JPH0337598B2 - - Google Patents
Info
- Publication number
- JPH0337598B2 JPH0337598B2 JP61066982A JP6698286A JPH0337598B2 JP H0337598 B2 JPH0337598 B2 JP H0337598B2 JP 61066982 A JP61066982 A JP 61066982A JP 6698286 A JP6698286 A JP 6698286A JP H0337598 B2 JPH0337598 B2 JP H0337598B2
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- oil
- blended
- parts
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003205 fragrance Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 9
- JLKIAKRBHSJJCQ-UHFFFAOYSA-N 2,2,7,7-tetramethylcycloheptan-1-one Chemical compound CC1(C)CCCCC(C)(C)C1=O JLKIAKRBHSJJCQ-UHFFFAOYSA-N 0.000 claims description 8
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 4
- 241000207199 Citrus Species 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 3
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
- -1 -allyl-2 Chemical class 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 239000005792 Geraniol Substances 0.000 description 2
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 2
- 244000179970 Monarda didyma Species 0.000 description 2
- 235000010672 Monarda didyma Nutrition 0.000 description 2
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 2
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 2
- 235000000484 citronellol Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229960000956 coumarin Drugs 0.000 description 2
- 235000001671 coumarin Nutrition 0.000 description 2
- 229940113087 geraniol Drugs 0.000 description 2
- 239000010648 geranium oil Substances 0.000 description 2
- 235000019717 geranium oil Nutrition 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- 229940067107 phenylethyl alcohol Drugs 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 1
- VPKMGDRERYMTJX-CMDGGOBGSA-N 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1-penten-3-one Chemical compound CCC(=O)\C=C\C1C(C)=CCCC1(C)C VPKMGDRERYMTJX-CMDGGOBGSA-N 0.000 description 1
- YBUIAJZFOGJGLJ-SWRJLBSHSA-N 1-cedr-8-en-9-ylethanone Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(C)=C(C(C)=O)C2 YBUIAJZFOGJGLJ-SWRJLBSHSA-N 0.000 description 1
- DLHQZZUEERVIGQ-UHFFFAOYSA-N 3,7-dimethyl-3-octanol Chemical compound CCC(C)(O)CCCC(C)C DLHQZZUEERVIGQ-UHFFFAOYSA-N 0.000 description 1
- ORMHZBNNECIKOH-UHFFFAOYSA-N 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde Chemical compound CC(C)(O)CCCC1=CCC(C=O)CC1 ORMHZBNNECIKOH-UHFFFAOYSA-N 0.000 description 1
- XRHCAGNSDHCHFJ-UHFFFAOYSA-N Ethylene brassylate Chemical compound O=C1CCCCCCCCCCCC(=O)OCCO1 XRHCAGNSDHCHFJ-UHFFFAOYSA-N 0.000 description 1
- DUKPKQFHJQGTGU-UHFFFAOYSA-N Hexyl salicylic acid Chemical compound CCCCCCOC(=O)C1=CC=CC=C1O DUKPKQFHJQGTGU-UHFFFAOYSA-N 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- QUMXDOLUJCHOAY-UHFFFAOYSA-N alpha-methylbenzyl acetate Natural products CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 1
- 229940062909 amyl salicylate Drugs 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 239000001111 citrus aurantium l. leaf oil Substances 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 229940019836 cyclamen aldehyde Drugs 0.000 description 1
- CGZZMOTZOONQIA-UHFFFAOYSA-N cycloheptanone Chemical compound O=C1CCCCCC1 CGZZMOTZOONQIA-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- ONKNPOPIGWHAQC-UHFFFAOYSA-N galaxolide Chemical compound C1OCC(C)C2=C1C=C1C(C)(C)C(C)C(C)(C)C1=C2 ONKNPOPIGWHAQC-UHFFFAOYSA-N 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000001469 lavandula hydrida abrial herb oil Substances 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000001683 mentha spicata herb oil Substances 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は賦香剤として有用な次式（）
で表わされる２，２，７，７−テトラメチルシク
ロヘプタノンを含有する香料組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention provides the following formula () useful as a flavoring agent: The present invention relates to a fragrance composition containing 2,2,7,7-tetramethylcycloheptanone represented by:
２，２，７，７−テトラメチルシクロヘプタノ
ン（）はすでに公知の化合物であり、例えば１
−アリル−２，２，７，７−テトラメチルシクロ
ヘプタン−１−オール等の芳香性化合物の製造原
料として有用であることが知られている。
2,2,7,7-tetramethylcycloheptanone () is already a known compound, for example 1
It is known to be useful as a raw material for producing aromatic compounds such as -allyl-2,2,7,7-tetramethylcycloheptan-1-ol.
しかしながら、この化合物自体は樟脳様のあま
り好ましくない香りを有するため、これ自体を香
料として使用しようとする試みは全くなされてい
なかつた。 However, since this compound itself has an undesirable camphor-like odor, no attempt has been made to use it as a fragrance.
〔問題点を解決するための手段〕
斯かる実状において、本発明者らは、２，２，
７，７−テトラメチルシクロペンタノン（）の
香気について詳細な検討を行つた結果、これをシ
トラス系、ハーバル系の調合香料に少量配合する
とシトラス及びハーバルの香りがリストアツプさ
れると共にフレツシユ感が付与されること、また
薬用タイプの調合香料に配合すると、メデイカル
感が向上したフレツシユな香料組成物が得られる
ことを見出し、本発明を完成した。[Means for solving the problem] In such an actual situation, the present inventors have solved the following problems:
As a result of a detailed study on the aroma of 7,7-tetramethylcyclopentanone (), we found that when a small amount of this is added to a citrus or herbal blended fragrance, the citrus and herbal aroma is restored and a fresh feeling is created. The present invention has been completed based on the discovery that a fresh fragrance composition with an improved medical feel can be obtained when it is added to a medicinal type blended fragrance.
従つて、本発明は、２，２，７，７−テトラメ
チルシクロヘプタノンを含有する香料組成物を提
供するものである。 Therefore, the present invention provides a fragrance composition containing 2,2,7,7-tetramethylcycloheptanone.
本発明の香料組成物は、種々の調合香料を調製
する際の一成分として２，２，７，７−テトラメ
チルシクロヘプタノンを配合することによつて調
製される。その配合量は調合香料の種類及び目的
とする香気によつても異なるが、薬用タイプの調
合香料の如く、２，２，７，７−テトラメチルシ
クロヘプタノンによつて生起される香気を付与せ
んとする場合には、全組成の５〜20重量％が好ま
しく、またシトラス又はハーバル系調合香料の香
りをリストアツプする場合には、全組成の0.1〜
３重量％が好ましい。 The fragrance composition of the present invention is prepared by incorporating 2,2,7,7-tetramethylcycloheptanone as a component when preparing various mixed fragrances. The amount added varies depending on the type of blended fragrance and the desired aroma, but it imparts the scent generated by 2,2,7,7-tetramethylcycloheptanone, such as in medicinal type blended fragrances. When the scent is to be added, it is preferably 5 to 20% by weight of the total composition, and when the scent of a citrus or herbal fragrance is restored, it is preferably 0.1 to 20% by weight of the total composition.
3% by weight is preferred.
〔発明の効果〕
本発明の香料組成物は、調合香料の香りがリス
トアツプされると共にフレツシユ感が付与されて
いるので、高級な香料組成物、香水、石鹸、シヤ
ンプー、ヘアリンス、洗剤、化粧品、ヘアスプレ
ー、芳香剤等の賦香が必要とされるものに広汎に
使用できる。[Effects of the Invention] The fragrance composition of the present invention restores the scent of the blended fragrance and gives a fresh feeling, so it can be used as a high-grade fragrance composition, perfume, soap, shampoo, hair rinse, detergent, cosmetics, etc. It can be widely used in hair sprays, fragrances, and other products that require fragrance.
次に実施例を挙げて本発明を説明する。 Next, the present invention will be explained with reference to Examples.
実施例 １
薬用タイプ調合香料
レモンベース 100重量部
ベルガモツトベース 50
テトラハイドロリナロール 30
ローズマリー油 20
ラベンダー油モンブラン（40／42） 20
シトロネロール 50
ゲラニオール 100
フエニルエチルアセテート 30
フエニルエチルアルコール 150
ヒドロキシシトロネラール 60
４−（４−ヒドロキシ−４−メチルペンチル）−
３−シクロヘキセン−１−カルバルデヒド
40
ヘキシルシンナミツクアルデヒド 200
ベチバー油ジヤワ 10 エチレンブラシレート 40
900
上記調合香料900部に２，２，７，７−テトラ
メチル−１−シクロヘプタノンを100部加えるこ
とによりフレツシユでグリーンなよりメデイカル
感のアツプした調合香料が得られた。Example 1 Medicinal type mixed fragrance lemon base 100 parts by weight Bergamot base 50 Tetrahydrolinalool 30 Rosemary oil 20 Lavender oil Mont Blanc (40/42) 20 Citronellol 50 Geraniol 100 Phenylethyl acetate 30 Phenylethyl alcohol 150 Hydroxycitronone Ral 60 4-(4-hydroxy-4-methylpentyl)-
3-cyclohexene-1-carbaldehyde
40 Hexyl cinnamic aldehyde 200 Vetiver oil 10 Ethylene brasylate 40 900 By adding 100 parts of 2,2,7,7-tetramethyl-1-cycloheptanone to 900 parts of the above blended fragrance, a fresher, greener and more medical feel is created. A blended fragrance with enhanced flavor was obtained.
実施例 ２
シヤンプー用調合香料
レモンベース 50重量部
ベルガモツトベース 50
オレンジ油ギニア 100
シス−３−ヘキセノール ２
リナロール 40
ベンジルアセテート 50
フエニルエチルアルコール 100
シトロネロール 50
ゲラニオール 60
ゼラニウム油アフリカ 10
アミルサリシレート 40
シクラメンアルデヒド 10
ｐ−ｔ−ブチル−α−メチルハイドロシンナミ
ツクアルデヒド 40
ヘキシルシンナミツクアルデヒド 2.08
メチルイオノンガンマ 30
アセチルセドレン 50
ボルニルメトキシシクロヘキサノール 30
ガラクソライド50％DEP（I.F.F社商品名）
50 クマリン 20
990
上記調合香料990部に２，２，７，７−テトラ
メチル−１−シクロヘプタノンを10部加えること
によりシトラス感が強調されたよりフレツシユグ
リーンな調合香料が得られた。Example 2 Mixed fragrance for shampoo Lemon base 50 parts by weight Bergamot base 50 Orange oil Guinea 100 Cis-3-hexenol 2 Linalool 40 Benzyl acetate 50 Phenylethyl alcohol 100 Citronellol 50 Geraniol 60 Geranium oil Africa 10 Amyl salicylate 40 Cyclamen aldehyde 10 pt-Butyl-α-methylhydrocinnamic aldehyde 40 Hexyl cinnamic aldehyde 2.08 Methyl ionone gamma 30 Acetyl cedrene 50 Bornylmethoxycyclohexanol 30 Galaxolide 50% DEP (IFF company product name)
50 Coumarin 20 990 By adding 10 parts of 2,2,7,7-tetramethyl-1-cycloheptanone to 990 parts of the above blended flavor, a fresher green blended flavor with an accentuated citrus feel was obtained.
実施例 ３
ハーバルタイプ調合香料
ラバンジン油 200重量部
タイム油 50
スペアミント油 50
ゼラニウム油 300
クローブ油 100
クマリン 50
ヘキシルサリシレート 100 プチグレン油 50
900
上記調合香料900部に２，２，７，７−テトラ
メチル−１−シクロヘプタノンを100部加えるこ
とによりハーバル感が強調された調合香料が得ら
れた。Example 3 Herbal type mixed fragrance Lavandin oil 200 parts by weight Thyme oil 50 Spearmint oil 50 Geranium oil 300 Clove oil 100 Coumarin 50 Hexyl salicylate 100 Petitgrain oil 50 900 2,2,7,7-tetramethyl- By adding 100 parts of 1-cycloheptanone, a blended fragrance with an emphasized herbal feel was obtained.
Claims (1)
ノンを含有する香料組成物。1 A fragrance composition containing 2,2,7,7-tetramethylcycloheptanone.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5450586 | 1986-03-12 | ||
| JP61-54505 | 1986-03-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6310714A JPS6310714A (en) | 1988-01-18 |
| JPH0337598B2 true JPH0337598B2 (en) | 1991-06-06 |
Family
ID=12972489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61066982A Granted JPS6310714A (en) | 1986-03-12 | 1986-03-25 | Perfumery composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6310714A (en) |
-
1986
- 1986-03-25 JP JP61066982A patent/JPS6310714A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6310714A (en) | 1988-01-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |