JPH0368A - Granule having absorbing and discharging properties - Google Patents
Granule having absorbing and discharging propertiesInfo
- Publication number
- JPH0368A JPH0368A JP1134353A JP13435389A JPH0368A JP H0368 A JPH0368 A JP H0368A JP 1134353 A JP1134353 A JP 1134353A JP 13435389 A JP13435389 A JP 13435389A JP H0368 A JPH0368 A JP H0368A
- Authority
- JP
- Japan
- Prior art keywords
- bamboo
- oxygen
- perfume
- activated
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008187 granular material Substances 0.000 title abstract description 11
- 238000007599 discharging Methods 0.000 title abstract 5
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 32
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 32
- 241001330002 Bambuseae Species 0.000 claims abstract description 32
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 32
- 239000011425 bamboo Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 150000002926 oxygen Chemical class 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 23
- 239000003205 fragrance Substances 0.000 claims description 22
- 239000002250 absorbent Substances 0.000 claims description 4
- 230000002745 absorbent Effects 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 abstract description 11
- 239000001301 oxygen Substances 0.000 abstract description 11
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 238000001179 sorption measurement Methods 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract 6
- 238000009738 saturating Methods 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 17
- 230000001877 deodorizing effect Effects 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 230000002354 daily effect Effects 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 208000035985 Body Odor Diseases 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 239000005539 carbonized material Substances 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
この発明は脱臭性を有するとともに芳香性を有する吸放
出性粉粒体およびその製法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to an absorbing/releasing powder having deodorizing properties and aromatic properties, and a method for producing the same.
〔従来の技術]
一般に、有機物の腐敗臭、体臭、煙草臭、ベット臭その
他の生活雑臭の脱臭剤として、活性炭、沸石その他の多
孔性物質が使用されている。[Prior Art] Activated carbon, zeolite, and other porous substances are generally used as deodorizing agents for decomposing organic odors, body odors, cigarette odors, bed odors, and other household odors.
このうち活性炭は、木材、ヤシ殻、液化石油ガスその他
を原料とし、この原料を炭化させ、さらに水蒸気や薬品
によって活性化して製造されている。Among these, activated carbon is manufactured by using wood, coconut shells, liquefied petroleum gas, and other raw materials as raw materials, carbonizing the raw materials, and activating the raw materials with steam or chemicals.
一方、生活雑臭に対する香料、または、衣類、食品その
他の生活用品に添加される香料として、天然香料または
人造香料が使用されている。この人造香料は、天然香料
に比較して香りが申請であり、また他の香りと混合され
た場合に異臭化し易い欠点を有していた。On the other hand, natural fragrances or artificial fragrances are used as fragrances to combat everyday odors or as fragrances added to clothing, food, and other daily necessities. This artificial fragrance has a weak fragrance compared to natural fragrances, and also has the disadvantage that it tends to give off a strange odor when mixed with other fragrances.
また、前記した脱臭剤は必ずしも人体に無害でなく、そ
のために生活用品としての用途に制限があり、さらに前
記した香料と別個に使用しなければ有効に機能しないも
のであった。Further, the above-mentioned deodorizing agents are not necessarily harmless to the human body, which limits their use as daily necessities, and they do not function effectively unless they are used separately from the above-mentioned fragrances.
(発明が解決しようとする課題〕
このように従来の技術においては、臭気成分の吸着性と
芳香性を併せ持ち、しかもそれぞれが有効に機能するも
のがなく、しかも人体に対して安全性の高い吸放出性の
薬剤がないという問題があり、これを早急に解決するこ
とが課題となっていた。(Problems to be Solved by the Invention) As described above, in the conventional technology, there is no one that has both odor component adsorption properties and aromatic properties, and that each function effectively, and that is highly safe for the human body. There is a problem that there is no releasable drug, and it has been an issue to solve this problem as soon as possible.
上記の課題を解決するために、この発明は活性化されか
つ脱臭された竹から吸放出性粉粒体を構成し、また、吸
放出性粉粒体に香料を添加して吸放出性わ)粒体を構成
し、また、磁界中を通過して準活性化された酸素を溶存
させた水に、水蒸気によって活性化された竹を浸漬した
後、乾燥して吸放出性粉粒体を製造する手段を採用した
ものである。In order to solve the above-mentioned problems, the present invention comprises an absorbent-release powder made from activated and deodorized bamboo, and also adds a fragrance to the absorbent-release powder. Bamboo activated by water vapor is immersed in water that forms the granules and semi-activated oxygen is dissolved therein by passing through a magnetic field, and then dried to produce absorptive and granular granules. This method adopted a method to do so.
(作用]
上記した様に、この発明に係る竹の粉粒体は、磁気処理
により準活性化された酸素を溶存させた水に、水蒸気に
よって活性化された11を浸漬し、脱水乾燥することに
よって製造される。(Function) As described above, the bamboo powder according to the present invention can be obtained by immersing 11 activated by water vapor in water in which oxygen has been dissolved and semi-activated by magnetic treatment, and then dehydrating and drying. Manufactured by.
この場合、磁気処理によって準活性化した酸素は、反応
性が若干高められて、常温、常圧下における酸素飽和量
を越えて水に相当N溶存でき、この溶存酸素が前記した
竹の組織内に保持されたにおい成分と作用し、このにお
い成分を水中へ溶出しやすくするものと推定される。In this case, the reactivity of the oxygen semi-activated by the magnetic treatment is slightly increased, and an equivalent amount of N can be dissolved in the water, exceeding the oxygen saturation amount at room temperature and pressure, and this dissolved oxygen is absorbed into the bamboo tissue described above. It is presumed that it acts on the retained odor components and makes it easier to elute these odor components into water.
したがって、このにおい成分が溶出した水を脱水乾燥し
た竹は、竹そのもののにおいはなくなるが、このような
竹そのもののにおい成分に代わって多孔質状の竹の組織
間に新たな芳香剤を保持するようになるものと推定され
る。Therefore, bamboo that has been dehydrated and dried from the water in which these odor components have been eluted will lose its own odor, but instead of the odor components of bamboo itself, a new aromatic agent will be retained between the porous bamboo structures. It is assumed that the
また、このような脱臭処理を行なう場合、若干の竹のに
おいを残すことは可能であり、神経の鎮静作用を存する
といわれる竹のにおいを有効に利用し、さらに他の香料
を添加して、人造香料の香りの単調性を補った芳香性を
有する吸放出性粉粒体とすることができる。In addition, when performing such deodorizing treatment, it is possible to leave a slight bamboo odor, and by effectively utilizing the bamboo odor, which is said to have a calming effect on the nervous system, and adding other fragrances, It is possible to obtain absorbing and releasing powder particles that have an aromatic property that compensates for the monotony of the scent of artificial fragrances.
この発明の吸放出性粉粒体は、活性化された竹を素材と
し、このような竹をさらに脱臭することによって製造さ
れる。The absorptive and releasable powder of the present invention is made from activated bamboo and is produced by further deodorizing such bamboo.
この場合、素材となる活性化された竹は、孟宋竹その他
の竹を種類を限らずに用い、蒸気温度80〜tso’c
で高圧の水蒸気によって蒸煮して、その後、乾燥、粉砕
して粉粒体(平均粒径0.5n〜4龍)としたものであ
る。このような粉粒体として、乾留性(たとえば竹泉産
業社製]きよら)を用いることができる。In this case, the activated bamboo used as the material is Meng-Song bamboo and other types of bamboo without limitation, and the steam temperature is 80~tso'c.
It is steamed using high-pressure steam, then dried and pulverized to form powder (average particle size 0.5n to 4n). As such a granular material, a carbonized material (for example, Kiyora manufactured by Takeizumi Sangyo Co., Ltd.) can be used.
この活性化された竹は、竹のにおいを未だ残しており、
このにおいを除去するために、脱臭処理が以下の手順で
行なわれる。すなわち、空気磁化器(中央熱器社製:エ
ヤー磁化器A型)を通過した空気を水中に曝気させ、つ
いでこの水に活性化された竹の粉粒体を浸漬し、その後
、この竹の粉粒体を脱水し、さらに加熱して乾燥を行な
う。前記した空気磁化器は、複数の永久磁石を組み合わ
せて、内部に約7200ガウスの磁界を形成したもので
あって、この強磁界中に波路を狭めて空気を高速で通し
、空気中に含まれる酸素分子の電子を賦活して、分子状
態の酸素を準活性化している。This activated bamboo still retains the smell of bamboo.
In order to remove this odor, deodorizing treatment is performed in the following manner. That is, air that has passed through an air magnetizer (manufactured by Chuo Neki Co., Ltd.: Air Magnetizer Type A) is aerated into water, and then activated bamboo powder is immersed in this water. The powder is dehydrated and further heated to dry it. The above-mentioned air magnetizer combines multiple permanent magnets to form a magnetic field of about 7,200 Gauss inside, and narrows the wave path in this strong magnetic field to pass air at high speed to reduce the amount of particles contained in the air. The electrons in oxygen molecules are activated to semi-activate molecular oxygen.
上記のようにして活性化され、かつ脱臭された竹に対し
て添加される香料は、たとえば水溶性香料(太陽香料社
製;フレグランEGC−1)などの人造香料のほか、天
然香料も用いることができる。The fragrance added to the activated and deodorized bamboo as described above may be an artificial fragrance such as a water-soluble fragrance (manufactured by Taiyo Kogyo Co., Ltd.; Fragran EGC-1), or a natural fragrance. I can do it.
この場合、液体の香料は、直接に吸放出性粉粒体に含ま
せるほか別途、吸放出性粉粒体に含浸処理した後、乾燥
して混合するとかでき、固体の香料は粉砕して混合する
。このような香料の配合量は、香料の種類によって一律
に規定されるものではないが、おおよそ吸放出性粉粒体
100重量部に対し、5〜10重量部を添加して良好な
結果を得ている。In this case, the liquid fragrance can be directly included in the absorptive powder or granules, or can be separately impregnated into the absorptive powder and then dried and mixed, and the solid fragrance can be crushed and mixed. do. The blending amount of such fragrances is not uniformly prescribed depending on the type of fragrance, but good results can be obtained by adding approximately 5 to 10 parts by weight to 100 parts by weight of the absorptive powder. ing.
実験例;
水蒸気によって活性化された平均粒径0.5mの竹の微
粉末(竹泉産業社製;きよら)を脱臭するため、空気磁
化器(中央熱器社製:エアー磁化器A型)によって準活
性化された酸素を水温26℃で9.6g/l(同温の酸
素飽和度7.99■/1)f4存させた水100リット
ルに、前記した竹の微粉末5kgを24時間浸漬し、そ
の後、ろ別して水分を除くとともに、200℃で60分
間温風乾燥した。Experimental example: In order to deodorize fine bamboo powder (manufactured by Takeizumi Sangyo Co., Ltd.; Kiyora) with an average particle size of 0.5 m activated by water vapor, an air magnetizer (manufactured by Chuo Neki Co., Ltd.: Air Magnetizer Type A) was used. ) 5 kg of the fine bamboo powder described above was added to 100 liters of water containing 9.6 g/l (oxygen saturation at the same temperature of 7.99 ■/1) of oxygen semi-activated at a water temperature of 26° C. for 24 hours. The sample was immersed for an hour, and then filtered to remove moisture and dried with hot air at 200°C for 60 minutes.
このようにして得られた吸放出性粉粒体の脱臭性を確認
するために、ポリカーボネイト製デシケータ(全体内容
積18リツトル)に試薬特級アンモニア水の10倍希釈
液0.41と試供品を入れ密閉した後、乾燥器内で10
5℃を保ち、それぞれ15分間、25分間、35分間、
50分間放置し、アンモニア水溶液を蒸発させる。つい
で、乾燥器から取り出し、残留アンモニア濃度を検知管
法により測定した。In order to confirm the deodorizing properties of the absorptive powder and granules thus obtained, a 10-fold diluted solution of reagent special grade ammonia water (0.41) and a sample were placed in a polycarbonate desiccator (total internal volume: 18 liters). After sealing, store in a dryer for 10 minutes.
Maintain the temperature at 5℃ for 15 minutes, 25 minutes, and 35 minutes, respectively.
Leave to stand for 50 minutes to evaporate the ammonia aqueous solution. Then, it was taken out from the dryer, and the residual ammonia concentration was measured by the detection tube method.
この結果を第1表に示す。The results are shown in Table 1.
第1表
第1表からも明らかなように、吸放出性粉粒体は、他の
試供品である脱臭剤A、Bの単位重量当りに比較してア
ンモニアをよく吸着し、アミン系の臭気についても同様
であろうと推定された。また、室温で1ケ月放置した後
の吸放出性粉粒体についても、同様の結果が得られた。Table 1 As is clear from Table 1, the absorptive powder adsorbs ammonia better than the other sample deodorizers A and B per unit weight, and eliminates amine-based odors. It was assumed that the same would apply to Similar results were also obtained for the absorptive powder after being left at room temperature for one month.
さらに、上記した吸放出性粉粒体200gと、香料水溶
液(太陽香料社製:フレグランEGC−1) 10gと
を前記した準活性化酸素が溶存した水1001に混合し
た後、24時間自然乾燥し、1ケ月間、室内で放置した
ものについても、同様の結果が得られ、しかも添加され
た香りと竹の微香が混和した芳香を有していることが判
明した。Further, 200 g of the absorbing/releasing powder described above and 10 g of a fragrance aqueous solution (manufactured by Taiyo Kogyo Co., Ltd.: Fragran EGC-1) were mixed with the above-mentioned water 1001 in which semi-activated oxygen was dissolved, and then air-dried for 24 hours. Similar results were obtained when the product was left indoors for one month, and it was found that the product had an aroma that was a mixture of the added scent and the faint scent of bamboo.
〔発明の効果]
以上の説明からも明らかなように、この発明の吸放出性
粉粒体は、臭気成分の吸着性と芳香性をそれぞれ有効に
機能するよう併せ持ち、しかも人体に対して安全な竹を
素材として製造されているので、食品その他の生活用品
に混入して使用できる産業上利用価値の高いものである
。[Effects of the Invention] As is clear from the above explanation, the adsorbing and releasing powder of the present invention has both adsorption properties for odor components and aromatic properties so as to function effectively, and is also safe for the human body. Since it is manufactured from bamboo, it has high industrial value as it can be mixed into food and other daily necessities.
特許出願人 新紀産業株式会社 同Patent applicant Shinki Sangyo Co., Ltd. same
Claims (3)
粉粒体。(1) Absorption-release powder made of activated and deodorized bamboo.
なる吸放出性粉粒体。(2) A absorbent-release powder obtained by adding a fragrance to the absorbent-release powder according to claim 1.
た水に、水蒸気によって活性化された竹を浸漬した後、
乾燥する請求項1記載の吸放出性粉粒体の製法。(3) After immersing bamboo activated by water vapor in water that has passed through a magnetic field and dissolved semi-activated oxygen,
2. The method for producing absorbing and releasing powder according to claim 1, wherein the material is dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1134353A JPH0368A (en) | 1989-05-26 | 1989-05-26 | Granule having absorbing and discharging properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1134353A JPH0368A (en) | 1989-05-26 | 1989-05-26 | Granule having absorbing and discharging properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0368A true JPH0368A (en) | 1991-01-07 |
| JPH0525506B2 JPH0525506B2 (en) | 1993-04-13 |
Family
ID=15126382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1134353A Granted JPH0368A (en) | 1989-05-26 | 1989-05-26 | Granule having absorbing and discharging properties |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0368A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011000428A (en) * | 2009-05-20 | 2011-01-06 | Chuniti Seiko Kk | Method of manufacturing deodorant and deodorant composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63109864A (en) * | 1986-10-27 | 1988-05-14 | 清岡 高敏 | Production of odorless powdery dry undistilled bamboo |
| JPS63150075A (en) * | 1986-12-16 | 1988-06-22 | オルガノ株式会社 | Deodorizing material |
-
1989
- 1989-05-26 JP JP1134353A patent/JPH0368A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63109864A (en) * | 1986-10-27 | 1988-05-14 | 清岡 高敏 | Production of odorless powdery dry undistilled bamboo |
| JPS63150075A (en) * | 1986-12-16 | 1988-06-22 | オルガノ株式会社 | Deodorizing material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011000428A (en) * | 2009-05-20 | 2011-01-06 | Chuniti Seiko Kk | Method of manufacturing deodorant and deodorant composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0525506B2 (en) | 1993-04-13 |
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