JPH03213310A - Method and device for manufacture of preformed product - Google Patents
Method and device for manufacture of preformed productInfo
- Publication number
- JPH03213310A JPH03213310A JP2330841A JP33084190A JPH03213310A JP H03213310 A JPH03213310 A JP H03213310A JP 2330841 A JP2330841 A JP 2330841A JP 33084190 A JP33084190 A JP 33084190A JP H03213310 A JPH03213310 A JP H03213310A
- Authority
- JP
- Japan
- Prior art keywords
- mold
- preform
- blank
- reinforcement
- binder resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 69
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000011230 binding agent Substances 0.000 claims abstract description 102
- 229920005989 resin Polymers 0.000 claims abstract description 62
- 239000011347 resin Substances 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 43
- 239000003365 glass fiber Substances 0.000 claims abstract description 9
- 239000012779 reinforcing material Substances 0.000 claims abstract description 4
- 238000005520 cutting process Methods 0.000 claims abstract 5
- 230000002787 reinforcement Effects 0.000 claims description 70
- 238000000465 moulding Methods 0.000 claims description 20
- 239000002131 composite material Substances 0.000 claims description 11
- 229920002994 synthetic fiber Polymers 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 4
- 230000003014 reinforcing effect Effects 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 5
- 238000003490 calendering Methods 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 2
- 238000005096 rolling process Methods 0.000 abstract description 2
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 230000008569 process Effects 0.000 description 28
- 238000003466 welding Methods 0.000 description 18
- 238000001723 curing Methods 0.000 description 17
- 239000000835 fiber Substances 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 9
- 230000005855 radiation Effects 0.000 description 9
- 229920001169 thermoplastic Polymers 0.000 description 9
- 238000013461 design Methods 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- 239000011162 core material Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000010134 structural reaction injection moulding Methods 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000001721 transfer moulding Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004616 structural foam Substances 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000010107 reaction injection moulding Methods 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/70—Feed lines
- H05B6/707—Feed lines using waveguides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/14—Making preforms characterised by structure or composition
- B29B11/16—Making preforms characterised by structure or composition comprising fillers or reinforcement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/70—Feed lines
- H05B6/701—Feed lines using microwave applicators
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/80—Apparatus for specific applications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0855—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using microwave
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
- B29K2105/0854—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns in the form of a non-woven mat
Landscapes
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Thermal Sciences (AREA)
- Toxicology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Reinforced Plastic Materials (AREA)
- Moulding By Coating Moulds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Sampling And Sample Adjustment (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、構造的合成物のための樹脂トランスファー成
形(RTM)および反応射出成形(SRAM)法用の構
造強化予備成形物を製造する方法と装置に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application] The present invention relates to a method for producing structurally reinforced preforms for resin transfer molding (RTM) and reaction injection molding (SRAM) processes for structural composites. and regarding equipment.
〔従来技術および解決しようとする課題〕指向繊維予備
成形物を製造する際に、これまで成形品を通って引き寄
せられた空気を有する成形品の上へチョツプドファイバ
ーを結合剤樹脂と共に噴射して繊維を位置させかつ保持
することが実施されていた。それから、繊維と結合剤樹
脂を有する成形品を熱い空気ブレナム室の中へ回転させ
、乾燥しおよび/または硬化して結合剤樹脂を固定する
。加えて、乾燥しかつ硬化するために予備成形物のため
のたくさんの貯蔵空間が必要である。熱成形される予備
成形物を作る際には、これまで繊維製造業者により予め
熱可塑性結合剤で被覆された連続的なストランド繊維を
用いることが実施されていた。熱成形可能なマットがロ
ール形状で供給され、その際マントはさまざまな層厚の
平らなシートになって繰り出されて縁で保持フレームの
中にクランプされる。それから、フレーム網状構造が放
射ヒータを含むオーブン室に位置され、放射ヒータが強
化材マットと熱可塑性結合剤を両側からゆっくりと加熱
する。加熱すると、熱可塑性結合剤が軟化し、そして軟
化している間に、フレーム網状構造が迅速に冷たい型へ
移送される。PRIOR ART AND PROBLEM TO BE SOLVED: In producing oriented fiber preforms, it has heretofore been possible to inject chopped fibers with a binder resin onto a molded part with air drawn through the molded part. It was practiced to position and hold the fibers using The molded article with the fibers and binder resin is then rotated into a hot air brenum chamber to dry and/or cure and fix the binder resin. In addition, a lot of storage space is required for the preforms to dry and harden. In making thermoformed preforms, it has heretofore been practiced by fiber manufacturers to use continuous strands of fiber that have been previously coated with a thermoplastic binder. The thermoformable mat is supplied in roll form, the cloak being rolled out in flat sheets of varying layer thickness and clamped at the edges into a holding frame. The frame network is then placed in an oven chamber containing radiant heaters that slowly heat the reinforcement mat and thermoplastic binder from both sides. Upon heating, the thermoplastic binder softens and, while softening, the frame network is rapidly transferred to a cold mold.
型が、補強マットを部品の形状に強制的にするプレスを
介して閉じる。冷却すると、熱可塑性結合剤が熱成形可
能なマットを堅くし、従ってその新しい形状に保持する
。上記の過程はゆっくりであり、たくさんの空間を必要
としかつ大量のエネルギーを必要とする。本発明を実施
する際には、予備成形物が製造位置に留まることができ
、かつ予備成形物が硬化されたときにのみ出ることがで
きる。本発明は、結合剤樹脂が硬化のためのエネルギー
を用いて加熱されるだけである点ではいっそうエネルギ
ーが有効である。強化材は加熱されないし、成形体も加
熱されない。それ故、一定に作動するオーブンを有する
大きな場所が必要でない。その過程は、硬化範囲が時間
ではなく秒であるので極めて速い。The mold is closed via a press that forces the reinforcing mat into the shape of the part. Upon cooling, the thermoplastic binder stiffens the thermoformable mat, thus holding it in its new shape. The above process is slow, requires a lot of space and requires a large amount of energy. When practicing the invention, the preform can remain in the manufacturing position and can only be ejected when the preform is cured. The present invention is even more energy efficient in that the binder resin is only heated using energy for curing. The reinforcement is not heated and neither is the compact. Therefore, a large area with a constantly operating oven is not required. The process is extremely fast since the curing range is seconds rather than hours.
その過程は、はとんど揮発性物質を必要とせず、かつ加
熱されるオーブンを必要とするシステムのように何も蒸
発されない点では、環境りいっそう安全である。The process requires very few volatile substances and is much safer for the environment in that nothing is evaporated as in systems that require heated ovens.
構造要素のための慣用のl?IM/SRIM法の応用で
は、予備成形物全体を横切る繊維層厚さが、成る範囲の
強度必要条件を満たすために増加されており、そのため
材料を不必要に使用しかつ厚さと重さを増加させること
になる。また、指向繊維法も熱成形可能なマットを用い
る方法も、設計者がリブまたは密閉形材を付は加えて設
計特性を最大にすることができない。Conventional l for structural elements? In the application of the IM/SRIM method, the fiber layer thickness across the preform is increased to meet a range of strength requirements, thus using unnecessary material and increasing thickness and weight. I will let you do it. Additionally, neither the oriented fiber method nor the thermoformable mat method allows the designer to add ribs or sealing features to maximize design properties.
熱成形および指向繊維法はゆっくりであり、煩わしくか
つエネルギーと材料を浪費する。Thermoforming and directed fiber methods are slow, cumbersome and waste energy and materials.
紫外線放射とマイクロ波放射の使用のように、過程で要
素に影響を与えるために電磁エネルギーを加えることが
当該技術で知られている。It is known in the art to apply electromagnetic energy to influence elements in the process, such as the use of ultraviolet and microwave radiation.
特定の例として、慣用のマイクロ波オーブンのように、
熱を発生させるためにマイクロ波を用いることはよ(知
られている。マイクロ波加熱のための多数の応用は、紙
、織物、ベニア、食品、薬および同様なものを乾燥する
ために米国特許3,597,567 、米国特許2.5
60.903および米国特許3.277、580を含む
ものが開発された。As a specific example, like a conventional microwave oven,
The use of microwaves to generate heat is well known. Numerous applications for microwave heating include US patents for drying paper, textiles, veneers, food, medicine and the like. 3,597,567, U.S. Pat. No. 2.5
60.903 and US Pat. No. 3.277,580.
そのような技術は、強化材を実施する際に用いることが
できる。また、そのようなシステムに空気流が乾燥過程
で蒸気として作られた湿気を除くために組み込まれた。Such techniques can be used in implementing reinforcements. Also, airflow was incorporated into such systems to remove moisture created as steam during the drying process.
本発明の目的は、樹脂トランスファー成形(RTM)、
樹脂射出成形(RIM)および構造反応射出成形(SR
IM)法用の構造強化予備成形物を製造するために指向
エネルギーを用いた新規なおよび改善された方法と装置
を提供することである。The purpose of the present invention is to perform resin transfer molding (RTM),
Resin injection molding (RIM) and structural reaction injection molding (SR
An object of the present invention is to provide new and improved methods and apparatus for using directed energy to produce structurally reinforced preforms for the IM) process.
本発明の他の目的は、エネルギーが有効であり、論理的
であり、基本的に簡単でありかつ起こり得る浪費をでき
るだけ少なくすると共に材料を最大に使用できる方法を
提供することである。Another object of the invention is to provide a method which is energy efficient, logical and basically simple and which allows maximum use of materials with as little possible waste as possible.
本発明のなお他の目的は、予備成形物の設計において、
リブ、密閉形材、コア、金属や発泡体や木材または他の
材料の封入を含む自由度を設計者に与えることである。Still another object of the present invention is that in the design of preforms:
It gives the designer flexibility to include ribs, sealing profiles, cores, encapsulation of metal, foam, wood or other materials.
本発明により、広い種類の強化材を利用して制限されな
い幾何学的形状と細かい組立を許す剛性化した合成成形
品の高速高容積生産高のための方法が設計される。多数
の繊維強化材と共に、構造発泡体、木材または金属のよ
うな構成要素をどんな形状または構造を達成するために
も利用できる。In accordance with the present invention, a method is designed for high-speed, high-volume production of stiffened composite molded parts that utilizes a wide variety of reinforcement materials to allow unlimited geometry and detailed assembly. Components such as structural foam, wood or metal, along with multiple fiber reinforcements, can be utilized to achieve any shape or structure.
本発明の方法は、合成成形品を利用しかつ構造要素を予
備成形物にエネルギーステッチ溶接技術を介して取り付
けるために指向エネルギーシステムと共に、特別に開発
された結合剤を利用する。その過程能力と結合剤系は、
RTMおよびRIM樹脂系、すなわちポリエステル類、
ビニールエステル類、ウレタン類、エポキシ類、フェノ
ール系およびアクリル系樹脂に当てはまりかつこれらと
相溶性である。The method of the present invention utilizes a specially developed bonding agent in conjunction with a directed energy system to utilize synthetic moldings and attach structural elements to the preform via energy stitch welding techniques. Its process capacity and binder system are
RTM and RIM resin systems, i.e. polyesters,
Applicable to and compatible with vinyl esters, urethanes, epoxies, phenolics and acrylic resins.
本発明の方法は、完全に自動可されるようにかつ必要な
場合に予備成形物の必要な構造特性のための多数の種類
の強化材を特別に分配しかつ配置できるように設計され
ている。それ故、設計の完全な自由度はその方法に固有
であり、かつ設計基準を満たす密閉構造形材やさまざま
な壁形材を含む最も望ましい強化材形式および/または
構造を許す。構成要素の構造を剛性化しおよび/または
取り付ける過程を増大させて、成形機のサイクル時間に
適合するように変えることができ、または一つより多い
成形機にさまざまのまたは複数の予備成形物を供給する
ことができる。The method of the invention is designed to be completely automatic and to allow for the special distribution and placement of numerous types of reinforcement for the required structural properties of the preform, if necessary. . Therefore, complete freedom of design is inherent in the method and allows for the most desirable reinforcement types and/or structures, including closed structural profiles and various wall profiles that meet the design criteria. The process of stiffening and/or mounting the component structure can be varied to suit the molding machine cycle time, or feeding different or multiple preforms to more than one molding machine. can do.
方法の自動化は、反復可能な、−貫した品質および構造
上の完全性をもつ予備成形物を作る統計学的処理技術の
完全な使用をするように設計される。方法技術の応用は
、船舶、航空機、気圏、防御およびスポーツ、および消
費材のような種々様々な製品範囲の中に合体させること
ができる。The automation of the process is designed to make full use of statistical processing techniques to produce repeatable - consistent quality and structural integrity preforms. Applications of the method technology can be incorporated into a wide variety of product ranges such as marine, aircraft, aerospace, defense and sports, and consumer products.
詳細に後述するように、指向エネルギーシステムに加え
て巧みに処理されるポリマー樹脂の化学的性質が、構造
キャリア予備成形物の製造のために特別に設計された自
動機と共に用いられる。予備成形物を、RTMおよびS
RIM成分に必要な特別な構造上のおよび寸法上の必要
条件に向くように造ることができる。As discussed in more detail below, a directed energy system as well as engineered polymer resin chemistry is used in conjunction with specially designed automated machinery for the production of structural carrier preforms. The preforms are RTM and S
It can be tailored to the special structural and dimensional requirements needed for RIM components.
予備成形および成型中に強化材を配置する場合の大きな
問題は、所望の複雑な形状に合致するように種々の強化
材を組み合わせかつ剛性化することにより克服できる。The major problems with placing reinforcements during preforming and molding can be overcome by combining and stiffening various reinforcements to fit the desired complex shape.
本発明の特徴により、他の強化材の利用は補剛材または
リブを付は加えることにより予備成形物構造と統合する
ことができ、かつ構造のための強化材ならびにクラスA
の適用が必要である場合にインサートと共にコア材料の
封入を達成することができる。Due to the features of the present invention, the use of other reinforcements can be integrated with the preform structure by adding stiffeners or ribs, and reinforcement for the structure as well as class A
Encapsulation of the core material with the insert can be achieved if application of the core material is required.
本発明を実施する際に、ガラス繊維強化材のマットをブ
ランクとして合致する形状に予め切断し、結合剤を加え
、そしてそれから各ブランクを、エネルギーを予備成形
物結合剤に指向させる特別に巧みに処理されかつ部品の
形状を複製する型セットの中へ移送する。エネルギーを
数秒間加えて結合剤を活性化し、次いで予備成形物を剛
性化する。活性化エネルギーを止めると、型セットを開
いて、予備成形物を成型ステーションへまたは任意のエ
ネルギーステッチ溶接ステーションへ移送スる。In practicing the present invention, mats of glass fiber reinforcement are precut into matching shapes as blanks, a binder is added, and each blank is then cut using a specially engineered method that directs energy into the preform binder. Processed and transferred into a mold set that replicates the shape of the part. Energy is applied for a few seconds to activate the binder and then stiffen the preform. When the activation energy is turned off, the mold set is opened and the preform is transferred to the molding station or to any energy stitch welding station.
予備成形可能な強化材マットを、それが成形型の輪郭に
合致することができる所定のパターンに切断する。強化
材の両側を結合剤樹脂で含浸する。単一層または多層の
強化材マットを一緒に間に挟んで、キャリア予備成形物
の装入をもたらす。キャリア予備成形物は、半組立体と
して使われる過程での予備成形物を述べるために、また
は最終組立体を造るためにエネルギーステッチ溶接によ
り引き続き取り付けられる強化材を有する過程での予備
成形物を述べるためにシー・ニー・ロートン(C,A、
Lawton)カンパニーにより造り出された用語であ
る。エネルギーステッチ溶接は、構造体を基本予備成形
物に配置しかつ取り付ける過程を述べるためにC0^。The preformable reinforcement mat is cut into a predetermined pattern that allows it to match the contours of the mold. Impregnate both sides of the reinforcement with binder resin. Single or multi-layer reinforcement mats are sandwiched together to provide a carrier preform charge. Carrier preform refers to a preform in the process of being used as a subassembly or having reinforcements that are subsequently attached by energy stitch welding to create the final assembly. For Sean Lawton (C, A,
This is a term coined by the Lawton Company. Energy stitch welding is used to describe the process of placing and attaching a structure to a basic preform.
Lawtonカンパニーにより造り出された用語である
。結合剤樹脂は触媒(マイクロ波システム)で促進され
るかまたは紫外線システムのために供給されるものとし
て使用され、かつ施与システムの中に配量される。結合
剤を加える際に、結合剤樹脂を噴射し、フィルムとして
圧延しまたはカレンダー掛けすることができる。結合剤
を加えた後、強化材マットが成形型の釣り合った半部(
雄または雌)の上へ機械的に装入される。This is a term coined by the Lawton Company. The binder resin is used as catalyst-promoted (microwave system) or supplied for the UV system and is metered into the application system. When adding the binder, the binder resin can be jetted and rolled or calendered as a film. After adding the binder, the reinforcement mat is placed in the balanced half of the mold (
(male or female).
型が成形プレスの中へ迅速に輸送され、そして指向エネ
ルギー源に接続される。成形プレスが閉鎖して強化材マ
ットを所望の形状に成形する。閉じられている間、紫外
線エネルギーが成形型に加えられ、従って触媒結合剤樹
脂を迅速に硬化する。結合剤樹脂は、硬化する際に、重
合化して剛性のあるマスになり、予備成形物が成形型の
形状を保持することができる。結合剤が反応のための熱
を発生するかまたは発熱を伴うシステムでエネルギーが
止められると、ガラス強化材が脱熱剤として作用し、予
備成形物を冷却することができる。ガラスの加熱は最小
である。なぜなら、それは入力パワーからエネルギーを
吸収しないで、結合剤反応から放出される熱からのみ吸
収するからである。それ故、型表面の加熱も最小である
。The mold is rapidly transported into a forming press and connected to a directed energy source. The forming press closes to form the reinforcement mat into the desired shape. While closed, ultraviolet energy is applied to the mold, thus rapidly curing the catalytic binder resin. When the binder resin cures, it polymerizes into a rigid mass that allows the preform to retain the shape of the mold. When the binder generates heat for reaction or the energy is turned off in an exothermic system, the glass reinforcement can act as a heat sink and cool the preform. Heating of the glass is minimal. This is because it does not absorb energy from the input power, but only from the heat released from the binder reaction. Heating of the mold surface is therefore also minimal.
強化材マットはもはや加熱する必要がなく、キャリア予
備成形物の形状に合致するように引き伸ばされて、冷却
される。必要なかつ剛性化される場合に、ここでも、前
述したエネルギーステッチ溶接と呼ばれる化学的ステッ
チ溶接技術により所定の場所に形材を加えることができ
る。The reinforcement mat no longer needs to be heated, it is stretched to match the shape of the carrier preform and allowed to cool. Once again, when required and to be made rigid, profiles can be added in place by the previously mentioned chemical stitch welding technique called energy stitch welding.
慣用の予備成形法は目下自動化で改良されているが、一
般に作業者に依存し続けている。本発明は、高いレベル
の自動化で、完全な製品を提供する産業上の製造方法の
ために設計される。Although conventional preforming methods are currently being improved with automation, they generally remain operator dependent. The present invention is designed for industrial manufacturing methods that provide complete products with a high level of automation.
自動化/ロボットの使用と共に、ガラスの配分が非常に
均一になりかつ繰り返し一貫しており、方法の全ての面
を統計学的に制御可能にする。With the use of automation/robots, the glass distribution becomes very uniform and repeatably consistent, making all aspects of the process statistically controllable.
剛性化サイクルの後、成形プレスが開かれ、そして型が
迅速に外に輸送され、そこでキャリア予備成形物が機械
的に取り出されて、インサート適用または成形のために
他の処理位置へ移送される。After the stiffening cycle, the forming press is opened and the mold is quickly transported out where the carrier preform is mechanically removed and transported to another processing location for insert application or molding. .
慣用のRTM/SRIM成形法を構造要素に通用する際
に、繊維層厚さが強度必要条件に抵抗するように調節さ
れる。エネルギーステッチ溶接法は、全体の厚さと重さ
を増加させずに強化材を高い応力範囲に選択的にかつ特
別に付は加えることができる。それ故、本発明の方法は
、二つの種類のステッチ溶接技術、すなわちマイクロ波
および紫外線に役に立つ。インサート、密閉形材および
/またはコアのキャリア予備成形物への応用は、エネル
ギーステッチ溶接技術を用いて処理できる。強化材の予
め切断した形材を、二次マイクロ波または紫外線エネル
ギー施与装置を用いて所定の場所に仮付は溶接すること
ができる。マイクロ波エネルギーを用いるとき、付は加
えた強化材と結合剤を有するキャリア予備成形物を成形
プレスの中へまたはエネルギーが加えられている間材料
を所定の場所に保持する二次クランプ装置の中へ迅速に
輸送することができる。同様に、紫外線ステッチ溶接法
では、強化材が所定の場所にプレスされ、特別なUV感
知結合剤樹脂が特定の点位置に加えられ、それから紫外
線エネルギーが結合剤樹脂を硬化するために加えられる
。When applying conventional RTM/SRIM molding techniques to structural elements, the fiber layer thickness is adjusted to resist strength requirements. Energy stitch welding allows reinforcement to be selectively and specifically added to high stress ranges without increasing overall thickness and weight. Therefore, the method of the present invention is useful for two types of stitch welding techniques: microwave and ultraviolet. The application of inserts, closure profiles and/or cores to carrier preforms can be processed using energy stitch welding techniques. Pre-cut sections of reinforcement can be tack-welded in place using a secondary microwave or ultraviolet energy application device. When using microwave energy, the carrier preform with added reinforcement and binder is placed into a forming press or into a secondary clamping device that holds the material in place while the energy is applied. can be quickly transported to Similarly, in the UV stitch welding method, the reinforcement is pressed into place, a special UV-sensitive binder resin is applied at specific point locations, and then UV energy is applied to cure the binder resin.
仕上げられた予備成形物は、保持領域へまたは直接成型
操作へ移送することができる。予備成形物の剛性化は成
型サイクルより早いので、種々の成形型を剛性化過程で
設置することができ、従って他の成形ステーションに供
給するために多数の予備成形物の付形物を造ることがで
きる。The finished preform can be transferred to a holding area or directly to a molding operation. Since the stiffening of the preform is faster than the molding cycle, different molds can be installed during the stiffening process, thus making it possible to create a large number of preform appendages for feeding other molding stations. I can do it.
材料因子は、剛性化過程を有効に達成するためにきわめ
て重要である。マイクロ波の適用の際に、非常に低い電
気的損失を有する合成材料が型表面に必要である。型に
使用される材料にマイクロ波エネルギーが影響を及ぼす
ことができないしかつ予備成形物を剛性化するために必
要なエネルギーを型材料が吸収することができない。ま
た、型材料は、予備成形物結合剤により発生される熱に
関して良好な熱安定性を必要とする。発生した熱は最小
であるけれども、繰り返しサイクルは著しい熱の発生を
引き起こすかもしれない。他方では、剛性化結合剤とし
て使用される材料は、マイクロ波エネルギーに反応して
電気的損失特性が高く、それ故この方法にきわめて有効
である。Material factors are critical to effectively accomplishing the stiffening process. During microwave applications, synthetic materials with very low electrical losses are required for the mold surface. The microwave energy cannot affect the material used in the mold and the mold material cannot absorb the energy required to stiffen the preform. The mold material also requires good thermal stability with respect to the heat generated by the preform binder. Although the heat generated is minimal, repeated cycling may cause significant heat generation. On the other hand, the materials used as stiffening binders have high electrical loss properties in response to microwave energy and are therefore very useful in this method.
指向エネルギー予備成形システムを容易にするために、
適当な結合剤系が必要である。慣用の予備成形に使用さ
れる典型的な標準結合剤は、通常熱硬化性ポリエステル
類または種々の熱可塑性ポリマー類である。指向エネル
ギー過程のために、必要条件はいっそう厳しい。熱可塑
性結合剤をキャリア予備成形物に使用する場合には、繊
維インサートの添加中指向工ふルギーを再び加えて、成
型すべき部品の種々の範囲をさらに強化するときに熱可
塑性結合剤が軟化して離れるだろう。それ故、ある場合
には、熱可塑性結合剤が付属物には満足であるが、主キ
ャリア予備成形物には満足ではないだろう。このために
、熱硬化性ポリマーが必要である。付加的な必要条件も
必要である。結合剤は、予備成形物と共に使用される種
々の母材樹脂と相溶性でなければならない。これは、ポ
リエステル類、ビニールエステル類、ポリウレタン類、
ポリイソシアネート類、ポリ尿素類、JPN樹脂類、お
よびポリエステル/ウレタン混成物(および多分エポキ
シ類)を含む。ポテンシャル母材樹脂の全てに化学的性
質を使用できるならば、特に有用であろう。上記の必要
条件に加えて、この方法のために結合剤は、指向エネル
ギーに反応して高度に活性でなければならない。ここで
は、結合剤樹脂が特別に化学的に組織立てられ、これに
よりそれ自体が加えられたエネルギーに反応して高度に
活性であるようになる。エネルギーが加えられたときに
、結合剤が活性化されて数秒内で硬化することは重要で
ある。熱は硬化過程の部分であることができるので、エ
ネルギーが導かれたときに熱を迅速に発生させなければ
ならないが、エネルギーが終えたときに瞬間的に加熱を
止めなければならない。反応のために熱を発生するまた
は発熱を伴う結合剤系が選択される場合には、強化材は
脱熱剤として作用し、予備成形物それ自体が熱しないよ
うにかなり防止される。マントの加熱はこの方法では必
要条件ではないので、熱成形形式の場合のように、結合
剤系を活性化する前に、結合剤が加えられている強化材
を吸引して所定の形状にすることができる。硬化の完了
後指向エネルギーをさらに加えることにより、結合剤が
さらに活性化せず、または少なくとも結合特性を劣化さ
せないかまたは放出しない。剛性化後、硬化した状態の
結合剤が、加えられるエネルギーに対して充分に透過性
になって、その剛性化特性の劣化や損失を防止する。こ
のことは、インサートを付は加えるために特に重要であ
る。指向エネルギーに対し高度に活性である大抵の熱硬
化性ポリマー結合剤は硬化の初期段階でしかし硬化が連
続するにつれて活性の減少する段階で高度に活性である
傾向がある。それ故、完全な硬化を得ることは難しい。To facilitate directed energy preforming systems,
A suitable binder system is required. Typical standard binders used in conventional preforming are usually thermosetting polyesters or various thermoplastic polymers. For directed energy processes, the requirements are even more stringent. If a thermoplastic binder is used in the carrier preform, the thermoplastic binder will soften during the addition of the fiber inserts and when the directional strength is added again to further strengthen the various areas of the part to be molded. and leave. Therefore, in some cases, a thermoplastic binder may be satisfactory for the accessory, but not for the main carrier preform. For this purpose, thermosetting polymers are required. Additional requirements are also necessary. The binder must be compatible with the various matrix resins used with the preform. This includes polyesters, vinyl esters, polyurethanes,
Includes polyisocyanates, polyureas, JPN resins, and polyester/urethane hybrids (and possibly epoxies). It would be particularly useful if chemistry could be used for all of the potential matrix resins. In addition to the above requirements, the binding agent for this method must be highly active in response to directed energy. Here, the binder resin is specially chemically structured so that it is itself highly active in response to applied energy. Importantly, when energy is applied, the binder is activated and hardens within seconds. Since heat can be part of the curing process, the heat must be generated quickly when the energy is introduced, but the heating must be stopped momentarily when the energy is finished. If a binder system is selected that generates heat for reaction or is exothermic, the reinforcement acts as a heat sink and is largely prevented from heating the preform itself. Heating the mantle is not a prerequisite for this method, so the reinforcement to which the binder has been added is vacuumed into shape before activating the binder system, as in the case of thermoforming formats. be able to. Further application of directed energy after curing is complete does not further activate the binder, or at least does not degrade or release the bonding properties. After stiffening, the binder in the cured state becomes sufficiently transparent to the applied energy to prevent degradation or loss of its stiffening properties. This is particularly important for attaching inserts. Most thermosetting polymeric binders that are highly active to directed energy tend to be highly active during the initial stages of curing, but with decreasing activity as curing continues. Therefore, it is difficult to obtain complete curing.
なぜなら、ポリマーがエネルギーを吸収することを止め
るからである。This is because the polymer stops absorbing energy.
また、空気の抑制も硬化の完了に影響を及ぼす。Air suppression also affects the completion of curing.
硬化が不完全であるので、母材樹脂のための結合場所が
利用可能でありかつそのため成型が完全であるときに物
理的特性が高められることになる。他の熱硬化性ポリマ
ー結合剤は硬化過程を通じて高度に活性であり、かつモ
ノマーのような揮発性添加剤が用いられる場合に、過度
の加熱および結合剤の結合能力の劣化が起こる。Because the cure is incomplete, bonding sites are available for the matrix resin and therefore physical properties will be enhanced when molding is complete. Other thermoset polymeric binders are highly active throughout the curing process, and when volatile additives such as monomers are used, excessive heating and degradation of the binding capacity of the binder occurs.
マイクロ波指向エネルギーシステムの場合に、結合剤樹
脂の反応温度が低温に対し設計されるが、増進されたと
きに適当な過程貯蔵寿命をを許すために環境より充分上
に設計される。エネルギー源から局部に制限されかつ指
向された加熱は、硬化の完了に充分である300°F以
上の温度を達成できる。マイクロ波技術で本発明を実施
する際に使用するために開発された特殊な結合剤は、フ
リーマン・ケミカル・コーポレーション(Freema
n Chemical Corp、)のスチポール(S
typol) XP44−A旧2−51Bとして知ら
れている。これは、希釈された型のFreeman 4
4−7010結合剤である。この結合剤は、加えられた
エネルギーの下で必要な硬化特性、全ての必要な母材樹
脂と相溶性である適当な化学的性質、ガラス繊維に対し
てだけでなく大抵の有機補強繊維に対しても良好な接着
性、優れた結合特性および剛性のある予備成形物の製造
を有する。また結合剤は、繊維成分インサートを付は加
える際に使用される付加的な結合剤とも相溶性である。In the case of microwave directed energy systems, the reaction temperature of the binder resin is designed for low temperatures, but well above the environment to allow adequate processing shelf life when enhanced. Localized and directed heating from an energy source can achieve temperatures in excess of 300° F., which are sufficient to complete curing. Special binders developed for use in practicing the invention with microwave technology are available from Freeman Chemical Corporation (Freema).
n Chemical Corp, ) Stypol (S
typol) XP44-A Formerly known as 2-51B. This is a diluted version of Freeman 4
4-7010 binder. This binder has the necessary curing properties under applied energy, a suitable chemistry that is compatible with all the necessary matrix resins, and is suitable for most organic reinforcing fibers as well as for glass fibers. It also has good adhesion, excellent bonding properties and production of rigid preforms. The binder is also compatible with any additional binders used in attaching or adding the fiber component insert.
キャリア予備成形のためのマントの形態のガラス繊維は
、負荷を支承する部品に理想的である。連続的なストラ
ンド予備成形可能なマットは、成形過程の間部品形状に
容易に合致するのに役立ち、かつ予備成形物を製造する
のに有利に使用できる。Glass fibers in the form of cloaks for carrier preforming are ideal for load-bearing parts. Continuous strand preformable mats lend themselves to easily conforming to part shapes during the forming process and can be advantageously used to produce preforms.
多層の強化材77)を同時に所望の形状に成形できる。Multiple layers of reinforcing material 77) can be simultaneously molded into a desired shape.
他の種類の強化材を、エネルギーステッチ溶接法を用い
て、補剛し、リブを付けかつ取り付けられた構成要素の
ために封入することができる。これらの種類の強化材、
繊維状の、金属質のおよび/または軽量構造の発泡体お
よび低密度コアを、インサート材料の配置が予備成形物
構造に必要である場合に、装入および行形過程の手始め
にキャリア予備成形物の部品としてまたは二次操作とし
て付Gノ加えることができる。Other types of reinforcement can be stiffened, ribbed and encapsulated for attached components using energy stitch welding techniques. These types of reinforcements,
Fibrous, metallic and/or lightweight structural foams and low-density cores are added to the carrier preform at the beginning of the charging and shaping process when placement of insert material is necessary for the preform construction. It can be added as a component or as a secondary operation.
マット材料を単一指向性織物または他の強化材と共に特
定の位置に用いるときに、高い繊維含量の最適な補強構
造を達成できると共に、成型作業中樹脂系を容易にハン
ドリングしかつ透過するために剛性のある形状を維持す
ることができる。When matte materials are used in specific locations with unidirectional fabrics or other reinforcements, an optimal reinforcement structure with high fiber content can be achieved, as well as for easy handling and penetration of the resin system during molding operations. A rigid shape can be maintained.
強化材を特定の位置に配置することにより、成型製品の
必要な強度を得るために必要な場所に繊維配向ができる
。By placing the reinforcement in specific locations, fiber orientation can be achieved where necessary to obtain the required strength of the molded product.
実際のテストでは、二つの指向エネルギーパワー源が両
方別々におよび互いに一緒に使用された。In actual testing, two directed energy power sources were used both separately and in conjunction with each other.
実際のテストに用いられた指向エネルギーパワー源は、
2450 MHzで作用するO−6’kw−’イクロ波
発生器である。パワーレベル必要条件は、材料装入のマ
スに対する成形工具の寸法に依存する。初期のバワーレ
ヘル較正は、剛性化するサイクルタイムを最適化するよ
うに要求される。The directed energy power source used in the actual test was
It is an O-6'kw-' microwave generator operating at 2450 MHz. Power level requirements depend on the dimensions of the forming tool relative to the mass of the material charge. An initial bower level calibration is required to optimize the stiffening cycle time.
パワー出力き反射されるエネルギーレベルは制御される
。比較的高いパワーを必要とする比較的大きな成形用具
のためには、付加的な発生器を付は加えることができる
。パワーを減少させるためのパワーランピングを利用し
て結合剤硬化過程を補償することができる。なぜなら、
反応中、結合剤がエネルギー場に幾分透過になり、それ
故充分な出力パワーを必要としないからである。また、
パワーランピングは発生器寿命を延ばし、かつパワーサ
ージを防止する。The energy level reflected from the power output is controlled. For larger molding tools requiring higher power, additional generators can be added. Power ramping to reduce power can be used to compensate for the binder curing process. because,
This is because during the reaction the binder becomes somewhat transparent to the energy field and therefore does not require sufficient output power. Also,
Power ramping extends generator life and prevents power surges.
エネルギーステッチ溶接および強化材インサートのため
の指向エネルギーは、局部化したマイクロ波エネルギー
の施与、またはステッチ溶接結合剤樹脂の重合化を引き
起こすために予備成形物の特定の位置にエネルギーを指
向させるための紫外線エネルギーレベルムからなる。Directed energy for energy stitch welds and reinforcement inserts for the application of localized microwave energy or for directing energy to specific locations on the preform to cause polymerization of the stitch weld binder resin consists of ultraviolet energy levels.
紫外線硬化システムのために、紫外線放射源が予備成形
物型の本体内に型表面の後に含まれることを除いて、同
様な型構造が用いられる。For UV curing systems, a similar mold structure is used, except that the UV radiation source is included within the body of the preform mold after the mold surface.
型表面は、紫外線放射が予備成形物を貫通しかつ予備成
形物の中へ通ることができる金属スクリーン、透明なア
クリルまたは他の剛性のある材料で構成することができ
る。透明なアクリルのような材料は、費用をかけずに複
雑な形状に熱成形することができかつ磨耗が明らかなと
きに容易に取り替えられるので、望ましい。The mold surface can be constructed of a metal screen, clear acrylic or other rigid material that allows ultraviolet radiation to pass through and into the preform. Materials such as clear acrylic are desirable because they can be inexpensively thermoformed into complex shapes and are easily replaced when wear is apparent.
特別に設計された合成材料が、予備成形物の形状を形成
するために用いられる。いっそう複雑な形状には、予備
成形物型の組み合わせを、同しエネルギー源とまたは独
立して成形されたいくつかの付形物(半組立体)と同時
に用い、かつ後で全部の予備成形操作においてエネルギ
ーステッチ溶接で結合することができる。工具は、予備
成形物の形状を成形するためだけではなく、エネルギー
を結合剤を含む強化材の中へ特別に指向させるように設
計される。この設計のかぎは、予備成形物を最も高い硬
化エネルギー強度の領域に予備成形物部分を配置するこ
とおよびエネルギー波を一様に分配する適当な工具構造
に依存する。マイクロ波技術で指向エネルギーの一様性
を有効に達成するために、三次元の一致する導波管を直
接型設計に配置して多軸波の形成を生じさせる。導波管
は、最大エネルギーが中心にある特定の横断面寸法を有
するチャンネルからなるので、導波管が分割されかつ各
半部が型の対応する半分の表面に配置される。導波管ま
たは材料を動かさないで波の同調を達成するために、型
設計の輪郭はへび状のパターンを作る。また、適当な横
断面寸法を導波管のヘンド内で維持することも重要であ
る。ベンドの製造は、最適の性能を達成するために注意
深く考慮しなければならない。導波管の各手部分は、マ
イクロ波に透過でありかつ型表面として作用する材料か
らなる、予備成形物材料に面する、第四の側部を有する
金属材料で作られた三つの側部からなる。型のキャビテ
ィまたは導波管部分の各対応する半部の間の間隔は、そ
れるエネルギーの損失を防止しかつ導波管の適当な横断
面寸法を確保するように設計しなければならない。型表
面範囲の中心に向かって、間隔を増加して波の交差同調
を許すことができる。A specially designed synthetic material is used to form the shape of the preform. For more complex shapes, a combination of preform molds can be used simultaneously with the same energy source or with several independently formed features (subassemblies) and later combined with the entire preform operation. Can be joined by energy stitch welding. The tool is designed not only to shape the preform, but also to specifically direct the energy into the binder-containing reinforcement. The key to this design relies on positioning the preform portions in areas of highest curing energy intensity and appropriate tooling configuration to evenly distribute the energy waves. To effectively achieve directed energy uniformity in microwave technology, three-dimensional matched waveguides are placed in a direct design to produce multiaxial wave formation. Since the waveguide consists of a channel with a particular cross-sectional dimension in which the maximum energy is centered, the waveguide is divided and each half is placed on the surface of a corresponding half of the mold. To achieve wave tuning without moving the waveguide or material, the contours of the mold design create a snake-like pattern. It is also important to maintain appropriate cross-sectional dimensions within the waveguide ends. Bend manufacturing must be carefully considered to achieve optimal performance. Each hand portion of the waveguide has three sides made of metallic material with a fourth side facing the preform material, consisting of a material that is transparent to microwaves and acts as a mold surface. Consisting of The spacing between each corresponding half of the mold cavity or waveguide section must be designed to prevent stray energy losses and ensure proper cross-sectional dimensions of the waveguide. Towards the center of the mold surface area, the spacing can be increased to allow cross-tuning of the waves.
以下、本発明を図面に示す実施例により詳細に説明する
。Hereinafter, the present invention will be explained in detail with reference to embodiments shown in the drawings.
第1図を参照すると、基本的工具が、上方部分14と下
方部分16を有する分割したへび状導波管12からなる
ものとして10で総括的に示されており、これらの部分
は基本的に互いに鏡像であって、間隙18により分離さ
れかつマイクロ波入力継手20を備えている。導波管1
4は、へび状構造を形成する頂壁24と側壁26からな
る。ウェブ22の形態の合成材料が、マイクロ波エネル
ギーを加えるために間隙I8に位置している。Referring to FIG. 1, the basic tool is shown generally at 10 as consisting of a segmented serpentine waveguide 12 having an upper portion 14 and a lower portion 16, which portions are essentially They are mirror images of each other, separated by a gap 18 and provided with a microwave input fitting 20. waveguide 1
4 consists of a top wall 24 and a side wall 26 forming a snake-like structure. A synthetic material in the form of a web 22 is located in gap I8 for applying microwave energy.
本発明を試験するために用いられた形式の構造が分割マ
イクロ波導波管30からなるものとして28で総括的に
示されており、この導波管は、側壁32と頂壁34から
なる上方部分を有する。側壁32は、36と38で示さ
れた型の輪郭に合致するように行形されており、型は、
成型すべき予備成形物の形状に合致する内面40と内面
42を有する。表面40と42を担持する材料およびそ
れらの表面と導波管の間の支持材料がマイクロ波エネル
ギーに対して透過性である。導波管は部分に設けられか
つ44で示されたように互いにかつマイクロ波エネルギ
ーの入力のために継手を有する。強化材と結合剤樹脂の
合成材料は、表面40と42の間に46で示されている
。合成材料46が工具の型部分の中へ装入されると、マ
イクロ波エネルギーが加えられて硬化のために結合剤樹
脂を活性化する。A structure of the type used to test the present invention is shown generally at 28 as consisting of a segmented microwave waveguide 30, with an upper portion consisting of side walls 32 and a top wall 34. has. The sidewalls 32 are contoured to match the contours of the molds indicated at 36 and 38;
It has an inner surface 40 and an inner surface 42 that match the shape of the preform to be molded. The materials carrying surfaces 40 and 42 and the support material between those surfaces and the waveguide are transparent to microwave energy. The waveguides are provided in sections and have couplings as indicated at 44 to each other and for the input of microwave energy. A composite material of reinforcement and binder resin is shown at 46 between surfaces 40 and 42. Once the composite material 46 is loaded into the mold section of the tool, microwave energy is applied to activate the binder resin for curing.
第3図のフローチャートに眼を転じると、本発明を実施
するための典型的な方法が48で示されており、この方
法は、強化材(ガラス繊維マット)と未硬化の剛性化材
料(結合剤樹脂)の積み重ね層の工程50を有し、この
工程では、結合剤樹脂を強化材に加えることにより形成
される。または、方法48は、これに代わり、未硬化の
剛性化材料を強化材マットに噴射する工程52を有する
。次に、ブランクが、予備成形物の平坦な展開の形状に
合致するように54で切断される。56で、ブランクが
型の中でプレスされて予備成形物の形状になり、マイク
ロ波エネルギーが58で加えられて結合剤の硬化を引き
起こす。Turning to the flowchart of FIG. 3, a typical method for carrying out the present invention is shown at 48 and includes a reinforcement material (glass fiber mat) and an uncured stiffening material (bonded 50 of stacked layers of binder resin) formed by adding a binder resin to the reinforcement. Alternatively, method 48 may alternatively include injecting 52 an uncured stiffening material onto the reinforcement mat. The blank is then cut at 54 to match the flattened shape of the preform. At 56, the blank is pressed into a preform shape in a mold and microwave energy is applied at 58 to cause curing of the binder.
60で、結合剤が硬化されて堅くなり、そして剛性化し
た予備成形物を型から取り出すことができる。At 60, the binder is cured and hardened, and the stiffened preform can be removed from the mold.
第4図は、処理ステーションの間の材料を取り扱うため
のロボットを用いた同様な方法を示す。FIG. 4 shows a similar method using a robot to handle materials between processing stations.
第4図では、最初の工程は、ダイカッタ62により示さ
れたように、予備成形物の展開した形状に合致するよう
に強化材マットを予め切断することである。これは、第
3図に示した方法の始めの部分に代わる工程である。マ
ットが62で切断された後、結合剤が64で結合剤施与
装置66において加えられるが、この結合剤施与装置は
、結合剤樹脂源68と触媒促進剤70とを有する。前述
したように、結合剤を結合剤施与装置66において噴射
、圧延またはカレンダー掛けによす施される。次に、強
化材と結合剤の合成ブランクが結合剤施与装置から型7
2にロボット74により移送される。型72は、合成ブ
ランクが第2図の42.46で示したように型の雄部分
に位置するように第2図に示した形式のものでよい。第
4図に戻ると、それから型72がシャツトル78に沿っ
てプレス76へ動かされ、そこでは型の二つの半部がプ
レスされて予備成形物の所望の形状を複製し、そしてエ
ネルギーがマイクロ波エネルギーのような指向エネルギ
ー源80から加えられる。In FIG. 4, the first step is to pre-cut the reinforcement mat to match the developed shape of the preform, as shown by die cutter 62. This is an alternative step to the initial part of the method shown in FIG. After the mat is cut at 62, a binder is added at 64 in a binder application device 66, which includes a source of binder resin 68 and a catalyst promoter 70. As previously discussed, the binder is applied by spraying, rolling or calendering in the binder applicator 66. The reinforcement and binder composite blank is then transferred from the binder applicator to mold 7.
2 by the robot 74. The mold 72 may be of the type shown in FIG. 2 such that the composite blank is located in the male portion of the mold as shown at 42.46 in FIG. Returning to FIG. 4, mold 72 is then moved along shuttle 78 to press 76 where the two halves of the mold are pressed to replicate the desired shape of the preform and energy is applied to the microwave. The energy is applied from a directed energy source 80, such as energy.
次に、シャツトル78に沿って型72を取り出し位置へ
動かすことによりロボット82が硬化された予備成形物
84を型72から取り出す。ここでは、予備成形物は、
強化材を補強構造の形態で施さなければならないという
点でキャリア予備成形物になる。それから、ロボット8
2が短期間貯蔵のために予備成形物を積み重ねるかまた
はそれを直接エネルギーステッチ溶接過程へ移動させる
。The robot 82 then removes the cured preform 84 from the mold 72 by moving the mold 72 along the shuttle 78 to the removal position. Here, the preform is
This results in a carrier preform in that the reinforcement must be applied in the form of a reinforcing structure. Then robot 8
2 stack the preform for short-term storage or transfer it directly to the energy stitch welding process.
要素をキャリア予備成形物にステッチ溶接しなければな
らないときに、強化材が86で前のように予め切断され
、そして予め切断された材料が強化材形状92をとるよ
うにロボット88がそれをフォーマ−90の上へ位置決
めする。それから、ロボット94は、今やキャリア予備
成形物である予備成形物84を取り戻し、そしてキャリ
ア予備成形物を成形された要素92の上へ配置する。そ
こには、キャリア予備成形物84および成形された要素
92が緊密に接触して係合する箇所(図示省略)がある
。エネルギーステッチ溶接過程がマイクロ波エネルギー
を利用するときには、要素92は結合剤樹脂を含む。エ
ネルギーステッチ溶接過程が紫外線エネルギーを当てに
しているときには、要素84と92が緊密に係合してい
る特定の点位置に紫外線感知結合剤樹脂が加えられる。When the element has to be stitch welded to the carrier preform, the reinforcement is precut as before at 86 and the robot 88 forms it so that the precut material assumes the reinforcement shape 92. Position above -90. Robot 94 then retrieves preform 84, now a carrier preform, and places the carrier preform onto molded element 92. There is a point (not shown) where carrier preform 84 and molded element 92 engage in intimate contact. When the energy stitch welding process utilizes microwave energy, element 92 includes a binder resin. When the energy stitch welding process relies on ultraviolet energy, ultraviolet sensitive binder resin is added at specific point locations where elements 84 and 92 are intimately engaged.
それから、紫外線エネルギーが硬化および結合のために
加えられる。どちらの場合にも、そのとき指向エネルギ
ー源96を用いて結合剤を硬化しかつ二つの要素を一緒
に結合して強化構造体98を形成する。それがら、構造
体98が最終構造の成形のために成形過程へ移送される
。Ultraviolet energy is then applied for curing and bonding. In either case, a directed energy source 96 is then used to cure the bonding agent and bond the two elements together to form a reinforced structure 98. Structure 98 is then transferred to a molding process for forming the final structure.
上記のことから認められるように、付属物をキャリア予
備成形物に結合して成型最終製品の構造強さを増加させ
るかまたは予備成形物への要素のエネルギーステッチ溶
接により成型最終製品のための付属装置をっけ加えるこ
とができる。他の要素に取り付けるべき一つの要素を、
同じエネルギー指向過程によりまたはともがくエネルギ
ー指向過程により作ることは必要でない。一つの要素を
他の要素に取り付けるには、マイクロ波感知または紫外
線感知結合剤樹脂を加え、かつ対応するエネルギーをそ
の結合剤樹脂を硬化するために加えればよい。それ故、
この可撓性は、マイクロ波技術により製造された予備成
形物が紫外線技術を用いたエネルギーステッチ溶接によ
る強化材要素を有しかっこの逆もある点で、エネルギー
ステッチ溶接過程の利点である。また、木材、鋼、カー
ボンブラックおよび同様なもののような要素を、適当な
結合剤樹脂と組み合わせたどちらかの技術を用いること
により予備成形物に取り付けることができる。As can be seen from the above, attachments for a molded final product by bonding the appendage to the carrier preform to increase the structural strength of the molded final product or by energy stitch welding of the elements to the preform. You can add devices. One element that should be attached to another element,
It is not necessary to create by the same energy-directing process or by struggling energy-directing processes. To attach one element to another, a microwave or ultraviolet sensitive binder resin may be added and a corresponding energy applied to cure the binder resin. Therefore,
This flexibility is an advantage of the energy stitch welding process in that preforms produced by microwave technology have reinforcement elements by energy stitch welding using ultraviolet light technology and vice versa. Also, elements such as wood, steel, carbon black, and the like can be attached to the preform using either technique in combination with a suitable binder resin.
第5図には、工具が、補完的な成形部材104を有する
成形部材102を含む一対の分離可能な型部分からなる
ものとして100で示されている。In FIG. 5, the tool is shown at 100 as consisting of a pair of separable mold sections including a molding member 102 having a complementary molding member 104. As shown in FIG.
成形部材102.104はマイクロ波透過性材料で作ら
れかつ型キャビティの内面を形成する。型の残りはその
上に形成され、かつ外層106.108と、複数の半径
部分112を経てへび状導波管に連結される複数の導波
管部分110とを含む。The molding members 102, 104 are made of microwave transparent material and form the inner surface of the mold cavity. The remainder of the mold is formed thereon and includes an outer layer 106, 108 and a plurality of waveguide sections 110 connected to the serpentine waveguide via a plurality of radial sections 112.
二つの部分を一緒にしたときに、完全な導波管が形成さ
れ、そしてそこには型キャビティを区画する層102と
104の間の空間がある。114と116で示したよう
に、型は木材、発泡体または樹脂のような支持材料を含
んでもよい。When the two parts are brought together, a complete waveguide is formed, and there is a space between layers 102 and 104 that defines the mold cavity. As shown at 114 and 116, the mold may include a support material such as wood, foam or resin.
予備成形物を作る際の紫外線の使用について上に述べた
。この技術は、紫外線光源を成形用具に配置して、紫外
線放射を繊維強化予備成形物の方へ指向させて剛性化構
造体を形成する。The use of ultraviolet light in making preforms was mentioned above. This technique places an ultraviolet light source in a forming tool to direct ultraviolet radiation toward a fiber-reinforced preform to form a stiffened structure.
剛性化結合剤樹脂を含むガラス繊維強化材が工具の二つ
の釣り合う半部分の間に配置される。A glass fiber reinforcement containing a stiffening binder resin is placed between the two counterbalanced halves of the tool.
紫外線放射が加えられると、結合剤樹脂は、ガラス繊維
材料を工具の合致する形状に保持することができる剛性
のある製品を形成する分子の重合化を受ける。When UV radiation is applied, the binder resin undergoes molecular polymerization that forms a rigid product capable of holding the glass fiber material into the conforming shape of the tool.
マイクロ波技術と同様に、紫外線放射に分子的に鋭敏で
ある結合剤樹脂がガラス繊維強化材に加えられる。次い
で、その強化材が、最終部品の形状に合致するように作
られる成形型に配置される。成形型の二つの半部分を接
合するときに、繊維状材料が型の形状に合致する。繊維
材料と接触している成形型−の対応する半部の表面は、
紫外線放射を伝達する材料で作られる。Similar to microwave technology, a binder resin that is molecularly sensitive to ultraviolet radiation is added to the glass fiber reinforcement. The reinforcement is then placed in a mold that is made to match the shape of the final part. When joining the two halves of the mold, the fibrous material conforms to the shape of the mold. The surface of the corresponding half of the mold in contact with the fibrous material is
Made of materials that transmit ultraviolet radiation.
この材料は、固体の透明なアクリル型熱プラスチックま
たは金属ワイヤメツシュスクリーンであることができる
。それ故、紫匁線光源が成形用具構造内に配置されて、
放射線を型表面を通ってそして繊維状材料に指向させる
。簡単な成形用具については、光源が型表面の下の開放
室の中へ配置される。型表面への構造支持が必要である
いっそう複雑な予備成形物の形状必要条件のためには、
紫外線光源が多室部分に配置され、かつ同時に剛性化操
作を行うように付勢する。This material can be a solid transparent acrylic type thermoplastic or a metal wire mesh screen. Therefore, a violet momme light source is placed within the forming tool structure,
Radiation is directed through the mold surface and into the fibrous material. For simple molding tools, the light source is placed into an open chamber below the mold surface. For more complex preform shape requirements where structural support to the mold surface is required,
An ultraviolet light source is placed in the multichamber section and simultaneously energized to perform the stiffening operation.
成る結合剤樹脂を紫外線技術で用いることができること
が見出された。これらはフリーマンケミカルから入手で
き、かつ80497 (スローシステム) 、747−
10(媒体システム)および19−4837(迅速シス
テム)として知られている。適用は、マイクロ波技術の
通用と同様である。It has been found that binder resins consisting of the following can be used in ultraviolet technology. These are available from Freeman Chemical and 80497 (Slow System), 747-
10 (media system) and 19-4837 (rapid system). The application is similar to that of microwave technology.
第6図を参照すると、紫外線過程のための工具が、上方
型部品120と下方型部品122からなるものとして1
18で示されている。型表面は、それぞれ124 、+
26で示されている。室128は下方型部品122の型
部品126により形成されかつその中に複数の紫外線源
130〜・140が取り付けられている。Referring to FIG. 6, a tool for an ultraviolet process is shown comprising an upper mold part 120 and a lower mold part 122.
18. The mold surfaces are 124 and +
26. A chamber 128 is formed by the mold part 126 of the lower mold part 122 and has a plurality of ultraviolet light sources 130-140 mounted therein.
型を閉じた場合、第7図に示したように、合成材料が、
型表面124.126により区画された形状に合致する
ようになされがっ#130〜140から紫外線エネルギ
ーを加えることによりその形状が剛性化される。When the mold is closed, as shown in Figure 7, the synthetic material
It is made to conform to the shape defined by mold surfaces 124, 126, and the shape is made rigid by applying ultraviolet energy from #130-140.
第8図と第9図を参照すると、もう一つの工具が上方型
部品146および下方型部品148からなるものとして
144で示されている。見える通りに、上方型部品は、
側壁15o、側壁152、上壁154、および型壁16
0により完了される内壁とからなる。下方工具部品14
8には、下壁170オヨヒ型壁172により完了される
内壁がある。Referring to FIGS. 8 and 9, another tool is shown at 144 as consisting of an upper mold part 146 and a lower mold part 148. As you can see, the upper mold part is
Side wall 15o, side wall 152, top wall 154, and mold wall 16
and an inner wall completed by 0. Lower tool part 14
8 has an inner wall completed by a lower wall 170 and an Oyohi-type wall 172.
最も上の部分では、壁が型壁160の両側で室164を
区画している。紫外線源166と168は室164内に
取り付けられている。最も下の部分148では、底壁1
70と型壁172が室174を区画している。紫外線源
176が室174に取り付けられている。At the top, walls define a chamber 164 on either side of the mold wall 160. Ultraviolet light sources 166 and 168 are mounted within chamber 164. In the lowest part 148, the bottom wall 1
70 and a mold wall 172 define a chamber 174. A UV light source 176 is attached to chamber 174.
第9図に仕切り線178に沿って閉じられて示されてい
るように、型を閉じると、合成材料が紫外線源166
、168および176により紫外線放射を受けることが
できる。When the mold is closed, the synthetic material is exposed to the ultraviolet light source 166, as shown closed along the dividing line 178 in FIG.
, 168 and 176 can receive ultraviolet radiation.
本発明をその特別な図示の実施例を参照して述べたけれ
ども、本発明の精神と範囲から逸脱せずに本発明の多数
の変更と修正をなしうろことは当業者にとって明らかで
あろう。それ故、当該技術に本発明が寄与する範囲内に
合理的にかつ適正に含められるような全ての変更と修正
をここに保証された特許内に含めるつもりである。Although the invention has been described with reference to specific illustrative embodiments thereof, it will be apparent to those skilled in the art that numerous changes and modifications may be made thereto without departing from the spirit and scope of the invention. It is therefore intended to cover within the scope of the patent warranted herein all such changes and modifications as may reasonably and properly come within the scope of the invention's contribution to the art.
本発明により、樹脂トランスファー成形(RTM)樹脂
射出成形(RIM)および構造反応射出成形(SRIM
)法用の構造強化予備成形物を製造するために指向エネ
ルギーを用いた新規なおよび改善された方法と装置が得
られる。また、本発明により、エネルギーが有効であり
、論理的であり、基本的に簡単でありかつ起こり得る浪
費をできるだけ少なくすると共に材料を最大に使用でき
る。さらに、本発明により、予備成形物の設計において
、リブ、密閉形材、コア、金属や発泡体や木材または他
の材料の封入を含む自由度を設計者に与えることができ
る。The present invention provides resin transfer molding (RTM), resin injection molding (RIM) and structural reaction injection molding (SRIM).
) A new and improved method and apparatus are provided for using directed energy to produce structurally reinforced preforms for use in a method. The invention is also energy efficient, logical, fundamentally simple and allows maximum use of materials with as little possible waste as possible. Additionally, the present invention allows flexibility to the designer in the design of the preform, including the inclusion of ribs, sealing profiles, cores, metal, foam, wood or other materials.
第1図は硬化すべき合成材料を間に挟む分割したへび状
導波管の斜視図、第2図は本発明により構成された工具
の斜視図で、各部品が分割したへび状導波管のそれぞれ
の部分を担持する一つの部品の分離可能な型からなる。
第3図は本発明の基本的方法を示すブロックダイアグラ
ムフローチャート、第4図は本発明を実施するための自
動化された過程の概略図、第5図は本発明を実施する際
に用いることができる工具の分解配列斜視図、第6図は
本発明により構成された工具の概略斜視図で、部品の一
方内に取り付けられた源から紫外線エネルギーをブラン
クに照射することにより結合剤樹脂を剛性化するように
作用可能な二つの部品の分離可能な型からなる。第7図
は第6図の工具の端面図、第8図は本発明により構成さ
れた工具の他の実施例の概略斜視図で、型部品の各々に
取り付けられた源により与えられる紫外線エネルギーに
反応して結合剤樹脂を剛性化するための二つの部品の分
離可能な型からなる。第9図は第8図の端面図である。
12、14.30.110・・・導波管、40.42;
124.126・・・型表面、46・・・結合剤樹脂と
強化材の合成材料、72 ; 102.104;120
.122;146.148・・・型、76・−・プレス
、78・・・シャツトル、80・・・指向エネルギー源
、84・・・予備成形物FIG. 1 is a perspective view of a segmented serpentine waveguide sandwiching the synthetic material to be cured, and FIG. 2 is a perspective view of a tool constructed in accordance with the present invention, in which each part is a segmented serpentine waveguide. Consists of one piece separable mold carrying each part of the. FIG. 3 is a block diagram flowchart showing the basic method of the invention, FIG. 4 is a schematic diagram of an automated process for implementing the invention, and FIG. 5 is a diagram that can be used in implementing the invention. Figure 6 is a schematic perspective view of a tool constructed in accordance with the present invention, in which the binder resin is stiffened by irradiating the blank with ultraviolet energy from a source mounted within one of the parts; It consists of a separable mold in two parts that can be operated in the same way. FIG. 7 is an end view of the tool of FIG. 6, and FIG. 8 is a schematic perspective view of another embodiment of a tool constructed in accordance with the present invention, in which ultraviolet energy is applied by a source attached to each of the mold parts. It consists of a two-part separable mold that reacts to stiffen the binder resin. FIG. 9 is an end view of FIG. 8. 12, 14.30.110... waveguide, 40.42;
124.126...Mold surface, 46...Synthetic material of binder resin and reinforcing material, 72; 102.104;120
.. 122; 146.148...Mold, 76...Press, 78...Shuttle, 80...Directed energy source, 84...Preform
Claims (1)
し、結合剤樹脂をそのブランクに加え、ブランクを予備
成形物の形状に付形し、そして電磁エネルギーを付形さ
れたブランクに加えて結合剤樹脂を剛性化する工程から
なる、剛性のある予備成形物を製造する方法。 (2)結合剤樹脂をガラス繊維強化材に加えて合成ブラ
ンクを形成し、この合成ブランクを所定の形状にプレス
し、そして紫外線エネルギーをプレスしたブランクに加
えて、結合剤樹脂を重合化しかつプレスしたブランクを
剛性のある予備成形物に剛性化する工程からなる、剛性
のある予備成形物を製造する方法。 (3)強化材の可撓性ブランクと未硬化の剛性化材料の
合成物から剛性化した予備成形物を製造する方法におい
て、ブランクを型で予備成形物の形状にプレスし、そし
て型内にある間にそのブランクに電磁エネルギーを加え
て剛性化材料を硬化する工程からなる方法。(4)可撓
性の強化材と未硬化の剛性化材料から予備成形物を製造
する方法において、未硬化の剛性化材料の層を可撓性の
強化材の層に加えて含浸した層構造を形成し、含浸した
層構造からブランクを切断し、そのブランクを予備成形
物の寸法と形状の型キャビティを有する型でプレスし、
そしてプレスしたブランクに型内にある間に紫外線エネ
ルギーを加えて剛性化材料を硬化しかつ剛性化する工程
からなる方法。 (5)ブランクを強化材のマットから切断し、そのブラ
ンクに結合剤樹脂を加え、ブランクを型の二つの部品の
間に配置し、型をプレスへ迅速に輸送し、二つの型部品
を一緒にプレスし、ブランクに電磁エネルギーを加える
と共にプレスして結合剤樹脂を剛性化し、型をプレスか
ら迅速に輸送し、そして剛性のある予備成形物を型から
取り出す工程からなる剛性のある予備成形物を製造する
方法。 (6)所定の形状を有するキャビティを含む型を備え、
前記型は、各型部品が型キャビティの部分を区画する第
一と第二の分離可能な型部品を有し、また第一と第二の
部品を有する分離可能な導波管を備え、前記第一の型部
品には前記第一の導波管部品が取り付けられかつ前記第
二の型部品には前記第二の導波管部品が取り付けられ、
また前記導波管に連結されたマイクロ波エネルギーの源
を備えた、予備成形物を製造するための成型工具。 (7)強化材と剛性化材料からなる合成材料から所定の
三次元形状を有する予備成形物を製造するための成型工
具において、間に合成材料を受け入れるための第一と第
二の分離可能な型部品を備え、これらの型部品は、接合
されたときに前記所定の三次元形状を形成する、協働す
る分離可能な型表面を有し、また第一と第二の部品を有
するマイクロ波導波管を備え、前記第一の部品が前記第
一の型部品により担持されかつ前記第二の部品が前記第
二の型部品により担持され、前記導波管は前記剛性化材
料の硬化を引き起こすように付勢可能である成型工具。 (8)ガラス補強マットを所定の形状のブランクに切断
するための切断手段と、結合剤樹脂を前記ブランクに加
えて強化材と結合剤樹脂材料の合成ブランクを形成する
ための結合剤施与装置と、結合剤樹脂を担持する強化材
を受入れてプレスするために型キャビティを一緒に区画
する第一と第二の分離可能な型部品を有する型と、第一
と第二の分離可能な導波管区分を有するマイクロ波導波
管とを備え、前記第一の区分は前記第一の型部品に取り
付けられかつ前記第二の区分は前記第二の型部品に取り
付けられ、かつマイクロ波入力部を有し、また強化材と
結合剤樹脂の合成ブランクを前記型キャビティに配置す
るための装入手段と、ブランクが予備成形物の形状を複
製するように前記型部品を一緒にプレスするためのプレ
スと、前記型を前記プレスに対し搬入および搬出するた
めのシャットルと、前記マイクロ波導波管を付勢しかつ
結合剤樹脂の硬化および剛性化を引き起こすために前記
マイクロ波入力部に接続するためのマイクロ波発生器と
、型から剛性のある予備成形物を取り出すための取出し
手段とを備えた、剛性のある予備成形物を製造するため
の装置。 (9)電磁エネルギー感知結合剤樹脂の点位置を強化材
要素に加え、強化材要素を移動させて点位置でキャリア
予備成形物と緊密に接触させ、そして電磁エネルギーを
強化材要素の点位置に加えて結合剤樹脂を剛性化しかつ
強化材要素を予備成形物キャリアに結合する工程からな
る、強化材要素を予備成形物キャリアに取り付ける方法
。 (10)マイクロ波感知結合剤樹脂の点位置を強化材要
素に加え、強化材要素を点位置でキャリア予備成形物と
緊密に接触させるように移動させ、そしてマイクロ波エ
ネルギーを強化材要素の点位置に加えて結合剤樹脂を剛
性化しかつ強化材要素を予備成形物キャリアに結合する
工程からなる、強化材要素を予備成形物キャリアに取り
付ける方法。 (11)紫外線感知結合剤樹脂の点位置を強化材要素に
加え、強化材要素を点位置でキャリア予備成形物と緊密
に接触するように移動させ、そして紫外線エネルギーを
強化材要素の点位置に加えて結合剤樹脂を剛性化しかつ
強化材要素を予備成形物キャリアに結合する工程からな
る、強化材要素を予備成形物キャリアに取り付ける方法
。[Claims] (1) Cutting a blank of a predetermined shape from a mat of reinforcement, adding a binder resin to the blank, shaping the blank into the shape of a preform, and applying electromagnetic energy to the shape. A method for producing rigid preforms comprising the step of stiffening a binder resin in addition to a blank that has been prepared. (2) Adding a binder resin to the glass fiber reinforcement to form a composite blank, pressing the composite blank into a predetermined shape, and adding ultraviolet energy to the pressed blank to polymerize and press the binder resin. A method for producing a rigid preform, comprising the steps of: stiffening a blank into a rigid preform. (3) A method of producing a stiffened preform from a composite of a flexible blank of reinforcement and an uncured stiffening material, in which the blank is pressed into the shape of the preform in a mold and A method consisting of applying electromagnetic energy to the blank during a period of time to harden the stiffening material. (4) A method for producing a preform from a flexible reinforcement and an uncured stiffening material, in which a layer of uncured stiffening material is added to and impregnated with a layer of the flexible reinforcement. forming and cutting a blank from the impregnated layered structure, pressing the blank in a mold having a mold cavity of the dimensions and shape of the preform;
and applying ultraviolet energy to the pressed blank while in the mold to cure and stiffen the stiffening material. (5) Cut the blank from the mat of reinforcement, add binder resin to the blank, place the blank between the two parts of the mold, quickly transport the mold to the press, and put the two mold parts together. a rigid preform consisting of pressing with electromagnetic energy to the blank to stiffen the binder resin, rapid transport of the mold from the press, and removal of the rigid preform from the mold. How to manufacture. (6) comprising a mold including a cavity having a predetermined shape;
The mold has first and second separable mold parts, each mold part defining a portion of the mold cavity, and a separable waveguide having the first and second parts; the first waveguide component is attached to the first mold component, and the second waveguide component is attached to the second mold component;
A molding tool for producing a preform, also comprising a source of microwave energy coupled to said waveguide. (7) In a forming tool for producing a preform having a predetermined three-dimensional shape from a synthetic material comprising a reinforcing material and a stiffening material, first and second separable parts for receiving the synthetic material therebetween; a microwave guide comprising mold parts having cooperating separable mold surfaces which form said predetermined three-dimensional shape when joined, and having first and second parts; a waveguide, the first part carried by the first mold part and the second part carried by the second mold part, the waveguide causing hardening of the stiffening material; A molding tool that can be biased in the same way. (8) a cutting means for cutting the glass reinforcing mat into blanks of a predetermined shape, and a binder application device for adding a binder resin to the blank to form a composite blank of reinforcement and binder resin material; a mold having first and second separable mold parts defining a mold cavity together for receiving and pressing a reinforcement carrying a binder resin; and a first and second separable mold part. a microwave waveguide having a wave tube section, the first section attached to the first mold part and the second section attached to the second mold part, and a microwave input section; and charging means for placing a composite blank of reinforcement and binder resin into said mold cavity, and for pressing said mold parts together such that the blank replicates the shape of the preform. a press; a shuttle for transporting the mold into and out of the press; and a shuttle for connecting to the microwave input for energizing the microwave waveguide and causing curing and stiffening of the binder resin. Apparatus for producing a rigid preform, comprising: a microwave generator; and ejection means for ejecting the rigid preform from the mold. (9) applying a point location of electromagnetic energy sensing binder resin to the reinforcement element, moving the reinforcement element into intimate contact with the carrier preform at the point location, and applying electromagnetic energy to the point location of the reinforcement element; A method of attaching reinforcement elements to a preform carrier comprising the additional steps of stiffening the binder resin and bonding the reinforcement element to the preform carrier. (10) applying a point location of microwave sensitive binder resin to the reinforcement element, moving the reinforcement element into intimate contact with the carrier preform at the point location, and applying microwave energy to the reinforcement element point location; A method of attaching a reinforcement element to a preform carrier comprising the steps of: stiffening the binder resin in addition to positioning and bonding the reinforcement element to the preform carrier. (11) applying a spot location of UV-sensitive binder resin to the reinforcement element, moving the reinforcement element into intimate contact with the carrier preform at the spot location, and applying UV energy to the spot location of the reinforcement element; A method of attaching reinforcement elements to a preform carrier comprising the additional steps of stiffening the binder resin and bonding the reinforcement element to the preform carrier.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US446,859 | 1989-12-06 | ||
| US07/446,859 US6001300A (en) | 1989-12-06 | 1989-12-06 | Method for making rigid three-dimensional preforms using directed electromagnetic energy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03213310A true JPH03213310A (en) | 1991-09-18 |
| JP3185983B2 JP3185983B2 (en) | 2001-07-11 |
Family
ID=23774094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33084190A Expired - Fee Related JP3185983B2 (en) | 1989-12-06 | 1990-11-30 | Method and apparatus for producing a preform |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US6001300A (en) |
| EP (1) | EP0431442B1 (en) |
| JP (1) | JP3185983B2 (en) |
| KR (1) | KR100193588B1 (en) |
| AT (1) | ATE134559T1 (en) |
| CA (1) | CA2030419C (en) |
| DE (2) | DE431442T1 (en) |
| ES (1) | ES2025047T3 (en) |
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| DE69304042T2 (en) * | 1990-07-12 | 1996-12-19 | C A Lawton Co | Method and device for the production of structurally reinforced preforms, with energetic temporary gluing or stitching |
| US5192387A (en) * | 1990-11-05 | 1993-03-09 | The C.A. Lawton Company | Method of making preforms |
| US5217654A (en) * | 1992-01-30 | 1993-06-08 | The C. A. Lawton Company | Two-stage mat forming preforming and molding process |
| ZA93819B (en) * | 1992-02-24 | 1993-10-15 | Cook Composites & Polymers | Process of making a rigid multi-layer preform |
| US5576358A (en) * | 1995-02-03 | 1996-11-19 | Alliedsignal Inc. | Composition for use in friction materials and articles formed therefrom |
| CN1108955C (en) * | 1997-04-17 | 2003-05-21 | 十集团的集团十责任有限公司 | Method for making stable disposable container from flexible film and article produced thereby |
| US6280550B1 (en) * | 1998-12-15 | 2001-08-28 | General Electric Company | Fabrication of composite articles having an infiltrated matrix |
| US6692603B1 (en) * | 1999-10-14 | 2004-02-17 | Kimberly-Clark Worldwide, Inc. | Method of making molded cellulosic webs for use in absorbent articles |
| US6617490B1 (en) | 1999-10-14 | 2003-09-09 | Kimberly-Clark Worldwide, Inc. | Absorbent articles with molded cellulosic webs |
| US6478926B1 (en) | 2000-03-31 | 2002-11-12 | Solectria Corporation | Apparatus and method for forming structural preforms |
| DE10035237C1 (en) * | 2000-07-20 | 2001-09-06 | Daimler Chrysler Ag | Press molding method for producing plastic shells from fiber-reinforced duroplastics, comprises feeding sections of fiber mat into molding press, spraying on resin, closing mold, allowing resin to cure and trimming flash from molding |
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-
1990
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- 1990-11-27 DE DE199090122607T patent/DE431442T1/en active Pending
- 1990-11-27 DE DE69025559T patent/DE69025559T2/en not_active Expired - Fee Related
- 1990-11-27 EP EP90122607A patent/EP0431442B1/en not_active Expired - Lifetime
- 1990-11-27 ES ES90122607T patent/ES2025047T3/en not_active Expired - Lifetime
- 1990-11-27 AT AT90122607T patent/ATE134559T1/en not_active IP Right Cessation
- 1990-11-30 JP JP33084190A patent/JP3185983B2/en not_active Expired - Fee Related
- 1990-12-04 KR KR1019900019807A patent/KR100193588B1/en not_active Expired - Fee Related
-
1995
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1997
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Also Published As
| Publication number | Publication date |
|---|---|
| US6001300A (en) | 1999-12-14 |
| EP0431442A3 (en) | 1991-09-11 |
| DE431442T1 (en) | 1992-01-16 |
| ES2025047A4 (en) | 1992-03-16 |
| KR100193588B1 (en) | 1999-06-15 |
| CA2030419C (en) | 1998-03-31 |
| DE69025559T2 (en) | 1996-09-12 |
| JP3185983B2 (en) | 2001-07-11 |
| CA2030419A1 (en) | 1991-06-07 |
| EP0431442A2 (en) | 1991-06-12 |
| US6004123A (en) | 1999-12-21 |
| DE69025559D1 (en) | 1996-04-04 |
| ES2025047T3 (en) | 1996-06-01 |
| ATE134559T1 (en) | 1996-03-15 |
| EP0431442B1 (en) | 1996-02-28 |
| US5866060A (en) | 1999-02-02 |
| KR910011432A (en) | 1991-08-07 |
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