JPH04108175A - Softening finish - Google Patents

Abstract

PURPOSE:To provide the title finish capable of imparting various kinds of textiles with excellent flexibility, antistatic nature and elasticity, containing an inorganic or organic acid-neutralized or quaternarized product of a specific (di-long chain type) tertiary amine. CONSTITUTION:The objective water-based finish with good storage stability for a long period of time, containing 4-40wt.% of an inorganic or l-6C organic acid-neutralized product of (A) a tertiary amine compound having in the molecule two groups of formula I (R<1> is 12-22C alkyl or alkenyl) derived from a 12-22C higher alcohol or (B) another tertiary amine compound having one group of formula II and one group of formula III (R<2> is 11-21C alkyl or alkenyl) derived from a 12-22C fatty acid. Said amine compound is e.g. a compound of formula IV (R<1> is 12-22C alkyl or alkenyl; R<3> is 1-4C alkyl, etc.), or formula V (R<2> is 11-21C alkyl, etc.; R<4> is 1-4C alkyl, etc.).

Description

[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a fabric softener, and more specifically, a liquid fabric softener that can impart excellent flexibility and elasticity (fluffiness) to various fibers. It is related to.

[Prior art and problems to be solved by the invention] Currently,
Most commercially available household fabric softeners contain quaternary ammonium salts with two long-chain alkyl groups in each molecule, such as di(hardened tallow alkyl)dimethylammonium chloride. It is a composition with

The reason for this is that a small amount of quaternary ammonium salt has a good softening effect on various fibers.

However, although the above-mentioned quaternary ammonium salts have a remarkable softening effect on cotton, it is difficult to say that the effect is sufficient on synthetic fibers such as acrylic, polyester, and polyamide. However, if treated at a higher concentration, the elasticity of the clothing may decrease and the texture may be lost.

Furthermore, since the quaternary ammonium salt has strong hydrophobicity, if the stirring force is weak when adding it to the rinsing water, the dispersibility in water will be poor, and there is a risk that it will be uneven on the garment. In addition, especially when stored for a long time at low temperatures, it may thicken, become gel-like, or separate.

Commercially available softeners contain additives such as polyoxyethylene nonionic surfactants, electrolytes, and solvents in addition to the above-mentioned quaternary ammonium salts to improve dispersibility in water and long-term storage stability. However, the effects are still insufficient.

Furthermore, liquid softeners using various amines as softening bases have been known. For example, JP-A-52-59796
JP-A-58-60070 discloses a composition that imparts flexibility to fibers containing a long-chain alkylamine such as methyldi(hardened tallow alkyl)amine, and JP-A-58-60070 discloses a composition that imparts flexibility to fibers containing a long-chain alkylamine such as methyldi(hardened tallow alkyl)amine. A textile material finishing agent containing a quaternary ammonium salt and a fatty acid ester that gives smoothness and a comfortable touch is disclosed in JP-A No. 61167083.
JP-A No. 61-275474 discloses a softening agent with good dispersibility containing a quaternary ammonium compound, a condensation reaction product of a higher fatty acid and a hydroxy-lower alkyl polyamine, and an alkylamine polyglycol ether; A stable aqueous dispersion containing a (higher alkyl)cyclic amine and a Brønsted acid for treating textiles was disclosed in JP-A-64
85368 discloses a softening composition containing a di-long chain alkylamine anionic surfactant ion pair complex, a non-silicone wax and a liquid carrier, and JP-A-2-6662 discloses a hydroxy lower alkyl alkylene diamine. A fabric conditioning composition containing an amine and an amphoteric fabric conditioning agent, such as a condensate of and a higher fatty acid,
JP-A-2-14076 describes a fabric conditioning composition that imparts flexibility and antistatic properties and contains a di-long-chain alkylamine-polyfunctional carboxylic acid complex.

Further, JP-A-52-5394 describes a fabric conditioning composition containing a mono- or di-long chain alkyl alkylene diamine static electricity suppressant and a quaternary ammonium softener.

However, although these amine-containing softeners have relatively better dispersibility and storage stability than those containing quaternary ammonium salts, their softening ability is still insufficient.

[Means to solve the problem]

As a result of extensive research into fabric softeners containing amines, the present inventors found that a neutralized product of a special (di-long chain type) amine compound has excellent flexibility and can impart elasticity (fluffiness) to clothing. They discovered this and completed the present invention.

That is, in the present invention, 1! having 12 to 22 carbon atoms in the molecule! R'-0-C- group (R+
is an alkyl group or alkenyl group having 12 to 22 carbon atoms], or R'
1 -0-C- group [+ is the same as above] and 12 to 2 carbon atoms
R2-C-0- group derived from fatty acid of No. 2 [RZ is an alkyl group or alkenyl group having 11 to 21 carbon atoms]
The present invention provides an aqueous softening agent containing a neutralized product of an inorganic acid or an organic acid having 1 to 6 carbon atoms of a tertiary amine compound (B) having one tertiary amine compound (B) as a softening base.

A tertiary amine compound (
^) is a compound of the following formula (Aa) obtained by Michael addition of a lower monoalkylamine such as a lower alkylamine such as methylamine or ethylamine or a monoalkanolamine with acrylic acid, to a higher compound having 12 to 22 carbon atoms. It can be obtained by reacting with alcohol.

[In the formula, R3 represents an alkyl group or a hydroxyalkyl group having 1 to 4 carbon atoms. ] As the compound (A), those represented by the following 2 (A) are preferable.

(In the formula, R1 is an alkyl group or alkenyl group having 12 to 22 carbon atoms, and R3 is an alkyl group or hydroxyalkyl group having 1 to 4 carbon atoms.) The tertiary amine compound (B) is obtained by reacting a compound represented by the following formula (Bb) obtained by intramolecular dehydration cyclization reaction of N-alkyl or alkenyljetanolamine with a higher alcohol having 12 to 22 carbon atoms. After that, it is obtained by reacting with a fatty acid halide having 12 to 22 carbon atoms.

[In the formula, R4 represents an alkyl group having 1 to 4 carbon atoms, a hydroxyalkyl group, or an alkyl group or alkenyl group having 12 to 22 carbon atoms. ] The compound (B) is preferably represented by the following formula (B).

[In the formula, R1 is an alkyl group or alkenyl group having 12 to 22 carbon atoms, R2 is an alkyl group or alkenyl group having 11 to 21 carbon atoms, and R4 is an alkyl group having 1 to 4 carbon atoms, a hydroxyalkyl group, or an alkyl group having 12 to 22 carbon atoms. Or represents an alkenyl group. ] Examples of acids for obtaining the neutralized product of the present invention from compound (A) or (B) include inorganic acids such as hydrochloric acid, nitric acid, and phosphoric acid; acetic acid;
Examples include organic acids having 6 or less carbon atoms, such as lactic acid, glycolic acid, citric acid, and maleic acid, but hydrochloric acid is the cheapest and has the highest performance. In addition, in the neutralization step, the compound (A) or (B) may be neutralized in advance and dispersed in water, or the compound (A) or (B) may be dissolved in a liquid or solid form in an acid aqueous solution. You can also put it in. Of course, the compound (A) or (B) and the acid component may be added at the same time.

When commercializing a fabric softener that essentially includes the compound according to the present invention, the total amount of the compound according to the present invention is 4 to 40% by weight, preferably 6 to 30% by weight, especially considering the viscosity and handling properties of the product. Preferably it is 10 to 30% by weight.

The softening agent of the present invention further includes dimethylpolysiloxane,
By incorporating a silicone compound such as dimethylpolysiloxane partially modified with an amino group or a polyoxyalkylene group, particularly preferably a dimethylpolysiloxane partially modified with a polyoxyalkylene group, water absorption performance can be maintained without deterioration. The feel of softened clothing can be improved. These silicone compounds are preferably blended in an amount of 0.3 to 5% by weight based on the total amount of compounds related to the present invention.

It has been found that the softening agent of the present invention has almost the same softening effect as dihardened tallow alkyldimethylammonium chloride, which has been widely used in the past, but surprisingly provides elastic softness. .

When the composition of the present invention is used as an aqueous liquid softener, 0.05 to 0.4% by weight of an inorganic electrolyte such as sodium chloride, calcium chloride, or magnesium chloride is added to adjust the viscosity.
It is desirable to add

The fabric softener of the present invention has high stability during long-term storage, but in order to stabilize it under even more severe storage conditions, polyoxyethylene (5 to 50 mol) alkyl or alkenyl (C
+□~24) A nonionic surfactant such as ether, a solvent such as ethanol, isopropanol, propylene glycol or ethylene glycol, or urea can be blended. In addition, known esters, nonionic or cationic compounds, long chain alcohols, etc. may be used in combination as flexible bases.

In addition, pigments or dyes can be added to improve the appearance of the product, fluorescent brighteners can be added to improve the whiteness of the finished product, and fragrances can be added to improve the taste during use and after finishing.

C. Effects of the Invention The fabric softener of the present invention can impart sufficient flexibility, antistatic properties, and excellent elasticity to various fibers.

〔Example〕

Next, the present invention will be explained in detail with reference to Examples, but the present invention is not limited to these Examples. Compounds used in Examples and Comparative Examples are shown below.

table note) l) General formula (C) is shown below.

Examples 1 to 12 The compositions having the formulations shown in Table 2 were evaluated for flexibility and elasticity by the following methods.

<Evaluation of flexibility and elasticity> (1) Processing method 2 kg of commercially available cotton towels and 1 kg of acrylic chassis were repeatedly treated with commercially available detergent Attack (manufactured by Kao Corporation, registered trademark) 5 times in 3.5° DH hard water. After washing (30j2 washing machine) and removing the fiber treatment side attached to each fiber,
1.5g of the blended composition in Table 2 was added as an active ingredient,
The mixture was treated at 25° C. for 11 minutes under stirring.

In each case, 1% by weight of polyoxyethylene-modified dimethylpolysiloxane was blended based on the total amount of the compound of the present invention.

(2) Evaluation method After drying the cloth treated with the above method indoors at 25°C165
It was left for 24 hours in a thermostatic chamber at %RH.

These fabrics were evaluated for flexibility and elasticity.

The softness and elasticity were evaluated using a pair of fabrics treated with 10 cc of a fabric softener containing 15% by weight of dihydrogenated beef tallow alkyldimethylammonium chloride as a control. The evaluation is expressed as follows.

+2; Softer or more elastic than the control +1; Slightly softer or more elastic than the control O; Same as the control 1; Control is slightly softer or slightly less elastic than the control -2; Control is soft or more elastic than the control As shown in Table 2 where elasticity is low, by using the compound of the present invention, an effect that satisfies both flexibility and elasticity can be obtained.

Flexibility, Elasticity Examples 13 to 15, Comparative Examples 3 and 4 In order to evaluate the elasticity of the compositions with the formulations shown in Table 3, the stacked heights of cotton towels were measured.

<Evaluation of elasticity> Cotton towels treated in the same manner as in Examples 1 to 12 were folded into eight and stacked in three layers, and after pressurizing at a pressure of 5 g/cia for 5 minutes, the pressure was removed and the height of the towel was adjusted. was measured. The higher the height of the towel, the better the elasticity.

Procedural amendment (spontaneous) November 27, 1991 Display of incidents Patent application No. 2-221743 name of invention Softener person who makes corrections Relationship to the case Patent applicant Hana Wang Stock Company

Claims (1)

[Scope of Claims] 1. There are ▲ mathematical formulas, chemical formulas, tables, etc. derived from higher alcohols having 12 to 22 carbon atoms in the molecule ▼ group [R^1
is an alkyl group or alkenyl group having 12 to 22 carbon atoms] or a ▲ mathematical formula, chemical formula, table, etc. ▼ group [R^1 is the same as above] 1 There are ▲ mathematical formulas, chemical formulas, tables, etc. derived from fatty acids with 12 to 22 carbon atoms [R^2 is 11 carbon atoms]
~21 alkyl or alkenyl groups] The inorganic acid of the tertiary amine compound (B) having 1 or more carbon atoms
An aqueous fabric softener containing a neutralized product of organic acid No. 6 as a softening base. 2 The tertiary amine compound (A) has the following formula (A) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (A) [In the formula, R^1 is an alkyl group or alkenyl group having 12 to 22 carbon atoms, R ^3 represents an alkyl group or hydroxyalkyl group having 1 to 4 carbon atoms. The fabric softener according to claim 1, which is a compound represented by the following formula. 3 The tertiary amine compound (B) has the following formula (B) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (B) [In the formula, R^1 is an alkyl group or alkenyl group having 12 to 22 carbon atoms, R ^2 represents an alkyl group or alkenyl group having 11 to 21 carbon atoms, and R^4 represents an alkyl group or hydroxyalkyl group having 1 to 4 carbon atoms, or an alkyl group or alkenyl group having 12 to 22 carbon atoms. The fabric softener according to claim 1, which is a compound represented by the following formula.