JPH0371390B2 - - Google Patents
Info
- Publication number
- JPH0371390B2 JPH0371390B2 JP21049983A JP21049983A JPH0371390B2 JP H0371390 B2 JPH0371390 B2 JP H0371390B2 JP 21049983 A JP21049983 A JP 21049983A JP 21049983 A JP21049983 A JP 21049983A JP H0371390 B2 JPH0371390 B2 JP H0371390B2
- Authority
- JP
- Japan
- Prior art keywords
- metal
- ceramic
- ceramics
- brazing
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002184 metal Substances 0.000 claims description 60
- 229910052751 metal Inorganic materials 0.000 claims description 60
- 239000000919 ceramic Substances 0.000 claims description 49
- 238000005219 brazing Methods 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 description 10
- 150000002739 metals Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Landscapes
- Ceramic Products (AREA)
Description
【発明の詳細な説明】
本発明は耐熱、耐摩耗及び断熱などの目的で構
造物又は部材の一部に用いられるセラミツクスを
金属へ取付けるための方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for attaching ceramics, which are used for parts of structures or members, to metal for purposes such as heat resistance, wear resistance, and heat insulation.
一般に、セラミツクスと金属との接合は困難で
ある。特に、溶接によつて接合することは不可能
である。したがつて、従来、金属とセラミツクス
との接合は、セラミツクスの表面に特殊な金属を
蒸着しこれと金属とろう付する方法、特殊な金属
を介して拡散接合を行う方法、セラミツクスを鋳
ぐるむ方法、及びボルトやスタツドなどにより機
械的に取付ける方法などが検討されている。しか
しながら、ろう付方法や拡散接合方法などは、一
般にセラミツクスが高温で使用されているため、
セラミツクスと金属との熱膨脹差に起因する応力
の発生によつて使用中に剥離を生じたり、セラミ
ツクスに割れが発生するなど、問題点が多い。一
方、ボルトやスタツドなどによる機械的な取付方
法は、取付部材や構造物の形状・寸法による制約
を受けやすいなど、いずれの方法も一長一短があ
り、実用的でない。 Generally, it is difficult to bond ceramics and metals. In particular, it is not possible to join by welding. Therefore, conventional methods for joining metals and ceramics include depositing a special metal on the surface of the ceramic and brazing it with the metal, performing diffusion bonding via a special metal, and casting the ceramics together. Methods of mechanical attachment using bolts, studs, etc. are being considered. However, brazing and diffusion bonding methods are generally used at high temperatures, so
There are many problems such as peeling during use due to stress caused by the difference in thermal expansion between the ceramic and the metal, and cracks in the ceramic. On the other hand, mechanical attachment methods using bolts, studs, etc. are susceptible to restrictions due to the shape and dimensions of the attachment member or structure, and each method has advantages and disadvantages and is not practical.
したがつて、金属へのセラミツクスの取付方法
の非常にむずかしい点がセラミツクスの利用を阻
害していることが多い。 Therefore, the extremely difficult method of attaching ceramics to metal often inhibits their use.
本発明は、先きにのべたように部材の一部とし
てセラミツクスを積極的に利用するため、従来に
ない手法により金属へセラミツクスを取付ける簡
便で確実な方法を提供するものである。すなわ
ち、本発明は、金属へセラミツクスを取付けるに
あたり、金属と接触するセラミツクスの表面に凹
みを設け、該凹み部分に上記金属より低融点の金
属ろう材を配置したのち、上記金属と上記セラミ
ツクスを所定の形状に取り付け、上記金属とセラ
ミツクスとろう材とを該ろう材が溶融する温度以
上に加熱することを特徴とするセラミツクスの取
付方法である。本発明によれば、セラミツクス表
面の凹みに装着された低融点の金属のろう材が所
定の温度に加熱されることにより溶融して金属部
材へ接合し、いわば金属部材の一部がセラミツク
スの凹みへ突出した形状となるため、金属部材か
らのセラミツクスの離脱が防止されることにな
る。 As mentioned above, the present invention actively utilizes ceramics as a part of a member, and thus provides a simple and reliable method for attaching ceramics to metal using an unprecedented method. That is, in the present invention, when attaching ceramics to metal, a recess is provided on the surface of the ceramic that comes into contact with the metal, a metal brazing material having a lower melting point than the metal is placed in the recess, and then the metal and the ceramic are placed in a predetermined position. This method of mounting ceramics is characterized in that the metal, the ceramic, and the brazing material are heated to a temperature higher than that at which the brazing material melts. According to the present invention, a low melting point metal brazing filler metal attached to a recess on the ceramic surface is heated to a predetermined temperature and melts and joins to the metal member, so that a part of the metal member is inserted into the recess of the ceramic. Since it has a protruding shape, separation of the ceramic from the metal member is prevented.
以下に、本発明の具体的実施例をのべる。 Specific examples of the present invention will be described below.
第1図は、本発明の第1実施例を示すもので、
円筒形の金属部材1の内面に円筒形のセラミツク
ス2を取付ける方法を示す。セラミツクス2の外
表面に加工された複数個の凹み2aに、低融点金
属、例えばろう材3を装着したのち円筒形のセラ
ミツクス2を第1図のように円筒形の金属部材1
の内面に装着し、所定の温度に加熱、冷却すれ
ば、ろう材3が溶融、凝固し、ろう材3と金属部
材1は金属接合を生じ、かつ、凝固したろう材3
がセラミツクスの凹み2a内に突出した形状とな
るので、両部材1及び2の離脱は防止される。 FIG. 1 shows a first embodiment of the present invention.
A method of attaching a cylindrical ceramic 2 to the inner surface of a cylindrical metal member 1 will be shown. After attaching a low melting point metal such as a brazing filler metal 3 to a plurality of depressions 2a formed on the outer surface of the ceramic 2, the cylindrical ceramic 2 is inserted into the cylindrical metal member 1 as shown in FIG.
When the brazing filler metal 3 is heated and cooled to a predetermined temperature, the brazing filler metal 3 melts and solidifies, the brazing filler metal 3 and the metal member 1 form a metal bond, and the solidified brazing filler metal 3
Since the shape protrudes into the recess 2a of the ceramic, both members 1 and 2 are prevented from coming off.
第2図は、本発明の第2実施例を示すもので、
平板の金属部材21に、リング状のセラミツクス
22を取付ける方法を示す。22aはセラミツク
ス22の内外側面に設けられた溝状の凹みで、こ
れにろう材(低融点金属)23を装着したのち、
第2図のように、所定の位置に装着される。その
後全体を加熱・冷却することによつて、ろう材2
3を溶融、かつ凝固させ、第1実施例でのべた作
用効果により、金属部材21とセラミツクス22
との離脱を防止するものである。 FIG. 2 shows a second embodiment of the present invention.
A method of attaching a ring-shaped ceramic 22 to a flat metal member 21 will be shown. 22a is a groove-shaped recess provided on the inner and outer surfaces of the ceramic 22, and after a brazing filler metal (low melting point metal) 23 is attached to this,
It is mounted in a predetermined position as shown in FIG. After that, by heating and cooling the whole, the brazing material 2
3 is melted and solidified, and the metal member 21 and the ceramic 22 are melted and solidified by the effects described in the first embodiment.
This is to prevent separation from the government.
第3図は、本発明の第3実施例を示すもので、
平板の金属部材31に、平板のセラミツクス32
を重ね合せ、両者を取付ける方法を示す。この場
合は、セラミツクス32の厚さ方向に貫通し、表
面へ開口した複数個のテーパ穴32aを設け、こ
の穴の底部にろう材33を装着し、前記と同様の
加熱・冷却を行つて両部材31及び32の離脱を
防止するもので34はテーパ穴32aを覆うため
の栓である。 FIG. 3 shows a third embodiment of the present invention,
A flat ceramic member 32 is attached to a flat metal member 31.
to show how to attach the two. In this case, a plurality of tapered holes 32a that penetrate the ceramic 32 in the thickness direction and open toward the surface are provided, a brazing material 33 is attached to the bottom of the hole, and heating and cooling are performed in the same manner as described above. It prevents the members 31 and 32 from coming off, and 34 is a plug for covering the tapered hole 32a.
第4図は、本発明の第4実施例を示すもので、
金属管41とセラミツクス管42をスリーブ44
を介して取付ける場合を示したものである。この
場合も、セラミツクス管42の一端で、スリーブ
44に挿入される部分の外表面に1個又は複数個
の溝42aを設け、その溝42aに、ろう材43
を配置したのち、第4図に示すように組立てられ
る。その後、上記取合部をろう材43の溶融点以
上の温度に加熱し、スリーブ44とろう材43を
接合させ、セラミツクス管42の離脱を防止す
る。金属管41とスリーブ44の接合は金属同士
の接合なので、通常の溶接やろう付で接合させる
ことになる。 FIG. 4 shows a fourth embodiment of the present invention.
The metal tube 41 and the ceramic tube 42 are connected to the sleeve 44.
This figure shows the case where it is installed through the In this case as well, one or more grooves 42a are provided on the outer surface of the part of the ceramic tube 42 that is inserted into the sleeve 44, and the brazing material 43 is inserted into the groove 42a.
After arranging them, they are assembled as shown in FIG. Thereafter, the joining portion is heated to a temperature higher than the melting point of the brazing material 43 to join the sleeve 44 and the brazing material 43, thereby preventing the ceramic tube 42 from separating. Since the metal tube 41 and the sleeve 44 are joined together by metals, they are joined by ordinary welding or brazing.
以上、本発明の代表的な実施例についてのべた
が、このほかにも金属部材とセラミツクス部材の
取合いに応じて本発明を利用範囲は広い。 Although typical embodiments of the present invention have been described above, the present invention can be used in a wide range of other applications depending on the combination of metal members and ceramic members.
本発明は、前にのべたようにセラミツクス部材
とろう材とは直接的に接合されるわけではない。
したがつて、両部材の熱膨脹差によつて取付完了
後に常温で使用する場合には両部材間に若干のす
き間が生じることになるので、両部材間の気密維
持が必要な場合には本発明の利用は好ましくな
い。 In the present invention, as described above, the ceramic member and the brazing material are not directly joined.
Therefore, due to the difference in thermal expansion between the two members, a slight gap will be created between the two members when used at room temperature after completion of installation. The use of is not recommended.
しかしながら、両部材間を若干のすき間が生じ
ることは高温で使用される場合の熱応力によるセ
ラミツクスの割れ防止の面に却つて好都合であ
る。しかも、使用条件によつては両部材が必ずし
も完全に接合されている必要はない場合もあり、
本発明は使用条件にある程度の制約はあるものの
その利用範囲は広いものである。例えば、石炭焚
ボイラーなどに用いられる耐摩耗バーナチツプの
噴孔、耐摩耗整流板、微粉炭の搬送用配管の一部
や、高温での耐摩耗、耐食性が要求される内燃機
関のシリンダライナ、ピストン冠、給排気弁の一
部などに効果的に利用される。 However, creating a slight gap between the two members is rather advantageous in terms of preventing cracking of the ceramic due to thermal stress when used at high temperatures. Moreover, depending on the usage conditions, it may not be necessary for both parts to be completely joined.
The present invention has a wide range of applications, although there are some restrictions on the conditions of use. For example, the nozzle holes of wear-resistant burner chips used in coal-fired boilers, wear-resistant rectifier plates, parts of pulverized coal conveyance piping, cylinder liners and pistons of internal combustion engines that require wear and corrosion resistance at high temperatures. Effectively used for crowns, parts of supply and exhaust valves, etc.
第1図は本発明の第1実施例で、同筒形の金属
とセラミツクスの嵌合を示す断面図、第2図は本
発明の第2実施例で、平板の金属とリング状のセ
ラミツクの嵌合を示す断面図、第3図は本発明の
第3実施例で、金属部材とセラミツクス部材の二
重構成を示す断面図、第4図は本発明の第4実施
例で、金属管とセラミツクス管をスリーブを介し
て嵌合することを示す断面図である。
1……金属管、2……セラミツクス管、2a…
…セラミツクス管の外表面に設けられた溝状凹
み、3……ろう材(低融点金属)、21……金属
板、22……セラミツクスの内外面に設けられた
溝状の凹み、23……ろう材、31……金属板、
32……セラミツクス板、32a……セラミツク
ス板に設けられ外面へ開口したテーパ穴、33…
…ろう材、34……栓、41……金属管、42…
…セラミツクス管、42a……セラミツクス管の
外表面に設けられた溝状の凹み、43……ろう
材、44……スリーブ。
Fig. 1 shows a first embodiment of the present invention, which is a sectional view showing how a cylindrical metal and a ceramic fit together, and Fig. 2 shows a second embodiment of the invention, which shows a cylindrical metal and a ring-shaped ceramic fitted together. FIG. 3 is a cross-sectional view showing the fitting, and FIG. 3 is a cross-sectional view showing a dual structure of a metal member and a ceramic member, and FIG. 4 is a fourth example of the present invention, in which a metal tube and FIG. 3 is a cross-sectional view showing how ceramic tubes are fitted through a sleeve. 1...Metal tube, 2...Ceramics tube, 2a...
...Groove-like depression provided on the outer surface of the ceramic tube, 3... Brazing metal (low melting point metal), 21... Metal plate, 22... Groove-like recess provided on the inner and outer surfaces of the ceramics, 23... Brazing filler metal, 31...metal plate,
32...Ceramics plate, 32a...Tapered hole provided in the ceramics plate and opened to the outer surface, 33...
...Brazing metal, 34...Plug, 41...Metal tube, 42...
...ceramics tube, 42a...groove-shaped recess provided on the outer surface of the ceramic tube, 43...brazing material, 44...sleeve.
Claims (1)
属と接触するセラミツクスの表面に凹みを設け、
該凹みの部分に上記金属より低融点の金属のろう
材を配置したのち、上記金属と上記セラミツクス
を所定の形状に取り付け、上記金属とセラミツク
スとろう材とを該ろう材が溶融する温度以上に加
熱することを特徴とするセラミツクスの取付方
法。1. When attaching ceramics to metal, make a recess on the surface of the ceramic that will come into contact with the metal,
After placing a brazing filler metal of a metal with a lower melting point than the metal in the recess, the metal and the ceramic are attached to a predetermined shape, and the metal, ceramic, and brazing filler metal are heated to a temperature higher than that at which the brazing filler metal melts. A method for installing ceramics that involves heating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21049983A JPS60103083A (en) | 1983-11-09 | 1983-11-09 | Ceramic setting method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21049983A JPS60103083A (en) | 1983-11-09 | 1983-11-09 | Ceramic setting method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60103083A JPS60103083A (en) | 1985-06-07 |
| JPH0371390B2 true JPH0371390B2 (en) | 1991-11-13 |
Family
ID=16590369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21049983A Granted JPS60103083A (en) | 1983-11-09 | 1983-11-09 | Ceramic setting method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60103083A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60204676A (en) * | 1984-02-20 | 1985-10-16 | 日本特殊陶業株式会社 | Zirconia-metal composite body |
-
1983
- 1983-11-09 JP JP21049983A patent/JPS60103083A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60103083A (en) | 1985-06-07 |
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