JPH03219863A - Laying material for ashtray - Google Patents

Laying material for ashtray

Info

Publication number
JPH03219863A
JPH03219863A JP2014064A JP1406490A JPH03219863A JP H03219863 A JPH03219863 A JP H03219863A JP 2014064 A JP2014064 A JP 2014064A JP 1406490 A JP1406490 A JP 1406490A JP H03219863 A JPH03219863 A JP H03219863A
Authority
JP
Japan
Prior art keywords
particles
ashtray
sodium bicarbonate
laying material
soda
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2014064A
Other languages
Japanese (ja)
Other versions
JP2761957B2 (en
Inventor
Kazuo Hase
長谷 和雄
Katsuya Ueda
勝也 上田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Tokuyama Corp
Original Assignee
Takasago International Corp
Tokuyama Corp
Takasago Perfumery Industry Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago International Corp, Tokuyama Corp, Takasago Perfumery Industry Co filed Critical Takasago International Corp
Priority to JP2014064A priority Critical patent/JP2761957B2/en
Publication of JPH03219863A publication Critical patent/JPH03219863A/en
Application granted granted Critical
Publication of JP2761957B2 publication Critical patent/JP2761957B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Fire-Extinguishing Compositions (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

PURPOSE:To extinguish fire of tobacco by spreading a laying material on an ashtray, not to cause a fumigating smell after fire extinguishing and to facilitate handling by using particles of sodium bicarbonate as a main component. CONSTITUTION:An aroma and a deodorant are adsorbed on particles of sodium bicarbonate (average particle diameter: 1.0-6.0mm) to give a laying material for ashtray. The blending ratio of the components is >=50wt.% based on the whole amounts of particles of sodium bicarbonate, 0.5-2.0wt.% aroma and 1.0-5.0wt.% deodorant. The particles of sodium bicarbonate having 1.0-6.0mm particle diameters are preferably obtained by granulating powder of sodium bicarbonate with petalous calcium silicate having gyrolite type crystal structure and a molar ratio of SiO2/CaO of 1.6-4.2.

Description

【発明の詳細な説明】[Detailed description of the invention] 【産業上の利用分野】[Industrial application field]

本発明は、灰皿に敷き詰めてタバコの火を消火し、かつ
消火後もくすぶり臭が生しることのない灰皿用敷設材に
関する。
The present invention relates to an ashtray laying material that can be spread over an ashtray to extinguish a cigarette and does not produce a smoldering odor even after the cigarette is extinguished.

【従来の技術】[Conventional technology]

従来、例えば特開昭64−27462号の灰皿用敷設材
として、多孔質の無機粉体に香料等の清浄感付与剤を吸
着させたものを灰皿内の底部に層状に敷設して使用する
構成が知られている。 この従来の灰皿用敷設材ては無機粉体を用いるためタバ
コの火との接触面積が大きくなり消火が確実に行えるこ
と、また、無機粉体は廉価であるため使い捨てしても経
費がそれほとかからないことが記載されている。 しかし、この灰皿用敷設材では、消火に際して、タバコ
の火を粉体で隙間なく覆って酸素を遮断し消火している
ために、確実に消火するにはタバコの燃焼部分を完全に
灰皿用敷設材内に埋没させる必要がある。 また灰皿用敷設材が粉体であるために、灰皿内に移すと
きに飛散したり、エアコン等の風で吹き飛ばされやすく
、そのための掃除も面倒である等、取扱い上煩雑である
という欠点がある。 その傾向は、時間の経過につれて香料が揮散して粉体自
体の重量が軽くなると一層大きくなる。
Conventionally, for example, as a laying material for an ashtray in Japanese Patent Application Laid-Open No. 64-27462, a structure in which porous inorganic powder adsorbs a cleansing agent such as a fragrance is laid in a layer at the bottom of an ashtray. It has been known. This conventional ashtray bedding material uses inorganic powder, which increases the area of contact with the cigarette and ensures fire extinguishment.Also, since inorganic powder is inexpensive, it costs less even if it is disposable. It is stated that it does not apply. However, with this ashtray laying material, when extinguishing a fire, the cigarette flame is completely covered with powder to block oxygen and extinguish the fire. It needs to be buried in the material. Furthermore, since the ashtray laying material is powder, it tends to scatter when transferred into the ashtray or be blown away by the wind from an air conditioner, etc., and cleaning is also troublesome, making it cumbersome to handle. . This tendency becomes even greater as the fragrance evaporates over time and the weight of the powder itself becomes lighter.

【発明が解決しようとする課題】[Problem to be solved by the invention]

本発明はかかる欠点を解決するために創案されたもので
あって、その主たる課題は、主成分に重炭酸ソーダを用
いることによりタバコの火の熱分解で炭酸ガスを発生さ
せて消火作用を促進させると共に、上記重炭酸ソーダを
比較的大きい粒子として取扱を容易とした灰皿用敷設材
を提供することにある。
The present invention was devised to solve these drawbacks, and its main object is to use bicarbonate of soda as the main component to generate carbon dioxide gas through thermal decomposition of cigarettes, thereby promoting extinguishing action. The object of the present invention is to provide an ashtray laying material in which the above-mentioned bicarbonate of soda is made into relatively large particles and is easy to handle.

【課題を解決するための手段】[Means to solve the problem]

上記課題を達成するために、本発明では、平均粒径が1
.0〜6.0mmの重炭酸ソーダの粒子(以下、重曹粒
子と略称する)に芳香剤または消臭剤を吸着させてなる
、という技術的手段を講している。 即ち、重炭酸ソーダ(炭酸水素ナトリウム)はタバコの
火の熱で分解し炭酸ガスを発生させ、消火を促進させる
働きをする。この重曹粒子の平均粒径は1.0〜6.0
mmの範囲であることが必要である。粒径が1.0mm
以下であると粉体に似た飛散なとの取扱い上の弊害が出
てくる。また粒径が6.0mm以上になるとタバコの火
との接触面積が少なくなり消火効果が劣るという結果を
招く。 本発明の重曹粒子の粒子形状は特に限定されず、任意の
形状であってよい。しかし、粒子形状が球状の場合には
、重曹粒子の流動性が良好となるため、タバコの火が灰
皿用敷設材の中へ埋没しやすくなる。その結果、酸素の
供給遮断により、タバコの消火効果がより一層優れたも
のとなる。また、柱状の粒子は製造経費が廉価で、一定
形状に揃え易い等の利点があり好ましい。 尚、粒子形状における球状とは、重曹粒子の長径と短径
の比が1.5以下であるものが好ましい。 粒子形状が球状でない場合の粒径は、球体相当径(ワン
デル径、粒径=3    (粒子の体積)π て表わす。 平均粒径が1.0〜6.0mmの重曹粒子を得る方法は
特に限定されないが、重炭酸ソーダの粉末を適当なバイ
ンダーを使用して造粒することにより得られる。 ここでバインダーとしては、殿粉、セルロース、アラビ
アガム、ポリビニルアルコール、ポリエチレングリコー
ル、ポリアクリル酸ソーダ、カルボキシメチルセルロー
ズソーダ(CMC)等の有機系バインダー;珪酸ソーダ
、シリカゾル、珪酸カルシウム、石膏、セメント等の無
機系バインダーの単独あるいは朝合せが好適に用いられ
る。 この中でも不燃性の無機バインダーを用いるのが好まし
く、特に、一般式2Ca・3SiO2・n S i 0
2 ・mH2O(式中m、  nは正の数)で示される
、シャロライト型結晶構造を有し、且つ5102/Ca
Oのモル比が1.6〜4.2である珪酸カルシウムを用
いることが好ましい。 上記珪酸カルシウムは3000−10000倍の電子顕
微鏡写真によれは、長手方向の平均直径0.1〜30μ
m、厚み0. 005〜O,1μmの円状あるいごよ楕
円状である対称形の2辺を有する薄片が集合して花弁、
特にバラの花弁に類似していることが確認され、一般に
嵩比容積が7〜15 cc/ gと非常に大きいと同時
に、細孔容積4〜10cc/gの空孔を多数に有する無
機粉体である。 以下、かかる珪酸カルシウムを花弁状珪酸カルシウムと
もいう。 花弁状珪酸カルシウムは、製法が特開昭5493698
号に示されており、また商品名「フローライト」(徳山
曹達株式会社)で市販されている。 重炭酸ソーダを粒状にするための造粒方法としては、重
炭酸ソーダの粉体とバインダーを混合、プレスし、次い
て所望の粒径に粉砕する方法、重炭酸ソーダの粉体とバ
インダーを湿式混合して押出し造粒、押出し成型した後
に柱状に切断する方法、あるいは転動造粒する方法、更
には、重炭酸ソーダの粉体を流動させ、それにバインダ
ー溶液を吹き付けながら転動造粒していく方法等、公知
の方法が採用される。 バインダーの量は、造粒を行いやすくするため及び重炭
酸ソーダの量の相対的低下を避けて消火性を大きくする
ために、一般には2〜30重量%の範囲から採用される
。 造粒方法としてプレスや転勤造粒を採用する場合には、
重曹粒子の機械的強度を向上させ、しかも後述する芳香
剤や消臭剤の吸着性を向上させるために、バインダーと
して前記の花弁状珪酸カルシウムが好適に用いられる。 押出し造粒又は押出し成型後の切断による造粒を採用す
る場合には、押出し性を特徴とする特許に前記花弁状珪
酸カルシウムを3〜50重量%と他のバインダを97〜
50重量%とを併用することが好ましい。 本発明において、重曹の粒子に芳香剤又は消臭剤を含浸
させる方法は特に限定されず、重曹粒子を攪拌中にスプ
レーする方法、芳香剤又は消臭剤を含む液中に重曹粒子
を浸漬させる方法等が採用される。 芳香剤又は消臭剤としては、例えばアップル、ストロへ
リー メロン等のフルーツ系、レモン、ライム、オレン
ジ、等の柑橘系、ローズ、ジャスミン、ミューゲ等のフ
ローラル系、ハーブ系、香水タイプ、ミントタイプ等の
一般に芳香剤に使用されている香料であれば全て使用で
きる。 消臭剤としてはタバコのマスキング効果があるベル力モ
ット、バシル、ユーカリブタス、ラベンダー、レモン、
ライム、ペパーミント、ローズマリー等の天然精油の一
種あるいは二種以上の混合物、及び、茶等の椿科植物の
抽出物に代表される植物抽出物などが使用される。 また、重曹粒子に吸着させる芳香剤又は消臭剤の量は、
一般に0. 1〜20重量%の範囲て含浸(吸着、吸収
)させることができるが、芳香剤としては、0.5〜2
.0重量%が、消臭剤としては1.0〜5.0重量%の
使用が好ましい。 尚、本発明においては、消火性に大きな影響を与えない
範囲において、他の添加剤、例えば着色剤、防カビ剤等
を併用してもよい。 また、本発明においては、重曹粒子が灰皿用敷設材の全
体の50重量%以上含まれていれば、良好な消化性が得
られる。 本発明の灰皿用敷設材は、その使用場所を問わず、一般
の家庭用の灰皿や、自動車内の灰皿をはしめ、ホテル、
公会堂等の公共施設の灰皿等に単に投入するだけて使用
できる。
In order to achieve the above object, in the present invention, the average particle size is 1
.. A technical measure is taken in which an aromatic agent or deodorizer is adsorbed onto bicarbonate of soda particles (hereinafter abbreviated as sodium bicarbonate particles) of 0 to 6.0 mm. That is, bicarbonate of soda (sodium hydrogen carbonate) decomposes with the heat of a cigarette and generates carbon dioxide gas, which helps extinguish the fire. The average particle size of these baking soda particles is 1.0 to 6.0
It is necessary to be in the range of mm. Particle size is 1.0mm
If it is less than that, there will be problems in handling such as scattering similar to powder. Furthermore, if the particle size is 6.0 mm or more, the area of contact with the cigarette will decrease, resulting in poor extinguishing effect. The shape of the baking soda particles of the present invention is not particularly limited, and may be any shape. However, when the particle shape is spherical, the fluidity of the sodium bicarbonate particles is good, making it easier for the cigarette to be buried in the ashtray laying material. As a result, by cutting off the supply of oxygen, the cigarette extinguishing effect becomes even more excellent. Further, columnar particles are preferable because they have advantages such as low manufacturing cost and easy arrangement into a certain shape. In addition, the spherical particle shape is preferably one in which the ratio of the major axis to the minor axis of the sodium bicarbonate particles is 1.5 or less. When the particle shape is not spherical, the particle size is expressed as spherical equivalent diameter (Wandel diameter, particle size = 3 (particle volume) π. The method for obtaining baking soda particles with an average particle size of 1.0 to 6.0 mm is particularly Although not limited to, it can be obtained by granulating sodium bicarbonate powder using a suitable binder. Examples of the binder include starch, cellulose, gum arabic, polyvinyl alcohol, polyethylene glycol, sodium polyacrylate, and carboxymethyl. Organic binders such as cellulose soda (CMC); inorganic binders such as sodium silicate, silica sol, calcium silicate, gypsum, and cement are preferably used alone or in combination. Among these, it is preferable to use nonflammable inorganic binders. , especially the general formula 2Ca.3SiO2.n S i 0
2 ・mH2O (in the formula, m and n are positive numbers), it has a charolite type crystal structure, and 5102/Ca
It is preferable to use calcium silicate having an O molar ratio of 1.6 to 4.2. The above calcium silicate has an average longitudinal diameter of 0.1 to 30μ according to an electron micrograph magnified 3000 to 10000 times.
m, thickness 0. 005~O, 1 μm circular or elliptical flakes with two symmetrical sides gather to form petals,
Inorganic powder that is particularly similar to rose petals and has a large bulk specific volume of 7 to 15 cc/g and a large number of pores with a pore volume of 4 to 10 cc/g. It is. Hereinafter, such calcium silicate is also referred to as petal-shaped calcium silicate. The manufacturing method for petal-shaped calcium silicate is disclosed in JP-A-5493698.
It is also commercially available under the trade name "Fluorite" (Tokuyama Soda Co., Ltd.). Granulation methods for making soda bicarbonate into granules include mixing bicarbonate soda powder and a binder, pressing them, and then pulverizing them to the desired particle size, and extrusion granulation by wet mixing bicarbonate soda powder and a binder. There are known methods such as extrusion molding and then cutting into columns, or rolling granulation, and furthermore, fluidizing sodium bicarbonate powder and rolling granulation while spraying a binder solution. Adopted. The amount of binder is generally employed in the range of 2 to 30% by weight in order to facilitate granulation and to increase fire extinguishing properties while avoiding a relative decrease in the amount of sodium bicarbonate. When using press or transfer granulation as the granulation method,
The petal-shaped calcium silicate described above is preferably used as a binder in order to improve the mechanical strength of the sodium bicarbonate particles and also to improve the adsorption of fragrances and deodorants described below. When extrusion granulation or granulation by cutting after extrusion molding is adopted, the above-mentioned petal-shaped calcium silicate is added at 3 to 50% by weight and other binders are added at 97 to 97% by weight in a patent characterized by extrudability.
It is preferable to use 50% by weight in combination. In the present invention, the method of impregnating baking soda particles with an aromatic agent or deodorizer is not particularly limited, and includes a method of spraying the baking soda particles while stirring, and a method of immersing the baking soda particles in a liquid containing an aromatic agent or deodorant. method etc. will be adopted. Examples of air fresheners or deodorants include fruit-based products such as apple and strawberry melon, citrus-based products such as lemon, lime, and orange, floral-based products such as rose, jasmine, and muguet, herbal-based products, perfume-based products, and mint-based products. All fragrances commonly used in fragrances, such as fragrances, can be used. Deodorants include bell motte, basil, eucalyptus, lavender, lemon, which have a tobacco masking effect.
Used are one or a mixture of two or more natural essential oils such as lime, peppermint, and rosemary, and plant extracts such as extracts from plants of the Camellia family such as tea. In addition, the amount of fragrance or deodorant to be adsorbed to the baking soda particles is
Generally 0. It can be impregnated (adsorbed, absorbed) in a range of 1 to 20% by weight, but as an aromatic agent, it can be impregnated in a range of 0.5 to 20% by weight.
.. It is preferable to use 1.0 to 5.0% by weight as a deodorant. In the present invention, other additives such as colorants, antifungal agents, etc. may be used in combination within the range that does not significantly affect the fire extinguishing property. Further, in the present invention, if the baking soda particles are contained in an amount of 50% or more by weight of the entire ashtray laying material, good digestibility can be obtained. The ashtray laying material of the present invention can be used in general household ashtrays, ashtrays in cars, hotels, hotels, etc.
It can be used by simply dropping it into an ashtray in public facilities such as public halls.

【実施例】【Example】

以下に、実施例、比較例をもって灰皿用敷設材の好適実
施例を説明するが、本発明はこの実施例によって限定さ
れるものではない。 [実施例1] (重曹粒子の調ilり ■、花弁状珪酸カルシウム(フローライトR徳山曹達株
式会社製)(粒子径約30ミクロン)250重量部に水
800重量部を加え、重炭酸ソーダ2250重量部を加
えて、粒子径が(1)1〜21TIm、(2)2〜3 
mm、(3) 3〜4 mm、(4)4〜4. 8 m
m、(5)4. 8〜5−7mm の球状粒子となるよ
うにマルメライザー(不二バウダル株式会社製)を用い
て成長造粒をした。これを40℃以下で送風乾燥して、
上記粒子径の(1)〜(5)に応じてそれぞれ重曹粒子
(1)〜(5)とした。 ■、花弁状珪酸カルシウム(フローライトR徳山曹達株
式会社製)(粒子径約30ミクロン)3重量部に重炭酸
ソーダ87重量部を加え、それにデンプン5重量部、C
MC5重量部をバインダーとして配合したものに適宜に
加水して混練した後、2mm径で押し出し成型を行い、
得られる柱状物を3〜4mmの長さて切断して円柱状粒
子を得た。これを40°C以下で送風乾燥して重曹粒子
(P)とした。 (香料の含浸法) (a)1重曹粒子(+)〜(5)各々97gをレボリン
グパンに入れ、次に香料(高砂香料工業株式会社製、レ
モン香料またはコーヒー香料)3gを数回に分けて分注
し重曹粒子をレボリングパンにより回転移動させながら
吸収含浸させた。表面の香料による濡れがなくなった時
をもって終点とした。 (b)0重曹粒子(P)97 gをレボリングパンに入
れ、次に香料(高砂香料工業株式会社製、レモン香料ま
たはコーヒー香料)3gを添加した。 重曹粒子(P)をレボリングパンにより回転でまんべん
なく吸収含浸させ、表面の濡れがみられなくなったとき
をもって終点とした。 こうして調整した灰皿用敷設材について下記の方法で評
価を行ない、その結果を表1に示した。 [消火能試験方法コ 内径φ60mm、高さh=210mmの円柱瓶に30m
mの深さまで灰皿用敷設材を入れ、紙巻タバコ(マイル
ドセブン(タイプ))に着火し、吸引し完全に燃焼を始
めるのを確認した後、フィルタまての長さの残部が50
關になフたもの3本を着火部を下にして第1図のごとく
配置し、紙コツプの底に径20mmの穴をあけたもので
蓋をした。 空気流入孔を絞りこむことにより完全に酸素欠乏になら
ないようにして各灰皿用敷設材について各々5組の燃焼
試験を行い残存の長さを比較検討を行なった。 データは上限、下限を除き、データにまとまりのある部
分の10本の平均残存の長さとした。 (芳香試験法) 同一香料につき各灰皿用敷設剤10gを時計皿に取り、
それを各々官能評価ボックス(0,9XO,9X2m)
の床の中央に置いて約20分経過時に香りの強さを専門
パネラ−5名で評価し、平均を出した。 評価は10段階の強度として平均数値を用いた。 1・・・非常に弱い 10◆争・非常に強い (着火試験法) 各灰皿敷設材20gを時計皿に入れ上部に着火したマツ
チを近づけた時の燃え方を観察した。 [比較例] 下記の(イ)〜(ネ)を実施例の[香料の含浸法]の(
a)と同様にして香料を含浸させ、次いで実施例と同様
に各種の方法で評価を行ない、その結果を表1に示した
。 (イ)、フローライトRM−10: 徳山曹達株式会社
製 フローライトR(粉体)を球形に造粒したものでフ
ローライトRの粒子径が1〜2柵のもの。 (ロ)、フローライトRM−40: 同上のもので、粒
子径が4〜5mmのもの。 (ハ)、シリカゲルBタイプビーズ:富士デビソン株式
会社製 粒子径が2〜4mmの球形の乾燥剤に使用され
る半透明粒子。 (ニ)、ゼオライト#2: 日東工業株式会社製 2×
4mm径の天然ゼオライト粒子。 (本)、川砂:建築川砂 5mn+程度の粒子。 表1 尚、着火したのは含浸させた香料が燃焼したものである
Preferred embodiments of the ashtray laying material will be described below with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples. [Example 1] (Preparation of baking soda particles) 800 parts by weight of water was added to 250 parts by weight of petal-shaped calcium silicate (Fluorite R manufactured by Tokuyama Soda Co., Ltd.) (particle diameter of about 30 microns), and 2250 parts by weight of sodium bicarbonate. and the particle size is (1) 1 to 21 TIm, (2) 2 to 3
mm, (3) 3-4 mm, (4) 4-4. 8 m
m, (5)4. Growth granulation was performed using a Marmerizer (manufactured by Fuji Baudal Co., Ltd.) to obtain spherical particles of 8 to 5-7 mm. Dry this with air at a temperature below 40℃,
Baking soda particles (1) to (5) were prepared according to the above particle diameters (1) to (5), respectively. ■, Add 87 parts by weight of sodium bicarbonate to 3 parts by weight of petal-shaped calcium silicate (Fluorite R manufactured by Tokuyama Soda Co., Ltd.) (particle size approximately 30 microns), add 5 parts by weight of starch, C.
After appropriately adding water and kneading a mixture of 5 parts by weight of MC as a binder, extrusion molding was performed to a diameter of 2 mm.
The obtained columnar material was cut into a length of 3 to 4 mm to obtain columnar particles. This was air-dried at 40°C or lower to obtain baking soda particles (P). (Fragrance impregnation method) (a) Put 97 g of each of 1 baking soda particles (+) to (5) into a revoling pan, then add 3 g of fragrance (manufactured by Takasago Fragrance Industries Co., Ltd., lemon flavor or coffee flavor) several times. The solution was divided into portions, and the sodium bicarbonate particles were absorbed and impregnated while being rotated using a rotating pan. The end point was when the surface was no longer wetted by the fragrance. (b) 97 g of sodium bicarbonate particles (P) were placed in a Revoling pan, and then 3 g of flavor (manufactured by Takasago International Corporation, lemon flavor or coffee flavor) was added. The baking soda particles (P) were evenly absorbed and impregnated by rotation using a rotating pan, and the end point was when the surface no longer became wet. The ashtray laying material thus prepared was evaluated by the following method, and the results are shown in Table 1. [Extinguishing ability test method] 30 m in a cylindrical bottle with inner diameter φ60 mm and height h = 210 mm.
Insert the ashtray bedding material to a depth of 50 m, ignite the cigarette (Mild Seven (type)), inhale it, and confirm that it has started to burn completely.
Three lids were placed in the vicinity as shown in Figure 1, with the ignition part facing down, and the lid was covered with a paper cup with a hole 20 mm in diameter drilled in the bottom. Five sets of combustion tests were conducted for each ashtray laying material by narrowing down the air inflow holes to prevent complete oxygen deficiency, and the remaining lengths were compared and examined. The data was the average remaining length of 10 fibers in the part where the data was consistent, excluding the upper and lower limits. (Fragrance test method) Place 10g of each ashtray laying agent for the same fragrance on a watch glass,
Each sensory evaluation box (0,9XO, 9X2m)
After about 20 minutes had elapsed after the product was placed in the center of the floor, five expert panelists evaluated the strength of the scent, and the average was calculated. For the evaluation, the average value was used as a 10-level intensity scale. 1...Very weak 10◆Very strong (Ignition test method) 20g of each ashtray bedding material was placed in a watch glass and a lit pine was brought close to the top to observe how it burned. [Comparative example] The following (A) to (N) were compared with (Fragrance impregnation method) in the example.
A fragrance was impregnated in the same manner as in a), and then evaluation was performed using various methods in the same manner as in the examples. The results are shown in Table 1. (A) Fluorite RM-10: Fluorite R (powder) manufactured by Tokuyama Soda Co., Ltd. is granulated into a spherical shape, and the particle size of Fluorite R is 1 to 2 bars. (b) Fluorite RM-40: Same as above, but with a particle size of 4 to 5 mm. (c) Silica gel B type beads: manufactured by Fuji Davison Co., Ltd. Semi-transparent particles used in spherical desiccants with a particle diameter of 2 to 4 mm. (d) Zeolite #2: Nitto Kogyo Co., Ltd. 2×
Natural zeolite particles with a diameter of 4 mm. (Book), River sand: Architectural river sand, particles of about 5mm+. Table 1 Note that what ignited was the impregnated fragrance that burned.

【発明の効果】【Effect of the invention】

本発明の灰皿用敷設材は粒状であるため、灰皿への投入
時に飛散することはなく、周囲の汚れを防止することが
でき、また取扱いも極めて簡単である。 しかも、本発明の灰皿用敷設材は、重炭酸ソーダを主成
分とするため、タバコの火の部分を完全に覆うことがな
くても、炭酸ガスの作用によって消火力を促進すること
ができる。 更にまた、重炭酸ソーダを粒状化するためのバインダー
として、花弁状珪酸カルシウムを用いた場合には、これ
が有する芳香剤や消臭剤の優れた担持力及び除放性のた
め芳香作用や消臭作用を長期にわたって持続するさせる
ことができ好適である。
Since the ashtray laying material of the present invention is granular, it does not scatter when placed in the ashtray, prevents the surrounding area from becoming dirty, and is extremely easy to handle. Moreover, since the ashtray laying material of the present invention has bicarbonate of soda as its main component, it can promote extinguishing power through the action of carbon dioxide gas even if it does not completely cover the lit part of the cigarette. Furthermore, when petal-shaped calcium silicate is used as a binder for granulating sodium bicarbonate, it has an excellent aromatic and deodorizing effect due to its excellent support and sustained release properties for aromatics and deodorants. This is suitable because it can last for a long period of time.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は実施例で用いた燃焼試験装置の説明図、第2図
はタバコの一例としたマイルドセブンの燃焼残存部を示
す説明図である。
FIG. 1 is an explanatory diagram of the combustion test apparatus used in the examples, and FIG. 2 is an explanatory diagram showing the combustion remaining part of Mild Seven, which is an example of a cigarette.

Claims (1)

【特許請求の範囲】[Claims] (1)、平均粒径が1.0〜6.0mmの重炭酸ソーダ
の粒子に芳香剤または消臭剤を吸着させてなる灰皿用敷
設材。
(1) An ashtray laying material made by adsorbing an aromatic agent or deodorizer to bicarbonate of soda particles having an average particle size of 1.0 to 6.0 mm.
JP2014064A 1990-01-24 1990-01-24 Laying materials for ashtrays Expired - Lifetime JP2761957B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2014064A JP2761957B2 (en) 1990-01-24 1990-01-24 Laying materials for ashtrays

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2014064A JP2761957B2 (en) 1990-01-24 1990-01-24 Laying materials for ashtrays

Publications (2)

Publication Number Publication Date
JPH03219863A true JPH03219863A (en) 1991-09-27
JP2761957B2 JP2761957B2 (en) 1998-06-04

Family

ID=11850661

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014064A Expired - Lifetime JP2761957B2 (en) 1990-01-24 1990-01-24 Laying materials for ashtrays

Country Status (1)

Country Link
JP (1) JP2761957B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006061249A (en) * 2004-08-25 2006-03-09 Nippon Shokubai Co Ltd Ashtray having fire extinguishing action, and gel for fire extinguishment
JP2014156375A (en) * 2013-02-15 2014-08-28 Lion Corp Sodium hydrogen carbonate particle and method for producing the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5295784A (en) * 1976-02-06 1977-08-11 Muneyasu Fukunaga Machine for making and processing reinforced tire

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5295784A (en) * 1976-02-06 1977-08-11 Muneyasu Fukunaga Machine for making and processing reinforced tire

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006061249A (en) * 2004-08-25 2006-03-09 Nippon Shokubai Co Ltd Ashtray having fire extinguishing action, and gel for fire extinguishment
JP2014156375A (en) * 2013-02-15 2014-08-28 Lion Corp Sodium hydrogen carbonate particle and method for producing the same

Also Published As

Publication number Publication date
JP2761957B2 (en) 1998-06-04

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