JPH03100034A - Polynorbornene resin composition - Google Patents
Polynorbornene resin compositionInfo
- Publication number
- JPH03100034A JPH03100034A JP23650789A JP23650789A JPH03100034A JP H03100034 A JPH03100034 A JP H03100034A JP 23650789 A JP23650789 A JP 23650789A JP 23650789 A JP23650789 A JP 23650789A JP H03100034 A JPH03100034 A JP H03100034A
- Authority
- JP
- Japan
- Prior art keywords
- low
- polynorbornene resin
- polynorbornene
- resin
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000636 poly(norbornene) polymer Polymers 0.000 title claims abstract description 28
- 239000011342 resin composition Substances 0.000 title claims description 6
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 11
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 11
- 229920001194 natural rubber Polymers 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 abstract description 7
- 239000006229 carbon black Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000000945 filler Substances 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 230000000052 comparative effect Effects 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野］
本発明は、ポリノルボルネン樹脂組成物に関する。更に
詳しくは、低反発弾性体を形成せしめるポリノルボルネ
ン樹脂組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to polynorbornene resin compositions. More specifically, the present invention relates to a polynorbornene resin composition that forms a low-resilience body.
ＯＡ・情報機器関係の防振ゴムとして、常温付近に大き
な減衰を持つ材料が求められており、ポリノルボルネン
樹脂や軟質塩化ビニル樹脂がこのために用いられている
。As anti-vibration rubber for office automation and information equipment, there is a demand for materials that have large damping near normal temperatures, and polynorbornene resins and soft vinyl chloride resins are used for this purpose.
ポリノルボルネン樹脂の場合、そこに大量の石油系オイ
ル、石油系樹脂などを配合すると超低反発弾性が得られ
、更に加硫剤を配合した配合物なども市販されている（
例えば１日本ゼオン製品ＮＸ５５２）。In the case of polynorbornene resin, ultra-low impact resilience can be obtained by blending a large amount of petroleum-based oil or petroleum-based resin with it, and formulations containing vulcanizing agents are also commercially available (
For example, 1 Nippon Zeon product NX552).
このようなポリノルボルネン樹脂を主体とする低反発弾
性配合物は、その特徴が常温域に限られ、０〜５℃付近
から凍結し、一方４０℃以上では弾性が増大するという
欠点がみられる。Such a low-resilience compound mainly composed of polynorbornene resin has the disadvantage that its characteristics are limited to the room temperature range, and it freezes from around 0 to 5°C, while its elasticity increases at temperatures above 40°C.
こうした問題点を解決するために、種々の方法が検討さ
れているが、例えば他のポリマーとのブレンドでは相溶
性、加硫系に限定がみられ、配合するオイルや可塑剤の
種類や量の検討では温度依存性が改良されるものの高反
発弾性となり、・また超高充填配合も根本的な改良とは
ならないなど。Various methods have been studied to solve these problems, but for example, when blending with other polymers, there are limitations in compatibility and vulcanization systems, and the types and amounts of oils and plasticizers to be blended are limited. In the study, although the temperature dependence was improved, the impact resilience was high, and ultra-high filling formulations did not provide any fundamental improvement.
決め手を欠いているのが現状である。The current situation is that we lack a decisive factor.
本発明は、ポリノルボルネン樹脂を主体とする低反発弾
性配合物が本来有するその特徴を失うことなく、−３０
〜１００℃、特に−３０〜２０℃の俯温域における温度
依存性を改良したポリノルボルネン樹脂組酸物を提供す
ることを目的としている。The present invention achieves -30
The object of the present invention is to provide a polynorbornene resin combination acid having improved temperature dependence in the temperature range of -100°C, particularly -30 to 20°C.
かかる本発明の目的は、ポリノルボルネン樹脂を主体と
する低反発弾性配合物に、配合物中のポリノルボルネン
樹脂１００重量部当り約１００〜３００重量部の天然ゴ
ムを添加したポリノルボルネン樹脂組成物によって達成
される。The object of the present invention is to provide a polynorbornene resin composition in which about 100 to 300 parts by weight of natural rubber is added to a low-resilience compound mainly composed of polynorbornene resin, and about 100 to 300 parts by weight of natural rubber per 100 parts by weight of polynorbornene resin in the blend. achieved.
ポリノルボルネン樹脂を主体とする低反発弾性配合物は
、前述の如く市版品そのものを使用し得るが、−船釣に
は次のような各配合成分からなっている。The low-resilience compound containing polynorbornene resin as a main component can be used as a commercial product as described above, but for boat fishing, it consists of the following ingredients.
ポリノルボルネン樹脂 １００重量部石油系オ
イル １００〜３００〃石油系樹脂
０〜１００〃カーボンブラツク
Ｏ〜３００〃ホワイトフィラー ０〜３０
０ ＃加硫系 ５〜３０〃他の
ポリマー（ＥＰＤＭなど） ０〜５０ ｎこの配
合物に添加される天然ゴムは、配合物中のポリノルボル
ネン樹脂１００重量部当り約１００〜３００重量部、好
ましくは約１５０〜２５０重量部゛、特に好ましくは約
２００重量部である。天然ゴムの添加割合がこれより少
ないと、低反発弾性ではあるが温度依存性、特に低温域
における温度依存性が改良されず、一方これより多い割
合で用いられると、温度依存性は改良されるものの高反
発弾性となり、ポリノルボルネン樹脂本来の特徴が失わ
れるようになる。Polynorbornene resin 100 parts by weight Petroleum oil 100-300 Petroleum resin
0~100〃Carbon black
0~300〃White filler 0~30
0 # Vulcanized system 5-30 Other polymers (such as EPDM) 0-50 n The natural rubber added to this formulation is about 100-300 parts by weight per 100 parts by weight of polynorbornene resin in the formulation, preferably is about 150 to 250 parts by weight, particularly preferably about 200 parts by weight. If the proportion of natural rubber added is less than this, although the elasticity is low, the temperature dependence, especially in the low temperature range, will not be improved; on the other hand, if the proportion is greater than this, the temperature dependence will be improved. However, the original properties of polynorbornene resin are lost.
組成物の調製は、ニーダ、バンバリーミキサなどを用い
て混練することによって行われ、混練物は約１００〜２
００℃の温度に約０．５〜１２０分間程度加熱すること
によって加硫される。The composition is prepared by kneading using a kneader, Banbury mixer, etc., and the kneaded material has a
It is vulcanized by heating to a temperature of 0.000C for about 0.5 to 120 minutes.
ポリノルボルネン樹脂を主体とする低反発弾性配合物に
天然ゴムを添加することにより、ポリノルボルネン樹脂
が本来有する低反発弾性特性を殆ど低下させることなく
、−３０〜１００℃、特に−３０〜２０℃の低温域にお
ける温度依存性が改良される。By adding natural rubber to a low-resilience compound mainly composed of polynorbornene resin, the low-resilience properties inherent to the polynorbornene resin can be maintained at -30 to 100°C, especially -30 to 20°C. Temperature dependence in the low temperature range is improved.
従って、かかる特徴を有する本発明の°ポリノルボルネ
ン樹脂組成物は、 ＯＡ機器などの防振材の成形材料と
して有効に使用することができる。Therefore, the polynorbornene resin composition of the present invention having such characteristics can be effectively used as a molding material for vibration isolators for office automation equipment and the like.
次に、実施例について本発明を説明する。 Next, the present invention will be explained with reference to examples.
実施例１〜３
ポリノルボルネン（日本ゼオン製品ノーソレックス）１
００重量部ナフテン油
１５０即ＤＭ
３０沈降性流憩バリウム
３００石油樹脂
８０酸イ’
ｔ、ｉｍ
５１１ＡＦカーボンブラツク（
三菱化成製品ダイアブラックＨ） １２０加硫剤（
イオウ系）
１５８００重量部
以上の配合組成を有するポリノルボルネン樹脂配合物８
００重量部に、天然ゴム（Ｒ３Ｓ＃１）−ホワイトフィ
ラー（日本シリカ製品ニップシールＶＮ−３）を１００
−２５重量部［実施例１コ、２００−５０重量部［実施
例２］または３００−７５重量部［実施例３］添加し、
３Ｑのニーダを用いて混練した後、１５０℃で１０分間
加熱加硫した。Examples 1 to 3 Polynorbornene (Nippon Zeon product Norsolex) 1
00 parts by weight naphthenic oil
150 Immediate DM
30 Precipitating flow barium
300 petroleum resin
80 acid i'
t,im
511AF carbon black (
Mitsubishi Kasei Diablack H) 120 vulcanizing agent (
sulfur type)
Polynorbornene resin formulation 8 having a formulation composition of 15,800 parts by weight or more
00 parts by weight, 100 parts by weight of natural rubber (R3S#1)-white filler (Nip Seal VN-3 manufactured by Nippon Silica)
-25 parts by weight [Example 1], 200-50 parts by weight [Example 2] or 300-75 parts by weight [Example 3],
After kneading using a 3Q kneader, the mixture was heated and vulcanized at 150° C. for 10 minutes.
加硫物について、ＪＩＳ Ｋ−６３０１に従って硬さ（
ＪＩＳ−Ａ）および反発弾性の温度依存性を測定し、そ
の結果を表および第１図のグラフに示した。Regarding vulcanizates, hardness (
JIS-A) and the temperature dependence of impact resilience were measured, and the results are shown in the table and the graph of FIG.
比較例１
ポリノルボルネン樹脂について、実施例と同様の加硫お
よび測定を行い、その結果を表および第１図のグラフに
示した。Comparative Example 1 Polynorbornene resin was vulcanized and measured in the same manner as in the examples, and the results are shown in the table and the graph in FIG.
比較例２〜３
実施例２において、天然ゴムの代わりに、同量のスチレ
ン・ブタジェンゴム（日本ゼオン製品＃１５０２、比較
例２）またはブチルゴム（エクソン・ブチル社製品ＨＴ
−１０−６６、比較例３）が用いられ、実施例と同様の
加硫および測定を行い、その結果を表に示した。Comparative Examples 2 to 3 In Example 2, the same amount of styrene-butadiene rubber (Nippon Zeon product #1502, Comparative Example 2) or butyl rubber (Exxon Butyl Co. product HT) was used instead of natural rubber.
-10-66, Comparative Example 3) was used, and the same vulcanization and measurements as in Examples were performed, and the results are shown in the table.
比較例４
実施例２において、天然ゴムの代わりに、１００重量部
の可塑剤（ジオクチルセバケート）が用いられ、実施例
と同様の加硫および測定を行い、その結果を表に示した
。Comparative Example 4 In Example 2, 100 parts by weight of a plasticizer (dioctyl sebacate) was used instead of natural rubber, and the same vulcanization and measurements as in Example were performed, and the results are shown in the table.
−実施例一一一一退漱外一一一 硬さ ４０℃ ２０℃ ０℃ ・・２０℃ 硬さの差（４０℃と一２０℃） 反発弾性（２０℃＞ Ｃ％） 総合判定-Example 111 Retirement 111 Hardness 40℃ 20℃ 0℃ ・・20℃ Difference in hardness (40℃ and -20℃) Repulsion elasticity (20℃＞ C%) Comprehensive judgment
第１図は、実施例１〜３および比較例１における硬さの
温度依存性を示すグラフである。FIG. 1 is a graph showing the temperature dependence of hardness in Examples 1 to 3 and Comparative Example 1.
Claims (1)
物に、配合物中のポリノルボルネン樹脂１００重量部当
り約１００〜３００重量部の天然ゴムを添加してなるポ
リノルボルネン樹脂組成物。1. A polynorbornene resin composition obtained by adding about 100 to 300 parts by weight of natural rubber per 100 parts by weight of the polynorbornene resin in the blend to a low-resilience blend mainly composed of a polynorbornene resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23650789A JPH03100034A (en) | 1989-09-12 | 1989-09-12 | Polynorbornene resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23650789A JPH03100034A (en) | 1989-09-12 | 1989-09-12 | Polynorbornene resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03100034A true JPH03100034A (en) | 1991-04-25 |
Family
ID=17001748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23650789A Pending JPH03100034A (en) | 1989-09-12 | 1989-09-12 | Polynorbornene resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03100034A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020011372A (en) * | 2018-07-10 | 2020-01-23 | 安田工業株式会社 | Machine tool vibration control device |
-
1989
- 1989-09-12 JP JP23650789A patent/JPH03100034A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020011372A (en) * | 2018-07-10 | 2020-01-23 | 安田工業株式会社 | Machine tool vibration control device |
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