JPH0294355A - Supporting cylinder insulating structure of sodium-sulfur battery - Google Patents
Supporting cylinder insulating structure of sodium-sulfur batteryInfo
- Publication number
- JPH0294355A JPH0294355A JP63248391A JP24839188A JPH0294355A JP H0294355 A JPH0294355 A JP H0294355A JP 63248391 A JP63248391 A JP 63248391A JP 24839188 A JP24839188 A JP 24839188A JP H0294355 A JPH0294355 A JP H0294355A
- Authority
- JP
- Japan
- Prior art keywords
- battery
- supporting
- support
- sodium
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000012212 insulator Substances 0.000 claims abstract description 27
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 24
- 239000011593 sulfur Substances 0.000 claims abstract description 24
- 238000009413 insulation Methods 0.000 claims description 5
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 claims description 3
- 239000011521 glass Substances 0.000 abstract description 4
- 238000010292 electrical insulation Methods 0.000 abstract description 3
- 208000032953 Device battery issue Diseases 0.000 abstract 3
- 239000006182 cathode active material Substances 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 4
- 230000007257 malfunction Effects 0.000 description 4
- 239000006183 anode active material Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/213—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for cells having curved cross-section, e.g. round or elliptic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Secondary Cells (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
この発明は収納ケース内に単体のナトリウム−硫黄電池
を前記収納ケースと電気的に絶縁して支持するための支
持筒の絶縁構造に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to an insulating structure of a support tube for supporting a single sodium-sulfur battery in a storage case while electrically insulating it from the storage case. be.
［従来の技術］
従来の支持筒は第８図に示すように、従来、グラステー
プ１２で全面を覆われた単電池を支持筒内に挿入し、ま
た支持筒底部に絶縁性の底板を嵌合固定して電池陽極と
収納ケース間の絶縁を保っていた。そして、このように
構成した支持筒１４を電池の収納ケース１５（底部のみ
図示する）内に複数本収納した後、それぞれの支持筒１
４内に単体のナトリウム−硫黄電池１６を収納するか、
それぞれの支持筒１４内にナトリウム−硫黄電池［発明
が解決しようとする課題］
ところが、前記従来の支持筒は約３５０℃で作動する高
温型のナトリウム−硫黄電池１６が気密性不良などの故
障により陽極容器１７内に収容したカーボンマット等の
陽極用導電材に含浸させた陽極活物質としての溶融硫黄
または陰極物質と反応して形成された多硫化ナトリウム
、あるいはその両方（以下単に溶融硫黄等という）が該
陽極容器１７内部から漏洩した場合、前記グラステープ
１２に前記溶ｉｔ硫黄等が染み込むため、あるいは、さ
らに前記硫黄等が支持管本体を腐蝕貫通し、漏洩する場
合があるため電池１６の陽極容器１７と支持筒本体１１
もしくは直接収納ケースとが電気的に導通し、このため
電池１６と収納ケース１５が導通する。そして複数個の
単電池がケース短絡した場合不具合が生じるという問題
があった。[Prior Art] As shown in FIG. 8, conventional support tubes have conventionally inserted a cell whose entire surface is covered with glass tape 12 into the support tube, and fitted an insulating bottom plate to the bottom of the support tube. They were fixed together to maintain insulation between the battery anode and the storage case. After storing a plurality of support tubes 14 configured in this manner in a battery storage case 15 (only the bottom part is shown), each support tube 1
A single sodium-sulfur battery 16 is housed in the battery 4, or
[Problem to be Solved by the Invention] However, in the conventional support tube, the high-temperature sodium-sulfur battery 16, which operates at about 350° C., is damaged due to malfunctions such as poor airtightness. Molten sulfur as an anode active material impregnated into a conductive material for an anode such as carbon mat housed in the anode container 17, sodium polysulfide formed by reaction with the cathode material, or both (hereinafter simply referred to as molten sulfur etc.) ) leaks from inside the anode container 17, the molten sulfur, etc. may seep into the glass tape 12, or the sulfur, etc. may corrode and penetrate the support tube body and leak. Anode container 17 and support tube body 11
Alternatively, the battery 16 and the storage case 15 are electrically connected to each other, and therefore the battery 16 and the storage case 15 are electrically connected to each other. Furthermore, there is a problem in that a problem occurs when a plurality of single cells are short-circuited in the case.
この発明の目的はナトリウム−硫黄電池が故障して溶融
硫黄等が電池内部から漏洩した場合も、電池と収納ケー
スとの電気的絶縁を確保することができるナトリウム−
硫黄電池の支持筒絶縁＃Ｉ！！を堤供することにある。The purpose of this invention is to provide a sodium-sulfur battery that can ensure electrical insulation between the battery and the storage case even if the sodium-sulfur battery malfunctions and molten sulfur leaks from inside the battery.
Sulfur battery support cylinder insulation #I! ! The purpose is to provide.
［課題を解決するための手段］
この発明は前記目的を達成するため、収納ゲースの内部
に四部を有する支持碍子を設置し、該支持ｉ１子の上部
にナトリウム−硫黄電池の支持筒を立設するという手段
をとっている。[Means for Solving the Problems] In order to achieve the above object, the present invention provides a support insulator having four parts inside a storage case, and a support tube for a sodium-sulfur battery is erected on top of the support insulator. We are taking steps to do so.
ス、この発明は支持筒の下部にナトリウム−硫黄電池の
内部から漏洩した溶融硫黄等を案内する案内溝を設ける
とよい。In this invention, it is preferable to provide a guide groove in the lower part of the support tube to guide molten sulfur leaked from inside the sodium-sulfur battery.
［作用〕
この発明はナトリウム−硫黄電池が故障して陽極活物質
の溶融硫黄等が電池内部から漏洩して支持筒から外部に
漏出した場合、前記支持筒が支持碍子により所定の高さ
に支持され、かつ該支持碍子の表面に凹部があるので、
前記溶融硫黄等が収納ケースの底面に滴下され、該溶融
硫黄等による陽極側と収納ケースとの電気的導通が防止
される。[Function] This invention provides that when a sodium-sulfur battery malfunctions and molten sulfur, etc. of the anode active material leaks from inside the battery and leaks out from the support tube, the support tube is supported at a predetermined height by a support insulator. and since there is a recess on the surface of the support insulator,
The molten sulfur or the like is dripped onto the bottom surface of the storage case, thereby preventing electrical continuity between the anode side and the storage case due to the molten sulfur or the like.
又、支持筒の下部に案内溝を設けると、漏出した硫黄等
が支持碍子には移動しにくいので、支持碍子の絶縁強度
が長期にわたって安定的に保持される。Further, by providing a guide groove in the lower part of the support tube, leaked sulfur and the like are difficult to move to the support insulator, so that the dielectric strength of the support insulator is stably maintained over a long period of time.
［実施例］
以下、請求項１記載の発明を具体化した第一実施例を第
１図に基づいて説明する。[Example] Hereinafter, a first example embodying the invention set forth in claim 1 will be described based on FIG. 1.
第１図に示すように、電池の収納ケース１５の底板上面
には支持碍子１が設置され、その上部には円筒状をなす
支持１！ｊ２が載置されている。前記支持碍子１は収納
ケース１５の底面に接触する支持台部１ａと、前記支持
筒２内に嵌合する頭部１ｂと、両者を一体に連結する柱
状部ＩＣと、さらにこの柱状部ＩＣの中間部に形成した
ヒダ部１ｄと前記頭部１ｂの夕「層下縁に下向きに形成
したヒダ部１ｅとにより形成されている。又、前記支持
台部１ａと頭部１ｂの間には所定高さの空間が凹部１ｆ
として形成されている。As shown in FIG. 1, a support insulator 1 is installed on the upper surface of the bottom plate of a battery storage case 15, and a cylindrical support 1 is mounted on the top of the support insulator 1! j2 is placed. The support insulator 1 includes a support base portion 1a that contacts the bottom surface of the storage case 15, a head portion 1b that fits into the support cylinder 2, a columnar portion IC that connects both together, and a columnar portion IC that connects the two together. It is formed by a pleat part 1d formed in the middle part and a pleat part 1e formed downward at the lower edge of the head 1b. The height space is the recess 1f
It is formed as.
前記支持ｉ！ｊ２を構成する金属製の支持筒本体３の下
部内周面には前記支持碍子１の上面に当接される支持用
フランジ部３ａを有し、支持百本体３の内周面にはグラ
ステープ４が接着されている。Said support i! The lower inner circumferential surface of the metal support cylinder body 3 constituting j2 has a supporting flange portion 3a that comes into contact with the upper surface of the support insulator 1, and the inner circumferential surface of the support body 3 is covered with glass tape. 4 is glued.
前記支持筒本体３の内部にはナトリウム−硫黄電池１６
が収納され、その下端面が前記支持用フランジ部３ａに
支持されている。A sodium-sulfur battery 16 is installed inside the support tube body 3.
is housed, and its lower end surface is supported by the supporting flange portion 3a.
前記支持碍子１の上端部は支持筒本体３下端部に嵌合さ
れているが、これを第３図に示すように単に載置しても
よい、又、第４図に示すように、支持碍子１を収納ケー
ス１５に立設したボルト５により固定すると共に、支持
碍子１の頭部１ｂを支持筒本体３の下端内周面に螺合し
てもよい。The upper end of the support insulator 1 is fitted to the lower end of the support cylinder main body 3, but it may be simply placed as shown in FIG. 3, or as shown in FIG. The insulator 1 may be fixed by bolts 5 set upright in the storage case 15, and the head 1b of the support insulator 1 may be screwed onto the inner peripheral surface of the lower end of the support cylinder body 3.
前述した支持筒２に代えて、第３図に示すように、セラ
ミックにより一体状の支持筒を使用してもよい、このセ
ラミックとしては、コージライト（２Ｍｇ０・２Ａ１１
０． ・５ＳｉＯ，）、ムライト（３Ａ １２０ ｓ
・２ＳｉＯ２）、アルミナ（Ａ１２０ｊ）、シリカ
（ＳｉＯｚ）等が考えられる。これらのセラミックは電
池１６から漏洩した溶融硫黄等、あるいは多硫化ナトリ
ウムに対する耐久性が高く、かつその浸透を防止する性
質を有している。Instead of the support tube 2 described above, an integral support tube made of ceramic may be used as shown in FIG.
0.・5SiO, ), mullite (3A 120 s
Possible materials include 2SiO2), alumina (A120j), and silica (SiOz). These ceramics have high durability against molten sulfur or the like leaked from the battery 16 or sodium polysulfide, and have the property of preventing penetration thereof.
万一、電池１６が故障して陽極活物質の溶融硫黄等が電
池内部から支持ｆ！ｉ２内に漏洩しても、前記支持筒２
の下部から支持碍子１の頭部１ｂを伝って、ヒダ部１ａ
から滴下され、この結果、前記溶融硫黄等が支持筒２を
介して収納ゲース１５と電気的に接続されることはない
、さらに支持筒がセラミックスの場合には、たとえそれ
が破損するような多量の活物質が漏洩しても電気的に収
納ケースや他の支持筒に収納されている陽極と導通する
ことはない、従って、複数個の単電池がケース短絡する
ことにより発生する事故を未然に防止することができる
。In the unlikely event that the battery 16 fails, molten sulfur, etc. from the anode active material will be supported from inside the battery f! Even if leakage occurs in i2, the support tube 2
from the lower part of the head 1b of the support insulator 1 to the fold part 1a.
As a result, the molten sulfur etc. will not be electrically connected to the storage gauge 15 through the support tube 2. Furthermore, if the support tube is made of ceramics, even if the support tube is made of ceramics, even if a large amount Even if the active material leaks, it will not electrically conduct with the anode housed in the storage case or other support cylinder, thus preventing accidents caused by short-circuiting of multiple cells in the case. It can be prevented.
次に、第５図により請求項２記載の発明の詳細な説明す
る。Next, the invention according to claim 2 will be explained in detail with reference to FIG.
この実施例は支持筒本体３の下部に溶融硫黄等が支持碍
子１のヒダ部１ｅを伝わないように案内溝３ｂを設けて
いる。In this embodiment, a guide groove 3b is provided in the lower part of the support cylinder body 3 to prevent molten sulfur and the like from being transmitted through the folds 1e of the support insulator 1.
従って、この実施例では支持碍子１への溶融硫黄等の移
動を抑制して、その絶縁強度を長期にわたって安定して
保持することができる。Therefore, in this embodiment, the movement of molten sulfur and the like to the support insulator 1 can be suppressed, and its insulation strength can be stably maintained over a long period of time.
次に、この発明の別例を第６図及び第７図に基づいて説
明する。Next, another example of the present invention will be explained based on FIGS. 6 and 7.
この実施例では三本の支持筒２を一つの支持碍子１によ
り支持し、それぞれの支持ＷＪ２は例えば５ＵＳ３０４
のステンレススチールよりなる一対のホルダー７．８と
、この両端部を締付は固定するボルト９及びナツト１０
とにより互に千鳥状に接合され、締付は固定されている
。In this embodiment, three support cylinders 2 are supported by one support insulator 1, and each support WJ2 is made of, for example, 5US304.
A pair of holders 7 and 8 made of stainless steel, and bolts 9 and nuts 10 that tighten and fix both ends of the holders 7 and 8.
They are joined to each other in a staggered manner, and the tightening is fixed.
従って、この実施例では支持碍子１の個数を減少するこ
とができると共に、それぞれの支持筒２を互いに固定し
て収納ケース１５内に安定して載置することができる。Therefore, in this embodiment, the number of support insulators 1 can be reduced, and the support tubes 2 can be fixed to each other and stably placed in the storage case 15.
［発明の効果］
以上詳述したように、この発明は、ナトリウム−硫黄電
池が故障して陽極活物質の溶融硫黄等が電池内部から漏
洩した場合、溶融硫黄等が外部へ漏出しても、電池が支
持筒を介して収納ケースに電気的に導通することはなく
、従って、複数個の単電池がケース短絡することによっ
て起こる事故を未然に防止することができる効果がある
。[Effects of the Invention] As described in detail above, the present invention provides that when a sodium-sulfur battery malfunctions and molten sulfur, etc. of the positive electrode active material leaks from inside the battery, even if the molten sulfur, etc. leaks to the outside, The battery is not electrically connected to the storage case via the support tube, and therefore, it is possible to prevent accidents caused by short-circuiting of a plurality of unit cells to the case.
又、支持筒本体の底部に案内溝を設けると、支持碍子表
面への溶融硫黄等の移動を抑制して絶縁信頼性をさらに
向上することができる効果がある。Further, if a guide groove is provided at the bottom of the support cylinder body, it is possible to suppress the movement of molten sulfur and the like to the surface of the support insulator, thereby further improving insulation reliability.
第１図は請求項１記載の発明を具体化した支持筒の縦断
面図、第２図は支持筒を収納ケース内に収納した状態を
示す斜視図、第３図及び第４図はそれぞれこの発明の別
例を示す断面図、第５図は請求項２記載の発明を具体化
した支持筒の縦断面図、第６図は支持筒のホルダーを示
す斜視図、第７図は第６図の支持筒の使用状態を示す平
面図、第８図は従来の支持筒の縦断面図である。
１・・・支持碍子、２・・・支持筒、３・・・支持筒本
体。
５・・・ボルト、７．８・・・ホルダー特許出願人
日本目子 株式会社
代理人 弁理士 恩１）博宣
第７ｇ
］FIG. 1 is a longitudinal cross-sectional view of a support tube embodying the invention as claimed in claim 1, FIG. 2 is a perspective view showing the support tube stored in a storage case, and FIGS. 3 and 4 are respectively views of the support tube. A sectional view showing another example of the invention, FIG. 5 is a longitudinal sectional view of a support cylinder embodying the invention as claimed in claim 2, FIG. 6 is a perspective view showing a holder of the support cylinder, and FIG. 7 is a view as shown in FIG. FIG. 8 is a plan view showing how the support tube is used, and FIG. 8 is a longitudinal sectional view of the conventional support tube. 1... Support insulator, 2... Support tube, 3... Support tube body. 5...Bolt, 7.8...Holder patent applicant
Nipponmeko Co., Ltd. Agent Patent Attorney On 1) Hironobu No. 7g]
Claims (1)
、該支持碍子の上部にナトリウム−硫黄電池の支持筒を
立設したことを特徴とするナトリウム−硫黄電池の支持
筒絶縁構造。 ２、支持筒の下部にはナトリウム−硫黄電池の内部から
漏洩した溶融硫黄又は多硫化ナトリウムあるいはその両
方を案内する案内溝が設けられている請求項１記載のナ
トリウム−硫黄電池の支持筒絶縁構造。[Claims] 1. A support for a sodium-sulfur battery, characterized in that a support insulator having a recessed portion is installed inside a storage case, and a support tube for a sodium-sulfur battery is erected above the support insulator. Cylindrical insulation structure. 2. The support cylinder insulating structure for a sodium-sulfur battery according to claim 1, wherein a guide groove is provided in the lower part of the support cylinder to guide molten sulfur and/or sodium polysulfide leaked from inside the sodium-sulfur battery. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63248391A JPH0294355A (en) | 1988-09-30 | 1988-09-30 | Supporting cylinder insulating structure of sodium-sulfur battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63248391A JPH0294355A (en) | 1988-09-30 | 1988-09-30 | Supporting cylinder insulating structure of sodium-sulfur battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0294355A true JPH0294355A (en) | 1990-04-05 |
| JPH0472350B2 JPH0472350B2 (en) | 1992-11-18 |
Family
ID=17177410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63248391A Granted JPH0294355A (en) | 1988-09-30 | 1988-09-30 | Supporting cylinder insulating structure of sodium-sulfur battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0294355A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077563A (en) * | 1986-04-10 | 1991-12-31 | Ngk Insulators, Ltd. | Thermally printing head operable with electrically resistive layer provided on printt film or ribbon or on recording medium |
-
1988
- 1988-09-30 JP JP63248391A patent/JPH0294355A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077563A (en) * | 1986-04-10 | 1991-12-31 | Ngk Insulators, Ltd. | Thermally printing head operable with electrically resistive layer provided on printt film or ribbon or on recording medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0472350B2 (en) | 1992-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO951045L (en) | Energy storage device, as well as a method for making such | |
| US20090052115A1 (en) | Capacitor and method of manufacturing the same | |
| DE3685822D1 (en) | BATTERY. | |
| US12278048B2 (en) | Electrochemical energy storage device | |
| KR19990082935A (en) | Battery pack, battery charger and electronic equipment using battery pack | |
| JPH0294355A (en) | Supporting cylinder insulating structure of sodium-sulfur battery | |
| WO2015029793A1 (en) | Secondary cell | |
| JPH06236751A (en) | Electrochemical cell, manufacturing method thereof, and battery of electrochemical cell | |
| US4276361A (en) | Electrochemical cell with electrode hold-down | |
| CN220830030U (en) | Single battery and battery assembly | |
| JPH02135663A (en) | Sodium-sulfur battery | |
| EP0269867A2 (en) | Electrochemical cell with container support | |
| JPS6331483Y2 (en) | ||
| CN222953227U (en) | Batteries and electrical equipment | |
| JPH0557704B2 (en) | ||
| CN211372333U (en) | Battery bracket and power supply device of pen lamp | |
| US20240380008A1 (en) | Power storage cell | |
| CN211371975U (en) | Pen lamp and charging connection assembly thereof | |
| JPH0419781Y2 (en) | ||
| JPH0418427B2 (en) | ||
| JPH0418426B2 (en) | ||
| JPH11162475A (en) | Dry cell | |
| JPS6366863A (en) | Sodium-sulfur battery | |
| JP2559943B2 (en) | Sodium-sulfur battery | |
| WO2024228470A1 (en) | Secondary battery tray |