JPH0241373A - Cloisonn'e blend paint - Google Patents
Cloisonn'e blend paintInfo
- Publication number
- JPH0241373A JPH0241373A JP19166988A JP19166988A JPH0241373A JP H0241373 A JPH0241373 A JP H0241373A JP 19166988 A JP19166988 A JP 19166988A JP 19166988 A JP19166988 A JP 19166988A JP H0241373 A JPH0241373 A JP H0241373A
- Authority
- JP
- Japan
- Prior art keywords
- paint
- smoothness
- ketones
- polyhydric alcohol
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 23
- 239000000203 mixture Substances 0.000 title claims abstract description 18
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 150000005846 sugar alcohols Chemical class 0.000 claims abstract description 10
- 150000002576 ketones Chemical class 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 230000008719 thickening Effects 0.000 claims abstract description 6
- 238000009835 boiling Methods 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 241001385733 Aesculus indica Species 0.000 claims 1
- 239000000843 powder Substances 0.000 abstract description 5
- 239000011521 glass Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000049 pigment Substances 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 6
- 238000010304 firing Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 3
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000004859 Copal Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000782205 Guibourtia conjugata Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- -1 etc. Substances 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は水彩画用絵具や油絵用絵具等にみられるような
筆タッチ感覚で描くことのできる七宝ブレンド絵具に関
する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a cloisonné blend paint that can be painted with a brush touch similar to that found in watercolor paints, oil paints, and the like.
（従来の技術）
従来、七宝、ホーロー、陶磁器等に上絵を描く場合、顔
料と澱粉質糊料（ＣＭＣ１布のり）を水にて混練したも
のにコーパル樹脂、にかわ、アラビアゴム、デキストリ
ン、ゼラチン、グルコース、メチルセルロース、メチル
エチルセルロース、澱粉、カゼイン、酢酸セルローズ等
の有機結合剤の一種類または二種類を加えた物を使用し
ていた。(Prior art) Conventionally, when painting on cloisonné, enamel, ceramics, etc., pigments and starch paste (CMC1 cloth glue) were mixed with water, then copal resin, glue, gum arabic, dextrin, and gelatin were used. , glucose, methyl cellulose, methyl ethyl cellulose, starch, casein, cellulose acetate, and other organic binders.
また、これらの有機結合剤は水と顔料を混練した場合に
、その量により低粘度から高粘度まで自由に調整でき、
さらに上絵を描く場合の筆に対してなじみもよく、繊細
な描画ができる。In addition, when these organic binders are mixed with water and pigment, the viscosity can be adjusted freely from low to high depending on the amount.
Furthermore, it blends well with the brush when painting overlays, allowing for delicate drawings.
（発明が解決しようとする課題）
このような従来の有機結合剤を使用したものは、その有
機結合剤のほとんどが焼成温度が１０００℃以上でない
と有機物の炭化物が製品に残り、汚れ、シミ、ヒビ等の
原因となる。(Problems to be Solved by the Invention) Most of the products using conventional organic binders leave organic carbides on the products unless the firing temperature is 1000°C or higher, resulting in dirt, stains, etc. This may cause cracks, etc.
一方、七宝焼きに使用する釉薬は通常、焼成温度は７０
０℃〜８５０℃であり、高温七宝釉薬であっても、１０
００℃を超えることはないため、汚れ、シミ、ヒビ等を
防止することができなかった。また、七宝基板は表面が
平滑であるため、水分含有の釉はハジキを生じ、繊細な
描画タッチは表現できない。On the other hand, the glaze used for cloisonne ware is usually fired at a temperature of 70°C.
0℃~850℃, even with high temperature cloisonné glaze, 10
Since the temperature never exceeds 00°C, it was not possible to prevent dirt, stains, cracks, etc. In addition, since the surface of the cloisonné board is smooth, glaze containing moisture will cause repellency, making it impossible to express delicate drawing touches.
更に、上記有機結合剤を使用した上絵用絵具を七宝基板
に用いると割れ、シミ、汚れ等が発生し使用できない等
の問題があった。Furthermore, when overglaze paints using the above-mentioned organic binders are used on cloisonné substrates, there are problems such as cracks, stains, stains, etc., which make them unusable.
本発明はこのような従来の問題を解決し、従来の水彩画
用絵具または油絵用絵具等にみられるような筆タッチ感
覚で七宝面を描くことができ、焼成後は焼物特有の平滑
さと光沢をもち、しかも七宝表面にヒビ、割れ、汚れな
どが生じない七宝ブレンド絵具の提供を目的としたもの
である。The present invention solves these conventional problems and allows cloisonné surfaces to be drawn with the touch of a brush similar to those found in conventional watercolor paints or oil paints, and after firing, it maintains the smoothness and luster characteristic of pottery. The purpose is to provide a cloisonne blend paint that is sticky and does not cause cracks, breaks, stains, etc. on the cloisonné surface.
（課題を解決するための手￥１１）
本発明者等は上記の問題を解すべく、有機結合剤を検討
した結果、溶剤としてケトン類及び多価アルコール誘導
体を使用し、それに界面活性を混合したものを無機系顔
料らしくは七宝絵具に混合し混練したものが問題を解決
できることを見出して本発明を完成したのであり、その
特徴は溶剤としてケトン類のうち沸点が１５０〜２００
℃の間にあるものを３０〜８０％、及び分子量が４００
〜６０００の間にある多価アルコール誘導体１０〜５０
％と増粘と平滑性を調整する界面活性剤を２〜１０％加
え、これを無機系顔料もしくは七宝ガラス粉末と無機顔
料の混合物を３０〜７０％混合したことにある。(Measures to solve the problem ¥11) In order to solve the above problem, the present inventors investigated organic binders, and as a result, they used ketones and polyhydric alcohol derivatives as solvents and mixed surfactants with them. The present invention was completed by discovering that the problem could be solved by mixing inorganic pigments with cloisonné pigments and kneading them.
30-80% of those between ℃ and molecular weight of 400
Polyhydric alcohol derivatives between ~6000 10 and 50
% and 2 to 10% of a surfactant to adjust thickening and smoothness, and this is mixed with 30 to 70% of an inorganic pigment or a mixture of cloisonné glass powder and inorganic pigment.
（作用及び効果）
従来の陶磁器、七宝焼に用いられる釉薬は水溶性樹脂（
上記記載の有機結合剤）水及び顔料で構成されており、
この組成物の分散系は水である。(Functions and Effects) The glaze used for traditional ceramics and cloisonne ware is made of water-soluble resin (
The organic binder described above) is composed of water and pigment,
The dispersion system of this composition is water.
水の表面張力は大きく、ハジキ発生の原因となり、基板
上の描画に悪い影響を及ぼす、そこで水分は全く使用せ
ず親水性溶剤を使用し、また水にて希釈できるように界
面活性剤を混合することが考えられるが、顔料及び七宝
絵具の中には親水性ものと親油性らのがあり親油性のも
のは色分れや乾燥後のしとの発生のため顔料の数が限定
され、親水性の場合は平滑性や艶に難点がある場合があ
る。The surface tension of water is large and causes repellency, which has a negative effect on the drawings on the substrate.Therefore, we do not use any water at all, but use a hydrophilic solvent, and also mix a surfactant so that it can be diluted with water. However, some pigments and cloisonne paints are hydrophilic and others are lipophilic, and the number of pigments that can be used with lipophilic paints is limited due to color separation and the appearance of stains after drying. In the case of hydrophilic properties, there may be problems with smoothness and gloss.
そこで本発明では、溶剤にケトン類及び高分子多価アル
コール、それに界面活性剤を加えたものに、七宝絵具ま
たは無機顔料を混合したものを検討した結果、焼成温度
７５０℃前後で表面にシミ、汚れ、割れ等がなく、しか
も輝きのある七宝製品ができた。Therefore, in the present invention, we investigated a mixture of ketones, high-molecular polyhydric alcohols, and surfactants as solvents, and cloisonné paints or inorganic pigments.As a result, we found that at a firing temperature of around 750°C, stains appeared on the surface. A shiny cloisonné product with no stains or cracks was created.
ケトン類の沸点が１５０℃以下の場合は、施釉、または
描画時において乾燥してしまい、板上にのりづらい、２
００℃以上の沸点では、焼成前の乾燥に時間がかかりす
ぎる。多価アルコールの分子量が４００以下の場合、乳
化分散ができず液体状になってしまうため、絵具として
の性状に欠ける。If the boiling point of ketones is below 150℃, it will dry out during glazing or drawing, making it difficult to apply on the board.
If the boiling point is 00°C or higher, it will take too long to dry before firing. When the molecular weight of the polyhydric alcohol is 400 or less, it cannot be emulsified and dispersed and becomes liquid, which results in poor properties as a paint.
６０００以上だと、焼成後、シミ、シワ、黒色斑点がで
きる。If it exceeds 6000, stains, wrinkles, and black spots will appear after firing.
また本発明の七宝ブレンド絵具は、しぼり出しチューブ
や瓶等の容器に入れて保存できる。Further, the cloisonne blend paint of the present invention can be stored in a container such as a squeezing tube or a bottle.
（実施例１）
シクロヘキサン・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・３０部ポポリチレングリコー
ル＃６００・・・・・・５０部界面活性剤・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・５部を調剤、混練してペースト状にし、上
記ペースト状物に対し無機顔料を５０％加え、練和して
製品としな。(Example 1) Cyclohexane・・・・・・・・・・・・・・・・・・
......30 parts Polyethylene glycol #600...50 parts Surfactant...
・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・Prepare 5 parts, knead to form a paste, add 50% inorganic pigment to the above paste, and knead to form a product.
（実施例２）
ジアセトンアルコール・・・・・・・・・・・・・・・
・・・・・・２５部ジイソブチルケトン・・・・・・・
・・・・・・・・・・・・・・・・・２５部ポポリチレ
ングリコール＃４０００・・・３０部界面活性剤・・・
・・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・２部を調剤、混練してペースト
状にし、上記ペースト状物に対し七宝絵具（粉末状）を
５０％加え練和して製品とした。(Example 2) Diacetone alcohol・・・・・・・・・・・・・・・
...25 parts diisobutyl ketone...
・・・・・・・・・・・・・・・・・・25 parts Popolyethylene glycol #4000...30 parts Surfactant...
・・・・・・・・・・・・・・・・・・・・・・・・
..... Two parts were prepared and kneaded to form a paste, and 50% cloisonné pigment (powder) was added to the above paste and kneaded to form a product.
（実施例３）
ホロン・・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・２５部ジアセトンア
ルコール・・・・・・・・・・・・・・・・・・・・・
２０部ポポリチレングリコール＃４０００・・・４０部
を調剤、混練してペースト状にし、上記ペースト状物に
対し無機顔料２５％、七宝絵具（粉末状）２５％を加え
、練和して製品とした。(Example 3) Holon・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・25 parts diacetone alcohol・・・・・・・・・・・・・・・・・・・・・
Prepare 20 parts of polyethylene glycol #4000...40 parts to make a paste, add 25% of inorganic pigment and 25% of cloisonné paint (powder) to the above paste, and knead to form a product. did.
（比較例１）
水・・・・・・・・・・・・・・・・・・・・・・・・
・・・３５部布海苔・・・・・・・・・・・・・・・・
・・・・・・・・２部デキストリン・・・・・・・・・
・・・・・・３部を調剤、混練してペースト状にし、上
記ペースト状物に対し無機顔料を５０％加え練和して製
品とした。(Comparative example 1) Water・・・・・・・・・・・・・・・・・・・・・
・・・35 parts Funori・・・・・・・・・・・・・・・
・・・・・・・・・Two-part dextrin・・・・・・・・・
...3 parts were prepared and kneaded to form a paste, and 50% of an inorganic pigment was added to the above paste and kneaded to form a product.
（比較例２）
水・・・・・・・・・・・・・・・・・・・・・・・・
・・・９１部ＣＭ Ｃ・・・・・・・・・・・・・・・
・・・・・・・・・３部（カルボキシルメチルセルロー
スソーダ）ゼラチン・・・・・・・・・・・・・・・・
・・・・・６部を調剤、混練してペースト状にし、上記
ペースト状物に対し七宝絵具（粉末状）を５０％加え練
和して製品とした。(Comparative Example 2) Water・・・・・・・・・・・・・・・・・・・・・
・・・91st part CM C・・・・・・・・・・・・・・・
・・・・・・・・・3 parts (carboxyl methyl cellulose soda) gelatin・・・・・・・・・・・・・・・・
... 6 parts were prepared and kneaded to form a paste, and 50% cloisonné pigment (powder) was added to the above paste and kneaded to form a product.
前記実施例１〜３、及び比較例１〜２で得られた水溶性
七宝ブレンド絵具を用いて比鮫色試験を行った結果を第
１表に示した。Table 1 shows the results of a Hi-Same color test using the water-soluble cloisonné blend paints obtained in Examples 1 to 3 and Comparative Examples 1 to 2.
なお、基板としてはいずれも純銅の上に七宝釉を施釉焼
成したものを使用し、その上に上記塗布、乾燥後、７５
０℃で２分間焼成した。The substrate used in each case was pure copper coated with cloisonné glaze and fired, and after the above coating and drying, 75%
It was baked at 0°C for 2 minutes.
比 較
第１表
焼 成
結 果
第１表より明らかに比較例１．２と実施例１．２．３を
比教すると、実施例はいずれも変色、割れ、色分れ、汚
れが無く、さらに光沢にも優れていた。Comparison Table 1 Firing Results Table 1 clearly shows that comparing Comparative Example 1.2 and Example 1.2.3, there was no discoloration, cracking, color separation, or staining in any of the Examples. Furthermore, it had excellent gloss.
Claims (4)
ール誘導物１０〜５０％と増粘と平滑性を調整する界面
活性剤２〜１０％と無機系顔料３０〜７０％とを混合し
てなる七宝ブレンド絵具。(1) Mix 30-80% of ketones and 10-50% of polyhydric alcohol derivatives as a solvent, 2-10% of a surfactant to adjust thickening and smoothness, and 30-70% of an inorganic pigment. Naru cloisonne blend paint.
ール誘導物１０〜５０％と増粘と平滑性を調整する界面
活性剤２〜１０％と粉末状七宝絵具３０〜７０％とを混
合してなる七宝ブレンド絵具。(2) Mix 30 to 80% of ketones and 10 to 50% of polyhydric alcohol derivatives as a solvent, 2 to 10% of a surfactant to adjust thickening and smoothness, and 30 to 70% of powdered cloisonne paint. Cloisonne blend paint.
ール誘導物１０〜５０％と増粘と平滑性を調整する界面
活性剤２〜１０％と粉末状七宝絵具と無機系顔料の混合
物３０〜７０％とを混合してなる七宝ブレンド絵具。(3) A mixture of 30 to 80% ketones and 10 to 50% polyhydric alcohol derivatives as a solvent, 2 to 10% surfactant to adjust thickening and smoothness, powdered cloisonne paint, and inorganic pigment. Cloisonné blend paint made by mixing 70%.
アルコール誘導体は分子量が４００〜６０００である特
許請求の範囲第１項、第２項または第３項に記載の七宝
ブレンド絵具。(4) The cloisonne blend paint according to claim 1, 2 or 3, wherein the ketones have a boiling point of 150 to 200°C, and the polyhydric alcohol derivative has a molecular weight of 400 to 6,000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19166988A JPH0633203B2 (en) | 1988-07-30 | 1988-07-30 | Cloisonne blend paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19166988A JPH0633203B2 (en) | 1988-07-30 | 1988-07-30 | Cloisonne blend paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0241373A true JPH0241373A (en) | 1990-02-09 |
| JPH0633203B2 JPH0633203B2 (en) | 1994-05-02 |
Family
ID=16278488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19166988A Expired - Lifetime JPH0633203B2 (en) | 1988-07-30 | 1988-07-30 | Cloisonne blend paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0633203B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0441786A (en) * | 1990-06-02 | 1992-02-12 | Moritoshi Tsukamoto | Ornament |
| CN102589298A (en) * | 2012-02-23 | 2012-07-18 | 沈阳东大三建工业炉制造有限公司 | Pressure-differential type aluminum producing device for aluminum alloy melting furnace |
-
1988
- 1988-07-30 JP JP19166988A patent/JPH0633203B2/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0441786A (en) * | 1990-06-02 | 1992-02-12 | Moritoshi Tsukamoto | Ornament |
| CN102589298A (en) * | 2012-02-23 | 2012-07-18 | 沈阳东大三建工业炉制造有限公司 | Pressure-differential type aluminum producing device for aluminum alloy melting furnace |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0633203B2 (en) | 1994-05-02 |
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