JPH0352141A - optical recording medium - Google Patents

optical recording medium

Info

Publication number
JPH0352141A
JPH0352141A JP1186481A JP18648189A JPH0352141A JP H0352141 A JPH0352141 A JP H0352141A JP 1186481 A JP1186481 A JP 1186481A JP 18648189 A JP18648189 A JP 18648189A JP H0352141 A JPH0352141 A JP H0352141A
Authority
JP
Japan
Prior art keywords
optical recording
dye
wavelength
recording
absorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1186481A
Other languages
Japanese (ja)
Inventor
Masaaki Suzuki
正明 鈴木
Eiji Ando
安藤 栄司
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP1186481A priority Critical patent/JPH0352141A/en
Publication of JPH0352141A publication Critical patent/JPH0352141A/en
Pending legal-status Critical Current

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  • Optical Record Carriers And Manufacture Thereof (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 産業上の利用分野 本発明(友 情報記録用の光ディスクなどに利用される
光学記録媒体 特に高密度記録を実現するための波長多
重光学記録媒体に関すん 従来の技術 有機材料を記録体とする光学記録媒体を用いた光学記録
技術において、情報の高密度記録を行なうための方法と
して、吸収極大波長の異なる色素を利用して1つの記録
スポットに複数ビットの情報を記録する波長多重記録方
式があも その1方式として、そのピーク吸収波長の異
なる色素薄膜を順次積層した光学記録媒体が提案されて
いる(例えば 特開昭61−205187号公報)。こ
の波長多重光学記録媒体への記録《よ 各ピーク吸収波
長に対応する発振波長のレーザ光を照射し 熱モードに
よってそれぞれ対応するピークが消丸 あるいは低減す
るた△ それぞれのピークの吸収変化による多重記録が
行なわれも 波長多重記録方式に適用される光学記録媒体として(友
 有機フォトクロミック化合物やJ会合体を形或する色
素材料などが用いられも 発明が解決しようとする課題 上記記録方式において、波長多重度を上げるために選択
した光学記録媒体のう松 ある光記録層の吸収スペクト
ルが他の光記録層の吸収スペクトルと重なりがある場合
に(上 lつの記録光の照射の際に その記録光に対応
する光記録層以外の光記録層がその光を吸収して吸収ス
ペクトルが変化してしまうことがあも すなわ叛 光記
録層間の光吸収によるクロストークが大きくなり、波長
多重度を上げられないという問題点があった本発明L&
  このような従来技術の課題を解決することを目的と
すも 課題を解決するための手段 本発明(友 各光記録層においてその吸収極大波長力文
 他の光記録層の吸収極大波長に対してその半値幅以上
離れた光学記録媒体であも 作用 熱モードで記録される光記録層{友 エネルギー閾値を
持っており、吸収波長によってその値は異なん その値
は吸収極大波長で最大となり、吸収極大波長からその吸
収半値幅以上離れた波長において(上 吸収極大波長で
充分な記録を行なうのに必要なエネルギー値の光照射に
より、全く吸収が変化しなくなム したがって、光記録
層の色素を選択する際に 各光記録層の色素の吸収極大
波長がそれぞれ他の光記録層の吸収極大波長よりその半
値幅以上離れているように選択することによって、記録
層間の光吸収によるクロストークを防ぎ、波長多重度を
向上させることが可能となも実施例 以下に 本発明の実施例について図面を参照しながら説
明すも 本実施例でit  J会合体を気水界面で形戊するシア
ニン色素を光記録層として、ラングミュアープロジェッ
ト法を用いて基板上に光学記録媒体を作製しtも  使
用したシアニン色素{上 下記に示す構造式の色素A,
色素B,色素Cであも色素A (以下余白) 色素B 色素C 第l図(a),  (b)に色素Aの吸収スペクトルと
記録波長特性を示す。色素Aほ J会合体ピーク波長は
約700nrrK 吸収半値幅26nmであん 記録波
長特性C友  各記録光の波長におけるエネルギーを一
定として、ピーク吸光度の変化を測定した ピーク吸光
度の変化(表 吸収スペクトルの形状に対応し ピーク
波長での光記録の際に最も大きく変化する特性を示す。
[Detailed Description of the Invention] Industrial Application Fields of the Invention Optical recording media used in optical disks for information recording, etc. Conventional technology related to wavelength multiplexing optical recording media for realizing high-density recording, etc. In optical recording technology that uses optical recording media that use materials as recording bodies, multiple bits of information are recorded in one recording spot using dyes with different absorption maximum wavelengths as a method for high-density recording of information. As one such method, an optical recording medium in which dye thin films having different peak absorption wavelengths are sequentially laminated has been proposed (for example, Japanese Patent Application Laid-Open No. 61-205187). Recording onto a medium 《The laser beam with the oscillation wavelength corresponding to each peak absorption wavelength is irradiated, and the corresponding peaks are erased or reduced by the thermal mode. Multiplex recording is performed by the absorption change of each peak. Problems to be Solved by the Invention Even though organic photochromic compounds and dye materials forming J-aggregates are used as optical recording media applied to the multiplex recording system, in order to increase the wavelength multiplicity in the above recording system, When the absorption spectrum of a selected optical recording medium overlaps with that of another optical recording layer (when the absorption spectrum of a certain optical recording layer overlaps with the absorption spectrum of another optical recording layer), The problem is that the optical recording layer other than the optical recording layer absorbs the light and the absorption spectrum changes. The present invention L&
The purpose of the present invention is to solve the problems of the prior art. An optical recording layer that records in an active thermal mode even if the optical recording medium is separated by more than the half-width. At wavelengths that are more than the absorption half-width away from the maximum wavelength (upper), the absorption does not change at all due to light irradiation with the energy value necessary to perform sufficient recording at the absorption maximum wavelength. When selecting dyes in each optical recording layer, the maximum absorption wavelength of the dye is selected to be more than half-width apart from the maximum absorption wavelength of the other optical recording layer, thereby preventing crosstalk due to light absorption between the recording layers. In the following, examples of the present invention will be explained with reference to the drawings, but in this example, it is possible to improve the wavelength multiplicity. As an optical recording layer, an optical recording medium was prepared on a substrate using the Langmuir-Projet method.
Dye B, Dye C, and Dye A (hereinafter referred to as blank spaces) Dye B Dye C Figures 1 (a) and (b) show the absorption spectrum and recording wavelength characteristics of dye A. Dye A Ho J aggregate peak wavelength is approximately 700 nrrK Absorption half width is 26 nm Recording wavelength characteristics C The change in peak absorbance was measured with the energy at each wavelength of recording light being constant Change in peak absorbance (Table Shape of absorption spectrum The characteristics change the most during optical recording at the peak wavelength.

ピーク波長を中心にして、色素Aの半値幅以上離れた波
長で記録を行なう時に(友 吸光度は全く変化しなくな
も他の色素B,色素Cも同様な特性を示しt4これらの
3色素を光記録層として用いて、 3波長多重光学記録
媒体を作製し 評価した結果を第2図に示す。同図C↓
 色素ん 色素B,色素Cの3光記録層で構成された3
波長多重光学記録媒体の記録結果を示L,  (a)は
色素Aへの記録結果を、 (b)は色素Bへの記録結果
を、 (c)は色素Cの記録結果であん 図はこの光学
記録媒体の吸収スペクトルであり、図中の実線は記録前
のもQ 点線はそれぞれ各記録層に記録を行なった後の
スペクトルであも 各記録層間にGEL  分離層を設
けて熱的なクロストークを防いでいも また光記録は各
ピークに対応ずる波長で行なち\ 記緑エネルギーの値
はピーク吸光度変化率が50%程度になる値であん 色
素A.色素B,色素Cの」会合体ピークの波長はそれぞ
れ700nm,64Onm,  600nm,  そし
て半値幅はそれぞれ26 n m,  2 7 n n
l  1 4 n mであり、光記録層間のピーク波長
間隔はそれぞれの色素の半値幅以上離れるように構威さ
れている。そのた△ 第2図に示すように 各光記録層
に対する記録によって、光吸収によるクロストークを生
じていな鶏 しかし 色素の吸収ピーク間隔が半値幅以
内になる色素どうしを用いて光学記録媒体を構戊した場
合に{友 各光記録層の充分な記録を行なう際に 光吸
収によるクロストークを生じてしま(\ 波長多重光記
録方式を適用できなかっtも 発明の効果 以上に説明したように 本発明により、波長多重光記録
方式に用いる光学記録媒体の光記録層間に生じム 光吸
収によるクロストークを防止出来へ
When recording at a wavelength that is more than half-width apart from the peak wavelength of dye A, the absorbance does not change at all, but the other dyes B and C have similar characteristics. Figure 2 shows the results of fabricating and evaluating a 3-wavelength multiplexing optical recording medium using this as an optical recording layer.Figure C↓
3.Dye composed of 3 optical recording layers of dye B and dye C.
Showing the recording results of the wavelength multiplexing optical recording medium, (a) shows the recording results for dye A, (b) shows the recording results for dye B, and (c) shows the recording results for dye C. The solid line in the figure is the absorption spectrum of the optical recording medium before recording, and the dotted line is the spectrum after recording on each recording layer. In addition, optical recording is performed at a wavelength corresponding to each peak.The value of green energy recorded is the value at which the peak absorbance change rate is approximately 50%.Dye A. The wavelengths of the aggregate peaks of dye B and dye C are 700 nm, 64 nm, and 600 nm, respectively, and the half-widths are 26 nm and 27 nm, respectively.
l 14 nm, and the peak wavelength interval between the optical recording layers is set to be more than the half width of each dye. △ As shown in Figure 2, recording in each optical recording layer does not cause crosstalk due to light absorption.However, optical recording media can be constructed using dyes whose absorption peak intervals are within half width If the wavelength division multiplexing optical recording method cannot be applied, crosstalk occurs due to light absorption when sufficient recording is performed in each optical recording layer. The invention makes it possible to prevent crosstalk caused by optical absorption, which occurs between optical recording layers of optical recording media used in wavelength multiplexing optical recording systems.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は色素Aの吸収スペクトル及び色素Aからなる光
記録層の記録波長特性を示すグラフ、第2図は色素A,
色素B,色素Cの3光記録層で構戊された3波長多重光
学記録媒体の記録結果を示すグラフである。
Figure 1 is a graph showing the absorption spectrum of dye A and the recording wavelength characteristics of an optical recording layer made of dye A, and Figure 2 is a graph showing the absorption spectrum of dye A,
2 is a graph showing the recording results of a three-wavelength multiplexing optical recording medium configured with three optical recording layers of dye B and dye C.

Claims (1)

【特許請求の範囲】[Claims] 光吸収波長領域が各々異なる複数種類の光記録層で構成
され、各層が対応する波長の光によって選択的に記録さ
れる光学記録媒体において、前記光記録層の吸収極大波
長間の波長幅が各光記録層の光吸収の半値幅以上離れて
いることを特徴とする光学記録媒体。
In an optical recording medium that is composed of a plurality of types of optical recording layers each having a different light absorption wavelength region, and in which each layer is selectively recorded by light of a corresponding wavelength, the wavelength width between the absorption maximum wavelengths of the optical recording layers is different from each other. An optical recording medium characterized in that the optical recording layers are separated by more than the half-width of light absorption.
JP1186481A 1989-07-19 1989-07-19 optical recording medium Pending JPH0352141A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1186481A JPH0352141A (en) 1989-07-19 1989-07-19 optical recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1186481A JPH0352141A (en) 1989-07-19 1989-07-19 optical recording medium

Publications (1)

Publication Number Publication Date
JPH0352141A true JPH0352141A (en) 1991-03-06

Family

ID=16189241

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1186481A Pending JPH0352141A (en) 1989-07-19 1989-07-19 optical recording medium

Country Status (1)

Country Link
JP (1) JPH0352141A (en)

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