JPH0229467A - Film finishing agent - Google Patents

Film finishing agent

Info

Publication number
JPH0229467A
JPH0229467A JP17984288A JP17984288A JPH0229467A JP H0229467 A JPH0229467 A JP H0229467A JP 17984288 A JP17984288 A JP 17984288A JP 17984288 A JP17984288 A JP 17984288A JP H0229467 A JPH0229467 A JP H0229467A
Authority
JP
Japan
Prior art keywords
agent
weight
film
plasticizer
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP17984288A
Other languages
Japanese (ja)
Other versions
JP2883336B2 (en
Inventor
Boetsuku Harii
ハリー ボエック
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHINPO HACHIROU
Original Assignee
SHINPO HACHIROU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHINPO HACHIROU filed Critical SHINPO HACHIROU
Priority to JP63179842A priority Critical patent/JP2883336B2/en
Publication of JPH0229467A publication Critical patent/JPH0229467A/en
Application granted granted Critical
Publication of JP2883336B2 publication Critical patent/JP2883336B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE:To obtain the title agent which can impart extensibility to a coating film and can prevent a coating film from cracking after coating by mixing an acrylic resin with an antifoamer, a flowable wetting component, a moistureproofing agent, a plasticizer, a mildewproofing agent, a pigment dispersing agent, etc. CONSTITUTION:68-88pts.wt. acrylic resin (A) (a mixture of two aqueous acrylic resins) is mixed with 1.5-0.20pt.wt. antifoamer (B), 1-0.22pt.wt. flowable wetting component (C), 1-0.033pt.wt. moistureproofing agent (D), 4-0.50pt.wt. water (E), 3-0.62pt.wt. plasticizer (F), 1-0.10pt.wt. mildewproofing agent (G), 1-0.15pt.wt. pigment dispersing agent (H), an inorganic material (I), for example, calcium carbonate, kaolin or talc, in an amount of 8-1.45pts.wt. for titanium oxide or 9-16pts.wt. for materials other than that and a drying integration component (J) comprising 2-0.5pt.wt. hydrocarbon and 3-0.25pt.wt. ethylene glycol monobutyl ether to obtain a film finishing agent desirable for finishing a waterproofing film.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は塗膜仕上部にかかる。詳細には、例えば、コ
ンクリート、アスベスト、鉄板、幌等の屋根、屋上、レ
ンガ、ブロック、フィブロセメント等の壁、中高層建築
物、工場、住宅等の防水、小さな割れ目、引っ掻き傷、
小さな穴の補修、ファイバーグラス、綿布、その他の布
地併用による大きな割れ目、穴の補修、外壁のコーチン
グ、屋根の継ぎ目、雨樋、その他の配管の継ぎ目のシー
リング、屋根の補修、窓枠のシーリング、ヘーベルノコ
インド、エキスパンション目地のコーキングけとして、
浴室壁、天井仕上げ、厨房壁面仕上げ等に使用可能な防
水被膜剤等の、上塗りに適するとともに、それ以外の木
材、鋼材、コンクリート、石材等にブライマーを介しで
ある′いはプライマーなしで、堅牢で柔軟性のある着色
被膜を有する、■液性のアクリル系、中厚被膜の塗膜仕
上材に係る。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to coating film finishing. In detail, for example, roofs made of concrete, asbestos, iron plates, canopies, rooftops, walls made of bricks, blocks, fibrocement, etc., waterproofing of medium-to-high-rise buildings, factories, houses, etc., small cracks, scratches, etc.
Repairing small holes, repairing large cracks and holes using fiberglass, cotton cloth, and other fabrics, coating exterior walls, sealing roof joints, gutters, and other plumbing joints, roof repair, sealing window frames, Heberno Coindo, as caulking for expansion joints.
Suitable for topcoating, such as waterproof coating agents that can be used for bathroom walls, ceiling finishes, kitchen wall finishes, etc., and is durable and can be applied to other materials such as wood, steel, concrete, stone, etc. with a primer or without a primer. It relates to a liquid acrylic-based, medium-thick film finishing material that has a flexible colored film.

(従来の技術) 従来所謂エマルジョン塗料は各種のものが知られている
。例えばビニル系、アクリル系、ビニルアクリル共重合
系ラテックスを塗膜の主要素とし数ミクロン以下の樹脂
粒子を水に分散させた塗料等である。
(Prior Art) Various types of so-called emulsion paints have been known. For example, there are paints in which vinyl, acrylic, or vinyl-acrylic copolymer latex is the main component of the coating film, and resin particles of several microns or less are dispersed in water.

(発明が解決しようとする課題) しかしながら、従来の防水塗料、あるいは塗膜仕上材に
よる防水塗膜では伸縮性に欠けるため、塗装後に被塗装
面である建築物、屋根、壁への塗装後に割れを生ずると
いう課題を有した。
(Problem to be solved by the invention) However, since conventional waterproof paints or waterproof coatings made from coating film finishing materials lack elasticity, cracks may occur after coating on buildings, roofs, and walls. The problem was that it caused problems.

(課題を解決する為の手段) 本発明者は、このような実状に鑑みて、被膜に伸縮性を
与えろことで、塗装された被塗装物への塗装後発生する
割れを生じない優れた塗膜仕上材を提供することを目的
とする。
(Means for Solving the Problems) In view of the above-mentioned circumstances, the present inventor has developed an excellent coating that does not cause cracks that occur after coating the coated object by giving the coating elasticity. The purpose is to provide membrane finishing materials.

すなわち、この発明は、アクリル系樹脂と、泡消剤と、
流動加湿成分と、防湿剤と、水と、可塑剤と、防黴剤と
、顔料分散剤と、無機材と、乾燥合体成分からなる。ア
クリル系樹脂としては、アクリル単独重合物、アクリル
酸エステルとメタクリル酸メチルを主体とした共重合物
、ビニルエステル等と共重合させたもの、その曲の共重
合物知られているが、水性のアクリル系樹脂を2種類混
合してえる。
That is, this invention provides an acrylic resin, a defoaming agent,
It consists of a fluid humidifying component, a moisture-proofing agent, water, a plasticizer, a fungicide, a pigment dispersant, an inorganic material, and a dry combination component. As acrylic resins, acrylic homopolymers, copolymers mainly composed of acrylic esters and methyl methacrylate, copolymers with vinyl esters, etc., and copolymers of the song are known, but water-based Made by mixing two types of acrylic resin.

アクリル系樹脂は、68〜88重量部含有させる。The acrylic resin is contained in an amount of 68 to 88 parts by weight.

消泡剤は、1.5〜0,20重量部含有させる。流動湿
潤成分(Flow and wetting agen
t)は、1〜0,22重量部含有させる。防湿剤(In
 canpreserver)は1〜0033重量部含
有させる。水は4〜0,50重量部含有させる。可塑剤
は、3〜0.62重量部含有さ仕る。防黴剤は、1〜0
.100重量部含有させる。顔料分散剤は、1〜0.1
5重M部含有させる。無機材としては、チタニウム、炭
酸カルシウム、か焼アルミナ、マイカ(water g
round maica) 、カオリン(チャイナクレ
イ)、ドロマイト、タルク、酸化亜鉛、を加え、チタニ
ウムについては8〜1.45重量部、それ以外について
はそれぞれ9〜16重里部加える。乾燥合体成分(Dr
ying andCoalesing Agent)と
しては、炭化水素を、2〜05重量部、エヂレングリコ
ールモノブヂルエーテルを3〜0.25重量部加える。
The antifoaming agent is contained in an amount of 1.5 to 0.20 parts by weight. Flow and wetting agent
t) is contained in an amount of 1 to 0.22 parts by weight. Moisture-proofing agent (In
campreserver) is contained in an amount of 1 to 0,033 parts by weight. Water is contained in an amount of 4 to 0.50 parts by weight. The plasticizer is contained in an amount of 3 to 0.62 parts by weight. Antifungal agent is 1 to 0
.. Contains 100 parts by weight. The pigment dispersant is 1 to 0.1
Contains 5 M parts. Inorganic materials include titanium, calcium carbonate, calcined alumina, mica (water g
round maica), kaolin (China clay), dolomite, talc, and zinc oxide, and 8 to 1.45 parts by weight of titanium and 9 to 16 parts by weight of each other. Dry combined component (Dr.
2 to 0.5 parts by weight of hydrocarbon and 3 to 0.25 parts by weight of ethylene glycol monobutyl ether are added as a tying and coalesing agent.

このようにして得られた塗膜仕上材をプライマーを塗布
した上からあるいは、せずにその上から塗布する。即ち
、石化したエマルジョンペイント、清浄な新いコンクリ
ート製品、石材、コンクリート、外装用木材、鋼材、フ
レキ板(新しいもの)に塗布する場合は、それぞれプラ
イマーを塗布しておこなう。内装用木材、および次の防
水被膜剤の塗布面には、特にプライマーは不要である。
The film finish thus obtained is applied with or without primer. That is, when applying to petrified emulsion paint, clean new concrete products, stone, concrete, exterior wood, steel, and flexible boards (new), apply a primer to each. No primer is required for interior wood and the surface to which the next waterproof coating will be applied.

すなわち、本発明者は先に、アクリル樹脂系エマルジョ
ンと、エマルジョン中に可塑剤と、顔料分散剤と、消泡
剤と、無機微粉末とを分散させてなる防水被膜剤につい
て提案したが、本発明の塗膜仕上材は、この防水被膜剤
によって塗装された上から塗膜仕上材として塗布するに
適するものである。既に提案した、防水被膜剤を更に説
明すると、アクリル樹脂系エマルジョンとしては、アク
リル単独重合物、アクリル酸エステルとメタクリル酸メ
チルを主体とした共重合物、ビニルエステル等と共重合
させたもの、その曲の共重合物でもよく、スチレンモノ
マーアクリルエマルジョン(A 5tyrene Mo
nomer Acrylic EmulusOn)、あ
るいは非スチレン化アクリルエマルンヨン(Unsty
renated Acrylic Emulusion
 ofthe Aqueous Dispersion
 Type)を、45〜85重量%含有することか望ま
しい。消泡剤は、0゜2〜1.0重ffi%、顔料分散
剤(Pigment Dispersing agen
t)は0.1〜0,4含有することが望ましい。可塑剤
としてはアクリル系樹脂に使用される公知の可塑剤が使
用可能である。可塑剤は1.0〜25重量%含有する。
That is, the present inventor previously proposed an acrylic resin emulsion and a waterproof coating agent in which a plasticizer, a pigment dispersant, an antifoaming agent, and an inorganic fine powder are dispersed in the emulsion. The paint film finishing material of the invention is suitable for being applied as a paint film finishing material over a surface coated with this waterproof film agent. To further explain the waterproof coating agents already proposed, acrylic resin emulsions include acrylic homopolymers, copolymers mainly composed of acrylic esters and methyl methacrylate, copolymers with vinyl esters, etc. A 5tyrene monomer acrylic emulsion (A5tyrene Mo
Nomer Acrylic EmulusOn) or non-styrenated acrylic emulsion (Unsty
Renated Acrylic Emulsion
of the Aqueous Dispersion
It is desirable to contain 45 to 85% by weight of The antifoaming agent is 0°2 to 1.0% by weight, pigment dispersing agent (pigment dispersing agent)
t) is desirably contained in the range of 0.1 to 0.4. As the plasticizer, known plasticizers used for acrylic resins can be used. The plasticizer is contained in an amount of 1.0 to 25% by weight.

防腐剤は被塗装面により要否を選択し、0〜2.00重
1%含存する。無機微粉末は3〜25ミクロンの粒状か
らなり、18〜288〜28重量%含有機微粉末として
は、炭酸カルシウム(whiting)、あるいは滑石
パウダー、ガラスピーズ、ソリ力フラワー等が望ましい
。それ以外に、二酸化チタン(Titanium Di
oxide(Dray) RutileType)を0
〜12重重%、あるいは既分散顔料(Pred+5pe
rsed pigment in paste or 
1iquid form)0〜24重量%、ホワイトス
ピリット0.8〜26、水0〜1重量%を含有させろ。
The necessity of the preservative is selected depending on the surface to be coated, and the preservative is contained in an amount of 0 to 2.00% by weight. The inorganic fine powder has a granular shape of 3 to 25 microns, and the fine powder containing 18 to 288 to 28% by weight is preferably calcium carbonate (whiting), talcum powder, glass peas, sori flour, or the like. In addition, titanium dioxide (Titanium Di
oxide(Dray)RutileType) to 0
~12% by weight, or pre-dispersed pigment (Pred+5pe
rsed pigment in paste or
1quid form) 0 to 24% by weight, white spirit 0.8 to 26%, and water 0 to 1% by weight.

コンクリート、アスベスト、鉄板、幌等の屋根、屋−に
、レンガ、ブロック、フィブロセメント等の壁、中高層
建築物、工場、住宅等、小さな割れ目、引っ掻き傷、小
さな穴、ファイバーグラス、柿布、その他の布地併用に
よる大きな割れ目、穴の補修箇所、外壁のコーティング
および仕上剤、屋根の継ぎ目、雨樋、その他の配管の継
ぎ目のシーリング、屋根の補修箇所、窓枠のシーリング
、ヘーベルジョイント、エギスパンノヨン目地のコーキ
ング必要箇所、浴室壁、天井仕上げ、厨房壁面等の施工
箇所の接着性を良くするため、ごみ、油性分、はこり、
等を洗い流す。施工面自体は多少の濡れ、湿気が有って
も良い。
Roofs and buildings made of concrete, asbestos, iron plates, canopies, etc., walls of bricks, blocks, fibrocement, etc., medium and high-rise buildings, factories, houses, etc., small cracks, scratches, small holes, fiberglass, persimmon cloth, etc. Repairs of large cracks and holes, exterior wall coatings and finishing agents, sealing of roof joints, rain gutters, and other piping joints, roof repairs, window frame sealing, Hebel joints, Egispan Noyon joints. In order to improve the adhesion of caulking required areas, bathroom walls, ceiling finishes, kitchen walls, etc., remove dirt, oil, and flakes.
Wash away etc. The construction surface itself may be slightly wet or damp.

ついて、被塗装面にプライマー作業を行う。Then, apply a primer to the surface to be painted.

即ち、金属面にはメタルプライマーを、コンクリート/
フィブロ(繊維セメント)面には、ソーラー/プライマ
ー混入の水あるいは溶剤を、既塗装の施工面への作業に
は、バインダー(結合剤)/シーラーを、開被覆面への
作業には水性バインダー/シーラーを、アスファルト仕
上げ面への作業には水性バインダー/ソーラーをあらか
じめ塗布する。
In other words, metal primer is applied to metal surfaces, and concrete/
For fibro (fiber cement) surfaces, use solar/primer-containing water or solvent; for previously painted surfaces, use a binder/sealer; for open coated surfaces, use a water-based binder/sealer. Pre-apply sealer or water-based binder/solar when working on asphalt surfaces.

施工面にはブラシ、ローラー、スプレー等で防水被膜剤
を塗布する。膜厚は乾燥時に1〜1.2mm程度が望ま
しい。割れ目、継ぎ目に塗るときは、施工面にまず防水
被膜剤を塗り、−回目の塗布が乾く前にファイバーグラ
ス、綿布、寒冷紗、その他の布地でパッチングし、−回
目の塗布の粘着状態がなくなったところで、二回目の塗
布を行う。
Apply a waterproof coating to the construction surface using a brush, roller, spray, etc. The film thickness is desirably about 1 to 1.2 mm when dried. When applying to cracks and seams, first apply a waterproof coating to the surface to be applied, then patch with fiberglass, cotton cloth, cheesecloth, or other fabric before the second application dries, and - the adhesive state of the second application is gone. By the way, do the second application.

実施例1 スチレンモノマーアクリルエマルジョン65重量 % 消泡剤           0.6重量 %顔料分散
剤         0.25重量%可塑剤     
      1.75重重%防腐剤         
  1. 、 O0重里%炭酸カルシウム粉末    
  23重量%二酸化チタン         6重量
 %ホワイトスピリッツ     1.7重量 %水 
                    0.7重量
  %実施例2 スチレンモノマーアクリルエマルジョン65重量 % 消泡剤           0.6重量顔料分散剤 
        0.25重重可塑剤        
   175重貴防腐剤           1.0
0重虫滑石パウダー         23重M二酸化
チタン         6重虫ポワイトスピリソツ 
    1.7重量水               
      0.7重量実施例3 スチレンモノマーアクリルエマルジョン65重量 消泡剤           0.6重量顔料分散剤 
        0.25重重可塑剤        
   1.75重量防腐剤           1.
00重量ガラスヒーンズ        23重M二酸
化チタン         6重量ホワイトスピリッツ
     17重量水               
      07重量実施例4 スチレンモノマーアクリルエマルジョン65重重 % 消泡剤            0.6重量%顔料分散
剤          0,25重量%可塑剤    
        175重量%防腐剤        
    1.00重量%ンリカフラワー       
  23重量%二酸化チタン           6
重量%ホワイトスピリッツ      17重量%水 
                      0.7
重−量%実施例1〜4に示される防水被膜剤を、辺が3
0cmの正方形のスレート仮に各々塗布した試験版を1
20℃雰囲気中に放置し、板をそらせた後急冷するテス
トを10回繰り返した。
Example 1 Styrene monomer acrylic emulsion 65% by weight Defoamer 0.6% by weight Pigment dispersant 0.25% by weight Plasticizer
1.75wt% preservative
1. , O0 Shigesato% calcium carbonate powder
23% by weight Titanium dioxide 6% by weight White spirits 1.7% by weight Water
0.7% by weight Example 2 Styrene monomer acrylic emulsion 65% by weight Defoamer 0.6% by weight Pigment dispersant
0.25 heavy plasticizer
175 Preservatives 1.0
0-layer talc powder 23-layer M titanium dioxide 6-layer talcum powder
1.7 weight water
0.7 weight Example 3 Styrene monomer acrylic emulsion 65 weight Antifoam agent 0.6 weight Pigment dispersant
0.25 heavy plasticizer
1.75 weight preservative 1.
00 weight glass heens 23 weight M titanium dioxide 6 weight white spirits 17 weight water
07 Weight Example 4 Styrene monomer acrylic emulsion 65% by weight Antifoaming agent 0.6% by weight Pigment dispersant 0.25% by weight Plasticizer
175% preservatives by weight
1.00% by weight Nrika flower
23% by weight titanium dioxide 6
Weight% White Spirits 17% Water
0.7
% by weight The waterproof coating agents shown in Examples 1 to 4 were
A test plate of 0cm square slate, each coated with
A test was repeated 10 times in which the board was left in an atmosphere at 20°C, the board was deflected, and then rapidly cooled.

同様に作成した試験版を一30℃迄急冷し常温まで昇温
する試験を10回繰り返した。
A test plate prepared in the same manner was rapidly cooled to -30°C and then heated to room temperature, which was repeated 10 times.

実施例1.2.3.4、ともいずれの試験によっても塗
膜に亀裂や剥離は生ずることなく、異常は認められなか
った。また、JIS6909による試験によって6耐候
性等は充分に満たされた。
In both Examples 1, 2, 3, and 4, no cracks or peeling occurred in the coating film, and no abnormality was observed. In addition, according to the test according to JIS6909, 6 weather resistance etc. were fully satisfied.

本発明にかかる塗膜仕上十オは、この防水被膜剤を塗布
された上から塗布するに適する。
The coating film finish according to the present invention is suitable for coating on top of the waterproof coating agent.

本実施例にかかる塗膜仕上材は、1回の塗布につき乾燥
被膜で100ミクロン厚が適当である。施工温度は、4
〜5°C以上である。
The coating film finish material according to this example has a dry film thickness of 100 microns per application. The construction temperature is 4
~5°C or higher.

(実施例) アクリル系樹II!t68〜88重り部消泡剤    
  15〜020重1部流動湿潤成分   1〜0.2
2重量部防湿剤      1〜0033重量部水  
       4〜0.50重量部可塑剤      
3〜0.62重量部防黴剤      1〜0100重
量部顔料分散剤    1〜0.15重4部チタニウム
、炭酸カルシウム、か焼アルミナ、マイカ、カオリン(
チャイナクレイ)、ドロマイト、タルク、酸化亜鉛、チ
タニウムについては8〜1.45重項部、それ以外につ
いてはそれぞれ9〜16重量部 乾燥合体成分として炭化水素 2〜0.5重量部、エチ
レングリコールモノブチルエーテル3〜0.25重量部 加える。
(Example) Acrylic tree II! t68-88 weight part antifoaming agent
15-020 weight 1 part fluid wet component 1-0.2
2 parts by weight Moisture-proofing agent 1-0033 parts by weight Water
4-0.50 parts by weight plasticizer
3-0.62 parts by weight Antifungal agent 1-0,100 parts by weight Pigment dispersant 1-0.15 parts by weight 4 parts Titanium, calcium carbonate, calcined alumina, mica, kaolin (
8 to 1.45 parts by weight for dolomite, talc, zinc oxide, and titanium, 9 to 16 parts by weight for each other, 2 to 0.5 parts by weight of hydrocarbons as dry combined components, ethylene glycol mono Add 3 to 0.25 parts by weight of butyl ether.

(発明の効果) 従って、この発明では、伸縮性に富みひび割れの生じに
くく、耐候性に優れ紫外線による劣化の少ない優れたた
塗膜仕り材を特徴する 特許出願人 へイウットインターナノヨナル昧式会社
(Effects of the Invention) Therefore, in this invention, the patent applicant has developed an excellent coating material that is highly elastic, resistant to cracking, has excellent weather resistance, and is less susceptible to deterioration due to ultraviolet rays. company

Claims (1)

【特許請求の範囲】[Claims] アクリル系樹脂と、泡消剤と、流動加湿成分と、防湿剤
と、水と、可塑剤と、防黴剤と、顔料分散剤と、無機材
と、乾燥合体成分とからなることを特徴とする塗膜仕上
材。
It is characterized by consisting of an acrylic resin, a defoaming agent, a fluid humidifying component, a moisture-proofing agent, water, a plasticizer, an anti-mold agent, a pigment dispersant, an inorganic material, and a dry combination component. Paint finishing material.
JP63179842A 1988-07-19 1988-07-19 Coating materials Expired - Fee Related JP2883336B2 (en)

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JP63179842A JP2883336B2 (en) 1988-07-19 1988-07-19 Coating materials

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Publication Number Publication Date
JPH0229467A true JPH0229467A (en) 1990-01-31
JP2883336B2 JP2883336B2 (en) 1999-04-19

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Country Link
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997031694A1 (en) * 1996-02-27 1997-09-04 Nippon Paint Co., Ltd. Method for suppressing foams in booth circulation water
KR20010000356A (en) * 2000-09-21 2001-01-05 홍승익 The manufacturing method of color putty
KR20010007808A (en) * 2000-09-27 2001-02-05 홍승익 The manufacturing method of mono-fluid type plaster finishings
KR20010083861A (en) * 2001-07-05 2001-09-03 정진황 The manufacturing method of non coloring plaser finishings for EIFS
KR100315715B1 (en) * 1999-06-04 2001-12-12 강병우 The flexible coating water resistant organdzation and manufature method of a water type acrylic
KR100351109B1 (en) * 1999-05-01 2002-09-09 한양방수 주식회사 One-Package Type Membranous Waterproof Composition and Construction Method therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6279875A (en) * 1985-10-02 1987-04-13 Toagosei Chem Ind Co Ltd Waterproofing method
JPS63372A (en) * 1986-06-19 1988-01-05 Sony Chem Corp Antibacterial coating for air-conditioning equipment
JPS6381177A (en) * 1986-09-25 1988-04-12 Mitsubishi Yuka Badische Co Ltd Coating compound composition for preventing alga

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6279875A (en) * 1985-10-02 1987-04-13 Toagosei Chem Ind Co Ltd Waterproofing method
JPS63372A (en) * 1986-06-19 1988-01-05 Sony Chem Corp Antibacterial coating for air-conditioning equipment
JPS6381177A (en) * 1986-09-25 1988-04-12 Mitsubishi Yuka Badische Co Ltd Coating compound composition for preventing alga

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997031694A1 (en) * 1996-02-27 1997-09-04 Nippon Paint Co., Ltd. Method for suppressing foams in booth circulation water
KR100351109B1 (en) * 1999-05-01 2002-09-09 한양방수 주식회사 One-Package Type Membranous Waterproof Composition and Construction Method therefor
KR100315715B1 (en) * 1999-06-04 2001-12-12 강병우 The flexible coating water resistant organdzation and manufature method of a water type acrylic
KR20010000356A (en) * 2000-09-21 2001-01-05 홍승익 The manufacturing method of color putty
KR20010007808A (en) * 2000-09-27 2001-02-05 홍승익 The manufacturing method of mono-fluid type plaster finishings
KR20010083861A (en) * 2001-07-05 2001-09-03 정진황 The manufacturing method of non coloring plaser finishings for EIFS

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