JPH02284757A - Mold for lead alloy - Google Patents
Mold for lead alloyInfo
- Publication number
- JPH02284757A JPH02284757A JP1106436A JP10643689A JPH02284757A JP H02284757 A JPH02284757 A JP H02284757A JP 1106436 A JP1106436 A JP 1106436A JP 10643689 A JP10643689 A JP 10643689A JP H02284757 A JPH02284757 A JP H02284757A
- Authority
- JP
- Japan
- Prior art keywords
- mold
- ceramic
- ptfe
- lead alloy
- temp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000978 Pb alloy Inorganic materials 0.000 title claims abstract description 10
- 239000000919 ceramic Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract description 9
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract description 9
- 229920006015 heat resistant resin Polymers 0.000 abstract description 5
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 3
- 230000035699 permeability Effects 0.000 abstract description 3
- 230000000630 rising effect Effects 0.000 abstract 1
- 238000005336 cracking Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- -1 Polytetrafluoroethylene Polymers 0.000 description 1
- 229910001245 Sb alloy Inorganic materials 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 239000002140 antimony alloy Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000009732 tufting Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/82—Multi-step processes for manufacturing carriers for lead-acid accumulators
- H01M4/84—Multi-step processes for manufacturing carriers for lead-acid accumulators involving casting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、鉛電池用格子体または芯金の鋳造に用いる鋳
型の改良に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to improvements in molds used for casting grids or cores for lead batteries.
従来技術とその問題点
従来、鉛合金の１造はコｙり粉末を主成分としたいわゆ
る滑剤を鋳鉄製鋳型の表面に吹付け、塗布し、型変形の
修正、断熱、離型等の機能を持たせていた。しかるに、
この滑剤は溶湯鉛の熱によって徐々に劣化が進み、又鉛
合金の押圧力によって厚さが薄くなって良品を長期にわ
たって生産することができない。普通アンチモン合金の
場合、２０００〜４０００ Ｖ ＩＩ −／ ）毎に吹
付は直しを行う必要がある。又、途中タフチアツブと称
して、部分的な補修の吹付けを行うこともあり、本工程
を無人化することは、極めて困難であり、常時、鋳造機
のそばｌｃ型製品品質確認のための要員が必要である。Conventional technology and its problems Traditionally, when making lead alloys, a so-called lubricant mainly composed of iron powder was sprayed onto the surface of a cast iron mold to provide functions such as correcting mold deformation, heat insulation, and mold release. I was allowed to have it. However,
This lubricant gradually deteriorates due to the heat of the molten lead, and its thickness decreases due to the pressing force of the lead alloy, making it impossible to produce good products over a long period of time. In the case of normal antimony alloys, the spraying needs to be corrected every 2,000 to 4,000 V II -/). In addition, it is extremely difficult to automate this process as partial repairs are sometimes sprayed during the process, called tufting. is necessary.
これを解決するために、各種のコーティングや鋳鉄に代
わる材料の提案がなされている。To solve this problem, proposals have been made for various coatings and materials to replace cast iron.
その一つに通気性の金属材やセブミックス材を用いると
いうものがある。One such method is to use breathable metal materials or Sebumix materials.
しかしながら、通気性の金属材やセラミックス材同士の
構成の鋳型は前者の場合、型温度かや＼高く、ソリを発
生し易い。又温度調節に高精度が要求されるという欠点
がある。後者の場合、立上りの加熱時に、熱応力が生じ
ワレを引き起すという欠点がある。However, in the case of a mold made of breathable metal or ceramic materials, the mold temperature is rather high and warpage is likely to occur. Another drawback is that high precision is required for temperature control. In the latter case, there is a drawback that thermal stress is generated at the time of initial heating, causing cracking.
発明の目的
本発明は上記従来の問題点に鑑みなされたものであり、
ソリの発生しない、温度１１節の容易な、ワレの発生し
にくい鉛合金用鋳型を提供することを目的とするもので
ある。Purpose of the Invention The present invention has been made in view of the above-mentioned conventional problems.
The object of the present invention is to provide a mold for lead alloy that does not cause warpage, can easily be heated to 11 degrees, and is less likely to crack.
発明の構成
本発明は上記目的を速成するべく、鋳型の片面が通気性
を有するセラミックス、もう一方の面は無孔性の樹脂材
から成ることを特徴とする鉛合金用鋳型である。DESCRIPTION OF THE INVENTION In order to achieve the above object quickly, the present invention provides a mold for lead alloy, characterized in that one side of the mold is made of air-permeable ceramic and the other side is made of non-porous resin material.
実施例 以下、本発明の一実施例について図により説明する。Example Hereinafter, one embodiment of the present invention will be described with reference to the drawings.
第１図は本発明の鉛合金用鋳型の要部断面図であり、こ
−で、１は通気性セラミックス、２は無孔性耐熱樹脂相
、６はあて板、４はヒーター、５は彫刻面である。FIG. 1 is a sectional view of the main parts of the lead alloy mold of the present invention, in which 1 is a breathable ceramic, 2 is a non-porous heat-resistant resin phase, 6 is a cover plate, 4 is a heater, and 5 is a sculpture. It is a surface.
通気性を有する３５０ Ｘ ４００ Ｘ ３０ ’ｍの
セツミックｙ” ＩＣｓ鉛電池用格子体を彫刻した。セ
ラミックスとしてＳｉ３Ｎ４ 、ム１１０５． ＺｒＯ
２を用いた。A 350 x 400 x 30' m grid with air permeability was engraved for ICs lead battery.The ceramics were Si3N4, Mu1105.ZrO.
2 was used.
これらセラミックスは、最大孔径１０声飼の通気孔を有
する。格子体は巾１５０Ｘ高さ１２０×厚さ１．８−で
ある。無孔性耐熱樹脂材として、ポリ四７フ化エチレン
樹脂（ＦＩＦＥ）を用いた。These ceramics have vent holes with a maximum pore size of 10 holes. The grid body has a width of 150×height of 120×thickness of 1.8 mm. Polytetrafluoroethylene resin (FIFE) was used as the nonporous heat-resistant resin material.
鋳型が従来のセラミックス−セラミックスの場合、本発
明のセラミックスとポリ四フブ化エチレン四脂を用いた
場合について、型開閉装置に取付けて、力〃シウム合金
の湯温５００℃で鋳込み試験を行い、型温度を測定した
。この結果を第１表に示した。When the mold is conventional ceramics-ceramics, and when the ceramic of the present invention and polytetrafubuted ethylene tetrapolymer are used, the mold is attached to a mold opening/closing device, and a casting test is conducted at a lithium alloy hot water temperature of 500 ° C. The mold temperature was measured. The results are shown in Table 1.
セラミックスとＰＴＦＥの組合せは、ＰＴＦＥが適度の
弾性を有するので、型閉鎖時にセラミックス材によく密
着し、パリを生じない。（ソリの発生がないため。）又
、第１表の如く本発明は温度上昇が小さいので温度調節
が容易であり、ワレの発生もない。In the combination of ceramics and PTFE, since PTFE has appropriate elasticity, it adheres well to the ceramic material when the mold is closed and does not cause flaking. (Because no warping occurs.) Furthermore, as shown in Table 1, the temperature rise in the present invention is small, so temperature control is easy and no cracking occurs.
尚、樹脂側の溶湯と直接に接する部分は〜徐々に炭化し
て脱落するので、ａ） 表面をテトフェブチ（Ｎａを
液体ＮＨ３に溶かした障）シて、無機性＝−ディングを
施す。In addition, since the part of the resin side that is in direct contact with the molten metal gradually carbonizes and falls off, a) the surface is treated with tetofebutyment (a barrier made by dissolving Na in liquid NH3) and an inorganic coating is applied.
ｂ）彫刻なせず、ある程度劣化した時点で差し替えるか
、又は削り落しながら使う。ＰＴＦＥの加工費は安価で
あるので消耗品と考えても問題はない。b) It cannot be engraved, and when it has deteriorated to a certain extent, it must be replaced or scraped off before use. Since the processing cost of PTFE is low, there is no problem in considering it as a consumable item.
発明の効果
上述した如く、本発明はソリの発生しない、温度調節の
容易な、ワレの発生しにくい鉛合金用鋳型を提供するこ
とができるので、その工業的価値は極め工大である。Effects of the Invention As described above, the present invention can provide a lead alloy mold that does not cause warpage, can easily control temperature, and is less prone to cracking, and therefore its industrial value is extremely high.
第１図は本発明の一実施例である鉛合金用鋳型の要部断
面図である。
１・・・通気性セラミックス
２・・・無孔性耐熱樹脂材
３・・・あて板
４・・・ヒーター
５・・・彫刻面
第１図FIG. 1 is a sectional view of a main part of a lead alloy mold according to an embodiment of the present invention. 1... Breathable ceramics 2... Non-porous heat-resistant resin material 3... Cover plate 4... Heater 5... Engraved surface Fig. 1
Claims (1)
面は無孔性の樹脂材から成ることを特徴とする鉛合金用
鋳型。A lead alloy mold characterized in that one side of the mold is made of air-permeable ceramic and the other side is made of non-porous resin material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1106436A JPH02284757A (en) | 1989-04-25 | 1989-04-25 | Mold for lead alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1106436A JPH02284757A (en) | 1989-04-25 | 1989-04-25 | Mold for lead alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02284757A true JPH02284757A (en) | 1990-11-22 |
Family
ID=14433599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1106436A Pending JPH02284757A (en) | 1989-04-25 | 1989-04-25 | Mold for lead alloy |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02284757A (en) |
-
1989
- 1989-04-25 JP JP1106436A patent/JPH02284757A/en active Pending
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