JPH0256380B2 - - Google Patents
Info
- Publication number
- JPH0256380B2 JPH0256380B2 JP13437582A JP13437582A JPH0256380B2 JP H0256380 B2 JPH0256380 B2 JP H0256380B2 JP 13437582 A JP13437582 A JP 13437582A JP 13437582 A JP13437582 A JP 13437582A JP H0256380 B2 JPH0256380 B2 JP H0256380B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- correction
- correction fluid
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002989 correction material Substances 0.000 claims description 15
- 229920001971 elastomer Polymers 0.000 claims description 10
- 239000005060 rubber Substances 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 17
- 238000000576 coating method Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- -1 aromatics Substances 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D10/00—Correcting fluids, e.g. fluid media for correction of typographical errors by coating
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
【発明の詳細な説明】
本発明は、筆記或は印字された文字等の上に塗
布しそれらを隠ぺいする型式の修正液に関するも
のであり、水性インキ、油性インキ、タイプライ
ターリボン用インキ、スタンプインキ、PPCト
ナー等あらゆる筆記、印字用インキを問わず使用
可能であり、紙に対する接着力が強く表面平滑性
に優れ均一な修正塗膜を作ることを特徴とする修
正液に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a type of correction fluid that is applied to written or printed characters to hide them, and includes water-based inks, oil-based inks, typewriter ribbon inks, and stamp inks. This correction liquid can be used with any writing or printing ink such as ink or PPC toner, and is characterized by its strong adhesion to paper, excellent surface smoothness, and the creation of a uniform correction coating.
従来、修正液としては、水性型と油性型の二つ
のタイプがあり、前者は水溶性樹脂を結合剤と
し、溶剤である水には溶け出さない油性インキ用
修正液として使用され、一方、後者は油溶性樹脂
を結合剤とし、それを溶かす溶剤には溶け出さな
い水性インキ用修正液として使用されてきた。し
かし使用者側からすると、これら二つのタイプの
使い分けは非常に煩雑であり、特に水性型の場合
には塗布した後の乾燥性が悪く使いづらいという
欠点があつた。そこで、近年筆記具がますます多
様化するに伴ない上記の水性型、油性型の使い分
けが不要な、つまり水性、油性インキ共用タイプ
の、“万能型”と称する修正液が出現するに至つ
た。一般に筆記、印字用インキ成分は染料、顔料
等の着色剤、樹脂類等の結合剤、界面活性剤等の
油脂類、さらにこれらをよく溶解、展開する為の
アルコール類、ケトン類、エステル類、エーテル
類、クロライド類、アミン類、芳香族類及び水等
の比較的極性の高い溶剤から成るのに対し、“万
能型”の修正液はこれらのインキを溶かし、着色
成分を修正塗膜上に浮き上がらせないような脂肪
族系、またはナフテン系炭化水素等の非常に極性
の低い溶剤を使用しなければならず、従つて上記
溶剤に溶解しうる樹脂の種類は極端に制限され、
更にその中から修正液の結合剤としての顔料であ
る酸化チタンに対する分散能、修正塗膜の特性、
溶液粘度等の性質を充分に兼ねそなえた樹脂を選
択することは非常に困難であつた。 Conventionally, there are two types of correction fluid: water-based and oil-based.The former uses water-soluble resin as a binder and is used as a correction fluid for oil-based inks that does not dissolve in water, which is a solvent. has been used as a correction fluid for water-based inks that uses oil-soluble resin as a binder and does not dissolve in solvents that dissolve it. However, from the user's perspective, it is very complicated to distinguish between these two types, and in particular, the water-based type has the drawback of poor drying properties after application, making it difficult to use. Therefore, in recent years, as writing instruments have become more and more diverse, correction fluids called "universal type" have emerged that do not require the use of water-based and oil-based types, that is, can be used with both water-based and oil-based inks. In general, writing and printing ink components include colorants such as dyes and pigments, binders such as resins, oils and fats such as surfactants, alcohols, ketones, esters, etc. to dissolve and spread these well. Comprised of relatively polar solvents such as ethers, chlorides, amines, aromatics, and water, "all-purpose" correction fluids dissolve these inks and transfer colored components onto the correction coating. Very low polarity solvents such as aliphatic or naphthenic hydrocarbons that do not float must be used, and the types of resins that can be dissolved in these solvents are therefore extremely limited.
In addition, we investigated the dispersibility of titanium oxide, which is a pigment used as a binder in correction fluid, the characteristics of correction coatings,
It has been extremely difficult to select a resin that has sufficient properties such as solution viscosity.
現在、この既存の“万能型”修正液に用いられ
ている結合剤の主成分としては、ある類のスチレ
ンブタジエンエラストマーがあるが、これを結合
剤主成分とした場合には、塗布後の修正塗膜のレ
ベリング性（塗布後の塗膜の平滑性）が悪く刷毛
むらやナシハダ状になり、また被膜硬度が柔かす
ぎる為、塗膜の上から筆記具などによる再書き込
みが困難で、また紙との接着が悪いなどの欠点が
あつた。そこで本発明者は、この“万能型”修正
液について鋭意研究の結果、脂肪族系、またはナ
フテン系炭化水素を主成分とする溶剤及び酸化チ
タンの系に於いて、結合剤主成分として環化ゴム
を用いることにより上記欠点を充分に解消出来う
ることを突き止めたのである。環化ゴムを結合主
成分として用いた場合には、酸化チタンに対する
分散能が大きく、溶液粘度が良好で塗布時のレベ
リング性が良いため平滑で均一な修正塗膜が得ら
れ、その上紙との接着も非常に強く、修正液とし
て要求されるすべての条件を充分に満足出来るも
のである。また、上記環化ゴムの結合助剤として
塗膜強度の微調整の為に、環化ゴムと相溶性があ
り、上記溶剤に可溶なブタジエンゴム、ブチルゴ
ム、スチレンブタジエンエラストマー、エチレン
プロピレンゴム等を併用しても良い。その際の添
加量は環化ゴムに対し40重量％未満が最適であ
る。 Currently, the main component of the binder used in this existing "universal" correction fluid is a type of styrene-butadiene elastomer, but if this is used as the main component of the binder, it will be difficult to correct the problem after application. The leveling properties of the paint film (smoothness of the paint film after application) are poor, resulting in uneven brushing and flaking, and the hardness of the film is too soft, making it difficult to rewrite on top of the paint film with a writing instrument. There were drawbacks such as poor adhesion. As a result of intensive research into this "universal" correction fluid, the present inventor found that in a system containing aliphatic or naphthenic hydrocarbon-based solvents and titanium oxide, cyclized as the main component of the binder. It was discovered that the above drawbacks could be sufficiently overcome by using rubber. When cyclized rubber is used as the main bonding component, it has a high dispersion ability for titanium oxide, good solution viscosity, and good leveling properties during application, resulting in a smooth and uniform correction coating. The adhesion is also very strong and satisfies all the requirements for a correction fluid. In addition, as a bonding agent for the cyclized rubber, butadiene rubber, butyl rubber, styrene-butadiene elastomer, ethylene propylene rubber, etc., which are compatible with the cyclized rubber and soluble in the above solvent, are used to finely adjust the strength of the coating film. May be used together. In this case, the optimum amount of addition is less than 40% by weight based on the cyclized rubber.
尚、上記脂肪族系、またはナフテン系炭化水素
としてはｎ−ヘキサン、ｎ−ヘプタン、オクタ
ン、イソオクタン、シクロヘキサン、メチルシク
ロヘキサン、エチルシクロヘキサン、シクロヘプ
タン等が挙げられる。 The aliphatic or naphthenic hydrocarbons include n-hexane, n-heptane, octane, isooctane, cyclohexane, methylcyclohexane, ethylcyclohexane, cycloheptane, and the like.
以下、本発明を実施例を挙げて説明する。 Hereinafter, the present invention will be explained by giving examples.
実施例 １
シクロヘキサン36重量部に環化ゴム5.6重量部
とブタジエンゴム1.4重量部を溶かした溶液に酸
化チタン45重量部とｎ−ヘプタン12重量部を加
え、ボールミルにて12時間粉砕、分散させて作成
した。このようにして調整した修正液は水性イン
キ、油性インキ、タイプライターリボン用イン
キ、スタンプインキ、PPCトナー等あらゆる筆
記、印字用インキに対してその修正文字インキ中
の着色剤を浮き上がらせることなく、隠ぺい被覆
し、またレベリング性も良好で平滑で均一でしか
も紙との接着の強い修正塗膜が得られた。Example 1 45 parts by weight of titanium oxide and 12 parts by weight of n-heptane were added to a solution of 5.6 parts by weight of cyclized rubber and 1.4 parts by weight of butadiene rubber dissolved in 36 parts by weight of cyclohexane, and the mixture was ground and dispersed in a ball mill for 12 hours. Created. The correction liquid prepared in this way can be applied to all kinds of writing and printing inks such as water-based ink, oil-based ink, typewriter ribbon ink, stamp ink, and PPC toner without lifting the colorant in the correction character ink. A repair coating was obtained that had good concealment coverage and good leveling properties, was smooth and uniform, and had strong adhesion to paper.
実施例 ２
シクロヘキサン35重量部とメチルシクロヘキサ
ン10重量部に環化ゴム６重量部とスチレンブタジ
エンエラストマー0.5重量部を溶かした溶液に酸
化チタン40重量部とイソオクタン8.5重量部を加
えボールミルにて12時間粉砕、分散あせて作成し
た。このようにして調整した修正液は実施例１と
同様優れた修正塗膜特性をもつものであつた。Example 2 40 parts by weight of titanium oxide and 8.5 parts by weight of isooctane were added to a solution of 6 parts by weight of cyclized rubber and 0.5 parts by weight of styrene-butadiene elastomer dissolved in 35 parts by weight of cyclohexane and 10 parts by weight of methylcyclohexane, and the mixture was ground in a ball mill for 12 hours. , hastily created distributed. The correction fluid thus prepared had excellent correction coating properties similar to those of Example 1.
実施例 ３
シクロヘキサン40重量部に環化ゴム6.5重量部
とエチレンプロピレンゴム1.5重量部を溶かした
溶液に酸化チタン47重量部とｎ−ヘキサン５重量
部を加え、アトライターにて５時間粉砕、分散さ
せて作成した。このようにして調整した修正液は
実施例１と同様優れた修正塗膜特性をもつもので
あつた。Example 3 47 parts by weight of titanium oxide and 5 parts by weight of n-hexane were added to a solution of 6.5 parts by weight of cyclized rubber and 1.5 parts by weight of ethylene propylene rubber in 40 parts by weight of cyclohexane, and the mixture was pulverized and dispersed in an attritor for 5 hours. I made it. The correction fluid thus prepared had excellent correction coating properties similar to those of Example 1.
実施例 ４
シクロヘキサン40重量部に環化ゴム９重量部を
溶かした溶液に酸化チタン40重量部とオクタン11
重量部を加えボールミルにて12時間粉砕、分散さ
せて作成した。このようにして調整した修正液は
実施例１と同様優れた修正塗膜特性をもつもので
あつた。Example 4 40 parts by weight of titanium oxide and 11 parts by weight of octane were added to a solution of 9 parts by weight of cyclized rubber dissolved in 40 parts by weight of cyclohexane.
Parts by weight were added, and the mixture was ground and dispersed in a ball mill for 12 hours. The correction fluid thus prepared had excellent correction coating properties similar to those of Example 1.
以上のように本発明は紙に対する接着力が強
く、表面平滑性に優れ、均一な塗膜の万能型修正
液を与えるものである。 As described above, the present invention provides a versatile correction fluid that has strong adhesion to paper, excellent surface smoothness, and a uniform coating.
Claims (1)
またはナフテン系炭化水素を主成分とする溶剤及
び酸化チタンを構成主成分とすることを特徴とす
る修正液の組成物。1 Binder based on cyclized rubber, aliphatic type,
Alternatively, a composition of a correction fluid characterized by comprising a solvent containing a naphthenic hydrocarbon as a main component and titanium oxide as a main component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13437582A JPS5924765A (en) | 1982-07-30 | 1982-07-30 | Ink eraser composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13437582A JPS5924765A (en) | 1982-07-30 | 1982-07-30 | Ink eraser composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5924765A JPS5924765A (en) | 1984-02-08 |
| JPH0256380B2 true JPH0256380B2 (en) | 1990-11-30 |
Family
ID=15126916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13437582A Granted JPS5924765A (en) | 1982-07-30 | 1982-07-30 | Ink eraser composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5924765A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5199976A (en) * | 1991-06-13 | 1993-04-06 | The Gillette Company | Ozone-friendly correction fluid |
| US5332599A (en) * | 1993-07-19 | 1994-07-26 | The Gillette Company | Aqueous correction fluid |
-
1982
- 1982-07-30 JP JP13437582A patent/JPS5924765A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5924765A (en) | 1984-02-08 |
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