JPH0356800B2 - - Google Patents
Info
- Publication number
- JPH0356800B2 JPH0356800B2 JP62148499A JP14849987A JPH0356800B2 JP H0356800 B2 JPH0356800 B2 JP H0356800B2 JP 62148499 A JP62148499 A JP 62148499A JP 14849987 A JP14849987 A JP 14849987A JP H0356800 B2 JPH0356800 B2 JP H0356800B2
- Authority
- JP
- Japan
- Prior art keywords
- deodorizing
- ferrous sulfate
- acid
- livestock
- manure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000001877 deodorizing effect Effects 0.000 claims description 14
- 239000010871 livestock manure Substances 0.000 claims description 14
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 11
- 239000011790 ferrous sulphate Substances 0.000 claims description 11
- 235000015203 fruit juice Nutrition 0.000 claims description 11
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 11
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 235000009508 confectionery Nutrition 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 9
- 235000019645 odor Nutrition 0.000 description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 210000003608 fece Anatomy 0.000 description 5
- 244000144972 livestock Species 0.000 description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 229930003268 Vitamin C Natural products 0.000 description 3
- 235000011054 acetic acid Nutrition 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 230000009965 odorless effect Effects 0.000 description 3
- 235000006408 oxalic acid Nutrition 0.000 description 3
- 235000019154 vitamin C Nutrition 0.000 description 3
- 239000011718 vitamin C Substances 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- KPGXRSRHYNQIFN-UHFFFAOYSA-N 2-oxoglutaric acid Chemical compound OC(=O)CCC(=O)C(O)=O KPGXRSRHYNQIFN-UHFFFAOYSA-N 0.000 description 2
- 241000951471 Citrus junos Species 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 229940099596 manganese sulfate Drugs 0.000 description 2
- 235000007079 manganese sulphate Nutrition 0.000 description 2
- 239000011702 manganese sulphate Substances 0.000 description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000003895 organic fertilizer Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Fertilizers (AREA)
- Housing For Livestock And Birds (AREA)
- Treatment Of Sludge (AREA)
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は主として牛舎、豚舎などの畜舎におい
て生じる家畜糞尿の悪臭を軽減させるための家畜
糞尿の処理剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention mainly relates to a treatment agent for livestock manure for reducing the bad odor of livestock manure generated in livestock housing such as cow pens and pig pens.
（従来の技術）
牛舎、豚斜などの畜舎において生じる家畜糞尿
はそのまま田畠などの所定場所に堆積して腐敗発
酵させたうえ有機肥料として活用されるのを普通
とするが、堆積間に周辺に及ぼす悪臭の問題があ
り、これを解決するため近時は金属の硫酸塩、塩
化物などの水溶液よりなる脱臭処理剤が各種出現
してそれぞれの期待する程度の脱臭効果を発揮し
ている。(Conventional technology) Livestock manure generated in livestock barns such as cow sheds and pig sheds is usually deposited in a designated place such as a rice field, left to rot and ferment, and then used as organic fertilizer. In order to solve this problem, various deodorizing agents made of aqueous solutions of metal sulfates, chlorides, etc. have recently appeared, each exhibiting the desired degree of deodorizing effect.
（発明が解決しようとする問題点）
ところが、前記のような従来の脱臭処理剤の多
くは金属化合物のみをもつてするため、これを使
用して脱臭処理した後の糞尿を田畠に肥料として
長期間施した場合の金属化合物の土壌への好まし
くない影響が懸念されるという問題点がある。(Problem to be solved by the invention) However, since most of the conventional deodorizing agents mentioned above contain only metal compounds, the manure after deodorizing with these agents is used as fertilizer in the fields for a long time. There is a problem in that there is concern that metal compounds may have an unfavorable effect on soil when applied for a period of time.
（問題点を解決するための手段）
本発明は前記のような問題点を解決するために
なされた家畜糞尿の脱臭処理剤であつて、硫酸第
一鉄を主成分としてこれに甘橘類の果汁成分を加
配して水溶液としたものである。(Means for Solving the Problems) The present invention is a deodorizing treatment agent for livestock manure made to solve the above-mentioned problems. It is made into an aqueous solution by adding fruit juice components.
本発明において主成分とする硫酸第一鉄
（FeSO4・7H2O）はこれに加配された甘橘類の果
汁成分との混合水溶液として家畜糞尿に散布して
おけば、糞尿中の硫化水素およびアンモニアの一
部は硫酸第一鉄と逐次反応して硫化鉄および硫酸
アンモニウムを生成し、他方、甘橘類の果汁成分
はこれを組成するリンゴ酸、クエン酸、蟻酸、シ
ユウ酸、酢酸、グリコール酸、ケトグルタル酸、
ビタミンＣなどのうち蟻酸、シユウ酸、酢酸は同
じく糞尿中のアンモニアの一部と反応して蟻酸ア
ンモニウム、シユウ酸アンモニウム、酢酸アンモ
ニウムを生成するものと推量され、その結果、糞
尿の悪臭源である硫化水素およびアンモニアの大
部分は糞尿中に前記のような無臭の化合物となつ
て固定され、糞尿からの悪臭な発散は大きく抑止
されるものである。なお、前記甘橘類の果汁成分
はゆず、かぼす、レモン、みかん類などの天然果
汁をそのまま使用するか或いはこれらの天然果汁
に近似な組成となるように各組成化合物を調合し
て水溶液としたものを使用するかは適宜である。
しかして、甘橘類の果汁成分のうち蟻酸、シユウ
酸、酢酸は前記のように糞尿中の悪臭源の一つで
あるアンモニアの一部の無臭化に効果があるもの
であるが、その他のリンゴ酸、クエン酸、グリコ
ール酸、ケトグルタル酸などはそれらの総合的な
香気を糞尿に付与することとなり、また、ビタミ
ンＣは前記のような果汁成分の有機酸とは別に特
有の消臭作用を発揮するものである。 Ferrous sulfate (FeSO 4 .7H 2 O), which is the main component of the present invention, can be sprayed on livestock manure as a mixed aqueous solution with sweet fruit juice added to it, to remove hydrogen sulfide from the manure. and a part of the ammonia react sequentially with ferrous sulfate to produce iron sulfide and ammonium sulfate, while the sweet fruit juice components make up the malic acid, citric acid, formic acid, oxalic acid, acetic acid, and glycol of which it is composed. acid, ketoglutaric acid,
Among vitamin C, formic acid, oxalic acid, and acetic acid are also thought to react with a portion of ammonia in excrement to produce ammonium formate, ammonium oxalate, and ammonium acetate, which are the source of the foul odor of excrement. Most of hydrogen sulfide and ammonia are fixed in the excrement as odorless compounds as mentioned above, and emission of bad odor from the excrement is greatly suppressed. As the sweet fruit juice component, natural fruit juices such as yuzu, kabosu, lemon, and mandarin oranges may be used as they are, or each component may be prepared as an aqueous solution by blending each component to have a composition similar to these natural fruit juices. It is up to you which one to use.
As mentioned above, formic acid, oxalic acid, and acetic acid among the fruit juice components of sweet fruits are effective in deodorizing ammonia, which is one of the sources of bad odors in excrement and urine. Malic acid, citric acid, glycolic acid, ketoglutaric acid, etc. impart their comprehensive aroma to excrement, and vitamin C has a unique deodorizing effect apart from the organic acids of fruit juice components mentioned above. It is something that can be demonstrated.
本発明は前記のように、硫酸第一鉄とこれに加
配する甘橘類の果汁成分によつて家畜糞尿から発
生する悪臭を抑止して脱臭効果を発揮できるもの
であるが、硫酸第一鉄のほかに少量の硫酸マグネ
シウムの硫酸マンガンを添加しておけば、硫酸第
一鉄による前記悪臭抑止作用は一層向上されるこ
とが実験により確認され、そして、これらの添加
は肥料成分として有効なマグネシウムおよびマン
ガンの増強にもなるものである。また、明礬の少
量を添加しておけば、使用前における水溶液の安
定に効果があり、沈澱物の生成をよく防止できる
ものであり、さらに、必要に応じてサイクロデキ
ストリンなどの一般的な消臭剤を少量添加してお
くようなことは適宜である。 As described above, the present invention is capable of suppressing bad odors generated from livestock manure and exerting a deodorizing effect by using ferrous sulfate and sweet fruit juice components added to the ferrous sulfate. It has been confirmed through experiments that if a small amount of magnesium sulfate or manganese sulfate is added in addition to ferrous sulfate, the odor suppressing effect of ferrous sulfate can be further improved. It also enhances manganese. Additionally, if a small amount of alum is added, it is effective in stabilizing the aqueous solution before use and can effectively prevent the formation of precipitates.Additionally, if necessary, general deodorizing agents such as cyclodextrin can be added. It is appropriate to add a small amount of the agent.
実施例
硫酸第一鉄100（重量部、以下同じ）に硫酸マグ
ネシウム20および硫酸マンガン１を添加して１％
水溶液とし、この硫酸第一鉄を主成分とする水溶
液100にゆずの果汁５〜25を加配した。この脱臭
処理剤を畜舎の床上の家畜糞尿に散布した結果、
悪臭が著しく抑止され、田畠の所定場所に堆積し
た場合にも周辺に悪臭が少なく、顕著な脱臭効果
が認められた。Example: Add 20% magnesium sulfate and 1% manganese sulfate to 100% ferrous sulfate (parts by weight, same below) to make 1%
An aqueous solution was prepared, and 5 to 25 grams of yuzu juice was added to 100 grams of this aqueous solution containing ferrous sulfate as a main component. As a result of spraying this deodorizing agent on the livestock manure on the floor of the livestock barn,
The odor was significantly suppressed, and even when it was deposited in a designated area in a rice field, there was little odor in the surrounding area, and a remarkable deodorizing effect was observed.
（発明の効果）
本発明は以上の説明から明らかなように、硫酸
第一鉄を主成分として家畜糞尿中の悪臭成分であ
る硫化水素およびアンモニアの一部を無臭の化合
物として固定させ、同時に該硫酸第一鉄に加配し
た甘橘類の果汁成分を組成する各種有機酸をもつ
て主としてアンモニアの一部を無臭の化合物とし
て固定するとともにビタミンＣをもつて特有の消
臭作用を発揮させ、牛舎、豚舎などの畜舎の糞尿
やその堆積間の糞尿の脱臭を効果的に行うことが
できるものであり、しかも、糞尿処理後堆積して
田畠に肥料として施した場合には、加配した甘橘
類の果汁成分に基づく有機化合物が有機質肥料化
することによつて土壌に好影響を与えることにな
るものであつて、従来のこの種脱臭処理剤の問題
点を解決したものとして畜産業者に寄与するとこ
ろ大なものである。(Effects of the Invention) As is clear from the above description, the present invention uses ferrous sulfate as a main component to fix part of hydrogen sulfide and ammonia, which are malodorous components in livestock manure, as an odorless compound, and at the same time Ferrous sulfate is added to various organic acids that make up the juice components of sweet fruits, and a part of the ammonia is fixed as an odorless compound, and vitamin C has a unique deodorizing effect. It can effectively deodorize the manure in livestock houses such as pig pens and the manure between the piles, and when the manure is piled up after treatment and applied as fertilizer to fields, it is possible to remove the added sweet fruits. The organic compound based on the fruit juice component is turned into organic fertilizer, which has a positive effect on the soil, and contributes to livestock producers by solving the problems of conventional deodorizing agents of this type. However, it is a big thing.
Claims (1)
汁成分を加配して水溶液とした家畜糞尿の脱臭処
理剤。1. A deodorizing treatment agent for livestock manure made into an aqueous solution containing ferrous sulfate as the main component and the addition of sweet fruit juice components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62148499A JPS63315200A (en) | 1987-06-15 | 1987-06-15 | Deodorizer for cattle feces and urine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62148499A JPS63315200A (en) | 1987-06-15 | 1987-06-15 | Deodorizer for cattle feces and urine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63315200A JPS63315200A (en) | 1988-12-22 |
| JPH0356800B2 true JPH0356800B2 (en) | 1991-08-29 |
Family
ID=15454121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62148499A Granted JPS63315200A (en) | 1987-06-15 | 1987-06-15 | Deodorizer for cattle feces and urine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63315200A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009004932A1 (en) | 2007-06-29 | 2009-01-08 | Uni-Charm Petcare Corporation | Sheet for treating animal feces and urine |
| WO2009004931A1 (en) | 2007-06-29 | 2009-01-08 | Uni-Charm Petcare Corporation | Sheet for treating animal feces and urine |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2945402B2 (en) * | 1988-12-28 | 1999-09-06 | ダイヤフロツク株式会社 | Sludge deodorant |
| US5054434A (en) * | 1989-09-27 | 1991-10-08 | W. R. Grace & Co.-Conn. | Suppression of ammonia odors from animal wastes |
| US5204091A (en) * | 1991-12-06 | 1993-04-20 | Barrett Lawrence E | Method for combatting foot odors |
| JPH05284869A (en) * | 1992-04-10 | 1993-11-02 | Mitajiri Kagaku Kogyo Kk | Flooring material for domestic animal |
| FR2733425B1 (en) * | 1995-04-26 | 1997-07-25 | Guyomarch Alimentaire Sa | PROCESS FOR RAPID DEODORIZATION OF MANURE |
| JP2003500173A (en) * | 1999-05-31 | 2003-01-07 | ジボーダン ソシエテ アノニム | Odor absorbing aqueous composition |
| US20090012488A1 (en) * | 2006-03-10 | 2009-01-08 | Basf Se | Super-Absorber Having Improved Smell-Inhibition |
| WO2014067012A1 (en) | 2012-11-05 | 2014-05-08 | Absorbent Products Ltd. | Ammonia reducing agent for animal beddings and litters |
-
1987
- 1987-06-15 JP JP62148499A patent/JPS63315200A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009004932A1 (en) | 2007-06-29 | 2009-01-08 | Uni-Charm Petcare Corporation | Sheet for treating animal feces and urine |
| WO2009004931A1 (en) | 2007-06-29 | 2009-01-08 | Uni-Charm Petcare Corporation | Sheet for treating animal feces and urine |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63315200A (en) | 1988-12-22 |
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| LAPS | Cancellation because of no payment of annual fees |