JPH0241163A - Deodorant and its manufacturing method - Google Patents
Deodorant and its manufacturing methodInfo
- Publication number
- JPH0241163A JPH0241163A JP63191565A JP19156588A JPH0241163A JP H0241163 A JPH0241163 A JP H0241163A JP 63191565 A JP63191565 A JP 63191565A JP 19156588 A JP19156588 A JP 19156588A JP H0241163 A JPH0241163 A JP H0241163A
- Authority
- JP
- Japan
- Prior art keywords
- sulfate
- polypeptide
- ammonia
- mmol
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000002781 deodorant agent Substances 0.000 title description 10
- 229920001184 polypeptide Polymers 0.000 claims description 18
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 18
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 18
- 229910021645 metal ion Inorganic materials 0.000 claims description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 239000011133 lead Substances 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 239000011135 tin Substances 0.000 claims description 4
- 238000004332 deodorization Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 24
- 229910021529 ammonia Inorganic materials 0.000 description 12
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 10
- 230000001877 deodorizing effect Effects 0.000 description 10
- 239000000835 fiber Substances 0.000 description 9
- 125000003277 amino group Chemical group 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 6
- 235000019645 odor Nutrition 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000009257 reactivity Effects 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229920001436 collagen Polymers 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910000337 indium(III) sulfate Inorganic materials 0.000 description 1
- XGCKLPDYTQRDTR-UHFFFAOYSA-H indium(iii) sulfate Chemical compound [In+3].[In+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O XGCKLPDYTQRDTR-UHFFFAOYSA-H 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Peptides Or Proteins (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明はアンモニア等の悪臭を消臭する耐久性に優れた
消臭剤及びその製法に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a highly durable deodorizer that deodorizes bad odors such as ammonia, and a method for producing the same.
〈従来の技術〉
従来、消臭剤は活性炭、ゼオライト等の物理吸着性を利
用したものや硫酸第一鉄の様な化学反応性を利用したも
のが知られているが、前者の物理吸着性を利用したもの
は極性の強いアンモニア等の悪臭を吸着する効果が劣り
、後者の化学反応性を利用したものは水溶液として利用
されるので使用方法が限定され、又耐久性に欠けるもの
であった。この改良として繊維学会誌４２、Ｐ２Ｏ（１
９８６）のように硫酸第一鉄／アスコルビン酸系、又は
繊維学会誌４１．Ｐ２６７（１９８５）のように第二鉄
フタロシアニン等が提案されているが、これらも水分の
無い状態での耐久性に欠け、安定性に欠けるものであり
、水性液としても長時間空気に触れると効果が低下し、
高分子成型物に含有させると成型時の熱で性能低下をき
たし易く、後加工で高分子成型物に含有させようとする
と全く洗濯等の耐久性に乏しいものである。<Conventional technology> Conventionally, deodorants have been known to utilize the physical adsorption properties of activated carbon, zeolite, etc., and those that utilize chemical reactivity such as ferrous sulfate. The ones that used the latter were less effective at adsorbing bad odors such as highly polar ammonia, and the ones that made use of the latter chemical reactivity were used as an aqueous solution, so their usage was limited and they lacked durability. . As this improvement, the Journal of Fiber Science Society 42, P2O (1
Ferrous sulfate/ascorbic acid system, such as 986), or Journal of the Japan Textile Society 41. P267 (1985), ferric phthalocyanine, etc. have been proposed, but these also lack durability and stability in the absence of moisture, and even as an aqueous liquid, they do not react well when exposed to air for a long time. effectiveness decreases,
If it is incorporated into a polymer molded product, its performance is likely to deteriorate due to the heat during molding, and if it is attempted to be incorporated into a polymer molded product after post-processing, it will have poor durability against washing, etc.
〈発明が解決しようとする課題〉
本発明は従来のかかる消臭剤の問題点を解決し、耐久性
に優れた消臭剤及びその製法を提供するものである。<Problems to be Solved by the Invention> The present invention solves the problems of conventional deodorants and provides a deodorant with excellent durability and a method for producing the same.
く課題を解決するための手段〉
本発明は銅、銀、錫、アルミニウム、鉄、クロム、亜鉛
、ニッケル、鉛、インジウム及びジルコニウムの群から
選ばれる少なくとも一つの金属イオンを配位させたポリ
ペプチドからなる消臭剤及びポリペプチドを前記金属イ
オンを含む水溶液中で熱処理することを特徴とする消臭
剤の製法にある。Means for Solving the Problems> The present invention provides a polypeptide coordinated with at least one metal ion selected from the group of copper, silver, tin, aluminum, iron, chromium, zinc, nickel, lead, indium, and zirconium. A method for producing a deodorant comprising heat-treating a polypeptide in an aqueous solution containing the metal ion.
本発明では金属イオンの状態では不安定である金属イオ
ンをポリペプチドのアミノ基及びカルボキシル基に配位
させ安定化して利用するもので、本発明の消臭剤はその
化学反応性、触媒反応性、物理吸着性により従来の消臭
剤に無い著しい消臭作用効果を奏する。In the present invention, metal ions, which are unstable in the metal ion state, are stabilized by being coordinated to the amino groups and carboxyl groups of polypeptides, and the deodorant of the present invention has a high chemical reactivity and catalytic reactivity. Due to its physical adsorption properties, it exhibits remarkable deodorizing effects not found in conventional deodorants.
更に任意の形状で利用可能であり使用目的に応じた形態
で提供しうる。Furthermore, it can be used in any shape and can be provided in a form depending on the purpose of use.
本発明の消臭剤はポリペプチドを基体とするもので、ポ
リペプチドとしてアミン基８２０ミリモル／に！？、カ
ルボキシル基７７０ミリモル／時のケラチンからなる羊
毛、アミノ基１５０ミリモル／ｋｉ９、カルボキシル基
２９０ミリモル／ゆの絹、アミノ基１０９０ミリモル／
ユ、カルボキシル基４２０ミリモル／に９のゼラチン、
アミノ基８００ミリモル／に９．カルボキシル基１６２
０ミリモル／ｋｌ？のカゼイン、アミン基９４０ミリモ
ル／ｋｇ、カルボキシル基７７０ミリモル／ゆのコラー
ゲン等の天然ポリペプチド又は合成ポリペプチドが挙げ
られる。The deodorant of the present invention is based on a polypeptide, and has 820 mmol/amine group as a polypeptide! ? , wool consisting of keratin with carboxyl groups 770 mmol/h, amino groups 150 mmol/ki9, carboxyl groups 290 mmol/yun silk, amino groups 1090 mmol/h
U, gelatin with 420 mmol of carboxyl groups/9 in,
800 mmol/amino group9. carboxyl group 162
0 mmol/kl? Examples include natural polypeptides or synthetic polypeptides such as casein with 940 mmol of amine groups/kg and collagen with 770 mmol of carboxyl groups/kg.
本発明における消臭剤においてはポリペプチド中の２個
のアミン基と２個のカルボキシル基に１個の金属イオン
が配位しているものと思われる。金属イオンを配位させ
るにはポリペプチドを金属イオン含有水溶液中で熱処理
する方法により達成される。In the deodorant of the present invention, one metal ion seems to be coordinated to two amine groups and two carboxyl groups in the polypeptide. Coordination of metal ions is achieved by heat-treating the polypeptide in an aqueous solution containing metal ions.
本発明でポリペプチドに金属イオンを配位させて導入す
る量は１０００ ｐｐｍ以上必要である。In the present invention, the amount of metal ions to be introduced by coordinating with the polypeptide must be 1000 ppm or more.
本発明の消臭剤の形状はポリペプチドの形態により、液
状、ゲル状、パウダー、成型物等使用目的に合わせて任
意に選択することができる。The form of the deodorant of the present invention can be arbitrarily selected depending on the form of the polypeptide, such as liquid, gel, powder, or molded product, depending on the purpose of use.
なお、ポリペプチドは重金属イオンを含む排水処理に用
いることが特開昭５５−４９１４２号公報で提案され、
ポリペプチドに金属イオンが配位し易いことは知られて
いるが、本発明はポリペプチドに配位した金属イオンを
この金属イオンと化学反応性の高いアンモニア、硫化水
素、メチルメルカプタン等の悪臭と・反応させ消臭に利
用するものである。It should be noted that the use of polypeptides in the treatment of wastewater containing heavy metal ions was proposed in JP-A-55-49142.
It is known that metal ions are easily coordinated to polypeptides, but the present invention eliminates the odor of metal ions coordinated to polypeptides from ammonia, hydrogen sulfide, methyl mercaptan, etc. that are highly chemically reactive with the metal ions.・It is used for deodorization by reaction.
本発明の金属イオンは銅、銀、錫、アルミニウム、鉄、
クロム、亜鉛、ニッケル、鉛、インジウム及びジルコニ
ウム等の金属イオンが用いられる。銅、銀は単独でアン
モニア、硫化水素、メチルメルカプタンを消臭し易く、
錫、アルミニウム、鉄、りｐムはアンモニアの消臭性に
優れ、亜鉛、ニッケル、鉛は硫化水素の消臭性に優れ、
インジウム、ジルコニウムはメチルメルカプタンの消臭
性に優れ、それぞれ目的に応じて選ばれる。ポリペプチ
ドとの配位結合を１硫酸鋼、塩化第二銅、硫酸第二鉄、
塩化第二錫、硝酸銀、硫酸アルミニウム、硫酸第ニクロ
ム、硫酸鉛、硫酸亜鉛、硫酸ニッケル、硫酸インジウム
、硫酸ジルコニウム等の水溶液にポリペプチドを浸漬し
熱処理して行われる。熱処理は４０〜１２０℃で行われ
る。この熱処理は金属イオン含有水溶液の浸漬とは別工
程で行ってもよいし、又同一工程で行ってもよい。The metal ions of the present invention include copper, silver, tin, aluminum, iron,
Metal ions such as chromium, zinc, nickel, lead, indium and zirconium are used. Copper and silver alone easily deodorize ammonia, hydrogen sulfide, and methyl mercaptan.
Tin, aluminum, iron, and lime have excellent deodorizing properties for ammonia, and zinc, nickel, and lead have excellent deodorizing properties for hydrogen sulfide.
Indium and zirconium have excellent deodorizing properties for methyl mercaptan, and are selected depending on the purpose. Coordination bonds with polypeptides are formed using steel sulfate, cupric chloride, ferric sulfate,
Polypeptides are immersed in an aqueous solution of stannic chloride, silver nitrate, aluminum sulfate, dichrome sulfate, lead sulfate, zinc sulfate, nickel sulfate, indium sulfate, zirconium sulfate, etc., and then heat-treated. Heat treatment is performed at 40-120°C. This heat treatment may be performed in a separate step from the immersion in the metal ion-containing aqueous solution, or may be performed in the same step.
〈実施例〉 以下本発明を実施例により説明する。<Example> The present invention will be explained below with reference to Examples.
なお、実施例中の％は重量％を意味する。アミノ基の含
有量はオレンジＩｔ（酸性染料）の染着量より求め、金
属の含有量は炭化物の原子吸光分析で行った。In addition, % in an example means weight %. The content of amino groups was determined from the amount of orange It (acidic dye) dyed, and the content of metals was determined by atomic absorption spectrometry of carbide.
実施例１
羊毛（アミン基５１３ミリモル／ｋｇ）織物を硫酸鋼２
０％ｏｗ４ （対繊維重量）の浴比１：３０の水溶液中
で沸騰下で３０分間処理し、７０℃で湯洗し、約７０℃
で乾燥し、銅１４０００ ｐｐｍ含有の緑色の繊維を得
た。Example 1 Wool (amine group 513 mmol/kg) fabric was coated with sulfuric acid steel 2
Treated at boiling for 30 minutes in an aqueous solution of 0% OW4 (to fiber weight) at a bath ratio of 1:30, washed with hot water at 70°C, and washed at about 70°C.
A green fiber containing 14,000 ppm of copper was obtained.
３７０１ｄの三角フラスコにアンモニア９８０ｐｐｍ、
硫化水素６３０ ｐｐｍ、メチルメルカプタン１１０
ｐｐｒｎを入れ、得られた繊維をＩＰづつ封入し３０分
後残った濃度を測定したところ、それぞれＯ＋ ０．
０．２ｐｐｍと優れた消臭効果を示した。又この繊維を
サンシャインウェザ−カメ−ター３００時間（約１年の
屋外暴露に相当）加水分解テスト７０℃×９０〜１００
％ＲＨＸ１週間（約３年の室内放置に相当）ＪＩＳＬ−
０２１７の１０３法に規定する家庭洗濯を１０回行った
もの、ドライクリーニング３回行ったものそれぞれ１！
を１０２’０，１０８０，１０２０．９９０ｐｐｔｎの
アンモニア濃度に調整した３７０１の三角フラスコに封
入し３０分後のアンモニア濃度を測定したところ、いず
れも Ｏｐｐｍと極めて優れた耐久性のある消臭効果を
示した。Ammonia 980ppm in Erlenmeyer flask 3701d,
Hydrogen sulfide 630 ppm, methyl mercaptan 110
pprn was added, the resulting fibers were encapsulated in IP portions, and the remaining concentration was measured after 30 minutes.
It showed an excellent deodorizing effect of 0.2 ppm. This fiber was also subjected to a 300-hour (equivalent to about 1 year of outdoor exposure) hydrolysis test using a sunshine weather camera at 70°C x 90-100°C.
%RHX 1 week (equivalent to being left indoors for about 3 years) JISL-
1 for each item that has been washed at home 10 times and dry cleaned 3 times as stipulated in Law 103 of 0217!
was sealed in a 3701 Erlenmeyer flask adjusted to an ammonia concentration of 102'0, 1080, and 1020.990 pptn, and the ammonia concentration was measured 30 minutes later.The ammonia concentration was measured at Oppm in all cases, showing an extremely durable deodorizing effect. Ta.
実施例２
実施例１で用いた羊毛織物を硫酸アルミニウム５％ｏｗ
ｆ 、硫酸ニッケル５％ｏｗｆ、硫酸ジルコニウム２％
ｏｖｆの浴比１：３０の水溶液中で沸騰下で３０分間処
理、７０℃で湯洗し、約７０℃で乾燥し、アルミニウム
１５００ｐｐｍ、ニッケル６２００ｐｐｍ、ジルコニウ
ム５８００ ｐｐｍ含有の白色の繊維を得た。Example 2 The wool fabric used in Example 1 was treated with 5% aluminum sulfate.
f, nickel sulfate 5%owf, zirconium sulfate 2%
The fibers were treated in an aqueous solution of OVF at a bath ratio of 1:30 under boiling for 30 minutes, washed with hot water at 70°C, and dried at about 70°C to obtain white fibers containing 1500 ppm of aluminum, 6200 ppm of nickel, and 5800 ppm of zirconium.
３７ＯＮの三角フラスコにアンモニア１１０３０ｐｐ
％硫化水素６７０ Ｐｐｔｎ、メチルメルカプタン１０
０ ｐｐｍを入れ、得られた繊維を１１づつ封入し３０
分後残った濃度を測定したところ、それぞれ０ 、 ０
．３ 、 ０．２ ｐｐｍで優れた消臭効果を示した。Ammonia 11030pp in a 37ON Erlenmeyer flask
% hydrogen sulfide 670 Pptn, methyl mercaptan 10
0 ppm and encapsulated the obtained fibers in groups of 11 and 30
When the remaining concentrations were measured after 1 minute, they were 0 and 0, respectively.
．． 3. It showed excellent deodorizing effect at 0.2 ppm.
又この繊維をサンシャインウェザ−カメ−ター３００時
間、加水分解テスト７０℃×９０〜１００％ＲＨＸ １
週間、洗濯１０回、ドライクリーニング３回行りても消
臭効果が低下しないことを確認した。In addition, this fiber was subjected to a hydrolysis test using a sunshine weather camera for 300 hours at 70°C x 90-100% RH x 1.
It was confirmed that the deodorizing effect did not decrease even after washing 10 times and dry cleaning 3 times per week.
実施例３
コラーゲンのパウダー１０７’と硝酸銀ＩＰを水１！中
で攪拌し、７０℃に加熱１時間後に冷却し、４０℃で湯
洗後乾燥し、銀２８０００ｐｐｍ含有の灰色のパウダー
を得た。Example 3 Collagen powder 107' and silver nitrate IP in 1 part water! The mixture was stirred in a vacuum chamber, heated to 70°C for 1 hour, cooled, washed with hot water at 40°C, and dried to obtain a gray powder containing 28,000 ppm of silver.
３７０＋ｊの三角フラスコにアンモニアを１０１０ＰＰ
ｒＱ％硫化水素６５０ｐｐｍ、メチルメルカプタフ１１
Ｏｐｐｒｎ入れ、得られたパウダーをＩＰづつ封入し３
０分後残った濃度を測定したところ、いずれもＯｐｐｍ
で優れた消臭効果を示した。こ（７） パウダーを加水
分解テスト７０℃×９０〜１００％ＲＨＸ１週間を行っ
たが、何れの悪臭についても消臭効果の低下が無かった
。1010PP ammonia in a 370+J Erlenmeyer flask
rQ% hydrogen sulfide 650 ppm, methyl mercaptaf 11
Put the Opprn and encapsulate the obtained powder in each IP.3
When the concentration remaining after 0 minutes was measured, both were Oppm.
It showed excellent deodorizing effect. (7) The powder was subjected to a hydrolysis test at 70° C. x 90-100% RH for 1 week, but there was no decrease in the deodorizing effect for any bad odor.
〈発明の効果〉
本発明の消臭剤はアンモニア等の悪臭を極めて効率よ（
消臭し、又極めて耐久性に優れた任意の形状で利用しう
るものである。<Effects of the Invention> The deodorizer of the present invention removes bad odors such as ammonia very efficiently (
It deodorizes, is extremely durable, and can be used in any shape.
Claims (1)
ッケル、鉛、インジウム及びジルコニウムの群から選ば
れる少なくとも一つの金属イオンを配位させたポリペプ
チドからなる消臭剤。 ２、ポリペプチドを銅、銀、錫、アルミニウム、鉄、ク
ロム、亜鉛、ニッケル、鉛、インジウム及びジルコニウ
ムの群から選ばれる少なくとも一つの金属イオンを含む
水溶液中で熱処理することを特徴とする消臭剤の製法。[Scope of Claims] 1. Deodorizer consisting of a polypeptide coordinated with at least one metal ion selected from the group of copper, silver, tin, aluminum, iron, chromium, zinc, nickel, lead, indium, and zirconium. agent. 2. Deodorization characterized by heat-treating a polypeptide in an aqueous solution containing at least one metal ion selected from the group of copper, silver, tin, aluminum, iron, chromium, zinc, nickel, lead, indium, and zirconium. Method of manufacturing the agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63191565A JPH0241163A (en) | 1988-07-29 | 1988-07-29 | Deodorant and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63191565A JPH0241163A (en) | 1988-07-29 | 1988-07-29 | Deodorant and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0241163A true JPH0241163A (en) | 1990-02-09 |
Family
ID=16276785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63191565A Pending JPH0241163A (en) | 1988-07-29 | 1988-07-29 | Deodorant and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0241163A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2814743A1 (en) * | 2000-05-19 | 2002-04-05 | Chiang Ling Hui Cheng | Production of trivalent chromium complex compound useful for preparing milk product for controlling blood sugar involves addition of lactoferrin or whey protein to a trivalent chromium compound |
| JP2006504448A (en) * | 2002-07-02 | 2006-02-09 | プロサイト コーポレイション | Composition containing peptide copper complex and soft tissue filler |
| JP2023501362A (en) * | 2019-11-04 | 2023-01-18 | ウィソク コ | Food packaging material containing zinc polypeptide |
-
1988
- 1988-07-29 JP JP63191565A patent/JPH0241163A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2814743A1 (en) * | 2000-05-19 | 2002-04-05 | Chiang Ling Hui Cheng | Production of trivalent chromium complex compound useful for preparing milk product for controlling blood sugar involves addition of lactoferrin or whey protein to a trivalent chromium compound |
| JP2006504448A (en) * | 2002-07-02 | 2006-02-09 | プロサイト コーポレイション | Composition containing peptide copper complex and soft tissue filler |
| JP2023501362A (en) * | 2019-11-04 | 2023-01-18 | ウィソク コ | Food packaging material containing zinc polypeptide |
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