JPH03121404A - ガラスファイバー - Google Patents

ガラスファイバー

Info

Publication number: JPH03121404A
Authority: JP; Japan
Prior art keywords: coating; radiation; low; coating composition; groups
Prior art date: 1990-09-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP2233084A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0551546B2 (fr

Inventor

E Ansel Robert

ロバート　イー．アンセル

Jr Orvid R Cutler

オービツド　レイ　カツトラー，ジユニア

Timothy E Bishop

テイモシイ　イー．ビシヨプ

George Pasternack

ジヨージ　パスターナツク

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

DeSoto Inc

Original Assignee

DeSoto Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-09-03

Filing date

1990-09-03

Publication date

1991-05-23

1990-09-03 Application filed by DeSoto Inc filed Critical DeSoto Inc

1990-09-03 Priority to JP2233084A priority Critical patent/JPH03121404A/ja

1991-05-23 Publication of JPH03121404A publication Critical patent/JPH03121404A/ja

1993-08-02 Publication of JPH0551546B2 publication Critical patent/JPH0551546B2/ja

Status Granted legal-status Critical Current

Links

239000003365 glass fiber Substances 0.000 title description 4
229920002635 polyurethane Polymers 0.000 claims abstract description 12
239000004814 polyurethane Substances 0.000 claims abstract description 12
239000000835 fiber Substances 0.000 claims abstract description 10
239000000178 monomer Substances 0.000 claims abstract description 8
XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 6
230000009477 glass transition Effects 0.000 claims abstract description 3
239000008199 coating composition Substances 0.000 claims description 20
230000005855 radiation Effects 0.000 claims description 12
239000005304 optical glass Substances 0.000 claims description 3
229920001519 homopolymer Polymers 0.000 claims 1
238000000576 coating method Methods 0.000 abstract description 39
239000011248 coating agent Substances 0.000 abstract description 28
NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 6
239000012530 fluid Substances 0.000 abstract description 4
238000005452 bending Methods 0.000 abstract description 3
239000000853 adhesive Substances 0.000 abstract description 2
230000001070 adhesive effect Effects 0.000 abstract description 2
238000005510 radiation hardening Methods 0.000 abstract 3
NBZANZVJRKXVBH-GYDPHNCVSA-N alpha-Cryptoxanthin Natural products O[C@H]1CC(C)(C)C(/C=C/C(=C\C=C\C(=C/C=C/C=C(\C=C\C=C(/C=C/[C@H]2C(C)=CCCC2(C)C)\C)/C)\C)/C)=C(C)C1 NBZANZVJRKXVBH-GYDPHNCVSA-N 0.000 abstract 2
125000005442 diisocyanate group Chemical group 0.000 description 8
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
-1 alkane diols Chemical class 0.000 description 7
239000011521 glass Substances 0.000 description 7
239000013307 optical fiber Substances 0.000 description 6
239000000047 product Substances 0.000 description 5
FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
239000004721 Polyphenylene oxide Substances 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical group OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
229920000728 polyester Polymers 0.000 description 4
229920000570 polyether Polymers 0.000 description 4
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 3
RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 3
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
125000004386 diacrylate group Chemical group 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
125000005395 methacrylic acid group Chemical group 0.000 description 3
238000000034 method Methods 0.000 description 3
239000000203 mixture Substances 0.000 description 3
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
229920001296 polysiloxane Polymers 0.000 description 3
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
238000005299 abrasion Methods 0.000 description 2
235000011037 adipic acid Nutrition 0.000 description 2
239000001361 adipic acid Substances 0.000 description 2
239000002671 adjuvant Substances 0.000 description 2
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
239000012965 benzophenone Substances 0.000 description 2
238000001723 curing Methods 0.000 description 2
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
125000004356 hydroxy functional group Chemical group O* 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
125000002768 hydroxyalkyl group Chemical group 0.000 description 2
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
238000003847 radiation curing Methods 0.000 description 2
239000002904 solvent Substances 0.000 description 2
229940096522 trimethylolpropane triacrylate Drugs 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
VNQXSTWCDUXYEZ-UHFFFAOYSA-N 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2(C)C(=O)C(=O)C1C2(C)C VNQXSTWCDUXYEZ-UHFFFAOYSA-N 0.000 description 1
UUWJBXKHMMQDED-UHFFFAOYSA-N 1-(3-chlorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(Cl)=C1 UUWJBXKHMMQDED-UHFFFAOYSA-N 0.000 description 1
WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
NJHYAKBXVZUFMU-UHFFFAOYSA-N C(C)OC(C=C)=O.[O] Chemical compound C(C)OC(C=C)=O.[O] NJHYAKBXVZUFMU-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000005058 Isophorone diisocyanate Substances 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
229920002396 Polyurea Polymers 0.000 description 1
244000028419 Styrax benzoin Species 0.000 description 1
235000000126 Styrax benzoin Nutrition 0.000 description 1
235000008411 Sumatra benzointree Nutrition 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
125000000746 allylic group Chemical group 0.000 description 1
230000001668 ameliorated effect Effects 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
150000004056 anthraquinones Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
229960002130 benzoin Drugs 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229930006711 bornane-2,3-dione Natural products 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229910021419 crystalline silicon Inorganic materials 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
239000004205 dimethyl polysiloxane Substances 0.000 description 1
235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
XVKKIGYVKWTOKG-UHFFFAOYSA-N diphenylphosphoryl(phenyl)methanone Chemical compound C=1C=CC=CC=1P(=O)(C=1C=CC=CC=1)C(=O)C1=CC=CC=C1 XVKKIGYVKWTOKG-UHFFFAOYSA-N 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
125000001033 ether group Chemical group 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
235000019382 gum benzoic Nutrition 0.000 description 1
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
239000004611 light stabiliser Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229950000688 phenothiazine Drugs 0.000 description 1
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
RSVDRWTUCMTKBV-UHFFFAOYSA-N sbb057044 Chemical compound C12CC=CC2C2CC(OCCOC(=O)C=C)C1C2 RSVDRWTUCMTKBV-UHFFFAOYSA-N 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
GBGATMPHTZEUHH-UHFFFAOYSA-N trimethoxysilane hydrochloride Chemical compound Cl.CO[SiH](OC)OC GBGATMPHTZEUHH-UHFFFAOYSA-N 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1
230000003313 weakening effect Effects 0.000 description 1

Landscapes

Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)
Macromonomer-Based Addition Polymer (AREA)

JP2233084A 1990-09-03 1990-09-03 ガラスファイバー Granted JPH03121404A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP2233084A JPH03121404A (ja)	1990-09-03	1990-09-03	ガラスファイバー

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP2233084A JPH03121404A (ja)	1990-09-03	1990-09-03	ガラスファイバー

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
JP58045842A Division JPH0645766B2 (ja)	1983-03-18	1983-03-18	放射線硬化性コーティング組成物

Publications (2)

Publication Number	Publication Date
JPH03121404A true JPH03121404A (ja)	1991-05-23
JPH0551546B2 JPH0551546B2 (fr)	1993-08-02

Family

ID=16949549

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2233084A Granted JPH03121404A (ja)	1990-09-03	1990-09-03	ガラスファイバー

Country Status (1)

Country	Link
JP (1)	JPH03121404A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2002060444A (ja) *	2000-07-31	2002-02-26	Alcatel	光ファイバー用速硬化ｕｖ硬化性コーティング層配合物
JP2005524094A (ja) *	2002-04-24	2005-08-11	ディーエスエムアイピーアセッツビー．ブイ．	コートされた光ファイバー

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS4828533A (fr) *	1971-08-18	1973-04-16
JPS5737179A (en) *	1980-08-14	1982-03-01	Usui Kokusai Sangyo Kk	Pipe end connection head structure and its forming method in double wound steel pipe
US4324575A (en) *	1980-08-11	1982-04-13	Bell Telephone Laboratories, Incorporated	Low TG soft UV-curable coatings

1990
- 1990-09-03 JP JP2233084A patent/JPH03121404A/ja active Granted

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS4828533A (fr) *	1971-08-18	1973-04-16
US4324575A (en) *	1980-08-11	1982-04-13	Bell Telephone Laboratories, Incorporated	Low TG soft UV-curable coatings
JPS5737179A (en) *	1980-08-14	1982-03-01	Usui Kokusai Sangyo Kk	Pipe end connection head structure and its forming method in double wound steel pipe

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2002060444A (ja) *	2000-07-31	2002-02-26	Alcatel	光ファイバー用速硬化ｕｖ硬化性コーティング層配合物
JP2005524094A (ja) *	2002-04-24	2005-08-11	ディーエスエムアイピーアセッツビー．ブイ．	コートされた光ファイバー
JP4922549B2 (ja) *	2002-04-24	2012-04-25	ディーエスエムアイピーアセッツビー．ブイ．	コートされた光ファイバー

Also Published As

Publication number	Publication date
JPH0551546B2 (fr)	1993-08-02

Publication	Publication Date	Title
EP0111280B1 (fr)	1987-05-06	Fibre optique à revêtement unique
US4472019A (en)	1984-09-18	Topcoats for buffer-coated optical fiber using urethane acrylate and epoxy acrylate and vinyl monomer
EP0208845B1 (fr)	1992-02-26	Revêtements durcissables par rayons ultraviolets pour fibre de verre optique
US4798852A (en)	1989-01-17	Ultraviolet curable coatings for optical glass fiber
US4472021A (en)	1984-09-18	Strippable radiation-cured coatings for optical fiber and method
US5416880A (en)	1995-05-16	Optical fibre coatings and method for producing same
US4629287A (en)	1986-12-16	Ultraviolet curable buffer coatings for optical fiber
US4682851A (en)	1987-07-28	Soft and tough radiation-curable coatings for fiber optic application
EP0113779B1 (fr)	1987-01-14	Revetements de polysiloxane insature flexibles a faible temperature et polymerisables sous l'effet de radiation pour des applications dans des fibres optiques
US4624994A (en)	1986-11-25	Soft and tough radiation-curable coatings for fiber optic application
US6180741B1 (en)	2001-01-30	Liquid curable resin composition
US4690501A (en)	1987-09-01	Ultraviolet curable optical glass fiber coatings from acrylate terminated, end-branched polyurethane polyurea oligomers
JPS61276863A (ja)	1986-12-06	紫外線硬化性液体被覆組成物
JPS6320312A (ja)	1988-01-28	紫外線硬化性液体被覆組成物
EP0149741B1 (fr)	1989-08-09	Composition de revêtement liquide, durcissable par rayons et fibres optiques de verre ainsi recouvertes
JPS59170154A (ja)	1984-09-26	放射線硬化性コ−テイング組成物
JPH03121404A (ja)	1991-05-23	ガラスファイバー
JPH0221424B2 (fr)	1990-05-14
JP2509409B2 (ja)	1996-06-19	ガラス表面を被覆するための放射線硬化可能なオリゴマ―の製造法
CA1292752C (fr)	1991-12-03	Enrobage durcissable aux ultraviolets pour fibres de verre d'optique
EP0250631A1 (fr)	1988-01-07	Revêtements-tampons réticulables par les rayons ultraviolets pour les fibres optiques
US4564666A (en)	1986-01-14	Urethane acrylates based on polyepichlorohydrin polyether diols and optical fiber coatings based thereon
JPH0453824B2 (fr)	1992-08-27