JPH04176818A - Production of steel tube or square tube excellent in earthquake resistance - Google Patents

Production of steel tube or square tube excellent in earthquake resistance

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Publication number
JPH04176818A
JPH04176818A JP30464090A JP30464090A JPH04176818A JP H04176818 A JPH04176818 A JP H04176818A JP 30464090 A JP30464090 A JP 30464090A JP 30464090 A JP30464090 A JP 30464090A JP H04176818 A JPH04176818 A JP H04176818A
Authority
JP
Japan
Prior art keywords
steel
tube
square tube
square
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP30464090A
Other languages
Japanese (ja)
Inventor
Yasushi Yamamoto
康士 山本
Kazumasa Yamazaki
一正 山崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP30464090A priority Critical patent/JPH04176818A/en
Publication of JPH04176818A publication Critical patent/JPH04176818A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To inexpensively produce a steel tube or square tube having high strength and low yield ratio and excellent in earthquake resistance by subjecting a steel tube or square tube of low carbon steel or low carbon log alloy steel to forming at a temp. not lower than the Ac3 point and successively to controlled cooling. CONSTITUTION:A steel tube or square tube of low carbon steel or low carbon low alloy steel is heated to >=Ac3 and formed into a round tube or square tube in the above temp. range. Successively, this steel tube or square tube is cooled slowly at <=10 deg.C/sec cooling rate and subjected, if necessary, to tempering at 200-600 deg.C. The structure can be formed into a dual phase structure of clean ferrite + pearlite while removing the influence of forming by subjecting the above steel tube of square tube to slow cooling after forming, and further, the excessive softening of the secondary phase can be prevented by lowering the subsequent tempering temp. By this method, the steel tube or square tube having strength as high as >= about 40kgf/mm<2>, reduced in yield ratio, and excellent in earthquake resistance can be obtained while obviating the necessity of using particularly expensive alloying elements.

Description

【発明の詳細な説明】 [産業上の利用分野コ 本発明は、降伏比の低い鋼管または角管の製造方法に関
するものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for manufacturing steel pipes or square pipes with a low yield ratio.

[従来の技術] 近年鉄鋼材料を扱う各分野にわたって、競争力向上のた
めの使用特性の向上、製造コストの低減など各種の要求
が高まっている。
[Prior Art] In recent years, various demands have been increasing across various fields that handle steel materials, such as improving usage characteristics and reducing manufacturing costs in order to improve competitiveness.

このうち建築分野では、構造物の安全性向上のため、特
に耐震性向上のために降伏比の低下が望まれている。こ
れまでは主に厚板分野でこの要求が強かったが、最近で
は鋼管分野でこの要求がたかまっている。低降伏比を有
する厚鋼板の製造方法に関しては、種々の方法が検討さ
れているが、残念ながら鋼管の分野では、少なくとも建
築用として検討された例はほとんどないのが現状である
。例えば電縫鋼管は、ホットコイルを成形して製造する
が、成形の際の加工硬化により降伏比が上昇するため、
降伏比の低い鋼管の製造には、不利な製造方法とされて
いる。例えば、低降伏比油井用電縫鋼管の製造方法とし
て、特開昭57−16118号があるが、この方法では
低降伏比化のためにC量をかなり添加しているため(C
量: 0.26〜0.48%)、溶接性の観点からCe
q上限の規定される建築構造用には適用できない。また
同様に、低降伏比高張力電縫鋼管の製造方法として、特
開昭57−16119号があるが、これはホットコイル
の段階で極低YR鋼を製造し、電縫鋼管を製造する際の
加工硬化を押えるために、歪量をかなり制限しているが
、実操業ではかなり困難か伴う。
Among these, in the field of construction, it is desired to reduce the yield ratio in order to improve the safety of structures, especially in order to improve their seismic resistance. Until now, this requirement has been strong mainly in the thick plate field, but recently it has become stronger in the steel pipe field. Various methods have been studied for manufacturing thick steel plates with a low yield ratio, but unfortunately, in the field of steel pipes, there are currently almost no examples of such methods being studied, at least for construction purposes. For example, ERW steel pipes are manufactured by forming hot coils, but the yield ratio increases due to work hardening during forming.
It is considered to be a disadvantageous manufacturing method for manufacturing steel pipes with a low yield ratio. For example, there is a method for manufacturing ERW steel pipes for oil wells with a low yield ratio in JP-A-57-16118, but in this method a considerable amount of C is added to achieve a low yield ratio (C
amount: 0.26-0.48%), from the viewpoint of weldability
It cannot be applied to architectural structures where the upper limit of q is specified. Similarly, there is Japanese Patent Application Laid-Open No. 57-16119 as a manufacturing method for low yield ratio, high tensile resistance welded steel pipes, but this method involves manufacturing extremely low YR steel at the hot coil stage, and then manufacturing ERW steel pipes. In order to suppress work hardening, the amount of strain is considerably limited, but this is quite difficult or difficult in actual operation.

[発明が解決しようとする課題] 建築用低降伏比鋼管または、角管として、引張り強さ4
0キロ以上で降伏比80%以下という要求があるが、現
状の製造方法では製造が不可能である。つまり、ホット
コイルを丸く成形しただけで製造する非調質型、いわゆ
るアズロール型では、その成形時の加工硬化のために、
また調質型いわゆるQT型では、その組織が焼戻しマル
テンサイトとなるため、降伏比80%以下では達成され
ていない。
[Problem to be solved by the invention] As a low yield ratio steel pipe for construction or a square pipe, the tensile strength is 4
There is a requirement for a yield ratio of 80% or less at a temperature of 0 kg or more, but this is impossible with current manufacturing methods. In other words, in the non-thermal type, so-called azurol type, which is manufactured by simply molding a hot coil into a round shape, due to work hardening during molding,
In addition, in the tempered type so-called QT type, the structure becomes tempered martensite, so a yield ratio of 80% or less cannot be achieved.

また、耐震構造用として必要な鋼材の材質特性として最
近、降伏比だけでなく応力−歪曲線の形状か注目されだ
した。つまり、鋼材が充分な望性伸び能力を持つために
は、第1図、第2図で示したA。の増加が必要であると
言われ始めている。そのためには、YRの低下はもちろ
んであるが、さらに降伏点伸びの増大によって達成でき
る。第1図、第2図を比較すると明らかなように、耐震
構造用としては第2図のような鋼材が通しているといえ
る。つまり耐震構造用としては、降伏点伸びを有し、か
つ降伏比の低い鋼管または角管が必要である。
In addition, recently, attention has been paid not only to the yield ratio but also to the shape of the stress-strain curve as a material characteristic of steel materials required for earthquake-resistant structures. In other words, in order for the steel material to have sufficient desired elongation ability, A shown in Figures 1 and 2 must be achieved. It is beginning to be said that there is a need for an increase in This can be achieved not only by lowering YR, but also by increasing elongation at yield point. As is clear from comparing Figures 1 and 2, it can be said that steel materials as shown in Figure 2 are used for earthquake-resistant structures. In other words, for earthquake-resistant structures, steel pipes or square pipes that have elongation at the yield point and a low yield ratio are required.

[課題を解決するための手段] そこで本発明者らは、降伏比を低下させるために、多数
の実験と詳細な検討を加えた結果、降伏比を低下させる
ためには、鋼のミクロ組織をフェライトと第2相(パー
ライト)の2相組織にする必要性を確認した。さらに、
降伏比を下げるためには、降伏点を下げ、引張り強さを
高めることが重要であることも確認した。また降伏点を
下げ、かつ充分な降伏点伸びを出すためには、フェライ
ト組織を歪のないクリーンフェライトにすることが重要
であることを確認した。
[Means for Solving the Problems] Therefore, the present inventors conducted numerous experiments and detailed studies in order to reduce the yield ratio. The necessity of creating a two-phase structure consisting of ferrite and a second phase (pearlite) was confirmed. moreover,
It was also confirmed that in order to lower the yield ratio, it is important to lower the yield point and increase the tensile strength. It was also confirmed that in order to lower the yield point and achieve sufficient elongation at the yield point, it is important to make the ferrite structure a clean ferrite without distortion.

本発明は、このような知見に基き、耐震特性に優れた鋼
管または角管の製造を可能にしたもので、その要旨とす
るところは、低炭素鋼または低炭素低合金鋼鋼管(また
は角管)を、AC3以上に加熱し、その温度範囲で丸管
のまま成形したり、丸管から角管に成形した後、引き続
き10℃/sec以下の冷却速度で冷却し、その後必要
に応じて200〜600℃の温度範囲で焼戻しすること
を特徴とする、耐震特性に優れた鋼管または角管の製造
方法である。
Based on this knowledge, the present invention has made it possible to manufacture steel pipes or square pipes with excellent earthquake resistance. ) is heated to AC3 or above and formed into a round tube in that temperature range, or from a round tube to a square tube, and then cooled at a cooling rate of 10°C/sec or less, and then heated to 200°C as necessary. This is a method for manufacturing steel pipes or square pipes with excellent seismic properties, characterized by tempering at a temperature range of ~600°C.

[作   用] 本発明においては、加熱温度をAC3変態点以上とし、
その後徐冷することによって、パイプ成形やその後の熱
間の角管成形の影響を除去しつつ、クリーンフェライト
+パーライトの2相鋼化を達成することに成功している
[Function] In the present invention, the heating temperature is set to the AC3 transformation point or higher,
By then slowly cooling it, we succeeded in creating a dual-phase steel of clean ferrite and pearlite while removing the effects of pipe forming and subsequent hot square tube forming.

さらに焼戻し温度を低くすることによって、第2相の部
分を必要以上に軟化させないことの相乗的効果により、
降伏比が低く、かつ降伏点伸びを有した耐震特性に優れ
た鋼管または角管の製造を可能にしたものである。
Furthermore, by lowering the tempering temperature, the synergistic effect of not softening the second phase part more than necessary,
This makes it possible to manufacture steel pipes or square pipes with excellent seismic properties that have a low yield ratio and elongation at yield point.

次に本発明の鋼管製造・角管成形・加熱・冷却・テンパ
ーの条件について述べる。
Next, the conditions for manufacturing steel pipes, forming square pipes, heating, cooling, and tempering according to the present invention will be described.

まず、鋼管の製造およびその後の角管成形については、
特に規定はなくどのような方法でも許容される。例えば
鋼管はその製造方法から、シームレス鋼管、電縫鋼管、
UO鋼管、スパイラル鋼管、鍜接管等に分類できるが、
本発明はこれらのどの製造方法でも許容される。ホット
コイルのような板から直接角管に成形して溶接したもの
でも、もちろん許容される。これは、その後の熱処理で
の加熱温度を加工歪が除去される温度に規定するためで
ある。
First, regarding the manufacturing of steel pipes and the subsequent forming of square pipes,
There are no particular regulations and any method is acceptable. For example, steel pipes are manufactured using different manufacturing methods, such as seamless steel pipes, electric resistance welded steel pipes,
It can be classified into UO steel pipes, spiral steel pipes, ferruled pipes, etc.
The present invention is applicable to any of these manufacturing methods. Of course, it is also acceptable to directly form a square tube from a plate such as a hot coil and weld it. This is to set the heating temperature in the subsequent heat treatment to a temperature at which processing strain is removed.

次に成形後加熱温度をAC3以上にしたのは、この温度
範囲に加熱することによって、冷却後の2相鋼化を達成
しつつ成形歪の除去を同時に狙ったためである。すなわ
ち、加熱温度を八。。
Next, the reason why the post-forming heating temperature was set to AC3 or higher was that by heating to this temperature range, it was possible to achieve duplex steel after cooling and simultaneously eliminate forming distortion. In other words, the heating temperature is 8. .

以下にすると、2相鋼化するものの、フェライトに加工
歪が残存するためにフェライトの強度が高く、結果的に
低降伏比を達成することができない。
If the steel is made below, although it becomes a dual-phase steel, the strength of the ferrite is high because of residual working strain in the ferrite, and as a result, a low yield ratio cannot be achieved.

AC3以上での成形は、加工歪が瞬時に除去されるため
に、最終製品の材質に問題とはならない。そのため、サ
イジング処理や引き抜き処理、および丸管から角管への
成形等、どのような成形でも許容される。
Molding at AC3 or higher eliminates processing strain instantly, so there is no problem with the material quality of the final product. Therefore, any type of molding, such as sizing treatment, drawing treatment, and molding from a round tube to a square tube, is acceptable.

AC3以上に加熱後の冷却速度を10℃/sec以下と
したのは、再加熱時にオーステナイト化してCの濃化し
た部分からクリーンフェライトとパーライトの2相組織
とすることで、引張り強さを高め低降伏比を得るためで
ある。冷却速度が大きいと、オーステナイトからフェラ
イト十パーライトへの変態が不十分となり、$2相にベ
ーナイトやマルテンサイトが含まれた組織となるため、
降伏比は低いが降伏点伸びがなく、結局耐震特性の劣化
した材質となる。冷却速度が10℃/sec以下であれ
ば良いということで、通常は空冷を採用するが、冷却速
度を満足すれば、その方法は問わない。
The reason why the cooling rate after heating to AC3 or higher is set to 10℃/sec or less is that the tensile strength is increased by converting the C-enriched part into austenite during reheating to create a two-phase structure of clean ferrite and pearlite. This is to obtain a low yield ratio. If the cooling rate is high, the transformation from austenite to ferrite and pearlite will be insufficient, resulting in a structure containing bainite and martensite in the $2 phase.
Although the yield ratio is low, there is no elongation at the yield point, resulting in a material with deteriorated seismic properties. Air cooling is usually adopted as it is sufficient if the cooling rate is 10° C./sec or less, but any method may be used as long as the cooling rate is satisfied.

ところで、鋼種によっては加熱後徐冷だけでは靭性のよ
くないものがあり、靭性改善のために冷却後焼戻し処理
の必要な場合がある。その際焼戻し温度としては、フェ
ライトと第2相のパーライトの2相組織について、その
前の空冷である程度硬化したパーライトをあまり高温で
焼戻すと軟化しすぎ、これが引張り強さの低下つまり降
伏比の上昇の原因となるため、上限を600℃とした。
By the way, depending on the type of steel, there are some steels whose toughness is not good only by slow cooling after heating, and it may be necessary to perform tempering treatment after cooling in order to improve the toughness. At this time, the tempering temperature is determined as follows: Regarding the two-phase structure of ferrite and second phase pearlite, if pearlite, which has been hardened to some extent by air cooling, is tempered at too high a temperature, it will become too soft, resulting in a decrease in tensile strength, or a decrease in yield ratio. The upper limit was set at 600°C to avoid this.

しかし焼戻し温度が低くて、200℃未満になるとほと
んど焼戻しの効果がなくなり、靭性が改善されない場合
があるため、その下限を200℃とした。
However, if the tempering temperature is too low to be less than 200°C, the tempering effect will be almost gone and the toughness may not be improved, so the lower limit was set at 200°C.

本発明法は低炭素鋼またはこれに特殊元素を添加した低
炭素低合金鋼に適用して好結果を得ることができる。好
ましい成分組成としては、C:  0.03〜0.30
% St :  0.02〜0.50% Mn :  0.2(1〜2.00% An : 0.001〜0.100% N  :  0.0005〜0.0100%を成分とす
る低炭素鋼、または前記成分の他に強度鋼の要求特性に
よって、 Cu:2.0%以下 Ni : 9.5%以下 Cr:5.5%以下 Ti : 0.15%以下 B : 0.0003〜0.0030%Ca : 0.
0080%以下 の1種または2種以上添加してもよい。
The method of the present invention can be applied to low carbon steel or low carbon low alloy steel to which special elements are added with good results. A preferred component composition is C: 0.03 to 0.30.
% St: 0.02-0.50% Mn: 0.2 (1-2.00% An: 0.001-0.100% N: 0.0005-0.0100% Low carbon steel , or depending on the required properties of the strength steel in addition to the above components: Cu: 2.0% or less Ni: 9.5% or less Cr: 5.5% or less Ti: 0.15% or less B: 0.0003-0. 0030%Ca: 0.
0080% or less of one type or two or more types may be added.

Cuは強度上昇、耐食性向上に有用で添加されるが、 
2.0%を越えて添加しても強度の上昇代がほとんどな
くなるので、含有量の上限は2.0%とする。
Cu is added because it is useful for increasing strength and improving corrosion resistance, but
Even if it is added in excess of 2.0%, there is almost no increase in strength, so the upper limit of the content is set at 2.0%.

Niは低温靭性の改善に有用で添加されるが、高価な元
素であるため含有量は9.5%を上限とする。
Ni is added because it is useful for improving low-temperature toughness, but since it is an expensive element, the upper limit of the content is 9.5%.

Crは強度上昇や耐食性向上に有用で添加されるが、多
くなると低温靭性、溶接性を阻害するため含有量は5.
5%を上限とする。
Cr is added because it is useful for increasing strength and improving corrosion resistance, but if it increases, it impedes low temperature toughness and weldability, so the content should be 5.
The upper limit is 5%.

Tiはオーステナイト粒の細粒化に有用で添加されるが
、多くなると溶接性を阻害するため、含有量は0.15
%を上限とする。
Ti is added because it is useful for refining austenite grains, but if it increases, it inhibits weldability, so the content is 0.15
The upper limit is %.

Bは微量の添加によって、鋼の焼入性を著しく高める効
果を有する。この効果を有効に得るためには、少なくと
も0.0003%を添加することが必要である。しかし
過多に添加するとB化合物を生成して、靭性を劣化させ
るので、上限は0.0030%とする。
When added in a small amount, B has the effect of significantly increasing the hardenability of steel. In order to effectively obtain this effect, it is necessary to add at least 0.0003%. However, if added in excess, B compounds will be generated and the toughness will deteriorate, so the upper limit is set at 0.0030%.

Caは硫化物系介在物の形態制御に有用で添加されるが
、多くなると鋼中介在物を形成し鋼の性質を悪化させる
ため、含有量はo、ooao%を上限とする。
Ca is added because it is useful for controlling the form of sulfide-based inclusions, but if it increases, it forms inclusions in the steel and deteriorates the properties of the steel, so the upper limit of the content is set at o, ooao%.

[実 施 例] 第1表に供試材の化学成分を示し、第2表に鋼管または
角管のサイズ、熱処理条件と、得られた鋼管の機械−的
性質を示す。
[Example] Table 1 shows the chemical composition of the test materials, and Table 2 shows the size of the steel pipe or square pipe, heat treatment conditions, and mechanical properties of the obtained steel pipe.

第2表で示した鋼管No、AI、 Bl、C1、Dl、
El、Fl、 Gl、Hl、T1、Jl、K1、Ll、
Ml、N1.01、Pl、Ql、R1,51、T1、U
l、vlはそれぞれ本発明実施鋼であり、本発明の狙い
とする低降伏比(降伏比80%以下)を達成している。
Steel pipe No. shown in Table 2, AI, Bl, C1, Dl,
El, Fl, Gl, Hl, T1, Jl, K1, Ll,
Ml, N1.01, Pl, Ql, R1,51, T1, U
1 and vl are steels according to the present invention, which have achieved the low yield ratio (yield ratio of 80% or less) targeted by the present invention.

これに対し、A2.A3は加熱温度が低すぎるため降伏
比が高くなっている(フェライトが完全にクリーンにな
っていない)。A4は加熱後の冷却速度が高すぎるため
Acが低くなっている(降伏点伸びが出てないため)。
On the other hand, A2. A3 has a high yield ratio because the heating temperature is too low (ferrite is not completely clean). A4 has a low Ac because the cooling rate after heating is too high (because no elongation at yield point has been achieved).

A5は焼戻し温度が高すぎるため降伏比が高くなってい
る。
A5 has a high yield ratio because the tempering temperature is too high.

また、B2は焼戻し温度が高すぎるため降伏比が高くな
っている。C2は冷却速度が高すぎるためAcが低くな
っている。B2は加熱温度が低すぎるため降伏比が高く
なっている。
Further, B2 has a high yield ratio because the tempering temperature is too high. C2 has a low Ac because the cooling rate is too high. B2 has a high yield ratio because the heating temperature is too low.

[発明の効果コ 以上詳細に説明した通り、本発明は特別に高価な合金元
素を使用することなく、40kgf/mm’以上の高強
度を有する低降伏比鋼管または角管を、安価に製造可能
としたもので、産業上その効果は大である。
[Effects of the Invention] As explained in detail above, the present invention enables low-yield ratio steel pipes or rectangular pipes with high strength of 40 kgf/mm' or more to be manufactured at low cost without using particularly expensive alloying elements. As a result, the industrial effects are significant.

【図面の簡単な説明】 第1図、第2図は鋼材のストレス−ストレインの関係を
示す図である。 第1図 第2図
BRIEF DESCRIPTION OF THE DRAWINGS FIGS. 1 and 2 are diagrams showing the stress-strain relationship of steel materials. Figure 1 Figure 2

Claims (1)

【特許請求の範囲】 1 低炭素鋼または低炭素低合金鋼鋼管または角管を、
A_C_3以上に加熱し、その温度範囲で成形した後、
引き続き10℃/sec以下の冷却速度で冷却すること
を特徴とする、耐震特性に優れた鋼管または角管の製造
方法。 2 低炭素鋼または低炭素低合金鋼鋼管または角管を、
A_C_3以上に加熱し、その温度範囲で成形した後、
引き続き10℃/sec以下の冷却速度で冷却し、その
後200〜600℃の温度範囲で焼戻しすることを特徴
とする、耐震特性に優れた鋼管または角管の製造方法。 3 低炭素鋼または低炭素低合金鋼鋼管を、A_C_3
以上に加熱し、その温度範囲で丸管を角管に成形した後
、引き続き10℃/sec以下の冷却速度で冷却するこ
とを特徴とする、耐震特性に優れた角管の製造方法。 4 低炭素鋼または低炭素低合金鋼鋼管を、A_C_3
以上に加熱し、その温度範囲で丸管を角管に成形した後
、引き続き10℃/sec以下の冷却速度で冷却し、そ
の後200〜600℃の温度範囲で焼戻しすることを特
徴とする、耐震特性に優れた角管の製造方法。
[Claims] 1. Low carbon steel or low carbon low alloy steel pipe or square pipe,
After heating to A_C_3 or higher and molding in that temperature range,
A method for producing a steel pipe or square pipe with excellent seismic properties, characterized by successively cooling at a cooling rate of 10° C./sec or less. 2 Low carbon steel or low carbon low alloy steel pipe or square pipe,
After heating to A_C_3 or higher and molding in that temperature range,
A method for manufacturing a steel pipe or square pipe with excellent seismic properties, which comprises subsequently cooling at a cooling rate of 10°C/sec or less, and then tempering at a temperature range of 200 to 600°C. 3 Low carbon steel or low carbon low alloy steel pipe, A_C_3
A method for producing a square tube with excellent seismic properties, which comprises heating to a temperature above and forming a round tube into a square tube within that temperature range, followed by cooling at a cooling rate of 10° C./sec or less. 4 Low carbon steel or low carbon low alloy steel pipe, A_C_3
Earthquake-resistant, characterized by heating the round tube to a temperature above and forming the round tube into a square tube within that temperature range, followed by cooling at a cooling rate of 10°C/sec or less, and then tempering at a temperature range of 200 to 600°C. A method for manufacturing square tubes with excellent properties.
JP30464090A 1990-11-09 1990-11-09 Production of steel tube or square tube excellent in earthquake resistance Pending JPH04176818A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30464090A JPH04176818A (en) 1990-11-09 1990-11-09 Production of steel tube or square tube excellent in earthquake resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30464090A JPH04176818A (en) 1990-11-09 1990-11-09 Production of steel tube or square tube excellent in earthquake resistance

Publications (1)

Publication Number Publication Date
JPH04176818A true JPH04176818A (en) 1992-06-24

Family

ID=17935470

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30464090A Pending JPH04176818A (en) 1990-11-09 1990-11-09 Production of steel tube or square tube excellent in earthquake resistance

Country Status (1)

Country Link
JP (1) JPH04176818A (en)

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