JPH03111495A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH03111495A JPH03111495A JP25111289A JP25111289A JPH03111495A JP H03111495 A JPH03111495 A JP H03111495A JP 25111289 A JP25111289 A JP 25111289A JP 25111289 A JP25111289 A JP 25111289A JP H03111495 A JPH03111495 A JP H03111495A
- Authority
- JP
- Japan
- Prior art keywords
- polypropylene glycol
- cleaning
- builder
- anionic
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 239000003599 detergent Substances 0.000 title claims abstract description 9
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 19
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 9
- 125000000129 anionic group Chemical group 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- 238000009472 formulation Methods 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 21
- 230000000694 effects Effects 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 10
- -1 sodium alkyl sulfate Chemical class 0.000 description 9
- UDVJSHMSCJKUAP-UHFFFAOYSA-L trisodium;n-sulfonatosulfamate Chemical compound [Na+].[Na+].[Na+].[O-]S(=O)(=O)NS([O-])(=O)=O UDVJSHMSCJKUAP-UHFFFAOYSA-L 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 241001274216 Naso Species 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 235000012000 cholesterol Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- PVNIQBQSYATKKL-UHFFFAOYSA-N tripalmitin Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HVYWMOMLDIMFJA-UHFFFAOYSA-N 3-cholesterol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 HVYWMOMLDIMFJA-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 206010018910 Haemolysis Diseases 0.000 description 1
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000008588 hemolysis Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- OBTSLRFPKIKXSZ-UHFFFAOYSA-N lithium potassium Chemical compound [Li].[K] OBTSLRFPKIKXSZ-UHFFFAOYSA-N 0.000 description 1
- 150000002646 long chain fatty acid esters Chemical class 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
- 229960001947 tripalmitin Drugs 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は新規な洗浄剤配合物に関するものであり、特に
アニオン、非イオン、両性各界面活性剤に、ビルダーと
して、
で表されるポリプロピレングリコール（式中、ｎは、１
０〜４０）を配合及びアニオン、非イオン、両性各界面
活性剤に、ビルダーとして、で表されるポリプロピレン
グリコール（式中、ｎは、１０〜４ｏ）と共に一般式（
ＭＳＯ，） ２ＮＭ’（■）（式中、Ｍはナトリウム、
カリウム、リチウム及びアンモニウムの中から選ばれる
カチオンを表し、Ｍ′は水素またはナトリウム・カリウ
ムリチウム及びアンモニウムの中から選ばれるカチオン
を表す）で表されるイミドビス硫酸塩を配合せしめてな
るそれぞれ安価にして低毒性かつ洗浄力に優れた新規洗
浄配合物に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to novel detergent formulations, in particular anionic, nonionic and amphoteric surfactants containing polypropylene glycol (wherein n is 1
0 to 40) and anionic, nonionic, and amphoteric surfactants, and as a builder, polypropylene glycol (in the formula, n is 10 to 4o) represented by the general formula (
MSO,) 2NM'(■) (where M is sodium,
(representing a cation selected from potassium, lithium and ammonium, and M' represents a cation selected from hydrogen or sodium, potassium lithium and ammonium). The present invention relates to a new cleaning formulation with low toxicity and excellent cleaning power.
［従来技術］
ビルダーは界面活性剤に配合した場合に界面活性剤の界
面活性を増加したり粉末の物性を向上させる効果を有す
るものと定義されるが、その特性として洗浄力、キレー
ト効果、分散力、乳化力、耐硬水性、腐食防止力、経済
性などに優れておりかつ無公害性であることが要求され
る。[Prior art] Builders are defined as having the effect of increasing the surfactant's surface activity and improving the physical properties of powder when added to surfactants, and their properties include detergency, chelating effect, and dispersion. It is required to have excellent strength, emulsifying power, hard water resistance, corrosion prevention power, economic efficiency, etc., and to be non-polluting.
［産業上の利用分野］
従来知られたビルダーとしては、トリポリリン酸ナント
リウムを初めとして各種リン酸塩、メタケイ酸ナトリウ
ム・ボウ硝、炭酸ナトリウムなどがあるが、前記要求特
性のすべてを満足するものはなく、実用上十分満足のい
くビルダーが開発されていたとはいえない。例えば、リ
ン酸塩の場合には、排水上に問題があり、通常のケイ酸
塩の場合には耐硬水性などの点で難点があり、またボウ
硝は安価であるが、ビルダー本来の性能に劣るといった
欠点を有している。これらのうちに一般にリン酸塩は洗
浄力等その優れたビルダー本来の性能から最も広く実用
され、従って、これらの有する欠点である環境上の問題
を解決し、更にビルダー本来の性能をも相乗的に向上せ
しめ得らればきわめて好都合である。[Industrial Application Fields] Conventionally known builders include nanthorium tripolyphosphate, various phosphates, sodium metasilicate/silicate, sodium carbonate, etc., but none satisfy all of the above-mentioned required properties. Therefore, it cannot be said that a builder that is sufficiently satisfactory for practical use has been developed. For example, phosphates have problems with drainage, regular silicate has problems with hard water resistance, and silicate is cheap, but it lacks the builder's original performance. It has the disadvantage that it is inferior to Among these, phosphates are generally the most widely used due to their excellent builder properties such as detergency, and therefore, they can solve the environmental problems that they have and also synergistically improve the builder properties. It would be extremely advantageous if this could be improved.
［発明が解決しようとする問題点コ
本発明者は、このような観点から、リン酸塩系洗剤に見
られるような前期欠点を克服し、性能、経済性とともに
、殊に公害性の面からも改善された洗浄剤配合物を開発
すべく鋭意研究を重ねた結果、界面活性剤に対して、ビ
ルダーとして、前記ポリプロピレングリコールを用い、
更にイミドビス硫酸塩等を適宜配合することにより目的
を達成し得ることを見出し、本発明を完成するに至った
。[Problems to be Solved by the Invention] From this perspective, the present inventors have attempted to overcome the drawbacks of phosphate-based detergents and to improve performance, economy, and especially from the standpoint of pollution. As a result of intensive research to develop cleaning agent formulations with improved cleaning properties, we found that using the polypropylene glycol as a builder for surfactants,
Furthermore, it was discovered that the object could be achieved by appropriately blending imidobis sulfate, etc., and the present invention was completed.
これらの各ビルダーはいずれも安価かつ低毒性であり、
洗浄力、安全性、経済性のいずれをも同時に達成される
という顕著な技術効果を得るものである。Each of these builders is cheap and has low toxicity;
This provides a remarkable technical effect in that cleaning power, safety, and economy are all achieved at the same time.
［問題点を解決するための手段］
本発明の必須成分であるポリプロピレングリコールは、
で表される。ｎは３〜数百にわたるが、水には約１３以
下が溶は易く、約３０以下が溶は難く、それ以上が不溶
である。アルコール、ケトン、エーテル、塩素化炭化水
素、炭化水素などの有機溶媒に溶は易いものである。無
色または微黄色の不揮発性液体で引火点は、１９８．９
〜２２６．７℃と高く毒性はほとんどない。[Means for Solving the Problems] Polypropylene glycol, which is an essential component of the present invention, is represented by the following formula. n ranges from 3 to several hundreds, but about 13 or less is easily soluble in water, about 30 or less is difficult to dissolve, and above that is insoluble. It is easily soluble in organic solvents such as alcohols, ketones, ethers, chlorinated hydrocarbons, and hydrocarbons. A colorless or slightly yellow non-volatile liquid with a flash point of 198.9
It has a high temperature of ~226.7°C and has almost no toxicity.
本発明による洗浄剤配合物は前記の通りポリプロピレン
グリコールを界面活性剤に配合し、更にイミドビス硫酸
塩相乗的ビルダー効果を達成しようとするものである。The detergent formulation according to the present invention combines polypropylene glycol with a surfactant as described above and further seeks to achieve an imidobis sulfate synergistic builder effect.
アニオン界面活性剤としては、例えばアルキル硫酸エス
テルナトリウム、 アルキルベンゼンスルホン酸ナトリ
ウム、長鎖α−オレフィンスルホン酸ナトリウム、アル
キルポリオキシアルキレンエーテル硫酸エステル塩など
の慣用のものを単独あるいは混合して用いることができ
る。また非イオン界面活性剤としては、例えばポリオキ
シエチレンアルキルエーテル、ポリオキシエチレン長鎖
脂肪酸エステル、ポリオキシエチレンポリオキシプロピ
レンブロックコポリマー、ポリオキシエチレンノニルフ
ェニルエーテル、長鎖脂肪酸アルキロールアミドなど、
両性界面活性剤としては、アルキルアミノプロピオン酸
アルキル、アルキルジメチルベタイン、アルキルジヒド
ロキシエチルベタイン、アルキルイミダシリン型などの
慣用のものを単独あるいは混合して適宜使用することが
できる。As the anionic surfactant, conventional surfactants such as sodium alkyl sulfate, sodium alkylbenzene sulfonate, sodium long-chain α-olefin sulfonate, and alkyl polyoxyalkylene ether sulfate salts can be used alone or in combination. . Examples of nonionic surfactants include polyoxyethylene alkyl ether, polyoxyethylene long chain fatty acid ester, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene nonylphenyl ether, long chain fatty acid alkylolamide, etc.
As the amphoteric surfactant, conventional surfactants such as alkyl alkylaminopropionates, alkyl dimethyl betaines, alkyl dihydroxyethyl betaines, and alkylimidacillin types can be used individually or in combination as appropriate.
更にトリアルキルアンモニウムハライド、アルキルピリ
ジニウムハライドなどのカチオン界面活性剤を殺菌や帯
電防止の目的で適宜併用することもできる。Furthermore, cationic surfactants such as trialkylammonium halides and alkylpyridinium halides may be appropriately used in combination for the purpose of sterilization and antistatic properties.
本発明洗浄剤組成物の必須成分であるイミドビス硫酸塩
（ｎ）は、イオウとアンモニアを原料として容易に製造
でき、また廃ＮＯｘガスの処理からも得られることから
極めて安価であると共に、そのイオウ含量もホウ硝の１
０％に比較しはるかに高くイオウの有効利用面からも優
れているといえる。Imidobis sulfate (n), which is an essential component of the cleaning composition of the present invention, can be easily produced from sulfur and ammonia as raw materials, and can also be obtained from the treatment of waste NOx gas, so it is extremely inexpensive and The content is also 1 of borax
It is much higher than 0% and can be said to be superior in terms of effective use of sulfur.
またこの化合物は富栄養化問題に関与しているといわれ
るリンを構造上含んでおらず、また窒素の含有量もアル
カリ金属塩は特に少ない。またこの化合物の水溶液は中
性ないし弱アルカリ性であり、ビルダーとして好適なｐ
Ｈ範囲を維持している。水溶性もビルダーとして不可欠
な要素であるが、この化合物はビルダーとしての使用に
十分な水溶性を有している。Furthermore, this compound structurally does not contain phosphorus, which is said to be involved in the problem of eutrophication, and the nitrogen content is particularly low in alkali metal salts. In addition, the aqueous solution of this compound is neutral to weakly alkaline, and is suitable as a builder.
Maintains H range. Water solubility is also an essential element as a builder, and this compound has sufficient water solubility for use as a builder.
イミドビス硫酸三ナトリウム（１水塩）の場合は、ｐＨ
１０，９、溶解度１９．７ （３０”Ｃ）及び６８．８
（４０℃）、リン含量０％、窒素含量５．４％である
。In the case of trisodium imidobis sulfate (monohydrate), the pH
10.9, solubility 19.7 (30”C) and 68.8
(40°C), phosphorus content is 0%, and nitrogen content is 5.4%.
また粉末洗浄用ビルグーの副次的性質として欠かせない
ものに結晶性、粉末安定性、流動性、造粒性、固結防止
性などがあるが、イミドビス硫酸塩類は概していずれも
満足すべき性能を有している。In addition, the essential secondary properties of powder cleaning virgoo include crystallinity, powder stability, fluidity, granulation properties, and anti-caking properties, and imidobis sulfates generally have satisfactory performance in all of them. have.
また、イミドビス硫酸三ナトリウムは急性経口毒性、皮
膚刺激性、魚毒性、溶血性などがいずれも極めて低く他
の塩も同様に考えられ実用的価値は著しく高い。In addition, trisodium imidobis sulfate has extremely low acute oral toxicity, skin irritation, fish toxicity, hemolysis, etc., and other salts can be considered similarly, so its practical value is extremely high.
イミド硫酸塩としては、例えば（ＮＨ４Ｓ○、）２ＮＨ
１（Ｎａ Ｓｏ、）２ＮＨ・２Ｈ２０などのイミドビス
硫酸塩（中性）、（ＮＨ４ＳＱ、）、ＮＮＨ４Ｈ２Ｏ、
（ＮａＳｏ、） ２ＮＮａ−Ｈ，０１（Ｎ ａ Ｓ Ｏ
，）、ＮＮａ・１２Ｈ２ｏなどのイミドビス硫酸塩（塩
基性）などをあげることができる。Examples of imidosulfate include (NH4S○,)2NH
Imidobis sulfate (neutral) such as 1(NaSo,)2NH・2H20, (NH4SQ, ), NNH4H2O,
(NaSo,) 2NNa-H,01(NaSO
), imidobis sulfates (basic) such as NNa.12H2o, and the like.
次に本発明における各ビルダーの配合割合を示す。Next, the blending ratio of each builder in the present invention will be shown.
界面活性剤とポリプロピレングリコールの配合比（Ｍ量
）は１：ｏ、１〜４、好マシくハ、に０．２〜２の範囲
で顕著な効果がみられる。界面活性剤とポリプロピレン
グリコール及びイミドビス硫酸三ナトリウムの配合比は
界面活性剤と両ビルダーの総計との比は前例同様であり
、両ピルダ」ｉは７：１〜１ニア、好ましくは３：１〜
１：３の顕著な結果が得られる。ポリプロピレングリコ
ールの効果はポリプロピレングリコールのカルシウムキ
レートカにイミドビス硫酸三ナトリウムのアルカリ性及
びキレート力が加わった効果及びポリプロピレングリコ
ールあるいはポリプロピレングリコールと界面活性剤の
混合による界面活性の向上によると考えられる。A remarkable effect can be seen when the blending ratio (M amount) of surfactant and polypropylene glycol is 1:o, 1 to 4, preferably 0.2 to 2. The blending ratio of the surfactant, polypropylene glycol, and trisodium imidobis sulfate is the same as the previous example, and the ratio of the surfactant to the total of both builders is 7:1 to 1, preferably 3:1 to 1.
A remarkable result of 1:3 is obtained. The effect of polypropylene glycol is thought to be due to the addition of the alkalinity and chelating power of trisodium imidobis sulfate to the calcium chelating power of polypropylene glycol, and the improvement of surface activity by mixing polypropylene glycol or polypropylene glycol with a surfactant.
なお当然のことながら、本発明の配合組成物に対しては
、必要に応じ種々のビルダー、すなわち炭酸ナトリウム
、ケイ酸ナトリウム、アルミノケイ酸ナトリウム、ＥＤ
ＴＡ、ＮＴＡ、クエン酸ナトリウムなどを配合すること
ができる。It goes without saying that various builders, such as sodium carbonate, sodium silicate, sodium aluminosilicate, ED
TA, NTA, sodium citrate, etc. can be blended.
［問題点を解決するための手段］
本発明の組成物は、前記から明かなようにいずれも毒性
、刺激性などがほとんどなく富栄養化なども起こさない
低公害性の物質でかつ経済的であり、優れた洗浄効果、
すなわちＰＰＧ添加のみで８０〜９０、ＴＳＩＳ配合（
系で約１ｏＯ１他成分配合系で約１１０などの満足すべ
き値が得られた。）
また、界面活性としては、洗浄に限らず、浸透、乳化、
分散、可溶化などの諸用途に用いることも可能である。[Means for Solving the Problems] As is clear from the above, the composition of the present invention is an economical and low-pollution material that has almost no toxicity or irritation, and does not cause eutrophication. Yes, excellent cleaning effect,
That is, 80-90 with PPG addition alone, and 80-90 with TSIS combination (
Satisfactory values were obtained, such as approximately 10O1 for the system and approximately 110 for the system containing other components. ) In addition, surface activity is not limited to cleaning, but also has benefits such as penetration, emulsification,
It can also be used for various purposes such as dispersion and solubilization.
［実施例］ 次に本発明を実施例により、更に詳廁に説明する。[Example] Next, the present invention will be explained in more detail with reference to Examples.
試験方法
人工汚垢は日本サンホーム（１９７１）式、洗浄力試験
法は日本油化学協会法にそれぞれ準じて行った。Test method: Artificial stains were tested according to the Nippon Sunhome (1971) method, and detergency test methods were performed according to the Japan Oil Chemists' Association method.
（１）人工汚染布（モメン）の形成
油分８部、カーボンブラック０．４０−０．４５部及び
パークレン８００部から汚染浴にモメン布を１分間浸漬
した後、風乾して人工汚染布を形成した。なお、油分の
組成は、オレイン酸１５部、パルミチン酸７．５部、ミ
リスチン酸７．５部トリオレイン１５部、トリパルミチ
ン１５部、コレステリン１０部、スクヮレン５部、流動
パラフィン１０部、セメノール１０部、コレステロール
パルミ−８５部からなるものであった。(1) Formation of artificially contaminated cloth (Momen) Soak Momen cloth in a contaminated bath for 1 minute with 8 parts of oil, 0.40-0.45 parts of carbon black, and 800 parts of Parkrene, and then air dry to form artificially contaminated cloth. did. The oil composition is 15 parts of oleic acid, 7.5 parts of palmitic acid, 7.5 parts of myristic acid, 15 parts of triolein, 15 parts of tripalmitin, 10 parts of cholesterin, 5 parts of squalene, 10 parts of liquid paraffin, and semenol. It consisted of 10 parts of cholesterol and 85 parts of cholesterol palmy.
（２）洗浄試験
前記のようにして得た人工汚染布（寸法５×１０ｃｍ）
４枚を、内部に鋼球（直径６．５ｍｍ）１０個を有する
内容積４００ ｍ Ｑの洗浄ビンに入れ、ラウンダオメ
ーターを用い、次の条件下で洗浄した。(2) Cleaning test Artificially contaminated cloth obtained as described above (dimensions 5 x 10 cm)
The four pieces were placed in a cleaning bottle with an internal volume of 400 m Q containing 10 steel balls (diameter 6.5 mm), and washed using a round-o-meter under the following conditions.
第１表
１ ） ５０ ｐ ｐ ｒｎ ； Ｃａ ＣＯ５（３
）洗浄効率（％）及び洗浄指数（％）の算出法
洗浄力は次の式により求めた。Table 1 1) 50 p p rn ; Ca CO5 (3
) Calculation method of cleaning efficiency (%) and cleaning index (%) The cleaning power was calculated using the following formula.
Ｒ′：原布の反射率 Ｒｏ：洗浄前の汚染布の反射率 なお、反射率はグリーンフィルターを通して測定した。R': Reflectance of original fabric Ro: Reflectance of contaminated cloth before cleaning Note that the reflectance was measured through a green filter.
また、洗浄指数は第２表に示した実用に近い基準洗剤を
用いて同一条件下で洗浄した場合の洗浄効率に対する、
測定洗浄効率の％により表わす。In addition, the cleaning index is the cleaning efficiency when cleaning under the same conditions using the standard detergent that is close to practical as shown in Table 2.
It is expressed as a percentage of the measured cleaning efficiency.
第２表
基本洗剤の組成
１）
トリポリリン酸ナトリウム
２）カルボキシメチルセルロース
実施例１
アニオン及び非イオン界面活性剤に各種の分子量のポリ
プロピレングリコール（ｐｐＧ）を加え、洗浄力を求め
た結果、第３表のＮｏ、１〜９に示す６分子量の４００
〜２ｏＯＯ１特に１０００〜１２００付近で顕著なビル
ダー効果が現れていることが明らかである。Table 2 Composition of basic detergent 1) Sodium tripolyphosphate 2) Carboxymethylcellulose Example 1 Polypropylene glycol (ppG) of various molecular weights was added to anionic and nonionic surfactants, and the cleaning power was determined. No. 400 with 6 molecular weights shown in 1 to 9
~2oOO1 It is clear that a remarkable builder effect appears especially around 1000 to 1200.
実施例２
アニオン及び非イオン界面活性剤に各種の分子量のポリ
プロピレングリコールの４００．１０００．１２００と
イミドビス硫酸三ナトリウム（ＴＳＩＳ）を種々の割合
で配合した場合の洗浄力を第１図に示す、ポリプロピレ
ングリコールとイミドビスａ酸三ナトリウムの３：ｌ〜
ｌ：３の範囲で顕著な相乗効果がみられた。Example 2 The cleaning power of polypropylene glycol 400.1000.1200 with various molecular weights and trisodium imidobis sulfate (TSIS) in various proportions is shown in Fig. 1 as anionic and nonionic surfactants. 3:l of glycol and trisodium imidobisa acid
A significant synergistic effect was observed in the l:3 range.
実施例３
更に各種ビルダーを補足した場合及び非イオン界面活性
剤を用いた場合を第３表のＮｏ、１０〜１３に示す、洗
浄力が更に向上し配合効果が顕著にマｎれていることが
明らかである。Example 3 The cases in which various builders were further supplemented and the cases in which nonionic surfactants were used are shown in Nos. 10 to 13 in Table 3, and the detergency was further improved and the blending effect was significantly improved. is clear.
第１図は、ＬＡＳにＴＳＩＳ及びＰＰＧを種々の割合で
配合した場合の、洗浄効率と配合割合の関係を示す図で
あり、特にＰＰＧの１０００ないし１２００とＴＳＩＳ
間の各配合物に顕著な相乗効果が表れることを示したも
のである。FIG. 1 is a diagram showing the relationship between cleaning efficiency and blending ratio when LAS is blended with TSIS and PPG in various ratios.
This shows that each formulation in between has a remarkable synergistic effect.
Claims (2)
ダーとして、 一般式（ I ） ▲数式、化学式、表等があります▼ で表されるポリプロピレングリコール（式中、ｎは、１
０〜４０）を配合してなる洗浄剤配合物。(1) For anionic, nonionic, and amphoteric surfactants, polypropylene glycol (where n is 1
0 to 40).
ダーとして、 一般式（ I ） ▲数式、化学式、表等があります▼ で表されるポリプロピレングリコール（式中、ｎは、１
０〜４０）と共に一般式（ＭＳＯ＿３）＿２ＮＭ’（I
I）（式中、Ｍはナトリウム、カリウム、リチウム及び
アンモニウムの中から選ばれるカチオンを表し、Ｍ’は
水素またはナトリウム、カリウム、リチウム及びアンモ
ニウムの中から選ばれるカチオンを表す）で表されるイ
ミドビス硫酸塩を配合してなる洗浄剤配合物。(2) For anionic, nonionic, and amphoteric surfactants, polypropylene glycol (where n is 1
0 to 40) together with the general formula (MSO_3)_2NM'(I
I) (wherein M represents a cation selected from sodium, potassium, lithium and ammonium, and M' represents hydrogen or a cation selected from sodium, potassium, lithium and ammonium) A detergent formulation containing sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1251112A JPH0631410B2 (en) | 1989-09-27 | 1989-09-27 | Detergent formulations |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1251112A JPH0631410B2 (en) | 1989-09-27 | 1989-09-27 | Detergent formulations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03111495A true JPH03111495A (en) | 1991-05-13 |
| JPH0631410B2 JPH0631410B2 (en) | 1994-04-27 |
Family
ID=17217832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1251112A Expired - Lifetime JPH0631410B2 (en) | 1989-09-27 | 1989-09-27 | Detergent formulations |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0631410B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017048330A (en) * | 2015-09-03 | 2017-03-09 | ライオン株式会社 | Liquid detergent for clothing |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51135905A (en) * | 1975-05-21 | 1976-11-25 | Lion Corp | Liquid detergent composition |
| JPS5239706A (en) * | 1975-09-25 | 1977-03-28 | Sunstar Inc | Liquid detergent composition |
| JPS5335711A (en) * | 1976-09-14 | 1978-04-03 | Kao Corp | Neutral liquid detergent composition |
| JPS5742800A (en) * | 1980-08-28 | 1982-03-10 | Shiseido Co Ltd | Transparent soap |
| JPS58101198A (en) * | 1981-12-09 | 1983-06-16 | ライオン株式会社 | Liquid detergent composition |
| JPS61157593A (en) * | 1984-12-28 | 1986-07-17 | ライオン株式会社 | Detergent composition for bathroom |
-
1989
- 1989-09-27 JP JP1251112A patent/JPH0631410B2/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51135905A (en) * | 1975-05-21 | 1976-11-25 | Lion Corp | Liquid detergent composition |
| JPS5239706A (en) * | 1975-09-25 | 1977-03-28 | Sunstar Inc | Liquid detergent composition |
| JPS5335711A (en) * | 1976-09-14 | 1978-04-03 | Kao Corp | Neutral liquid detergent composition |
| JPS5742800A (en) * | 1980-08-28 | 1982-03-10 | Shiseido Co Ltd | Transparent soap |
| JPS58101198A (en) * | 1981-12-09 | 1983-06-16 | ライオン株式会社 | Liquid detergent composition |
| JPS61157593A (en) * | 1984-12-28 | 1986-07-17 | ライオン株式会社 | Detergent composition for bathroom |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017048330A (en) * | 2015-09-03 | 2017-03-09 | ライオン株式会社 | Liquid detergent for clothing |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0631410B2 (en) | 1994-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69508967T2 (en) | SILICATE-FREE MEDIUM, NOT AGGRESSIVE TO SOFT METALS | |
| US3814692A (en) | Free flowing soap-nonionic detergent | |
| US3850854A (en) | Novel detergent composition | |
| JPH0231759B2 (en) | ||
| EP0030461B1 (en) | Detergent composition | |
| US5767050A (en) | Light duty liquid cleaning compositions comprising partially esterified polyhydric alcohol solubilizing agent | |
| JPS5920754B2 (en) | industrial metal cleaning agent | |
| JPS61166895A (en) | Liquid detergent composition | |
| CN104480489A (en) | Environment-friendly efficient train cleaning agent and preparation method thereof | |
| DE69819698T2 (en) | TRANSPARENT LIQUID DETERGENT CONTAINING ALKYLBENZENE SULFONATE AND SODIUM SILICATE | |
| CN104480482A (en) | Special cleaning solution for slightly alkaline chemical equipment | |
| JPWO1999031209A1 (en) | A clear liquid cleaner containing alkylbenzene sulfonate anionic surfactant and sodium silicate. | |
| CA1202853A (en) | Cleaning compositions | |
| JPH0425319B2 (en) | ||
| US5707955A (en) | High foaming nonionic surfactant based liquid detergent | |
| US5906972A (en) | Liquid detergent composition | |
| JPS63168499A (en) | Liquid saponifying composition utilizing waste oil | |
| JPH04249599A (en) | Cleaning composition which gives improvement in reducing mash and/or improvement in mildness | |
| JPH0631410B2 (en) | Detergent formulations | |
| CN104498970A (en) | Chemical equipment detergent | |
| DE69200612T2 (en) | Liquid concentrated detergent composition containing polyphosphonate complexing agents. | |
| CN113355175A (en) | Trace efficient laundry detergent and preparation method thereof | |
| FI60029C (en) | DETERGENTKOMPOSITION | |
| JP3193322B2 (en) | Liquid detergent composition | |
| SU950759A1 (en) | Detergent and desinfectant for cleaning milk-processing equipment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |