JPH0240355A - Benzylalkylthiophenyl ether compound - Google Patents
Benzylalkylthiophenyl ether compoundInfo
- Publication number
- JPH0240355A JPH0240355A JP18780588A JP18780588A JPH0240355A JP H0240355 A JPH0240355 A JP H0240355A JP 18780588 A JP18780588 A JP 18780588A JP 18780588 A JP18780588 A JP 18780588A JP H0240355 A JPH0240355 A JP H0240355A
- Authority
- JP
- Japan
- Prior art keywords
- ether
- benzylalkylthiophenyl
- ether compound
- alkoxybenzyl
- methoxybenzyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title claims abstract description 13
- -1 ether compound Chemical class 0.000 title description 5
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 4
- 239000003054 catalyst Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 150000002170 ethers Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 2
- MOHYOXXOKFQHDC-UHFFFAOYSA-N 1-(chloromethyl)-4-methoxybenzene Chemical compound COC1=CC=C(CCl)C=C1 MOHYOXXOKFQHDC-UHFFFAOYSA-N 0.000 description 1
- OKEHURCMYKPVFW-UHFFFAOYSA-N 2-methoxythiophene Chemical compound COC1=CC=CS1 OKEHURCMYKPVFW-UHFFFAOYSA-N 0.000 description 1
- WLHCBQAPPJAULW-UHFFFAOYSA-N 4-methylbenzenethiol Chemical compound CC1=CC=C(S)C=C1 WLHCBQAPPJAULW-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- UREBWPXBXRYXRJ-UHFFFAOYSA-N ethyl acetate;methanol Chemical compound OC.CCOC(C)=O UREBWPXBXRYXRJ-UHFFFAOYSA-N 0.000 description 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
”（発明の″分野）
本発明は新規なベンジルアルキルチオフェニルエーテル
化合物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to novel benzylalkylthiophenyl ether compounds.
（従来技術）
記録材料用熱可融性物質としてエーテル系化合物、チオ
エーテル系化合物は、各種知られているが、何れも発色
濃度、感度等の点でいくつかの欠点を有していた。(Prior Art) Various ether compounds and thioether compounds are known as thermofusible substances for recording materials, but all of them have several drawbacks in terms of color density, sensitivity, and the like.
（発明の目的）
本発明の目的は記録材料用の熱可融性物質として有用な
新規なベンジルアルキルチオフェニルエーテル化合物を
提供することである。OBJECTS OF THE INVENTION It is an object of the present invention to provide novel benzylalkylthiophenyl ether compounds useful as thermofusible substances for recording materials.
（発明の構成）
本発明は（４−アルコキシベンジル）−４−アルキルチ
オフェニルエーテルから構成される９本発明で言うアル
コキシ基、アルキルチオ基はメトキシ基、エトキシ基、
メチルチオ基、エチルチオ基を言う。(Structure of the Invention) The present invention consists of (4-alkoxybenzyl)-4-alkylthiophenyl ether;
Refers to methylthio group and ethylthio group.
本発明の（４−アルコキシベンジ／リー４−アルキルチ
オフェニルエーテルの具体例を示す。Specific examples of (4-alkoxybendi/4-alkylthiophenyl ether) of the present invention are shown below.
（４−メトキシベンジル）−４＋、メチルチオフ”エニ
ルエーテル、（４−メトキシベンジル）−４−エチルチ
オフェニルエーテル、（４−エトキシペンジノｖ）−４
−メチルチオフェニルエーテル、（４−エトキシベンジ
ル）−４−エチルチオフェニルエーテル。(4-methoxybenzyl)-4+, methylthiophenyl ether, (4-methoxybenzyl)-4-ethylthiophenyl ether, (4-ethoxypendinov)-4
-Methylthiophenyl ether, (4-ethoxybenzyl)-4-ethylthiophenyl ether.
本発明の化合物は様々な合成方法があるが、対応するｐ
−アルコキシベンジルハライドとアルキルチオフェノー
ルを塩基性触媒下に反応させる方法が最も簡便である。The compounds of the present invention can be synthesized by various methods, but the corresponding p
The simplest method is to react an alkoxybenzyl halide with an alkylthiophenol under a basic catalyst.
塩基性触媒としてはアルカリ金属化合物が一般的であり
す） ＩＪウム化合物、又はカリウム化合物等が好まし
い。As the basic catalyst, an alkali metal compound is generally used, but an IJium compound or a potassium compound is preferable.
また反応に際しては、溶媒を使用しても差し支えない。Furthermore, a solvent may be used during the reaction.
（実施例）
ｐ−メチルチオフェノール１４０ｇ及び炭酸カリウム２
（１７ｇのＮ、Ｎ、 ジメチルアセトアミド１１溶液
にｐ−メトキシベンジルクロリド１６０ｇを加え１反応
混度、８５’Ｃで３時間攪拌しながら反応させた０反応
混合物を水にあけ、析出した結晶を濾取した後、メタノ
ール−酢酸エチルから再結晶し、（４−メトキシベンジ
ル）−４−メチルチオフェニルエーテルヲ２２９ ｇ％
だ、 ｍ、 ｐ。(Example) 140 g of p-methylthiophenol and 2 potassium carbonate
(160 g of p-methoxybenzyl chloride was added to 17 g of N, N, dimethylacetamide 11 solution and reacted at 85'C for 3 hours with stirring. The reaction mixture was poured into water and the precipitated crystals were filtered. After that, it was recrystallized from methanol-ethyl acetate to obtain 229 g% of (4-methoxybenzyl)-4-methylthiophenyl ether.
Da, m, p.
１００．５〜１０１’Ｃ （実施例２〜４） 同様にして以下の化合物を得た。100.5~101'C (Examples 2 to 4) The following compounds were obtained in the same manner.
Claims (1)
ルエーテル(4-alkoxybenzyl)-4-alkylthiophenyl ether
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18780588A JPH0240355A (en) | 1988-07-27 | 1988-07-27 | Benzylalkylthiophenyl ether compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18780588A JPH0240355A (en) | 1988-07-27 | 1988-07-27 | Benzylalkylthiophenyl ether compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0240355A true JPH0240355A (en) | 1990-02-09 |
Family
ID=16212550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18780588A Pending JPH0240355A (en) | 1988-07-27 | 1988-07-27 | Benzylalkylthiophenyl ether compound |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0240355A (en) |
-
1988
- 1988-07-27 JP JP18780588A patent/JPH0240355A/en active Pending
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