていた。If the high pressure switch malfunctions, the drive of the compressor 2 will be stopped, which may impair the function of the refrigerator.Also, once the compressor 2 has stopped, it may not be possible to restart it for a predetermined period of time, or you may have to restart it manually. This had to be done each time, which was troublesome and caused a decrease in the reliability of the refrigerator.
この点から、コンプレッサ2の入口付近にサーモタット
6の感熱管を設けて熱伝達遅れによる弊害を少なくする
方法が考えられるが、この場合、コンデンサ3の入口部
はモリエル線図上冷媒の過熱ガス域と飽和域の境界に近
く、冷媒の温度−圧力特性上不安定であり、実用上問題
があった。From this point of view, it is conceivable to install a heat-sensitive tube of the thermostat 6 near the inlet of the compressor 2 to reduce the adverse effects caused by the delay in heat transfer. The temperature and pressure characteristics of the refrigerant are unstable, and this poses a practical problem.
また、高圧スイッチ作動によるコンプレッサの駆動停止
を防止する高圧カット防止対策として、−段低い冷媒圧
力値で動作する圧力スイッチを設け、この圧力スイッチ
により送風機のファンモータを作動問罪する方法も考え
られるが、この場合には圧力スイッチのメンテナンス時
に冷媒放出のおそれがあり、送風機の作動制御用として
経済上、環境対策上不適であった。Additionally, as a measure to prevent high-pressure cuts to prevent the compressor from stopping due to high-pressure switch activation, it is possible to install a pressure switch that operates at a -stage lower refrigerant pressure value and use this pressure switch to check the operation of the fan motor of the blower. In this case, there is a risk of refrigerant being released during maintenance of the pressure switch, making it economically and environmentally unsuitable for controlling the operation of a blower.
この発明は、上述した事情を考慮してなされたもので、
過渡期の温度センサの動作遅れによる冷媒の凝縮圧力の
上昇を防止し、圧力スイッチの誤動作を未然にかつ確実
に防止し、信頼性を向上させた冷凍機の送風機制御装置
を提供することを目的とする。This invention was made in consideration of the above-mentioned circumstances,
The purpose of the present invention is to provide a blower control device for a refrigerator that prevents an increase in refrigerant condensation pressure due to a delay in the operation of a temperature sensor during a transient period, prevents malfunction of a pressure switch in advance, and improves reliability. shall be.
(課題を解決するための手段)
この発明に係る冷凍機の送風機制御装置は、上述した従
来技術が有する課題を解決するために、コンプレッサ、
コンデンサおよび送風機等を備えた冷凍機において、前
記コンデンサの入口付近およびその中間部以降の出口側
に冷媒温度検出用の温度センサをそれぞれ設け、上記両
濡度センサの検出温度信号が入力されるal(1m部に
、前記送風機の作動を制御する温度補正手段を備えたも
のである。(Means for Solving the Problems) A blower control device for a refrigerator according to the present invention has the following features:
In a refrigerator equipped with a condenser, a blower, etc., temperature sensors for detecting refrigerant temperature are provided near the inlet of the condenser and on the outlet side after the intermediate part thereof, and temperature signals detected by both of the wetness sensors are inputted. (The 1 m section is equipped with temperature correction means for controlling the operation of the blower.
(作用)
この冷凍機の送風機制御装置は、コンデンサの入口付近
および中間部以降の出口側に冷媒温度検出用の温度セン
サをそれぞれ設け、両温度センサで検出される冷媒温度
を制(社)部に入力させて、その温度差により制御部の
温度補正手段で補正を行ない送風機の作動を制御させた
から、過渡期の温度セン勺の動作遅れを解消あるいは小
さくすることができ、動作遅れによる冷媒の凝縮圧力の
上昇を未然に防止して圧力スイッチの誤動作を防止し、
冷凍機の信頼性を向上させることができる。(Function) This refrigerator blower control device is equipped with temperature sensors for detecting refrigerant temperature near the inlet of the condenser and on the outlet side after the intermediate section, and controls the refrigerant temperature detected by both temperature sensors. Since the operation of the blower is controlled by making corrections using the temperature correction means of the control unit based on the temperature difference, it is possible to eliminate or reduce the operation delay of the temperature sensor during the transition period, and to reduce the refrigerant flow due to the operation delay. Prevents condensation pressure from rising and prevents pressure switch malfunctions.
The reliability of the refrigerator can be improved.
(実施例)
以下、この発明に係る冷凍機の送風機11J tll装
誼の一実施例について添付図面を参照して説明する。(Example) Hereinafter, an example of the arrangement of a blower 11J for a refrigerator according to the present invention will be described with reference to the accompanying drawings.
第1図は、冷蔵庫や冷凍ショーケース、冷蔵設備等に好
適に用いられるスプリット型冷凍機の室外側ユニツ1へ
を示ずものであり、この室外側ユニット10内にコンプ
レッサ11、コンデンサ12および送風様13等が収容
される。上記室外側ユニット10はパックドバルブ14
a、14bを介して冷凍機の室内側に接続され、冷凍サ
イクル15を構成している。Fig. 1 does not show the outdoor unit 1 of a split type refrigerator that is suitably used for refrigerators, freezer showcases, refrigeration equipment, etc. In this outdoor unit 10, a compressor 11, a condenser 12, and an air blower are installed. 13 etc. will be accommodated. The outdoor unit 10 has a packed valve 14
It is connected to the indoor side of the refrigerator via a and 14b, and constitutes a refrigeration cycle 15.
一方、コンデンサ12の入日付近や中間部以降の出口側
の伝熱パイプ16に、冷媒温度検出用温度センサとして
サーモスタット17.18がそれぞれ設けられ、両サー
モスタット17.18はサーミスタ等で構成され、送J
il13のファンモータ19を作動制御する制御部20
に電気的に接続され、この制御部20に両サーモスタッ
ト17゜18の検出温度信号がそれぞれ入力される。制
御部20はマイコン等のCPUで構成され、検出される
温度差から送風機13のファンモータ19の作動を制御
する温度補正手段20aを備えている。On the other hand, thermostats 17 and 18 are respectively provided as temperature sensors for detecting refrigerant temperature on the heat transfer pipe 16 near the entrance of the condenser 12 and on the exit side after the middle part, and both thermostats 17 and 18 are composed of a thermistor or the like, Send J
A control unit 20 that controls the operation of the fan motor 19 of the il 13
The temperature signals detected by both thermostats 17 and 18 are input to the control section 20, respectively. The control section 20 is composed of a CPU such as a microcomputer, and includes a temperature correction means 20a that controls the operation of the fan motor 19 of the blower 13 based on the detected temperature difference.
制御部20の温度補正手段20aは両サーモスタット1
7.18から入力される検出温度信号を比較・演算し、
第2図および第3図に示すように、それらの温度差Δt
が規定値以上のとき、フィンモーター9の駆動制御用リ
レー(図示せず)を動作させるようになっている。この
制御部20の温度補正手段20aの具体的な演算・制御
は、入口側サーモスタット17と出口側サーモスタット
18との温度差Δtが、基準規定値Δt 、例えば10
度以上のとき、第3図に示すように、送J[13のファ
ンコントロール動作値(〕7ンモータON値)を通常時
の設定” tslから設定値ts2(<tsl)に移す
ようになっている。ファンモータ19のOFF値は設定
値tslからts2に移動しでも同じ設定値になるよう
にセットされる。第2図において、破線へは入口側サー
モスタット17の検出温度曲線を、実線Bは出口側ナー
モスタット18の検出温度曲線をそれぞれ示す。また、
符号Pdは冷媒の温度換算圧力曲線である。The temperature correction means 20a of the control unit 20 has both thermostats 1
7. Compare and calculate the detected temperature signal input from 18,
As shown in FIGS. 2 and 3, the temperature difference Δt
When the value is greater than a specified value, a drive control relay (not shown) for the fin motor 9 is operated. The specific calculation and control of the temperature correction means 20a of the control unit 20 is such that the temperature difference Δt between the inlet side thermostat 17 and the outlet side thermostat 18 is a reference specified value Δt, for example, 10
As shown in Fig. 3, when the temperature exceeds the normal setting, the fan control operation value (7 motor ON value) of feed J[13] is moved from the normal setting tsl to the setting value ts2 (<tsl). The OFF value of the fan motor 19 is set so that it remains the same even when moving from the set value tsl to ts2.In Fig. 2, the broken line indicates the detected temperature curve of the inlet side thermostat 17, and the solid line B indicates the detected temperature curve Detection temperature curves of the outlet side nermostat 18 are shown.
The symbol Pd is a temperature-converted pressure curve of the refrigerant.
逆に、入口側サーモタット17と出口側サーモスタット
18との温度差Δtが、他の基準設定値Δt 1例えば
5度以下になると、ファンコント0一ル動作値を設定値
t からtslに戻すようになっている。Conversely, when the temperature difference Δt between the inlet side thermostat 17 and the outlet side thermostat 18 becomes less than another standard set value Δt1, for example, 5 degrees, the fan control operation value is returned from the set value t to tsl. It has become.
また、コンデンサ12に取り付けられるサーモスタッ1
−17および18は第4図に示す取付領域CおよびDに
取り付けれられるのが理想的である。In addition, the thermostat 1 attached to the capacitor 12
-17 and 18 are ideally attached to attachment areas C and D shown in FIG.
第4図は冷凍サイクル15のモリエル線図を示すもので
、実線Eは冷凍機の過負荷運転時(夏S)の冷凍サイク
ルを、鎖線Fは冷凍機の低負荷運転時(冬場)の冷凍サ
イクルをそれぞれ示す。このモリエル線図に示すように
入口側サーモスタット17は飽和ガス線G上から若干飽
和域(湿りガス)側に、出口側サーモスタット18は飽
和液線H上から若干飽和域(湿りガス)側にそれぞれ好
適に取り付けられる。送風機13のファンコントロール
を行なう主制御用サーモスタットは、例えば出口側サー
モスタットである。Fig. 4 shows a Mollier diagram of the refrigeration cycle 15, where the solid line E represents the refrigeration cycle when the refrigerator is operating with an overload (summer S), and the chain line F represents the refrigeration cycle when the refrigerator is operating with a low load (winter). Each cycle is shown below. As shown in this Mollier diagram, the inlet thermostat 17 is located slightly above the saturated gas line G toward the saturated region (wet gas), and the outlet thermostat 18 is located slightly toward the saturated region (wet gas) from above the saturated liquid line H. Can be installed conveniently. The main control thermostat that controls the fan of the blower 13 is, for example, an outlet-side thermostat.
次に、冷ll1機の送風機制御装置の作用を説明する。Next, the operation of the blower control device for the refrigeration machine will be explained.
この送風機制御装置は、制御部20に温度補正手段20
aを備え、この温度補正手段20aにてコンデンサ12
の入口付近の冷媒温度および中間部以降出口側の冷凍温
度を両サーモスタット17゜18によりそれぞれ検出し
、その温度差により、送風1113のファンコントロー
ル動作値t、を補正するようにしたものである。This blower control device includes a temperature correction means 20 in the control section 20.
a, and with this temperature correction means 20a, the capacitor 12
The refrigerant temperature near the inlet and the refrigeration temperature from the intermediate section to the outlet side are detected by both thermostats 17 and 18, respectively, and the fan control operating value t of the air blower 1113 is corrected based on the temperature difference.
この冷凍機は]ンブレッサ11の起動により運転が開始
され、コンプレッサ11にて圧縮された冷媒を冷凍サイ
クル15内へ案内し、循環させている。しかし、冷凍サ
イクル15内を流れる冷媒の温度は、第4図に示すモリ
エル線図上では表現できず、過渡期には起動時や安定期
に較べてコンデンサ12人口部の冷媒温度の急激な上昇
が見られる。コンデンサ12人口部の冷媒は、過渡期に
過熱ガス域になっているため、このときの冷ts温度上
昇は、過渡時における冷媒圧力の飽和4度換算より高い
ものになる。The operation of this refrigerator is started by starting the compressor 11, and the refrigerant compressed by the compressor 11 is guided into the refrigeration cycle 15 and circulated. However, the temperature of the refrigerant flowing in the refrigeration cycle 15 cannot be expressed on the Mollier diagram shown in FIG. can be seen. Since the refrigerant in the capacitor 12 is in the superheated gas region during the transition period, the cold ts temperature rise at this time is higher than the saturation 4 degrees equivalent of the refrigerant pressure during the transition period.
この過渡期には、出口側サーモスタット18が感知する
冷媒温度は、熱容量の関係で温度上昇が遅れる。過渡期
の温度センサであるサーモスタット18の動作遅れによ
る悪影響を防止し、高圧カットを防止するために、制御
部20に温度補正手段20aを備えており、この温度補
正手段20aは、サーモスタット17と18の温度差Δ
tを算出し、この温度差ΔtがあるM準設定値Δt1、
例えば10度以上になると、ファンコントロール動作値
13 (ファンモータON値)を通常の設定&r1t
カラMQ定(UtS2(<t、) に下げ”’C1C
1側音ナーモスタット18の動作遅れ(時間遅れ)を短
くしている。During this transition period, the refrigerant temperature sensed by the outlet side thermostat 18 is delayed in temperature rise due to heat capacity. In order to prevent an adverse effect due to a delay in the operation of the thermostat 18, which is a temperature sensor during a transitional period, and to prevent a high pressure cut, the control unit 20 is equipped with a temperature correction means 20a, and this temperature correction means 20a is provided with a temperature correction means 20a. temperature difference Δ
t is calculated, and this temperature difference Δt is the M semi-set value Δt1,
For example, if the temperature exceeds 10 degrees, set the fan control operation value 13 (fan motor ON value) to the normal setting &r1t
Kara MQ constant (UtS2 (<t,) lowered to "'C1C
The operation delay (time delay) of the first sidetone nermostat 18 is shortened.
冷凍機の運転状態が、過渡期から安定した状態に移ると
、入口側サーモスタット17の検出冷媒温度が凝縮圧力
換算値に近付き、出口側ケーモスタッ]・18も冷媒の
検出温度が追従していくため、両サーモスタット17.
18による検出温度差Δtが小さくなり、この温度差Δ
tが他の基準設定値Δt 、例えば約5度以下のとき、
制御部20の温度補正手段20aにより安全運転状態で
あると推定して、ファンコントロール動作値tS ()
?ンモータON値)を再び設定値ts2からtslに戻
してやる。その際、ファンモータ0FFrf1t。When the operating state of the refrigerator shifts from a transient period to a stable state, the refrigerant temperature detected by the inlet side thermostat 17 approaches the condensing pressure conversion value, and the refrigerant temperature detected by the outlet side thermostat 18 also follows. , both thermostats 17.
The temperature difference Δt detected by 18 becomes smaller, and this temperature difference Δt
When t is less than another reference setting value Δt, for example about 5 degrees,
The temperature correction means 20a of the control unit 20 estimates that it is in a safe operating state, and the fan control operating value tS ()
? (motor ON value) is returned from the set value ts2 to tsl. At that time, the fan motor 0FFrf1t.
は一定であるため、送風機13はファンモーター9が0
N10FFを繰り返すことなく、安定した運転を保証す
ることができ、冷凍機の信頼性を向上させることができ
る。is constant, the blower 13 has a fan motor 9 of 0.
Stable operation can be guaranteed without repeating N10FF, and reliability of the refrigerator can be improved.
なお、この発明の一実施例では、入口側および出口側サ
ーモスタットの熱容aについて格別の考慮は払っていな
いが、入口側サーモスタットの熱容量を小さ(、出口側
サーモスタットの熱容けを大きくして両サーモスタット
の取付位置を互いに接近させ、取付作業性を向上させて
もよい。In one embodiment of the present invention, no particular consideration is given to the heat capacity a of the inlet-side and outlet-side thermostats; The mounting positions of both thermostats may be moved close to each other to improve the mounting workability.
以上に述べたようにこの発明に係る冷凍機の送風機制御
装置おいては、コンデンサの入口付近およびその中間部
以降の出口側に冷媒温度検出用湿度センサをそれぞれ設
け、両温度センサの検出温度信号を制御部に入力させ、
このあり罪部で温度差補正を行なって送風機の作動を制
御する温度補正手段を備えたから、過渡期における温度
センサの動作遅れを吸収することができ、温度センサの
動作遅れを小さくして圧力スイッチの誤動作を防止して
、冷凍機の信頼性を向上させることができる。As described above, in the blower control device for a refrigerator according to the present invention, humidity sensors for detecting refrigerant temperature are provided near the inlet of the condenser and on the outlet side after the intermediate part thereof, and the detected temperature signals of both temperature sensors are input to the control unit,
Since a temperature correction means is provided to correct the temperature difference at this point and control the operation of the blower, it is possible to absorb the operation delay of the temperature sensor during the transition period, and to reduce the operation delay of the temperature sensor, the pressure switch It is possible to prevent malfunctions and improve the reliability of the refrigerator.
第1図はこの発明に係る冷凍機の送1虱機制御fIl装
置の一実施例を示す図、第2図はサーモスタットにより
検出されるコンデンサでの冷媒温度の時間変化を示す図
、第3図は前記送f@閤υ1611装置に備えられる制
御部の温度補正手段のフローチャートを示す図、第4図
は前記冷凍機に組み込まれる冷凍サイクルのモリエル線
図、第5図は従来の冷凍機の室外側ユニットを示す図、
M6図はサーモスタットにより検出される冷媒温度と実
際の冷Is凝縮温度とを比較して示す図である。
10・・・室外側ユニツI・、11・・・コンプレッサ
、12・・・コンデンサ、13・・・送風□、15・・
・冷凍サイクル、16・・・伝熱パイプ、17.18・
・・サーモスタット(温度センサ)、20・・・制御部
、20a・・・温度補正手段。
帽部 ?
第
図
(エンタルピ)必
第
図
吟
間
第
図FIG. 1 is a diagram showing an embodiment of a refrigerating machine feed unit control fll device according to the present invention, FIG. 2 is a diagram showing temporal changes in refrigerant temperature in a condenser detected by a thermostat, and FIG. 4 is a Mollier diagram of the refrigeration cycle incorporated in the refrigerator, and FIG. 5 is a diagram showing the chamber of a conventional refrigerator. Diagram showing the outer unit,
Diagram M6 is a diagram showing a comparison between the refrigerant temperature detected by the thermostat and the actual cold Is condensation temperature. 10... Outdoor unit I, 11... Compressor, 12... Condenser, 13... Air blower □, 15...
・Refrigerating cycle, 16...Heat transfer pipe, 17.18・
...Thermostat (temperature sensor), 20...Control unit, 20a...Temperature correction means. Hat part? Diagram (enthalpy) Necessary diagram Ginma diagram
Claims (1)
機において、前記コンデンサの入口付近およびその中間
部以降の出口側に冷媒温度検出用の温度センサをそれぞ
れ設け、上記両温度センサの検出温度信号が入力される
制御部に、前記送風機の作動を制御する温度補正手段を
備えたことを特徴とする冷凍機の送風機制御装置。In a refrigerator equipped with a compressor, a condenser, a blower, etc., temperature sensors for detecting the refrigerant temperature are provided near the inlet of the condenser and on the outlet side after the intermediate part thereof, and temperature signals detected by the two temperature sensors are inputted. A blower control device for a refrigerator, characterized in that a control section includes a temperature correction means for controlling operation of the blower.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9317189A JPH02275256A (en) | 1989-04-14 | 1989-04-14 | Air blower control device of freezer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9317189A JPH02275256A (en) | 1989-04-14 | 1989-04-14 | Air blower control device of freezer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02275256A true JPH02275256A (en) | 1990-11-09 |
Family
ID=14075124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9317189A Pending JPH02275256A (en) | 1989-04-14 | 1989-04-14 | Air blower control device of freezer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02275256A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4220503A1 (en) * | 1992-06-23 | 1994-01-05 | Licentia Gmbh | Refrigerator or freezer with temp.-responsive control of fan - benefits from energy-saving with fan switched-off below temp. threshold, and run at low speed during compression of refrigerant |
| US5459200A (en) * | 1994-10-11 | 1995-10-17 | Shell Oil Company | Polyurethane coatings and adhesives containing monohydroxylated diene polymers and epoxidized derivatives thereof |
| US5461112A (en) * | 1994-10-11 | 1995-10-24 | Shell Oil Company | Epoxidized monohydroxylated block polymer, epoxy resin, curing agent and epoxy diluent |
| US5500481A (en) * | 1995-05-17 | 1996-03-19 | Shell Oil Company | Compositions containing epoxidized monohydroxylated diene polymers, amino resins, and reactive reinforcement agents |
| US5721316A (en) * | 1995-07-12 | 1998-02-24 | Shell Oil Company | Process for incorporation of expoxidized polydienes into epoxy resins |
| US5750627A (en) * | 1995-11-16 | 1998-05-12 | Shell Oil Company | Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them |
| US5922467A (en) * | 1996-10-15 | 1999-07-13 | Shell Oil Company | Method for coating crosslinkable epoxidized monohydroxylated diene polymer coating compositions on primed substrates |
| US6043316A (en) * | 1996-11-13 | 2000-03-28 | Shell Oil Company | Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them |
| US6525142B1 (en) | 1994-10-11 | 2003-02-25 | Kraton Polymers U.S. Llc | Monohydroxylated diene polymers and epoxidized derivatives thereof |
-
1989
- 1989-04-14 JP JP9317189A patent/JPH02275256A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4220503A1 (en) * | 1992-06-23 | 1994-01-05 | Licentia Gmbh | Refrigerator or freezer with temp.-responsive control of fan - benefits from energy-saving with fan switched-off below temp. threshold, and run at low speed during compression of refrigerant |
| DE4220503C2 (en) * | 1992-06-23 | 2001-03-15 | Aeg Hausgeraete Gmbh | Refrigerator and / or freezer |
| US5459200A (en) * | 1994-10-11 | 1995-10-17 | Shell Oil Company | Polyurethane coatings and adhesives containing monohydroxylated diene polymers and epoxidized derivatives thereof |
| US5461112A (en) * | 1994-10-11 | 1995-10-24 | Shell Oil Company | Epoxidized monohydroxylated block polymer, epoxy resin, curing agent and epoxy diluent |
| US6525142B1 (en) | 1994-10-11 | 2003-02-25 | Kraton Polymers U.S. Llc | Monohydroxylated diene polymers and epoxidized derivatives thereof |
| US5500481A (en) * | 1995-05-17 | 1996-03-19 | Shell Oil Company | Compositions containing epoxidized monohydroxylated diene polymers, amino resins, and reactive reinforcement agents |
| US5721316A (en) * | 1995-07-12 | 1998-02-24 | Shell Oil Company | Process for incorporation of expoxidized polydienes into epoxy resins |
| US5750627A (en) * | 1995-11-16 | 1998-05-12 | Shell Oil Company | Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them |
| US5916941A (en) * | 1995-11-16 | 1999-06-29 | Shell Oil Company | Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them |
| US5962077A (en) * | 1995-11-16 | 1999-10-05 | Shell Oil Company | Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them |
| US5922467A (en) * | 1996-10-15 | 1999-07-13 | Shell Oil Company | Method for coating crosslinkable epoxidized monohydroxylated diene polymer coating compositions on primed substrates |
| US6043316A (en) * | 1996-11-13 | 2000-03-28 | Shell Oil Company | Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them |
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