JPH03106089A - Semiconductor laser element - Google Patents

Semiconductor laser element

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Publication number
JPH03106089A
JPH03106089A JP24368289A JP24368289A JPH03106089A JP H03106089 A JPH03106089 A JP H03106089A JP 24368289 A JP24368289 A JP 24368289A JP 24368289 A JP24368289 A JP 24368289A JP H03106089 A JPH03106089 A JP H03106089A
Authority
JP
Japan
Prior art keywords
semiconductor laser
conductive paste
laser element
bonding
solder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24368289A
Other languages
Japanese (ja)
Inventor
Kenji Kunihara
健二 国原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Electric Co Ltd
Original Assignee
Fuji Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Electric Co Ltd filed Critical Fuji Electric Co Ltd
Priority to JP24368289A priority Critical patent/JPH03106089A/en
Publication of JPH03106089A publication Critical patent/JPH03106089A/en
Pending legal-status Critical Current

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  • Semiconductor Lasers (AREA)

Abstract

PURPOSE:To elongate a semiconductor laser element in service life even if it is assembled in an UPSIDE-DOWN mode by a method wherein Ag containing epoxy resin conductive paste of specific thickness is used as a bonding material. CONSTITUTION:A sub-mount 11 is provided onto a heat sink 10 of a Cu stem, and a metal layer 12 is formed on the sub-mount 11, and a conductive paste layer 13 of Ag containing epoxy resin is applied as thick as prescribed onto the whole face or the required part of the metal layer 12 through a method such as a screen printing or a stamping method. That is, an Ag containing epoxy resin conductive paste layer having a thickness of 0.5-3mum is used as a bonding material for bonding a semiconductor laser element 1 to the heat sink 10 provided with the sub-mount 11 in an UP-SIDE-DOWN mode. Therefore, if the thickness of the conductive paste is set in a range of 0.5-3mum, the semiconductor laser element 1 is free of the influence of inner stress caused by the conductive paste when it is in operation after bonded. By this setup, the semiconductor laser element has a life span equivalent to that when it is bonded with solder, a net time required for bonding is 1/6 of that of solder bonding, and optical shielding caused by the squeeze-out of resin hardly occurs, so that a semiconductor laser element can be efficiently assembled high in yield.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明はサブマウントを有するヒートシンクを用いてt
lP−SIDE−DOWNにマウントとした半導体レー
ザ素子に関する. 〔従来の技術〕 半導体レーザ素子を室温で長期間連続発振させるために
は、その素子の活性層で発生する熱を効率よく放散動作
温度を下げることが必要であり、一般に半導体レーザ素
子の活性層に近い主面側をヒートシンク(放熱体)に接
合するUP−SIDE−DOWNの組み立て方式が採用
され、これにより活性層の熱を逃がしている.このとき
基板にGaAsなどを用いている半導体レーザ素子とC
uなどのヒートシンクは熱膨張係数が大きく異なるため
、直接半田接合すると半田溶融後の凝固過程で活性層に
強いストレスが加わり、そこにダークラインと呼ばれる
転移網を発生して、発振しきい値電流が上昇し遂には発
振不可能となる.そこでこの対策としてInなどの軟ら
かい半田を用いてヒートシンクに半導体レーザ素子を接
合するか、もしくはGaAs基板と熱膨張係数の差が小
さいSin Moなどサブマウントを介在させて、その
上にAuSn合金などの硬い半田層を数μ形威し、これ
を溶融してヒートシンクに半導体レーザ素子を接合する
かいずれかの方法が用いられている. 〔発明が解決しようとする課題〕 以上のように半導体レーザ素子を組み立てる際に、この
ような発光素子ではヒートシンクとなるステムの基準面
に対して発光点が正確に位置すること、即ち発光点の位
置精度を極めて高く定めることが必要となる.したがっ
て、前述のような半田接合を行なうとき、半導体レーザ
素子のチップを半田層の上で最適な位置に置いた後も、
半田が溶融して流れることによるチップの位置ずれを防
ぐためにチンブを加圧,固定しておかねばならない.そ
のため半導体レーザ素子のチップのグイボンディングを
行なうときは、チップを高精度に位置決めしてステムの
半田面に載置し、さらに上方からチンブをステムに対し
加圧固定し、半田を加熱溶融して接合した後冷却固化さ
せるという一連のプロセスを要することになり、1個の
チップの接合に必要な時間は、位置決めに10秒,半田
接合が50秒であるから合計60秒かかる.このように
半導体レーザ素子チップのグイボンデイングに要する時
間の大半は半田接合時間であり、組み立て効率に劣り量
産性が問題となる.したがってこの時間を短縮するのが
コスト低減の点から望ましいことである.また半田を使
うために、接合時に半田が盛り上がって活性領域を塞ぎ
レーザ発光を妨げる可能性が大きいという問題もある. 一方例えば発光ダイオード,IC,フォトダイオードな
どのように、基板側ではなく能動層側でヒートシンクに
接合するUP−SIDE−DOWII方式の組み立て素
子では、Agを含むエボキシ樹脂のような導電性ペース
トを用いて接合時間1〜2秒の高速グイボンディングが
可能であるが、半導体レーザ素子に対しては活性fiI
域がヒートシンクから遠い位置にあるので放熱効果の点
では好ましくない.しかし、これまで厚さ10u程度の
Ag含有エボキシ樹脂の導電性ペーストを用いて、UP
−SIDE−DOWli方式でヒートシンクに半導体レ
ーザ素子チンブを接合した場合、サブマウントを用いて
いるにも拘らず、半導体レーザ素子の寿命は期待できる
ものはなかった.これはペースト硬化後の樹脂成分の熱
膨張係数が半田の場合に比べてチップより著しく大きく
、半導体レーザ素子作動時の僅かの温度変化が生じても
これらの熱膨張係数の差により、大きな応力が作用する
ものとみられる.本発明は上述の点に鑑みてなされたも
のであり、その目的はAg含有エポキシ樹脂導電性ベー
ストを用いてUP−SI[l!!−DOInN方式で組
み立てたときも長寿命を保持することが可能な半導体レ
ーザ素子を提供することにある. 〔課題を解決するための手段〕 上記の課題を解決するために本発明は半導体レーザ素子
をサブマウントを有するヒートシンクにUP−8101
!−DOWNに接合するための材料として、0.5〜3
nの厚さを持つAg入りエボキシ樹脂の導電性ペースト
を用いたものである. 〔作用〕 本発明は上記のように構威したことにより、接合後の半
導体レーザ素子はこの範囲の厚さでは導電性ペーストに
起因する作動時の内部応力の影響は見られず、従来と同
等の寿命を持っており、しかも導電性ペーストを用いた
ために接合に要する時間は、従来の半田を用いた場合に
比べて176で済ますことが可能となる, 〔実施例〕 以下、本発明を実施例に基づき説明する.第1図は本発
明による組み立て後の半導体レ−ザ素子の要部構或を示
した模式断面図である.第1図において、半導体レーザ
素子のチップ上は半導体結晶基板2と、この基板2の上
に結晶或長などによって形威した活性領域3を持つ活性
114と、必要な各結晶戊長層である第1のクラフド層
5,第2クラソド層6.コンタクト層7および蒸着また
はメッキなどにより形威した二つの電極金属8,9から
なる.チンプ上から放熱させるためのCu製ステムのヒ
ートシンクIOにSlのサブマウント11ヲ半田もしく
は導電性ペーストを用いて接合してあり、サブマウント
11に蒸着などによりTtNi−Auの金属lwl2を
形威してある.本発明ではこの金属層12の表面に所定
の厚さを有するAgを含むエボキシI4脂の導電性ペー
スト層13を塗布しチップ上とサブマウン}11を接合
した構戒となっている.次にこのような接合構造を得る
ための手順について述べる.まずあらかじめCu製ステ
ムのヒートシンク10にサブマウント11と、このサブ
マウント1lに金属層12を形或しておき、金属FI1
2の全面もしくは必要な部分に、スクリーン印刷または
スタンビングなどの手法を用いて所定の厚さにAg含有
エポキシ樹脂導電性ペースト層13を塗布する.その後
チップ上をUP−SIDE−DOWNに位置決めし、金
属層12上に塗布された導電性ペースト層13に重ねる
ように所定の位置に載せて全体を加圧する.このとき、
ヒートシンク10を図示してない熱板上にIきサブマウ
ント11が100℃程度に加熱されるようにするのがよ
い.そして全体をトンネル炉または恒温槽を用いて20
0℃,40秒の樹!n化を行う.導電性ペースト層13
の硬化時は、殆どペースト体積の変化がないから加圧を
しておく必要がなく、チップ上の位置決めの時の発光点
精度を保つことができる.以上のダイボンドの正味の所
要時間については、樹脂硬化時間は多数個同時処理され
るから無視してよく、チフブ土の位置決めに必要な10
秒で済む.これら従来この過程で必要とする時間の1/
6でよいことになる. 次にag含有エポキシ樹脂導電性ペースト層13の厚さ
を0.1μ.0.5Jllll  1 its.  2
 n+  3一事 4−15n,lQ4と変えて、各厚
さのものについて10個づつ上記の手順により、チップ
上をサブマウント11に接合した第1図の構造をもつ半
導体レーザ素子を作製し、接合強度を調べるとともに光
出力20mW,温度50℃の条件下で、AgP.C.(
Automatic PowerControl)動作
の寿命試験を行い、得られた結果を第1表に示す.第1
表中のペースト厚さは各10個の平均値.素子寿命は平
均故障時間で示した.なお比較のためにAuSn合金半
田を用いた従来の接合構造における場合についても併記
した。
[Detailed Description of the Invention] [Industrial Application Field] The present invention uses a heat sink having a submount to
Regarding a semiconductor laser device mounted on an lP-SIDE-DOWN. [Prior Art] In order to cause a semiconductor laser device to oscillate continuously for a long period of time at room temperature, it is necessary to efficiently dissipate the heat generated in the active layer of the device and lower the operating temperature. An UP-SIDE-DOWN assembly method was adopted in which the main surface side closest to the main surface is joined to a heat sink (heat dissipation body), thereby dissipating heat from the active layer. At this time, a semiconductor laser element whose substrate is made of GaAs or the like and C
Since heat sinks such as U heat sinks have significantly different thermal expansion coefficients, when they are directly soldered together, strong stress is applied to the active layer during the solidification process after melting the solder, creating a transition network called a dark line, which causes the oscillation threshold current to increase. increases and eventually oscillation becomes impossible. Therefore, as a countermeasure to this problem, it is necessary to bond the semiconductor laser element to the heat sink using a soft solder such as In, or to interpose a submount such as Sin Mo, which has a small difference in thermal expansion coefficient from the GaAs substrate, and then mount a submount such as AuSn alloy on top of it. One of the methods used is to apply a few micrometers of hard solder layer and melt it to bond the semiconductor laser element to the heat sink. [Problems to be Solved by the Invention] When assembling a semiconductor laser device as described above, in such a light emitting device, it is necessary to accurately position the light emitting point with respect to the reference plane of the stem that serves as a heat sink. It is necessary to determine extremely high positional accuracy. Therefore, when performing solder bonding as described above, even after placing the semiconductor laser chip in the optimal position on the solder layer,
The tip must be pressurized and fixed to prevent the chip from shifting due to melted solder and flowing. Therefore, when bonding the chip of a semiconductor laser element, the chip is positioned with high precision and placed on the solder surface of the stem, and then the chimney is fixed to the stem under pressure from above, and the solder is heated and melted. A series of processes are required, including cooling and solidifying after bonding, and the time required to bond one chip is 10 seconds for positioning and 50 seconds for soldering, so it takes a total of 60 seconds. In this way, most of the time required for bonding a semiconductor laser chip is soldering time, which leads to poor assembly efficiency and problems with mass production. Therefore, it is desirable to shorten this time from the point of view of cost reduction. Another problem is that because solder is used, there is a high possibility that the solder will swell during bonding and block the active region, thus interfering with laser emission. On the other hand, in UP-SIDE-DOWII assembled elements such as light emitting diodes, ICs, and photodiodes, which are bonded to the heat sink on the active layer side rather than on the substrate side, a conductive paste such as epoxy resin containing Ag is used. High-speed bonding with a bonding time of 1 to 2 seconds is possible, but active fiI is not suitable for semiconductor laser devices.
Since the area is located far from the heat sink, it is not desirable in terms of heat dissipation effect. However, until now, UP
When a semiconductor laser chip was bonded to a heat sink using the -SIDE-DOWli method, the life of the semiconductor laser chip could not be expected, even though a submount was used. This is because the coefficient of thermal expansion of the resin component after the paste has hardened is significantly larger than that of the chip compared to the case of solder, and even if a slight temperature change occurs during operation of the semiconductor laser element, a large stress will be generated due to the difference in these coefficients of thermal expansion. It seems to work. The present invention has been made in view of the above points, and its purpose is to perform UP-SI[l! ! -An object of the present invention is to provide a semiconductor laser device that can maintain a long life even when assembled using the DOInN method. [Means for Solving the Problems] In order to solve the above problems, the present invention provides a method for mounting a semiconductor laser element on a heat sink having a submount.
! -0.5 to 3 as a material for bonding to DOWN
It uses conductive paste of Ag-containing epoxy resin with a thickness of n. [Function] Because the present invention is constructed as described above, the semiconductor laser element after bonding is not affected by internal stress during operation due to the conductive paste at a thickness within this range, and is equivalent to the conventional one. Moreover, since the conductive paste is used, the time required for bonding can be reduced to 176 times compared to the case of using conventional solder. [Example] The present invention will be implemented below. Let's explain based on an example. FIG. 1 is a schematic sectional view showing the main structure of a semiconductor laser device after assembly according to the present invention. In FIG. 1, the chip of the semiconductor laser device includes a semiconductor crystal substrate 2, an active region 114 having an active region 3 shaped by crystal or elongation on this substrate 2, and each necessary crystal elongation layer. First clad layer 5, second clad layer 6. It consists of a contact layer 7 and two electrode metals 8 and 9 formed by vapor deposition or plating. A submount 11 of Sl is bonded to the heat sink IO of a Cu stem for dissipating heat from the top of the chimp using solder or conductive paste, and a metal lwl2 of TtNi-Au is formed on the submount 11 by vapor deposition or the like. There is. In the present invention, a conductive paste layer 13 of epoxy I4 resin containing Ag having a predetermined thickness is applied to the surface of this metal layer 12, and the chip top and submount 11 are bonded together. Next, we will describe the procedure for obtaining such a joint structure. First, a submount 11 is formed on the heat sink 10 of the Cu stem, a metal layer 12 is formed on this submount 1l, and the metal FI 1 is formed.
An Ag-containing epoxy resin conductive paste layer 13 is applied to the entire surface or necessary portions of 2 to a predetermined thickness using a method such as screen printing or stamping. Thereafter, the chip is positioned UP-SIDE-DOWN, placed in a predetermined position so as to overlap the conductive paste layer 13 coated on the metal layer 12, and the whole is pressurized. At this time,
It is preferable to place the heat sink 10 on a heat plate (not shown) so that the submount 11 is heated to about 100°C. Then, the entire body is heated for 20 minutes using a tunnel furnace or constant temperature bath.
0℃, 40 seconds tree! Perform n conversion. Conductive paste layer 13
During curing, there is almost no change in the paste volume, so there is no need to apply pressure, and the accuracy of the light emitting point can be maintained when positioning on the chip. Regarding the net time required for die bonding, the resin curing time can be ignored since many pieces are processed at the same time, and the time required for positioning the typhoon soil is
It only takes seconds. 1/1/2 of the time traditionally required for this process
6 would be fine. Next, the thickness of the ag-containing epoxy resin conductive paste layer 13 was set to 0.1 μm. 0.5 Jlll 1 its. 2
n+ 3 items 4-15n, lQ4, 10 pieces of each thickness were fabricated using the above procedure to fabricate a semiconductor laser device having the structure shown in FIG. 1 with the chip top bonded to the submount 11, and the bonding In addition to examining the intensity, AgP. C. (
A lifespan test was conducted on the Automatic Power Control (Automatic Power Control) operation, and the results are shown in Table 1. 1st
The paste thickness in the table is the average value of each 10 pieces. Element life is expressed as mean failure time. For comparison, a conventional bonding structure using AuSn alloy solder is also shown.

第1表 第1表からAg入りエポキシ樹脂の導電性ペースト層1
3の厚さが0.5〜3μ間でAuSn半田を用いた従来
と同様の結果を得られることがわかる.導電性ペースト
層13の厚さが0.I nの最も薄い場合は十分な接合
強度を得ることができず、3nより厚くなるにつれて半
導体レーザ素子上の寿命は急激に低下してゆく.その原
因は導電性ペースト層13が薄いときは、温度上昇に対
してレーザチップ上との熱膨張によって発生する内部応
力は無視できる範囲であるが、厚さが増すに従って内部
応力が顕著に現われてレーザチソプ上の活性層4に直接
作用を及ぼすようになるからである.したがって本発明
で用いるAg入りエボキシ樹脂の導電性ぺ一スト層13
の厚さは0.5〜3nとするのが最適である. 以上のように本発明では半田の代わりに薄い導電性ペー
ストを用いて接合効率を高め、半田に起因する不都合な
点を除去し、半導体レーザ素子に従来と同様の寿命特性
を付与するものである.〔発明の効果〕 半導体レーザ素子をヒートシンクにマウントするための
材料は従来半田を用いていたので、接合効率が悪い上に
半田のはみ出しなど種々の問題があったが、本発明では
実施例で述べたように、半田の代わりに厚さが0.5〜
3nという薄いAg含有エポキシ樹脂の導電性ペースト
を用いたために、半田接合の場合と同等の寿命特性を持
ち、接合の正味所要時間は176で済ますことができ、
樹脂のはみ出しによる遮光なども起きないから歩留りよ
く高効率の組み立てが可能となった.
From Table 1 Table 1 Conductive paste layer 1 of Ag-containing epoxy resin
It can be seen that the same results as the conventional method using AuSn solder can be obtained when the thickness of No. 3 is between 0.5 and 3 μm. The thickness of the conductive paste layer 13 is 0. When In is the thinnest, sufficient bonding strength cannot be obtained, and as the thickness becomes thicker than 3n, the lifetime of the semiconductor laser device decreases rapidly. The reason for this is that when the conductive paste layer 13 is thin, the internal stress generated by thermal expansion with respect to the laser chip due to temperature rise can be ignored, but as the thickness increases, the internal stress becomes more noticeable. This is because it directly acts on the active layer 4 on the laser beam. Therefore, the conductive paste layer 13 of Ag-containing epoxy resin used in the present invention
The optimal thickness is 0.5 to 3 nm. As described above, the present invention uses a thin conductive paste instead of solder to improve bonding efficiency, eliminate the disadvantages caused by solder, and provide semiconductor laser elements with the same life characteristics as conventional ones. .. [Effects of the Invention] Conventionally, solder was used as the material for mounting the semiconductor laser element on the heat sink, which caused various problems such as poor bonding efficiency and solder protrusion. As shown above, instead of solder, the thickness is 0.5 ~
Because it uses a conductive paste of 3n Ag-containing epoxy resin, it has the same life characteristics as solder joints, and the net time required for joining is only 176 cm.
Since there is no light blocking due to resin protruding, it is possible to assemble with high yield and high efficiency.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はヒートシンクにマウントした構造を持つ本発明
の半導体レーザ素子の要部を示す模式断面図である.
Figure 1 is a schematic cross-sectional view showing the main parts of the semiconductor laser device of the present invention, which has a structure mounted on a heat sink.

Claims (1)

【特許請求の範囲】[Claims] 1)サブマウントを有するヒートシンクに活性層に近い
側の電極面をUP−SIDE−DOWNに接合した半導
体レーザ素子であって、この接合用材料として0.5〜
3μmの厚さを持つAg含有エポキシ樹脂の導電性ペー
ストを用いたことを特徴とする半導体レーザ素子。
1) A semiconductor laser device in which the electrode surface on the side closer to the active layer is bonded UP-SIDE-DOWN to a heat sink having a submount, and the bonding material is 0.5 to
A semiconductor laser device characterized by using a conductive paste of Ag-containing epoxy resin having a thickness of 3 μm.
JP24368289A 1989-09-20 1989-09-20 Semiconductor laser element Pending JPH03106089A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24368289A JPH03106089A (en) 1989-09-20 1989-09-20 Semiconductor laser element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24368289A JPH03106089A (en) 1989-09-20 1989-09-20 Semiconductor laser element

Publications (1)

Publication Number Publication Date
JPH03106089A true JPH03106089A (en) 1991-05-02

Family

ID=17107421

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24368289A Pending JPH03106089A (en) 1989-09-20 1989-09-20 Semiconductor laser element

Country Status (1)

Country Link
JP (1) JPH03106089A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0537089A (en) * 1991-07-25 1993-02-12 Mitsubishi Electric Corp Semiconductor laser device
JPH0722652A (en) * 1993-06-30 1995-01-24 Matsushita Electric Works Ltd Injection molded printed circuit board and manufacturing method thereof
JP2002158390A (en) * 2000-11-21 2002-05-31 Sharp Corp Semiconductor laser device manufacturing method and semiconductor laser device
US6967979B2 (en) 2000-10-06 2005-11-22 Sharp Kabushiki Kaisha Semiconductor laser device, optical pickup and fabrication method of semiconductor laser device
US6972205B2 (en) 1999-12-01 2005-12-06 Sharp Kabushiki Kaisha Semiconductor laser device, fabricating method thereof and optical pickup employing the semiconductor laser device
TWI460041B (en) * 2012-05-04 2014-11-11 Laser Tek Taiwan Co Ltd Method for applying laser solder device on shielding screen or soldering

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0537089A (en) * 1991-07-25 1993-02-12 Mitsubishi Electric Corp Semiconductor laser device
JPH0722652A (en) * 1993-06-30 1995-01-24 Matsushita Electric Works Ltd Injection molded printed circuit board and manufacturing method thereof
US6972205B2 (en) 1999-12-01 2005-12-06 Sharp Kabushiki Kaisha Semiconductor laser device, fabricating method thereof and optical pickup employing the semiconductor laser device
US6967979B2 (en) 2000-10-06 2005-11-22 Sharp Kabushiki Kaisha Semiconductor laser device, optical pickup and fabrication method of semiconductor laser device
JP2002158390A (en) * 2000-11-21 2002-05-31 Sharp Corp Semiconductor laser device manufacturing method and semiconductor laser device
TWI460041B (en) * 2012-05-04 2014-11-11 Laser Tek Taiwan Co Ltd Method for applying laser solder device on shielding screen or soldering

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