JPH0264510A - coated optical fiber - Google Patents
coated optical fiberInfo
- Publication number
- JPH0264510A JPH0264510A JP63214819A JP21481988A JPH0264510A JP H0264510 A JPH0264510 A JP H0264510A JP 63214819 A JP63214819 A JP 63214819A JP 21481988 A JP21481988 A JP 21481988A JP H0264510 A JPH0264510 A JP H0264510A
- Authority
- JP
- Japan
- Prior art keywords
- optical fiber
- coated optical
- resin
- polymerization initiator
- polymn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013307 optical fiber Substances 0.000 title claims abstract description 37
- 229920005989 resin Polymers 0.000 claims abstract description 48
- 239000011347 resin Substances 0.000 claims abstract description 48
- 239000011247 coating layer Substances 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
- 125000004437 phosphorous atom Chemical group 0.000 claims abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 3
- 239000003505 polymerization initiator Substances 0.000 claims description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 18
- 239000003085 diluting agent Substances 0.000 claims description 11
- 125000004429 atom Chemical group 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 239000003999 initiator Substances 0.000 abstract description 7
- 230000001678 irradiating effect Effects 0.000 abstract description 4
- 238000003776 cleavage reaction Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 230000007017 scission Effects 0.000 abstract description 3
- XVKKIGYVKWTOKG-UHFFFAOYSA-N diphenylphosphoryl(phenyl)methanone Chemical compound C=1C=CC=CC=1P(=O)(C=1C=CC=CC=1)C(=O)C1=CC=CC=C1 XVKKIGYVKWTOKG-UHFFFAOYSA-N 0.000 abstract description 2
- 238000012681 fiber drawing Methods 0.000 abstract 2
- -1 2-hydroxypropyl Chemical group 0.000 description 11
- 239000000835 fiber Substances 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- KKKOPDOQTDPTRH-UHFFFAOYSA-N dimethylphosphoryl(phenyl)methanone Chemical compound CP(C)(=O)C(=O)C1=CC=CC=C1 KKKOPDOQTDPTRH-UHFFFAOYSA-N 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- VCQYDZJGTXAFRL-UHFFFAOYSA-N s-phenyl benzenecarbothioate Chemical compound C=1C=CC=CC=1C(=O)SC1=CC=CC=C1 VCQYDZJGTXAFRL-UHFFFAOYSA-N 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- UEKQIWJSTOZWEA-UHFFFAOYSA-N (2,4-dimethylphenyl)-dimethylphosphorylmethanone Chemical compound CC1=CC=C(C(=O)P(C)(C)=O)C(C)=C1 UEKQIWJSTOZWEA-UHFFFAOYSA-N 0.000 description 1
- MLVHFGDCDCGKSB-UHFFFAOYSA-N (2,4-dimethylphenyl)-diphenylphosphorylmethanone Chemical compound CC1=CC(C)=CC=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MLVHFGDCDCGKSB-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- DYBIGIADVHIODH-UHFFFAOYSA-N 2-nonylphenol;oxirane Chemical compound C1CO1.CCCCCCCCCC1=CC=CC=C1O DYBIGIADVHIODH-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- KEJXDPOZJBGYOI-UHFFFAOYSA-N CC1=CC(=C(C=C1)SC2=C(C=C(C=C2)C)C(=O)C3=CC=CC=C3)C(=O)C4=CC=CC=C4 Chemical compound CC1=CC(=C(C=C1)SC2=C(C=C(C=C2)C)C(=O)C3=CC=CC=C3)C(=O)C4=CC=CC=C4 KEJXDPOZJBGYOI-UHFFFAOYSA-N 0.000 description 1
- ALBFVSBDBUILIW-UHFFFAOYSA-N CC1=CC=C(C=C1)C(=O)C2=CC=CC=C2SC3=CC=CC=C3C(=O)C4=CC=C(C=C4)C Chemical compound CC1=CC=C(C=C1)C(=O)C2=CC=CC=C2SC3=CC=CC=C3C(=O)C4=CC=C(C=C4)C ALBFVSBDBUILIW-UHFFFAOYSA-N 0.000 description 1
- MBOMKPHWZFGUPS-UHFFFAOYSA-N CC1=CC=CC=C1C(=O)C2=CC=CC=C2SC3=CC=CC=C3C(=O)C4=CC=CC=C4C Chemical compound CC1=CC=CC=C1C(=O)C2=CC=CC=C2SC3=CC=CC=C3C(=O)C4=CC=CC=C4C MBOMKPHWZFGUPS-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- FPODCVUTIPDRTE-UHFFFAOYSA-N bis(prop-2-enyl) hexanedioate Chemical compound C=CCOC(=O)CCCCC(=O)OCC=C FPODCVUTIPDRTE-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- DVNSSYMAASOKKW-UHFFFAOYSA-N diethylphosphoryl(phenyl)methanone Chemical compound CCP(=O)(CC)C(=O)C1=CC=CC=C1 DVNSSYMAASOKKW-UHFFFAOYSA-N 0.000 description 1
- JUWZXMSETNUPAW-UHFFFAOYSA-N diethylphosphoryl-(2,4-dimethylphenyl)methanone Chemical compound CCP(=O)(CC)C(=O)C1=CC=C(C)C=C1C JUWZXMSETNUPAW-UHFFFAOYSA-N 0.000 description 1
- URFIOHKIVRMKKR-UHFFFAOYSA-N diethylphosphoryl-(2-methylphenyl)methanone Chemical compound CCP(=O)(CC)C(=O)C1=CC=CC=C1C URFIOHKIVRMKKR-UHFFFAOYSA-N 0.000 description 1
- GVZWVCMTOCTDMO-UHFFFAOYSA-N dimethylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=C(C(=O)P(C)(C)=O)C(C)=C1 GVZWVCMTOCTDMO-UHFFFAOYSA-N 0.000 description 1
- CZCLNTFOGUHVEY-UHFFFAOYSA-N dimethylphosphoryl-(2-methylphenyl)methanone Chemical compound CC1=CC=CC=C1C(=O)P(C)(C)=O CZCLNTFOGUHVEY-UHFFFAOYSA-N 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- HZWAUDKTZOUQPD-UHFFFAOYSA-N diphenylphosphoryl-(2-methylphenyl)methanone Chemical compound CC1=CC=CC=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 HZWAUDKTZOUQPD-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- DFENKTCEEGOWLB-UHFFFAOYSA-N n,n-bis(methylamino)-2-methylidenepentanamide Chemical compound CCCC(=C)C(=O)N(NC)NC DFENKTCEEGOWLB-UHFFFAOYSA-N 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005304 optical glass Substances 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Landscapes
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用公費〉
本発明は、光ファイバの外周に、例えば紫外線等のエネ
ルギー線によって硬化した被覆層を形成、した被覆光フ
ァイバに関する。DETAILED DESCRIPTION OF THE INVENTION <Public Expenses for Industrial Use> The present invention relates to a coated optical fiber in which a coating layer cured by energy rays such as ultraviolet rays is formed on the outer periphery of the optical fiber.
〈従来の技術〉
光通信に用いる光ファイバにおいては、光学ガラスファ
イバ、石英系ガラスファイバに限らず、いずれもファイ
バ化した後直ちにその外周にプラスチック被覆を施こす
ことが好ましいとされている。これは、ファイバ化され
ることにより発生するファイバ表面のキズや、裸ファイ
バの状態で空気中に曝されることによるクラックの成長
で、ファイバの強度が劣化するのを防ぐためである。こ
のようなプラスチック層としては、一般に熱硬化型のシ
リコーン樹脂の他、紫外線硬化型樹脂（以下「ＵＶ樹脂
」という）、放射線硬化型樹脂等のエネルギー線硬化型
樹脂が用いられており、近年は特にとのＵＶ樹脂被覆光
ファイバの需要が増大している。<Prior Art> In optical fibers used for optical communications, it is considered preferable to immediately apply a plastic coating to the outer periphery of any optical fiber, not only optical glass fiber or quartz-based glass fiber, after being made into a fiber. This is to prevent the strength of the fiber from deteriorating due to scratches on the surface of the fiber that occur when the fiber is made into a fiber, or cracks that grow when the bare fiber is exposed to the air. In addition to thermosetting silicone resins, energy ray curable resins such as ultraviolet ray curable resins (hereinafter referred to as "UV resins") and radiation curable resins are generally used for such plastic layers. In particular, demand for UV resin-coated optical fibers is increasing.
かかるＵＶＩＩ脂被覆光ファイバは、例えば線引炉によ
秒線引きされた光ファイバにコーティングダイスにより
連続的にＵＶＩＩ脂を塗布し、続いて紫外線を照射して
塗布されたＵＶ樹脂を硬化させることにより製造される
。また、このようなＵＶＩＩ脂被覆光ファイバはさらに
単独で又は複数本台せて二次被覆を施されろことにより
光フアイバ心線とされる。Such a UVII resin-coated optical fiber can be produced, for example, by continuously applying UVII resin using a coating die to an optical fiber that has been drawn in a drawing furnace, and then curing the applied UV resin by irradiating it with ultraviolet rays. Manufactured. Further, such UVII fat-coated optical fibers can be further coated with a secondary coating either singly or in combination to form optical fiber cores.
〈発明が解決しようとする課題〉
前述しなＵＶ樹脂は比較的短時間で硬化する性質を有し
ているが、より生産性を高めるために、樹脂特性を維持
しながら硬化速度はできるだけ高める改良がなされてい
る。従来においては、光開始剤の種類や量を変える方法
や光増感剤を使用する方法が検討されている（特開昭５
５−１５４７１号公報、特公昭６０−８０４７号公報）
が、より簡便に硬化速度を高めろ方法の出現が要望され
ている。<Problem to be solved by the invention> The UV resin described above has the property of curing in a relatively short time, but in order to further increase productivity, improvements have been made to increase the curing speed as much as possible while maintaining the resin properties. is being done. Conventionally, methods of changing the type and amount of photoinitiators and methods of using photosensitizers have been studied (Japanese Patent Laid-Open No.
5-15471, Special Publication No. 60-8047)
However, there is a need for a method to increase the curing speed more easily.
本発明はこのような事情に鑑み、硬化速度の向上により
短時間で要求される物性を得るようにして生産性を向上
させた被覆光ファイバを提供することを目的とする。In view of these circumstances, an object of the present invention is to provide a coated optical fiber that can obtain required physical properties in a short time by increasing the curing speed, thereby improving productivity.
く課題を解決するための手段〉
前記目的を達成する本発明にかかる被覆光ファイバは、
光ファイバの外周にエネルギー線硬化型樹脂を塗布し、
エネルギー線の照射により硬化させて被覆層を施してな
る被覆光ファイバにおいて、上記エネルギー線硬化型樹
脂が、エネルギー線の照射により当該樹脂内の異種原子
間単結合を開裂させる重合開始剤を含有することを特徴
とする。Means for Solving the Problems〉 The coated optical fiber according to the present invention that achieves the above object has the following features:
Apply energy ray-curable resin to the outer circumference of the optical fiber,
In a coated optical fiber formed by applying a coating layer by curing by irradiation with energy rays, the energy ray-curable resin contains a polymerization initiator that cleaves single bonds between different atoms in the resin upon irradiation with energy rays. It is characterized by
本発明に用いるエネルギー線硬化型樹脂は、好適にはア
クリル若しくはメタクリルオリゴ７−と、反応性希釈剤
と、重合開始剤とを必須成分とするものがよいが、これ
に限定サレず、要はエネルギー線の照射により硬化する
ものであればよく、さらに必要に応じてアクリル樹脂、
ポリアミド樹脂、ポリエーテル樹脂、ポリウレタン樹脂
、ポリアミドイミド樹脂、シリコーン樹脂、フェノール
樹脂などの各種の変性用樹脂や、有機ケイ素化合物、界
面活性剤などの各種添加剤を配合してもよい。The energy ray-curable resin used in the present invention preferably contains acrylic or methacrylic oligo 7-, a reactive diluent, and a polymerization initiator as essential components, but is not limited to these, and the key points are Any material that can be cured by irradiation with energy rays may be used, and if necessary, acrylic resin,
Various modifying resins such as polyamide resin, polyether resin, polyurethane resin, polyamideimide resin, silicone resin, and phenol resin, and various additives such as organosilicon compounds and surfactants may be blended.
また、当該エネルギー線硬化型樹脂の粘度は作業性の観
点から通常、２５℃で１０００〜１０．０００センチポ
イズの範囲にＷｉｉｌｌされているのが好ましい。Further, from the viewpoint of workability, the viscosity of the energy ray-curable resin is preferably within the range of 1000 to 10.000 centipoise at 25°C.
上述したアクリル若しくはメタクリルオリゴマー（以下
、アクリル若しくはメタクリルオリゴマーを（メタ）ア
クリルオリゴマーと記載する）とは、アクリレート若し
くはメタクリレート成分（以下、アクリレート若しくは
メタクリレートを（メタ）アクリレートと記載する）と
、イソシアネート成分と、ポリオール成分とからなる。The above-mentioned acrylic or methacrylic oligomer (hereinafter, acrylic or methacrylic oligomer is referred to as (meth)acrylic oligomer) includes an acrylate or methacrylate component (hereinafter, acrylate or methacrylate is referred to as (meth)acrylate), an isocyanate component, and an isocyanate component. , and a polyol component.
ここで、（メタ）アクリレート成分としては、２−ヒド
ロキシエチル（メタ）アクリレート、２−ヒドロキシプ
ロピル（メタ）アクリレートなど、ヒドロキシアルキル
基の炭素数が２〜４程度のものが用いられる。Here, as the (meth)acrylate component, those having a hydroxyalkyl group having about 2 to 4 carbon atoms are used, such as 2-hydroxyethyl (meth)acrylate and 2-hydroxypropyl (meth)acrylate.
イソシアネート成分としては、トリレンジイソシアネー
ト、ジフェニルメタンジイソシアネ“ト１ｐ−フェニレ
ンジイソシアネート、ヘキサメチレンジイソシアネート
、キシリレンジイソシアネート、イソホロンジイソシア
ネートなどを挙げることができる。Examples of the isocyanate component include tolylene diisocyanate, diphenylmethane diisocyanate, 1p-phenylene diisocyanate, hexamethylene diisocyanate, xylylene diisocyanate, and isophorone diisocyanate.
また、ポリオール成分としては、ポリオキシテトラメチ
レングリコール、ポリプロピレングリコール、ポリエチ
レングリコールなどのポリエーテルポリオール、ポリオ
レフィングリコール、ポリエステルポリオール、ポリカ
ーボネートポリオール、ポリカブ費うクトンポリオール
などを挙げることができる。In addition, examples of the polyol component include polyether polyols such as polyoxytetramethylene glycol, polypropylene glycol, and polyethylene glycol, polyolefin glycols, polyester polyols, polycarbonate polyols, and polycarbonate polyols.
一方、上述した反応性希釈剤としては次のものを挙げる
ことができる。On the other hand, the above-mentioned reactive diluents include the following.
２−エチルへキシル（メタ）１クリレート、テトラにド
ロフルフリルアルコ−
ラクトン付加物の（メタ）アクリレート、ノニルフェノ
ールエチレンオキサイド付加物の（メタ）アクリレート
、
ポリエチレングリコールジ（メタ）アクリレート、
ポリプ四ピレングリコールジ（メタ）アクリ し ー
１・ 、
ビスフェノールジエチレングリコールジ（メタ）アクリ
レート、
水添ビスフェノールトリエチレングリコールジ（メタ）
アクリレート、
トリメチ四ールプロパントリ （メタ）アクリレート、
ペンタエリスリトールトリ （メタ）アクリレート、
ビスフェノールジグリシジルエーテルから合成したエポ
キシ（メタ）アクリレートなどのモノないしポリ （メ
タ）アクリレート。2-Ethylhexyl (meth)1 acrylate, (meth)acrylate of tetra-drofurfuryl alcohol lactone adduct, (meth)acrylate of nonylphenol ethylene oxide adduct, polyethylene glycol di(meth)acrylate, polytetrapyrene glycol Di(meth)acrylate 1., Bisphenol diethylene glycol di(meth)acrylate, Hydrogenated bisphenol triethylene glycol di(meth)
Mono- or poly(meth)acrylates such as epoxy(meth)acrylate synthesized from acrylate, trimethy4ylpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, and bisphenol diglycidyl ether.
また、反応性希釈剤としては次のようなビニル化合物を
使用することも可能である。Furthermore, the following vinyl compounds can also be used as the reactive diluent.
ジアリルアジペート、 ジアリルフタレート、 トリアリルトリメリテート、 トリアリルイソシアヌレートなどのアリルエステル、 スチレン、 ビニルアセテート、 Ｎ−ビニルピロリドン、 Ｎ，Ｎ−ジメチルアクリルアミド、 Ｎ，Ｎ−ジメチルアミノプロピルアクリルアミド、 Ｎ，Ｎ−ジメチルアミノエチルアクリレート。diallyl adipate, diallyl phthalate, triallyl trimellitate, Allyl esters such as triallyl isocyanurate, styrene, vinyl acetate, N-vinylpyrrolidone, N,N-dimethylacrylamide, N,N-dimethylaminopropylacrylamide, N,N-dimethylaminoethyl acrylate.
本発明においてエネルギー線硬化型樹脂に含有される重
合開始剤は、エネルギー線の照射により異種原子間単結
合を開裂させるものであり、以下のものを例示すること
ができる。In the present invention, the polymerization initiator contained in the energy ray curable resin is one that cleaves a single bond between different atoms upon irradiation with energy rays, and the following can be exemplified.
炭素原子とリン原子との異種原子間単結合を開裂させる
ものとしては、
ベンゾイルジフェニル７オスフインオキサイド、
ベンゾイルジメチルフォスフインオキサイド、
ベンゾイルジエチルフォスフインオキサイド、
２−メチルベンゾイルジフェニルフォスフインオキサイ
ド、
２−メチルベンゾイルジメチルフォスフインオキサイド
、
２−メチルベンゾイルジエチルフォスフインオキサイド
、
２、４−ジメチルベンゾイルジフェニルフォスフインオ
キサイド、
２、４−ジメチルベンゾイルジメチルフォスフインオキ
サイド、
２、４−ジメチルベンゾイルジエチルフォスフインオキ
サイド、
２、４．６−ドリメチルペンゾイルジフエニル７オスフ
インオキサイド、
２、４．６−トリメチルベンゾイルジメチルフオスフイ
ンオキサイド、
２、４．６−）リメチルペンゾイルジエチルフオスフィ
ンオキサイド
などを挙げることができる。Examples of substances that cleave a single bond between different atoms between a carbon atom and a phosphorus atom include benzoyldiphenyl 7-osphine oxide, benzoyldimethylphosphine oxide, benzoyldiethylphosphine oxide, 2-methylbenzoyldiphenylphosphine oxide, 2-methyl benzoyldimethylphosphine oxide, 2-methylbenzoyldiethylphosphine oxide, 2,4-dimethylbenzoyldiphenylphosphine oxide, 2,4-dimethylbenzoyldimethylphosphine oxide, 2,4-dimethylbenzoyldiethylphosphine oxide, 2, Examples include 4,6-dolimethylpenzoyldiphenyl7osphine oxide, 2,4,6-trimethylbenzoyldimethylphosphine oxide, and 2,4,6-)limethylpenzoyldiethylphosphine oxide.
また、炭素原子とイオウ原子との異種原子間単結合を開
裂させるものとしては、
ベンゾイルフェニルスルフィド、
２−メチルベンゾイルフェニルスルフィド、４−メチル
ベンゾイルフェニルスルフィド、２、４−ジメチルベン
ゾイルフェニルスルフィド、
２、４，６−）ジメチルベンゾイルフェニルスルフィド
、
４−クロロベンゾイルフェニルスルフィド為ベンゾイル
−２−メチルフェニルスルフィド、
ベンゾイル−４−メチルフェニルスルフィド、
ベンゾイル−２，４−ジメチルフェニルスルフィド１
ベンゾイル−２，４，６−）リメチルフ二二ルスルフィ
ド、
ベンゾイル−４−クロ彎フェニルスルフィド
などを挙げることができる。In addition, substances that cleave a single bond between different atoms between a carbon atom and a sulfur atom include benzoylphenyl sulfide, 2-methylbenzoylphenyl sulfide, 4-methylbenzoylphenyl sulfide, 2,4-dimethylbenzoylphenyl sulfide, 2, 4,6-)dimethylbenzoylphenyl sulfide, 4-chlorobenzoylphenyl sulfide, benzoyl-2-methylphenylsulfide, benzoyl-4-methylphenylsulfide, benzoyl-2,4-dimethylphenylsulfide 1 benzoyl-2,4,6 -) Limethyl phenyl sulfide, benzoyl-4-chlorophenyl sulfide, and the like.
本発明で用いられるＩＡ種原子間単結合を開裂させる重
合開始剤は、従来から用いられている同種原子間単結合
（例えば炭素−炭素結合）を開裂させる重合開始剤に比
べると、開裂させるのに要するエネルギーが小さい。し
たがって、同じエネルギーが与えられた場合、異種原子
間単結合を開裂させる開始剤を用いた方が、開裂の効果
が大きく、これにより、硬化速度が上昇し、高速線引の
条件においても樹脂を完全に硬化させることが可能とな
る。The polymerization initiator used in the present invention, which cleaves a single bond between atoms of the IA species, is more difficult to cleave than the conventionally used polymerization initiator, which cleaves a single bond between atoms of the same type (for example, a carbon-carbon bond). The energy required is small. Therefore, when the same energy is applied, using an initiator that cleaves the single bond between different atoms has a greater cleavage effect, which increases the curing rate and allows the resin to hold up even under high-speed drawing conditions. It can be completely cured.
重合開始剤の添加量は、エネルギー線硬化型樹脂の他の
成分、例えば（メタ）アクリルオリゴマーと反応性希釈
剤との合計量１００重量部に対して、通常０．１〜１０
重量部程度用いればよい。この重合開始剤が少なすぎる
と硬化性を満足できにくくなり、一方、所定量を超える
とそれ以上の硬化速度の向上が望めず、逆に硬化後の樹
脂とファイバとの界面から析出したりすることがある。The amount of the polymerization initiator added is usually 0.1 to 10 parts by weight per 100 parts by weight of the other components of the energy beam curable resin, such as (meth)acrylic oligomer and reactive diluent.
It is sufficient to use about parts by weight. If the amount of this polymerization initiator is too small, it will be difficult to satisfy the curability, while if it exceeds a certain amount, no further improvement in the curing speed can be expected, and conversely, the polymerization initiator may precipitate from the interface between the resin and the fiber after curing. Sometimes.
く実 施 例〉
以下、本発明の好適な実施例及び比較のための比較例に
ついて説明す４゜
実施例１
攪拌機、冷却晋および温度計を付した３１の四つロフラ
スコに平均分子量１０００のポリオキシテトラメチレン
グリコール１モル、トリレンジイソシアネート２モルを
仕込み、６０〜７０℃で２時間反応させた。ついで、２
−とドロキシエチルアクリレート２モルを加え赤外線吸
収スペクトルによりイソシアネート基の２２７０ ｃｍ
−’の特性吸収帯が消失するまで反応を続けた。Examples Preferred examples of the present invention and comparative examples for comparison will be described below.Example 1 Polymer having an average molecular weight of 1000 was placed in 31 four-lobe flasks equipped with a stirrer, a cooler, and a thermometer. 1 mole of oxytetramethylene glycol and 2 moles of tolylene diisocyanate were charged and reacted at 60 to 70°C for 2 hours. Then, 2
- and 2 moles of droxyethyl acrylate were added, and the infrared absorption spectrum showed that the isocyanate group was 2270 cm
The reaction was continued until the characteristic absorption band −' disappeared.
このようにして得られたウレタンアクリレートオリゴマ
ー６０部（重量部を示す、以下同じ）に反応性希釈剤と
して２−エチルへキシルアクリレート４０部、重合開始
剤としてベンゾイルジフェニル７オスフインオキサイド
３部を配合してエネルギー線硬化型樹脂を得た。40 parts of 2-ethylhexyl acrylate as a reactive diluent and 3 parts of benzoyldiphenyl 7-osphine oxide as a polymerization initiator were added to 60 parts of the urethane acrylate oligomer thus obtained (indicated by weight, the same applies hereinafter). An energy ray-curable resin was obtained.
このエネルギー線硬化型樹脂を線引きして得た光ファイ
バの周囲に塗布し、紫外線を照射することにより、第１
図に示すように、光ファイバｌの周囲に被覆層２を形成
してなる被覆光ファイバ３を得た。By applying this energy ray curable resin around the optical fiber obtained by drawing and irradiating it with ultraviolet rays, the first
As shown in the figure, a coated optical fiber 3 was obtained by forming a coating layer 2 around an optical fiber 1.
このとき、被覆樹脂が完全に硬化するための最高線速は
１６０ ｍ／ｓｉｎであった。At this time, the maximum linear speed for completely curing the coating resin was 160 m/sin.
実施例２
実施例１と同様にして得たウレタンアクリレートオリゴ
マー６０部に反応性希釈剤として２−エチルへキシルア
クリレート４０部、重合開始剤としてベンゾイルジメチ
ルフォスフインオキサイド３部を配合してエネルギー線
硬化型Ｉ１１脂を得た。Example 2 40 parts of 2-ethylhexyl acrylate as a reactive diluent and 3 parts of benzoyldimethylphosphine oxide as a polymerization initiator were added to 60 parts of urethane acrylate oligomer obtained in the same manner as in Example 1, and the mixture was cured with energy rays. Type I11 fat was obtained.
このエネルギー線硬化型樹脂を用いて実施例１と同様に
、被覆光ファイバ３を製造した。A coated optical fiber 3 was manufactured in the same manner as in Example 1 using this energy ray curable resin.
このとき、被覆樹脂が完全に硬化するための最高線速は
１６５ｍ／＠ｉｎであった。At this time, the maximum linear speed for completely curing the coating resin was 165 m/@in.
実施例３
実施例１と同様にして得たウレタンアクリレートオリゴ
マー６０部に反応性希釈剤として２−エチルへキシルア
クリレート４０部、ｆｆｉ 合間始剤としてベンゾイル
フェニルスルフィド３部を配合してエネルギー線硬化型
樹脂を得た。Example 3 40 parts of 2-ethylhexyl acrylate as a reactive diluent and 3 parts of benzoylphenyl sulfide as an intermediate initiator were blended with 60 parts of urethane acrylate oligomer obtained in the same manner as in Example 1 to produce an energy ray-curable product. Resin was obtained.
このエネルギー線硬化型樹脂を用いて実施例１と同様に
、被覆光ファイバ３を製造した。A coated optical fiber 3 was manufactured in the same manner as in Example 1 using this energy ray curable resin.
このとき、被覆樹脂が完全に硬化するための最高線速は
１６０ ｍ ／ ｓｉｎであった。At this time, the maximum linear speed for completely curing the coating resin was 160 m/sin.
比較例１
実施例１と同様にして得たウレタンアクリレートオリゴ
マー６０部に反応性希釈剤として２−エチルへキシルア
クリレート４０部、重合開始剤としてベンゾイルジフェ
ニルフォスフインオキサイド０．０８部を配合してエネ
ルギーｍ１！化型樹脂を得た。Comparative Example 1 40 parts of 2-ethylhexyl acrylate as a reactive diluent and 0.08 parts of benzoyldiphenylphosphine oxide as a polymerization initiator were added to 60 parts of urethane acrylate oligomer obtained in the same manner as in Example 1 to obtain energy. m1! A molded resin was obtained.
このエネルギー線硬化型樹脂を用いて実施例１と同様に
、被覆光ファイバ３を製造した。A coated optical fiber 3 was manufactured in the same manner as in Example 1 using this energy ray curable resin.
このとき、被覆ｉｓＩ脂が完全に硬化するための最高線
速は１００ ｍ／ｗｉｎであった。At this time, the maximum linear speed for completely curing the coating isI resin was 100 m/win.
比較例２
実施例１と同様にして得たウレタンアクリレートオリゴ
マー６０部に、反応性希釈剤として２−エチルへキシル
アクリレート４０部、重合開始剤としてベンゾイルジフ
ェニル７オスフインオキサイド１２部を配合してエネル
ギー線硬化型樹脂を得た。Comparative Example 2 To 60 parts of urethane acrylate oligomer obtained in the same manner as in Example 1, 40 parts of 2-ethylhexyl acrylate as a reactive diluent and 12 parts of benzoyldiphenyl 7-osphine oxide as a polymerization initiator were added to give energy. A line-curing resin was obtained.
このエネルギー線硬化型樹脂を用い、実施例１と同様に
して被覆光ファイバ３を製造した。Using this energy ray curable resin, a coated optical fiber 3 was manufactured in the same manner as in Example 1.
このとき、？！２覆樹脂が完全に硬化するための最高線
速は１６０ ｍ ／ ｗｉｎであった。At this time,? ! The maximum linear speed for complete curing of the two-cover resin was 160 m/win.
この試作ファイバを放置して観察したところ、経時的に
ファイバと被覆樹脂との界面から重合開始剤が析出して
外観を損うことが認められた。なお、念のため他の実施
例、比較例の試作ファイバを調査したところ、重合開始
剤の析出現象は認められなかった。When this prototype fiber was left to stand and observed, it was found that the polymerization initiator precipitated from the interface between the fiber and the coating resin over time, impairing its appearance. As a precaution, trial fibers of other Examples and Comparative Examples were investigated, and no precipitation of the polymerization initiator was observed.
比較例３
実施例１と同様にして得たウレタンアクリレートオリゴ
マー６０部に、反応性希釈剤として２−エチルへキシル
アクリレート４０部、重合開始剤としてベンジルジメチ
ルケタール３部を配合してエネルギー線硬化型樹脂を得
た。Comparative Example 3 60 parts of urethane acrylate oligomer obtained in the same manner as in Example 1 was mixed with 40 parts of 2-ethylhexyl acrylate as a reactive diluent and 3 parts of benzyl dimethyl ketal as a polymerization initiator to produce an energy ray-curable type. Resin was obtained.
このエネルギー線硬化型樹脂を用いて実施例１と同様に
光ファイバの周囲に被覆層を形成した被覆光ファイバを
製造した。A coated optical fiber in which a coating layer was formed around the optical fiber was manufactured in the same manner as in Example 1 using this energy ray curable resin.
このとき、被覆樹脂が完全に硬化するための最高線速は
ｌｏｏｍ／ｗｉｎであった。At this time, the maximum linear speed for completely curing the coating resin was room/win.
〈発明の効果〉
以上説明したように、本発明では、エネルギー線硬化型
樹脂に配合される重合開始剤として、エネルギー線の照
射によって異種原子間単結合を開裂させる重合開始剤を
用いて樹脂の硬化速度を上昇させているので、線引速度
を上昇することにより生産性を向上させた被覆光ファイ
バを提供することができる。<Effects of the Invention> As explained above, in the present invention, a polymerization initiator that cleaves a single bond between different atoms when irradiated with energy rays is used as a polymerization initiator to be added to an energy ray curable resin. Since the curing speed is increased, it is possible to provide a coated optical fiber with improved productivity by increasing the drawing speed.
第１図は本発明の実施例の被覆光ファイバの断面図であ
る。
図 面 中、
１は光ファイバ、
２は被覆層、
３は被覆光ファイバである。FIG. 1 is a sectional view of a coated optical fiber according to an embodiment of the present invention. In the drawing, 1 is an optical fiber, 2 is a coating layer, and 3 is a coated optical fiber.
Claims (3)
布し、エネルギー線の照射により硬化させて被覆層を施
してなる被覆光ファイバにおいて、上記エネルギー線硬
化型樹脂が、エネルギー線の照射により当該樹脂内の異
種原子間単結合を開裂させる重合開始剤を含有すること
を特徴とする被覆光ファイバ。(1) In a coated optical fiber in which an energy ray curable resin is applied to the outer periphery of the optical fiber and cured by irradiation with energy rays to form a coating layer, the energy ray curable resin is applied to the outer periphery of the optical fiber. A coated optical fiber characterized by containing a polymerization initiator that cleaves single bonds between different atoms in a resin.
ギー線硬化型樹脂として、アクリレート若しくはメタア
クリレート成分とイソシアネート成分とポリオール成分
とからなるアクリル若しくはメタアクリルオリゴマーと
、反応性希釈剤と、重合開始剤とを有する樹脂を用い、
当該重合開始剤は炭素原子とリン原子若しくはイオウ原
子との異種原子間単結合を開裂させる重合開始剤である
ことを特徴とする被覆光ファイバ。(2) In the coated optical fiber according to claim 1, the energy ray-curable resin includes an acrylic or methacrylic oligomer consisting of an acrylate or methacrylate component, an isocyanate component, and a polyol component, a reactive diluent, and a polymerization initiator. Using a resin having
A coated optical fiber characterized in that the polymerization initiator is a polymerization initiator that cleaves a single bond between different atoms between a carbon atom and a phosphorus atom or a sulfur atom.
重合開始剤の含有量が他の成分１００重量部に対して０
．１〜１０重量部であることを特徴とする被覆光ファイ
バ。(3) In the coated optical fiber according to claim 1 or 2,
The content of polymerization initiator is 0 with respect to 100 parts by weight of other components.
．． A coated optical fiber characterized in that it contains 1 to 10 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63214819A JPH0264510A (en) | 1988-08-31 | 1988-08-31 | coated optical fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63214819A JPH0264510A (en) | 1988-08-31 | 1988-08-31 | coated optical fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0264510A true JPH0264510A (en) | 1990-03-05 |
Family
ID=16662048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63214819A Pending JPH0264510A (en) | 1988-08-31 | 1988-08-31 | coated optical fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0264510A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5288482A (en) * | 1993-03-11 | 1994-02-22 | Dow Corning Corporation | Silicone containing lip care cosmetic composition |
| US6850682B2 (en) | 2001-12-26 | 2005-02-01 | Dainippon Ink And Chemicals, Inc. | Resin composition for coating optical fiber and coated optical fiber and optical fiber unit using the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0234620A (en) * | 1988-07-26 | 1990-02-05 | Mitsui Toatsu Chem Inc | Photocurable resin composition |
-
1988
- 1988-08-31 JP JP63214819A patent/JPH0264510A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0234620A (en) * | 1988-07-26 | 1990-02-05 | Mitsui Toatsu Chem Inc | Photocurable resin composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5288482A (en) * | 1993-03-11 | 1994-02-22 | Dow Corning Corporation | Silicone containing lip care cosmetic composition |
| US6850682B2 (en) | 2001-12-26 | 2005-02-01 | Dainippon Ink And Chemicals, Inc. | Resin composition for coating optical fiber and coated optical fiber and optical fiber unit using the same |
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