JPH0363406B2 - - Google Patents

Info

Publication number
JPH0363406B2
JPH0363406B2 JP6595984A JP6595984A JPH0363406B2 JP H0363406 B2 JPH0363406 B2 JP H0363406B2 JP 6595984 A JP6595984 A JP 6595984A JP 6595984 A JP6595984 A JP 6595984A JP H0363406 B2 JPH0363406 B2 JP H0363406B2
Authority
JP
Japan
Prior art keywords
fibers
hollow
nonwoven fabric
amount
synthetic fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP6595984A
Other languages
Japanese (ja)
Other versions
JPS60209220A (en
Inventor
Haruki Kato
Kazushi Kimura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koken Co Ltd
Original Assignee
Koken Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koken Co Ltd filed Critical Koken Co Ltd
Priority to JP6595984A priority Critical patent/JPS60209220A/en
Publication of JPS60209220A publication Critical patent/JPS60209220A/en
Publication of JPH0363406B2 publication Critical patent/JPH0363406B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1615Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of natural origin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1623Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Filtering Materials (AREA)
  • Electrostatic Separation (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

(技術分野) 本発明は、静電作用により粉塵等を捕集する空
気ろ過フイルタに関するものである。 (従来技術) 従来、この種のフイルタとして、羊毛あるいは
羊毛と合成繊維の混紡による不織布に、フエノー
ル系等の樹脂を含浸又はコートし、さらに、なめ
し、折り曲げ、打叩、破砕等の機械的二次加工を
施すことによつて静電気を発生させ、自然冷却し
てエレクトレツト化したものが知られている。こ
のように構成されたフイルタに、粉塵等を含む空
気を通すと、その静電作用により粉塵を吸着し、
捕集する。なお、使用する合成繊維として、断面
形状を多角形や星形にして、その表面積を増加す
るとともに帯電量を大きくしたものもある。これ
ら、従来使用されている繊維は、通常、R.H.40
%以下でかなりの帯電量を持つことができる。し
かしながら、これに粉塵等が接触すると、瞬間的
に放電が起こり、その結果、帯電量が急激に低下
してしまう。即ち、フイルタとしての寿命が短
く、粉塵捕集容量も比較的小さいものであつた。 (発明の目的) 本発明は、上記従来例の欠点を解消するために
なされたもので、経時劣化が少なく、粉塵捕集容
量の大きい静電式空気ろ過フイルタを提供するも
のである。 (発明の構成) 上記目的を達成するために、不織布を構成する
繊維に中空構造を有する合成繊維を混入する。即
ち、繊維径17〜20μm程度の羊毛繊維を主成分と
し、それに、ポリエステル、ポリアミド、ビニロ
ン、ナイロン、ポリプロピレン(PP)、スチレ
ン、ポリエチレン(PE)等の絶縁抵抗が高く、
吸湿性の小さい、中空構造を有する繊維を混紡
し、不織布に加工する。これに、フエノール系等
の樹脂を含浸又はコートし、さらに、なめし、折
り曲げ、打叩、破砕等の機械的二次加工を施すこ
とにより静電気を発生させる。 中空構造の繊維では、発生した静電気のほとん
どがその中空構造内に効果的に保持されるので、
永久帯電(エレクトレツト)に近い状態となる。
また、この中空構造の繊維に外部から機械的衝撃
を加えると容易に歪みが生じ、従つて、帯電分極
を効果的に起こさせることができる。これらのこ
とから、従来構成のフイルタに比べて、帯電量に
して約10倍程度増加させることができ、また、経
時変化が極めて小さくなる。 (実施例) 以下、実施例について詳細に説明する。 羊毛60% ポリエステル(テトロン)の中空繊維、断面
形状三角形、2d(デニール)40% 羊毛60% ポリエステル(テトロン)の中空繊維、断面
形状星形、4d、40% 上記及びのように、羊毛60%、ポリエステ
ル中空繊維40%の割合でそれぞれ混紡し、フエル
ト状の不織布に加工したものに、既知の方法によ
り樹脂加工及び機械的二次加工を施してフイルタ
を作製した。別に、比較のために羊毛100%の不
織布に同様の処理を施した従来品を用意した。本
発明品及びと従来品について、それぞれJIS
−T−8151に準拠した試験をし、下表の結果を得
た。
(Technical Field) The present invention relates to an air filtration filter that collects dust and the like by electrostatic action. (Prior art) Conventionally, this type of filter has been made by impregnating or coating a nonwoven fabric made of wool or a blend of wool and synthetic fibers with a phenol-based resin, and then applying mechanical processes such as tanning, folding, beating, and crushing. It is known that static electricity is generated through subsequent processing, and the material is naturally cooled to become an electret. When air containing dust, etc. is passed through a filter configured in this way, the dust is attracted by its electrostatic action,
Collect. Note that some of the synthetic fibers used have polygonal or star-shaped cross-sections to increase the surface area and increase the amount of charge. These conventionally used fibers usually have a RH40
% or less, it can have a considerable amount of charge. However, when dust or the like comes into contact with this, electric discharge occurs instantaneously, and as a result, the amount of charge decreases rapidly. That is, the life as a filter was short and the dust collection capacity was relatively small. (Object of the Invention) The present invention has been made in order to eliminate the drawbacks of the above-mentioned conventional examples, and provides an electrostatic air filtration filter that has little deterioration over time and has a large dust collection capacity. (Structure of the Invention) In order to achieve the above object, synthetic fibers having a hollow structure are mixed into the fibers constituting the nonwoven fabric. That is, the main component is wool fiber with a fiber diameter of about 17 to 20 μm, and it is also made of polyester, polyamide, vinylon, nylon, polypropylene (PP), styrene, polyethylene (PE), etc., which have high insulation resistance.
Fibers with a hollow structure and low hygroscopicity are blended and processed into a nonwoven fabric. Static electricity is generated by impregnating or coating this with a phenol-based resin or the like, and then subjecting it to secondary mechanical processing such as tanning, bending, beating, and crushing. With hollow fibers, most of the static electricity generated is effectively retained within the hollow structure.
The state is close to permanent electrification.
Further, when a mechanical impact is applied from the outside to the fibers having the hollow structure, distortion is easily caused, and therefore charging polarization can be effectively caused. For these reasons, compared to a filter with a conventional configuration, the amount of charge can be increased by about 10 times, and the change over time is extremely small. (Example) Examples will be described in detail below. 60% wool Polyester (Tetoron) hollow fibers, triangular cross section, 2D (denier) 40% Wool 60% Polyester (Tetoron) hollow fibers, cross section star shape, 4D, 40% Wool 60% as above and as above and polyester hollow fibers at a ratio of 40% and processed into a felt-like nonwoven fabric, which was subjected to resin processing and mechanical secondary processing by known methods to produce a filter. Separately, for comparison, we prepared a conventional product made of 100% wool nonwoven fabric that was treated in the same way. For the present invention product and conventional product, JIS
A test was conducted in accordance with -T-8151, and the results shown in the table below were obtained.

【表】 表から明らかなように、本発明品は、従来品に
比較して、グラム重量当りの帯電量が略1桁大き
く、また捕集効率の点で非常に優れている。 次に、本発明の作用、効果について説明する。
第1図は、中空繊維における帯電モデルを示した
ものであり、1は中空部2を有する繊維、3は繊
維1の表面に付着したフエノール系等の樹脂であ
る。一般に、繊維に樹脂を付着させ、これに粉砕
等の機械的二次加工を施すと樹脂の一部が剥離
し、樹脂は負に帯電し、繊維は正に帯電する。こ
の帯電した静電気は、通常、空気中の水分や自由
電子等により次第に放電し、帯電量が時間ととも
に減少する。これに対し、本発明で使用される中
空繊維の場合は、機械的二次加工で生じる強い圧
縮、変形、衝撃、摩擦等により繊維1の表面の負
の電気が樹脂3に移行し、繊維表面から樹脂3が
剥離、分散するため、中空繊維1の内部空間面と
繊維表面との間で強い電気的不均衡が生じ、この
瞬間にかなりの静電気を発生する。このようにし
て、中空繊維1の内部空間面も分極するため、外
部の自由電子等の衝突による影響も受けにくくな
り、静電気を長期間保持することができる。 第2図は、密封状態で保存した場合の、フイル
タ1グラム当りの帯電量(Q/g)の経時変化を
示したものである。初期の帯電量は、従来品(羊
毛100%)に比べて約10倍程度大きく、さらに経
時における帯電量の減少も非常に小さい。 第3図は、粉塵堆積量に対する捕集効率と、通
気抵抗の関係を示している。本発明品は、従来品
に比べて通気抵抗の上昇も少なく、従つて目詰り
しにくいフイルタであることがわかる。また、捕
集効率の低下も非常に少ない。 さらに第4図は、密封状態で保存した場合の捕
集効率の経時変化を示したものである。従来品が
99.4%程度まで低下しているのに対し、本発明品
は1年以上経つても99.95%以上の性能を維持し
ている。 従来の静電捕集タイプのフイルタは、高線速で
の捕集効率が極端に低下するという問題があつた
が、本発明品は、表から明らかなように、10cm/
sec.程度の線速に対しても非常に高い捕集効率を
示している。 なお、実施例では示さなかつたが、羊毛の代り
に異形断面の合成繊維を使用し、これと中空合成
繊維とを混紡して、好結果が得られた。 (発明の効果) 以上説明したように、本発明によれば、不織布
を構成する繊維に中空構造の合成繊維を含ませる
ことにより、帯電量を非常に大きくすることがで
きるとともに、経時劣化の極めて小さい空気ろ過
フイルタを提供することができる。また、本構成
のフイルタは、高線速ろ過にも十分適用すること
ができる。さらに、帯電量が大きいので、従来の
半分程度の目付量で、繊維密度を低くとつても従
来品と同等以上の粉塵捕集効率が得られ、またこ
れによつて通気抵抗が低くなり、粉塵捕集容量を
著しく増大させることができる。
[Table] As is clear from the table, the product of the present invention has an amount of charge per gram weight that is approximately one order of magnitude larger than that of the conventional product, and is also very superior in terms of collection efficiency. Next, the functions and effects of the present invention will be explained.
FIG. 1 shows a charging model for hollow fibers, in which numeral 1 represents a fiber having a hollow portion 2, and numeral 3 represents a resin such as a phenolic resin attached to the surface of the fiber 1. Generally, when a resin is attached to fibers and subjected to mechanical secondary processing such as crushing, a portion of the resin is peeled off, the resin becomes negatively charged, and the fibers become positively charged. This charged static electricity is usually gradually discharged by moisture in the air, free electrons, etc., and the amount of charge decreases over time. On the other hand, in the case of the hollow fibers used in the present invention, the negative electricity on the surface of the fiber 1 is transferred to the resin 3 due to strong compression, deformation, impact, friction, etc. caused by mechanical secondary processing, and the fiber surface Since the resin 3 is peeled off and dispersed from the hollow fiber 1, a strong electrical imbalance occurs between the inner space surface of the hollow fiber 1 and the fiber surface, and a considerable amount of static electricity is generated at this moment. In this way, since the internal space surface of the hollow fiber 1 is also polarized, it becomes less susceptible to the effects of collisions of external free electrons, etc., and static electricity can be maintained for a long period of time. FIG. 2 shows the change over time in the amount of charge (Q/g) per gram of the filter when stored in a sealed state. The initial charge amount is approximately 10 times greater than that of conventional products (100% wool), and the decrease in charge amount over time is also extremely small. FIG. 3 shows the relationship between the collection efficiency and ventilation resistance with respect to the amount of accumulated dust. It can be seen that the product of the present invention has a smaller increase in ventilation resistance than the conventional product, and is therefore a filter that is less likely to become clogged. In addition, there is very little decrease in collection efficiency. Further, FIG. 4 shows the change over time in the collection efficiency when stored in a sealed state. Conventional product
In contrast, the product of the present invention maintains a performance of 99.95% or more even after more than one year. Conventional electrostatic collection type filters had the problem of extremely low collection efficiency at high linear speeds, but as is clear from the table, the product of the present invention
It shows extremely high collection efficiency even at linear speeds of about sec. Although not shown in the examples, good results were obtained by using synthetic fibers with irregular cross sections instead of wool and blending them with hollow synthetic fibers. (Effects of the Invention) As explained above, according to the present invention, by including synthetic fibers with a hollow structure in the fibers constituting the nonwoven fabric, it is possible to greatly increase the amount of electrostatic charge, and the amount of charge is extremely high, and it is extremely resistant to deterioration over time. A small air filtration filter can be provided. Further, the filter having this configuration can be sufficiently applied to high linear velocity filtration. Furthermore, since the amount of electrostatic charge is large, it is possible to obtain dust collection efficiency equal to or higher than that of conventional products even though the fiber density is low and with a basis weight of about half that of conventional products. Capture capacity can be significantly increased.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、中空繊維における帯電モデルを示す
図、第2図は、帯電量の経時変化を示す図、第3
図は、粉塵堆積量に対する捕集効率及び通気抵抗
の関係を示す図、第4図は、捕集効率の経時変化
を示す図である。 1……中空繊維、2……中空部、3……樹脂。
Figure 1 is a diagram showing a charging model for hollow fibers, Figure 2 is a diagram showing changes in the amount of charge over time, and Figure 3 is a diagram showing a charging model for hollow fibers.
The figure shows the relationship between the collection efficiency and ventilation resistance with respect to the amount of accumulated dust, and FIG. 4 is a diagram showing the change in the collection efficiency over time. 1...Hollow fiber, 2...Hollow part, 3...Resin.

Claims (1)

【特許請求の範囲】 1 不織布に樹脂加工及び機械的二次加工を施し
てエレクトレツト化してなる静電式空気ろ過フイ
ルタにおいて、前記不織布を構成する繊維に中空
構造の合成繊維を含むことを特徴とする静電式空
気ろ過フイルタ。 2 前記不織布を構成する繊維が、中空構造の合
成繊維と羊毛とからなることを特徴とする特許請
求の範囲第1項記載の静電式空気ろ過フイルタ。 3 前記不織布を構成する繊維が、中空構造の合
成繊維と異形断面の合成繊維とからなることを特
徴とする特許請求の範囲第1項記載の静電式空気
ろ過フイルタ。
[Scope of Claims] 1. An electrostatic air filtration filter made by applying resin processing and mechanical secondary processing to an electret nonwoven fabric, characterized in that the fibers constituting the nonwoven fabric include synthetic fibers with a hollow structure. Electrostatic air filtration filter. 2. The electrostatic air filtration filter according to claim 1, wherein the fibers constituting the nonwoven fabric are made of hollow synthetic fibers and wool. 3. The electrostatic air filtration filter according to claim 1, wherein the fibers constituting the nonwoven fabric are composed of synthetic fibers having a hollow structure and synthetic fibers having an irregular cross section.
JP6595984A 1984-04-04 1984-04-04 Electrostatic type air filtration filter Granted JPS60209220A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6595984A JPS60209220A (en) 1984-04-04 1984-04-04 Electrostatic type air filtration filter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6595984A JPS60209220A (en) 1984-04-04 1984-04-04 Electrostatic type air filtration filter

Publications (2)

Publication Number Publication Date
JPS60209220A JPS60209220A (en) 1985-10-21
JPH0363406B2 true JPH0363406B2 (en) 1991-10-01

Family

ID=13302029

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6595984A Granted JPS60209220A (en) 1984-04-04 1984-04-04 Electrostatic type air filtration filter

Country Status (1)

Country Link
JP (1) JPS60209220A (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62110720A (en) * 1985-11-11 1987-05-21 Japan Vilene Co Ltd Electrostatic charged nonwoven fabric
CA2124237C (en) * 1994-02-18 2004-11-02 Bernard Cohen Improved nonwoven barrier and method of making the same
US5834386A (en) * 1994-06-27 1998-11-10 Kimberly-Clark Worldwide, Inc. Nonwoven barrier
CA2136576C (en) * 1994-06-27 2005-03-08 Bernard Cohen Improved nonwoven barrier and method of making the same
WO1996017569A2 (en) * 1994-12-08 1996-06-13 Kimberly-Clark Worldwide, Inc. Method of forming a particle size gradient in an absorbent article
CA2153278A1 (en) * 1994-12-30 1996-07-01 Bernard Cohen Nonwoven laminate barrier material
WO1996037276A1 (en) * 1995-05-25 1996-11-28 Kimberly-Clark Worldwide, Inc. Filter matrix
ZA965786B (en) * 1995-07-19 1997-01-27 Kimberly Clark Co Nonwoven barrier and method of making the same
US5834384A (en) * 1995-11-28 1998-11-10 Kimberly-Clark Worldwide, Inc. Nonwoven webs with one or more surface treatments
KR100455923B1 (en) * 2002-06-11 2004-11-06 삼성전자주식회사 Polypropylen Air Filter

Also Published As

Publication number Publication date
JPS60209220A (en) 1985-10-21

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