JPH0336524Y2 - - Google Patents

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Publication number
JPH0336524Y2
JPH0336524Y2 JP1988028617U JP2861788U JPH0336524Y2 JP H0336524 Y2 JPH0336524 Y2 JP H0336524Y2 JP 1988028617 U JP1988028617 U JP 1988028617U JP 2861788 U JP2861788 U JP 2861788U JP H0336524 Y2 JPH0336524 Y2 JP H0336524Y2
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JP
Japan
Prior art keywords
electrode body
acid treatment
power source
dilute acid
oxide film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP1988028617U
Other languages
Japanese (ja)
Other versions
JPH01136178U (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to JP1988028617U priority Critical patent/JPH0336524Y2/ja
Publication of JPH01136178U publication Critical patent/JPH01136178U/ja
Application granted granted Critical
Publication of JPH0336524Y2 publication Critical patent/JPH0336524Y2/ja
Expired legal-status Critical Current

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  • Cleaning By Liquid Or Steam (AREA)
  • Cleaning In General (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

【考案の詳細な説明】 (産業上の利用分野) 本考案は、金属材料を空気中で熱処理した際に
生じる酸化物皮膜を迅速且つ容易に除去する手持
ち洗浄機に関する。
[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to a hand-held cleaning machine that quickly and easily removes an oxide film formed when a metal material is heat treated in the air.

(従来の技術) 金属材料例えばステンレス鋼材料を空気中で溶
接すると溶接線に沿つて帯状に酸化物皮膜を生
じ、このデスケーリングには主として硫酸又は塩
酸を用いている。現在では、金属材料を硫酸又は
塩酸溶液に浸漬する代わりに、塩酸溶液を含むゼ
リー状物を金属材料の酸化物皮膜の上に塗り、約
30分後に水で洗い流している。また、銀粉入りペ
ンキを帯状の酸化物皮膜に沿つて塗布し、該酸化
物皮膜を隠遮する方法がある。酸による方法とし
ては、硫酸の5〜20%溶液中で陰極電解、陽極電
解、PR電解を行う方法もある。
(Prior Art) When metal materials such as stainless steel materials are welded in air, a band-shaped oxide film is formed along the weld line, and sulfuric acid or hydrochloric acid is mainly used for descaling. At present, instead of immersing metal materials in sulfuric acid or hydrochloric acid solutions, a jelly-like substance containing hydrochloric acid solution is applied onto the oxide film of the metal materials.
Rinse with water after 30 minutes. Another method is to apply paint containing silver powder along a band-shaped oxide film to hide and shield the oxide film. Examples of methods using acids include cathodic electrolysis, anodic electrolysis, and PR electrolysis in a 5-20% solution of sulfuric acid.

(考案が解決しようとする課題) 塩酸溶液を含むゼリー状物を用いると、洗い流
した水には臭気があつて他の物質を腐食するため
に、排水の処理に関して公害問題が発生する。こ
のゼリー状物は、加温すれば除去効果が増加する
けれども、酸化物皮膜上に塗つたままで長時間放
置することを要し、作業効率が悪いという問題が
残つている。また、銀粉入りペンキの塗布は、塗
布コストが高いうえに使用中にペンキが剥がれや
すい。電解による方法は、電解設備が必要でコス
ト高になるうえに、凹部の酸化物皮膜が凸部に比
べて溶解が遅れ、しかも電解浴に浸漬できないよ
うな大型の金属材料は処理できず、排水処理の問
題も依然として残存している。
(Problem to be solved by the invention) When a jelly-like substance containing a hydrochloric acid solution is used, a pollution problem arises in the treatment of wastewater because the water used for washing has an odor and corrodes other substances. Although the removal effect of this jelly-like material increases when it is heated, there remains the problem that it is necessary to leave it on the oxide film for a long time, resulting in poor working efficiency. Furthermore, applying paint containing silver powder is expensive, and the paint tends to peel off during use. The electrolytic method requires electrolytic equipment and is expensive, and the oxide film on the recesses dissolves more slowly than on the convex parts. Moreover, it cannot treat large metal materials that cannot be immersed in the electrolytic bath, and waste water is Processing issues also remain.

本考案は、金属材料における酸化物皮膜の除去
に関する前記の問題点を改善するために提案され
たものであり、強固な酸化物皮膜であつても迅速
且つ容易に除去でき、しかも廃液処理の問題が殆
ど発生しない安価な手持ち洗浄機を提供すること
を目的としている。
The present invention was proposed to improve the above-mentioned problems regarding the removal of oxide films from metal materials. Even strong oxide films can be removed quickly and easily, and the present invention solves the problem of waste liquid treatment. The purpose is to provide an inexpensive hand-held washing machine that generates almost no waste.

(課題を解決するための手段) 上記目的を達成するために、本考案に係る手持
ち洗浄機30は、第1図に示すように、希酸処理
液を含浸させるタンポ36と、該タンポを先端に
取り付けた一方の棒状電極体6と、該電極体と近
接させた他方の棒状電極体8とを備える。タンポ
36は、図示のような綿を布地で包んだ吸液性素
材料であり、希酸処理液を十分に吸収・保持し且
つ耐摩耗性を有すると好ましく、一方、両電極体
6,8は焼結炭素などの不溶解性電極材料である
と好ましい。電極体8は、ばね10などで前方へ
付勢したり磁石片で金属材料に吸引されて該金属
材料に接触しやすい機構である。両電極体6,8
は、操作スイツチ12を経て外部電源に配線し、
該外部電源を用いて両電極体間に所定の電位を加
え、局所的に高い電流密度を発生させる。タンポ
36を取り付けた電極体6は、アノード又はカソ
ード電極体であるけれども、PR法によつて電解
を行うことも可能であり、アノード電極において
SO2などの気体を多く発生させないように電圧を
低く抑える。タンポ36には、タンク32から主
成分が硫酸又は塩酸などの希酸処理液を送り、所
望に応じて希酸処理液にインヒビターなどを添加
してもよい。処理可能な金属材料は、ステンレス
鋼などの各種の鉄鋼、アルミニウム、亜鉛とその
合金などである。ステンレス鋼材料では、溶接な
どで生じた表面の酸化物皮膜を吸水性部材で摩擦
して分離した後に、活性化したその分離部分にニ
ツケルメツキを行う場合もある。
(Means for Solving the Problems) In order to achieve the above object, the hand-held washer 30 according to the present invention, as shown in FIG. It includes one rod-shaped electrode body 6 attached to the electrode body and the other rod-shaped electrode body 8 placed close to the electrode body. The pad 36 is made of a liquid-absorbing material made of cotton wrapped in cloth as shown in the figure, and preferably has sufficient absorption and retention of the dilute acid treatment solution and is wear-resistant. is preferably an insoluble electrode material such as sintered carbon. The electrode body 8 is a mechanism that is biased forward by a spring 10 or the like, or is attracted to a metal material by a magnet piece, so that it can easily come into contact with the metal material. Both electrode bodies 6, 8
is wired to an external power source via the operation switch 12,
A predetermined potential is applied between both electrode bodies using the external power source to locally generate a high current density. Although the electrode body 6 to which the pad 36 is attached is an anode or cathode electrode body, it is also possible to perform electrolysis by the PR method, and it is possible to perform electrolysis at the anode electrode.
Keep the voltage low to avoid generating too much gas such as SO 2 . A dilute acid treatment liquid whose main component is sulfuric acid or hydrochloric acid is sent to the pad 36 from the tank 32, and an inhibitor or the like may be added to the dilute acid treatment liquid as desired. Metal materials that can be processed include various types of steel such as stainless steel, aluminum, zinc and its alloys. For stainless steel materials, after the oxide film on the surface produced by welding or the like is separated by friction with a water-absorbing member, the activated separated part is sometimes plated with nickel.

(作用) 本考案の洗浄機30では、局所的に高い電流密
度を発生させるとともに所望量の希酸処理液を強
制的に送り出しながら、タンポ36で金属材料表
面の酸化物皮膜48を強く摩擦するだけでよい。
この希酸処理液は、タンク32を押さない限り出
ないから、両電極体6,8を任意の位置に設定す
ることができる。処理する金属材料に関して、カ
ノード電解では金属材料の腐食は少なく、寸法精
度を維持でき、しかも活性化されるためにメツキ
の密着にもよい反面、水素ガスが発生するので水
素脆性の起こしやすい高炭素鋼やばね鋼には好ま
しくない。一方、アノード電解では、酸化物皮膜
を炭素ガスで物理的に剥離し、金属材料表面の不
働態化が生じて腐食を防止し、水素脆性の発生を
緩和できる反面、化学的に活性なアルミニウム、
亜鉛とその合金には適さない。
(Function) In the cleaning machine 30 of the present invention, the tampon 36 strongly rubs the oxide film 48 on the surface of the metal material while locally generating a high current density and forcibly sending out a desired amount of dilute acid treatment liquid. Just that is enough.
Since this dilute acid treatment liquid does not come out unless the tank 32 is pressed, both electrode bodies 6 and 8 can be set at arbitrary positions. Regarding the metal materials to be treated, cathode electrolysis causes less corrosion of metal materials, maintains dimensional accuracy, and is good for plating adhesion because it is activated. Not suitable for steel or spring steel. On the other hand, in anodic electrolysis, the oxide film is physically removed using carbon gas, and the surface of the metal material becomes passivated, preventing corrosion and mitigating the occurrence of hydrogen embrittlement.
Not suitable for zinc and its alloys.

(実施例) 本考案を図面に基づいて説明すると、第1図に
示す手持ち洗浄機30において、中空の機器本体
34は細長く、その上方部は水平に屈曲してい
る。吸液性部材であるタンポ36は、一方の棒状
電極体6の先端に取り付け、該電極体と近接させ
て他方の棒状電極体8を上方に配置し、両電極体
を機器上方部の先端面に水平に設置する。また、
希酸処理液を入れたタンク32を機器本体34の
背部に設置し、該タンクからバルブ35を介して
直接タンポ36まで希酸処理液を送る。この送液
管38は、不導電性のバルブ35から電極体6の
中心孔を通つてタンポ36まで延びている。タン
ク32は、吸液用キヤツプ(図示しない)を設け
たプラスチツクタンクである。電極体8の先端は
通常尖り、タンポ36の前面よりもやや前方に位
置させ、電極体8は機器本体34内のばね10に
よつて前方へ付勢する。両電極体6,8は、手動
操作のスイツチ12を経て外部電源(図示しな
い)に配線し、該外部電源は例えば交流電源に接
続する定電圧直流電源である。
(Example) To explain the present invention based on the drawings, in a hand-held washing machine 30 shown in FIG. 1, a hollow device main body 34 is elongated and has an upper portion bent horizontally. The pad 36, which is a liquid-absorbing member, is attached to the tip of one rod-shaped electrode body 6, and the other rod-shaped electrode body 8 is placed above the rod-shaped electrode body in close proximity to the electrode body, and both electrode bodies are placed on the tip surface of the upper part of the device. Install it horizontally. Also,
A tank 32 containing a dilute acid treatment liquid is installed at the back of the device main body 34, and the dilute acid treatment liquid is sent directly from the tank to a tampo 36 via a valve 35. The liquid feed pipe 38 extends from the non-conductive valve 35 to the pad 36 through the center hole of the electrode body 6. The tank 32 is a plastic tank equipped with a liquid absorption cap (not shown). The tip of the electrode body 8 is usually pointed and positioned slightly forward of the front surface of the pad 36, and the electrode body 8 is biased forward by a spring 10 within the device body 34. Both electrode bodies 6, 8 are wired to an external power source (not shown) via a manually operated switch 12, and the external power source is, for example, a constant voltage DC power source connected to an AC power source.

この洗浄機30は、機器本体34を手で握つて
使用し、タンク32を握る強さを加減すると、タ
ンポ36へ送る希酸処理液の量を適宜調整でき
る。タンポ36に希酸処理液を送り出しながら、
金属材料の酸化物皮膜48(第2図参照)の上に
タンポ36及び電極体8の先端を当てて通電する
と、タンポ36において電極体6の先端と金属材
料表面との間に局所的に高い電流密度が発生す
る。タンポ36及び電極体8を金属材料表面と接
触させ、洗浄機30を任意の形状の酸化物皮膜4
8に沿つて動かすと、該タンポで酸化物皮膜48
を摩擦して順次分離する。消費した希酸処理液
は、タンポ36から強制的に送り出すだけてある
から少量で済み、本格的な処理設備を必要とする
ほどの廃液は発生しない。電極体6,8はいずれ
も交換可能であり、電極体6を適宜交換して所望
の寸法と材質のタンポを使用すればよい。
This washer 30 is used by gripping the device main body 34 by hand, and by adjusting the strength with which the tank 32 is gripped, the amount of dilute acid treatment liquid sent to the tampo 36 can be adjusted as appropriate. While sending the dilute acid treatment liquid to the pad 36,
When the pad 36 and the tip of the electrode body 8 are placed on top of the oxide film 48 (see FIG. 2) of the metal material and energized, there is a local high temperature between the tip of the electrode body 6 and the surface of the metal material at the pad 36. A current density is generated. The pad 36 and the electrode body 8 are brought into contact with the surface of the metal material, and the cleaning machine 30 is used to clean the oxide film 4 of any shape.
8, the tampon will remove the oxide film 48.
are sequentially separated by rubbing. The consumed dilute acid treatment liquid is only forcibly sent out from the tampo 36, so only a small amount is required, and no waste liquid is generated to the extent that full-scale treatment equipment is required. Both the electrode bodies 6 and 8 are replaceable, and it is sufficient to replace the electrode body 6 as appropriate to use a pad of desired size and material.

第2図における他方の電極体42には、先端に
半球形の磁石片44を固着した筒体46を嵌め、
該筒体は電極体42上で限定的に摺動するけれど
も脱離しない。洗浄機47を酸化物皮膜48に沿
つて動かすと、磁石片44が金属材料に吸引され
て電極体42を金属材料表面と常に接触させるの
で、タンポ36で酸化物皮膜48を摩擦して順次
分離できる。磁石片44が希酸処理液で腐食しや
すい場合には、該磁石片をプラスチツクフイルム
でコーテイングしてもよい。
A cylindrical body 46 having a hemispherical magnet piece 44 fixed to its tip is fitted into the other electrode body 42 in FIG.
Although the cylinder slides on the electrode body 42 to a limited extent, it does not come off. When the cleaning machine 47 is moved along the oxide film 48, the magnet pieces 44 are attracted to the metal material and keep the electrode body 42 in constant contact with the surface of the metal material, so the tampon 36 rubs the oxide film 48 and separates it one by one. can. If the magnet piece 44 is easily corroded by the dilute acid treatment solution, the magnet piece 44 may be coated with a plastic film.

第3図に示す洗浄機50はピストル型であり、
第1図の洗浄機のように定置型の外部電源を使用
する代わりに、機器本体52内に所定電圧の所望
数の乾電池54を収納する。電極体56,58
は、機器水平部60の先端面に平行設置し、電極
体56の先端に取り付けたタンポ62からタンク
64まで送液管68を延設し、該送液管は操作ス
イツチ66で開閉するバルブ(図示しない)及び
電極体56の周面を通過する。タンク64は交換
自在な加圧式カートリツジであり、スイツチ66
を押すと前記のバルブが開いてタンポ62へ希酸
処理液が流出する。スイツチ66は2段階操作で
あり、該スイツチを軽く押すと直流電流が流れ、
次に強く押すと希酸処理液をタンク64からタン
ポ62へ送る。第4図では、送液管70の先端を
ノズル72に形成し、該送液管は電極体74から
離れている。この洗浄機は、ノズル72によつて
希酸処理液を酸化物皮膜上へ噴霧し、電極体74
の先端のタンポ76で酸化物皮膜を摩擦する。
The washing machine 50 shown in FIG. 3 is a pistol type,
Instead of using a stationary external power source like the washing machine shown in FIG. 1, a desired number of dry batteries 54 with a predetermined voltage are housed in the main body 52 of the device. Electrode bodies 56, 58
is installed parallel to the distal end surface of the horizontal part 60 of the device, and extends from a pad 62 attached to the distal end of the electrode body 56 to a tank 64, with a liquid supply pipe 68 having a valve ( (not shown) and the circumferential surface of the electrode body 56. The tank 64 is a replaceable pressurized cartridge, and the switch 66
When is pressed, the aforementioned valve opens and the dilute acid treatment liquid flows into the tampo 62. The switch 66 has a two-step operation; when the switch is pressed lightly, a direct current flows;
Next, when pressed strongly, the dilute acid treatment liquid is sent from the tank 64 to the pad 62. In FIG. 4, the tip of the liquid feeding tube 70 is formed into a nozzle 72, and the liquid feeding tube is separated from the electrode body 74. This cleaning machine sprays a dilute acid treatment liquid onto the oxide film using a nozzle 72, and
The oxide film is rubbed with the tampo 76 at the tip.

図示しないけれども、乾電池54を収納する代
わりに、機器本体52に充電器を収納したり、又
は使用者の腰ベルトに小型電源を取り付けるよう
にしてもよい。これらの変形例の洗浄機では可搬
性がいつそう良くなり、移動できない大型タンク
77(第5図)における溶接のように、不便な個
所の溶接で生じた酸化物皮膜78でも容易に除去
可能になる。
Although not shown, instead of storing the dry battery 54, a charger may be stored in the device main body 52, or a small power source may be attached to the user's waist belt. These modified cleaning machines have improved portability, and can easily remove oxide films 78 that are formed during welding in inconvenient locations, such as welding on large tanks 77 (Figure 5) that cannot be moved. Become.

(考案の効果) 本考案の洗浄機では、局所的に高い電流密度を
発生させるとともに所望量の希酸処理液を強制的
に送り出しながら、吸液性素材のタンポで金属材
料表面の酸化物皮膜を強く摩擦することにより、
金属材料表面から酸化物皮膜を迅速且つ容易に除
去し、手持ちであるから作業効率が優れ且つ作業
環境の悪化も殆ど起こらない。また、希酸処理液
は、タンクを押さない限り出ないから、上向きの
除去作業でも可能であつて作業性に優れている。
本考案の洗浄機は、通常の電解方法に比べて電解
設備が単純で設備コストが安く、タンポによる摩
擦を行うために、凹部の酸化物皮膜が凸部に比べ
て溶解が遅れるようなことが殆ど発生しない。ま
た、本考案の洗浄機は、一般に希酸処理液を少量
使用するだけであるから、電解浴を設置する電解
方法よりも廃液の生成が少なく、この希酸処理液
は臭気が少なくて他の物質を腐食せず、排水の処
理に関して公害問題が発生する恐れも少ない。
(Effects of the invention) The cleaning machine of this invention generates a locally high current density and forcibly sends out the desired amount of dilute acid treatment solution, while using a pad made of liquid absorbing material to remove the oxide film on the surface of the metal material. By strongly rubbing the
It quickly and easily removes oxide films from the surface of metal materials, and because it is handheld, it has excellent working efficiency and hardly causes any deterioration of the working environment. In addition, since the dilute acid treatment liquid does not come out unless the tank is pushed, removal work can be carried out in an upward direction, resulting in excellent workability.
The cleaning machine of this invention has simpler electrolytic equipment and lower equipment cost than normal electrolytic methods, and because the tampo friction is used, the oxide film on the recesses does not dissolve more slowly than on the convex parts. Almost never occurs. In addition, since the washing machine of the present invention generally uses only a small amount of dilute acid treatment liquid, it produces less waste liquid than the electrolytic method that installs an electrolytic bath, and this dilute acid treatment liquid has less odor and is comparable to other methods. It does not corrode substances, and there is little risk of pollution problems occurring when treating wastewater.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本考案に係る手持ち洗浄機を示す側面
図、第2図から第4図はそれぞれ本考案の変形例
を示す全体側面図と部分側面図、第5図は溶接で
生じた酸化物皮膜を有する大型タンクの斜視図で
ある。 30…手持ち洗浄機、36…タンポ、6,8…
電極体、10…ばね、12…操作スイツチ、48
…酸化物皮膜。
Fig. 1 is a side view showing a hand-held washing machine according to the present invention, Figs. 2 to 4 are an overall side view and a partial side view showing modifications of the present invention, respectively, and Fig. 5 is an oxide produced by welding. FIG. 2 is a perspective view of a large tank with a membrane. 30...Handheld washing machine, 36...Tampo, 6,8...
Electrode body, 10... Spring, 12... Operation switch, 48
...Oxide film.

Claims (1)

【実用新案登録請求の範囲】 1 金属材料を空気中で熱処理した際に生じる酸
化物皮膜を除去する洗浄機であつて、希酸処理
液を含浸させるタンポと、該タンポを先端に取
り付けた一方の棒状電極体と、該電極体と近接
させる他方の電極体と、希酸処理液を入れ且つ
機器本体に設置する変形可能なプラスチツクタ
ンクとを備え、外部電源を用いて両電極体間に
所定の電位を加えて局所的に高い電流密度を発
生させ、洗浄機を動かしてタンポで酸化物皮膜
を擦り取る際に、プラスチツクタンクを変形さ
せてタンポへ送る希酸処理液の量を強制的に加
減できる酸化物皮膜の手持ち洗浄機。 2 定置型の外部電源の代わりに、機器本体に所
定電圧の乾電池又は充電器を収納する請求項1
記載の洗浄機。 3 定置型の外部電源の代わりに、使用者の腰ベ
ルトに小型電源を取り付ける請求項1記載の洗
浄機。
[Claims for Utility Model Registration] 1. A cleaning machine for removing oxide films produced when metal materials are heat-treated in air, including a tampon impregnated with a dilute acid treatment solution and a machine with the tampo attached to the tip. It is equipped with a rod-shaped electrode body, another electrode body placed close to the electrode body, and a deformable plastic tank containing a dilute acid treatment solution and installed in the main body of the device. By applying an electric potential of A handheld oxide film cleaning machine that can be adjusted. 2.Claim 1: Instead of a stationary external power source, a dry battery or charger of a predetermined voltage is housed in the main body of the device.
The washing machine mentioned. 3. The washing machine according to claim 1, wherein a small power source is attached to the user's waist belt instead of the stationary external power source.
JP1988028617U 1988-03-02 1988-03-02 Expired JPH0336524Y2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1988028617U JPH0336524Y2 (en) 1988-03-02 1988-03-02

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1988028617U JPH0336524Y2 (en) 1988-03-02 1988-03-02

Publications (2)

Publication Number Publication Date
JPH01136178U JPH01136178U (en) 1989-09-18
JPH0336524Y2 true JPH0336524Y2 (en) 1991-08-02

Family

ID=31252135

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1988028617U Expired JPH0336524Y2 (en) 1988-03-02 1988-03-02

Country Status (1)

Country Link
JP (1) JPH0336524Y2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6898262B2 (en) * 2018-01-22 2021-07-07 ホシザキ株式会社 Electrode structure used in electrolytic baking equipment

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5612299U (en) * 1979-07-09 1981-02-02
JPS6038679U (en) * 1983-08-25 1985-03-18 八洲電機株式会社 Foot pressure device for resistance welding machine

Also Published As

Publication number Publication date
JPH01136178U (en) 1989-09-18

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