JPH03212415A - Solid polyelectrolyte - Google Patents
Solid polyelectrolyteInfo
- Publication number
- JPH03212415A JPH03212415A JP2007301A JP730190A JPH03212415A JP H03212415 A JPH03212415 A JP H03212415A JP 2007301 A JP2007301 A JP 2007301A JP 730190 A JP730190 A JP 730190A JP H03212415 A JPH03212415 A JP H03212415A
- Authority
- JP
- Japan
- Prior art keywords
- ester
- solid electrolyte
- polymer solid
- molecular weight
- polypropylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000867 polyelectrolyte Polymers 0.000 title abstract 3
- 239000007787 solid Substances 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 claims abstract description 21
- -1 diacrylic ester Chemical class 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- 229920000570 polyether Polymers 0.000 claims abstract description 8
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract 2
- 229920000642 polymer Polymers 0.000 claims description 18
- 239000007784 solid electrolyte Substances 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 12
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 230000005865 ionizing radiation Effects 0.000 claims description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000243 solution Substances 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 abstract 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 description 9
- 229920001155 polypropylene Polymers 0.000 description 9
- 239000012528 membrane Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 4
- 238000010894 electron beam technology Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- YZWVMKLQNYGKLJ-UHFFFAOYSA-N 1-[2-[2-(2-ethoxyethoxy)ethoxy]ethoxy]-2-methoxyethane Chemical compound CCOCCOCCOCCOCCOC YZWVMKLQNYGKLJ-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005650 polypropylene glycol diacrylate Polymers 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Secondary Cells (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyethers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Conductive Materials (AREA)
- Primary Cells (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は一次電池、二次電池、エレクトロクロミックデ
イスプレィ、電気化学センサー、イオントフォレーシス
、コンデンサーその他の電気化学的デバイスに用いるポ
リマー固体電解質に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application This invention relates to polymer solid electrolytes for use in primary batteries, secondary batteries, electrochromic displays, electrochemical sensors, iontophoresis, capacitors, and other electrochemical devices. It is.
従来技術とその問題点
従来のポリマー固体電解質は分子量が２．０ＤＣ＋より
低いポリエーテｙの架橋ネットワークが主であった。特
にシアクリ／Ｉ’酸エステル又はジメタクリル酸エステ
ルに変性したポリエーテルを架橋したものは柔軟性が低
いという欠点があった・このため電池等に使用した場合
、外部からの力によって破壊しやすくシーート等の原因
となっていた。Prior art and its problems Conventional polymer solid electrolytes have mainly consisted of a crosslinked network of polyethers having a molecular weight lower than 2.0DC+. In particular, cross-linked polyethers modified to cyacrylic/I' acid esters or dimethacrylic esters have the disadvantage of low flexibility.For this reason, when used in batteries, etc., sheets are easily destroyed by external force. etc., was the cause.
発明の目的
本発明は上記従来の問題点に鑑みなされたものであり、
機械的強度に優れた、イオン伝導度の高い、ポリマー固
体電解質を提供することを目的とするものである◎
発明の構成
本発明は上記目的を達成するべく、
ポリプロピレングリコ−ｙのシアクリル駿エステ〃又は
／及びジメタクリμ酸エステルとポリエーテルのセノア
クリ〜酸エステル又は／及びモノメタクリル酸エステル
の混合物を反応させて架橋ネットワーク構造とした高分
子がイオン性塩な含むことを特徴とするポリマー固体電
解質である。Purpose of the Invention The present invention has been made in view of the above-mentioned conventional problems.
It is an object of the present invention to provide a polymer solid electrolyte with excellent mechanical strength and high ionic conductivity. ◎ Structure of the Invention In order to achieve the above object, the present invention provides a cyacrylic ester of polypropylene glycol-y. or/and a polymer solid electrolyte characterized in that the polymer formed into a crosslinked network structure by reacting a mixture of a dimethacrylic acid ester and a senoacrylic acid ester of polyether or/and a monomethacrylic acid ester contains an ionic salt. be.
又）ポリプロピレングリコ−μの分子量が２．０００乃
至３０，０００である前記のポリマー固体電解質である
。and) the aforementioned polymer solid electrolyte in which polypropylene glyco-μ has a molecular weight of 2.000 to 30,000.
又、ポリエーテルがポリエチレングリコ−μ、ポリプロ
ピレングリコ−ｙ１エチレンオキＶドとプロピレンオキ
シドの共重合体の中より選んだ１種又は混合物である前
記のポリマー固体電解質である。Further, the above polymer solid electrolyte is one in which the polyether is one selected from polyethylene glyco-μ, polypropylene glyco-y, a copolymer of ethylene oxide and propylene oxide, or a mixture thereof.
又・イオン性塩を相溶することができる化合物を該イオ
ン性塩と共に含有する前記のポリマー固体電解質である
。- The polymer solid electrolyte described above contains a compound capable of dissolving the ionic salt together with the ionic salt.
又１架橋ネツトフークの形成は熱的、活性光線、又は電
離性放射線の照射による前記のポリマー固体電解質であ
る。Alternatively, the formation of a crosslinked net-link can be achieved by irradiating the polymer solid electrolyte thermally, with actinic light, or with ionizing radiation.
実施例 以下、本発明の詳細について実施例により説明する。Example Hereinafter, the details of the present invention will be explained with reference to Examples.
実施例１
ポリプロピレングリコールのジアクリル酸エヌテ、ｌｖ
（分子量４，０ＤＤ）５０重量部とメトキシ化ジエチレ
ングリコ−μのモノアクリｙ酸エステ１ｖ５０重量部を
混合した液Ｃ１Ｉ、１０Ｆ５ＳＯ３１１，５重量％のプ
ロピレンカーボネート溶液ヲ１００重量部加えて、均一
に混合した。この液をガラス板上にキャストし、８Ｍｒ
ａｄの電子線を照射した。この膜の厚みは１００声−で
複素インピーダンス法により測定したイオン伝導度は２
Ｘ ｊＯ−４８ＣＩｍ−１（２５℃）でありだ・又・
柔軟性テストとして１８００折り曲げテストによっても
、この膜は割れを生じなかった。Example 1 Polypropylene glycol diacrylate ent, lv
(Molecular weight: 4.0 DD) and 50 parts by weight of methoxylated diethylene glyco-μ monoacrylic acid ester (1v) were added to liquid C1I, and 100 parts by weight of a propylene carbonate solution containing 11.5% by weight of 10F5SO3 were added and mixed uniformly. Cast this liquid on a glass plate and add 8Mr.
irradiated with ad electron beam. The thickness of this membrane is 100 mm, and the ionic conductivity measured by the complex impedance method is 2.
X jO-48CIm-1 (25℃)
The membrane did not crack when subjected to an 1800 bend test as a flexibility test.
ポリプロピレングリコ−μのシアクリＮ酸エステルの分
子量を４００．１，０００．２．０００とＩＱ、０００
のものについての性能を表１にまとめた。The molecular weight of polypropylene glyco-μ cyacrylic acid ester is 400.1,000.2.000 and IQ, 000.
The performance of these products is summarized in Table 1.
表 １
実施例２
ポリプロピレングリコ−ｙのシアクリｙ駿エステＮ（分
子量４，０００）５０重量部とメトキシ化ジエチレング
リコ−〜のモノアクリル酸エステル５０重量部を混合し
た液に、Ｌｉ０Ｆ３ＳＯ５１１，５重量％のジメトキシ
エタンＭＩ［’１００重量部加えて、均一に混合した。Table 1 Example 2 11.5% by weight of Li0F3SO5 was added to a liquid mixture of 50 parts by weight of polypropylene glyco-y cyacrylic ester N (molecular weight 4,000) and 50 parts by weight of monoacrylic acid ester of methoxylated diethylene glyco-y. 100 parts by weight of dimethoxyethane MI was added and mixed uniformly.
この液をガラス板上にキャストし、ジメトキシエタンを
蒸発させた。その後、８ ａｒａａの電子線を照射した
。This liquid was cast on a glass plate, and dimethoxyethane was evaporated. Thereafter, an electron beam of 8 araa was irradiated.
この膜の厚みは１００μ調で複素インピーダンス法によ
り測定したイオン伝導度は５Ｘ１０−’８ ｏｓ−＋−
ｙた。１８０°折り曲げテスＦで割れは生じなかった。The thickness of this membrane is 100μ, and the ionic conductivity measured by the complex impedance method is 5X10-'8 os-+-
Yes. No cracking occurred in the 180° bending test F.
ポリプロピレングリコ−ｙのシアクリＮ酸エステルの分
子量を４００．１，０００゜２．０００と１０，０００
のものについても調査した結実施例５
実施例２において電子線照射に代えて１５重量部のアゾ
イソブチロニトリμを加えて８０℃で１時間反応させた
。これ以外は、すべて実施例２に同じとした。The molecular weight of polypropylene glyco-y cyacrylic acid ester is 400.1,000°2.000 and 10,000.
Example 5 In Example 2, instead of electron beam irradiation, 15 parts by weight of azoisobutyronitrium μ was added and the reaction was carried out at 80° C. for 1 hour. Everything else was the same as in Example 2.
ここで得られた膜は、厚みが１００声調であり、イオン
伝導度は４Ｘ１０−’ ５ｅｌｌ−’ （２５℃）であ
った０又・１８０°折り曲げテス）においても割れは生
じなかった。尚、この時のポリプロピレングリコ−ｙの
ジアクリル酸エステルの分子量は４．０００であった◎
実施例４
実施例２において、電子＠照射に代えて、２重量部のベ
ンゾフェノンと２重量部のトリエチルアミンを加えて、
１罰の水銀ランプで１５ｃｍの距離から３０秒間紫外線
を照射した。これ以外はすべて、実施例２に同じとした
・
ここで得られた膜は、ポリプロピレングリコ−ｙのジア
クリル酸エステルの分子量が４，０００であり、膜の厚
みが１００声解、イオン伝導度は４ Ｘ １０−６８Ｃ
ＩＩ−’ （２５℃）、１８０’ 折り曲げ？Ｘトで割
れは生じなかった。The membrane obtained here had a thickness of 100 tones and an ionic conductivity of 4X10-'5ell-' (25°C). No cracks occurred even in the 0-fold/180° bending test). The molecular weight of the diacrylic ester of polypropylene glyco-y at this time was 4.000 ◎ Example 4 In Example 2, instead of electron @ irradiation, 2 parts by weight of benzophenone and 2 parts by weight of triethylamine were used. In addition,
Ultraviolet rays were irradiated for 30 seconds from a distance of 15 cm using a mercury lamp. Everything else was the same as in Example 2. The membrane obtained here has a molecular weight of polypropylene glyco-y diacrylate ester of 4,000, a membrane thickness of 100 mm, and an ionic conductivity of 4 x 10-68C
II-' (25℃), 180' bend? No cracking occurred at X.
実施例５
実施例１において、ポリプロピレングリコーｙのジアク
リル酸エステルに代えて、ポリプロピレングリコ−μの
ジメタクリ〃酸エステル（分子量４，０００）を用いた
。これ以外はすべて同じとした。得られた膜は、厚さが
１００μ鯛、イオン伝導度は３Ｘ１０−’Ｓ備−１（２
５℃）であり、１８０°折り曲げテス）において割れが
生じなかった０
実施例６
ポリプロピレングリコー〜のジメタクリル酸エステル（
分子量４，０００）５０重量部と屹ツメＦキシ化したエ
チレンオキシドとプロピレンオキシドの共重合体（プロ
ピレンオキノド２０モＡ／％含む、分子量４００）５０
重量部を混合した液に、ｃｉｃｙ３ｓｏ３１１．５重量
％のプロピレンカーボネート溶液を１００重量部加えて
、均一に混合した・この液をガラス板上にキャストし、
６Ｍｒａｄの電子線を照射した。この膜の厚みは１００
μ解でイオン伝導度は４Ｘ１０−’ Ｓ備−１（２５℃
）であった。又、１８０°折り曲げテストにおいても割
れは生じなかった。Example 5 In Example 1, dimethacrylate ester of polypropylene glyco-μ (molecular weight 4,000) was used in place of diacrylate ester of polypropylene glycol y. Everything else was the same. The obtained membrane has a thickness of 100μ and an ionic conductivity of 3X10-'S-1 (2
Example 6 Dimethacrylic acid ester of polypropylene glycol (
Copolymer of ethylene oxide and propylene oxide (containing 20 moA/% of propylene oxide, molecular weight 400) 50 parts by weight (molecular weight: 4,000)
100 parts by weight of propylene carbonate solution of 11.5% by weight of cicy3so3 was added to the mixed solution of 11.5% by weight of cicy3so3 and mixed uniformly.・This liquid was cast on a glass plate,
It was irradiated with an electron beam of 6 Mrad. The thickness of this film is 100
The ionic conductivity in the μ solution is 4X10-'S-1 (25℃
)Met. Further, no cracks were observed in the 180° bending test.
又、イオン性塩を相溶することができる化合物（溶剤）
をポリマー固体電解質は含有する。Also, a compound (solvent) that can dissolve ionic salts.
The polymer solid electrolyte contains.
必要に応じて、溶剤を固体電解質に含ませることによっ
て、イオン伝導性を高めることが可能である。この場合
、ボリエーテ〃の分子量が高くなると、多くの溶剤を含
ませることができ、イオン伝導性についても有利になり
、さらに溶剤によって膨潤した架橋ネットワーク高分子
の強度を改善できる・
尚）イオン性塩としては、Ｌｉ０１０４． ＬｉＢＦ４
゜ＬｉＡＢＦ６． Ｌｉ０Ｆ５ＳＯ５，ＬｉＰＦ６．
ＬｉＩ 、 ＬｉＢｒＬｉ５（Ｎ ＮａＩ Ｌｉ２Ｂ
ｌ０Ｃ１１（１，Ｌｉ０Ｆ、５００２．ＮａＢｒＮａ５
ＯＮ、 ＫＳＣＮ、 ＭｇＣｌ２． Ｎ９（（ＪＯ４）
２゜（ＣＨ３）４ＮＢＦ４． （ａｎ５）４ＮＢｒ、
（０２Ｈ５）４ＮｃＪＯ４゜（Ｃ２Ｈ５）４ＮＩ （
Ｃ５Ｈ７）４ＮＢｒ （ｎ−０４Ｈ９）４ＮＩ（ｎ−
ＣζＨ＊＜）ａＮＩが好ましいが限定しない。Ionic conductivity can be increased by including a solvent in the solid electrolyte, if necessary. In this case, the higher the molecular weight of bolyate, the more solvent it can contain, which is advantageous in terms of ionic conductivity, and the strength of the crosslinked network polymer swollen by the solvent can be improved. As for Li0104. LiBF4
゜LiABF6. Li0F5SO5, LiPF6.
LiI, LiBrLi5(NNaILi2B
l0C11(1, Li0F, 5002.NaBrNa5
ON, KSCN, MgCl2. N9 ((JO4)
2゜(CH3)4NBF4. (an5)4NBr,
(02H5)4NcJO4゜(C2H5)4NI (
C5H7)4NBr (n-04H9)4NI(n-
CζH*<)aNI is preferred, but not limited.
イオン性塩を溶解することができる化合物とはテトラヒ
ドロフフン、２−メチルテトラヒドロフフン、１，３−
ジオキソフン、４，４−ジメチ１ｖ−１，３−ジオキソ
ヲン、ｒ−プチロフクトン、エチレンカーボネート、プ
ロピレンカーボネート、ブチレンカーボネート、スμホ
フン％３−メチルスルホフン、ｔｅｒｔ、−７’千〜エ
ーテ〜、１ｓｏ−ブチμエーテμ、１，２−ジメトキシ
エタン、１．２−エトキンメトキシエタン１メチμジグ
フイふ、メチμトリグフイム、メチルテトラグライム、
エチルグツイム、エチルジグフイム等があるが限定はし
ない。Compounds that can dissolve ionic salts include tetrahydrofufurn, 2-methyltetrahydrofufurn, 1,3-
Dioxofone, 4,4-dimethyl 1v-1,3-dioxofone, r-butylofuctone, ethylene carbonate, propylene carbonate, butylene carbonate, sulfophone% 3-methylsulfofone, tert, -7'1000~ether~, 1so- Butyμ ether μ, 1,2-dimethoxyethane, 1,2-ethquinmethoxyethane 1methyμ digufifu, methiμ trigfime, methyltetraglyme,
Examples include ethylgutzim, ethyldighuim, etc., but are not limited to these.
ポリプロピレングリコールの分子量を上げることによっ
て、柔軟性と強度をさらに上げることができる。しかし
分子量を上げすぎると反応速度が低下し、生産性が悪く
なることと、結晶化し易くなるために、伝導度の低下を
招き問題である。従って分子量はｚｏｏｏ乃至５０，０
００が好ましい。Flexibility and strength can be further increased by increasing the molecular weight of polypropylene glycol. However, if the molecular weight is increased too much, the reaction rate decreases, productivity deteriorates, and crystallization tends to occur, resulting in a decrease in conductivity, which is a problem. Therefore, the molecular weight is between zoooo and 50,0
00 is preferred.
発明の効果
上述した如（、本発明は機械的強度に優れた、イオン伝
導度の高いポリマー固体電解質を提供することができる
ので、その工業的価値は極めて大である。Effects of the Invention As described above, the present invention can provide a polymer solid electrolyte with excellent mechanical strength and high ionic conductivity, so its industrial value is extremely large.
Claims (5)
ル又は／及びジメタクリル酸エステルとポリエーテルの
モノジメタクリル酸エステル又は／及びモノアクリル酸
エステルの混合物を反応させて架橋ネットワーク構造と
した高分子がイオン性塩を含むことを特徴とするポリマ
ー固体電解質。(1) A polymer made into a crosslinked network structure by reacting a mixture of diacrylic acid ester and/or dimethacrylic acid ester of polypropylene glycol and monodimethacrylic acid ester and/or monoacrylic acid ester of polyether forms an ionic salt. A polymer solid electrolyte comprising:
乃至３０，０００である請求項１記載のポリマー固体電
解質。(2) The molecular weight of polypropylene glycol is 2,000
The polymer solid electrolyte according to claim 1, wherein the polymer solid electrolyte has a molecular weight of 30,000 to 30,000.
ロピレングリコール、エチレンオキシドとプロピレンオ
キシドの共重合体の中より選んだ１種又は混合物である
請求項１記載のポリマー固体電解質。(3) The polymer solid electrolyte according to claim 1, wherein the polyether is one or a mixture selected from polyethylene glycol, polypropylene glycol, and a copolymer of ethylene oxide and propylene oxide.
ン性塩と共に含有する請求項１記載のポリマー固体電解
質。(4) The polymer solid electrolyte according to claim 1, which contains, together with the ionic salt, a compound that is compatible with the ionic salt.
電離性放射線の照射による請求項１又は２記載のポリマ
ー固体電解質。(5) The polymer solid electrolyte according to claim 1 or 2, wherein the crosslinked network is formed thermally, by actinic rays, or by irradiation with ionizing radiation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007301A JPH0832755B2 (en) | 1990-01-16 | 1990-01-16 | Polymer solid electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007301A JPH0832755B2 (en) | 1990-01-16 | 1990-01-16 | Polymer solid electrolyte |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03212415A true JPH03212415A (en) | 1991-09-18 |
| JPH0832755B2 JPH0832755B2 (en) | 1996-03-29 |
Family
ID=11662200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007301A Expired - Lifetime JPH0832755B2 (en) | 1990-01-16 | 1990-01-16 | Polymer solid electrolyte |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0832755B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4338703A1 (en) * | 2022-09-15 | 2024-03-20 | VOCO GmbH | Opacity change in printing resins |
-
1990
- 1990-01-16 JP JP2007301A patent/JPH0832755B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4338703A1 (en) * | 2022-09-15 | 2024-03-20 | VOCO GmbH | Opacity change in printing resins |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0832755B2 (en) | 1996-03-29 |
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