JPH03505758A - セルロースパルプを漂白するための方法 - Google Patents
セルロースパルプを漂白するための方法Info
- Publication number
- JPH03505758A JPH03505758A JP1502856A JP50285689A JPH03505758A JP H03505758 A JPH03505758 A JP H03505758A JP 1502856 A JP1502856 A JP 1502856A JP 50285689 A JP50285689 A JP 50285689A JP H03505758 A JPH03505758 A JP H03505758A
- Authority
- JP
- Japan
- Prior art keywords
- bleaching
- pulp
- chlorine
- enzyme
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 27
- 238000004061 bleaching Methods 0.000 title claims description 25
- 239000001913 cellulose Substances 0.000 title claims description 13
- 229920002678 cellulose Polymers 0.000 title claims description 13
- 108090000790 Enzymes Proteins 0.000 claims description 43
- 102000004190 Enzymes Human genes 0.000 claims description 43
- 229940088598 enzyme Drugs 0.000 claims description 43
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 38
- 239000000460 chlorine Substances 0.000 claims description 38
- 229910052801 chlorine Inorganic materials 0.000 claims description 37
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 16
- 239000007844 bleaching agent Substances 0.000 claims description 11
- 239000004155 Chlorine dioxide Substances 0.000 claims description 8
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 108010059892 Cellulase Proteins 0.000 claims description 6
- 229940106157 cellulase Drugs 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 6
- 239000000123 paper Substances 0.000 claims description 6
- 108090000371 Esterases Proteins 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 230000002255 enzymatic effect Effects 0.000 claims description 5
- 239000011121 hardwood Substances 0.000 claims description 5
- 235000018185 Betula X alpestris Nutrition 0.000 claims description 4
- 235000018212 Betula X uliginosa Nutrition 0.000 claims description 4
- 239000011111 cardboard Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 238000010411 cooking Methods 0.000 claims description 3
- 235000013305 food Nutrition 0.000 claims description 3
- 108010002430 hemicellulase Proteins 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 230000029087 digestion Effects 0.000 claims description 2
- 229940059442 hemicellulase Drugs 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 230000002087 whitening effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 description 11
- 229920005610 lignin Polymers 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000004056 waste incineration Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 101710130006 Beta-glucanase Proteins 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000000220 Panda oleosa Species 0.000 description 1
- 235000016496 Panda oleosa Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 108010038658 exo-1,4-beta-D-xylosidase Proteins 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011347 resin Chemical class 0.000 description 1
- 229920005989 resin Chemical class 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Hard Magnetic Materials (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI881192A FI81395B (fi) | 1988-03-14 | 1988-03-14 | Foerfarande foer blekning av cellulosamassa. |
| FI881192 | 1988-03-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03505758A true JPH03505758A (ja) | 1991-12-12 |
Family
ID=8526077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1502856A Pending JPH03505758A (ja) | 1988-03-14 | 1989-03-13 | セルロースパルプを漂白するための方法 |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0407421B1 (no) |
| JP (1) | JPH03505758A (no) |
| AT (1) | ATE135429T1 (no) |
| AU (1) | AU626846B2 (no) |
| BR (1) | BR8907314A (no) |
| CA (1) | CA1334581C (no) |
| DE (1) | DE68925967T2 (no) |
| DK (1) | DK175185B1 (no) |
| FI (1) | FI81395B (no) |
| NO (1) | NO174722C (no) |
| NZ (1) | NZ228308A (no) |
| WO (1) | WO1989008738A1 (no) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5298405A (en) * | 1986-04-30 | 1994-03-29 | Alko Limited | Enzyme preparations with recombinantly-altered cellulose profiles and methods for their production |
| FI90888B (fi) * | 1989-02-14 | 1993-12-31 | Enso Gutzeit Oy | Menetelmä selluloosamassan valkaisemiseksi |
| FI86896B (fi) * | 1989-05-04 | 1992-07-15 | Enso Gutzeit Oy | Foerfarande foer blekning av cellulosamassa. |
| DK420289D0 (da) * | 1989-08-25 | 1989-08-25 | Novo Nordisk As | Fremgangsmaade til behandling af lignocellulosepulp |
| NZ235679A (en) * | 1989-10-18 | 1993-01-27 | Int Paper Co | Bleaching lignocellulosic pulp using (a) treatment with xylanase and (b) one or more chemical bleaching stages |
| SE465320B (sv) * | 1990-01-10 | 1991-08-26 | Korsnaes Ab | Preparat som uppvisar enzymatisk delignifieringsaktivitet, saett att framstaella detsamma och tillaempningar daerav |
| FI88315C (fi) * | 1990-04-04 | 1993-04-26 | Enso Gutzeit Oy | Foerfarande foer blekning av cellulosamassa |
| US5837515A (en) * | 1990-05-16 | 1998-11-17 | Alko-Yhtiot Oy | Enzyme preparations and methods for their production |
| GB9018426D0 (en) * | 1990-08-22 | 1990-10-03 | Sandoz Ltd | Improvements in or relating to novel compounds |
| NZ239500A (en) * | 1990-08-24 | 1993-08-26 | Novo Nordisk As | Xylanases obtained from bacillus pumilus and use in a lignocellulosic chemical pulping process |
| DE4129739A1 (de) * | 1990-09-11 | 1992-03-12 | Sandoz Ag | Chlorfreies bleichen von papierpulpe |
| FI108800B (fi) * | 1991-05-07 | 2002-03-28 | Iogen Corp | Menetelmä ja laitteisto entsyymin käyttämiseksi paperimassan valmistuksessa ja valkaisussa |
| US5498534A (en) * | 1992-03-25 | 1996-03-12 | The United States Of America As Represented By The Secretary Of Agriculture | Method of removing color from wood pulp using xylanase from streptomyces roseiscleroticus NRRL B-11019 |
| US5369024A (en) * | 1992-03-25 | 1994-11-29 | The United States Of America As Represented By The Secretary Of Agriculture | Xylanase from streptomyces roseiscleroticus NRRL-11019 for removing color from kraft wood pulps |
| US5935836A (en) * | 1994-07-29 | 1999-08-10 | Rohm Enzyme Finland Oy | Actinomadura xylanase sequences and methods of use |
| US5871730A (en) * | 1994-07-29 | 1999-02-16 | Universite De Sherbrooke | Thermostable xylanase DNA, protein and methods of use |
| US7816129B2 (en) | 1994-07-29 | 2010-10-19 | Ab Enzymes Gmbh | Production and secretion of proteins of bacterial origin in filamentous fungi |
| US6300114B1 (en) * | 1994-07-29 | 2001-10-09 | Rohm Enzyme Finland Oy | Sequences of xylanase and xylanase expression vectors |
| AU2002229430A1 (en) | 2001-01-18 | 2002-07-30 | Iogen Bio-Products Corporation | Use of xylanase in pulp bleaching |
| WO2003074780A1 (en) * | 2002-03-06 | 2003-09-12 | Iogen Bio-Products Corporation | Xylanase treatment of chemical pulp |
| CN104963206A (zh) * | 2014-12-11 | 2015-10-07 | 华东理工常熟研究院有限公司 | 酶改性纸浆纤维、木塑复合材料及其制备方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ216726A (en) * | 1985-07-15 | 1990-08-28 | Repligen Corp | Use of lignin-degrading enzymes from phanerochaete chrysosporium for treatment of wood pulp and e1 effluent |
| ZA894239B (en) * | 1988-06-08 | 1990-03-28 | Int Paper Co | Enzymatic delignification of lignocellulosic material |
| DE68914112T2 (de) * | 1988-11-23 | 1994-08-04 | Sandoz Ag | Benutzung von Enzymen von Aureobasidium Pullulans für das Bleichen von Zellstoff. |
-
1988
- 1988-03-14 FI FI881192A patent/FI81395B/fi not_active Application Discontinuation
-
1989
- 1989-03-13 NZ NZ228308A patent/NZ228308A/xx unknown
- 1989-03-13 CA CA000593523A patent/CA1334581C/en not_active Expired - Lifetime
- 1989-03-13 AT AT89903748T patent/ATE135429T1/de active
- 1989-03-13 WO PCT/FI1989/000045 patent/WO1989008738A1/en not_active Ceased
- 1989-03-13 DE DE68925967T patent/DE68925967T2/de not_active Revoked
- 1989-03-13 AU AU32923/89A patent/AU626846B2/en not_active Ceased
- 1989-03-13 JP JP1502856A patent/JPH03505758A/ja active Pending
- 1989-03-13 EP EP89903748A patent/EP0407421B1/en not_active Revoked
- 1989-03-13 BR BR898907314A patent/BR8907314A/pt not_active IP Right Cessation
-
1990
- 1990-09-04 DK DK199002119A patent/DK175185B1/da not_active IP Right Cessation
- 1990-09-07 NO NO903913A patent/NO174722C/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK211990D0 (da) | 1990-09-04 |
| FI881192A7 (fi) | 1989-09-15 |
| BR8907314A (pt) | 1991-03-19 |
| EP0407421A1 (en) | 1991-01-16 |
| CA1334581C (en) | 1995-02-28 |
| FI81395B (fi) | 1990-06-29 |
| DK211990A (da) | 1990-11-07 |
| NO174722B (no) | 1994-03-14 |
| DE68925967D1 (de) | 1996-04-18 |
| FI881192A0 (fi) | 1988-03-14 |
| DE68925967T2 (de) | 1996-09-12 |
| AU626846B2 (en) | 1992-08-13 |
| DK175185B1 (da) | 2004-06-28 |
| ATE135429T1 (de) | 1996-03-15 |
| AU3292389A (en) | 1989-10-05 |
| NO903913D0 (no) | 1990-09-07 |
| NZ228308A (en) | 1990-06-26 |
| WO1989008738A1 (en) | 1989-09-21 |
| NO174722C (no) | 1994-06-22 |
| NO903913L (no) | 1990-09-07 |
| EP0407421B1 (en) | 1996-03-13 |
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