JPH0357149B2 - - Google Patents
Info
- Publication number
- JPH0357149B2 JPH0357149B2 JP61066529A JP6652986A JPH0357149B2 JP H0357149 B2 JPH0357149 B2 JP H0357149B2 JP 61066529 A JP61066529 A JP 61066529A JP 6652986 A JP6652986 A JP 6652986A JP H0357149 B2 JPH0357149 B2 JP H0357149B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- graft
- polyorganosiloxane
- polyphenylene ether
- ether resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 claims description 39
- 239000005060 rubber Substances 0.000 claims description 38
- 229920001955 polyphenylene ether Polymers 0.000 claims description 37
- 229920000578 graft copolymer Polymers 0.000 claims description 35
- 229920005989 resin Polymers 0.000 claims description 27
- 239000011347 resin Substances 0.000 claims description 27
- 239000011342 resin composition Substances 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 16
- 229920002554 vinyl polymer Polymers 0.000 claims description 16
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229920005990 polystyrene resin Polymers 0.000 claims description 12
- 230000008961 swelling Effects 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 38
- -1 poly(2,6 -dimethyl-1,4-phenylene) Polymers 0.000 description 23
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 20
- 239000000203 mixture Substances 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 15
- 238000000034 method Methods 0.000 description 15
- 238000002156 mixing Methods 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 14
- 238000010559 graft polymerization reaction Methods 0.000 description 13
- 229920001577 copolymer Polymers 0.000 description 12
- 239000008188 pellet Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 229920000126 latex Polymers 0.000 description 9
- 239000004793 Polystyrene Substances 0.000 description 8
- 239000003431 cross linking reagent Substances 0.000 description 8
- 229920002223 polystyrene Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 7
- VLZDYNDUVLBNLD-UHFFFAOYSA-N 3-(dimethoxymethylsilyl)propyl 2-methylprop-2-enoate Chemical compound COC(OC)[SiH2]CCCOC(=O)C(C)=C VLZDYNDUVLBNLD-UHFFFAOYSA-N 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000004816 latex Substances 0.000 description 6
- 125000005375 organosiloxane group Chemical group 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 239000011259 mixed solution Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 229920005669 high impact polystyrene Polymers 0.000 description 3
- 239000004797 high-impact polystyrene Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 description 2
- IJAJGQIUSCYZPR-UHFFFAOYSA-N 3,5-diethyl-7-oxabicyclo[2.2.1]hepta-1(6),2,4-triene Chemical compound CCC1=C(O2)C(CC)=CC2=C1 IJAJGQIUSCYZPR-UHFFFAOYSA-N 0.000 description 2
- GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 description 2
- LOOUJXUUGIUEBC-UHFFFAOYSA-N 3-(dimethoxymethylsilyl)propane-1-thiol Chemical compound COC(OC)[SiH2]CCCS LOOUJXUUGIUEBC-UHFFFAOYSA-N 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229920006015 heat resistant resin Polymers 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical group CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 description 1
- JQCTVMZZQARCPW-UHFFFAOYSA-N 2,3,5-triethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound O1C2=C(CC)C(CC)=C1C=C2CC JQCTVMZZQARCPW-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- QZRFWQBUYGHLMU-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.N#CC=CC=CC1=CC=CC=C1 QZRFWQBUYGHLMU-UHFFFAOYSA-N 0.000 description 1
- OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical compound C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 101100208721 Mus musculus Usp5 gene Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- KCAMXZBMXVIIQN-UHFFFAOYSA-N octan-3-yl 2-methylprop-2-enoate Chemical compound CCCCCC(CC)OC(=O)C(C)=C KCAMXZBMXVIIQN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- TUQLLQQWSNWKCF-UHFFFAOYSA-N trimethoxymethylsilane Chemical compound COC([SiH3])(OC)OC TUQLLQQWSNWKCF-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
- C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
ãç£æ¥äžã®å©çšåéã
æ¬çºæã¯èè¡ææ§ãèç±æ§ãæ©æ¢°ç匷床ãæ圢
æ§åã³æµåæ§çã«åªããããªããšãã¬ã³ãšãŒãã«
æš¹èçµæç©ãããã«è©³ããã¯ããªããšãã¬ã³ãšãŒ
ãã«æš¹èãããªã¹ãã¬ã³æš¹èåã³ç¹å®ã®ããªãªã«
ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœããæ§æãã
ãããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã«é¢ããã
ã®ã§ããã ãåŸæ¥ã®æè¡ã ããªããšãã¬ã³ãšãŒãã«æš¹èã¯èç±æ§ãåæ§ç
ã«åªãããããšã³ãžãã¢ãªã³ã°ãã©ã¹ããã¯ãšã
ãŠã®çšéãæ¡å€§ããŠããããèè¡ææ§ã«è¥å¹²å£ã
ããšãããã®çšéãå¶éãããŠããã ããªããšãã¬ã³ãšãŒãã«æš¹èã®èè¡ææ§ãæ¹å
ããæ¹æ³ãšããŠãããªãã¿ãžãšã³ç³»ãšã©ã¹ãããŒ
ãé åããæ¹æ³ãç¹å ¬æ47â32731å·å ¬å ±ãç¹é
æ46â2345å·å ¬å ±çã«é瀺ãããŠãããããããª
ããããããæ¹æ³ã«ããå Žåã¯ããªãã¿ãžãšã³ç³»
ãšã©ã¹ãããŒäžã«äžé£œåçµåãæ®åããããç±ç
ã«äžå®å®ã§ãããå®çšçã«æçšãªç±å®å®æ§ã«åªã
ããã®ãåŸãããªãã åãããªããšãã¬ã³ãšãŒãã«æš¹èã«ãšãã¬ã³â
ãããã¬ã³å ±éåäœã®ãããªããªãªã¬ãã€ã³ãé
åããããšã«ããããªããšãã¬ã³ãšãŒãã«æš¹èã®
æ圢å å·¥æ§ãèè¡ææ§ãåäžãããæ¹æ³ãç±³åœç¹
蚱第336185å·æ现æžãç¹å ¬æ42â7069å·å ¬å ±çã«
é瀺ãããŠãããããããªããããããæ¹æ³ã«ã
ãå Žåã«ã¯ããªãªã¬ãã€ã³ã®é åéã10ééïŒ ä»¥
äžãšãããšãããªããšãã¬ã³ãšãŒãã«æš¹èãšããª
ãªã¬ãã€ã³ãšã®çžæº¶æ§ãæªãããæ圢åãšããå Ž
åå±€ç¶å¥é¢ãçããããã«ãªãè¡šé¢å€èŠ³ãæªãã
ãããèè¡ææ§ã®åäžçšåºŠãããçšé¡èã§ã¯ãª
ãã ããã«ãäžèšããªãªã¬ãã€ã³ãé åããæ¹æ³ã®
æ¹è¯æ³ãšããŠãã¹ãã¬ã³ç³»åéäœãããªãªã¬ãã€
ã³ã«ã°ã©ããéåãããããªãªã¬ãã€ã³ç³»ã°ã©ã
ãå ±éåäœãããªããšãã¬ã³ãšãŒãã«æš¹èãé å
ããããšã«ãã€ãŠããªããšãã¬ã³ãšãŒãã«æš¹èã®
åæ§ãæ©æ¢°ç匷床ãç¶æãã€ã€æ圢å å·¥æ§ãæ¹è¯
ããããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ãç¹éæ
49â75663å·å ¬å ±ã«é瀺ãããŠãããããããªã
ãããããæ¹æ³ã«ããå Žåã§ã¯å åãªèè¡ææ§ã®
æ¹è¯ããªãããŠããªãã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæè ãã¯ããªããšãã¬ã³ãšãŒãã«æš¹èæ¬æ¥
ã®åªããèç±æ§ãæ©æ¢°ç匷床ããã®ãŸãŸä¿æãã
ãã€èè¡ææ§ãæ¹åããæ¹æ³ã«ã€ããŠéææ€èšã
ãçµæãããªãªã«ã¬ãã·ãããµã³ãŽã ã«ããã«ç³»
åéäœãé«å¹çã§ã°ã©ããéåãããããªãªã«ã¬
ãã·ãããµã³ç³»ã°ã©ããå ±éåäœãããªããšãã¬
ã³ãšãŒãã«æš¹èãšããªã¹ãã¬ã³æš¹èãšçµåããŠé
åããããšã«ããããããåæš¹èéã®çžæº¶æ§ãè¯
奜ã§ãæ圢åãšããå Žåã«å±€ç¶å¥é¢ãçããããš
ããªãããããèè¡ææ§ãèããæ¹åã§ãããã€
èç±æ§åã³æ©æ¢°ç匷床ãæ圢æ§ãªãã³ã«æµåæ§ã
åªããæš¹èçµæç©ãšãåŸãããšãèŠãåºãæ¬çºæ
ã«å°éããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæã¯ãããªããšãã¬ã³ãšãŒãã«æš¹è(A)ãã
ãªã¹ãã¬ã³æš¹è(B)åã³ãã«ãšã³æº¶åªäžã§æž¬å®ãã
èšæœ€åºŠãïŒã15ã§ããããã€ã°ã©ãã亀åå€ãå«
æããããªãªã«ã¬ãã·ãããµã³ãŽã ã«ïŒçš®åã¯ïŒ
皮以äžã®ããã«ç³»åéäœãã°ã©ããéåãããã
ãªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)ãã
æ§æãããããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã§
ããã æ¬çºæã«ãããŠçšããããããªããšãã¬ã³ãšãŒ
ãã«æš¹è(A)ãšã¯äžèšäžè¬åŒã§è¡šããããåç¬éå
äœåã¯å ±éåäœã§ããã ïŒåŒäžQ1ãQ4ã¯æ°ŽçŽ ãçåæ°ŽçŽ åºãããªã矀ã
ãããããç¬ç«ã«éžæãããïœã¯30以äžã®æ°ã瀺
ããïŒ ãããããªããšãã¬ã³ãšãŒãã«æš¹èã®å ·äœäŸãš
ããŠã¯ããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšã
ã¬ã³ïŒãšãŒãã«ãããªïŒïŒïŒïŒâãžãšãã«âïŒïŒ
ïŒâããšãã¬ã³ïŒãšãŒãã«ãããªïŒïŒïŒïŒâãžã
ããã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãããª
ïŒïŒâã¡ãã«âïŒâãšãã«âïŒïŒïŒâããšãã¬ã³ïŒ
ãšãŒãã«ãããªïŒïŒâã¡ãã«âïŒâãããã«â
ïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãããªïŒïŒâãšã
ã«âïŒâãããã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒã
ã«ãïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒ
ãšãŒãã«ãšïŒïŒïŒïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ïŒãšãŒãã«ã®å ±éåäœãïŒïŒïŒïŒâãž
ãšãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãšïŒïŒïŒ
ïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒ
ãã«ã®å ±éåäœãïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ïŒãšãŒãã«ãšïŒïŒïŒïŒïŒïŒâããªãšã
ã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ã®å ±éåäœç
ãæãããããç¹ã«ããªïŒïŒïŒïŒâãžã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãåã³ïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãš
ïŒïŒïŒïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒ
ãšãŒãã«ã®å ±éåäœã奜ãŸãããããã«å¥œãŸãã
ã¯ããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬
ã³ïŒãšãŒãã«ã§ããããããããªããšãã¬ã³ãšãŒ
ãã«æš¹èã¯ããããé åæ¯çã®äžã§ããªã¹ãã¬ã³
æš¹èãšçžæº¶åãããæ¬çºæã«ãããŠçšããããã
ãªããšãã¬ã³ãšãŒãã«æš¹èã®éå床ã¯ç¹ã«å¶éã
ãããã®ã§ã¯ãªããã25âã¯ãããã«ã 溶åªäžã§
ã®éå ç²åºŠã0.3ã0.7dlïŒïœã®ãã®ã奜ãŸããçš
ããããã0.3dlïŒïœæªæºã®éå ç²åºŠã®ãã®ã§ã¯
ç±å®å®æ§ãæªããªãåŸåã§ãããå0.7dlïŒïœã
è¶ ããéå ç²åºŠã®ãã®ã§ã¯æ圢æ§ãæãªãããåŸ
åãšãªãããããã®ããªããšãã¬ã³ãšãŒãã«æš¹è
ã¯åç¬ã§åã¯ïŒçš®ä»¥äžæ··åããŠçšããããã åãæ¬çºæã«ãããŠçšããããããªã¹ãã¬ã³æš¹
è(B)ãšã¯äžèšäžè¬åŒã§è¡šããããè³éŠæããã«ç³»
åéäœåäœã50ééïŒ ä»¥äžããæ§æãããåç¬é
åäœåã¯ä»ã®å ±éåå¯èœãªããã«ç³»åéäœãšã®å ±
éåäœã§ããã ïŒåŒäžïŒ¹ã¯æ°ŽçŽ åååã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«
ãã«åºãã¯ããã²ã³åååã¯ççŽ ååæ°ïŒãïŒ
ã®ã¢ã«ãã«åºãïœã¯ïŒåã¯ïŒãïŒã®æ°ã瀺ããïŒ ãããããªã¹ãã¬ã³æš¹èã®å ·äœäŸãšããŠã¯ããª
ã¹ãã¬ã³ãããªã¯ãã«ã¹ãã¬ã³ãããªÎ±âã¡ãã«
ã¹ãã¬ã³ãã¹ãã¬ã³âã¢ã¯ãªããããªã«å ±éå
äœãã¹ãã¬ã³âã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±éåäœã
ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãã¹ãã¬ã³â
ãã¬ã€ããå ±éåäœãã¹ãã¬ã³ââããšãã«ã
ã¬ã€ããå ±éåäœãã¹ãã¬ã³âã¢ã¯ãªããããªã«
âαâã¡ãã«ã¹ãã¬ã³äžå å ±éåäœçãæããã
ããããªã¹ãã¬ã³ãç¹ã«å¥œãŸãããã®ã§ããã ããã«ãæ¬çºæã«ãããŠçšããããããªãªã«ã¬
ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)ãšã¯ãã«ãšã³
溶åªäžã§æž¬å®ããèšæœ€åºŠãïŒã15ã§ããããã€ã°
ã©ãã亀åå€ãå ±éåãããããªãªã«ã¬ãã·ãã
ãµã³ãŽã ã«ïŒçš®åã¯ïŒçš®ä»¥äžã®ããã«ç³»åéäœã
ã°ã©ããéåããããã®ã§ããããã®ããªãªã«ã¬
ãã·ãããµã³ç³»ã°ã©ããå ±éåäœäžã®ããªãªã«ã¬
ãã·ãããµã³ãŽã ã®å«æéã¯ïŒã90ééïŒ ã®ç¯å²
ã§ãããã®ã奜ãŸãããããã«ããªãªã«ã¬ãã·ã
ããµã³ãŽã ã¯ãªã«ã¬ãã·ãããµã³ãšã°ã©ãã亀å
å€åã³æ¶æ©å€ã®ïŒæåããæ§æããããã®ã§ã
ãã ããªãªã«ã¬ãã·ãããµã³ãŽã ãæ§æãããªã«ã¬
ãã·ãããµã³ãšããŠã¯ãäŸãã°ãããµã¡ãã«ããª
ã·ã¯ãã·ãããµã³ããªã¯ã¿ã¡ãã«ããã©ã·ã¯ãã·
ãããµã³ããã«ã¡ãã«ãã³ã¿ã·ã¯ãã·ãããµã³ã
ããã«ã¡ãã«ãããµã·ã¯ãã·ãã·ãµã³ãããªã¡ã
ã«ããªããšãã«ããªã·ã¯ãã·ãããµã³ãããã©ã¡
ãã«ããã©ããšãã«ããã©ã·ã¯ãã·ãããµã³ããª
ã¯ã¿ããšãã«ããã©ã·ã¯ãã·ãããµã³çãæãã
ãããããã¯åç¬ã§åã¯ïŒçš®ä»¥äžæ··åããŠçšãã
ããããããã®äœ¿çšéã¯ããªãªã«ã¬ãã·ãããµã³
ãŽã äž50ééïŒ ä»¥äžã奜ãŸããã¯70ééïŒ ä»¥äžã§
ããã ã°ã©ãã亀åå€ãšããŠã¯ãäžè¬åŒ CH2ïŒCHâSiR1 oO(3-o)/2 ïŒïŒ å㯠HSâïŒCH2âïŒpSiR1 oO(3-o)/2 ïŒïŒ ïŒååŒäžR1ã¯ã¡ãã«åºããšãã«åºããããã«åº
åã¯ããšãã«åºãR2ã¯æ°ŽçŽ åååã¯ã¡ãã«åºã
ïœã¯ïŒãïŒåã¯ïŒãïœã¯ïŒãïŒã®æ°ã瀺ããïŒ ã§è¡šãããããªã«ã¬ãã·ãããµã³ååç©çãçšã
ããããäžè¬åŒïŒïŒã®ïŒã¡ã¿ïŒã¢ã¯ãªããã·ã·
ãããµã³ã¯ã°ã©ããå¹çãé«ãçºæå¹ãªã°ã©ãã
éã圢æããããšãå¯èœã§ããèè¡ææ§çºçŸã®ç¹
ã§æå©ã§ããããªãäžè¬åŒïŒïŒã®å ã¡ã¿ã¯ãªã
ãã·ã·ãããµã³ãç¹ã«å¥œãŸãããã®ã§ããã ã°ã©ãã亀åå€ã®äœ¿çšéã¯ãããªãªã«ã¬ãã·ã
ããµã³ãŽã äž0.1ã20ééïŒ ã奜ãŸããã¯0.1ã10
ééïŒ ã§ããã ããã«æ¶æ©å€ãšããŠã¯ãïŒå®èœæ§åã¯ïŒå®èœæ§
ã®ã·ãããµã³ç³»æ¶æ©å€ãäŸãã°ããªã¡ããã·ã¡ã
ã«ã·ã©ã³ãããªãšããã·ããšãã«ã·ã©ã³ãã¡ãã«
ãªã«ãœã·ãªã±ãŒãããšãã«ãªã«ãœã·ãªã±ãŒããã
ãã«ãªã«ãœã·ãªã±ãŒãçãçšãããããæ¶æ©å€ã®
䜿çšéã¯ããªãªã«ã¬ãã·ãããµã³ãŽã äž0.2ã30
ééïŒ ã§ããããã®äœ¿çšéã¯ããªãªã«ã¬ãã·ãã
ãµã³ãŽã ã®èšæœ€åºŠïŒããªãªã«ã¬ãã·ãããµã³ãŽã
ããã«ãšã³æº¶åªäžã§25âã§é£œåãããšããããªãª
ã«ã¬ãã·ãããµã³ãŽã ãåžåããŠãããã«ãšã³ã®
ééå²åïŒãïŒã15ã®ç¯å²ã«ãªãããã«èª¿æŽãã
ãã¹ãã§ãããèšæœ€åºŠãïŒæªæºã§ã¯æ¶æ©å€éãå€
ããªãéããŠãŽã 匟æ§ãåŸãããªããªãããŸãèš
最床ã15ãè¶ ãããšãã°ã©ããå ±éåäœäžã§ãŽã
圢æ ãä¿æã§ããªããªãèè¡ææ§ãä»äžã§ããã
ããªããšãã¬ã³ãšãŒãã«æš¹èã«é åããŠããã å
ã«ããªãªã«ã¬ãã·ãããµã³ãªã€ã«ãæ·»å ããã®ãš
åçã®ç¡¬åããåŸãããªãã ãªãèšæœ€åºŠã®æž¬å®ã¯æ¬¡ã®ããã«ããŠè¡ããããª
ãã¡ãéåããŠåŸãããªãªã«ã¬ãã·ãããµã³ãŽã
ãã©ãã¯ã¹ãçŽïŒãïŒåéã®ã€ãœãããã«ã¢ã«ã³
ãŒã«äžã«æ¹æããªããæ·»å ãããšãã«ãžãšã³ãç Ž
å£ãååºããããšã«ããã·ãããµã³ããªããŒãåŸ
ããåŸãããªããŒãæ°ŽæŽããåŸã80âã§10æéæž
å§ä¹Ÿç¥ããã也ç¥åŸãçŽïŒïœã®ããªããŒã粟秀
ããçŽ30ïœã®ãã«ãšã³äžã«æµžæŒ¬ãã25âã§100æ
éæŸçœ®ãèšæœ€ãããã次ãã§æ®äœã®ãã«ãšã³ãã
ã«ã³ããŒã·ãšã³ã«ããåé¢é€å»ãã粟秀ããåŸã
80âã§16æéæžå§ä¹Ÿç¥ããåžåããããã«ãšã³ã
èžçºé€å»ããåã³ç²Ÿç§€ãããèšæœ€åºŠã¯æ¬¡åŒã«ãã
ç®åºãããã èšæœ€åºŠïŒïŒèšæœ€ããããªããŒéé
ïŒâïŒä¹Ÿç¥ããªããŒééïŒïŒïŒä¹Ÿç¥ããªããŒééïŒ ãã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éåã¯ãç±³
åœç¹èš±ç¬¬2891920å·æ现æžãå第3294725å·æ现æž
çã«èšèŒãããŠããæ¹æ³ãããªãã¡ãªã«ã¬ãã·ã
ããµã³ãšã°ã©ãã亀åå€åã³æ¶æ©å€ã®æ··å溶液
ããã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³é žãã¢ã«ãã«ã¹ã«
ãã³é žçã®ä¹³åå€ã®ååšäžã§æ°Žãšåªææ··åããæ¹
æ³ã«ãã補é ããããšã奜ãŸãããã¢ã«ãã«ãã³
ãŒã³ã¹ã«ãã³é žã¯ãªã«ã¬ãã·ãããµã³ã®ä¹³åå€ãš
ããŠäœçšãããšåæã«éåéå§å€ãšããªãã®ã§å¥œ
é©ã§ããããã®éãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³é ž
éå±å¡©ãã¢ã«ãã«ã¹ã«ãã³é žéå±å¡©çã䜵çšãã
ãšã°ã©ããéåãè¡ãéã«ããªããŒãå®å®ã«ç¶æ
ããã®ã«å¹æãããã®ã§å¥œãŸããã ãã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã«ã°ã©ããé
åãããããã«ç³»åéäœãšããŠã¯ãã¹ãã¬ã³ãα
âã¡ãã«ã¹ãã¬ã³ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâ
ãšãã«ããã·ã«ã¡ã¿ã¯ãªã¬ãŒããã¡ãã«ã¢ã¯ãªã¬
ãŒãããšãã«ã¢ã¯ãªã¬ãŒããããã«ã¢ã¯ãªã¬ãŒ
ããã¢ã¯ãªããããªã«ãã¡ã¿ã¯ãªããããªã«çã®
è³éŠæã¢ã«ã±ãã«ååç©ãã¡ã¿ã¯ãªã«é žãšã¹ã
ã«ãã¢ã¯ãªã«é žãšã¹ãã«çã®åçš®ã®ããã«ç³»åé
äœãæãããããããã¯åç¬ã§åã¯ïŒçš®ä»¥äžçµå
ããŠçšããããããããããã«ç³»åéäœã®å ã¹ã
ã¬ã³ãç¹ã«å¥œãŸããã äžèšããã«ç³»åéäœãšããªãªã«ã¬ãã·ãããµã³
ãŽã ãšã®å²åã¯ãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœã®ééã«åºã¥ãããªãªã«ã¬ãã·ãã
ãµã³ãŽã ïŒã90ééïŒ ãããã«ç³»åéäœ95ã10é
éïŒ ã§ãããããªãªã«ã¬ãã·ãããµã³ãŽã ãïŒé
éïŒ æªæºã§ã¯æ¬çºæã®æš¹èçµæç©ã®èè¡ææ§æ¹è¯
ã®å¹æãå åã§ãªããåã90ééïŒ ãè¶ ãããšã°
ã©ããã®å¹æãçºæ®ã§ããªããªãã®ã§å¥œãŸãããª
ãã ãããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±é
åäœã¯ãéåžžã®ä¹³åéåæ³ã«ãã€ãŠè£œé ããããš
ãã§ãããããªãã¡ãããªãªã«ã¬ãã·ãããµã³ãŽ
ã ã©ããã¯ã¹ãã¢ã«ã«ãªã«ããäžåããåŸãäžèš
ããã«ç³»åéäœãã©ãžã«ã«éåæè¡ã«ãã€ãŠäžæ®µ
ãããã¯å€æ®µã§éåããããšã«ããåŸãããšãã§
ããã ãã®ããã«ããŠåŸãããããªãªã«ã¬ãã·ãããµ
ã³ç³»ã°ã©ããå ±éåäœã©ããã¯ã¹ã¯å¡©åã«ã«ã·ãŠ
ã åã¯ç¡«é žãã°ãã·ãŠã çã®éå±å¡©ã溶解ããç±
æ°Žäžã«è©²ã©ããã¯ãæå ¥ããå¡©æãååºããããš
ã«ããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éå
äœãåé¢ãååããããšãã§ããã ãããåŸä¹Ÿç¥ããŠåŸãããªãªã«ã¬ãã·ãããµã³
ç³»ã°ã©ããå ±éåäœã¯ãã°ã©ããéåæã«æŽŸçã
ãã°ã©ããéåçšããã«ç³»åéäœã®ããªãŒã®éå
äœãšããªãªã«ã¬ãã·ãããµã³ãŽã ã«çµåããã°ã©
ããããªããŒãšã®æ··åç©ã§ããããã®ããªãªã«ã¬
ãã·ãããµã³ãŽã ãžã®ã°ã©ããããªããŒã®çµåå²
åãããªãã¡ã°ã©ããçã¯ããªããšãã¬ã³ãšãŒã
ã«æš¹èã®èè¡ææ§èœãçºçŸããã®ã«éèŠãªå åãš
ãªããããªãã¡ãã°ã©ããéã«ããããªããšãã¬
ã³ãšãŒãã«æš¹èåã³ããªã¹ãã¬ã³æš¹èãšããªãªã«
ã¬ãã·ãããµã³ãŽã ãšã®èŠªåãèšããã®ã§ããã
åŸã€ãŠã°ã©ããçã¯10ïŒ ä»¥äžã奜ãŸããã¯30ïŒ ä»¥
äžã§ããããšããããåãã°ã©ããéåã«çšãã
ããã«ç³»åéäœã¯äžè¿°ã®åŠãåçš®ããã«ç³»åéäœ
ãåç¬ã§åã¯ïŒçš®ä»¥äžçµåããŠçšããããšãã§ã
ããã¹ãã¬ã³ãçšããã®ã奜ãŸããã äžæ¹ãã°ã©ããéåæã«ããªãªã«ã¬ãã·ãããµ
ã³ãŽã ã«çµåããŠããªãããªãŒã®éåäœãäžéšç
æããããšã¯ãããåŸãªãããšããããããã®ç
æéã¯ã§ããã ãå°ãªãæ¹ãæ圢æ§ãæµåæ§ã®ç¹
ã§å¥œãŸãããããªãã¡ãã°ã©ããéåæã«äœ¿çšã
ãããã«ç³»åéäœã®å ã°ã©ããçµåã«é¢äžããå²
åãããããã°ã©ããå¹çã¯ããªãªã«ã¬ãã·ãã
ãµã³ãŽã äžã«å ±éåãããŠããã°ã©ãã亀åå€ã®
çš®é¡ã«ãã€ãŠå€§ããå€åãããããäžè¿°ã®åŠãäž
è¬åŒïŒïŒã§è¡šããããïŒã¡ã¿ïŒã¢ã¯ãªãã·ãã
ãµã³ã奜ãŸããã¯ã¡ã¿ã¯ãªããã·ã·ãããµã³ãã°
ã©ãã亀åå€ãšããŠçšããå Žåãã°ã©ããå¹çã
æãé«ãæ圢æ§ãæµåæ§ãåäžããã æ¬çºæã®æš¹èçµæç©ã«ãããŠæå(A)ã(B)åã³(C)
ã¯åºãç¯å²ã®å²åã§çµåãããããšãã§ããããª
ãæ¬çºæã®æš¹èçµæç©ã¯ãå šæš¹èçµæç©ã®ééã
åºã«ããŠãããªããšãã¬ã³ãšãŒãã«æš¹è(A)ã20ã
80ééïŒ ãããªã¹ãã¬ã³æš¹è(B)ã20ã75ééïŒ å
ã³ããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)
ãïŒã40ééïŒ ããæ§æããããã®ã奜ãŸããã æå(A)ã20ééïŒ æªæºã§ã¯èç±æ§ã®ä»äžãäžå
åã§ãªãåŸåã§ãããåã80ééïŒ ãè¶ ããå Žå
ã«ã¯æµåç¹æ§ãæªããªãåŸåãšãªãæ圢æ§ãäœäž
ããåŸåãšãªããåãæå(B)ã20ééïŒ æªæºã§ã¯
æ圢æ§ãšèç±æ§ãšã®ãã©ã³ã¹ããšãããšãå°é£ãš
ãªãåŸåãšãªããåã75ééïŒ ãè¶ ããå Žåã«ã¯
èè¡æãšèç±æ§ãšã®ãã©ã³ã¹ããšãããšãå°é£ãš
ãªãåŸåãšãªããããã«ãæå(C)ãïŒééïŒ æªæº
ã§ã¯èè¡ææ§èœæ¹åå¹æãå åã§ãªãåŸåãšãª
ããåã40ééïŒ ãè¶ ãããšããªãªã«ã¬ãã·ãã
ãµã³ãŽã ã®å«éãé«ããªãæ©æ¢°ç匷床ãäœäžãã
åŸåãšãªã䜿çšã«èãã«ãããªãã æ¬çºæã®æš¹èçµæç©ã¯ãèç±æ§ãèè¡ææ§ãç¹
ã«äœæž©äžã§ã®èè¡ææ§ã«åªããŠããããããæµå
æ§ã«ãåªããåãäžèšæå(A)ãšæå(B)ã®é åæ¯ç
ãå€ããããšã«ããèç±æ§ã®ã¬ãã«ãè¶ èç±æ§æš¹
èããéåžžã®èç±æ§æš¹èã®æ°ŽæºãŸã§èªç±ã«èšèšã§
ãããããã«æå(C)ã®é åæ¯çãå€ããããšã«ã
ãèè¡ææ§ãèªç±ã«èšèšããããšãã§ããã æ¬çºæã®æš¹èçµæç©ã調補ããæ¹æ³ãšããŠã¯æ
å(A)ã(B)åã³(C)ããã³ããªãããµãŒãããŒã«ã
ã«ãäºè»žæŒåºæ©çã®å ¬ç¥ã®è£ 眮ãçšãæ©æ¢°çã«æ··
åããã¬ããç¶ã«è³Šåœ¢ããã°ããã ããã«æ¬çºæã®æš¹èçµæç©ã«ã¯å¿ èŠã«å¿ããŠå®
å®å€ãå¯å¡å€ãæ»å€ãé£çå€ãé¡æãå å¡«å€çã
é åãåŸããå ·äœçã«ã¯ããªããšãã«ãã¹ãã¢ã€
ãçã®å®å®å€ïŒããªãšãã¬ã³ã¯ãã¯ã¹ãããªãã
ãã¬ã³ã¯ãã¯ã¹çã®æ»å€ïŒããªããšãã«ãã¹ããš
ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãçã®ãã¹ããšãŒ
ãç³»é£çå€ããã«ããã¢ãããšãã«ããã«ããã¢
ãããšãã«ãšãŒãã«çã®èçŽ ç³»é£çå€ïŒé žåãã¿
ã³ãç¡«åäºéãé žåäºéçã®é¡æïŒã¬ã©ã¹ç¹ç¶ã
ã¢ã¹ãã¹ãããŠãªã©ã¹ããã€ãããã€ã«ãã¿ã«ã¯
çã®å å¡«å€çãæããããã ãå®æœäŸã 以äžå®æœäŸã«ããæ¬çºæãå ·äœçã«èª¬æããã ãªãåå®æœäŸãæ¯èŒäŸã§ã®è«žç©æ§ã®æž¬å®æ³ã¯äž
èšã®æ¹æ³ã«ããã æ²ã匷床ïŒASTM  790ã®æ¹æ³ã«ããã ã¢ã€ãŸããè¡æ匷床ïŒASTM  256ã®æ¹æ³ã«
ãããïŒ1/4â³ãããä»ïŒ ããã«ãŒãè»å枩床ïŒISO  306ã®æ¹æ³ã«ã
ãã ã¡ã«ãã€ã³ããã¯ã¹ïŒASTM  1238ã®æ¹æ³ã«
æºæ ããæ¹æ³ã«ãããïŒïŒKgã®è·éäž275âã§ã®
枬å®å€ïŒ åèäŸ ïŒ ããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœïŒ³
âïŒã®è£œé ïŒ ãšãã«ãªã«ãœã·ãªã±ãŒãïŒéééšãγâã¡ã¿ã¯
ãªããã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ïŒéé
éšåã³ãªã¯ã¿ã¡ãã«ããã©ã·ã¯ãã·ãããµã³92é
ééšãæ··åããæ··åã·ãããµã³100éééšãåŸãã
ããã·ã«ãã³ãŒã³ã¹ã«ãã³é žãœãŒãåã³ããã·ã«
ãã³ãŒã³ã¹ã«ãã³é žãããããïŒéééšã溶解ã
ãèžçæ°Ž300éééšã«äžèšæ··åã·ãããµã³100éé
éšãå ãããã¢ãããµãŒã«ãŠ10000rpmã§äºåæ¹
æããåŸããã¢ãžãã€ã¶ãŒã«ãã300KgïŒcm2ã®å§
åã§ïŒåéãããšã«ããä¹³åãåæ£ããããªã«ã¬
ãã·ãããµã³ã©ããã¯ã¹ãåŸãããã®æ··å液ãã
ã³ã³ãã³ãµãŒåã³æ¹æç¿Œãåããã»ãã©ãã«ãã©
ã¹ã³ã«ç§»ããæ¹ææ··åããªãã80âã§ïŒæéå ç±
ããåŸ10âã§20æéå·åŽããã次ãã§æ°Žé žåãã
ãªãŠã 氎溶液ã§ãã®ã©ããã¯ã¹ã®PHã6.9ã«äžå
ããéåãå®çµãããåŸãããããªãªã«ã¬ãã·ã
ããµã³ãŽã ã®éåçã¯90.8ïŒ ãèšæœ€åºŠã¯6.8ã§ã
ããããªãªã«ã¬ãã·ãããµã³ãŽã ã®ç²ååŸã¯
0.14ÎŒïœã§ãã€ãã åŸãããããªãªã«ã¬ãã·ãããµã³ãŽã ã©ããã¯
ã¹264éééšãæ¹æåšãåããã»ãã©ãã«ãã©ã¹
ã³ã«å ¥ããçªçŽ 眮æãããŠãã80âã«ææž©ããã
ã®åŸã¹ãã¬ã³40éééšåã³ã¿ãŒã·ã€ãªãŒããã«ã
ãŒãªããµã€ã0.16éééšã®æ··å溶液ãä»èŸŒã¿30å
éæ¹æãããããã«ãã³ã¬ãªãã0.2éééšãç¡«
é žç¬¬ïŒé0.0004éééšããšãã¬ã³ãžã¢ãã³åé ¢é ž
äºãããªãŠã å¡©0.0008éééšåã³èžçæ°ŽïŒéééš
ã®æ··å溶液ãä»èŸŒã¿ã©ãžã«ã«éåãéå§ãããïŒ
æéåå¿æž©åºŠãç¶æããåŸå·åŽãéåãçµäºã
ããã°ã©ããéåæã®ã¹ãã¬ã³ã®éåçã¯92ïŒ ã§
ãããååŸãããã°ã©ããå ±éåäœã®ã°ã©ããç
ã¯52ïŒ ãã°ã©ããå¹çã¯78ïŒ ã§ãã€ããåŸããã
ã©ããã¯ã¹ããå¡©åã«ã«ã·ãŠã 1.5ééïŒ æ¿åºŠã®
ç±æ°Ž456éééšäžã«æ»Žäžããããšã«ããéåäœã
ååºãåé¢ããæŽæµããåŸ75âã§10æé也ç¥ããŠ
æ°Žåãé€å»ããã°ã©ããå ±éåäœã®ä¹Ÿç²ïŒ³âïŒã
åŸãã åèäŸ ïŒ ããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœïŒ³
âïŒãâïŒã®è£œé ïŒ åèäŸïŒã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éå
ã«ãããŠã°ã©ãã亀åå€ãšããŠÎ³âã¡ã¿ã¯ãªãã
ã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ã®ä»£ãã«Î³â
ã¡ã«ã«ãããããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ïŒé
ééšãããã©ã¡ãã«ããã©ããã«ã·ã¯ãã·ãããµ
ã³ïŒéééšåã³Î³âã¡ã¿ã¯ãªããã·ãããã«ããª
ã¡ããã·ã·ã©ã³ïŒéééšãããããçšãã以å€ã¯
åèäŸïŒãšåæ§ã®æ¹æ³ã§ããªãªã«ã¬ãã·ãããµã³
ãŽã ã®éååã³ã°ã©ããéåãè¡ããã°ã©ããå ±
éåäœã®ä¹Ÿç²ïŒ³âïŒãâïŒãããããåŸããã
ãªãªã«ã¬ãã·ãããµã³ãŽã ã®éååã³ã°ã©ããé
åã®è«žç¹æ§ã第ïŒè¡šã«ç€ºãã
æ§åã³æµåæ§çã«åªããããªããšãã¬ã³ãšãŒãã«
æš¹èçµæç©ãããã«è©³ããã¯ããªããšãã¬ã³ãšãŒ
ãã«æš¹èãããªã¹ãã¬ã³æš¹èåã³ç¹å®ã®ããªãªã«
ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœããæ§æãã
ãããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã«é¢ããã
ã®ã§ããã ãåŸæ¥ã®æè¡ã ããªããšãã¬ã³ãšãŒãã«æš¹èã¯èç±æ§ãåæ§ç
ã«åªãããããšã³ãžãã¢ãªã³ã°ãã©ã¹ããã¯ãšã
ãŠã®çšéãæ¡å€§ããŠããããèè¡ææ§ã«è¥å¹²å£ã
ããšãããã®çšéãå¶éãããŠããã ããªããšãã¬ã³ãšãŒãã«æš¹èã®èè¡ææ§ãæ¹å
ããæ¹æ³ãšããŠãããªãã¿ãžãšã³ç³»ãšã©ã¹ãããŒ
ãé åããæ¹æ³ãç¹å ¬æ47â32731å·å ¬å ±ãç¹é
æ46â2345å·å ¬å ±çã«é瀺ãããŠãããããããª
ããããããæ¹æ³ã«ããå Žåã¯ããªãã¿ãžãšã³ç³»
ãšã©ã¹ãããŒäžã«äžé£œåçµåãæ®åããããç±ç
ã«äžå®å®ã§ãããå®çšçã«æçšãªç±å®å®æ§ã«åªã
ããã®ãåŸãããªãã åãããªããšãã¬ã³ãšãŒãã«æš¹èã«ãšãã¬ã³â
ãããã¬ã³å ±éåäœã®ãããªããªãªã¬ãã€ã³ãé
åããããšã«ããããªããšãã¬ã³ãšãŒãã«æš¹èã®
æ圢å å·¥æ§ãèè¡ææ§ãåäžãããæ¹æ³ãç±³åœç¹
蚱第336185å·æ现æžãç¹å ¬æ42â7069å·å ¬å ±çã«
é瀺ãããŠãããããããªããããããæ¹æ³ã«ã
ãå Žåã«ã¯ããªãªã¬ãã€ã³ã®é åéã10ééïŒ ä»¥
äžãšãããšãããªããšãã¬ã³ãšãŒãã«æš¹èãšããª
ãªã¬ãã€ã³ãšã®çžæº¶æ§ãæªãããæ圢åãšããå Ž
åå±€ç¶å¥é¢ãçããããã«ãªãè¡šé¢å€èŠ³ãæªãã
ãããèè¡ææ§ã®åäžçšåºŠãããçšé¡èã§ã¯ãª
ãã ããã«ãäžèšããªãªã¬ãã€ã³ãé åããæ¹æ³ã®
æ¹è¯æ³ãšããŠãã¹ãã¬ã³ç³»åéäœãããªãªã¬ãã€
ã³ã«ã°ã©ããéåãããããªãªã¬ãã€ã³ç³»ã°ã©ã
ãå ±éåäœãããªããšãã¬ã³ãšãŒãã«æš¹èãé å
ããããšã«ãã€ãŠããªããšãã¬ã³ãšãŒãã«æš¹èã®
åæ§ãæ©æ¢°ç匷床ãç¶æãã€ã€æ圢å å·¥æ§ãæ¹è¯
ããããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ãç¹éæ
49â75663å·å ¬å ±ã«é瀺ãããŠãããããããªã
ãããããæ¹æ³ã«ããå Žåã§ã¯å åãªèè¡ææ§ã®
æ¹è¯ããªãããŠããªãã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæè ãã¯ããªããšãã¬ã³ãšãŒãã«æš¹èæ¬æ¥
ã®åªããèç±æ§ãæ©æ¢°ç匷床ããã®ãŸãŸä¿æãã
ãã€èè¡ææ§ãæ¹åããæ¹æ³ã«ã€ããŠéææ€èšã
ãçµæãããªãªã«ã¬ãã·ãããµã³ãŽã ã«ããã«ç³»
åéäœãé«å¹çã§ã°ã©ããéåãããããªãªã«ã¬
ãã·ãããµã³ç³»ã°ã©ããå ±éåäœãããªããšãã¬
ã³ãšãŒãã«æš¹èãšããªã¹ãã¬ã³æš¹èãšçµåããŠé
åããããšã«ããããããåæš¹èéã®çžæº¶æ§ãè¯
奜ã§ãæ圢åãšããå Žåã«å±€ç¶å¥é¢ãçããããš
ããªãããããèè¡ææ§ãèããæ¹åã§ãããã€
èç±æ§åã³æ©æ¢°ç匷床ãæ圢æ§ãªãã³ã«æµåæ§ã
åªããæš¹èçµæç©ãšãåŸãããšãèŠãåºãæ¬çºæ
ã«å°éããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæã¯ãããªããšãã¬ã³ãšãŒãã«æš¹è(A)ãã
ãªã¹ãã¬ã³æš¹è(B)åã³ãã«ãšã³æº¶åªäžã§æž¬å®ãã
èšæœ€åºŠãïŒã15ã§ããããã€ã°ã©ãã亀åå€ãå«
æããããªãªã«ã¬ãã·ãããµã³ãŽã ã«ïŒçš®åã¯ïŒ
皮以äžã®ããã«ç³»åéäœãã°ã©ããéåãããã
ãªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)ãã
æ§æãããããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã§
ããã æ¬çºæã«ãããŠçšããããããªããšãã¬ã³ãšãŒ
ãã«æš¹è(A)ãšã¯äžèšäžè¬åŒã§è¡šããããåç¬éå
äœåã¯å ±éåäœã§ããã ïŒåŒäžQ1ãQ4ã¯æ°ŽçŽ ãçåæ°ŽçŽ åºãããªã矀ã
ãããããç¬ç«ã«éžæãããïœã¯30以äžã®æ°ã瀺
ããïŒ ãããããªããšãã¬ã³ãšãŒãã«æš¹èã®å ·äœäŸãš
ããŠã¯ããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšã
ã¬ã³ïŒãšãŒãã«ãããªïŒïŒïŒïŒâãžãšãã«âïŒïŒ
ïŒâããšãã¬ã³ïŒãšãŒãã«ãããªïŒïŒïŒïŒâãžã
ããã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãããª
ïŒïŒâã¡ãã«âïŒâãšãã«âïŒïŒïŒâããšãã¬ã³ïŒ
ãšãŒãã«ãããªïŒïŒâã¡ãã«âïŒâãããã«â
ïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãããªïŒïŒâãšã
ã«âïŒâãããã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒã
ã«ãïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒ
ãšãŒãã«ãšïŒïŒïŒïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ïŒãšãŒãã«ã®å ±éåäœãïŒïŒïŒïŒâãž
ãšãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãšïŒïŒïŒ
ïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒ
ãã«ã®å ±éåäœãïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâ
ããšãã¬ã³ïŒãšãŒãã«ãšïŒïŒïŒïŒïŒïŒâããªãšã
ã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ã®å ±éåäœç
ãæãããããç¹ã«ããªïŒïŒïŒïŒâãžã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãåã³ïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ãš
ïŒïŒïŒïŒïŒïŒâããªã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒ
ãšãŒãã«ã®å ±éåäœã奜ãŸãããããã«å¥œãŸãã
ã¯ããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬
ã³ïŒãšãŒãã«ã§ããããããããªããšãã¬ã³ãšãŒ
ãã«æš¹èã¯ããããé åæ¯çã®äžã§ããªã¹ãã¬ã³
æš¹èãšçžæº¶åãããæ¬çºæã«ãããŠçšããããã
ãªããšãã¬ã³ãšãŒãã«æš¹èã®éå床ã¯ç¹ã«å¶éã
ãããã®ã§ã¯ãªããã25âã¯ãããã«ã 溶åªäžã§
ã®éå ç²åºŠã0.3ã0.7dlïŒïœã®ãã®ã奜ãŸããçš
ããããã0.3dlïŒïœæªæºã®éå ç²åºŠã®ãã®ã§ã¯
ç±å®å®æ§ãæªããªãåŸåã§ãããå0.7dlïŒïœã
è¶ ããéå ç²åºŠã®ãã®ã§ã¯æ圢æ§ãæãªãããåŸ
åãšãªãããããã®ããªããšãã¬ã³ãšãŒãã«æš¹è
ã¯åç¬ã§åã¯ïŒçš®ä»¥äžæ··åããŠçšããããã åãæ¬çºæã«ãããŠçšããããããªã¹ãã¬ã³æš¹
è(B)ãšã¯äžèšäžè¬åŒã§è¡šããããè³éŠæããã«ç³»
åéäœåäœã50ééïŒ ä»¥äžããæ§æãããåç¬é
åäœåã¯ä»ã®å ±éåå¯èœãªããã«ç³»åéäœãšã®å ±
éåäœã§ããã ïŒåŒäžïŒ¹ã¯æ°ŽçŽ åååã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«
ãã«åºãã¯ããã²ã³åååã¯ççŽ ååæ°ïŒãïŒ
ã®ã¢ã«ãã«åºãïœã¯ïŒåã¯ïŒãïŒã®æ°ã瀺ããïŒ ãããããªã¹ãã¬ã³æš¹èã®å ·äœäŸãšããŠã¯ããª
ã¹ãã¬ã³ãããªã¯ãã«ã¹ãã¬ã³ãããªÎ±âã¡ãã«
ã¹ãã¬ã³ãã¹ãã¬ã³âã¢ã¯ãªããããªã«å ±éå
äœãã¹ãã¬ã³âã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±éåäœã
ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãã¹ãã¬ã³â
ãã¬ã€ããå ±éåäœãã¹ãã¬ã³ââããšãã«ã
ã¬ã€ããå ±éåäœãã¹ãã¬ã³âã¢ã¯ãªããããªã«
âαâã¡ãã«ã¹ãã¬ã³äžå å ±éåäœçãæããã
ããããªã¹ãã¬ã³ãç¹ã«å¥œãŸãããã®ã§ããã ããã«ãæ¬çºæã«ãããŠçšããããããªãªã«ã¬
ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)ãšã¯ãã«ãšã³
溶åªäžã§æž¬å®ããèšæœ€åºŠãïŒã15ã§ããããã€ã°
ã©ãã亀åå€ãå ±éåãããããªãªã«ã¬ãã·ãã
ãµã³ãŽã ã«ïŒçš®åã¯ïŒçš®ä»¥äžã®ããã«ç³»åéäœã
ã°ã©ããéåããããã®ã§ããããã®ããªãªã«ã¬
ãã·ãããµã³ç³»ã°ã©ããå ±éåäœäžã®ããªãªã«ã¬
ãã·ãããµã³ãŽã ã®å«æéã¯ïŒã90ééïŒ ã®ç¯å²
ã§ãããã®ã奜ãŸãããããã«ããªãªã«ã¬ãã·ã
ããµã³ãŽã ã¯ãªã«ã¬ãã·ãããµã³ãšã°ã©ãã亀å
å€åã³æ¶æ©å€ã®ïŒæåããæ§æããããã®ã§ã
ãã ããªãªã«ã¬ãã·ãããµã³ãŽã ãæ§æãããªã«ã¬
ãã·ãããµã³ãšããŠã¯ãäŸãã°ãããµã¡ãã«ããª
ã·ã¯ãã·ãããµã³ããªã¯ã¿ã¡ãã«ããã©ã·ã¯ãã·
ãããµã³ããã«ã¡ãã«ãã³ã¿ã·ã¯ãã·ãããµã³ã
ããã«ã¡ãã«ãããµã·ã¯ãã·ãã·ãµã³ãããªã¡ã
ã«ããªããšãã«ããªã·ã¯ãã·ãããµã³ãããã©ã¡
ãã«ããã©ããšãã«ããã©ã·ã¯ãã·ãããµã³ããª
ã¯ã¿ããšãã«ããã©ã·ã¯ãã·ãããµã³çãæãã
ãããããã¯åç¬ã§åã¯ïŒçš®ä»¥äžæ··åããŠçšãã
ããããããã®äœ¿çšéã¯ããªãªã«ã¬ãã·ãããµã³
ãŽã äž50ééïŒ ä»¥äžã奜ãŸããã¯70ééïŒ ä»¥äžã§
ããã ã°ã©ãã亀åå€ãšããŠã¯ãäžè¬åŒ CH2ïŒCHâSiR1 oO(3-o)/2 ïŒïŒ å㯠HSâïŒCH2âïŒpSiR1 oO(3-o)/2 ïŒïŒ ïŒååŒäžR1ã¯ã¡ãã«åºããšãã«åºããããã«åº
åã¯ããšãã«åºãR2ã¯æ°ŽçŽ åååã¯ã¡ãã«åºã
ïœã¯ïŒãïŒåã¯ïŒãïœã¯ïŒãïŒã®æ°ã瀺ããïŒ ã§è¡šãããããªã«ã¬ãã·ãããµã³ååç©çãçšã
ããããäžè¬åŒïŒïŒã®ïŒã¡ã¿ïŒã¢ã¯ãªããã·ã·
ãããµã³ã¯ã°ã©ããå¹çãé«ãçºæå¹ãªã°ã©ãã
éã圢æããããšãå¯èœã§ããèè¡ææ§çºçŸã®ç¹
ã§æå©ã§ããããªãäžè¬åŒïŒïŒã®å ã¡ã¿ã¯ãªã
ãã·ã·ãããµã³ãç¹ã«å¥œãŸãããã®ã§ããã ã°ã©ãã亀åå€ã®äœ¿çšéã¯ãããªãªã«ã¬ãã·ã
ããµã³ãŽã äž0.1ã20ééïŒ ã奜ãŸããã¯0.1ã10
ééïŒ ã§ããã ããã«æ¶æ©å€ãšããŠã¯ãïŒå®èœæ§åã¯ïŒå®èœæ§
ã®ã·ãããµã³ç³»æ¶æ©å€ãäŸãã°ããªã¡ããã·ã¡ã
ã«ã·ã©ã³ãããªãšããã·ããšãã«ã·ã©ã³ãã¡ãã«
ãªã«ãœã·ãªã±ãŒãããšãã«ãªã«ãœã·ãªã±ãŒããã
ãã«ãªã«ãœã·ãªã±ãŒãçãçšãããããæ¶æ©å€ã®
䜿çšéã¯ããªãªã«ã¬ãã·ãããµã³ãŽã äž0.2ã30
ééïŒ ã§ããããã®äœ¿çšéã¯ããªãªã«ã¬ãã·ãã
ãµã³ãŽã ã®èšæœ€åºŠïŒããªãªã«ã¬ãã·ãããµã³ãŽã
ããã«ãšã³æº¶åªäžã§25âã§é£œåãããšããããªãª
ã«ã¬ãã·ãããµã³ãŽã ãåžåããŠãããã«ãšã³ã®
ééå²åïŒãïŒã15ã®ç¯å²ã«ãªãããã«èª¿æŽãã
ãã¹ãã§ãããèšæœ€åºŠãïŒæªæºã§ã¯æ¶æ©å€éãå€
ããªãéããŠãŽã 匟æ§ãåŸãããªããªãããŸãèš
最床ã15ãè¶ ãããšãã°ã©ããå ±éåäœäžã§ãŽã
圢æ ãä¿æã§ããªããªãèè¡ææ§ãä»äžã§ããã
ããªããšãã¬ã³ãšãŒãã«æš¹èã«é åããŠããã å
ã«ããªãªã«ã¬ãã·ãããµã³ãªã€ã«ãæ·»å ããã®ãš
åçã®ç¡¬åããåŸãããªãã ãªãèšæœ€åºŠã®æž¬å®ã¯æ¬¡ã®ããã«ããŠè¡ããããª
ãã¡ãéåããŠåŸãããªãªã«ã¬ãã·ãããµã³ãŽã
ãã©ãã¯ã¹ãçŽïŒãïŒåéã®ã€ãœãããã«ã¢ã«ã³
ãŒã«äžã«æ¹æããªããæ·»å ãããšãã«ãžãšã³ãç Ž
å£ãååºããããšã«ããã·ãããµã³ããªããŒãåŸ
ããåŸãããªããŒãæ°ŽæŽããåŸã80âã§10æéæž
å§ä¹Ÿç¥ããã也ç¥åŸãçŽïŒïœã®ããªããŒã粟秀
ããçŽ30ïœã®ãã«ãšã³äžã«æµžæŒ¬ãã25âã§100æ
éæŸçœ®ãèšæœ€ãããã次ãã§æ®äœã®ãã«ãšã³ãã
ã«ã³ããŒã·ãšã³ã«ããåé¢é€å»ãã粟秀ããåŸã
80âã§16æéæžå§ä¹Ÿç¥ããåžåããããã«ãšã³ã
èžçºé€å»ããåã³ç²Ÿç§€ãããèšæœ€åºŠã¯æ¬¡åŒã«ãã
ç®åºãããã èšæœ€åºŠïŒïŒèšæœ€ããããªããŒéé
ïŒâïŒä¹Ÿç¥ããªããŒééïŒïŒïŒä¹Ÿç¥ããªããŒééïŒ ãã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éåã¯ãç±³
åœç¹èš±ç¬¬2891920å·æ现æžãå第3294725å·æ现æž
çã«èšèŒãããŠããæ¹æ³ãããªãã¡ãªã«ã¬ãã·ã
ããµã³ãšã°ã©ãã亀åå€åã³æ¶æ©å€ã®æ··å溶液
ããã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³é žãã¢ã«ãã«ã¹ã«
ãã³é žçã®ä¹³åå€ã®ååšäžã§æ°Žãšåªææ··åããæ¹
æ³ã«ãã補é ããããšã奜ãŸãããã¢ã«ãã«ãã³
ãŒã³ã¹ã«ãã³é žã¯ãªã«ã¬ãã·ãããµã³ã®ä¹³åå€ãš
ããŠäœçšãããšåæã«éåéå§å€ãšããªãã®ã§å¥œ
é©ã§ããããã®éãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³é ž
éå±å¡©ãã¢ã«ãã«ã¹ã«ãã³é žéå±å¡©çã䜵çšãã
ãšã°ã©ããéåãè¡ãéã«ããªããŒãå®å®ã«ç¶æ
ããã®ã«å¹æãããã®ã§å¥œãŸããã ãã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã«ã°ã©ããé
åãããããã«ç³»åéäœãšããŠã¯ãã¹ãã¬ã³ãα
âã¡ãã«ã¹ãã¬ã³ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâ
ãšãã«ããã·ã«ã¡ã¿ã¯ãªã¬ãŒããã¡ãã«ã¢ã¯ãªã¬
ãŒãããšãã«ã¢ã¯ãªã¬ãŒããããã«ã¢ã¯ãªã¬ãŒ
ããã¢ã¯ãªããããªã«ãã¡ã¿ã¯ãªããããªã«çã®
è³éŠæã¢ã«ã±ãã«ååç©ãã¡ã¿ã¯ãªã«é žãšã¹ã
ã«ãã¢ã¯ãªã«é žãšã¹ãã«çã®åçš®ã®ããã«ç³»åé
äœãæãããããããã¯åç¬ã§åã¯ïŒçš®ä»¥äžçµå
ããŠçšããããããããããã«ç³»åéäœã®å ã¹ã
ã¬ã³ãç¹ã«å¥œãŸããã äžèšããã«ç³»åéäœãšããªãªã«ã¬ãã·ãããµã³
ãŽã ãšã®å²åã¯ãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœã®ééã«åºã¥ãããªãªã«ã¬ãã·ãã
ãµã³ãŽã ïŒã90ééïŒ ãããã«ç³»åéäœ95ã10é
éïŒ ã§ãããããªãªã«ã¬ãã·ãããµã³ãŽã ãïŒé
éïŒ æªæºã§ã¯æ¬çºæã®æš¹èçµæç©ã®èè¡ææ§æ¹è¯
ã®å¹æãå åã§ãªããåã90ééïŒ ãè¶ ãããšã°
ã©ããã®å¹æãçºæ®ã§ããªããªãã®ã§å¥œãŸãããª
ãã ãããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±é
åäœã¯ãéåžžã®ä¹³åéåæ³ã«ãã€ãŠè£œé ããããš
ãã§ãããããªãã¡ãããªãªã«ã¬ãã·ãããµã³ãŽ
ã ã©ããã¯ã¹ãã¢ã«ã«ãªã«ããäžåããåŸãäžèš
ããã«ç³»åéäœãã©ãžã«ã«éåæè¡ã«ãã€ãŠäžæ®µ
ãããã¯å€æ®µã§éåããããšã«ããåŸãããšãã§
ããã ãã®ããã«ããŠåŸãããããªãªã«ã¬ãã·ãããµ
ã³ç³»ã°ã©ããå ±éåäœã©ããã¯ã¹ã¯å¡©åã«ã«ã·ãŠ
ã åã¯ç¡«é žãã°ãã·ãŠã çã®éå±å¡©ã溶解ããç±
æ°Žäžã«è©²ã©ããã¯ãæå ¥ããå¡©æãååºããããš
ã«ããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éå
äœãåé¢ãååããããšãã§ããã ãããåŸä¹Ÿç¥ããŠåŸãããªãªã«ã¬ãã·ãããµã³
ç³»ã°ã©ããå ±éåäœã¯ãã°ã©ããéåæã«æŽŸçã
ãã°ã©ããéåçšããã«ç³»åéäœã®ããªãŒã®éå
äœãšããªãªã«ã¬ãã·ãããµã³ãŽã ã«çµåããã°ã©
ããããªããŒãšã®æ··åç©ã§ããããã®ããªãªã«ã¬
ãã·ãããµã³ãŽã ãžã®ã°ã©ããããªããŒã®çµåå²
åãããªãã¡ã°ã©ããçã¯ããªããšãã¬ã³ãšãŒã
ã«æš¹èã®èè¡ææ§èœãçºçŸããã®ã«éèŠãªå åãš
ãªããããªãã¡ãã°ã©ããéã«ããããªããšãã¬
ã³ãšãŒãã«æš¹èåã³ããªã¹ãã¬ã³æš¹èãšããªãªã«
ã¬ãã·ãããµã³ãŽã ãšã®èŠªåãèšããã®ã§ããã
åŸã€ãŠã°ã©ããçã¯10ïŒ ä»¥äžã奜ãŸããã¯30ïŒ ä»¥
äžã§ããããšããããåãã°ã©ããéåã«çšãã
ããã«ç³»åéäœã¯äžè¿°ã®åŠãåçš®ããã«ç³»åéäœ
ãåç¬ã§åã¯ïŒçš®ä»¥äžçµåããŠçšããããšãã§ã
ããã¹ãã¬ã³ãçšããã®ã奜ãŸããã äžæ¹ãã°ã©ããéåæã«ããªãªã«ã¬ãã·ãããµ
ã³ãŽã ã«çµåããŠããªãããªãŒã®éåäœãäžéšç
æããããšã¯ãããåŸãªãããšããããããã®ç
æéã¯ã§ããã ãå°ãªãæ¹ãæ圢æ§ãæµåæ§ã®ç¹
ã§å¥œãŸãããããªãã¡ãã°ã©ããéåæã«äœ¿çšã
ãããã«ç³»åéäœã®å ã°ã©ããçµåã«é¢äžããå²
åãããããã°ã©ããå¹çã¯ããªãªã«ã¬ãã·ãã
ãµã³ãŽã äžã«å ±éåãããŠããã°ã©ãã亀åå€ã®
çš®é¡ã«ãã€ãŠå€§ããå€åãããããäžè¿°ã®åŠãäž
è¬åŒïŒïŒã§è¡šããããïŒã¡ã¿ïŒã¢ã¯ãªãã·ãã
ãµã³ã奜ãŸããã¯ã¡ã¿ã¯ãªããã·ã·ãããµã³ãã°
ã©ãã亀åå€ãšããŠçšããå Žåãã°ã©ããå¹çã
æãé«ãæ圢æ§ãæµåæ§ãåäžããã æ¬çºæã®æš¹èçµæç©ã«ãããŠæå(A)ã(B)åã³(C)
ã¯åºãç¯å²ã®å²åã§çµåãããããšãã§ããããª
ãæ¬çºæã®æš¹èçµæç©ã¯ãå šæš¹èçµæç©ã®ééã
åºã«ããŠãããªããšãã¬ã³ãšãŒãã«æš¹è(A)ã20ã
80ééïŒ ãããªã¹ãã¬ã³æš¹è(B)ã20ã75ééïŒ å
ã³ããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)
ãïŒã40ééïŒ ããæ§æããããã®ã奜ãŸããã æå(A)ã20ééïŒ æªæºã§ã¯èç±æ§ã®ä»äžãäžå
åã§ãªãåŸåã§ãããåã80ééïŒ ãè¶ ããå Žå
ã«ã¯æµåç¹æ§ãæªããªãåŸåãšãªãæ圢æ§ãäœäž
ããåŸåãšãªããåãæå(B)ã20ééïŒ æªæºã§ã¯
æ圢æ§ãšèç±æ§ãšã®ãã©ã³ã¹ããšãããšãå°é£ãš
ãªãåŸåãšãªããåã75ééïŒ ãè¶ ããå Žåã«ã¯
èè¡æãšèç±æ§ãšã®ãã©ã³ã¹ããšãããšãå°é£ãš
ãªãåŸåãšãªããããã«ãæå(C)ãïŒééïŒ æªæº
ã§ã¯èè¡ææ§èœæ¹åå¹æãå åã§ãªãåŸåãšãª
ããåã40ééïŒ ãè¶ ãããšããªãªã«ã¬ãã·ãã
ãµã³ãŽã ã®å«éãé«ããªãæ©æ¢°ç匷床ãäœäžãã
åŸåãšãªã䜿çšã«èãã«ãããªãã æ¬çºæã®æš¹èçµæç©ã¯ãèç±æ§ãèè¡ææ§ãç¹
ã«äœæž©äžã§ã®èè¡ææ§ã«åªããŠããããããæµå
æ§ã«ãåªããåãäžèšæå(A)ãšæå(B)ã®é åæ¯ç
ãå€ããããšã«ããèç±æ§ã®ã¬ãã«ãè¶ èç±æ§æš¹
èããéåžžã®èç±æ§æš¹èã®æ°ŽæºãŸã§èªç±ã«èšèšã§
ãããããã«æå(C)ã®é åæ¯çãå€ããããšã«ã
ãèè¡ææ§ãèªç±ã«èšèšããããšãã§ããã æ¬çºæã®æš¹èçµæç©ã調補ããæ¹æ³ãšããŠã¯æ
å(A)ã(B)åã³(C)ããã³ããªãããµãŒãããŒã«ã
ã«ãäºè»žæŒåºæ©çã®å ¬ç¥ã®è£ 眮ãçšãæ©æ¢°çã«æ··
åããã¬ããç¶ã«è³Šåœ¢ããã°ããã ããã«æ¬çºæã®æš¹èçµæç©ã«ã¯å¿ èŠã«å¿ããŠå®
å®å€ãå¯å¡å€ãæ»å€ãé£çå€ãé¡æãå å¡«å€çã
é åãåŸããå ·äœçã«ã¯ããªããšãã«ãã¹ãã¢ã€
ãçã®å®å®å€ïŒããªãšãã¬ã³ã¯ãã¯ã¹ãããªãã
ãã¬ã³ã¯ãã¯ã¹çã®æ»å€ïŒããªããšãã«ãã¹ããš
ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãçã®ãã¹ããšãŒ
ãç³»é£çå€ããã«ããã¢ãããšãã«ããã«ããã¢
ãããšãã«ãšãŒãã«çã®èçŽ ç³»é£çå€ïŒé žåãã¿
ã³ãç¡«åäºéãé žåäºéçã®é¡æïŒã¬ã©ã¹ç¹ç¶ã
ã¢ã¹ãã¹ãããŠãªã©ã¹ããã€ãããã€ã«ãã¿ã«ã¯
çã®å å¡«å€çãæããããã ãå®æœäŸã 以äžå®æœäŸã«ããæ¬çºæãå ·äœçã«èª¬æããã ãªãåå®æœäŸãæ¯èŒäŸã§ã®è«žç©æ§ã®æž¬å®æ³ã¯äž
èšã®æ¹æ³ã«ããã æ²ã匷床ïŒASTM  790ã®æ¹æ³ã«ããã ã¢ã€ãŸããè¡æ匷床ïŒASTM  256ã®æ¹æ³ã«
ãããïŒ1/4â³ãããä»ïŒ ããã«ãŒãè»å枩床ïŒISO  306ã®æ¹æ³ã«ã
ãã ã¡ã«ãã€ã³ããã¯ã¹ïŒASTM  1238ã®æ¹æ³ã«
æºæ ããæ¹æ³ã«ãããïŒïŒKgã®è·éäž275âã§ã®
枬å®å€ïŒ åèäŸ ïŒ ããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœïŒ³
âïŒã®è£œé ïŒ ãšãã«ãªã«ãœã·ãªã±ãŒãïŒéééšãγâã¡ã¿ã¯
ãªããã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ïŒéé
éšåã³ãªã¯ã¿ã¡ãã«ããã©ã·ã¯ãã·ãããµã³92é
ééšãæ··åããæ··åã·ãããµã³100éééšãåŸãã
ããã·ã«ãã³ãŒã³ã¹ã«ãã³é žãœãŒãåã³ããã·ã«
ãã³ãŒã³ã¹ã«ãã³é žãããããïŒéééšã溶解ã
ãèžçæ°Ž300éééšã«äžèšæ··åã·ãããµã³100éé
éšãå ãããã¢ãããµãŒã«ãŠ10000rpmã§äºåæ¹
æããåŸããã¢ãžãã€ã¶ãŒã«ãã300KgïŒcm2ã®å§
åã§ïŒåéãããšã«ããä¹³åãåæ£ããããªã«ã¬
ãã·ãããµã³ã©ããã¯ã¹ãåŸãããã®æ··å液ãã
ã³ã³ãã³ãµãŒåã³æ¹æç¿Œãåããã»ãã©ãã«ãã©
ã¹ã³ã«ç§»ããæ¹ææ··åããªãã80âã§ïŒæéå ç±
ããåŸ10âã§20æéå·åŽããã次ãã§æ°Žé žåãã
ãªãŠã 氎溶液ã§ãã®ã©ããã¯ã¹ã®PHã6.9ã«äžå
ããéåãå®çµãããåŸãããããªãªã«ã¬ãã·ã
ããµã³ãŽã ã®éåçã¯90.8ïŒ ãèšæœ€åºŠã¯6.8ã§ã
ããããªãªã«ã¬ãã·ãããµã³ãŽã ã®ç²ååŸã¯
0.14ÎŒïœã§ãã€ãã åŸãããããªãªã«ã¬ãã·ãããµã³ãŽã ã©ããã¯
ã¹264éééšãæ¹æåšãåããã»ãã©ãã«ãã©ã¹
ã³ã«å ¥ããçªçŽ 眮æãããŠãã80âã«ææž©ããã
ã®åŸã¹ãã¬ã³40éééšåã³ã¿ãŒã·ã€ãªãŒããã«ã
ãŒãªããµã€ã0.16éééšã®æ··å溶液ãä»èŸŒã¿30å
éæ¹æãããããã«ãã³ã¬ãªãã0.2éééšãç¡«
é žç¬¬ïŒé0.0004éééšããšãã¬ã³ãžã¢ãã³åé ¢é ž
äºãããªãŠã å¡©0.0008éééšåã³èžçæ°ŽïŒéééš
ã®æ··å溶液ãä»èŸŒã¿ã©ãžã«ã«éåãéå§ãããïŒ
æéåå¿æž©åºŠãç¶æããåŸå·åŽãéåãçµäºã
ããã°ã©ããéåæã®ã¹ãã¬ã³ã®éåçã¯92ïŒ ã§
ãããååŸãããã°ã©ããå ±éåäœã®ã°ã©ããç
ã¯52ïŒ ãã°ã©ããå¹çã¯78ïŒ ã§ãã€ããåŸããã
ã©ããã¯ã¹ããå¡©åã«ã«ã·ãŠã 1.5ééïŒ æ¿åºŠã®
ç±æ°Ž456éééšäžã«æ»Žäžããããšã«ããéåäœã
ååºãåé¢ããæŽæµããåŸ75âã§10æé也ç¥ããŠ
æ°Žåãé€å»ããã°ã©ããå ±éåäœã®ä¹Ÿç²ïŒ³âïŒã
åŸãã åèäŸ ïŒ ããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœïŒ³
âïŒãâïŒã®è£œé ïŒ åèäŸïŒã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éå
ã«ãããŠã°ã©ãã亀åå€ãšããŠÎ³âã¡ã¿ã¯ãªãã
ã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ã®ä»£ãã«Î³â
ã¡ã«ã«ãããããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ïŒé
ééšãããã©ã¡ãã«ããã©ããã«ã·ã¯ãã·ãããµ
ã³ïŒéééšåã³Î³âã¡ã¿ã¯ãªããã·ãããã«ããª
ã¡ããã·ã·ã©ã³ïŒéééšãããããçšãã以å€ã¯
åèäŸïŒãšåæ§ã®æ¹æ³ã§ããªãªã«ã¬ãã·ãããµã³
ãŽã ã®éååã³ã°ã©ããéåãè¡ããã°ã©ããå ±
éåäœã®ä¹Ÿç²ïŒ³âïŒãâïŒãããããåŸããã
ãªãªã«ã¬ãã·ãããµã³ãŽã ã®éååã³ã°ã©ããé
åã®è«žç¹æ§ã第ïŒè¡šã«ç€ºãã
ãè¡šã
åèäŸ ïŒ
ããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå
±éåäœïŒ³
âïŒãâïŒã®è£œé ïŒ åèäŸïŒã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éå
ã«ãããŠã°ã©ãã亀åå€ãšããŠäœ¿çšããγâã¡ã¿
ã¯ãªããã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ã®äœ¿
çšéãïŒéééšã«åºå®ããæ¶æ©å€ãšããŠäœ¿çšãã
ãšãã«ãªã«ãœã·ãªã±ãŒãã®äœ¿çšéã第ïŒè¡šã«ç€ºã
ããã«çš®ã å€æŽãããšãã«ãªã«ãœã·ãªã±ãŒãã®ãª
ã¯ã¿ã¡ãã«ããã©ã·ã¯ãã·ãããµã³ã®åã98éé
éšãšãªãããã«ãããã調æŽããŠäœ¿çšãã以å€ã¯
åèäŸïŒãšåæ§ã®æ¹æ³ã§ããªãªã«ã¬ãã·ãããµã³
ãŽã ã®éååã³ã°ã©ããéåãè¡ããã°ã©ããå ±
éåäœã®ä¹Ÿç²ïŒ³âïŒãâïŒãããããåŸããã
ãªãªã«ã¬ãã·ãããµã³ãŽã ã®éååã³ã°ã©ããé
åã®è«žç¹æ§ã第ïŒè¡šã«ç€ºãã
âïŒãâïŒã®è£œé ïŒ åèäŸïŒã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éå
ã«ãããŠã°ã©ãã亀åå€ãšããŠäœ¿çšããγâã¡ã¿
ã¯ãªããã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³ã®äœ¿
çšéãïŒéééšã«åºå®ããæ¶æ©å€ãšããŠäœ¿çšãã
ãšãã«ãªã«ãœã·ãªã±ãŒãã®äœ¿çšéã第ïŒè¡šã«ç€ºã
ããã«çš®ã å€æŽãããšãã«ãªã«ãœã·ãªã±ãŒãã®ãª
ã¯ã¿ã¡ãã«ããã©ã·ã¯ãã·ãããµã³ã®åã98éé
éšãšãªãããã«ãããã調æŽããŠäœ¿çšãã以å€ã¯
åèäŸïŒãšåæ§ã®æ¹æ³ã§ããªãªã«ã¬ãã·ãããµã³
ãŽã ã®éååã³ã°ã©ããéåãè¡ããã°ã©ããå ±
éåäœã®ä¹Ÿç²ïŒ³âïŒãâïŒãããããåŸããã
ãªãªã«ã¬ãã·ãããµã³ãŽã ã®éååã³ã°ã©ããé
åã®è«žç¹æ§ã第ïŒè¡šã«ç€ºãã
ãè¡šã
å®æœäŸïŒãïŒãæ¯èŒäŸïŒãïŒ
åèäŸïŒãïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ç³»
ã°ã©ããå ±éåäœïŒ³âïŒãâïŒããããã8.3
ééïŒ ãã¯ãããã«ã äž25âã§æž¬å®ããéå ç²åºŠ
ïŒÎ·spïŒïŒ£ïŒã0.59dlïŒïœã®ããªïŒ2.6âãžã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«44ééïŒ åã³è·é
ïŒKgã§200âã§ã®ã¡ã«ãã€ã³ããã¯ã¹ã30ïœïŒ10
åã®ããªã¹ãã¬ã³47.7ééïŒ ãšãªãå²åã§ããã
ãé åãïŒçš®é¡ã®é åç©ã調æŽããïŒå®æœäŸïŒã
ïŒãæ¯èŒäŸïŒãïŒïŒãããã«äžèšããªïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«48éé
ïŒ åã³äžèšããªã¹ãã¬ã³52ééïŒ ãšãªãå²åã§é
åããé åç©ã調補ããïŒæ¯èŒäŸïŒïŒã ãããïŒçš®é¡ã®åé åç©ãäºè»žæŒåºæ©ïŒãŠãšã«
ã㌠ãã¢ãŠãã©ãŒç€Ÿè£œãZSKâ30åïŒã«ãã
ããäŸçµŠãã·ãªã³ããŒæž©åºŠ280âã§æº¶èæ··ç·Žãã
ããããã¬ããç¶ã¡è³ŠåãããåŸããããããã
ã®ãã¬ããã也ç¥åŸåŽå°åºæ圢æ©ïŒåæ©è£œäœæ
補ãSJâ35åïŒã«äŸçµŠãã·ãªã³ãâ枩床280âã
éå枩床60âã§å°åºæ圢ãå皮詊éšçãåŸããã
ããã®åè©Šéšçåã³ãã¬ãããçšãåçš®ç©æ§ãè©
䟡ããçµæã第ïŒè¡šã«ç€ºãã
ã°ã©ããå ±éåäœïŒ³âïŒãâïŒããããã8.3
ééïŒ ãã¯ãããã«ã äž25âã§æž¬å®ããéå ç²åºŠ
ïŒÎ·spïŒïŒ£ïŒã0.59dlïŒïœã®ããªïŒ2.6âãžã¡ãã«â
ïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«44ééïŒ åã³è·é
ïŒKgã§200âã§ã®ã¡ã«ãã€ã³ããã¯ã¹ã30ïœïŒ10
åã®ããªã¹ãã¬ã³47.7ééïŒ ãšãªãå²åã§ããã
ãé åãïŒçš®é¡ã®é åç©ã調æŽããïŒå®æœäŸïŒã
ïŒãæ¯èŒäŸïŒãïŒïŒãããã«äžèšããªïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«48éé
ïŒ åã³äžèšããªã¹ãã¬ã³52ééïŒ ãšãªãå²åã§é
åããé åç©ã調補ããïŒæ¯èŒäŸïŒïŒã ãããïŒçš®é¡ã®åé åç©ãäºè»žæŒåºæ©ïŒãŠãšã«
ã㌠ãã¢ãŠãã©ãŒç€Ÿè£œãZSKâ30åïŒã«ãã
ããäŸçµŠãã·ãªã³ããŒæž©åºŠ280âã§æº¶èæ··ç·Žãã
ããããã¬ããç¶ã¡è³ŠåãããåŸããããããã
ã®ãã¬ããã也ç¥åŸåŽå°åºæ圢æ©ïŒåæ©è£œäœæ
補ãSJâ35åïŒã«äŸçµŠãã·ãªã³ãâ枩床280âã
éå枩床60âã§å°åºæ圢ãå皮詊éšçãåŸããã
ããã®åè©Šéšçåã³ãã¬ãããçšãåçš®ç©æ§ãè©
䟡ããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
å®æœäŸïŒãšæ¯èŒäŸïŒã®æ¯èŒãããå®æœäŸïŒã®çµ
æç©ãèè¡ææ§èœãªãã³ã«æµåæ§ãé¡èã«æ¹åã
ããããšããããã åãå®æœäŸïŒãïŒãïŒåã³ïŒã®æ¯èŒããã䜿çš
ããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ
ã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éåæã«ã°ã©ã
ã亀åå€ãšããŠÎ³âã¡ã¿ã¯ãªããã·ãããã«ãžã¡
ããã·ã¡ãã«ã·ã©ã³åã³Î³âã¡ã¿ã¯ãªããã·ãã
ãã«ããªã¡ããã·ã·ã©ã³ãããããçšããå®æœäŸ
ïŒåã³ïŒã®çµæç©ã¯ã°ã©ãã亀åå€ãšããŠÎ³âã¡
ã«ã«ãããããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³åã³ã
ãã©ã¡ãã«ããã©ããã«ã·ã¯ãã·ãããµã³ããã
ããçšããå®æœäŸïŒåã³ïŒã®çµæç©ã«å¯ŸããŠã¢ã€
ãŸããè¡æ匷床åã³ã¡ã«ãã€ã³ããã¯ã¹å€ã®ãã
ããåªããŠããããšãããããããã¯Î³âã¡ã¿ã¯
ãªããã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³åã³Î³
âã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã·ã·ã©ã³ã
ã°ã©ãã亀åå€ãšããå Žåã«ã°ã©ããå¹çãé«ã
ãããåŸãããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ã
ãå ±éåäœãããªããšãã¬ã³ãšãŒãã«æš¹èåã³ã
ãªã¹ãã¬ã³æš¹èãšçµåãããŠé åããŠãæš¹èçµæ
ç©ã®æµåæ§ãé»å®³ããããšãªãèè¡ææ§èœã®åäž
ã«å¯äžããããã§ããã ããã«å®æœäŸïŒåã³ïŒã®æ¯èŒäŸïŒåã³ïŒã®æ¯èŒ
ããããªãªã«ã¬ãã·ãããµã³ãŽã ã®èšæœ€åºŠãæ¬çº
æã§èŠå®ããç¯å²å ã®ãã®ã§ããå Žåã«ã¯æå¹ãª
èè¡ææ§èœæ¹åå¹æã瀺ãããšããããã å®æœäŸïŒã14ãæ¯èŒäŸïŒãïŒ åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœïŒ³âïŒãåèšå®æœäŸã§çšããããª
ïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒ
ãã«åã³åèšå®æœäŸã§çšããããªã¹ãã¬ã³ã第ïŒ
è¡šã«ç€ºãé åå²åã§ããããé åãïŒæåãããª
ãåçš®é åç©ã調補ããïŒå®æœäŸïŒã14ïŒã åãåèšå®æœäŸã§çšããããªïŒïŒïŒïŒâãžã¡ã
ã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«åã³ããªãã¿
ãžãšã³å«éãïŒééïŒ ã§ã²ã«å«é13.3ééïŒ ã§ã
ãé«è¡ææ§ããªã¹ãã¬ã³ã第ïŒè¡šã«ç€ºãé åå²å
ã§ããããé åãïŒæåãããªãåçš®é åç©ã調
補ããïŒæ¯èŒäŸïŒãïŒïŒã ããã12çš®é¡ã®åé åç©ãåèšå®æœäŸã§çšãã
äºè»žæŒåºæ©åã³å°åºæ圢æ©ã«ããåèšå®æœäŸãšå
ãæ¡ä»¶ã§ãããããã¬ããåããå皮詊éšçãåŸ
ãããããã®åè©Šéšçåã³ãã¬ãããçšãåçš®ç©
æ§ãè©äŸ¡ããçµæã第ïŒè¡šã«ç€ºãã
æç©ãèè¡ææ§èœãªãã³ã«æµåæ§ãé¡èã«æ¹åã
ããããšããããã åãå®æœäŸïŒãïŒãïŒåã³ïŒã®æ¯èŒããã䜿çš
ããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ
ã®ããªãªã«ã¬ãã·ãããµã³ãŽã ã®éåæã«ã°ã©ã
ã亀åå€ãšããŠÎ³âã¡ã¿ã¯ãªããã·ãããã«ãžã¡
ããã·ã¡ãã«ã·ã©ã³åã³Î³âã¡ã¿ã¯ãªããã·ãã
ãã«ããªã¡ããã·ã·ã©ã³ãããããçšããå®æœäŸ
ïŒåã³ïŒã®çµæç©ã¯ã°ã©ãã亀åå€ãšããŠÎ³âã¡
ã«ã«ãããããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³åã³ã
ãã©ã¡ãã«ããã©ããã«ã·ã¯ãã·ãããµã³ããã
ããçšããå®æœäŸïŒåã³ïŒã®çµæç©ã«å¯ŸããŠã¢ã€
ãŸããè¡æ匷床åã³ã¡ã«ãã€ã³ããã¯ã¹å€ã®ãã
ããåªããŠããããšãããããããã¯Î³âã¡ã¿ã¯
ãªããã·ãããã«ãžã¡ããã·ã¡ãã«ã·ã©ã³åã³Î³
âã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã·ã·ã©ã³ã
ã°ã©ãã亀åå€ãšããå Žåã«ã°ã©ããå¹çãé«ã
ãããåŸãããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ã
ãå ±éåäœãããªããšãã¬ã³ãšãŒãã«æš¹èåã³ã
ãªã¹ãã¬ã³æš¹èãšçµåãããŠé åããŠãæš¹èçµæ
ç©ã®æµåæ§ãé»å®³ããããšãªãèè¡ææ§èœã®åäž
ã«å¯äžããããã§ããã ããã«å®æœäŸïŒåã³ïŒã®æ¯èŒäŸïŒåã³ïŒã®æ¯èŒ
ããããªãªã«ã¬ãã·ãããµã³ãŽã ã®èšæœ€åºŠãæ¬çº
æã§èŠå®ããç¯å²å ã®ãã®ã§ããå Žåã«ã¯æå¹ãª
èè¡ææ§èœæ¹åå¹æã瀺ãããšããããã å®æœäŸïŒã14ãæ¯èŒäŸïŒãïŒ åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœïŒ³âïŒãåèšå®æœäŸã§çšããããª
ïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒ
ãã«åã³åèšå®æœäŸã§çšããããªã¹ãã¬ã³ã第ïŒ
è¡šã«ç€ºãé åå²åã§ããããé åãïŒæåãããª
ãåçš®é åç©ã調補ããïŒå®æœäŸïŒã14ïŒã åãåèšå®æœäŸã§çšããããªïŒïŒïŒïŒâãžã¡ã
ã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«åã³ããªãã¿
ãžãšã³å«éãïŒééïŒ ã§ã²ã«å«é13.3ééïŒ ã§ã
ãé«è¡ææ§ããªã¹ãã¬ã³ã第ïŒè¡šã«ç€ºãé åå²å
ã§ããããé åãïŒæåãããªãåçš®é åç©ã調
補ããïŒæ¯èŒäŸïŒãïŒïŒã ããã12çš®é¡ã®åé åç©ãåèšå®æœäŸã§çšãã
äºè»žæŒåºæ©åã³å°åºæ圢æ©ã«ããåèšå®æœäŸãšå
ãæ¡ä»¶ã§ãããããã¬ããåããå皮詊éšçãåŸ
ãããããã®åè©Šéšçåã³ãã¬ãããçšãåçš®ç©
æ§ãè©äŸ¡ããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šã®å®æœäŸïŒã14ã®çµæããæãããªãã
ã«ã°ã©ããå ±éåäœïŒ³âïŒã®é åå²åã倧ãããª
ããšèè¡ææ§èœãåäžããããšãããããåãã
ãªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãš
ãŒãã«ã®é åå²åã倧ãããªããšãã«ããè»åæž©
床ã§ç€ºãããèç±æ§ãåäžããããšãããããã
ãã«ãããã®ç©æ§ãèè¡ææ§ããªã¹ãã¬ã³ãé å
ããç³»ãšæ¯èŒãããšå®æœäŸïŒãšæ¯èŒäŸïŒãå®æœäŸ
13ãšæ¯èŒäŸïŒãåã³å®æœäŸ14ãšæ¯èŒäŸïŒãšã®å¯Ÿæ¯
ããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ
ãé åããããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã®
æ¹ãã»ãŒåäžã®ãŽã å«éã«ãããŠèè¡ææ§èœãè
ç±æ§åã³æµåæ§ã®ç¹ã§å ±ã«åªããŠããããšããã
ãã å®æœäŸ15ãæ¯èŒäŸïŒ å®æœäŸïŒåã³æ¯èŒäŸïŒã§äœ¿çšããã¢ã€ãŸããè¡
æ匷床枬å®è©ŠéšçãçšããŠâ30âãâ60âã§ã®äœ
æž©ã¢ã€ãŸããè¡æ匷床ã枬å®ããçµæã23âã§æž¬
å®ããçµæãšäœµããŠç¬¬ïŒè¡šã«ç€ºãã
ã«ã°ã©ããå ±éåäœïŒ³âïŒã®é åå²åã倧ãããª
ããšèè¡ææ§èœãåäžããããšãããããåãã
ãªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãš
ãŒãã«ã®é åå²åã倧ãããªããšãã«ããè»åæž©
床ã§ç€ºãããèç±æ§ãåäžããããšãããããã
ãã«ãããã®ç©æ§ãèè¡ææ§ããªã¹ãã¬ã³ãé å
ããç³»ãšæ¯èŒãããšå®æœäŸïŒãšæ¯èŒäŸïŒãå®æœäŸ
13ãšæ¯èŒäŸïŒãåã³å®æœäŸ14ãšæ¯èŒäŸïŒãšã®å¯Ÿæ¯
ããããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ
ãé åããããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã®
æ¹ãã»ãŒåäžã®ãŽã å«éã«ãããŠèè¡ææ§èœãè
ç±æ§åã³æµåæ§ã®ç¹ã§å ±ã«åªããŠããããšããã
ãã å®æœäŸ15ãæ¯èŒäŸïŒ å®æœäŸïŒåã³æ¯èŒäŸïŒã§äœ¿çšããã¢ã€ãŸããè¡
æ匷床枬å®è©ŠéšçãçšããŠâ30âãâ60âã§ã®äœ
æž©ã¢ã€ãŸããè¡æ匷床ã枬å®ããçµæã23âã§æž¬
å®ããçµæãšäœµããŠç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šã®çµæããæãããªããã«æ¬çºæã®ããª
ããšãã¬ã³ãšãŒãã«æš¹èçµæç©ãé«è¡ææ§ããªã¹
ãã¬ã³ãé åããããªããšãã¬ã³ãšãŒãã«æš¹èçµ
æç©ã«æ¯ã¹ãŠäœæž©è¡æç¹æ§ã®ç¹ã§åªããŠããããš
ããããã å®æœäŸ16ãæ¯èŒäŸïŒ å®æœäŸïŒåã³æ¯èŒäŸïŒã§èª¿è£œããæš¹èé åç©ã®
ããããã®ãã¬ãããçšããã¡ã«ãã€ã³ããã¯ãµ
ãŒå ã«275âã«ãŠç¬¬ïŒè¡šã«ç€ºãåæå®ã®æéä¿æ
ãããåŸã®ã¡ã«ãã€ã³ããã¯ã¹ã枬å®ãèç±å®å®
æ§ãè©äŸ¡ããããããã®çµæã第ïŒè¡šã«ç€ºãã
ããšãã¬ã³ãšãŒãã«æš¹èçµæç©ãé«è¡ææ§ããªã¹
ãã¬ã³ãé åããããªããšãã¬ã³ãšãŒãã«æš¹èçµ
æç©ã«æ¯ã¹ãŠäœæž©è¡æç¹æ§ã®ç¹ã§åªããŠããããš
ããããã å®æœäŸ16ãæ¯èŒäŸïŒ å®æœäŸïŒåã³æ¯èŒäŸïŒã§èª¿è£œããæš¹èé åç©ã®
ããããã®ãã¬ãããçšããã¡ã«ãã€ã³ããã¯ãµ
ãŒå ã«275âã«ãŠç¬¬ïŒè¡šã«ç€ºãåæå®ã®æéä¿æ
ãããåŸã®ã¡ã«ãã€ã³ããã¯ã¹ã枬å®ãèç±å®å®
æ§ãè©äŸ¡ããããããã®çµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šã®çµæããæãããªããã«æ¬çºæã®ããª
ããšãã¬ã³ãšãŒãã«æš¹èçµæç©ãé«è¡ææ§ããªã¹
ãã¬ã³ãé åããããªããšãã¬ã³ãšãŒãã«æš¹èçµ
æç©ã«æ¯ã¹ãŠé·æéé«æž©åºŠã«ä¿æããŠãã¡ã«ãã€
ã³ããã¯ã¹ãæ®ãã©å€åãªãèç±æ§ã«åªããŠãã
ããšããããã å®æœäŸ 17 åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ãŽã ã©
ããã¯ã¹264éééšãæ¹æåšãåããã»ãã©ãã«
ãã©ã¹ã³ã«å ¥ããçªçŽ 眮æãããŠãã65âã«ææž©
ãããã®åŸã¹ãã¬ã³30éééšãã¢ã¯ãªããããªã«
10éééšåã³ã¿ãŒã·ã€ãªãŒããã«ããŒãªããµã€ã
0.08éééšã®æ··å溶液ãä»èŸŒã¿30åéæ¹æããã
ããã«ãã³ã¬ãªãã0.1éééšãç¡«é žç¬¬ïŒé
0.0002éééšããšãã¬ã³ãžã¢ãã³åé ¢é žäºãããª
ãŠã å¡©0.0004éééšåã³èžçæ°ŽïŒéééšã®æ··å溶
液ã«ä»èŸŒã¿ã©ãžã«ã«éåãéå§ãããïŒæéåå¿
枩床ãç¶æããåŸå·åŽãéåãçµäºãããã°ã©ã
ãéåæã®ã¹ãã¬ã³âã¢ã¯ãªããããªã«æ··ååé
äœã®éåçã¯98ïŒ ã§ãããååŸãããã°ã©ããå ±
éåäœã®ã°ã©ããçã¯56.7ïŒ ãã°ã©ããå¹çã¯85
ïŒ ã§ãã€ããåŸãããã©ããã¯ã¹ããç¡«é žãã°ã
ã·ãŠã ïŒééïŒ æ¿åºŠã®ç±æ°Ž456éééšäžã«æ»Žäžã
ãããšã«ããéåäœãååºãåé¢ããæŽæµããåŸ
75âã§10æé也ç¥ããŠæ°Žåãé€å»ããã°ã©ããå ±
éåäœã®ä¹Ÿç²ïŒ³âïŒãåŸãã 次ã«äžèšã®ã°ã©ããå ±éåäœã®ä¹Ÿç²ïŒ³âïŒã
8.3ééïŒ ãåèšå®æœäŸã§çšããããªïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ã44é
éïŒ åã³åèšå®æœäŸã§çšããããªã¹ãã¬ã³ã47.7
ééïŒ ãšãªãããã«é åããé åç©ãåèšå®æœäŸ
ã§çšããäºè»žæŒåºæ©åã³å°åºæ圢æ©ã«ããåèšå®
æœäŸãšåãæ¡ä»¶ã§ãã¬ããåããå皮詊éšçãåŸ
ãããããã®åè©Šéšçåã³ãã¬ãããçšãåçš®ç©
æ§ãè©äŸ¡ããçµæã第ïŒè¡šã«ç€ºãã
ããšãã¬ã³ãšãŒãã«æš¹èçµæç©ãé«è¡ææ§ããªã¹
ãã¬ã³ãé åããããªããšãã¬ã³ãšãŒãã«æš¹èçµ
æç©ã«æ¯ã¹ãŠé·æéé«æž©åºŠã«ä¿æããŠãã¡ã«ãã€
ã³ããã¯ã¹ãæ®ãã©å€åãªãèç±æ§ã«åªããŠãã
ããšããããã å®æœäŸ 17 åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ãŽã ã©
ããã¯ã¹264éééšãæ¹æåšãåããã»ãã©ãã«
ãã©ã¹ã³ã«å ¥ããçªçŽ 眮æãããŠãã65âã«ææž©
ãããã®åŸã¹ãã¬ã³30éééšãã¢ã¯ãªããããªã«
10éééšåã³ã¿ãŒã·ã€ãªãŒããã«ããŒãªããµã€ã
0.08éééšã®æ··å溶液ãä»èŸŒã¿30åéæ¹æããã
ããã«ãã³ã¬ãªãã0.1éééšãç¡«é žç¬¬ïŒé
0.0002éééšããšãã¬ã³ãžã¢ãã³åé ¢é žäºãããª
ãŠã å¡©0.0004éééšåã³èžçæ°ŽïŒéééšã®æ··å溶
液ã«ä»èŸŒã¿ã©ãžã«ã«éåãéå§ãããïŒæéåå¿
枩床ãç¶æããåŸå·åŽãéåãçµäºãããã°ã©ã
ãéåæã®ã¹ãã¬ã³âã¢ã¯ãªããããªã«æ··ååé
äœã®éåçã¯98ïŒ ã§ãããååŸãããã°ã©ããå ±
éåäœã®ã°ã©ããçã¯56.7ïŒ ãã°ã©ããå¹çã¯85
ïŒ ã§ãã€ããåŸãããã©ããã¯ã¹ããç¡«é žãã°ã
ã·ãŠã ïŒééïŒ æ¿åºŠã®ç±æ°Ž456éééšäžã«æ»Žäžã
ãããšã«ããéåäœãååºãåé¢ããæŽæµããåŸ
75âã§10æé也ç¥ããŠæ°Žåãé€å»ããã°ã©ããå ±
éåäœã®ä¹Ÿç²ïŒ³âïŒãåŸãã 次ã«äžèšã®ã°ã©ããå ±éåäœã®ä¹Ÿç²ïŒ³âïŒã
8.3ééïŒ ãåèšå®æœäŸã§çšããããªïŒïŒïŒïŒâ
ãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒãã«ã44é
éïŒ åã³åèšå®æœäŸã§çšããããªã¹ãã¬ã³ã47.7
ééïŒ ãšãªãããã«é åããé åç©ãåèšå®æœäŸ
ã§çšããäºè»žæŒåºæ©åã³å°åºæ圢æ©ã«ããåèšå®
æœäŸãšåãæ¡ä»¶ã§ãã¬ããåããå皮詊éšçãåŸ
ãããããã®åè©Šéšçåã³ãã¬ãããçšãåçš®ç©
æ§ãè©äŸ¡ããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šã®çµæããæãããªããã«ããªãªã«ã¬ã
ã·ãããµã³ç³»ã°ã©ããå ±éåäœã®ã°ã©ããæš¹èæ
åãã¢ã¯ãªããããªã«âã¹ãã¬ã³ç³»ã§ãã€ãŠãè
ç±æ§ãèè¡ææ§åã³æµåæ§çã«åªããããªããšã
ã¬ã³ãšãŒãã«æš¹èçµæç©ãåŸãããããšããã
ãã å®æœäŸ 18ã20 åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœïŒ³âã8.3ééïŒ ãåèšå®æœäŸã§çš
ããããªã¹ãã¬ã³ã47.7ééïŒ åã³ç¬¬ïŒè¡šã«ç€ºã
åçš®ã®Î·spïŒïŒ£ïŒã¯ãããã«ã äž25âã§ã®æž¬å®å€ïŒ
ãæããããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããš
ãã¬ã³ïŒãšãŒãã«ã44ééïŒ ãšãªãããã«é åã
ãé åç©ãåèšå®æœäŸã§çšããäºè»žæŒåºæ©åã³å°
åºæ圢æ©ã«ããåèšå®æœäŸãšåãæ¡ä»¶ã§ãã¬ãã
åããå皮詊éšçãåŸãããããã®åè©Šéšçåã³
ãã¬ãããçšãåçš®ç©æ§ãè©äŸ¡ããçµæã第ïŒè¡š
ã«ç€ºãã
ã·ãããµã³ç³»ã°ã©ããå ±éåäœã®ã°ã©ããæš¹èæ
åãã¢ã¯ãªããããªã«âã¹ãã¬ã³ç³»ã§ãã€ãŠãè
ç±æ§ãèè¡ææ§åã³æµåæ§çã«åªããããªããšã
ã¬ã³ãšãŒãã«æš¹èçµæç©ãåŸãããããšããã
ãã å®æœäŸ 18ã20 åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœïŒ³âã8.3ééïŒ ãåèšå®æœäŸã§çš
ããããªã¹ãã¬ã³ã47.7ééïŒ åã³ç¬¬ïŒè¡šã«ç€ºã
åçš®ã®Î·spïŒïŒ£ïŒã¯ãããã«ã äž25âã§ã®æž¬å®å€ïŒ
ãæããããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããš
ãã¬ã³ïŒãšãŒãã«ã44ééïŒ ãšãªãããã«é åã
ãé åç©ãåèšå®æœäŸã§çšããäºè»žæŒåºæ©åã³å°
åºæ圢æ©ã«ããåèšå®æœäŸãšåãæ¡ä»¶ã§ãã¬ãã
åããå皮詊éšçãåŸãããããã®åè©Šéšçåã³
ãã¬ãããçšãåçš®ç©æ§ãè©äŸ¡ããçµæã第ïŒè¡š
ã«ç€ºãã
ãè¡šã
第ïŒè¡šã®çµæããæãããªããã«åçš®ã®Î·spïŒ
ãæããããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ïŒãšãŒãã«ã䜿çšããŠãæ¬çºæã®ç¹åŸŽã§
ããé«ãèè¡ææ§èœãçºçŸããããšããããã å®æœäŸ 21ã23 åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœïŒ³âïŒã8.3ééïŒ ãã¯ãããã«ã
äž25âã§æž¬å®ããηspïŒïŒ£ã0.59dlïŒïœã®ããª
ïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒ
ãã«44ééïŒ åã³ç¬¬ïŒè¡šã«ç€ºãåçš®ã¹ãã¬ã³ç³»å ±
éåäœã47.7ééïŒ ãšãªãããã«é åããé åç©
ãåèšå®æœäŸã§çšããäºè»žæŒåºæ©åã³å°åºæ圢æ©
ã«ããåèšå®æœäŸãšåãæ¡ä»¶ã§ãã¬ããåããå
ã³å皮詊éšçãåŸãããããã®åè©Šéšçåã³ãã¬
ãããçšãåçš®ç©æ§ãè©äŸ¡ããçµæã第ïŒè¡šã«ç€º
ãã ãªã第ïŒè¡šäžã®ã¢ã¯ãªããããªã«âã¹ãã¬ã³å ±
éåäœã¯ã¢ã¯ãªããããªã«ïŒã¹ãã¬ã³ïŒ30éé
ïŒ ïŒ70ééïŒ ããæ§æãããDMFäž25âã§æž¬å®
ããηspïŒïŒ£ã0.61ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãâã¹
ãã¬ã³å ±éåäœã¯ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒã¹ãã¬
ã³ïŒ50ééïŒ ïŒ50ééïŒ ããæ§æãããã¯ããã
ã«ã äž25âã§æž¬å®ããηspïŒïŒ£ã0.54ãç¡æ°Žãã¬
ã€ã³é žâã¹ãã¬ã³å ±éåäœã¯ç¡æ°Žãã¬ã€ã³é žïŒã¹
ãã¬ã³ïŒ30ééïŒ ïŒ70ééïŒ ããæ§æããã
DMFäž25âã§æž¬å®ããηspïŒïŒ£ã0.4ã®ãã®ã§ã
ãã
ãæããããªïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâã
ãšãã¬ã³ïŒãšãŒãã«ã䜿çšããŠãæ¬çºæã®ç¹åŸŽã§
ããé«ãèè¡ææ§èœãçºçŸããããšããããã å®æœäŸ 21ã23 åèäŸïŒã§åŸãããªãªã«ã¬ãã·ãããµã³ç³»ã°ã©
ããå ±éåäœïŒ³âïŒã8.3ééïŒ ãã¯ãããã«ã
äž25âã§æž¬å®ããηspïŒïŒ£ã0.59dlïŒïœã®ããª
ïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâããšãã¬ã³ïŒãšãŒ
ãã«44ééïŒ åã³ç¬¬ïŒè¡šã«ç€ºãåçš®ã¹ãã¬ã³ç³»å ±
éåäœã47.7ééïŒ ãšãªãããã«é åããé åç©
ãåèšå®æœäŸã§çšããäºè»žæŒåºæ©åã³å°åºæ圢æ©
ã«ããåèšå®æœäŸãšåãæ¡ä»¶ã§ãã¬ããåããå
ã³å皮詊éšçãåŸãããããã®åè©Šéšçåã³ãã¬
ãããçšãåçš®ç©æ§ãè©äŸ¡ããçµæã第ïŒè¡šã«ç€º
ãã ãªã第ïŒè¡šäžã®ã¢ã¯ãªããããªã«âã¹ãã¬ã³å ±
éåäœã¯ã¢ã¯ãªããããªã«ïŒã¹ãã¬ã³ïŒ30éé
ïŒ ïŒ70ééïŒ ããæ§æãããDMFäž25âã§æž¬å®
ããηspïŒïŒ£ã0.61ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãâã¹
ãã¬ã³å ±éåäœã¯ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒã¹ãã¬
ã³ïŒ50ééïŒ ïŒ50ééïŒ ããæ§æãããã¯ããã
ã«ã äž25âã§æž¬å®ããηspïŒïŒ£ã0.54ãç¡æ°Žãã¬
ã€ã³é žâã¹ãã¬ã³å ±éåäœã¯ç¡æ°Žãã¬ã€ã³é žïŒã¹
ãã¬ã³ïŒ30ééïŒ ïŒ70ééïŒ ããæ§æããã
DMFäž25âã§æž¬å®ããηspïŒïŒ£ã0.4ã®ãã®ã§ã
ãã
æ¬çºæã¯ããªããšãã¬ã³ãšãŒãã«æš¹èãããªã¹
ãã¬ã³æš¹èåã³æ¬çºæã§èŠå®ããç¹å®ã®ããªãªã«
ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœãé åããã
ãšã«ããèè¡ææ§ãèç±æ§ãæ©æ¢°ç匷床ãæ圢æ§
åã³æµåæ§çã«åªããããªããšãã¬ã³ãšãŒãã«æš¹
èçµæç©ãšãåŸããã®ã§ããåªããå¹æãå¥ã
ãã
ãã¬ã³æš¹èåã³æ¬çºæã§èŠå®ããç¹å®ã®ããªãªã«
ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœãé åããã
ãšã«ããèè¡ææ§ãèç±æ§ãæ©æ¢°ç匷床ãæ圢æ§
åã³æµåæ§çã«åªããããªããšãã¬ã³ãšãŒãã«æš¹
èçµæç©ãšãåŸããã®ã§ããåªããå¹æãå¥ã
ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ããªããšãã¬ã³ãšãŒãã«æš¹è(A)ãããªã¹ãã¬
ã³æš¹è(B)åã³ãã«ãšã³æº¶åªäžã§æž¬å®ããèšæœ€åºŠã
ïŒã15ã§ããããã€ã°ã©ãã亀åå€ãå ±éåãã
ãããªãªã«ã¬ãã·ãããµã³ãŽã ã«ïŒçš®åã¯ïŒçš®ä»¥
äžã®ããã«ç³»åéäœãã°ã©ããéåãããããªãª
ã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)ããæ§æ
ãããããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã ïŒ ããªããšãã¬ã³ãšãŒãã«æš¹è(A)ã20ã80éé
ïŒ ãããªã¹ãã¬ã³æš¹è(B)ã20ã75ééïŒ åã³ããª
ãªã«ã¬ãã·ãããµã³ç³»ã°ã©ããå ±éåäœ(C)ãïŒã
40ééïŒ ããæ§æãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èš
èŒã®ããªããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã ïŒ ã°ã©ãã亀åå€ãäžè¬åŒïŒïŒ ïŒåŒäžR1ã¯ã¡ãã«åºããšãã«åºããããã«åºå
ã¯ããšãã«åºãR2ã¯æ°ŽçŽ åååã¯ã¡ãã«åºãïœ
ã¯ïŒãïŒåã¯ïŒãïœã¯ïŒãïŒã®æ°ã瀺ããïŒ ã§è¡šããããïŒã¡ã¿ïŒã¢ã¯ãªããã·ã·ãããµã³ã§
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé èšèŒã®ããª
ããšãã¬ã³ãšãŒãã«æš¹èçµæç©ã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61066529A JPS62223252A (ja) | 1986-03-25 | 1986-03-25 | ããªããšãã¬ã³ãšâãã«æš¹èçµæç© |
| JP62177843A JPS6422960A (en) | 1986-03-25 | 1987-07-16 | Polyphenylene ether resin composition |
| CA000578434A CA1321432C (en) | 1986-03-25 | 1988-09-26 | Polyphenylene ether resin composition |
| US07/250,734 US4892900A (en) | 1986-03-25 | 1988-09-29 | Polyphenylene ether resin composition |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61066529A JPS62223252A (ja) | 1986-03-25 | 1986-03-25 | ããªããšãã¬ã³ãšâãã«æš¹èçµæç© |
| JP62177843A JPS6422960A (en) | 1986-03-25 | 1987-07-16 | Polyphenylene ether resin composition |
| CA000578434A CA1321432C (en) | 1986-03-25 | 1988-09-26 | Polyphenylene ether resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62223252A JPS62223252A (ja) | 1987-10-01 |
| JPH0357149B2 true JPH0357149B2 (ja) | 1991-08-30 |
Family
ID=27168059
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61066529A Granted JPS62223252A (ja) | 1986-03-25 | 1986-03-25 | ããªããšãã¬ã³ãšâãã«æš¹èçµæç© |
| JP62177843A Pending JPS6422960A (en) | 1986-03-25 | 1987-07-16 | Polyphenylene ether resin composition |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62177843A Pending JPS6422960A (en) | 1986-03-25 | 1987-07-16 | Polyphenylene ether resin composition |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4892900A (ja) |
| JP (2) | JPS62223252A (ja) |
| CA (1) | CA1321432C (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2009053C (en) * | 1989-02-03 | 1999-09-28 | Isao Sasaki | Impact-resistant resin |
| US5219940A (en) * | 1989-10-13 | 1993-06-15 | Idemitsu Kosan Co., Ltd. | Styrene polymer composition |
| AU628651B2 (en) * | 1989-10-13 | 1992-09-17 | Idemitsu Kosan Co. Ltd | Styrene polymer composition |
| DE3935169A1 (de) * | 1989-10-21 | 1991-04-25 | Huels Chemische Werke Ag | Faserverstaerkte polyphenylenether-formmassen und verfahren zu ihrer herstellung |
| US5703164A (en) * | 1990-09-12 | 1997-12-30 | Idemitsu Kosan Co., Ltd. | Styrene polymer composition |
| TW444172B (en) * | 1998-04-07 | 2001-07-01 | Alps Electric Co Ltd | Input device |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2891920A (en) * | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
| GB1024024A (en) * | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
| JPS424574Y1 (ja) * | 1964-10-15 | 1967-03-11 | ||
| NL7212235A (ja) * | 1971-09-09 | 1973-03-13 | ||
| US4226761A (en) * | 1978-11-27 | 1980-10-07 | General Electric Company | Polyphenylene ether resin compositions containing polysiloxane-modified alkenyl aromatic resins |
| US4315084A (en) * | 1980-01-14 | 1982-02-09 | General Electric Company | Polyphenylene ether molding compositions that include an alkenyl aromatic resin and EPDM rubber |
| JPS597829U (ja) * | 1982-07-05 | 1984-01-19 | å¯å£«é»æ©æ ªåŒäŒç€Ÿ | å»ãã©ã¹ããã¯åºåè£ çœ® |
| JPS6084356A (ja) * | 1983-10-13 | 1985-05-13 | Mitsubishi Gas Chem Co Inc | é«èè¡ææ§ããªããšãã¬ã³ãšâãã«ç³»æš¹èçµæç© |
| JPH0694533B2 (ja) * | 1986-01-16 | 1994-11-24 | äžè±ã¬ã€ãšã³æ ªåŒäŒç€Ÿ | ç±å¯å¡æ§ããªãšã¹ãã«æš¹èçµæç© |
-
1986
- 1986-03-25 JP JP61066529A patent/JPS62223252A/ja active Granted
-
1987
- 1987-07-16 JP JP62177843A patent/JPS6422960A/ja active Pending
-
1988
- 1988-09-26 CA CA000578434A patent/CA1321432C/en not_active Expired - Fee Related
- 1988-09-29 US US07/250,734 patent/US4892900A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA1321432C (en) | 1993-08-17 |
| US4892900A (en) | 1990-01-09 |
| JPS62223252A (ja) | 1987-10-01 |
| JPS6422960A (en) | 1989-01-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4894415A (en) | Polyphenylene ether resin composition | |
| JPH01190746A (ja) | èè¡ææ§æš¹èçµæç© | |
| JP2719939B2 (ja) | é£çæ§ããªããšãã¬ã³ãšãŒãã«æš¹èçµæç© | |
| JPH0357149B2 (ja) | ||
| JPH04239010A (ja) | ã°ã©ããå ±éåäœ | |
| AU603924B2 (en) | Polyetherimide resin composition | |
| US5268403A (en) | Polyphenylene ether resin composition | |
| JPH04100812A (ja) | è€åãŽã ç³»ã°ã©ããå ±éåäœç²å | |
| EP0468462A2 (en) | Resin compositions excellent in impact resistance and heat stability | |
| JPH04146964A (ja) | ããªã¢ãªãŒã¬ã³ãµã«ãã¡ã€ãæš¹èçµæç© | |
| JP2707312B2 (ja) | ããªããšãã¬ã³ãšãŒãã«æš¹èçµæç© | |
| JP2958059B2 (ja) | ç±å¯å¡æ§æš¹èçµæç© | |
| JP2903432B2 (ja) | ç±å¯å¡æ§æš¹èçµæç© | |
| JP3163138B2 (ja) | æš¹èçµæç© | |
| JPH01279954A (ja) | å¡©åããã«ç³»æš¹èçšè¡ææ¹è³ªå€åã³ãããçšããå¡©åããã«ç³»æš¹èçµæç© | |
| JPS63202652A (ja) | ããªã¢ããâããªããšãã¬ã³ãšâãã«æš¹èçµæç© | |
| JPH01282257A (ja) | ããªããšãã¬ã³ãšãŒãã«æš¹èçµæç© | |
| JPH1036460A (ja) | ããªãªã«ã¬ãã·ãããµã³å«æã°ã©ããå ±éåäœ | |
| JPH02202550A (ja) | ããªã¢ãªãŒã¬ã³ãµã«ãã¡ã€ãæš¹èçµæç© | |
| JP3453212B2 (ja) | ã°ã©ããå ±éåäœ | |
| JPH02245050A (ja) | ããªã¡ã¿ã¯ãªã«ã€ãã系暹èçšè¡ææ¹è³ªå€ããã³ãããçšããããªã¡ã¿ã¯ãªã«ã€ãã系暹èçµæç© | |
| JPH02263861A (ja) | ç±å¯å¡æ§æš¹èçµæç© | |
| JPH03153751A (ja) | èè¡ææ§ãèç±å®å®æ§ã«åªããæš¹èçµæç© | |
| JPH04356562A (ja) | ããªã¢ãªâã¬ã³ãµã«ãã¡ã€ãæš¹èçµæç© | |
| JPS61138654A (ja) | èè¡ææ§æš¹èçµæç© |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |