JPH0249625B2 - - Google Patents

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Publication number
JPH0249625B2
JPH0249625B2 JP59123989A JP12398984A JPH0249625B2 JP H0249625 B2 JPH0249625 B2 JP H0249625B2 JP 59123989 A JP59123989 A JP 59123989A JP 12398984 A JP12398984 A JP 12398984A JP H0249625 B2 JPH0249625 B2 JP H0249625B2
Authority
JP
Japan
Prior art keywords
glass fibers
thread
bolt
cylindrical material
shaped molded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP59123989A
Other languages
Japanese (ja)
Other versions
JPS612536A (en
Inventor
Kazuo Shimomura
Mikio Kaneko
Fujio Aizawa
Hiroshi Yamaguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Chemical Co Ltd
Original Assignee
Sekisui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Priority to JP12398984A priority Critical patent/JPS612536A/en
Publication of JPS612536A publication Critical patent/JPS612536A/en
Publication of JPH0249625B2 publication Critical patent/JPH0249625B2/ja
Granted legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D1/00Producing articles with screw-threads
    • B29D1/005Producing articles with screw-threads fibre reinforced

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

(技術分野) 本発明はプラスチツクねじ状成形体、特に、ガ
ラス繊維で高度に補強されたプラスチツクねじ状
成形体に関する。 (従来技術) ねじ状成形体としては従来から金属ボルトや金
属ナツトが知られている。これらはねじ加工とし
ては最も生産速度の速い転造法により製作され
る。金属製ねじ状成形体は、このように高生産性
のもとで作られるが、重いうえに錆びやすいとい
う致命的な欠点を有する。これに対し、軽くて耐
蝕性に優れたプラスチツク製ねじ状成形体が生産
されている。例えば、プラスチツクボルトはプラ
スチツク材料の射出成形により得られる。射出成
形で得られるプラスチツクボルトは強度が低く、
構造締結に供し得ない。プラスチツクボルトの強
度を上げるためにガラス繊維を含有する強化プラ
スチツク材料を用いることが提案されている。し
かし、得られるプラスチツクボルトの強度は依然
として不充分であり、しかも、ねじ山表面に露出
するガラス繊維のために面摩擦が過大となりボル
ト本来の締めつけ機能を充分に果たし得ない。 (発明の目的) 本発明の目的は、軽量で耐蝕性・耐薬品性・電
気絶縁性をもち、しかも強化繊維により高度に補
強され、高締結力を有するねじ状成形体を提供す
ることにある。本発明の他の目的は締結時にねじ
山面の摩擦が小さく、ねじ山を損なわずに繰り返
し使用に耐えうるねじ状成形体を提供することに
ある。本発明の他の目的は、ねじ加工として最も
経済的な転造加工により高強度のプラスチツクね
じ状成形体を提供することにある。本発明のさら
に他の目的は、構造締結用として特に有用なプラ
スチツクねじ状成形体を提供することにある。 (発明の構成) 本発明のガラス繊維強化プラスチツクねじ状成
形体は長軸方向に配向したガラス短繊維を含有す
る熱可塑性樹脂製成形素材に転造加工によりねじ
山が形成されたねじ状成形体であつて、該ねじ山
表面に露出した該ガラス短繊維の少なくとも周囲
にフツ素樹脂層が設けられ、該フツ素樹脂層は、
スプレー塗装または焼きつけ塗装により形成さ
れ、そのことにより上記目的が達成される。上記
目的が達成される。本発明でいう「ねじ状成形
体」とはボルトやナツトなどねじ山を有する成形
体をいう。 本発明に用いられる熱可塑性樹脂にはポリアミ
ド、ポリエチレン、ポリプロピレン、ポリエチレ
ンフタレート、ポリブチレンフタレート、ポリ塩
化ビニル、ポリアセタール、ポリカーボネート、
ポリフエニレンサルフアイトなど、加熱により溶
融し冷却により固化する一般の熱可塑性樹脂が用
いられる。上記の化合物に限定される必要のない
ことはいうまでもない。 熱可塑性樹脂に混合されるガラス繊維は、熱可
塑性樹脂中へ均一に分散させるためにも、その直
径が1〜60μm、長さが0.01〜1.00mmである。た
だし、長さがこの範囲を数mm程度はずれても熱可
塑性樹脂との混練時に切断されて0.01〜1.00mmの
長さになるため、特に上記範囲に限定されること
はない。ガラス繊維の熱可塑性樹脂との接着性を
向上させるうえで、ガラス繊維表面がシランカツ
プリング剤などで処理されていてもよい。ガラス
繊維は熱可塑性樹脂100重量部に対して10〜200重
量部、好ましくは15〜150重量部の範囲で含有さ
れる。10重量部を下まわると得られるねじ状成形
体の強度が不充分である。 上記熱可塑性樹脂に、さらに必要に応じて、充
填剤、ガラス繊維と樹脂との接着性を改善する処
理剤、難燃剤、抗酸化剤などが加えられうる。こ
れらとガラス繊維とが押出成形機などを用いて混
練され、適当な大きさと形状とを有する成形素材
に成形される。例えばボルトを製造するときには
円筒状金型を用いて円柱状素材に成形される。円
柱状素材に含まれるガラス繊維はその大部分が円
柱状素材の長軸方向に配向していることが必要で
ある。具体的には円柱状素材の長軸方向に対して
±5゜以内の方向に配向するガラス繊維がガラス繊
維全体の50%以上であることが必要であり、60%
以上配向していることが好ましい。ガラス繊維の
配向度は円柱状素材を薄片に切断して顕微鏡で観
察することにより知ることができる。 ガラス繊維を円柱状素材の長軸方向に配向させ
るためには、成形法は押出成形法によることが好
ましい。射出成形によると、一般に、成形型での
樹脂の流れ速度が大きいためガラス繊維の所望の
配向が得られにくい。また、一般に、円柱状素材
成形型の断面積より樹脂注入ゲート断面積の方が
小さいため、ゲート付近でガラス繊維を含む樹脂
の流れに乱れが生じ、そのためガラス繊維がうま
く配向しない。本発明の円柱状素材を射出成形に
よつて得るには、射出成形機のゲート面積を円柱
状素材の断面積と等しいか大きくすることが必要
である。このときの注入方向は円柱状素材型の長
軸方向とすることはいうまでもない。 成形に際しては、必要に応じて、成形物の一端
にボルトに通常用いられる六角形状などの頭部が
一体形成されうる。押出成形においては、押出機
の先端にこの頭部を形成しうる金型が連結され
る。射出成形においては、頭部形状を一体的に備
えた円柱状素材型が使用される。その他に、成形
された円柱状素材を適当な長さに切断し、その一
端を再加熱して別に準備したボルト頭部を圧縮し
て付加する圧縮成形法を用いることも可能であ
る。円柱状素材の外径は最終的に得られるボルト
のサイズにより決定される。例えば、JIS M10サ
イズのボルトを得るときには直径約9mmの円柱状
素材があらかじめ準備される。 本発明のねじ状成形体のねじ加工に採用される
転造法は、格別である必要はなく、金属ねじのね
じ山成形加工に通常用いられる転造加工機械がそ
のまま適用されうる。表面にねじ山加工を施した
一対の転造ロールを同方向に回転させこの間に円
柱状素材を夾持・押出しねじ加工を行う2本ロー
ル転造機などがその例である。丸ダイス転造機、
平ダイス転造機なども用いられうる。 円柱状素材を転造機にかけると転造ダイスのね
じ山により円柱状素材にねじ山が形成される。こ
のとき、転造ダイス表面の凸部が円柱状素材の長
軸方向に配向したガラス繊維を横切るように押圧
される。そのため円柱状素材はダイス型に対応し
て変形しそこに含まれるガラス繊維のうち素材表
面付近に存在するガラス繊維が形成されたねじ山
に沿つて配向する。ガラス繊維の一部は破断し、
その端部がねじ山表面に露出する。その結果、こ
のガラス繊維露出端部の周囲にはガラス繊維を中
心とした微細なひび割れ(マイクロクラツク)が
発生し、ねじ山表面が荒れた状態になる。そのた
め、例えばナツトにボルトを締めつけるとねじ山
とナツトとの摩擦が大きく、繰り返しの締めつけ
によりいわゆる「ねじの焼き付き」現象が生じね
じ山が破壊される。摩擦が大きいため軸方向の充
分な締結力(軸力)も得られない。 本発明のねじ状成形体はこの露出したガラス繊
維の少なくとも周囲にフツ素樹脂層が設けられて
おり、このフツ素樹脂層により摩擦低減効果が得
られる。フツ素樹脂はその主鎖にパーフロロアル
キル基を有し、かつ分子末端に−COOH,−SO3
−OH,−CH=CH2,−OCOCH=CH2などの極性
基を有する分子量200〜50000の重合体である。こ
のフツ素樹脂は水または有機溶剤に分散させるこ
とができる。転造して得られたボルトの表面にフ
ツ素樹脂溶液がスプレー塗装もしくは焼きつけ塗
装されて安定な高重合体膜が形成される。フツ素
樹脂膜はボルトのねじ山表面全体にわたつて形成
されても、あるいはボルト表面の露出したガラス
繊維周囲を被覆しマイクロクラツク部に充填され
る形で形成されてもよい。ナツトにボルトを締め
つけたときボルトのねじ山面が圧力を受けて変形
し、露出ガラス繊維は比較的大きな強度で圧縮さ
れる。このとき、フツ素樹脂膜が少なくともガラ
ス繊維露出周囲に形成されていると、このガラス
繊維の周辺のマイクロクラツクにフツ素樹脂が充
填されているので、このフツ素樹脂が摩擦軽減材
として働く。したがつてねじ山とナツトとの摩擦
が小さくなる。この効果はボルトが高軸力で繰り
返し締めつけられるとき特に顕著である。高軸力
でボルトが締めつけられるとねじ山面の変形が大
きくなるがこの圧力をマイクロクラツクに充填さ
れたフツ素樹脂が露出したガラス繊維とともに優
先的に受けるためねじ山面とナツトとの摩擦が低
減される。そのためボルトを繰り返し使用しても
ねじの焼き付き現象が起こらず、したがつてねじ
山を損なうこともなく長期にわたる繰り返し使用
が可能となる。ねじ山面の摩擦が小さいためボル
トの軸力も上がる。 円柱状素材のガラス繊維が長軸方向に配向度50
%以下という不充分な配向状態で転造されると、
ガラス繊維がねじ山面に全く露出しないか、全体
が露出する。全体が露出する結果、ガラス繊維が
ねじ山面から脱落してしまう。ガラス繊維がねじ
山面から脱落した場合には、大きな凹部がねじ山
面に現れるため充分な強度が得られない。このよ
うなガラス繊維が適正に配向せず、および/もし
くはガラス繊維がねじ山から脱落したボルトにフ
ツ素樹脂膜を形成しても、上記所望ねじ山面の強
度と摩擦低減効果が同時に得られない。そのた
め、繰り返し使用にも耐え得ない。ガラス繊維と
熱可塑性樹脂との複合材料を用いて射出成形など
によりねじ山を形成したプラスチツクボルトにフ
ツ素樹脂をコーテイングしても良好な結果は得ら
れない。ガラス繊維がねじ山面に沿つて配向せ
ず、ガラス繊維の端面がねじ山の表面に露出せず
マイクロクラツクも存在しないためである。軸方
向に配向したガラス繊維を含有する素材を転造し
て得られたねじ状成形体にフツ素樹脂膜が形成さ
れたときにのみ本発明におけるフツ素樹脂膜の効
果が発揮されうる。 (実施例) 以下に本発明を実施例により説明する。 実施例 1 ナイロン6・6を100重量部とガラス繊維43重
量部とを配合した樹脂(東レ株式会社製:アミラ
ンCM3001G−30)を押出機を用いて、直径9mm
の丸棒を成形した。直径9mmの円柱状素材を形成
するために押出機の先端には内径9mmの流路を有
し、押出機の先端と内径9mmの円筒状金型を連結
するアダプターを接続した。得られた丸棒を10cm
の長さに切断し円柱状素材を得た。円柱状素材の
断面の電子顕微鏡写真をとり、軸方向±5゜以内の
方向に存在するガラス繊維の数を調べた。この軸
方向±5゜以内の配向度を有するガラス繊維がガラ
ス繊維全体に占める割合(ガラス繊維の配向度)
は95%であつた。円柱状素材を転造機を用いて転
造し、M10サイズのボルトを得た。ボルトの表面
にフツ素樹脂として四フツ化エチレンを50μmの
厚さにコーテイングし、プラスチツクボルトを得
た。プラスチツクボルトを12本製造し4本を引張
試験、8本を繰り返し締めつけ試験に供した。そ
の結果を下表に示す。各試験は下記の方法で行つ
た。試験に用いたナツトはボルトと同質の樹脂を
用い、射出成形により得られたM10サイズのナツ
トである。 引張試験 ボルトの両端にナツトを装着し、2個
のナツト間を70mmとした。ボルト両端
のナツトをオートグラフ(島津製作所
製)で5mm/min.の引張速度で引つ
張り、ボルトが破壊される直前の最大
荷重を測定し引張強度とした。 繰り返し締めつけ試験 250Kgで圧縮すると60mm
の長さとなる長さ70mmで内径12mmのバ
ネを準備した。このバネにボルトを通
し、ボルトの両端にナツトを装着し
た。バネの長さが60mmになるまでナツ
トを締めつけ、その後、バネの長さが
70mmとなるようにナツトをゆるめる操
作を1回の締めつけ操作とし、ボルト
のねじ山が潰れて締めつけが不能にな
るまでの締めつけ操作の回数を測定し
た。 実施例 2 アダプターの内径を8mmとしガラス繊維の配向
度が81%の円柱状素材を得たこと以外は実施例1
と同様である。その結果を下表に示す。 実施例 3 アダプターの内径を6.5mmとしガラス繊維の配
向度が62%の円柱状素材を得たこと以外は実施例
1と同様である。その結果を下表に示す。 比較例 1 ナイロン6・6を100重量部とガラス繊維43重
量部とを配合した樹脂(東レ株式会社製:アミラ
ンCM3001G−30)を射出成形によりM10サイズ
で長さが10cmのボルトを得た。実施例1と同様の
方法でボルトにフツ素樹脂をコーテイングし12本
のボルトを製造した。このボルトについて実施例
1と同様に試験を行つた。その結果を下表に示
す。 比較例 2 アダプターの内径を4mmとしガラス繊維の配向
度が48%の円柱状素材を得たこと以外は実施例1
と同様である。 比較例 3 ボルト表面にフツ素樹脂をコーテイングしなか
つたこと以外は実施例1と同様である。
TECHNICAL FIELD The present invention relates to a plastic thread-shaped molded body, and in particular to a plastic thread-shaped molded body highly reinforced with glass fibers. (Prior Art) Metal bolts and metal nuts have been known as thread-shaped molded bodies. These are manufactured by the rolling method, which has the fastest production speed for thread processing. Although metal screw-shaped molded bodies can be manufactured with high productivity in this way, they have the fatal disadvantage of being heavy and prone to rust. In contrast, plastic thread-shaped molded bodies that are lightweight and have excellent corrosion resistance have been produced. For example, plastic bolts are obtained by injection molding of plastic material. Plastic bolts obtained by injection molding have low strength;
It cannot be used for structural fastening. It has been proposed to use reinforced plastic materials containing glass fibers to increase the strength of plastic bolts. However, the strength of the resulting plastic bolt is still insufficient, and the surface friction caused by the glass fibers exposed on the thread surface is excessive, making it impossible for the bolt to perform its original tightening function satisfactorily. (Object of the invention) An object of the invention is to provide a thread-shaped molded body that is lightweight, has corrosion resistance, chemical resistance, and electrical insulation properties, is highly reinforced with reinforcing fibers, and has high fastening force. . Another object of the present invention is to provide a thread-shaped molded body that has low friction on the threaded surface during fastening and can withstand repeated use without damaging the threads. Another object of the present invention is to provide a high-strength plastic thread-shaped molded product by rolling, which is the most economical method for thread processing. A further object of the present invention is to provide a plastic threaded body particularly useful for structural fastening applications. (Structure of the Invention) The glass fiber-reinforced plastic screw-shaped molded article of the present invention is a screw-shaped molded article in which threads are formed by rolling on a thermoplastic resin molded material containing short glass fibers oriented in the longitudinal direction. A fluororesin layer is provided at least around the short glass fibers exposed on the thread surface, and the fluororesin layer comprises:
It is formed by spray painting or baking, thereby achieving the above object. The above objectives are achieved. The term "thread-shaped molded body" as used in the present invention refers to a molded body having a thread such as a bolt or a nut. Thermoplastic resins used in the present invention include polyamide, polyethylene, polypropylene, polyethylene phthalate, polybutylene phthalate, polyvinyl chloride, polyacetal, polycarbonate,
A general thermoplastic resin such as polyphenylene sulfite, which melts when heated and solidifies when cooled, is used. It goes without saying that there is no need to be limited to the above compounds. The glass fibers to be mixed into the thermoplastic resin have a diameter of 1 to 60 μm and a length of 0.01 to 1.00 mm in order to be uniformly dispersed in the thermoplastic resin. However, even if the length deviates from this range by several mm, the length will be cut during kneading with the thermoplastic resin to a length of 0.01 to 1.00 mm, so it is not particularly limited to the above range. In order to improve the adhesion of the glass fiber to the thermoplastic resin, the surface of the glass fiber may be treated with a silane coupling agent or the like. The glass fiber is contained in an amount of 10 to 200 parts by weight, preferably 15 to 150 parts by weight, based on 100 parts by weight of the thermoplastic resin. When the amount is less than 10 parts by weight, the strength of the thread-shaped molded product obtained is insufficient. If necessary, a filler, a treatment agent for improving the adhesion between the glass fiber and the resin, a flame retardant, an antioxidant, and the like may be added to the thermoplastic resin. These and glass fibers are kneaded using an extruder or the like to form a molding material having an appropriate size and shape. For example, when manufacturing a bolt, a cylindrical mold is used to mold the bolt into a cylindrical material. Most of the glass fibers contained in the cylindrical material must be oriented in the longitudinal direction of the cylindrical material. Specifically, 50% or more of the total glass fibers must be oriented within ±5° with respect to the long axis direction of the cylindrical material, and 60%
It is preferable that the orientation is as follows. The degree of orientation of glass fibers can be determined by cutting a cylindrical material into thin sections and observing them under a microscope. In order to orient the glass fibers in the long axis direction of the cylindrical material, the extrusion molding method is preferably used as the molding method. According to injection molding, it is generally difficult to obtain the desired orientation of the glass fibers because the flow rate of the resin in the mold is high. Furthermore, since the cross-sectional area of the resin injection gate is generally smaller than the cross-sectional area of the cylindrical material mold, the flow of the resin containing glass fibers is disturbed near the gate, so that the glass fibers are not properly oriented. In order to obtain the cylindrical material of the present invention by injection molding, it is necessary to make the gate area of the injection molding machine equal to or larger than the cross-sectional area of the cylindrical material. Needless to say, the injection direction at this time is the long axis direction of the cylindrical material. When molding, if necessary, a hexagonal head, such as a hexagonal head commonly used for bolts, may be integrally formed at one end of the molded product. In extrusion molding, a mold capable of forming this head is connected to the tip of an extruder. In injection molding, a cylindrical blank mold having an integral head shape is used. Alternatively, it is also possible to use a compression molding method in which a molded cylindrical material is cut to an appropriate length, one end of which is reheated, and a separately prepared bolt head is compressed and added. The outer diameter of the cylindrical material is determined by the size of the final bolt. For example, when obtaining a JIS M10 size bolt, a cylindrical material with a diameter of about 9 mm is prepared in advance. The rolling method adopted for threading the thread-shaped molded body of the present invention does not need to be special, and a rolling machine commonly used for thread forming of metal screws can be applied as is. An example is a two-roll rolling machine that rotates a pair of rolling rolls with threaded surfaces in the same direction to hold and extrude a cylindrical material to perform threading. round die rolling machine,
A flat die rolling machine or the like may also be used. When a cylindrical material is run through a rolling machine, threads are formed on the cylindrical material by the threads of the rolling die. At this time, the convex portion on the surface of the rolling die is pressed so as to cross the glass fibers oriented in the longitudinal direction of the cylindrical material. Therefore, the cylindrical material deforms in accordance with the die shape, and among the glass fibers contained therein, the glass fibers present near the surface of the material are oriented along the formed thread. Some of the glass fibers break,
Its ends are exposed on the thread surface. As a result, microcracks centering around the glass fibers occur around the exposed end of the glass fibers, and the thread surface becomes rough. Therefore, for example, when a bolt is tightened to a nut, there is a large friction between the threads and the nut, and repeated tightening causes a so-called "thread seizure" phenomenon, which destroys the threads. Because of the large friction, sufficient axial fastening force (axial force) cannot be obtained. In the thread-shaped molded article of the present invention, a fluororesin layer is provided at least around the exposed glass fibers, and this fluororesin layer provides a friction reducing effect. Fluororesin has a perfluoroalkyl group in its main chain, and -COOH, -SO 3 ,
It is a polymer with a molecular weight of 200 to 50,000 and has polar groups such as -OH, -CH= CH2 , and -OCOCH= CH2 . This fluororesin can be dispersed in water or an organic solvent. A fluororesin solution is spray-painted or baked onto the surface of the bolt obtained by rolling to form a stable high polymer film. The fluororesin film may be formed over the entire thread surface of the bolt, or may be formed to cover the exposed glass fibers on the bolt surface and fill the micro-crack portion. When a bolt is tightened into a nut, the threaded surface of the bolt is deformed under pressure, and the exposed glass fibers are compressed with relatively high strength. At this time, if a fluororesin film is formed at least around the exposed glass fibers, the microcracks around the glass fibers are filled with fluororesin, and this fluororesin acts as a friction reducing material. . Therefore, the friction between the thread and the nut is reduced. This effect is particularly noticeable when the bolt is repeatedly tightened with high axial forces. When a bolt is tightened with high axial force, the deformation of the thread surface becomes large, but this pressure is preferentially received by the fluororesin filled in the microcrack along with the exposed glass fibers, which causes friction between the thread surface and the nut. is reduced. Therefore, even if the bolt is used repeatedly, the bolt does not seize, and therefore can be used repeatedly over a long period of time without damaging the threads. Since the friction on the threaded surface is small, the axial force of the bolt also increases. The cylindrical material glass fiber has a degree of orientation of 50 in the long axis direction.
When rolled in an insufficiently oriented state of less than %,
No or all glass fibers are exposed on the thread surface. As a result of the entire surface being exposed, the glass fibers fall off the threaded surface. If the glass fibers fall off from the threaded surface, large recesses will appear on the threaded surface, making it impossible to obtain sufficient strength. Even if such glass fibers are not properly oriented and/or a fluororesin film is formed on a bolt where the glass fibers have fallen off the threads, the desired thread surface strength and friction reduction effect cannot be obtained at the same time. do not have. Therefore, it cannot withstand repeated use. Good results cannot be obtained even if a plastic bolt whose threads are formed by injection molding or the like using a composite material of glass fiber and thermoplastic resin is coated with fluororesin. This is because the glass fibers are not oriented along the thread surface, the end faces of the glass fibers are not exposed on the thread surface, and there are no microcracks. The effect of the fluororesin film in the present invention can be exhibited only when the fluororesin film is formed on a thread-shaped molded product obtained by rolling a material containing glass fibers oriented in the axial direction. (Example) The present invention will be explained below with reference to Examples. Example 1 A resin (Amiran CM3001G-30 manufactured by Toray Industries, Inc.) containing 100 parts by weight of nylon 6.6 and 43 parts by weight of glass fiber was made into a resin with a diameter of 9 mm using an extruder.
A round bar was formed. In order to form a cylindrical material with a diameter of 9 mm, the tip of the extruder had a flow path with an inner diameter of 9 mm, and an adapter was connected to connect the tip of the extruder with a cylindrical mold with an inner diameter of 9 mm. The obtained round bar is 10cm
A cylindrical material was obtained by cutting to length. An electron micrograph of a cross section of the cylindrical material was taken, and the number of glass fibers present within ±5° in the axial direction was determined. Percentage of glass fibers with a degree of orientation within ±5° in the axial direction of the total glass fibers (degree of orientation of glass fibers)
was 95%. A cylindrical material was rolled using a rolling machine to obtain an M10 size bolt. The surface of the bolt was coated with tetrafluoroethylene as a fluororesin to a thickness of 50 μm to obtain a plastic bolt. Twelve plastic bolts were manufactured, four were subjected to a tensile test, and eight were subjected to a repeated tightening test. The results are shown in the table below. Each test was conducted in the following manner. The nut used in the test was an M10 size nut obtained by injection molding using the same resin as the bolt. Tensile test Nuts were attached to both ends of the bolt, and the distance between the two nuts was 70 mm. The nuts at both ends of the bolt were pulled using an Autograph (manufactured by Shimadzu Corporation) at a tensile speed of 5 mm/min. The maximum load immediately before the bolt was broken was measured and determined as the tensile strength. Repeated tightening test 60mm when compressed with 250Kg
A spring with a length of 70 mm and an inner diameter of 12 mm was prepared. I put a bolt through this spring and attached nuts to both ends of the bolt. Tighten the nut until the spring length is 60mm, then
Loosening the nut to 70 mm was considered one tightening operation, and the number of tightening operations until the bolt thread was crushed and tightening became impossible was measured. Example 2 Example 1 except that the inner diameter of the adapter was 8 mm and a cylindrical material with a glass fiber orientation of 81% was obtained.
It is similar to The results are shown in the table below. Example 3 The same as Example 1 except that the inner diameter of the adapter was 6.5 mm and a cylindrical material with a glass fiber orientation of 62% was obtained. The results are shown in the table below. Comparative Example 1 A bolt with an M10 size and a length of 10 cm was obtained by injection molding a resin (Amiran CM3001G-30 manufactured by Toray Industries, Inc.) containing 100 parts by weight of nylon 6.6 and 43 parts by weight of glass fiber. Bolts were coated with fluororesin in the same manner as in Example 1 to produce 12 bolts. This bolt was tested in the same manner as in Example 1. The results are shown in the table below. Comparative Example 2 Example 1 except that the inner diameter of the adapter was 4 mm and a cylindrical material with a glass fiber orientation of 48% was obtained.
It is similar to Comparative Example 3 Same as Example 1 except that the bolt surface was not coated with fluororesin.

【表】 (発明の効果) 本発明のねじ状成形体は、このように、ガラス
繊維により高度に補強され、高強度・高締結力を
有する。締結時にねじ山面の摩擦が小さいためね
じ山が損なわれず繰り返しの締結に耐えうる。軽
量で耐蝕性・耐薬品性・電気絶縁性というプラス
チツク本来の特徴をも有する。このねじ状成形体
はねじ加工として最も経済的な転造加工により製
造される。このようにして得られたねじ状成形体
は、構造締結用に特に有用である。
[Table] (Effects of the Invention) The thread-shaped molded article of the present invention is thus highly reinforced with glass fibers and has high strength and high fastening force. Since there is little friction on the thread surface during fastening, the threads are not damaged and can withstand repeated fastening. It also has the inherent characteristics of plastic, such as being lightweight, corrosion resistant, chemical resistant, and electrically insulating. This thread-shaped molded body is manufactured by rolling, which is the most economical method for thread processing. The thread-shaped molded body thus obtained is particularly useful for structural fastening.

Claims (1)

【特許請求の範囲】 1 長軸方向に配向したガラス短繊維を含有する
熱可塑性樹脂製成形素材に転造加工によりねじ山
が形成されたねじ状成形体であつて、 該ねじ山表面に露出した該ガラス短繊維の少な
くとも周囲にフツ素樹脂層が設けられ、 該フツ素樹脂層が、スプレー塗装または焼きつ
け塗装により形成される、 ガラス繊維強化プラスチツクねじ状成形体。
[Scope of Claims] 1. A thread-shaped molded article in which threads are formed by rolling on a thermoplastic resin molding material containing short glass fibers oriented in the longitudinal direction, the threads being exposed on the surface of the threads. A fluororesin layer is provided at least around the short glass fibers, and the fluororesin layer is formed by spray painting or baking.
JP12398984A 1984-06-15 1984-06-15 Glass fiber reinforced plastic screwy molded shape Granted JPS612536A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12398984A JPS612536A (en) 1984-06-15 1984-06-15 Glass fiber reinforced plastic screwy molded shape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12398984A JPS612536A (en) 1984-06-15 1984-06-15 Glass fiber reinforced plastic screwy molded shape

Publications (2)

Publication Number Publication Date
JPS612536A JPS612536A (en) 1986-01-08
JPH0249625B2 true JPH0249625B2 (en) 1990-10-30

Family

ID=14874284

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12398984A Granted JPS612536A (en) 1984-06-15 1984-06-15 Glass fiber reinforced plastic screwy molded shape

Country Status (1)

Country Link
JP (1) JPS612536A (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60199634A (en) * 1984-03-23 1985-10-09 Sekisui Chem Co Ltd Screw-shaped plastic molding with film containing fluorine and manufacture thereof

Also Published As

Publication number Publication date
JPS612536A (en) 1986-01-08

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