JPH037201A - Antifungal and deodorant agent - Google Patents
Antifungal and deodorant agentInfo
- Publication number
- JPH037201A JPH037201A JP14135389A JP14135389A JPH037201A JP H037201 A JPH037201 A JP H037201A JP 14135389 A JP14135389 A JP 14135389A JP 14135389 A JP14135389 A JP 14135389A JP H037201 A JPH037201 A JP H037201A
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial
- glass
- metal ions
- powder
- bacteria
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000843 anti-fungal effect Effects 0.000 title 1
- 239000003429 antifungal agent Substances 0.000 title 1
- 229940121375 antifungal agent Drugs 0.000 title 1
- 239000002781 deodorant agent Substances 0.000 title 1
- 230000000844 anti-bacterial effect Effects 0.000 claims description 19
- 239000011521 glass Substances 0.000 claims description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 230000001877 deodorizing effect Effects 0.000 claims description 12
- 229910021645 metal ion Inorganic materials 0.000 claims description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 description 17
- 241000894006 Bacteria Species 0.000 description 9
- 235000019645 odor Nutrition 0.000 description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009291 secondary effect Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/10—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined specially adapted for sweaty feet; waterproof
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は特に汗等によって発生する靴内の雑菌発生防止
、及び雑菌による臭い発生防止に適した抗菌・消臭剤に
関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an antibacterial/deodorizing agent that is particularly suitable for preventing the generation of bacteria in shoes caused by sweat, etc., and for preventing the generation of odor caused by bacteria.
（従来の技術）
革靴、スポーツシェーズ、スリッパ等のＷｌ物の使用後
において汗等によって履物内に雑菌が発生し不潔になっ
たり、雑菌発生によって異臭を発生したりすることがし
ばしばある。そこで天然植物性系の抗菌剤を使用したス
プレータイプの抗菌・消臭剤、あるいは金属銅の微粉末
を含有した靴下、靴の中仕切等が提案されているが、い
ずれのものも抗菌効果が小さいうえに効果の持続性が短
く履物用の抗菌・消臭剤としては十分満足できるもので
はなかった。(Prior Art) After using Wl products such as leather shoes, sports chaises, slippers, etc., bacteria often grow inside the footwear due to sweat etc., making it unclean, and the germs often generate unpleasant odors. Therefore, spray-type antibacterial/deodorizers using natural plant-based antibacterial agents, or socks and shoe dividers containing fine powder of metallic copper, etc., have been proposed, but none of these products have an antibacterial effect. It is small and has a short-lasting effect, making it unsatisfactory as an antibacterial and deodorizing agent for footwear.
（発明が解決しようとする課題）
本発明は上記したような従来の問題点を解決して、長期
間にわたり安定した、しかも強力な抗菌・消臭効果を維
持することができ、更にはその取扱いも極めて容易であ
る抗菌・消臭剤を提供するために完成されたものである
。(Problems to be Solved by the Invention) The present invention solves the above-mentioned conventional problems, maintains stable and strong antibacterial and deodorizing effects over a long period of time, and further improves its handling. It was completed to provide an antibacterial and deodorizing agent that is extremely easy to use.
（ｉ！！！題を解決するための手段）
本発明は恨、銅、亜鉛、ニッケルから選択された１種又
は２種以上の金属イオンを含有する溶解性ガラスを３０
０ μ以下に粉砕し、０．００１〜１０重量％／Ｈｒの
溶解速度を持たせたことを特徴とするものである。(Means for Solving the Problem) The present invention provides 30% of meltable glass containing one or more metal ions selected from copper, zinc, and nickel.
It is characterized by being pulverized to 0 μm or less and having a dissolution rate of 0.001 to 10% by weight/Hr.
このように本発明においては、銀、銅、亜鉛、ニッケル
等の抗菌作用を有する金属イオンを一定速度で溶出させ
ることができる溶解性ガラスの粉末により、抗菌・消臭
作用を発揮させるものである。As described above, in the present invention, antibacterial and deodorizing effects are exerted by using soluble glass powder that can elute metal ions having antibacterial effects such as silver, copper, zinc, and nickel at a constant rate. .
この熔解性ガラスとは制御された溶解速度を持つように
ガラスの物理的、化学的特性を考慮して組成を調節した
ガラスの総称であり、銀、銅、亜鉛、ニッケル等の化合
物を含有させた溶解性ガラスは数時間から数年間の任意
の期間にわたって定められた一定速度で前記の金属イオ
ンを溶出させることができる。そして溶出した銀等の金
属イオンは細菌や微生物の細胞壁へ吸着したり、細胞膜
内に濃縮していわゆるオリゴシナミー作用によって細菌
や微生物の成育を阻害し、抗菌作用を発振することとな
る。This meltable glass is a general term for glasses whose composition has been adjusted in consideration of the physical and chemical properties of the glass so as to have a controlled dissolution rate, and which contains compounds such as silver, copper, zinc, and nickel. The meltable glass can elute the metal ions at a fixed, defined rate over any period of time from hours to years. The eluted metal ions, such as silver, are adsorbed to the cell walls of bacteria and microorganisms, or are concentrated within the cell membranes, inhibiting the growth of bacteria and microorganisms through the so-called oligocynamy effect, and exhibiting an antibacterial effect.
本発明においてはこのような銀、銅、亜鉛、ニッケルか
ら選択された１種又は２種以上の金属イオンを含有する
溶解性ガラスの粉末を用いる。この粉末の粒径は３００
μ以下とし、好ましくは５〜５０μの範囲とする。こ
れは粒径が３００ μを超えると履物の中へ散布した場
合に足の裏に違和感を生じさせるおそれがあり、また粉
末の散布密度を大きくするために多量のガラス粉末を必
要とし経済上好ましくないためである。一方、粒径が５
μより細かくなるとガラス粉末の保管時において再ｄ集
する傾向が生じ、保管上の管理が困難になるためである
。また、溶解性ガラスの溶解速度は０．００１〜１０重
量％／Ｈｒの範囲とする。これは０．００１重量％／Ｈ
ｒ−Ｊｉ、ａではガラスの溶解速度が遅いために金属イ
オンの溶出が十分でなく、また履物の使用時において溶
解性ガラスの粉末が靴下等に付着して＠量ずつ外へ出る
おそれを考慮すると十分な抗菌・消臭効果が得られない
ためである。一方、１０重量％／１１ｒを超えるとガラ
スの溶解速度が早すぎるために使用時において履物の中
でベタつくおそれがあり、また保管上の管理にも難があ
るためである。なお、上記の溶解速度の測定は蒸留水１
００ｍ１（２０°Ｃ）に対してガラス粉末０．６ｇｒを
浸漬し、１時間経過後のガラス重量の減少量を表したも
のである。In the present invention, a soluble glass powder containing one or more metal ions selected from silver, copper, zinc, and nickel is used. The particle size of this powder is 300
μ or less, preferably in the range of 5 to 50 μ. If the particle size exceeds 300 μ, it may cause discomfort on the soles of the feet when dispersed into footwear, and it requires a large amount of glass powder to increase the density of powder dispersion, which is not economically desirable. This is because there is no On the other hand, the particle size is 5
This is because when the glass powder becomes finer than μ, it tends to re-aggregate during storage, making storage management difficult. Further, the melting rate of the meltable glass is in the range of 0.001 to 10% by weight/Hr. This is 0.001% by weight/H
In r-Ji, a, metal ions are not sufficiently eluted due to the slow dissolution rate of glass, and the possibility of soluble glass powder adhering to socks, etc. when wearing footwear and leaking out in small quantities is taken into consideration. This is because sufficient antibacterial and deodorizing effects cannot be obtained. On the other hand, if it exceeds 10% by weight/11r, the melting rate of the glass is too fast and there is a risk that it will become sticky inside the footwear during use, and storage management will also be difficult. Note that the above dissolution rate measurement was performed using distilled water 1
0.6g of glass powder is immersed in 00ml (20°C), and the amount of decrease in glass weight after 1 hour has passed is shown.
（作用）
このような本発明の抗菌・消臭剤は履物の中へ直接に散
布して使用されるものであり、使用時において足から出
る汗あるいは履物内に含有される僅かな水分によって溶
解性ガラスの粉末が熔解し、銀等の金属イオンが一定期
間にわたって徐々に溶出することとなる。その結果、銀
等の金属イオンの抗菌作用によって履物内における雑菌
の発生を防止し、また雑菌発生による臭いの発生を完全
に防止するのである。３
（実施例）
ＳｉＯｚ ５０モル％、ＮａｔＯ３０モル％、ａｚｏ
ｉ ２０モル％からなるガラス中に第１表に示す金属
を含有（単位二重量％）させた溶解性ガラスを作成し、
所定の粒度の粉末とした。この溶解性ガラスの粉末を新
品の安全靴でウレタン樹脂製中仕切を入れたものに対し
、一方の靴のみに２ｇｒ均一・に散布してガラス製壜工
場で働（人を対象に１週間履いてもらった。その後、中
仕切を取り出し先端部の約ＩＣ−を切取り寒天培地によ
り培養テストを実施した結果、ガラス粉末を入れないも
のは全て菌の発生があったが、粉末を入れたものはいず
れも菌の発生が見られず、本発明の抗菌性が確認できた
。(Function) The antibacterial/deodorizing agent of the present invention is used by being sprayed directly into footwear, and is dissolved by sweat from the feet or a small amount of moisture contained in the footwear during use. The glass powder melts, and metal ions such as silver are gradually eluted over a certain period of time. As a result, the antibacterial action of metal ions such as silver prevents the growth of bacteria within the footwear, and also completely prevents the generation of odors due to the growth of bacteria. 3 (Example) SiOz 50 mol%, NatO 30 mol%, azo
i. A meltable glass containing 20 mol% of the metals shown in Table 1 (unit: double weight %) was prepared,
It was made into a powder with a predetermined particle size. 2 gr of this soluble glass powder was evenly applied to one pair of new safety shoes with a urethane resin partition, and then used to work at a glass bottle factory (for people wearing them for a week). After that, we took out the inner partition, cut out approximately IC- at the tip, and conducted a culture test on an agar medium.As a result, bacteria were generated in all cases without glass powder, but in cases with powder. No bacteria were observed in either case, confirming the antibacterial properties of the present invention.
また同様のガラス粉末を、使用中の安全靴で臭気が認め
られる人を選び片方の靴内に散布して２日後に靴内の臭
気の確認をしたところ、粉末を入れない側の靴内の臭気
は依然として感じられたのに対し、粉末を入れた側の靴
内の臭気はほとんど無くなっていることが認められ、本
発明の消臭効果がｉｉ認できた。In addition, similar glass powder was applied to the inside of one of the shoes of a person who had noticed an odor in the safety shoes they were using, and the odor inside the shoe was checked two days later. Although the odor was still felt, it was observed that the odor inside the shoe on the side into which the powder had been added had almost disappeared, confirming the deodorizing effect of the present invention.
第１表
（発明の効果）
本発明は以上の説明から明らかなように、抗菌性を有す
る銀、銅、亜鉛、ニッケルから選択された１種又は２種
以上の金属イオンを長期間にわたり徐々に溶出させて優
れた抗菌・消臭作用を発揮することができるものであり
、履物用の抗菌・消臭剤として好適なものである。また
、本発明はその取扱いが極めて容易であり、使用上、保
管上においても便利であるうえ、使用時に靴下等に付着
した溶解性ガラスの粉末が洗濯の際に溶解して抗菌効果
を発揮するという二次的効果をも有するものである。こ
のように本発明は従来の問題点を一掃した抗菌・消臭剤
として、産業の発展に寄与するところは極めて大である
。Table 1 (Effects of the Invention) As is clear from the above description, the present invention gradually introduces one or more metal ions selected from silver, copper, zinc, and nickel having antibacterial properties over a long period of time. It can be eluted and exhibit excellent antibacterial and deodorizing effects, making it suitable as an antibacterial and deodorizing agent for footwear. In addition, the present invention is extremely easy to handle, convenient in use and storage, and dissolves soluble glass powder that adheres to socks, etc. during use, and exhibits an antibacterial effect when washed. It also has the secondary effect of As described above, the present invention greatly contributes to the development of industry as an antibacterial/deodorizing agent that eliminates the problems of conventional products.
Claims (1)
上の金属イオンを含有する溶解性ガラスを３００μ以下
に粉砕し、０．００１〜１０重量％／Ｈｒの溶解速度を
持たせたことを特徴とする抗菌・消臭剤。Meltable glass containing one or more metal ions selected from silver, copper, zinc, and nickel is crushed to 300μ or less and has a dissolution rate of 0.001 to 10% by weight/Hr. An antibacterial and deodorizing agent featuring:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1141353A JPH0647522B2 (en) | 1989-06-02 | 1989-06-02 | How to deodorize footwear |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1141353A JPH0647522B2 (en) | 1989-06-02 | 1989-06-02 | How to deodorize footwear |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH037201A true JPH037201A (en) | 1991-01-14 |
| JPH0647522B2 JPH0647522B2 (en) | 1994-06-22 |
Family
ID=15289999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1141353A Expired - Lifetime JPH0647522B2 (en) | 1989-06-02 | 1989-06-02 | How to deodorize footwear |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0647522B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04343796A (en) * | 1991-05-14 | 1992-11-30 | Ishizuka Glass Co Ltd | Water-soluble paper with antibacterial and anti-mold properties |
| JPH05271029A (en) * | 1992-01-30 | 1993-10-19 | Koa Glass Kk | Antibacterial and anti-caries composite glass |
| WO1995004704A1 (en) * | 1993-08-06 | 1995-02-16 | Harcros Chemicals Uk Ltd. | Zinc oxide and a process of making it |
| US5470585A (en) * | 1989-01-27 | 1995-11-28 | Giltech Limited | Medicinal substance for topical application |
| US5961843A (en) * | 1994-10-05 | 1999-10-05 | Toto Ltd. | Antimicrobial solid material, process for producing the same, and method of utilizing the same |
| JP2021054966A (en) * | 2019-09-30 | 2021-04-08 | 大日本印刷株式会社 | Sulfur-based gas-absorbing film |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4436038B2 (en) * | 2002-12-20 | 2010-03-24 | 株式会社シーボン | Method for suppressing sebum adhesion of cosmetic tool and cosmetic tool |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5729358A (en) * | 1980-06-12 | 1982-02-17 | Itt | Material sealed with glass |
| JPS60155110A (en) * | 1983-09-15 | 1985-08-15 | エステイ−シ− ピ−エルシ− | Release control device |
| JPS6115804A (en) * | 1984-06-25 | 1986-01-23 | ポツターズ・インダストリーズ・インコーポレイテツド | Fungicidal composition |
| JPS6127906A (en) * | 1984-07-16 | 1986-02-07 | Toyo Contact Lens Co Ltd | Sintered article having antimicrobial action |
| JPS62158202A (en) * | 1985-12-28 | 1987-07-14 | Sakai Glass Kk | antifouling agent |
| JPH01313531A (en) * | 1988-06-13 | 1989-12-19 | Kinki Pipe Giken Kk | Synthetic resin molding |
-
1989
- 1989-06-02 JP JP1141353A patent/JPH0647522B2/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5729358A (en) * | 1980-06-12 | 1982-02-17 | Itt | Material sealed with glass |
| JPS60155110A (en) * | 1983-09-15 | 1985-08-15 | エステイ−シ− ピ−エルシ− | Release control device |
| JPS6115804A (en) * | 1984-06-25 | 1986-01-23 | ポツターズ・インダストリーズ・インコーポレイテツド | Fungicidal composition |
| JPS6127906A (en) * | 1984-07-16 | 1986-02-07 | Toyo Contact Lens Co Ltd | Sintered article having antimicrobial action |
| JPS62158202A (en) * | 1985-12-28 | 1987-07-14 | Sakai Glass Kk | antifouling agent |
| JPH01313531A (en) * | 1988-06-13 | 1989-12-19 | Kinki Pipe Giken Kk | Synthetic resin molding |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5470585A (en) * | 1989-01-27 | 1995-11-28 | Giltech Limited | Medicinal substance for topical application |
| JPH04343796A (en) * | 1991-05-14 | 1992-11-30 | Ishizuka Glass Co Ltd | Water-soluble paper with antibacterial and anti-mold properties |
| JPH05271029A (en) * | 1992-01-30 | 1993-10-19 | Koa Glass Kk | Antibacterial and anti-caries composite glass |
| WO1995004704A1 (en) * | 1993-08-06 | 1995-02-16 | Harcros Chemicals Uk Ltd. | Zinc oxide and a process of making it |
| US5876688A (en) * | 1993-08-06 | 1999-03-02 | Elementis Uk Limited | Zinc oxide and a process of making it |
| US5961843A (en) * | 1994-10-05 | 1999-10-05 | Toto Ltd. | Antimicrobial solid material, process for producing the same, and method of utilizing the same |
| JP2021054966A (en) * | 2019-09-30 | 2021-04-08 | 大日本印刷株式会社 | Sulfur-based gas-absorbing film |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0647522B2 (en) | 1994-06-22 |
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