JPH0358461B2 - - Google Patents

Info

Publication number
JPH0358461B2
JPH0358461B2 JP4990584A JP4990584A JPH0358461B2 JP H0358461 B2 JPH0358461 B2 JP H0358461B2 JP 4990584 A JP4990584 A JP 4990584A JP 4990584 A JP4990584 A JP 4990584A JP H0358461 B2 JPH0358461 B2 JP H0358461B2
Authority
JP
Japan
Prior art keywords
oxygen concentration
value
air
detection device
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP4990584A
Other languages
Japanese (ja)
Other versions
JPS60194350A (en
Inventor
Takashi Yoshida
Tomoharu Hasegawa
Manabu Fujii
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP4990584A priority Critical patent/JPS60194350A/en
Publication of JPS60194350A publication Critical patent/JPS60194350A/en
Publication of JPH0358461B2 publication Critical patent/JPH0358461B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/406Cells and probes with solid electrolytes
    • G01N27/4065Circuit arrangements specially adapted therefor
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/007Arrangements to check the analyser

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pathology (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Electrochemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Emergency Alarm Devices (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)

Description

【発明の詳細な説明】 〔発明の技術分野〕 この発明はガルバニ電池式酸素センサのような
空気中の酸素濃度に応じた電圧を発生する酸素セ
ンサの出力によつて酸素濃度が所定危険値に低下
したことを検知する酸素濃度検知装置に関する。
[Detailed Description of the Invention] [Technical Field of the Invention] This invention is a method for controlling oxygen concentration to a predetermined dangerous value by the output of an oxygen sensor, such as a galvanic cell type oxygen sensor, which generates a voltage according to the oxygen concentration in the air. The present invention relates to an oxygen concentration detection device that detects a decrease in oxygen concentration.

〔従来技術〕 従来この種装置として第1図、第2図に示すも
のがあつた。第1図は、例えば月刊誌「計報」昭
和55年9月号に示された従来の酸素濃度検知装置
を示すブロツク線図で、図において1はガルバニ
電池式酸素センサ、2は増幅器、3は電圧比較
器、4は警報設定用基準電池、5は警報ブザー、
6はソリツドステートリレーである。第2図はガ
ルバニ電池式酸素センサ1の構造を示す側断面図
で、図において7は正電極材、8は負電極材、9
は電解液、10は温度補償用サーミスタ、11は
ホルダ、12は正極端子、13は負極端子、14
は外部抵抗である。
[Prior Art] Conventionally, there have been devices of this type as shown in FIGS. 1 and 2. FIG. 1 is a block diagram showing a conventional oxygen concentration detection device, which was shown in the September 1980 issue of the monthly magazine Keiho, for example. In the figure, 1 is a galvanic cell type oxygen sensor, 2 is an amplifier, and 3 is a voltage comparator, 4 is a reference battery for alarm setting, 5 is an alarm buzzer,
6 is a solid state relay. FIG. 2 is a side sectional view showing the structure of the galvanic cell type oxygen sensor 1, in which 7 is a positive electrode material, 8 is a negative electrode material, and 9 is a negative electrode material.
is an electrolytic solution, 10 is a temperature compensation thermistor, 11 is a holder, 12 is a positive terminal, 13 is a negative terminal, 14
is the external resistance.

ガルバニ電池式酸素センサ1は第2図のように
構成されており、正極端子12と負極端子13間
に外部抵抗14を挿入することにより、外部抵抗
14の両端に電圧が発生し、この電圧は空気中の
酸素濃度に応じて変化する。第3図はその特性の
例を示し、空中の酸素濃度が大になると端子電圧
Vは上昇する。図中V1は空中の正常酸素濃度で
ある20.6%におけるセンサ1の出力電圧値、V2
危険酸素濃度である18.0%におけるセンサ1の出
力電圧値である。
The galvanic cell type oxygen sensor 1 is constructed as shown in FIG. 2, and by inserting an external resistor 14 between the positive terminal 12 and the negative terminal 13, a voltage is generated across the external resistor 14, and this voltage is It changes depending on the oxygen concentration in the air. FIG. 3 shows an example of the characteristic, and as the oxygen concentration in the air increases, the terminal voltage V increases. In the figure, V 1 is the output voltage value of sensor 1 at 20.6%, which is the normal oxygen concentration in the air, and V 2 is the output voltage value of sensor 1 at 18.0%, which is the dangerous oxygen concentration.

この空中の酸素濃度に応ずる出力電圧が酸素セ
ンサ1から出力され、第1図増幅器2で増幅さ
れ、電圧比較器3の一方の入力端に入力し、それ
の他方の入力端に警報設定用基準電池4からの電
圧が印加される。この基準電池4の電圧値は上記
V2と等しい値に設定されており、従つて被検知
空気の酸素濃度が18.0%の危険領域迄に下がる
と、上記電圧比較器3の出力は反転し、それによ
り警報ブザー5及びソリツドステートリレー6が
駆動され危険酸素濃度検知動作が行なわれる。
An output voltage corresponding to the oxygen concentration in the air is outputted from the oxygen sensor 1, amplified by the amplifier 2 shown in FIG. A voltage from battery 4 is applied. The voltage value of this reference battery 4 is above
V 2 , and therefore, when the oxygen concentration of the detected air drops to the dangerous range of 18.0%, the output of the voltage comparator 3 is inverted, which causes the alarm buzzer 5 and the solid state Relay 6 is driven and dangerous oxygen concentration detection operation is performed.

しかし、ガルバニ電池式酸素センサ1の上記特
性は、経時変化により変動する。第4図はこの特
性変動の例を示し、図中Aは初期品の特性を、B
は経時変化で劣化したものの特性を示し、酸素濃
度が正常値20.6%から危険値18.0%迄の変化に対
し、初期品の場合V1→V2、劣化品の場合V1′→
V2′となり、直線の傾きが変動し、危険濃度検出
電圧もV2からV2′へと減少する。
However, the above characteristics of the galvanic cell type oxygen sensor 1 change over time. Figure 4 shows an example of this characteristic variation, where A represents the characteristics of the initial product and B represents the characteristics of the initial product.
indicates the characteristics of a product that has deteriorated over time; when the oxygen concentration changes from a normal value of 20.6% to a dangerous value of 18.0%, V 1 →V 2 for an initial product and V 1 ′ → for a deteriorated product.
V 2 ′, the slope of the straight line changes, and the dangerous concentration detection voltage also decreases from V 2 to V 2 ′.

従つて、第1図の基準電池4の電圧を初期品用
としてV2に設定しておくと、センサ1が劣化す
ると第4図で示すように例えば19.5%付近を酸欠
の危険状態として検知し警報を発するという誤動
作を招く欠点を有していた。
Therefore, if the voltage of the reference battery 4 in Fig. 1 is set to V 2 for the initial product, if the sensor 1 deteriorates, it will detect, for example, around 19.5% as a dangerous state of oxygen deficiency, as shown in Fig. 4. This had the disadvantage of causing a malfunction in that it would issue an alarm.

〔発明の概要〕[Summary of the invention]

この発明は、上記欠点を除くためになされたも
ので、ガルバニ式酸素センサ等の酸素センサの、
正常酸素濃度(20.6%)における出力電圧V1に対
する、危険酸素濃度(18.0%)における出力電圧
V2の比率が初期品も経時変化した劣化品も殆ど
変らない点に着目し、この比率を酸素センサの出
力を測定しながらA/D変換器及び中央処理装置
によつて演算し、その演算値が所定値又はそれ以
下に低下したことを検知するようにすることによ
つて経時変化によつても誤動作のない信頼性の高
い酸素濃度検知装置を提供することを目的として
いる。
This invention was made in order to eliminate the above-mentioned drawbacks, and is aimed at eliminating the drawbacks of oxygen sensors such as galvanic oxygen sensors.
Output voltage at hazardous oxygen concentration (18.0%) versus output voltage V 1 at normal oxygen concentration (20.6%)
Focusing on the fact that the ratio of V 2 is almost the same for both the initial product and the deteriorated product that has changed over time, this ratio is calculated using an A/D converter and central processing unit while measuring the output of the oxygen sensor, and the calculation is performed. It is an object of the present invention to provide a highly reliable oxygen concentration detection device that does not malfunction even over time by detecting when the value has decreased to a predetermined value or lower.

〔発明の実施例〕[Embodiments of the invention]

以下この発明の一実施例を説明する。第5図は
この発明の一実施例の概略構成を示すブロツク線
図で、1,2,5,6は第1図の同一符号と同一
部分を示し、15は、酸素センサ1の増幅器2を
へての出力電圧をデジタル信号に変換するA/D
変換器、16はこのA/D変換器15のデジタル
出力を処理する中央処理装置(以下CPUという)
である。以上のように構成されたこの発明の一実
施例である酸素濃度検知装置の動作を第6図のフ
ローチヤートに従つて説明する。まず最初に正常
酸素濃度20.6%における酸素センサ1の出力電圧
e0が増幅器2を介してA/D変換器15に入力さ
れ、デジタル変換され、CPU16の、初期状態
では常にデータがクリアされる(第6図ステツプ
21)任意書込部(以下RAMという)に書き込
ませ(ステツプ22)、初期値としてRAMに初
期設定する(ステツプ23,24)。次に被検知
空気中における2回目以降の酸素センサ1の出力
電圧e2,e3,…,eoがデジタル変換されてCPU1
6に入力され書き込まれ、その書込み値の初期値
に対する比θo=eo/e0の演算が行なわれ(ステツ
プ25)、その値が予めCPU16に設定されてい
る基準設定値θk=V2/V1より大きい場合は、e2
e3,…,eoの値がCPU16に毎回書き込まれ(ス
テツプ26,27)、θk以下になると書き込みが
停止され、CPU16のデジタル出力信号で警報
ブザー5およびソリツドステートリレー16を駆
動する(ステツプ26,28,29)。
An embodiment of this invention will be described below. FIG. 5 is a block diagram showing a schematic configuration of an embodiment of the present invention. Reference numerals 1, 2, 5, and 6 indicate the same parts as those in FIG. 1, and 15 indicates the amplifier 2 of the oxygen sensor 1. A/D that converts the output voltage of the hete into a digital signal
Converter 16 is a central processing unit (hereinafter referred to as CPU) that processes the digital output of this A/D converter 15.
It is. The operation of the oxygen concentration detection device which is an embodiment of the present invention constructed as described above will be explained with reference to the flowchart shown in FIG. First, the output voltage of oxygen sensor 1 at a normal oxygen concentration of 20.6%
e 0 is input to the A/D converter 15 via the amplifier 2 and converted into digital data, and the data is always cleared in the initial state of the CPU 16 (Step 21 in Figure 6). Optional writing section (hereinafter referred to as RAM) (Step 22), and initialize it in RAM as an initial value (Steps 23, 24). Next, the second and subsequent output voltages e 2 , e 3 , ..., e o of the oxygen sensor 1 in the air to be detected are digitally converted and sent to the CPU 1.
The ratio of the written value to the initial value θ o =e o /e 0 is calculated (step 25), and that value is set as the standard setting value θ k =V set in advance in the CPU 16. If larger than 2 /V 1 , e 2 ,
The values of e 3 ,..., e o are written to the CPU 16 each time (steps 26, 27), and when they become less than θ k , writing is stopped, and the digital output signal of the CPU 16 drives the alarm buzzer 5 and the solid state relay 16. (Steps 26, 28, 29).

なお、劣化品の場合に関し、酸素センサの出力
電圧値e0,eoと酸素濃度との関係は第7図に示す
如くであり、上記e0,eoは後述の電圧v1′,v2′に
対応した値である。
Regarding the case of deteriorated products, the relationship between the output voltage values e 0 and e o of the oxygen sensor and the oxygen concentration is as shown in FIG . 2 ′.

従つて、ガルバニ電池式酸素センサ1の初期品
における酸素濃度18.0%の20.6%に対する端子電
圧値の比V2/V1を、CPU16に基準設定値θk
して予め書き込んでおくことによつて、劣化品に
おける上記電圧比V2′/V1′も基準設定値θkと等し
いため正確に被検知空気中の危険酸素濃度を検知
することができる。
Therefore, by writing in advance the ratio of the terminal voltage value V 2 /V 1 to 20.6% of the oxygen concentration of 18.0% in the initial product of the galvanic cell type oxygen sensor 1 into the CPU 16 as the reference setting value θ k , Since the voltage ratio V 2 ′/V 1 ′ in the degraded product is also equal to the reference setting value θ k , the dangerous oxygen concentration in the air to be detected can be accurately detected.

誤動作防止のため、CPU16への初期値設定
の折、正常空気中における酸素センサ1の出力電
圧を複数回書き込み、その値が一致した時初期値
として書き込むとか、その後の危険酸素濃度の検
知においてもθoがθk以下になつた時のeoの値が2
〜3回の書き込みで、その値の一致により最終的
に警報ブザー5及びソリツドステートリレー16
等を駆動させるようにしてもよい。
To prevent malfunction, when setting the initial value to the CPU 16, the output voltage of the oxygen sensor 1 in normal air is written multiple times, and when the values match, it is written as the initial value. The value of e o when θ o becomes less than θ k is 2
After writing ~3 times, the alarm buzzer 5 and solid state relay 16 are finally activated due to the matching of the values.
etc. may also be driven.

〔発明の効果〕〔Effect of the invention〕

この発明は以上のように、正常空気中における
酸素センサの出力電圧に対する被検知空気中にお
ける酸素センサの出力電圧の比を常に求め、その
値が所定値以下になることを検知するようにした
ので、酸素センサの経時変化による特性劣化によ
つても何等誤動作のない正確で信頼性の高い酸素
濃度検知装置を得ることができる効果を有してい
る。
As described above, the present invention constantly calculates the ratio of the output voltage of the oxygen sensor in the detected air to the output voltage of the oxygen sensor in normal air, and detects when the value becomes less than a predetermined value. This has the effect of making it possible to obtain an accurate and highly reliable oxygen concentration detection device that does not malfunction even if the characteristics of the oxygen sensor deteriorate over time.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、従来の酸素濃度検知装置を示すブロ
ツク線図、第2図はガルバニ電池式酸素センサの
構造を示す側断面図、第3図、第4図はそれの動
作特性図、第5図は、この発明の一実施例の概略
構成を示すブロツク線図、第6図は、その動作を
説明するためのフローチヤート、第7図は劣化品
の場合の動作特性図である。 図中1はガルバニ電池式酸素センサ、2は増幅
器、5は警報ブザー、15はD/A変換器、16
は中央処理装置(CPU)である。なお図中同一
符号は同一又は相当部分を示す。
Fig. 1 is a block diagram showing a conventional oxygen concentration detection device, Fig. 2 is a side sectional view showing the structure of a galvanic cell type oxygen sensor, Figs. 3 and 4 are its operating characteristics, and Fig. 5 FIG. 6 is a block diagram showing a schematic configuration of an embodiment of the present invention, FIG. 6 is a flowchart for explaining its operation, and FIG. 7 is an operation characteristic diagram in the case of a deteriorated product. In the figure, 1 is a galvanic cell type oxygen sensor, 2 is an amplifier, 5 is an alarm buzzer, 15 is a D/A converter, 16
is the central processing unit (CPU). Note that the same reference numerals in the figures indicate the same or equivalent parts.

Claims (1)

【特許請求の範囲】 1 空気中の酸素濃度に応じた電圧を発生する酸
素センサの出力によつて酸素濃度が所定危険値に
低下したことを検知する酸素濃度検知装置におい
て、上記酸素センサの出力電圧をデジタル信号に
変換するA/D変換器及びこのA/D変換器のデ
ジタル出力を処理する中央処理装置を設け、これ
らによる、上記酸素センサの正常酸素濃度の空気
中における出力電圧をデジタル変換し初期値とし
て上記中央処理装置に書込み設定する手段、被検
知空気中における出力電圧値をデジタル変換して
2回目以降の値として上記中央処理装置に書き込
み、上記初期値に対する比を演算する手段、この
演算値と予め設定された基準設定値とを比較する
手段及びこの比較により上記演算値が上記基準設
定値と等しく、又はそれ以下になつた時警報器を
駆動させる手段を備えたことを特徴とする酸素濃
度検知装置。 2 上記酸素センサはガルバニ電池式酸素センサ
である特許請求の範囲第1項記載の酸素濃度検知
装置。 3 上記初期値を書き込み設定する手段は、上記
酸素センサの正常酸素濃度の空気中における出力
電圧をデジタル変換し、複数回書き込み、その値
が一致した時初期値として上記中央処理装置に書
込み設定する手段であることを特徴とする特許請
求の範囲第1項又は第2項記載の酸素濃度検知装
置。 4 上記警報器を駆動する手段は、この比較によ
り上記演算値が複数回上記基準設定値と等しく、
又はそれ以下になつた時警報器を駆動させる手段
であることを特徴とする特許請求の範囲第1項、
第2項又は第3項記載の酸素濃度検知装置。 5 上記基準設定値は、上記酸素センサ初期品
の、20.6%酸素濃度の空気中における出力電圧に
対する、18.0%酸素濃度の空気中における出力電
圧の比であることを特徴とする特許請求の範囲第
1項ないし第4項のいずれかに記載の酸素濃度検
知装置。
[Scope of Claims] 1. In an oxygen concentration detection device that detects that the oxygen concentration has decreased to a predetermined dangerous value by the output of an oxygen sensor that generates a voltage according to the oxygen concentration in the air, the output of the oxygen sensor is An A/D converter that converts voltage into a digital signal and a central processing unit that processes the digital output of this A/D converter are provided, and the output voltage of the oxygen sensor in air with normal oxygen concentration is digitally converted by these. means for writing and setting the output voltage value in the air to be detected in the central processing unit as an initial value; means for digitally converting the output voltage value in the air to be detected and writing it in the central processing unit as a second or subsequent value; and calculating a ratio with respect to the initial value; It is characterized by comprising means for comparing the calculated value with a preset reference setting value, and means for driving an alarm when the calculated value becomes equal to or less than the reference setting value as a result of this comparison. Oxygen concentration detection device. 2. The oxygen concentration detection device according to claim 1, wherein the oxygen sensor is a galvanic cell type oxygen sensor. 3. The means for writing and setting the initial value is to digitally convert the output voltage of the oxygen sensor in air with normal oxygen concentration, write it multiple times, and when the values match, write and set it in the central processing unit as the initial value. The oxygen concentration detection device according to claim 1 or 2, wherein the oxygen concentration detection device is a means for detecting oxygen concentration. 4. The means for driving the alarm is such that the calculated value is equal to the reference setting value multiple times through this comparison;
Claim 1, characterized in that the device is a means for activating an alarm when the temperature reaches or below the
The oxygen concentration detection device according to item 2 or 3. 5. The reference set value is the ratio of the output voltage of the initial oxygen sensor in air with an oxygen concentration of 18.0% to the output voltage in air with an oxygen concentration of 20.6%. The oxygen concentration detection device according to any one of Items 1 to 4.
JP4990584A 1984-03-15 1984-03-15 Apparatus for detecting concentration of oxygen Granted JPS60194350A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4990584A JPS60194350A (en) 1984-03-15 1984-03-15 Apparatus for detecting concentration of oxygen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4990584A JPS60194350A (en) 1984-03-15 1984-03-15 Apparatus for detecting concentration of oxygen

Publications (2)

Publication Number Publication Date
JPS60194350A JPS60194350A (en) 1985-10-02
JPH0358461B2 true JPH0358461B2 (en) 1991-09-05

Family

ID=12844022

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4990584A Granted JPS60194350A (en) 1984-03-15 1984-03-15 Apparatus for detecting concentration of oxygen

Country Status (1)

Country Link
JP (1) JPS60194350A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3637304A1 (en) * 1986-08-23 1988-05-05 Vdo Schindling METHOD AND CIRCUIT FOR DETECTING THE READY FOR OPERATION OF AN OXYGEN MEASUREMENT PROBE

Also Published As

Publication number Publication date
JPS60194350A (en) 1985-10-02

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