JPH0319683B2 - - Google Patents
Info
- Publication number
- JPH0319683B2 JPH0319683B2 JP12678282A JP12678282A JPH0319683B2 JP H0319683 B2 JPH0319683 B2 JP H0319683B2 JP 12678282 A JP12678282 A JP 12678282A JP 12678282 A JP12678282 A JP 12678282A JP H0319683 B2 JPH0319683 B2 JP H0319683B2
- Authority
- JP
- Japan
- Prior art keywords
- thin plate
- rolls
- core
- sec
- thin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011162 core material Substances 0.000 description 27
- 239000000463 material Substances 0.000 description 18
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 238000005096 rolling process Methods 0.000 description 9
- 238000010791 quenching Methods 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 230000004907 flux Effects 0.000 description 3
- 239000000696 magnetic material Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 229910000702 sendust Inorganic materials 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910001017 Alperm Inorganic materials 0.000 description 1
- 229910020711 Co—Si Inorganic materials 0.000 description 1
- 229910000976 Electrical steel Inorganic materials 0.000 description 1
- 229910017082 Fe-Si Inorganic materials 0.000 description 1
- 229910017133 Fe—Si Inorganic materials 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910018619 Si-Fe Inorganic materials 0.000 description 1
- 229910008289 Si—Fe Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000005300 metallic glass Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
- H01F41/0206—Manufacturing of magnetic cores by mechanical means
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Magnetic Heads (AREA)
Description
【発明の詳細な説明】
本発明は、例えば融体超急冷法を採用すること
により、特に磁気ヘツド、トランス等のコア材を
形成する場合に好適な材料としての軟磁性薄板に
関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a soft magnetic thin plate as a material suitable for forming a core material of a magnetic head, a transformer, etc., by employing, for example, a melt ultra-quenching method.
磁気ヘツド、トランス等のコア材としては、セ
ンダスト合金、アルパーム合金、高珪素鋼などの
硬くて脆い軟磁性材料が用いられる場合がある
が、軟磁性材料はロールによる圧延が困難である
ため研削などの方法でブロツクからコア材を切り
出したり、研磨加工、ラツピング加工を経てコア
を製造していた。しかしこの方法では、生産性が
著しく悪く、コアの加工費が高くなつてしまう。
更に製作できるコアの板厚には限度があり、極薄
(500μm以下)は難しい。 Hard and brittle soft magnetic materials such as Sendust alloy, Alperm alloy, and high-silicon steel are sometimes used as core materials for magnetic heads, transformers, etc., but since soft magnetic materials are difficult to roll with rolls, grinding, etc. The core was manufactured by cutting out the core material from the block using the method described above, and through polishing and wrapping. However, with this method, productivity is extremely low and core processing costs are high.
Furthermore, there is a limit to the thickness of the core that can be manufactured, and it is difficult to make it extremely thin (less than 500 μm).
他方、物理的蒸着、化学的蒸着、スパツタリン
グなどの方法によつてもコア材が形成されてい
た。しかし蒸着、スパツタリング等も生産性が悪
い。 On the other hand, core materials have also been formed by methods such as physical vapor deposition, chemical vapor deposition, and sputtering. However, vapor deposition, sputtering, etc. are also poor in productivity.
また蒸着やスパツタリング等では薄板の組成を
厳密に制御することが難かしく、優れた磁気特性
の薄板を製造できなかつた。 Furthermore, it is difficult to strictly control the composition of the thin plate by vapor deposition, sputtering, etc., and it has been impossible to produce a thin plate with excellent magnetic properties.
最近、硬くて脆い軟磁性材料でコアを製造する
場合、融体超急冷法で軟磁性薄板を製造する方法
が行われるようになつてきた。 Recently, when manufacturing a core from a hard and brittle soft magnetic material, a method of manufacturing a soft magnetic thin plate using a melt ultra-quenching method has come to be used.
この方法では簡単な工程で一挙に薄板が製造さ
れるため生産性が良く、得られた薄板の磁気特性
も一般に優れており、実用性の高い加工法と言え
る。 In this method, thin plates are manufactured in one step in a simple process, so productivity is high, and the magnetic properties of the obtained thin plates are generally excellent, so it can be said to be a highly practical processing method.
このようにして製造された薄板からコアを取り
して磁気ヘツドやトランスなどに使用する場合、
コアの占積率を高くする必要があることから、表
面の平滑な薄板が要求される。 When cores are taken from thin sheets manufactured in this way and used in magnetic heads, transformers, etc.
Since it is necessary to increase the space factor of the core, a thin plate with a smooth surface is required.
表面が平滑な薄板を製作する方法としては、超
急冷加工法の中で第1図に示すような双ロール法
が採用されている。即ち、0は融体超急冷装置の
一例を示したもので、この融体超急冷装置0は、
耐熱容器1内で溶融された溶融母材2がロール
3,3に噴出すべきノズル1Aを先端に設け、ま
た耐熱容器1の外周に懸回した抵抗加熱ヒータH
または高周波加熱などの適当な加熱手段によつて
耐熱容器1内に収納された溶融母材2を加熱す
る。 As a method for producing a thin plate with a smooth surface, a twin roll method as shown in FIG. 1 is adopted among the ultra-quench processing methods. That is, 0 shows an example of a melt super-quenching device, and this melt super-quenching device 0 is as follows:
A resistance heater H is provided at its tip with a nozzle 1A through which the molten base material 2 melted in the heat-resistant container 1 is ejected onto the rolls 3, 3, and is suspended around the outer periphery of the heat-resistant container 1.
Alternatively, the molten base material 2 housed in the heat-resistant container 1 is heated by appropriate heating means such as high-frequency heating.
そしてヒータHなどの加熱手段によつて耐熱容
器1内で加熱された溶融母材2を耐熱容器1内に
アルゴンガスなどの不活性ガスを導入し、圧力を
瞬時に高めることによりノズル1Aからロール
3,3に噴出しローラ表面で超急冷し、ロール
3,3内で圧延することによつて薄板4′を得る。
このようにロール3,3間で圧延することによ
り、第2図に示すように断面凸面形の薄板41′を
得る。これはロール3,3間で圧延された溶融母
材2が、ロール3,3の表面で冷却され、剛性が
増し、ロール3,3の表面を弾性変形させて断面
凸面形とする。 Then, the molten base material 2 heated in the heat-resistant container 1 by a heating means such as a heater H is introduced into the heat-resistant container 1 with an inert gas such as argon gas, and by instantly increasing the pressure, the molten base material 2 is rolled from the nozzle 1A. A thin plate 4' is obtained by ultra-quenching the material on the surface of the jetting rollers 3, 3 and rolling it within the rollers 3, 3.
By rolling between the rolls 3 and 3 in this manner, a thin plate 4 1 ' having a convex cross section as shown in FIG. 2 is obtained. This is because the molten base material 2 rolled between the rolls 3, 3 is cooled on the surfaces of the rolls 3, 3, and its rigidity increases, and the surfaces of the rolls 3, 3 are elastically deformed to have a convex cross section.
このような形状を有する薄板41′を、積層して
使用する場合、第3図のように占積率の悪いコア
となる。また積層したときの安定性が悪く、コア
材の左右の厚さを等しくすることが難かしかつ
た。 When the thin plates 4 1 ' having such a shape are used in a stacked manner, the result is a core with a poor space factor as shown in FIG. 3. Furthermore, the stability when laminated was poor, and it was difficult to make the thickness of the left and right sides of the core material equal.
また双ロール法で薄板41′を製造する場合、溶
融母材2の溶解温度、ノズル1Aからの噴出速
度、ロール3の表面の周速度、ロール3の直径、
ロール3の圧延荷重などが薄板41′の形状を決め
る主な要因となる。 In addition, when manufacturing the thin plate 4 1 ' by the twin roll method, the melting temperature of the molten base material 2, the jetting speed from the nozzle 1A, the circumferential speed of the surface of the roll 3, the diameter of the roll 3,
The rolling load of the rolls 3 and the like are the main factors that determine the shape of the thin plate 4 1 ′.
本発明は上述の如き点に鑑みてなされたもので
その目的とするところは、凸面形の薄板をより平
坦化したことにより機械的に強く、またラミネー
ト・コアを形成した場合のコアの占積率が高く、
材料本来の性能、例えば磁束密度、透磁率の性能
を活かすことができ、またコア材を積層するのに
用いる接着剤の厚さが均一で薄くできるので接着
力が強く、剥離し易い等のトラブルが少ない軟磁
性薄板を提供するのにある。 The present invention has been made in view of the above points, and its purpose is to improve mechanical strength by flattening a convex thin plate, and to improve the core space when a laminated core is formed. The rate is high;
The inherent properties of the material, such as magnetic flux density and magnetic permeability, can be utilized, and the thickness of the adhesive used to laminate the core material can be made uniform and thin, resulting in strong adhesive strength and problems such as easy peeling. The aim is to provide a soft magnetic thin plate with less oxidation.
以下本発明の詳細を図面に従つて説明する。 The details of the present invention will be explained below with reference to the drawings.
そして第1図に示す融体超急冷装置0のローラ
3,3に溶融母材2を噴出させて超急冷し、その
後ローラ3,3で圧延することによつて断面形状
が略凸面形に形成されて且つその中央部に長手方
向の上下面に伸びるような凹条溝4A,4Aを有
する薄板4を形成する。 Then, the molten base material 2 is jetted out to the rollers 3, 3 of the melt super-quenching device 0 shown in FIG. A thin plate 4 is formed which has concave grooves 4A, 4A extending in the upper and lower surfaces in the longitudinal direction at the center thereof.
上記薄板4を製造するための条件としては、双
ロール法の薄板形状を決める主な要素のうち、特
に溶融母材温度、ロール3,3の直径、ロール
3,3の周速度が重要となる。またノズル1Aの
噴出速度を0.2c.c./sec以上、ロール3,3の圧延
荷重を0.2ton以上に設定した場合の溶融母材温度
は、材料の融点より30℃以上、高く選ばれる。 Among the main factors that determine the shape of the thin plate using the twin-roll method, the conditions for manufacturing the thin plate 4 mentioned above are particularly important, such as the temperature of the molten base material, the diameter of the rolls 3, and the circumferential speed of the rolls 3, 3. . Further, when the ejection speed of the nozzle 1A is set to 0.2 cc/sec or more and the rolling load of the rolls 3, 3 is set to 0.2 ton or more, the temperature of the molten base material is selected to be 30° C. or more higher than the melting point of the material.
またロール3,3の直径が40mmでは、ロール
3,3の周速度が0.5m/sec〜3m/secに選ぶ
ことにより所望の薄板4が得られる。 Further, when the diameter of the rolls 3, 3 is 40 mm, the desired thin plate 4 can be obtained by selecting the circumferential speed of the rolls 3, 3 from 0.5 m/sec to 3 m/sec.
またロール3,3の直径が100mmの場合には、
ロール3,3の周速度を0.5m/sec〜4m/sec
に選ぶことにより所望の薄板4が得られる。 Also, if the diameter of rolls 3 and 3 is 100mm,
Circumferential speed of rolls 3 and 3 from 0.5m/sec to 4m/sec
A desired thin plate 4 can be obtained by selecting the following.
次に本発明の実施例の幾つかを説明する。 Next, some embodiments of the present invention will be described.
実施例 (1)
先ず、A1−Si−Feの組成が5.4:9.6:85重量パ
ーセントのセンダスト合金(融点1250℃)を用い
て耐熱容器1内で加熱し、耐熱容器1のノズル1
Aから噴出時の温度1550℃、ロール3,3への噴
出速度1c.c./secでロール3,3に噴出した。こ
の場合のロール3,3の直径は100mmで、ロール
3,3の周速度は4m/secで、ロール3,3の
圧延荷重を1tonとすると、第4図に示すような断
面略凸面形の薄板4が製造される。Example (1) First, a sendust alloy (melting point 1250°C) with a composition of A1-Si-Fe of 5.4:9.6:85 weight percent was heated in a heat-resistant container 1, and the nozzle 1 of the heat-resistant container 1 was heated.
The liquid was ejected from A to the rolls 3, 3 at a temperature of 1550° C. and at a ejection speed of 1 c.c./sec to the rolls 3, 3. In this case, the diameter of the rolls 3, 3 is 100 mm, the circumferential speed of the rolls 3, 3 is 4 m/sec, and the rolling load of the rolls 3, 3 is 1 ton. A thin plate 4 is produced.
また実施例2として
Fe−Al−Moの組成比が、84:14:2重量パー
セントの組成の合金(融点1480℃)を溶融母材2
として用いて加熱容器1内で加熱し、加熱容器1
のノズル1Aから噴出温度1550℃、周速度2m/
secで回転する直径40mmのローラ3,3に溶融母
材2を噴出させた場合、ローラ3,3の圧着力が
2tonであると、第4図のように断面略凸面形の薄
板4を得た。 In addition, as Example 2, an alloy (melting point 1480°C) with a Fe-Al-Mo composition ratio of 84:14:2 weight percent was melted into the base material 2.
heating container 1.
Blowout temperature 1550℃ from nozzle 1A, circumferential speed 2m/
When the molten base material 2 is jetted onto the rollers 3, 3 with a diameter of 40 mm rotating at sec, the pressing force of the rollers 3, 3 is
When the weight was 2 tons, a thin plate 4 having a substantially convex cross section as shown in FIG. 4 was obtained.
実施例 3
次に、その組成が93.5:6.5重量パーセントの
組成比を有するFe−Si系合金(融点1300℃)を
加熱容器1内で溶解し、そしてノズル1Aから、
0.5c.c./secの噴出速度で、直径100mm、周速度4
m/secで回転するロール3,3に噴出した。こ
うして第1図に示すような断面略凸面形状の薄板
4が得られた。Example 3 Next, an Fe-Si alloy (melting point 1300°C) having a composition ratio of 93.5:6.5% by weight was melted in the heating container 1, and from the nozzle 1A,
0.5cc/sec jetting speed, diameter 100mm, circumferential speed 4
It was ejected onto rolls 3, 3 rotating at m/sec. In this way, a thin plate 4 having a substantially convex cross section as shown in FIG. 1 was obtained.
実施例 4
また、その組成が40:60重量パーセントの組成
比を有するFe−Ni系合金(融点1470℃)を加熱
容器1内で溶解し、そしてノズル1Aから、0.4
c.c./secの噴出速度で、直径100mm、周速度3m/
secで回転するロール3,3に噴出した。こうし
て第4図に示すような断面略凸面形の薄板4が得
られた。Example 4 In addition, an Fe-Ni alloy (melting point 1470°C) having a composition ratio of 40:60 weight percent was melted in the heating container 1, and from the nozzle 1A, 0.4
With a jetting speed of cc/sec, a diameter of 100mm, and a circumferential speed of 3m/sec.
It squirted onto rolls 3 and 3, which rotated at sec. In this way, a thin plate 4 having a substantially convex cross section as shown in FIG. 4 was obtained.
実施例 5
また組成が77:13:10重量パーセントの組成比
を有するFe−Co−Si系合金(融点1360℃)を耐
熱容器1内で溶解し、そしてノズル1Aから、
0.5c.c./secの噴出速度で、径100mm、周速度3.5
m/secで回転するロール3,3に噴出した。之
により第4図に示すような断面略凸面形状の薄板
4が得られた。Example 5 An Fe-Co-Si alloy (melting point 1360°C) having a composition ratio of 77:13:10 weight percent was melted in a heat-resistant container 1, and then melted through a nozzle 1A.
0.5cc/sec jetting speed, diameter 100mm, circumferential speed 3.5
It was ejected onto rolls 3, 3 rotating at m/sec. As a result, a thin plate 4 having a substantially convex cross section as shown in FIG. 4 was obtained.
実施例 6
さらに、その組成が84:16重量パーセントの組
成を有するFe−Al系合金(融点1470℃)を加熱
容器1内で溶解し、そしてノズル1Aから、0.3
c.c./secの噴出速度、直径100mm、周速度4m/
secで回転するロール3,3に噴出した。こうし
て第4図に示すような断面略凸面形状の薄板4が
得られた。Example 6 Further, an Fe-Al alloy (melting point 1470°C) having a composition of 84:16 weight percent was melted in the heating container 1, and from the nozzle 1A, 0.3
Ejection speed of cc/sec, diameter 100mm, peripheral speed 4m/
It squirted onto rolls 3 and 3 rotating at sec. In this way, a thin plate 4 having a substantially convex cross section as shown in FIG. 4 was obtained.
このような略凸面形の断面形状を有する薄板4
を所望の形状に切断したり、または研磨して形成
されるラミネート・コアを用いて磁気ヘツドやト
ランスを形成した。この場合、薄板4の長手方向
に設けた凹条溝4A,4A内に接着剤5が溜まる
ため、積層したコア材相互の接着力は大きくな
る。そしてラミネート・コアを形成する上下の薄
板4相互が、その長手方向に設けた凹条溝44の
左右の突部が衝合することによつて積層が行える
ため、その占積率は高くなり、材料本来の性能、
例えば磁束密度、透磁率の性能を活かすことがで
きる。 A thin plate 4 having such a substantially convex cross-sectional shape
A magnetic head and a transformer were formed using a laminate core that was formed by cutting or polishing the core into a desired shape. In this case, since the adhesive 5 accumulates in the grooves 4A, 4A provided in the longitudinal direction of the thin plate 4, the adhesive force between the laminated core materials increases. Since the upper and lower thin plates 4 forming the laminate core can be stacked by abutting the left and right protrusions of the grooves 44 provided in the longitudinal direction, the space factor becomes high. The original performance of the material,
For example, the performance of magnetic flux density and magnetic permeability can be utilized.
そして磁気ヘツドやトランスを形成すべきラミ
ネート・コアの薄板4に設けた凹条溝4Aの左右
に位置する突部を上下、衝合するため、薄板4を
安定に積層できる。このようにラミネート・コア
を安定に積層できるのでコアの機械的強度を高め
ることができる。 Since the protrusions located on the left and right sides of the grooves 4A provided on the thin plates 4 of the laminate core on which the magnetic head and transformer are to be formed are brought into contact with each other vertically, the thin plates 4 can be stacked stably. Since the laminate core can be stacked stably in this manner, the mechanical strength of the core can be increased.
なお、薄板4を形成するのに上記実施例のほか
アモルフアス金属によつて形成してもよい。 Note that the thin plate 4 may be formed of an amorphous metal other than the above embodiment.
上述のように本発明の軟磁性薄板はその長さ方
向に垂直な断面形状が略凸面形で且つその中央部
には長手方向に凹条溝が設けられることによつて
従来の薄板よりも平坦化されて形成されているの
でラミネート・コアを形成した場合のコア材の占
積率が高く、しかも材料本来の性能、例えば磁束
密度、透磁率の性能を活かすことができる。また
コア材を積層するのに用いる接着剤の厚さが均一
で薄くできるため、接着力が強く剥離し易く、ト
ラブルが少ない。 As mentioned above, the soft magnetic thin plate of the present invention has a generally convex cross-sectional shape perpendicular to its length direction, and has grooves in the longitudinal direction in its center, making it flatter than conventional thin plates. Since it is formed into a laminate core, the space factor of the core material is high when a laminate core is formed, and the inherent performance of the material, such as magnetic flux density and magnetic permeability, can be utilized. Furthermore, since the thickness of the adhesive used to laminate the core materials is uniform and can be made thin, the adhesive strength is strong and peeling is easy, resulting in fewer troubles.
第1図は触体超急冷装置における双ロール法の
一例を示した断面図、第2図は同じく双ロールを
示した下面図、第3図は上記双ロールによつて形
成された薄板を積層して形成される従来のラミネ
ート・コアの断面図、第4図は同じく上記双ロー
ルによつて形成された本発明のラミネート・コア
の一例を示した断面図である。
1……耐熱容器、2……溶融母材、3……ロー
ル、4……薄板、4A……凹条溝。
Fig. 1 is a cross-sectional view showing an example of the twin roll method in a contact ultra-quenching device, Fig. 2 is a bottom view also showing the twin rolls, and Fig. 3 is a lamination of thin plates formed by the above twin rolls. FIG. 4 is a sectional view showing an example of the laminate core of the present invention also formed by the twin rolls described above. 1...Heat-resistant container, 2...Melting base material, 3...Roll, 4...Thin plate, 4A...Concave groove.
Claims (1)
つその中央部には長さ方向に伸びる凹条溝が形成
されたことを特徴とする軟磁性薄板。1. A soft magnetic thin plate characterized in that the cross-sectional shape perpendicular to the length direction is substantially convex, and a groove extending in the length direction is formed in the center thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12678282A JPS5918608A (en) | 1982-07-22 | 1982-07-22 | Soft magnetic thin plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12678282A JPS5918608A (en) | 1982-07-22 | 1982-07-22 | Soft magnetic thin plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5918608A JPS5918608A (en) | 1984-01-31 |
| JPH0319683B2 true JPH0319683B2 (en) | 1991-03-15 |
Family
ID=14943797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12678282A Granted JPS5918608A (en) | 1982-07-22 | 1982-07-22 | Soft magnetic thin plate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5918608A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007133399A2 (en) * | 2006-05-09 | 2007-11-22 | Spang & Company | Electromagnetic assemblies, core segments that form the same, and their methods of manufacture |
-
1982
- 1982-07-22 JP JP12678282A patent/JPS5918608A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5918608A (en) | 1984-01-31 |
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